WO2009101822A1 - Procédé de production d'une pièce moulée composite - Google Patents

Procédé de production d'une pièce moulée composite Download PDF

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Publication number
WO2009101822A1
WO2009101822A1 PCT/JP2009/000583 JP2009000583W WO2009101822A1 WO 2009101822 A1 WO2009101822 A1 WO 2009101822A1 JP 2009000583 W JP2009000583 W JP 2009000583W WO 2009101822 A1 WO2009101822 A1 WO 2009101822A1
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WIPO (PCT)
Prior art keywords
mold
resin
temperature
molding
thermoplastic resin
Prior art date
Application number
PCT/JP2009/000583
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English (en)
Japanese (ja)
Inventor
Yasumitsu Miyamoto
Akihiro Mochizuki
Tatsuya Kanezuka
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Polyplastics Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polyplastics Co., Ltd. filed Critical Polyplastics Co., Ltd.
Priority to CN2009801049845A priority Critical patent/CN102089134A/zh
Publication of WO2009101822A1 publication Critical patent/WO2009101822A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14311—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles using means for bonding the coating to the articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B29C45/72—Heating or cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B29C45/76—Measuring, controlling or regulating
    • B29C45/78—Measuring, controlling or regulating of temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2705/00—Use of metals, their alloys or their compounds, for preformed parts, e.g. for inserts

Definitions

  • the present invention relates to a method for producing a composite molded product of at least one thermoplastic resin selected from polyarylene sulfide resin and polyamide resin and a metal part, and in particular, ensures excellent adhesion between the resin and the metal part.
  • the present invention relates to a method for manufacturing a composite molded article having an improved molding cycle.
  • Composite molded products composed of resin and metal typified by insert molded products are used in the manufacture of electrical / electronic parts, automobile parts and the like.
  • the close contact between the metal insert and the resin interface is not sufficient by a normal molding method, and it causes dropout or gas / liquid leakage from the interface.
  • a method is known in which irregularities are formed by surface treatment of a metal and a molten resin is injected there. According to this method, a resin-metal composite molded product with excellent interface adhesion can be obtained.
  • chemicals are used for surface treatment, it is costly to introduce such as equipment installation and chemical management. There are many difficult points from up.
  • JP 2001-1382 by performing the control of pouring the molten resin into the system heated above the melting point by the insert heating method, maintaining the pressure, further lowering the temperature and raising the load pressure, Although a technique for improving the adhesion between the resin and the metal has been proposed, it is required to strictly control the temperature and pressure, and the incidental facilities tend to increase, so it cannot be said that it is highly practical.
  • JP 2001-1382 assumes low density polyethylene resin, polypropylene, polystyrene, and the like. In the case of polyarylene sulfide resin and polyamide resin, the method disclosed in JP 2001-1382 A A composite molded article with good metal adhesion cannot be obtained.
  • Japanese Patent Application Laid-Open No. 2005-342922 proposes to improve the adhesion strength between metal and resin by using a die surface-treated with a diamond-like carbon coating. There was a problem that molding could not be performed in cycle time. Disclosure of the invention
  • the object of the present invention is to solve the above-mentioned problems of the prior art, to shorten the molding cycle time, and to provide a composite molded product of resin and metal having stable and good adhesion.
  • the present inventors have performed molding by controlling the temperature of the molding die to a specific condition, and for that purpose, using a molding die having a specific structure. It has been found that it is extremely effective, and the present invention has been completed.
  • the present invention is a method for producing a composite molded product of at least one thermoplastic resin selected from polyarylene sulfide resin and polyamide resin and a metal part,
  • the molding die has a main mold for controlling the interlocking with the molding machine, and a portion where a thermoplastic resin having a heating circuit and a cooling circuit for temperature control and a metal part are in contact with each other. Divided into pieces that are included in (2) The portion where resin flows in and comes into contact with the mold during molding is surface-treated with a 10-point average roughness (Rz) of 0.5 ⁇ m or less, and the volume of the piece mold is 60 cm 3 or less.
  • Rz 10-point average roughness
  • thermoplastic resin in a state where the die mold temperature is heated to 200 ° C to the melting point of the thermoplastic resin.
  • the piece-shaped heating circuit is immediately shut off, and the piece-shaped cooling circuit is rapidly cooled at a cooling rate of 7 ° C./second or more. It is a manufacturing method.
  • thermoplastic resin metals it has become possible to produce a composite molded article having improved adhesion between a thermoplastic resin and a metal, which has been insufficient with the conventional method.
  • excellent adhesion between thermoplastic resin metals can be ensured in a shorter molding cycle by temperature control simpler than the conventional method.
  • FIG. 1 is a view showing an example of a piece shape used in the present invention.
  • (A) is a top view of a piece shape on the metal component set side
  • (b) is a side sectional view
  • (c) is a metal component opposite set.
  • (d) is a side cross-sectional view.
  • FIG. 2 is a view showing an example of a metal part used in the present invention.
  • FIG. 3 is a view showing an example of a composite molded product obtained by the present invention, in which (a) is a top view, (b) is a bottom view, (c) is a side view, and (d) is a side cross-sectional view.
  • FIG. 4A and 4B are schematic views showing the state of airtightness evaluation, where FIG. 4A is a schematic cross-sectional view, and FIG. 4B is a schematic perspective view.
  • FIG. 1 is a view showing another example of a piece shape used in the present invention.
  • (A) is a top view of a piece shape on the metal component set side
  • (b) is a side sectional view
  • (c) is a metal component.
  • (d) is a side cross-sectional view.
  • FIG. 6 is a view showing another example of the composite molded product obtained by the present invention, in which (a) is a top view and (b) is a side view.
  • FIG. 7 is a schematic diagram showing the situation of adhesion strength evaluation.
  • (A) is a schematic side view
  • (b) is a schematic front view.
  • the metal parts used in the present invention are not particularly limited in materials, and examples thereof include metals such as copper, aluminum and iron, alloys such as phosphor bronze and stainless steel, bonded bodies of different metals, and plated products thereof. .
  • Examples of stainless steel include martensite and austenite.
  • the metal part used in the present invention is a shape processed into a predetermined shape, and the shape is not particularly limited.
  • the metal part is an insert part, there is no particular limitation on the shape thereof, and one end part of the insert part is exposed or protrudes outside the molded product, for example, terminals of electric / electronic parts. Can be mentioned.
  • Metal parts generally have fine irregularities on rolled plates, etc., and can be adhered without special roughening treatment, but further adhesion can be achieved by roughening the surface. It is more preferable to perform surface treatment for improving the property.
  • Examples of the roughening treatment include a method of forming a porous shape by surface polishing, plating, etching, or the like.
  • thermoplastic resin and the metal In order to improve the adhesion between the thermoplastic resin and the metal, it is important to control the temperature of the metal part where the thermoplastic resin and the metal part are in contact with each other. It is necessary to design the frame shape so as to include the part where the metal part and the metal part are in contact.
  • the molding cycle can be shortened.
  • the target molding cycle cannot be shortened, the volume of the piece mold must be 60 cm 3 or less, and the outer peripheral portion in contact with the main mold of the piece mold needs to be heat-insulated.
  • a method such as providing a heat insulation layer is simple. When the volume of the piece shape exceeds 60 cm 3 , the molding cycle becomes long in normal equipment, which is not preferable.
  • the piece mold is molded with the piece mold embedded in the main mold, if the heat insulating layer is not provided, the instantaneous temperature change of the piece mold is impossible and the molding cycle cannot be shortened.
  • a heat insulating plate is used as the heat insulating layer, but it may be a heat insulating layer such as an air cap and is not particularly limited to this method.
  • the heat insulating plate include glass reinforced polyester, glass epoxy laminated plate, phenol resin and the like.
  • the portion where the resin flows in and comes into contact with the main mold and the piece mold is surface-treated so that the ten-point average roughness (Rz) is 0.5 ⁇ m or less. is necessary. If the ten-point average roughness (Rz) is greater than 0.5 ⁇ m, the resin will be in close contact with the mold (piece mold), and a good composite molded product cannot be obtained due to mold release failure.
  • any surface treatment may be used as long as the surface roughness is within the above range, but specifically, a surface treatment such as diamond-like carbon coating (DLC), CrN, Cr plating, etc. Surface treatment with a diamond-like carbon coating is preferred from the standpoint of corrosion resistance and abrasion resistance.
  • thermoplastic resin is injected and filled while being heated to a temperature range of 230 ° C. to the melting point of the thermoplastic resin.
  • the die temperature of the piece is lower than 200 ° C, the adhesion between the thermoplastic resin and the metal parts is reduced, and if the melting point of the thermoplastic resin is exceeded, the resin is difficult to solidify in the mold, causing problems in the molding process. May occur, which is not preferable.
  • thermoplastic resin is filled around the metal part and the thermoplastic resin is sufficiently pressed against the heated metal part by the injection pressure, and before that, if the temperature of the metal part falls below the above temperature, There arises a problem that the adhesion between the plastic resin and the metal part is insufficient. Therefore, after the thermoplastic resin is injected and filled, and the thermoplastic resin is completely filled in the molding die, the piece-shaped heating circuit is immediately shut off for release, and the piece-shaped cooling circuit is used. It is necessary to rapidly cool at a cooling rate of more than a second. As a result, the thermoplastic resin and the metal part can be brought into close contact with each other in a short time.
  • Both the main mold for controlling the interlocking with the molding machine and the block mold having a heating circuit and a cooling circuit for temperature control are heated by a heating element which is a method for heating a normal mold. And a method of heating with a heat medium.
  • a method of heating with a heating element a method of heating with a heater electrically insulated from a mold, an electromagnetic induction heater or a heat medium can be mentioned.
  • Examples of the method of heating with a heater electrically insulated from the mold include a method of embedding a sheath wire heater or the like in the mold, or a method of attaching a heating plate embedded with a heater to the mold surface.
  • a method for heating with a heat medium there is a method in which a heat medium flow path is provided in a mold, and a heat medium having a predetermined temperature is supplied from the outside and discharged.
  • a heat medium Fluids, such as oil, water, air, nitrogen, a combustion gas, are mentioned, In the case of a vapor
  • the main mold that maintains a constant temperature is not particularly limited, but as a piece-shaped heating method that requires instantaneous temperature control, a heating method using a heating element such as a heater is preferably used.
  • a heating method using a heating element such as a heater is preferably used.
  • the piece heating circuit is immediately shut off and rapidly cooled at a cooling rate of 7 ° C./second or more by the piece cooling circuit.
  • the heat medium is not particularly limited, and examples thereof include fluids such as oil, water, air, nitrogen, and combustion gas.
  • a cooling flow path is provided in the block shape as a cooling circuit, and the flow path is in the air.
  • Examples include a method in which low-temperature air in which moisture is condensed or solidified and frozen is allowed to pass, and the piece in contact with the metal part is cooled by heat of melting ice or heat of vaporization of moisture.
  • FIG. 1 is a view showing an example of a piece shape for holding a metal part in order to manufacture a composite molded product by the method of the present invention.
  • FIG. 1 has a piece shape that includes the entire metal part, it is not necessary to include the entire metal part, and the portion where the thermoplastic resin and the metal part are in contact is included in the interior to provide good adhesion.
  • the composite molded product can be obtained.
  • FIG. 1 is provided with a heat insulating plate 4 as shown in FIG. 1, embedded in the main mold (not shown), and used as a molding die.
  • the heating component (bar heater) 3 is a heater that raises the piece shape to a predetermined temperature as a heating circuit.
  • the flow path 2 allows low-temperature air to pass through low-temperature air in which moisture in the air is dewed or solidified and frozen, and cools the block shape by heat of melting ice or heat of vaporization of water. It becomes the flow path.
  • thermoplastic resin used in the present invention is at least one selected from polyarylene sulfide resins and polyamide resins.
  • the polyarylene sulfide resin is mainly composed of-(Ar-S)-(where Ar is an arylene group) as a repeating unit.
  • the arylene group include p-phenylene group, m-phenylene group, o-phenylene group, substituted phenylene group, p, p′-diphenylene sulfone group, p, p′-biphenylene group, and p, p′-di.
  • a phenylene ether group, p, p′-diphenylenecarbonyl group, naphthalene group, and the like can be used.
  • a copolymer containing different types of repeating units is used from the viewpoint of processability of the composition. It may be preferable.
  • polyphenylene sulfide using p-phenylene group as an arylene group and p-phenylene sulfide group as a repeating unit is preferably used.
  • the copolymer among the arylene sulfide groups comprising the above-mentioned arylene groups, two or more different combinations can be used, and among them, a combination containing a p-phenylene sulfide group and an m-phenylene sulfide group is particularly preferably used. It is done.
  • those containing p-phenylene sulfide groups of 70 mol% or more, preferably 80 mol% or more are suitable from the viewpoint of physical properties such as heat resistance, moldability and mechanical properties.
  • polyarylene sulfide resins a high molecular weight polymer having a substantially linear structure obtained by condensation polymerization from a monomer mainly composed of a bifunctional halogen aromatic compound can be preferably used.
  • a low molecular weight linear structure polymer that can be used and heated at a high temperature in the presence of oxygen or an oxidant to increase the melt viscosity by oxidative crosslinking or thermal crosslinking to improve molding processability, or a mixture thereof Can also be used.
  • the polyarylene sulfide resin is mainly composed of the linear polyarylene sulfide resin, and a part of the polyarylene sulfide resin (1 to 30% by weight, preferably 2 to 25% by weight) has a relatively high viscosity (resin temperature 310 ° C.,
  • a mixed system with a branched or crosslinked polyarylene sulfide resin having a melt viscosity of 300 to 3000 Pa ⁇ s, preferably 500 to 2000 Pa ⁇ s at a shear rate of 1200 sec ⁇ 1 is also suitable.
  • the polyarylene sulfide resin used in the present invention is preferably a polyarylene sulfide resin that has been subjected to acid cleaning, hot water cleaning, organic solvent cleaning (or a combination thereof) and the like to remove by-product impurities and the like after polymerization.
  • examples of the polyamide resin include various known polyamide resins.
  • dicarboxylic acids such as oxalic acid, adipic acid, suberic acid, sebacic acid, terephthalic acid, isophthalic acid, 1,4-cyclohexyl dicarboxylic acid and ethylenediamine, pentamethylenediamine, hexamethylenediamine, decamethylenediamine, 1,4- Polyamide resins obtained by polycondensation with diamines such as cyclohexyldiamine and m-xylylenediamine; Polyamide resins obtained by polymerizing cyclic lactams such as caprolactam and laurin lactam; or salts of cyclic lactam and diamine Examples thereof include a polyamide resin obtained by copolymerization. Among these polyamide-based resins, 6 nylon, 66 nylon, 12 nylon, 46 nylon, MXD6 nylon, and copolymers thereof are preferable.
  • a polyamide elastomer resin can also be used as the polyamide resin.
  • the polyamide elastomer resin is a polyamide block copolymer having a flexural modulus of 10,000 kgf / cm 2 or less (50% relative humidity, 23 ° C.) in which a polyamide hard segment and other soft segments are bonded.
  • a typical example of such an elastomer soft segment is polyalkylene oxide (alkylene group having 2 to 6 carbon atoms).
  • examples of the polyamide component of the hard segment include polyamides such as polyamide 6, polyamide 66, polyamide 6,12, polyamide 11, and polyamide 12.
  • Polyether components as the soft segment include polyoxyethylene glycol, polyoxy Examples include propylene glycol and polyoxytetramethylene glycol.
  • thermoplastic resin used in the present invention may be either a polyarylene sulfide resin or a polyamide resin, or both may be used in combination.
  • two or more polyarylene sulfide resins can be used in combination or two or more polyamide resins can be used in combination in order to adjust the target physical property value.
  • thermoplastic resin used in the present invention can also be used as a resin composition containing an elastomer, and a polyphenylene sulfide resin composition containing an elastomer is particularly preferred because the effect of the present invention is remarkable.
  • Any elastomer can be included as long as it has heat resistance that does not cause significant decomposition during the melt processing of the thermoplastic resin. From the viewpoint of heat resistance, an ethylene copolymer is preferred. .
  • Examples of the ethylene copolymer include an ethylene copolymer mainly composed of ethylene and a glycidyl ester of ⁇ , ⁇ -unsaturated acid, an ethylene copolymer mainly composed of ethylene and an alkyl ester of ⁇ , ⁇ -unsaturated acid, ethylene And ethylene copolymers of ⁇ -olefins having 5 or more carbon atoms.
  • a graft copolymer in which a third component such as acrylic acid, methyl acrylate, methacrylic acid, acrylonitrile, styrene or the like is branched or crosslinked chemically bonded to these ethylene ethylene copolymers may be used.
  • the elastomer content is preferably 1 to 15% by weight of the entire composition.
  • the resin may contain various resin additives and fillers.
  • [Usage] The composite molded article obtained by the present invention can be widely used for electric / electronic parts, automobile parts and the like.
  • A Polyphenylene sulfide (PPS) resin, manufactured by Kureha Co., Ltd., Fortron KPS (melting viscosity 30 Pa ⁇ s at a resin temperature of 310 ° C. and a shear rate of 1200 sec ⁇ 1 )
  • B Elastomer ⁇ (B-1) Copolymer obtained by grafting 30 parts by weight of methyl methacrylate / butyl acrylate copolymer (9/21) to 70 parts by weight of ethylene / ethyl acrylate copolymer (Nippon Yushi Co., Ltd.) Manufactured by Modiper A5300) ⁇ (B-2) Ethylene / octene copolymer (DuPont Dow Elastomers LLC, Engage 8440) (B-3) A copolymer obtained by grafting 30 parts by weight of a methyl methacrylate / butyl acrylate copolymer (9/21) to 70 parts by weight of an
  • Example 1 Using a molding die composed of a main mold for controlling the interlocking between the heating circuit and the molding machine having the cooling mold shown in FIG. 1 and maintaining the temperature of the main mold at 150 ° C.
  • the metal part shown in FIG. 2 was set in a piece shape, and immediately the temperature of the piece shape was raised from 150 ° C. to a predetermined temperature (245 ° C.). It took 9.5 seconds to reach 245 ° C.
  • the molding die was closed, and then a PPS resin was injection molded under the following conditions to obtain a composite molded product as shown in FIG.
  • the material 1 shown in Table 1 was used as the PPS resin.
  • Piece-shaped surface treatment A steel film SUS420J2 was coated with a diamond-like carbon coating (DLC) to a thickness of 1.0 ⁇ m.
  • the surface roughness is the resin flow direction; ten-point average roughness (Rz) of 0.45 ⁇ m and arithmetic average roughness (Ra) of 0.1 ⁇ m.
  • Test product shape for airtightness evaluation width 10 mm x length 10 mm x height 3 mm (see Fig. 3) Molding machine: TR40VR manufactured by Sodick Plustech Co., Ltd.
  • the molding cycle time refers to the time from the time when the metal part is set in the piece shape to the time when the composite molded product is taken out.
  • Example 2 The PPS resin was molded and evaluated in the same manner as in Example 1 except that the material 2 shown in Table 1 was used.
  • Example 3 Molding and evaluation were performed in the same manner as in Example 1 except that the piece temperature at the time of injection molding was 200 ° C.
  • Examples 4-5 The PPS resin was molded and evaluated in the same manner as in Example 3 except that the materials 3 and 4 in Table 1 were used.
  • Comparative Example 1 It was molded and evaluated in the same manner as in Example 1 except that a heat insulating plate was not used between the main mold and the piece mold. It took 10 minutes or more to raise the temperature to 245 ° C.
  • Comparative Example 2 Molding and evaluation were performed in the same manner as in Example 1 except that the volume of the piece was 250 cm 3 . It took 10 minutes or more to raise the temperature to 245 ° C.
  • Comparative Example 3 It was molded in the same manner as in Example 1 except that the piece shape was not subjected to the surface treatment and the 10-point average roughness (Rz) of 3.0 ⁇ m was used. I could't.
  • Comparative Example 4 Molding and evaluation were performed in the same manner as in Example 1 except that the piece temperature during injection molding was set to 170 ° C.
  • Example 6 Using a molding die comprising a main mold for controlling the interlocking between the heating circuit and the molding machine having the cooling mold shown in FIG. 5 and maintaining the temperature of the main mold at 150 ° C.
  • a metal plate having a thickness of 1 mm and 50 mm ⁇ 50 mm was set in a piece shape, and immediately the temperature of the piece shape was raised from 150 ° C. to a predetermined temperature (200 ° C.). It took 7 seconds to reach 200 ° C.
  • the molding die was closed, and then a PPS resin was injection molded under the following conditions to obtain a composite molded product as shown in FIG.
  • the material 1 shown in Table 1 was used as the PPS resin.
  • Piece-shaped surface treatment A steel film SUS420J2 was coated with a diamond-like carbon coating (DLC) to a thickness of 1.0 ⁇ m.
  • the surface roughness is the resin flow direction; ten-point average roughness (Rz) of 0.35 ⁇ m and arithmetic average roughness (Ra) of 0.09 ⁇ m.
  • Test article shape for adhesion strength evaluation see FIG. 6 Molding machine; TR40VR manufactured by Sodick Plustech Co., Ltd.
  • Thermal insulation plate Glass epoxy laminate Mold temperature; Main mold is 150 ° C Piece volume; 50cm 3 Cylinder temperature: 320 ° C Piece temperature during injection molding; 200 ° C Injection time (including pressure holding time); 5 seconds Injection speed; 200 mm / second Pressure holding; 100 MPa Cooling rate: 8 ° C / sec Cooling method at the time of cooling: Immediately after the thermoplastic resin is completely filled in the molding die, the heating rod heater is turned off and the moisture in the air is in a dew condensation state. Low-temperature compressed air—30 ° C., 0.6 MPa is passed through the flow path 2.
  • peel strength evaluation The peel strength was measured by the method shown in FIG. 7 by using the Tensilon RTC-1325A manufactured by Orientec Co., Ltd. and the indentation speed of 1 mm / min.
  • Examples 7-9 The PPS resin was molded and evaluated in the same manner as in Example 6 except that the materials 2, 3, and 4 shown in Table 1 were used.
  • Example 10 Molding and evaluation were performed in the same manner as in Example 6 except that the piece mold temperature at the time of injection molding was 220 ° C.
  • Examples 11-13 The PPS resin was molded and evaluated in the same manner as in Example 10 except that the materials 2, 3, and 4 in Table 1 were used.
  • Example 14 Nylon resin (manufactured by Mitsubishi Engineer Plastics Co., Ltd., polyamide MXD6 resin Reny 1025) was used as the resin, and molding was carried out in the same manner as in Example 6 except that the cylinder temperature of the injection molding machine was changed to 280 ° C.
  • Example 15 Molding and evaluation were performed in the same manner as in Example 14 except that the piece mold temperature at the time of injection molding was 220 ° C.
  • Comparative Example 5 Molding and evaluation were performed in the same manner as in Example 6 except that the piece mold temperature at the time of injection molding was set to 170 ° C.
  • Comparative Examples 6-7 It was molded and evaluated in the same manner as in Example 6 except that the piece-shaped temperature at the time of injection molding was 170 ° C., and the materials 3 and 4 in Table 1 were used as the PPS resin. Comparative Example 8 Molding and evaluation were performed in the same manner as in Example 14 except that the piece mold temperature at the time of injection molding was set to 170 ° C.

Abstract

L'invention concerne un procédé de production d'une pièce moulée composite qui comprend une ou plusieurs résines thermoplastiques sélectionnées parmi une résine de poly(sulfure d'arylène) et une résine de polyamide ainsi qu'une pièce métallique, et qui présente de manière stable une adhérence satisfaisante. Le procédé permet de réduire la durée du cycle de moulage. Le procédé est caractérisé en ce que (1) il utilise un moule divisé en un moule principal qui assure le contrôle de la liaison à une machine de moulage et un noyau doté d'un circuit de chauffage et d'un circuit de refroidissement dont l'intérieur présente une zone dans laquelle la ou les résines entrent en contact avec une pièce métallique. Le procédé est en outre caractérisé en ce que (2) la partie du moule qui entre en contact avec la ou les résines qui s'écoulent pendant le moulage a été traitée en surface de manière à présenter une rugosité moyenne dix points (Rz) de 0,5 µm ou moins, le noyau ayant une capacité de 60 cm3 ou moins et étant incorporé dans le moule principal, la partie périphérique du noyau en contact avec le moule principal ayant été isolée thermiquement. Le procédé est en outre caractérisé par (3) le placement de la pièce métallique dans le moule, le chauffage du noyau à une température comprise dans une plage spécifique, l'injection de la ou des résines de manière à remplir la cavité tout en maintenant la température du noyau, et immédiatement après que la cavité du moule a été remplie par la ou les résines, le blocage du circuit de chauffage du noyau et le refroidissement rapide du noyau à l'aide du circuit de refroidissement du noyau, à une vitesse de refroidissement de 7°C/s ou plus.
PCT/JP2009/000583 2008-02-15 2009-02-16 Procédé de production d'une pièce moulée composite WO2009101822A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2009801049845A CN102089134A (zh) 2008-02-15 2009-02-16 复合成形品的制造方法

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Application Number Priority Date Filing Date Title
JP2008034016A JP5128306B2 (ja) 2008-02-15 2008-02-15 複合成形品の製造方法
JP2008-034016 2008-02-15

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WO2009101822A1 true WO2009101822A1 (fr) 2009-08-20

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JP6471975B2 (ja) * 2015-07-31 2019-02-20 パナソニックＩｐマネジメント株式会社 三次元形状造形物の製造方法および三次元形状造形物
JP6885096B2 (ja) * 2016-02-26 2021-06-09 東レ株式会社 ポリフェニレンスルフィド樹脂組成物および成形品
KR101890406B1 (ko) * 2016-05-12 2018-08-24 한국엔지니어링플라스틱 주식회사 금속 수지 접합체의 제조방법
KR102275118B1 (ko) 2017-09-28 2021-07-07 코오롱플라스틱 주식회사 고온의 공기로 보조되는 열가소성 섬유강화 복합재의 성형방법 및 그 성형장치
EP3705257B1 (fr) * 2017-10-30 2023-07-12 Kuraray Co., Ltd. Composant étanche à l'eau et équipement électronique pourvu de ce dernier, procédé d'imperméabilisation d'un corps moulé par insertion et procédé d'imperméabilisation d'un équipement électronique

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