WO2009060752A1 - 固体酸化物形燃料電池用の酸化ニッケル粉末材料とその製造方法、並びにそれを用いた燃料極材料、燃料極、及び固体酸化物形燃料電池 - Google Patents

固体酸化物形燃料電池用の酸化ニッケル粉末材料とその製造方法、並びにそれを用いた燃料極材料、燃料極、及び固体酸化物形燃料電池 Download PDF

Info

Publication number
WO2009060752A1
WO2009060752A1 PCT/JP2008/069510 JP2008069510W WO2009060752A1 WO 2009060752 A1 WO2009060752 A1 WO 2009060752A1 JP 2008069510 W JP2008069510 W JP 2008069510W WO 2009060752 A1 WO2009060752 A1 WO 2009060752A1
Authority
WO
WIPO (PCT)
Prior art keywords
nickel oxide
powder material
oxide powder
fuel cell
fuel electrode
Prior art date
Application number
PCT/JP2008/069510
Other languages
English (en)
French (fr)
Inventor
Norimichi Yonesato
Yasumasa Hattori
Hideyuki Yamashita
Tai Itou
Original Assignee
Sumitomo Metal Mining Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Mining Co., Ltd. filed Critical Sumitomo Metal Mining Co., Ltd.
Priority to DK08846733.7T priority Critical patent/DK2211405T3/en
Priority to CN2008801142765A priority patent/CN101842925B/zh
Priority to EP08846733.7A priority patent/EP2211405B1/en
Priority to KR1020107009293A priority patent/KR101521420B1/ko
Priority to AU2008325771A priority patent/AU2008325771B2/en
Priority to US12/734,217 priority patent/US8557471B2/en
Priority to JP2009540023A priority patent/JP5218419B2/ja
Publication of WO2009060752A1 publication Critical patent/WO2009060752A1/ja
Priority to US13/954,467 priority patent/US8741502B2/en

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C01G25/02—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/04—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/628—Coating the powders or the macroscopic reinforcing agents
    • C04B35/62802—Powder coating materials
    • C04B35/62805—Oxide ceramics
    • C04B35/62818—Refractory metal oxides
    • C04B35/62823—Zirconium or hafnium oxide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/628—Coating the powders or the macroscopic reinforcing agents
    • C04B35/62886—Coating the powders or the macroscopic reinforcing agents by wet chemical techniques
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/628—Coating the powders or the macroscopic reinforcing agents
    • C04B35/62897—Coatings characterised by their thickness
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64—Burning or sintering processes
    • C04B35/645—Pressure sintering
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
    • H01M4/8657—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites layered
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
    • H01M4/8882—Heat treatment, e.g. drying, baking
    • H01M4/8885—Sintering or firing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9041—Metals or alloys
    • H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
    • H01M4/9066—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of metal-ceramic composites or mixtures, e.g. cermets
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3229—Cerium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3279—Nickel oxides, nickalates, or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5409—Particle size related information expressed by specific surface values
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5436—Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5445—Particle size related information expressed by the size of the particles or aggregates thereof submicron sized, i.e. from 0,1 to 1 micron
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Electrochemistry (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • Nanotechnology (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Inert Electrodes (AREA)
  • Fuel Cell (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

　固体酸化物形燃料電池用の燃料極材料として用いた際に、燃料供給異常などによって燃料極が酸化雰囲気に曝された場合でも、酸化膨張による電極の割れや電解質からの剥離を抑制し、発電特性の劣化を低減させることができる酸化ニッケル粉末材料とその効率的な製造方法、及び該酸化ニッケル粉末材料を用いた固体酸化物形燃料電池用の燃料極材料を提供する。 　固体酸化物形燃料電池を構成する燃料極材料に用いる酸化ニッケル粉末材料であって、酸化ニッケル微粒子からなる芯粒子（ａ）と、芯粒子（ａ）の表面上に形成されたジルコニウム水酸化物を主成分として含む被覆層（ｂ）とから構成され、かつ被覆層（ｂ）に含有されるジルコニウム量が、該酸化ニッケル微粒子の表面積あたり０．００１～０．０１ｇ／ｍ２であることを特徴とする。
PCT/JP2008/069510 2007-11-05 2008-10-28 固体酸化物形燃料電池用の酸化ニッケル粉末材料とその製造方法、並びにそれを用いた燃料極材料、燃料極、及び固体酸化物形燃料電池 WO2009060752A1 (ja)

Priority Applications (8)

Application Number Priority Date Filing Date Title
DK08846733.7T DK2211405T3 (en) 2007-11-05 2008-10-28 Nickel oxide powder material for solid oxide fuel cell, method for producing the nickel oxide powder material, and fuel electrode material, fuel electrode, and solid oxide fuel cell using the nickel oxide powder material.
CN2008801142765A CN101842925B (zh) 2007-11-05 2008-10-28 固体氧化物型燃料电池用的氧化镍粉末材料及其制造方法、采用它的燃料极材料、燃料极以及固体氧化物型燃料电池
EP08846733.7A EP2211405B1 (en) 2007-11-05 2008-10-28 Nickel oxide powder material for solid oxide fuel cell, process for producing the nickel oxide powder material, and fuel electrode material, fuel electrode, and solid oxide fuel cell using the nickel oxide powder material
KR1020107009293A KR101521420B1 (ko) 2007-11-05 2008-10-28 고체 산화물형 연료 전지용 산화 니켈 분말 재료와 그 제조 방법, 및 그것을 이용한 연료극 재료, 연료극, 및 고체 산화물형 연료 전지
AU2008325771A AU2008325771B2 (en) 2007-11-05 2008-10-28 Nickel oxide powder material for solid oxide fuel cell, process for producing the nickel oxide powder material, and fuel electrode material, fuel electrode, and solid oxide fuel cell using the nickel oxide powder material
US12/734,217 US8557471B2 (en) 2007-11-05 2008-10-28 Nickel oxide powder comprising zirconium hydroxide coating layer or zirconium oxide coating layer, SOFC anode material and method of producing the same
JP2009540023A JP5218419B2 (ja) 2007-11-05 2008-10-28 固体酸化物形燃料電池用の酸化ニッケル粉末材料とその製造方法、並びにそれを用いた燃料極材料、燃料極、及び固体酸化物形燃料電池
US13/954,467 US8741502B2 (en) 2007-11-05 2013-07-30 Nickel oxide powder material for solid oxide type fuel cell and method for producing the same, and anode material, anode and solid oxide type fuel cell using the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-286860 2007-11-05
JP2007286860 2007-11-05

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US12/734,217 A-371-Of-International US8557471B2 (en) 2007-11-05 2008-10-28 Nickel oxide powder comprising zirconium hydroxide coating layer or zirconium oxide coating layer, SOFC anode material and method of producing the same
US13/954,467 Division US8741502B2 (en) 2007-11-05 2013-07-30 Nickel oxide powder material for solid oxide type fuel cell and method for producing the same, and anode material, anode and solid oxide type fuel cell using the same

Publications (1)

Publication Number Publication Date
WO2009060752A1 true WO2009060752A1 (ja) 2009-05-14

Family

ID=40625646

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/069510 WO2009060752A1 (ja) 2007-11-05 2008-10-28 固体酸化物形燃料電池用の酸化ニッケル粉末材料とその製造方法、並びにそれを用いた燃料極材料、燃料極、及び固体酸化物形燃料電池

Country Status (8)

Country Link
US (2) US8557471B2 (ja)
EP (1) EP2211405B1 (ja)
JP (1) JP5218419B2 (ja)
KR (1) KR101521420B1 (ja)
CN (1) CN101842925B (ja)
AU (1) AU2008325771B2 (ja)
DK (1) DK2211405T3 (ja)
WO (1) WO2009060752A1 (ja)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010257871A (ja) * 2009-04-28 2010-11-11 Sumitomo Metal Mining Co Ltd 固体酸化物形燃料電池用燃料極およびその製造方法
JP2011157248A (ja) * 2010-02-03 2011-08-18 Mitsubishi Materials Corp ニッケル系合金粉末及びその製造方法

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012157748A1 (ja) * 2011-05-18 2012-11-22 Toto株式会社 固体酸化物形燃料電池セル及び固体酸化物形燃料電池セルの製造方法
GB2503896A (en) 2012-07-10 2014-01-15 Faradion Ltd Nickel doped compound for use as an electrode material in energy storage devices
GB2503898A (en) 2012-07-10 2014-01-15 Faradion Ltd Nickel doped compound for use as an electrode material in energy storage devices
GB2506859A (en) 2012-10-09 2014-04-16 Faradion Ltd A nickel-containing mixed metal oxide active electrode material
JP5562450B1 (ja) * 2013-01-25 2014-07-30 株式会社リケン 固体酸化物型燃料電池の支持体を兼ねる燃料極およびその製造方法
KR101516680B1 (ko) * 2013-05-14 2015-05-06 한국세라믹기술원 하이드라진 환원제와 계면활성제를 이용한 고체산화물연료전지용 연료극 코어-셀 복합체의 제조 방법
KR101854934B1 (ko) * 2013-07-15 2018-06-20 주식회사 엘지화학 연료전지의 연료극 형성 장치 및 방법, 이에 의해 제조된 고체산화물 연료전지의 연료극 및 이를 포함하는 고체산화물 연료전지
KR20240043333A (ko) 2022-09-27 2024-04-03 한국생산기술연구원 용융탄산염 수전해 셀 산소극의 내구성 향상 방법

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0855625A (ja) 1994-08-10 1996-02-27 Nippon Telegr & Teleph Corp <Ntt> 燃料電極基板の作製法
JP2001517859A (ja) * 1997-09-22 2001-10-09 シーメンス ウエスチングハウス パワー コーポレイション 固体酸化物燃料電池の焼結電極
JP2004327278A (ja) * 2003-04-25 2004-11-18 Nissan Motor Co Ltd 燃料電池用電極材料及びこれを用いた固体酸化物形燃料電池
JP2005339905A (ja) * 2004-05-25 2005-12-08 Kyocera Corp 燃料電池セル及び燃料電池
WO2006101136A1 (ja) * 2005-03-23 2006-09-28 Nippon Shokubai Co., Ltd. 固体酸化物形燃料電池用燃料極材料およびそれを用いた燃料極、並びに燃料電池セル
JP2006286607A (ja) * 2005-03-07 2006-10-19 Dainippon Printing Co Ltd 固体酸化物形燃料電池
WO2007020863A1 (ja) 2005-08-18 2007-02-22 Sumitomo Metal Mining Co., Ltd. 固体電解質型燃料電池用の酸化ニッケル粉末材料、その製造方法、それに用いられる原料組成物及びそれを用いた燃料極材料

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2166984A (en) * 1936-03-24 1939-07-25 Philips Nv Electric discharge tube having an oxide cathode
DE3914244A1 (de) * 1989-04-29 1990-10-31 Asea Brown Boveri Brennstoffzellenanordnung und verfahren zu deren herstellung
KR100519938B1 (ko) * 2001-11-01 2005-10-11 한국과학기술연구원 다공성 세라믹 막이 코팅된 용융탄산염 연료전지용 연료극
EP1328035A1 (fr) * 2002-01-09 2003-07-16 HTceramix S.A. - High Technology Electroceramics PEN de pile à combustible à oxydes solide
JP2005518645A (ja) * 2002-02-20 2005-06-23 アキュメントリクス・コーポレーション 燃料電池のスタッキングおよびシーリング
US20050019637A1 (en) * 2003-07-23 2005-01-27 Herman Gregory S. Method for manufacturing fuel cell components by low temperature processing
JP4555961B2 (ja) * 2003-12-10 2010-10-06 独立行政法人産業技術総合研究所 燃料電池、燃料電池の作動方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0855625A (ja) 1994-08-10 1996-02-27 Nippon Telegr & Teleph Corp <Ntt> 燃料電極基板の作製法
JP2001517859A (ja) * 1997-09-22 2001-10-09 シーメンス ウエスチングハウス パワー コーポレイション 固体酸化物燃料電池の焼結電極
JP2004327278A (ja) * 2003-04-25 2004-11-18 Nissan Motor Co Ltd 燃料電池用電極材料及びこれを用いた固体酸化物形燃料電池
JP2005339905A (ja) * 2004-05-25 2005-12-08 Kyocera Corp 燃料電池セル及び燃料電池
JP2006286607A (ja) * 2005-03-07 2006-10-19 Dainippon Printing Co Ltd 固体酸化物形燃料電池
WO2006101136A1 (ja) * 2005-03-23 2006-09-28 Nippon Shokubai Co., Ltd. 固体酸化物形燃料電池用燃料極材料およびそれを用いた燃料極、並びに燃料電池セル
WO2007020863A1 (ja) 2005-08-18 2007-02-22 Sumitomo Metal Mining Co., Ltd. 固体電解質型燃料電池用の酸化ニッケル粉末材料、その製造方法、それに用いられる原料組成物及びそれを用いた燃料極材料

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
See also references of EP2211405A4 *
SOLID STATE IONICS, vol. 176, 2005, pages 847 - 859

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010257871A (ja) * 2009-04-28 2010-11-11 Sumitomo Metal Mining Co Ltd 固体酸化物形燃料電池用燃料極およびその製造方法
JP2011157248A (ja) * 2010-02-03 2011-08-18 Mitsubishi Materials Corp ニッケル系合金粉末及びその製造方法

Also Published As

Publication number Publication date
US20130309399A1 (en) 2013-11-21
DK2211405T3 (en) 2017-07-17
JPWO2009060752A1 (ja) 2011-03-24
EP2211405B1 (en) 2017-05-31
EP2211405A1 (en) 2010-07-28
KR20100085942A (ko) 2010-07-29
JP5218419B2 (ja) 2013-06-26
US20100221640A1 (en) 2010-09-02
KR101521420B1 (ko) 2015-05-19
CN101842925A (zh) 2010-09-22
AU2008325771B2 (en) 2012-01-19
AU2008325771A1 (en) 2009-05-14
CN101842925B (zh) 2013-03-20
US8557471B2 (en) 2013-10-15
US8741502B2 (en) 2014-06-03
EP2211405A4 (en) 2012-10-31

Similar Documents

Publication Publication Date Title
WO2009060752A1 (ja) 固体酸化物形燃料電池用の酸化ニッケル粉末材料とその製造方法、並びにそれを用いた燃料極材料、燃料極、及び固体酸化物形燃料電池
EP1768204A3 (de) Dichtungsanordnung für einen Brennstoffzellenstapel und Verfahren zu dessen Herstellung
WO2011081417A3 (ko) 복합 세라믹 재료 및 그 제조방법
JP6398647B2 (ja) 固体酸化物型燃料電池用アノードの製造方法および燃料電池用電解質層−電極接合体の製造方法
WO2007035584A3 (en) High performance composite electrode materials
US9065104B2 (en) Process for manufacturing elementary electrochemical cells for energy- or hydrogen-producing electrochemical systems, in particular of SOFC and HTE type
WO2005124916A3 (en) Processing techniques for the fabrication of solid acid fuel cell membrane electrode assemblies
EP1922777A4 (en) ELECTROCATALYZERS WITH GOLD MONOSCREATS ON PLATINANANO ARTICLES CORE AND THEIR USE
TW200733142A (en) Paste for solar cell electrode, solar cell electrode manufacturing method, and solar cell
WO2008136361A1 (ja) 二次電池用電極及びその製造方法並びに二次電池
WO2010107228A3 (ko) 기공 경사 구조의 나노 기공성 층을 포함하는 연료극 지지형 고체 산화물 연료 전지 및 그 제조 방법
WO2008033421A3 (en) Catalysts compositions for use in fuel cells
WO2006086457A3 (en) Palladium-cobalt particles as oxygen-reduction electrocatalysts
JP2012525688A5 (ja)
WO2010080507A3 (en) Reduction-oxidation-tolerant electrodes for solid oxide fuel cells
WO2005023708A3 (en) Laser pyrolysis method for producing carbon nano-spheres
WO2009022664A1 (ja) リチウム系二次電池用負極、炭素系負極活物質の製造方法及びリチウム系二次電池及びその用途
WO2006004957A3 (en) Sub-micron solid oxide electrolyte membrane
WO2012146465A3 (de) Verfahren zur herstellung eines porösen körpers und zelle einer wieder aufladbaren oxidbatterie
JP2010027457A (ja) 固体電解質型燃料電池の発電膜及びこれを備えた固体電解質型燃料電池、並びに固体電解質型燃料電池の発電膜の製造方法
WO2010125252A3 (fr) Catalyseur et procede d&#39;oxydation electrochimique du methane
EP1806805A3 (de) Kathode-Electrolyt-Anode-Einheit für Festoxid-Brennstoffzellen und Verfahren zu deren Herstellung
JP2006028616A (ja) 多孔質焼結体およびその製造方法
WO2011077923A1 (ja) 固体酸化物形燃料電池セルの製造方法、及び、同セルの分割体の成形体の製造方法
WO2011037428A3 (ko) 연료 전지용 세퍼레이터와 이의 제조 방법 및 이를 포함하는 연료 전지 스택

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200880114276.5

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08846733

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 2008325771

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 2009540023

Country of ref document: JP

ENP Entry into the national phase

Ref document number: 2008325771

Country of ref document: AU

Date of ref document: 20081028

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 12734217

Country of ref document: US

REEP Request for entry into the european phase

Ref document number: 2008846733

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2008846733

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 20107009293

Country of ref document: KR

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE