WO2009011132A1 - リチウムイオン二次電池 - Google Patents

リチウムイオン二次電池 Download PDF

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Publication number
WO2009011132A1
WO2009011132A1 PCT/JP2008/001930 JP2008001930W WO2009011132A1 WO 2009011132 A1 WO2009011132 A1 WO 2009011132A1 JP 2008001930 W JP2008001930 W JP 2008001930W WO 2009011132 A1 WO2009011132 A1 WO 2009011132A1
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WO
WIPO (PCT)
Prior art keywords
active material
material layer
positive electrode
electrode active
negative electrode
Prior art date
Application number
PCT/JP2008/001930
Other languages
English (en)
French (fr)
Inventor
Kazuyoshi Honda
Toshitada Sato
Daisuke Suetsugu
Katsumi Kashiwagi
Kunihiko Bessho
Original Assignee
Panasonic Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Panasonic Corporation filed Critical Panasonic Corporation
Priority to CN2008800148158A priority Critical patent/CN101675545B/zh
Priority to JP2008550564A priority patent/JP4275192B2/ja
Priority to EP08790232A priority patent/EP2172995A4/en
Priority to KR1020097020844A priority patent/KR101138583B1/ko
Priority to US12/600,391 priority patent/US8486549B2/en
Publication of WO2009011132A1 publication Critical patent/WO2009011132A1/ja

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/36Accumulators not provided for in groups H01M10/05-H01M10/34
    • H01M10/38Construction or manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0402Methods of deposition of the material
    • H01M4/0421Methods of deposition of the material involving vapour deposition
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134Electrodes based on metals, Si or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1391Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1395Processes of manufacture of electrodes based on metals, Si or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/386Silicon or alloys based on silicon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/387Tin or alloys based on tin
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44Methods for charging or discharging
    • H01M10/446Initial charging measures
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

 正極集電体と、正極集電体に接して設けられた正極活物質層と、正極活物質層の正極集電体が設けられない側に設けられたセパレータ層と、セパレータ層の正極活物質層が設けられない側に設けられ、正極活物質層に対向する対向部と、正極活物質層に対向しない非対向部とを有し、対向部および非対向部に薄膜形成法で作製されたリチウムを含有し、シリコンまたは錫を主成分とする負極活物質層と、負極活物質層のセパレータ層が設けられない側に設けられた負極集電体とでリチウムイオン二次電池を構成する。これにより、負極の変形、それに伴うサイクル特性の低下が防止される。
PCT/JP2008/001930 2007-07-19 2008-07-18 リチウムイオン二次電池 WO2009011132A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN2008800148158A CN101675545B (zh) 2007-07-19 2008-07-18 锂离子二次电池
JP2008550564A JP4275192B2 (ja) 2007-07-19 2008-07-18 リチウムイオン二次電池
EP08790232A EP2172995A4 (en) 2007-07-19 2008-07-18 Lithium ion secondary battery
KR1020097020844A KR101138583B1 (ko) 2007-07-19 2008-07-18 리튬이온 이차전지
US12/600,391 US8486549B2 (en) 2007-07-19 2008-07-18 Lithium ion secondary battery

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007188176 2007-07-19
JP2007-188176 2007-07-19

Publications (1)

Publication Number Publication Date
WO2009011132A1 true WO2009011132A1 (ja) 2009-01-22

Family

ID=40259478

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/001930 WO2009011132A1 (ja) 2007-07-19 2008-07-18 リチウムイオン二次電池

Country Status (6)

Country Link
US (1) US8486549B2 (ja)
EP (1) EP2172995A4 (ja)
JP (1) JP4275192B2 (ja)
KR (1) KR101138583B1 (ja)
CN (1) CN101675545B (ja)
WO (1) WO2009011132A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011023710A (ja) * 2009-06-19 2011-02-03 Semiconductor Energy Lab Co Ltd 蓄電デバイスの作製方法
JP2011060471A (ja) * 2009-09-08 2011-03-24 Nec Energy Devices Ltd 非水系電解質二次電池
JP2011060520A (ja) * 2009-09-08 2011-03-24 Nissan Motor Co Ltd リチウムイオン二次電池およびその製造方法
JP2013510405A (ja) * 2009-11-03 2013-03-21 エンビア・システムズ・インコーポレイテッド リチウムイオン電池用の高容量アノード材料
WO2016051645A1 (ja) * 2014-09-29 2016-04-07 パナソニックIpマネジメント株式会社 フレキシブル電池
JP2019160435A (ja) * 2018-03-08 2019-09-19 トヨタ自動車株式会社 リチウムイオン二次電池およびリチウムイオン二次電池の製造方法
JP2022552733A (ja) * 2019-10-31 2022-12-19 ポスコ リチウム二次電池用負極、その製造方法およびこれを用いたリチウム二次電池

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011060024A2 (en) * 2009-11-11 2011-05-19 Amprius, Inc. Open structures in substrates for electrodes
KR20130132230A (ko) 2012-05-25 2013-12-04 주식회사 엘지화학 단차를 갖는 전극 조립체 및 이를 포함하는 전지셀, 전지팩 및 디바이스
KR20130135017A (ko) * 2012-05-31 2013-12-10 주식회사 엘지화학 단차를 갖는 전극 조립체 및 이를 포함하는 전지셀, 전지팩 및 디바이스
WO2017202444A1 (en) * 2016-05-23 2017-11-30 Applied Materials, Inc. Method of manufacturing a battery, vacuum processing apparatus and battery
US10686193B2 (en) * 2016-07-25 2020-06-16 Lg Chem, Ltd. Negative electrode comprising mesh-type current collector, lithium secondary battery comprising the same, and manufacturing method thereof
CN108172791B (zh) * 2017-12-25 2020-10-16 贝特瑞新材料集团股份有限公司 复合物负极材料及其制备方法、锂离子电池
CN109402589A (zh) * 2019-01-02 2019-03-01 重庆天齐锂业有限责任公司 一种磁控溅射制备超薄金属锂薄膜的方法及系统

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09283179A (ja) 1996-04-16 1997-10-31 Fuji Photo Film Co Ltd 非水二次電池
JP2000133308A (ja) * 1998-10-22 2000-05-12 Fuji Photo Film Co Ltd 非水二次電池
WO2001031722A1 (fr) 1999-10-22 2001-05-03 Sanyo Electric Co., Ltd. Electrode pour pile au lithium et accumulateur au lithium
JP2002356314A (ja) 2001-03-26 2002-12-13 Shin Etsu Chem Co Ltd 部分窒化酸化珪素粉末およびその製造方法
JP2003068283A (ja) * 2000-02-22 2003-03-07 Korea Inst Of Science & Technology 炭素電極及びその製造方法、並びにそれを用いたリチウム二次電池
JP2004127561A (ja) 2002-09-30 2004-04-22 Hitachi Maxell Ltd 微細パターン化薄膜電極と、これを負極とするリチウム二次電池
JP2005038720A (ja) 2003-07-15 2005-02-10 Sony Corp 負極の製造方法および電池の製造方法
JP2005085632A (ja) 2003-09-09 2005-03-31 Sony Corp 電池
JP2006139986A (ja) * 2004-11-11 2006-06-01 Mitsui Mining & Smelting Co Ltd 非水電解液二次電池用負極
JP2007165226A (ja) * 2005-12-16 2007-06-28 Sumitomo Electric Ind Ltd リチウム二次電池用電極の製造方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3816623B2 (ja) 1997-02-28 2006-08-30 株式会社東芝 アクティブマトリクス型液晶表示装置
JP4192462B2 (ja) 2001-11-27 2008-12-10 日本電気株式会社 二次電池用負極およびそれを用いた二次電池
TWI249868B (en) * 2003-09-09 2006-02-21 Sony Corp Anode and battery
JP4442235B2 (ja) 2004-01-28 2010-03-31 ソニー株式会社 二次電池用負極、二次電池およびそれらの製造方法
EP1892790A1 (en) * 2005-06-15 2008-02-27 Matsushita Electric Industrial Co., Ltd. Lithium secondary battery
JP4876531B2 (ja) * 2005-10-27 2012-02-15 パナソニック株式会社 リチウム二次電池用負極およびリチウム二次電池の製造方法
US7730148B1 (en) * 2007-03-30 2010-06-01 Emc Corporation Backfilling a local email archive store
JP5177361B2 (ja) * 2007-07-23 2013-04-03 ソニー株式会社 二次電池用負極および二次電池

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09283179A (ja) 1996-04-16 1997-10-31 Fuji Photo Film Co Ltd 非水二次電池
JP2000133308A (ja) * 1998-10-22 2000-05-12 Fuji Photo Film Co Ltd 非水二次電池
WO2001031722A1 (fr) 1999-10-22 2001-05-03 Sanyo Electric Co., Ltd. Electrode pour pile au lithium et accumulateur au lithium
JP2003068283A (ja) * 2000-02-22 2003-03-07 Korea Inst Of Science & Technology 炭素電極及びその製造方法、並びにそれを用いたリチウム二次電池
JP2002356314A (ja) 2001-03-26 2002-12-13 Shin Etsu Chem Co Ltd 部分窒化酸化珪素粉末およびその製造方法
JP2004127561A (ja) 2002-09-30 2004-04-22 Hitachi Maxell Ltd 微細パターン化薄膜電極と、これを負極とするリチウム二次電池
JP2005038720A (ja) 2003-07-15 2005-02-10 Sony Corp 負極の製造方法および電池の製造方法
JP2005085632A (ja) 2003-09-09 2005-03-31 Sony Corp 電池
JP2006139986A (ja) * 2004-11-11 2006-06-01 Mitsui Mining & Smelting Co Ltd 非水電解液二次電池用負極
JP2007165226A (ja) * 2005-12-16 2007-06-28 Sumitomo Electric Ind Ltd リチウム二次電池用電極の製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2172995A4 *

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011023710A (ja) * 2009-06-19 2011-02-03 Semiconductor Energy Lab Co Ltd 蓄電デバイスの作製方法
JP2011060471A (ja) * 2009-09-08 2011-03-24 Nec Energy Devices Ltd 非水系電解質二次電池
JP2011060520A (ja) * 2009-09-08 2011-03-24 Nissan Motor Co Ltd リチウムイオン二次電池およびその製造方法
US10003068B2 (en) 2009-11-03 2018-06-19 Zenlabs Energy, Inc. High capacity anode materials for lithium ion batteries
JP2013510405A (ja) * 2009-11-03 2013-03-21 エンビア・システムズ・インコーポレイテッド リチウムイオン電池用の高容量アノード材料
US9190694B2 (en) 2009-11-03 2015-11-17 Envia Systems, Inc. High capacity anode materials for lithium ion batteries
US11309534B2 (en) 2009-11-03 2022-04-19 Zenlabs Energy, Inc. Electrodes and lithium ion cells with high capacity anode materials
JPWO2016051645A1 (ja) * 2014-09-29 2017-07-06 パナソニックIpマネジメント株式会社 フレキシブル電池
WO2016051645A1 (ja) * 2014-09-29 2016-04-07 パナソニックIpマネジメント株式会社 フレキシブル電池
JP2019160435A (ja) * 2018-03-08 2019-09-19 トヨタ自動車株式会社 リチウムイオン二次電池およびリチウムイオン二次電池の製造方法
JP7031382B2 (ja) 2018-03-08 2022-03-08 トヨタ自動車株式会社 リチウムイオン二次電池およびリチウムイオン二次電池の製造方法
JP2022552733A (ja) * 2019-10-31 2022-12-19 ポスコ リチウム二次電池用負極、その製造方法およびこれを用いたリチウム二次電池
JP7416928B2 (ja) 2019-10-31 2024-01-17 ポスコホールディングス インコーポレーティッド リチウム二次電池用負極、その製造方法およびこれを用いたリチウム二次電池

Also Published As

Publication number Publication date
KR101138583B1 (ko) 2012-05-10
US8486549B2 (en) 2013-07-16
KR20090120502A (ko) 2009-11-24
US20100167112A1 (en) 2010-07-01
CN101675545A (zh) 2010-03-17
EP2172995A1 (en) 2010-04-07
JP4275192B2 (ja) 2009-06-10
CN101675545B (zh) 2012-06-13
JPWO2009011132A1 (ja) 2010-09-16
EP2172995A4 (en) 2012-05-09

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