WO2009003460A4 - Co2-umsetzer - Google Patents

Co2-umsetzer Download PDF

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Publication number
WO2009003460A4
WO2009003460A4 PCT/DE2008/001095 DE2008001095W WO2009003460A4 WO 2009003460 A4 WO2009003460 A4 WO 2009003460A4 DE 2008001095 W DE2008001095 W DE 2008001095W WO 2009003460 A4 WO2009003460 A4 WO 2009003460A4
Authority
WO
WIPO (PCT)
Prior art keywords
photolysis
photocatalysis
reactor
mixture
gas mixture
Prior art date
Application number
PCT/DE2008/001095
Other languages
English (en)
French (fr)
Other versions
WO2009003460A2 (de
WO2009003460A3 (de
Inventor
Georg Josef Uphoff
Heinrich Josef Uphoff
Original Assignee
Georg Fritzmeier Gmbh & Co. Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Georg Fritzmeier Gmbh & Co. Kg filed Critical Georg Fritzmeier Gmbh & Co. Kg
Priority to DE112008002413T priority Critical patent/DE112008002413A5/de
Publication of WO2009003460A2 publication Critical patent/WO2009003460A2/de
Publication of WO2009003460A3 publication Critical patent/WO2009003460A3/de
Publication of WO2009003460A4 publication Critical patent/WO2009003460A4/de

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/88Handling or mounting catalysts
    • B01D53/885Devices in general for catalytic purification of waste gases
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M29/00Means for introduction, extraction or recirculation of materials, e.g. pumps
    • C12M29/26Conditioning fluids entering or exiting the reaction vessel
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M43/00Combinations of bioreactors or fermenters with other apparatus
    • C12M43/04Bioreactors or fermenters combined with combustion devices or plants, e.g. for carbon dioxide removal
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P3/00Preparation of elements or inorganic compounds except carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00Preparation of oxygen-containing organic compounds
    • C12P7/02Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06Ethanol, i.e. non-beverage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/95Specific microorganisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/80Type of catalytic reaction
    • B01D2255/802Photocatalytic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/151Reduction of greenhouse gas [GHG] emissions, e.g. CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/59Biological synthesis; Biological purification

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Biomedical Technology (AREA)
  • Genetics & Genomics (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Biotechnology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Sustainable Development (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Catalysts (AREA)
  • Treating Waste Gases (AREA)

Abstract

Offenbart wird ein Verfahren zum Umsetzen von Kohlendioxid in Gasen, insbesondere in Bio- oder Verbrennungsabgasen, mit den Schritten - Vorkatalysieren des Gasgemischs in einem Reaktor (2), - Photolyse oder Photokatalyse des vorkatalysierten Gemisches (4) und - Zuführen des nach der Photolyse oder Photokatalyse vorliegenden Gasgemisches zu einem Gasfermenter (8) und Umsetzen zu Produkten, wie beispielsweise Ethanol, Butanol, HMF, DMF, H2 oder dergleichen.

Claims

GEÄNDERTE ANSPRÜCHE beim Internationalen Büro eingegangen am 30. Juli 2009 (30.07.2009)Neue Patentansprüche (geändert gemäß Art. 19 PCT)
1. Verfahren zum Umsetzen von Kohlendioxid in Gasen, insbesondere in Bio- oder Verbrennungsabgasen, mit den Schritten
- Vorkatalysieren des Gasgemischs über eine katalytisch aktive Oberfläche in einem Reaktor (2),
- Photolyse und/oder Photokatalyse des vorkatalysierten Gemisches (4) unter Zugabe lichtemittierender Mikroorganismen und
- Zuführen des nach der Photolyse oder Photokatalyse vorliegenden Gasgemisches zu einem Gasfermenter (8) und Umsetzen zu Produkten, wie beispielsweise Ethanol, Butanol, HMF, DMF, H2 oder dergleichen.
2. Verfahren nach Patentanspruch 1 , wobei die Photolyse und/oder Photokatalyse unter Zugabe einer Mischung von phosphorisierenden und lumineszierenden Mikroorganismen erfolgt.
3. Verfahren nach Patentanspruch 1 oder 2, wobei die Photolyse und/oder Photokatalyse durch zusätzliches Anlegen eines schwachen Stroms erfolgt.
4. Verfahren nach einem der vorhergehenden Patentansprüche, wobei während des Prozesses entstehendes Kohlendioxid wieder zurück zur Vorkatalyse oder zur Photolyse bzw. Photokatalyse zurückgeführt wird.
5. Verfahren nach Patentanspruch 3 oder 4, wobei die benötigte Ladungsenergie in situ über biologische Systeme bereitgestellt wird.
6. Reaktor für die Photolyse und/oder Photokatalyse mit katalytisch wirksamen Oberflächen und lichtemittierenden Mikroorganismen und mit einer Einrichtung zum Aufbau einer elektrochemischen Doppelschicht.
7. Reaktor nach Patentanspruch 6, wobei die Einrichtung derart ausgebildet ist, dass sie ein oberflächennahes Magnetfeld durch Anlegen eines schwachen Stroms bereitstellt.
PCT/DE2008/001095 2007-07-04 2008-07-04 Co2-umsetzer WO2009003460A2 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE112008002413T DE112008002413A5 (de) 2007-07-04 2008-07-04 CO2-Umsetzer

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
DE102007000911 2007-07-04
DE102007000911.0 2007-07-04
DE102007000984.6 2007-11-12
DE102007000984 2007-11-12
DE102008027985 2008-06-12
DE102008027985.4 2008-06-12

Publications (3)

Publication Number Publication Date
WO2009003460A2 WO2009003460A2 (de) 2009-01-08
WO2009003460A3 WO2009003460A3 (de) 2009-07-09
WO2009003460A4 true WO2009003460A4 (de) 2009-09-17

Family

ID=40226565

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2008/001095 WO2009003460A2 (de) 2007-07-04 2008-07-04 Co2-umsetzer

Country Status (2)

Country Link
DE (1) DE112008002413A5 (de)
WO (1) WO2009003460A2 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3048366A1 (fr) * 2016-03-02 2017-09-08 Air Liquide Procede de traitement d'un flux de biogaz
CN111974153A (zh) * 2020-07-31 2020-11-24 苏州巨联环保有限公司 一种多种类有机废气的串联处理装置及废气处理方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4444191C1 (de) * 1994-12-12 1996-06-05 Melkonian Ezekian Michael Prof Verfahren zur Abreicherung oder Entfernung von Kohlendioxid aus Abgasen
DE19721280C2 (de) * 1997-05-14 2002-11-07 Energy Of Nature Projektgesell Verfahren und Vorrichtung zur photobiologischen Trennung von kohlendioxid- und methanhaltigen Gasgemischen
DE19721243C2 (de) * 1997-05-14 2000-10-12 Ufz Leipzighalle Gmbh Verfahren und Anlage zur effizienten energetischen und stofflichen Nutzung von Biogas
US6667171B2 (en) * 2000-07-18 2003-12-23 Ohio University Enhanced practical photosynthetic CO2 mitigation
DE10346471B4 (de) * 2002-10-05 2004-09-23 Schmack Biogas Ag Verfahren zur biologischen Gasaufbereitung
GB0304709D0 (en) * 2003-03-01 2003-04-02 Univ Aberdeen Photo-catalytic fuel cell
DE102005010865A1 (de) * 2005-03-07 2006-09-14 Schmack Biogas Ag Verfahren zur biologischen Gasaufbereitung
WO2006100667A1 (en) * 2005-03-21 2006-09-28 Cargill, Incorporated A Register Delaware Corporation Of A method for the enhanced production of algal biomass
DE102005062727A1 (de) * 2005-12-22 2007-06-28 Mikrobiologisch-Analytisches Labor Gmbh Verfahren zur CO2-Verwertung

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Publication number Publication date
WO2009003460A2 (de) 2009-01-08
WO2009003460A3 (de) 2009-07-09
DE112008002413A5 (de) 2010-07-01

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