WO2008134969A1 - Composés benzamides et leurs applications - Google Patents
Composés benzamides et leurs applications Download PDFInfo
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- WO2008134969A1 WO2008134969A1 PCT/CN2008/070830 CN2008070830W WO2008134969A1 WO 2008134969 A1 WO2008134969 A1 WO 2008134969A1 CN 2008070830 W CN2008070830 W CN 2008070830W WO 2008134969 A1 WO2008134969 A1 WO 2008134969A1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/16—Halogen atoms or nitro radicals
Definitions
- the invention belongs to the field of agricultural insecticides and fungicides. It relates to a benzamide compound and its use. Background technique
- insecticides and fungicides are resistant to pests and germicides after a period of use, it is necessary to continuously invent new and improved insecticidal and bactericidal active compounds and compositions.
- WO 03/015518 A1 reports that certain benzamide compounds have insecticidal activity and have a high control effect on armyworms at a concentration of 50 ppm.
- An object of the present invention is to provide a novel benzamide compound which can be applied to the control of pests and diseases.
- the present invention provides a benzamide compound, as shown in Formula I:
- DC 6 is selected from H or alkyl
- R 2 is selected from H or dC 6 alkyl
- R 3 is selected from dC 6 alkyl or C 3 -C 6 cycloalkyl, and the hydrogen on the group may be further substituted by the following groups: halogen, N0 2 , dC 3 alkoxy, phenoxy, dC a 3 -alkylthio group, a dC 3 alkylsulfinyl group or a dC 3 alkylsulfonyl group;
- R 2 and R 3 together with the attached carbon form a C 3 -C 6 cycloalkyl group
- R 5 is selected from halogen or CC 3 alkyl; Re is selected from halogen, CrC 3 alkyl, dC 3 haloalkyl, dC 3 alkoxy or dC 3 haloalkoxy;
- R 7 is selected from H, halogen, CN, dC 3 alkyl, dC 3 haloalkyl, dC 3 alkoxy, dC 3 alkylthio, Ci-C 3 alkylsulfinyl or dC 3 alkylsulfonyl;
- R 8 is selected from halogen, CN, dC 3 alkyl, dC 3 haloalkyl, dC 3 alkoxy or dC 3 alkylthio;
- X is selected from white CH, CF, CC ⁇ N.
- Ri is selected from H;
- R 2 is selected from H or dC 3 alkyl
- R 3 is selected from dC 3 alkyl
- R 2 and R 3 together with the attached carbon form a C 3 -C 6 cycloalkyl group
- R 5 is selected from halogen or CC 3 alkyl
- R 7 is selected from H, halogen, CN or dC 3 haloalkyl
- R 8 is selected from halogen
- X selects white CH, CF, CC ⁇ N.
- a still further preferred compound in the present invention is, in the formula I:
- Ri is selected from H;
- R 2 is selected from H or methyl
- R 3 is selected from a methyl group
- R 5 is selected from chlorine, bromine or methyl
- R 7 is selected from H, chlorine or trifluoromethyl
- X selects white CH, CF, CC ⁇ N.
- the invention also includes intermediates which are directly employed in the preparation of compounds of formula I which have not previously been reported and which have the structure shown in formula II:
- R 2 is selected from H or dC 6 alkyl
- R 3 is selected from dC 6 alkyl or C 3 -C 6 cycloalkyl, and the hydrogen on the group may be further substituted by the following groups: halogen, N0 2 , dC 3 alkoxy, phenoxy, dC a 3 -alkylthio group, a dC 3 alkylsulfinyl group or a dC 3 alkylsulfonyl group;
- R 2 and R 3 together with the attached carbon form a C 3 -C 6 cycloalkyl group
- R 5 is selected from halogen or CC 3 alkyl.
- Alkyl means straight or branched form, for example methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, n-pentyl, isopentyl, A group such as n-hexyl.
- the cycloalkyl group means a group including a cyclic chain such as a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group or the like.
- Haloalkyl means a group in which an alkyl group is substituted by one or more halogen atoms.
- the alkoxy group means a group having an oxygen atom bonded to the terminal of the alkyl group, such as a methoxy group, an ethoxy group, a n-propoxy group, an isopropoxy group, a t-butoxy group or the like.
- a haloalkoxy group means a group in which an alkyl group is substituted by one or more halogen atoms and an oxygen atom is bonded to the terminal.
- the alkylthio group means a group having a sulfur atom bonded to the terminal of the alkyl group, such as a methylthio group, an ethylthio group or the like.
- alkylsulfinyl group refers to a group having an alkyl group terminal (SO-) such as a methylsulfinyl group.
- Alkylsulfonyl refers to a group having a terminal (so 2 -) at the alkyl group, such as a methylsulfonyl group.
- Halogen means fluorine, chlorine, bromine or iodine.
- the compound of the formula I of the present invention can be produced by the following method, wherein each group in the reaction formula is as defined above.
- Suitable solvents are selected from the group consisting of dichloromethane, chloroform, carbon tetrachloride, hexane, benzene, toluene, ethyl acetate, acetonitrile, THF, dioxane, DMF or dimethyl sulfoxide.
- Suitable bases are selected from organic bases such as sodium methoxide, sodium t-butoxide, potassium t-butoxide, triethylamine, N,N-dimethylaniline or pyridine, or inorganic bases such as sodium carbonate, potassium carbonate, sodium hydrogencarbonate. , sodium hydroxide or potassium hydroxide.
- nitro compound IV is reacted with a reducing agent such as iron, zinc or hydrogen (see the method described in the patent EPA 0 083 055 A2), and a compound II is obtained by reacting in a suitable solvent at a temperature of from -10 ° C to a boiling point for 0.5 to 48 hours.
- a reducing agent such as iron, zinc or hydrogen
- the solvent may be selected from the group consisting of water, acetic acid, acetone, dichloromethane, chloroform, carbon tetrachloride, hexane, benzene, toluene, ethyl acetate, ethanol, DMF, THF or dioxane;
- the compound II in which the mixed solvent of the three solvents is a halogen atom can also be obtained by reacting the compound II which is hydrogen with a halogenating agent in a suitable solvent at a temperature of -10 ° C to the boiling point for 0.5 to 48 hours.
- the halogenating agent is halogen, halogenated succinimide or the like;
- the solvent may be selected from the group consisting of dichloromethane, chloroform, carbon tetrachloride, DMF, THF, dioxane or dimethyl sulfoxide.
- Halogen is selected from the group consisting of iodine, bromine or chlorine.
- the compound II which is CN can also be obtained by reacting the compound II which is a halogen atom with a cyanating agent in a suitable solvent at a temperature of from -10 ° C to a boiling point for 0.5 to 48 hours.
- the cyanation reagent is sodium cyanide, potassium cyanide or cuprous cyanide; the solvent may be selected from the group consisting of DMF, THF, dioxane or dimethyl sulfoxide.
- Halogen is selected from the group consisting of iodine and bromine.
- the preparation method of the compound IV is as follows:
- Benzoyl chloride V (commercially available, can also be prepared by known general methods, see, March J, Advanced Organic Chemistry, 4 th Ed, John Wiley & sons, 1992) in a suitable solvent, acetonitrile with an aminoalkyl VI (Commercially available, can also be prepared by us, and the preparation method is described in J. Peptide Res. 56, 2000, 283-297).
- the compound IV is obtained by reacting at a temperature of -10 ° C to the boiling point for 0.5 to 48 hours.
- the solvent may be selected from the group consisting of chloroform, dichloromethane, carbon tetrachloride, hexane, benzene, toluene, ethyl acetate, DMF, THF or dioxane.
- a base such as triethylamine, pyridine, sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate or sodium hydrogencarbonate is advantageous for the reaction.
- Table 1 lists the structural and physical properties of some of the compounds of formula I.
- the fat solubility of the organic molecule can be improved.
- the fat solubility of molecules is closely related to the transport of molecules in organisms such as insects and plants.
- the appropriate transport properties of biologically active molecules play an important role in the efficacy of the drug.
- the suitability of bioactive molecular transport properties is unpredictable, but requires a large amount of creative labor to be known.
- the benzoyl group of the formula I of the present invention is compared to the known benzamidoacetonitrile compounds.
- Aminoalkyl acetonitrile compounds have unexpectedly high insecticidal activity while having high bactericidal activity. Accordingly, the present invention also encompasses the use of a compound of formula I for controlling pests and diseases.
- the present invention also encompasses insecticidal and bactericidal compositions having a compound of formula I as an active ingredient.
- the weight percent of active ingredient in the insecticidal, bactericidal composition is between 1 and 99%.
- the insecticidal and bactericidal compositions also include agricultural, forestry, and hygienic acceptable carriers.
- compositions of the invention may be administered in the form of a formulation.
- the compound of the formula I is dissolved or dispersed in the carrier as an active ingredient or formulated into a formulation for easier dispersion when used as an insecticide or bactericide.
- These chemicals can be formulated as wettable powders or creams.
- at least one liquid or solid carrier is added, and a suitable surfactant may be added as needed.
- the technical solution of the present invention also includes a method of controlling pests by applying the pesticidal composition of the present invention to the pest or the growth medium thereof.
- a more suitable effective amount is usually selected from 10 grams to 1000 grams per hectare, preferably from 20 grams to 500 grams per hectare.
- the technical solution of the present invention also includes a method of controlling a disease by applying the bactericidal composition of the present invention to the disease or its growth medium.
- a more suitable effective amount is usually selected from 100 grams to 2000 grams per hectare, preferably from 200 grams to 1000 grams per hectare.
- one or more other fungicides, insecticides, herbicides, plant growth regulators or fertilizers may be added to the pesticidal and bactericidal compositions of the invention, for example, in agriculture. Produces additional advantages and effects.
- N-(l-Cyanoethyl)-3-methyl-2-nitrobenzamide (4.0 g, 17.2 mmol), 40 ml of tetrahydrofuran, 40 ml of water and zinc were sequentially added to a 250 ml reaction flask.
- the powder (5.6 g, 86 mmol) was added dropwise with concentrated hydrochloric acid (5.2 g, 51.6 mmol) over 30 minutes with stirring at room temperature, and the reaction temperature did not exceed 30 °C. The reaction was continued at room temperature for 3 hours.
- the insoluble material in the reaction mixture was filtered, and the filtrate was evaporated,jjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjjj
- N-(l-Cyanoethyl)-3-methyl-2-aminobenzamide (1.8 g, 8.9 mmol)
- N-chlorosuccinimide N-chlorosuccinimide
- NCS 1.2 g, 8.9 mmol
- dimethylformamide 20 ml
- the reaction mixture was poured into 100 ml of water and extracted with 2 ⁇ 100 ml of ethyl acetate.
- the organic phase was washed with water and brine, and dried over anhydrous magnesium sulfate. The analysis showed no significant impurities, and the yield was 86%.
- 2,3-dichloropyridine (74 g, 500 mmol), 50% hydrazine hydrate (250 g, 2.5 mol) and 300 ml of dioxane were sequentially added to a 1000 ml reaction flask, and stirred at reflux temperature for 20 hours. . The reaction solution was cooled overnight, and white crystals were precipitated, filtered, and dried to give a solid, 51 g, yield: 71%.
- N-(l-Methyl-1-cyanoethyl)-3-methyl-2-nitrobenzamide (6.4 g, 25.9 mmol), 80 ml of acetic acid and then sequentially were placed in a 250 ml reaction flask. Iron powder (5.8 g, 103.6 mmol), the reaction temperature was controlled to not exceed 80 ° C, and the reaction was carried out for 3 hours. After cooling to room temperature, 100 ml of water was added, and the mixture was extracted with EtOAc EtOAc EtOAc. The yield was 80%.
- N-(l-Methyl-1-cyanoethyl)-3-methyl-2-aminobenzamide (4.3 g, 19.8 mmol), NCS (2.7 g, was added sequentially to a 150 ml reaction flask. 19.8 mmol) and 50 ml of dimethylformamide were stirred and heated to 100-110 ° C for 30 minutes. After cooling to room temperature, the reaction mixture was poured into 100 ml of water and extracted with 3 ⁇ 100 ml of ethyl acetate. The organic phase was washed with water and brine, dried over anhydrous magnesium sulfate 80%.
- the filtrate was concentrated to about 10 ml on a rotary evaporator, 50 ml of water was added, and the solid product was collected by filtration. The product was washed with 3 x 15 ml of 25% aqueous acetonitrile, and dried to give an orange solid, 1.6 g, yield: 56%.
- the original pharmaceutically acceptable acetone or dimethyl sulfoxide is dissolved, and then 1% is used.
- the Tween 80 solution is formulated into a desired concentration of 50 ml of test solution, and the content of acetone or dimethyl sulfoxide in the total solution is not more than 10%.
- the cabbage leaves were punched into a 1 cm diameter leaf disc with a puncher and sprayed with Airbrush. A certain concentration of the test compound was sprayed on the front and back of each leaf disc. The spray volume was 0.5 ml. After the dry operation, 10 shots were applied per treatment. Insects (2 years old), repeated 3 times per treatment. After the treatment, the cells were cultured at 24 ° C, relative humidity of 60% to 70%, and exposed to light. After 96 hours, the number of viable animals was investigated and the mortality was calculated.
- compounds 1.1, 1.2, 1.14a, 1.14, 1.25a, 1.26 had a mortality rate of more than 90% against Plutella xylostella.
- the cabbage leaves were punched into a 1 cm diameter leaf disc with a puncher and sprayed with Airbrush. A certain concentration of the test compound was sprayed on the front and back of each leaf dish, and the spray volume was 0.5 ml. After the dry operation, 8 passes per treatment were applied. Insects (3 years old), repeated 3 times per treatment. After the treatment, the cells were cultured at 24 ° C, relative humidity of 60% to 70%, and without light. After 96 hours, the number of surviving insects was investigated, and the mortality was calculated.
- the following compounds had better control effect on beet armyworm at a concentration of 1 ppm, and the mortality rate was above 90%: 1.1, 1.2, 1.3, 1.4, 1.5, 1.6, 1.7, 1.8, 1.9, 1.10, 1.11, 1.14, 1.15, 1.16, 1.17, 1.18, 1.19, 1.20, 1.21, 1.24, 1.27.
- the following compounds had better control effect on Spodoptera exigua at a concentration of 0.2 ppm, and the mortality rate was above 90%: 1.1, 1.4, 1.14, 1.15, 1.18, 1.19, 1.21, 1.24.
- the original pharmaceutically acceptable acetone or dimethyl sulfoxide is dissolved, and then 1% is used.
- the Tween 80 solution is formulated into a desired concentration of 50 ml of the test solution, and the content of acetone or dimethyl sulfoxide in the total solution is not more than 10
- Compound 1.17 has a control effect on rice blast of more than 90%.
- the potted cucumber seedlings with uniform growth were selected to cut off the growth point and two true leaves were retained.
- the test compound was sprayed at a concentration of 400 ppm and sprayed.
- the treated test material was inoculated with the cucumber downy mildew spore suspension on the next day, and then placed in an artificial climate chamber (temperature: ⁇ 25 °C, night 20 °C, relative humidity: 95 ⁇ 100%), and cultured for 6 days after moisturizing. Investigate the prevention and treatment effect, record according to the degree of disease, and calculate the control effect by disease index.
- Compound 1.14 has a control effect on cucumber downy mildew of more than 90%.
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- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200710011176 CN101298451B (zh) | 2007-04-30 | 2007-04-30 | 苯甲酰胺类化合物及其应用 |
CN200710011176.7 | 2007-04-30 | ||
CN2008100571021A CN101497602B (zh) | 2008-01-30 | 2008-01-30 | 邻氨基苯甲酸类化合物及其应用 |
CN200810057102.1 | 2008-01-30 |
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Publication Number | Publication Date |
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WO2008134969A1 true WO2008134969A1 (fr) | 2008-11-13 |
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Application Number | Title | Priority Date | Filing Date |
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PCT/CN2008/070830 WO2008134969A1 (fr) | 2007-04-30 | 2008-04-28 | Composés benzamides et leurs applications |
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WO (1) | WO2008134969A1 (zh) |
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CN101967139A (zh) * | 2010-09-14 | 2011-02-09 | 中化蓝天集团有限公司 | 一种含一氟甲氧基吡唑的邻甲酰氨基苯甲酰胺类化合物、其合成方法及应用 |
WO2011020579A1 (de) | 2009-08-20 | 2011-02-24 | Bayer Cropscience Ag | Verfahren zur herstellung von 1-phenyl-1,2,4-triazolen |
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WO2016124557A1 (de) | 2015-02-05 | 2016-08-11 | Bayer Cropscience Aktiengesellschaft | 2-(het)aryl-substituierte kondensierte bicyclische heterocyclen-derivate als schädlingsbekämpfungsmittel |
WO2016124563A1 (de) | 2015-02-05 | 2016-08-11 | Bayer Cropscience Aktiengesellschsaft | 2-(het)aryl-substituierte kondensierte bicyclische heterocyclen-derivate als schädlings-bekämpfungsmittel |
WO2016128261A2 (en) | 2015-02-11 | 2016-08-18 | Basf Se | Pesticidal mixture comprising a pyrazole compound, an insecticide and a fungicide |
WO2016128298A1 (de) | 2015-02-09 | 2016-08-18 | Bayer Cropscience Aktiengesellschaft | Substituierte 2-thioimidazolyl-carboxamide als schädlingsbekämpfungsmittel |
WO2016142394A1 (de) | 2015-03-10 | 2016-09-15 | Bayer Animal Health Gmbh | Pyrazolyl-derivate als schädlingsbekämpfungsmittel |
CN105941424A (zh) * | 2016-05-31 | 2016-09-21 | 河北博嘉农业有限公司 | 一种防治水稻稻飞虱的农业杀虫组合物 |
WO2016162318A1 (de) | 2015-04-08 | 2016-10-13 | Bayer Cropscience Aktiengesellschaft | Kondensierte bicyclische heterocyclen-derivate als schädlingsbekämpfungsmittel und deren zwischenprodukte |
WO2016162371A1 (en) | 2015-04-07 | 2016-10-13 | Basf Agrochemical Products B.V. | Use of an insecticidal carboxamide compound against pests on cultivated plants |
EP3081085A1 (en) | 2015-04-14 | 2016-10-19 | Bayer CropScience AG | Method for improving earliness in cotton |
WO2016174049A1 (en) | 2015-04-30 | 2016-11-03 | Bayer Animal Health Gmbh | Anti-parasitic combinations including halogen-substituted compounds |
CN106106469A (zh) * | 2016-08-05 | 2016-11-16 | 河北博嘉农业有限公司 | 一种含有n‑(氰烷基)苯甲酰胺类化合物和异噻菌胺的农业杀虫组合物 |
WO2016180802A1 (de) | 2015-05-13 | 2016-11-17 | Bayer Cropscience Aktiengesellschaft | Insektizide arylpyrrolidine, verfahren zu ihrer herstellung und ihre verwendung als wirkstoffe zur bekämpfung tierischer schädlinge |
WO2016198611A1 (en) | 2015-06-11 | 2016-12-15 | Basf Se | N-(thio)acylimino heterocyclic compounds |
WO2016198613A1 (en) | 2015-06-11 | 2016-12-15 | Basf Se | N-(thio)acylimino compounds |
WO2017005717A1 (en) | 2015-07-06 | 2017-01-12 | Bayer Cropscience Aktiengesellschaft | Heterocyclic compounds as pesticides |
CN106342870A (zh) * | 2016-07-28 | 2017-01-25 | 河北博嘉农业有限公司 | 一种含有n‑(氰烷基)苯甲酰胺类化合物的农业杀虫组合物 |
WO2017016883A1 (en) | 2015-07-24 | 2017-02-02 | Basf Se | Process for preparation of cyclopentene compounds |
EP3075729A4 (en) * | 2013-11-25 | 2017-04-19 | Shenyang Sinochem Agrochemicals R & D Co., Ltd. | Pyrazole amide compound and application thereof |
WO2017093163A1 (en) | 2015-11-30 | 2017-06-08 | Basf Se | Mixtures of cis-jasmone and bacillus amyloliquefaciens |
EP3210468A1 (de) | 2016-02-26 | 2017-08-30 | Bayer CropScience Aktiengesellschaft | Lösungsmittelfreie formulierungen von niedrig schmelzenden wirkstoffen |
WO2017153217A1 (en) | 2016-03-09 | 2017-09-14 | Basf Se | Spirocyclic derivatives |
WO2017153218A1 (en) | 2016-03-11 | 2017-09-14 | Basf Se | Method for controlling pests of plants |
US9776967B2 (en) | 2013-10-14 | 2017-10-03 | Bayer Animal Health Gmbh | Carboxamide derivatives as pesticidal compounds |
WO2017167832A1 (en) | 2016-04-01 | 2017-10-05 | Basf Se | Bicyclic compounds |
WO2017198588A1 (en) | 2016-05-18 | 2017-11-23 | Basf Se | Capsules comprising benzylpropargylethers for use as nitrification inhibitors |
WO2018013382A1 (en) | 2016-07-11 | 2018-01-18 | Covestro Llc, Et Al | Aqueous compositions for treating seeds, seeds treated therewith, and methods for treating seeds |
WO2018011111A1 (de) | 2016-07-12 | 2018-01-18 | Bayer Cropscience Aktiengesellschaft | Bicyclische verbindungen als schädlingsbekämpfungsmittel |
WO2018013381A1 (en) | 2016-07-11 | 2018-01-18 | Covestro Llc, Et Al. | Aqueous compositions for treating seeds, seeds treated therewith, and methods for treating seeds |
WO2018013380A1 (en) | 2016-07-11 | 2018-01-18 | Covestro Llc, Et Al. | Methods for treating seeds with an aqueous compostion and seeds treated therewith |
WO2018069842A1 (en) | 2016-10-14 | 2018-04-19 | Pi Industries Ltd | 4-amino substituted phenylamidine derivatives and their use to protect crops by fighting undesired phytopathogenic micoorganisms |
WO2018069841A1 (en) | 2016-10-14 | 2018-04-19 | Pi Industries Ltd | 4-substituted phenylamine derivatives and their use to protect crops by fighting undesired phytopathogenic micoorganisms |
WO2018104500A1 (en) | 2016-12-09 | 2018-06-14 | Bayer Cropscience Aktiengesellschaft | Plant health effect of purpureocillium lilacinum |
WO2018108671A1 (en) | 2016-12-16 | 2018-06-21 | Basf Se | Pesticidal compounds |
WO2018116072A1 (en) | 2016-12-20 | 2018-06-28 | Pi Industries Ltd. | Heterocyclic compounds |
WO2018116073A1 (en) | 2016-12-21 | 2018-06-28 | Pi Industries Ltd. | 1, 2, 3-thiadiazole compounds and their use as crop protecting agent |
WO2018162312A1 (en) | 2017-03-10 | 2018-09-13 | Basf Se | Spirocyclic derivatives |
WO2018166855A1 (en) | 2017-03-16 | 2018-09-20 | Basf Se | Heterobicyclic substituted dihydroisoxazoles |
WO2018177970A1 (en) | 2017-03-31 | 2018-10-04 | Basf Se | Process for preparing chiral 2,3-dihydrothiazolo[3,2-a]pyrimidin-4-ium compounds |
WO2018177993A1 (de) | 2017-03-31 | 2018-10-04 | Bayer Cropscience Aktiengesellschaft | Pyrazole zur bekämpfung von arthropoden |
WO2018177995A1 (de) | 2017-03-31 | 2018-10-04 | Bayer Cropscience Aktiengesellschaft | Trizyklische carboxamide zur bekämpfung von anthropoden |
WO2018177781A1 (en) | 2017-03-28 | 2018-10-04 | Basf Se | Pesticidal compounds |
WO2018192793A1 (en) | 2017-04-20 | 2018-10-25 | Basf Se | Substituted rhodanine derivatives |
WO2018193385A1 (en) | 2017-04-20 | 2018-10-25 | Pi Industries Ltd. | Novel phenylamine compounds |
WO2018197466A1 (en) | 2017-04-26 | 2018-11-01 | Basf Se | Substituted succinimide derivatives as pesticides |
WO2018206479A1 (en) | 2017-05-10 | 2018-11-15 | Basf Se | Bicyclic pesticidal compounds |
US10149477B2 (en) | 2014-10-06 | 2018-12-11 | Basf Se | Substituted pyrimidinium compounds for combating animal pests |
WO2018224455A1 (en) | 2017-06-07 | 2018-12-13 | Basf Se | Substituted cyclopropyl derivatives |
WO2018229202A1 (en) | 2017-06-16 | 2018-12-20 | Basf Se | Mesoionic imidazolium compounds and derivatives for combating animal pests |
WO2018234488A1 (en) | 2017-06-23 | 2018-12-27 | Basf Se | SUBSTITUTED CYCLOPROPYL DERIVATIVES |
WO2018234202A1 (en) | 2017-06-19 | 2018-12-27 | Basf Se | SUBSTITUTED PYRIMIDINIUM COMPOUNDS AND DERIVATIVES FOR CONTROLLING HARMFUL ANIMALS |
WO2019007891A1 (de) | 2017-07-06 | 2019-01-10 | Bayer Aktiengesellschaft | Insektizide wirkstoffkombinationen |
WO2019007887A1 (de) | 2017-07-06 | 2019-01-10 | Bayer Aktiengesellschaft | Insektizide und fungizide wirkstoffkombinationen |
WO2019007888A1 (de) | 2017-07-06 | 2019-01-10 | Bayer Aktiengesellschaft | Insektizide wirkstoffkombinationen |
WO2019043183A1 (en) | 2017-08-31 | 2019-03-07 | Basf Se | METHOD FOR CONTROLLING PESTS OF RICE IN RICE |
EP3453706A1 (en) | 2017-09-08 | 2019-03-13 | Basf Se | Pesticidal imidazole compounds |
WO2019072906A1 (en) | 2017-10-13 | 2019-04-18 | Basf Se | IMIDAZOLIDINE PYRIMIDINIUM COMPOUNDS FOR CONTROL OF HARMFUL ANIMALS |
EP3473103A1 (de) | 2017-10-17 | 2019-04-24 | Bayer AG | Wässrige suspensionskonzentrate auf basis von 2-[(2,4-dichlorphenyl)-methyl]-4,4'-dimethyl-3-isoxazolidinon |
WO2019121159A1 (en) | 2017-12-21 | 2019-06-27 | Basf Se | Pesticidal compounds |
WO2019123196A1 (en) | 2017-12-20 | 2019-06-27 | Pi Industries Ltd. | Fluoralkenyl compounds, process for preparation and use thereof |
WO2019121143A1 (en) | 2017-12-20 | 2019-06-27 | Basf Se | Substituted cyclopropyl derivatives |
WO2019128871A1 (zh) | 2017-12-29 | 2019-07-04 | 江苏中旗科技股份有限公司 | N-烷基-n-氰基烷基苯甲酰胺类化合物及其应用 |
WO2019137995A1 (en) | 2018-01-11 | 2019-07-18 | Basf Se | Novel pyridazine compounds for controlling invertebrate pests |
WO2019145140A1 (en) | 2018-01-09 | 2019-08-01 | Basf Se | Silylethynyl hetaryl compounds as nitrification inhibitors |
WO2019150311A1 (en) | 2018-02-02 | 2019-08-08 | Pi Industries Ltd. | 1-3 dithiol compounds and their use for the protection of crops from phytopathogenic microorganisms |
WO2019166561A1 (en) | 2018-02-28 | 2019-09-06 | Basf Se | Use of alkoxypyrazoles as nitrification inhibitors |
WO2019166558A1 (en) | 2018-02-28 | 2019-09-06 | Basf Se | Use of pyrazole propargyl ethers as nitrification inhibitors |
WO2019166560A1 (en) | 2018-02-28 | 2019-09-06 | Basf Se | Use of n-functionalized alkoxy pyrazole compounds as nitrification inhibitors |
WO2019175713A1 (en) | 2018-03-14 | 2019-09-19 | Basf Corporation | New catechol molecules and their use as inhibitors to p450 related metabolic pathways |
WO2019175712A1 (en) | 2018-03-14 | 2019-09-19 | Basf Corporation | New uses for catechol molecules as inhibitors to glutathione s-transferase metabolic pathways |
WO2019185413A1 (en) | 2018-03-27 | 2019-10-03 | Basf Se | Pesticidal substituted cyclopropyl derivatives |
WO2019219529A1 (en) | 2018-05-15 | 2019-11-21 | Basf Se | Mixtures comprising benzpyrimoxan and oxazosulfyl and uses and methods of applying them |
WO2019224092A1 (en) | 2018-05-22 | 2019-11-28 | Basf Se | Pesticidally active c15-derivatives of ginkgolides |
WO2020002472A1 (en) | 2018-06-28 | 2020-01-02 | Basf Se | Use of alkynylthiophenes as nitrification inhibitors |
WO2020002189A1 (de) | 2018-06-27 | 2020-01-02 | Bayer Aktiengesellschaft | Wirkstoffkombinationen |
WO2020021082A1 (en) | 2018-07-27 | 2020-01-30 | Bayer Aktiengesellschaft | Controlled release formulations for agrochemicals |
WO2020020765A1 (en) | 2018-07-23 | 2020-01-30 | Basf Se | Use of a substituted thiazolidine compound as nitrification inhibitor |
WO2020020777A1 (en) | 2018-07-23 | 2020-01-30 | Basf Se | Use of substituted 2-thiazolines as nitrification inhibitors |
WO2020025650A1 (en) | 2018-07-31 | 2020-02-06 | Bayer Aktiengesellschaft | Controlled release formulations with lignin for agrochemicals |
US10556844B2 (en) | 2015-02-06 | 2020-02-11 | Basf Se | Pyrazole compounds as nitrification inhibitors |
WO2020035826A1 (en) | 2018-08-17 | 2020-02-20 | Pi Industries Ltd. | 1,2-dithiolone compounds and use thereof |
EP3613736A1 (en) | 2018-08-22 | 2020-02-26 | Basf Se | Substituted glutarimide derivatives |
EP3628158A1 (en) | 2018-09-28 | 2020-04-01 | Basf Se | Pesticidal mixture comprising a mesoionic compound and a biopesticide |
EP3628157A1 (en) | 2018-09-28 | 2020-04-01 | Basf Se | Method of controlling insecticide resistant insects and virus transmission to plants |
EP3628156A1 (en) | 2018-09-28 | 2020-04-01 | Basf Se | Method for controlling pests of sugarcane, citrus, rapeseed, and potato plants |
WO2020064492A1 (en) | 2018-09-28 | 2020-04-02 | Basf Se | Method of controlling pests by seed treatment application of a mesoionic compound or mixture thereof |
EP3643705A1 (en) | 2018-10-24 | 2020-04-29 | Basf Se | Pesticidal compounds |
WO2020109039A1 (en) | 2018-11-28 | 2020-06-04 | Basf Se | Pesticidal compounds |
WO2020126591A1 (en) | 2018-12-18 | 2020-06-25 | Basf Se | Substituted pyrimidinium compounds for combating animal pests |
EP3696177A1 (en) | 2019-02-12 | 2020-08-19 | Basf Se | Heterocyclic compounds for the control of invertebrate pests |
WO2020239517A1 (en) | 2019-05-29 | 2020-12-03 | Basf Se | Mesoionic imidazolium compounds and derivatives for combating animal pests |
EP3766879A1 (en) | 2019-07-19 | 2021-01-20 | Basf Se | Pesticidal pyrazole derivatives |
EP3769623A1 (en) | 2019-07-22 | 2021-01-27 | Basf Se | Mesoionic imidazolium compounds and derivatives for combating animal pests |
WO2021048188A1 (de) | 2019-09-11 | 2021-03-18 | Bayer Aktiengesellschaft | Hochwirksame formulierungen auf basis von 2-[(2;4-dichlorphenyl)-m ethyl|-4,4'-dimethyl- 3-isoxazolidinone sowie vorauflaufherbiziden |
WO2021130143A1 (en) | 2019-12-23 | 2021-07-01 | Basf Se | Enzyme enhanced root uptake of agrochemical active compound |
US11053175B2 (en) | 2015-05-12 | 2021-07-06 | Basf Se | Thioether compounds as nitrification inhibitors |
WO2021170463A1 (en) | 2020-02-28 | 2021-09-02 | BASF Agro B.V. | Methods and uses of a mixture comprising alpha-cypermethrin and dinotefuran for controlling invertebrate pests in turf |
EP3733660A4 (en) * | 2017-12-29 | 2021-09-15 | Jiangsu Flag Chemical Industry Co., Ltd. | N-ALKYL-N-CYANOALKYLBENZAMIDE COMPOUND AND THE USE OF IT |
US11142514B2 (en) | 2015-10-02 | 2021-10-12 | Basf Se | Imino compounds with a 2-chloropyrimidin-5-yl substituent as pest-control agents |
EP3896065A1 (de) | 2015-08-07 | 2021-10-20 | Bayer CropScience Aktiengesellschaft | 2-(het)aryl-substituierte kondensierte heterocyclen-derivate als schädlingsbekämpfungsmittel |
WO2021219513A1 (en) | 2020-04-28 | 2021-11-04 | Basf Se | Pesticidal compounds |
EP3909950A1 (en) | 2020-05-13 | 2021-11-17 | Basf Se | Heterocyclic compounds for the control of invertebrate pests |
WO2022162129A1 (en) | 2021-01-28 | 2022-08-04 | Rhodia Operations | Method for treating rice seed with improved retention of agrochemical, micronutrient and colorant |
WO2022167488A1 (en) | 2021-02-02 | 2022-08-11 | Basf Se | Synergistic action of dcd and alkoxypyrazoles as nitrification inhibitors |
EP4043444A1 (en) | 2021-02-11 | 2022-08-17 | Basf Se | Substituted isoxazoline derivatives |
WO2022243521A1 (en) | 2021-05-21 | 2022-11-24 | Basf Se | Use of ethynylpyridine compounds as nitrification inhibitors |
WO2022243523A1 (en) | 2021-05-21 | 2022-11-24 | Basf Se | Use of an n-functionalized alkoxy pyrazole compound as nitrification inhibitor |
WO2022268810A1 (en) | 2021-06-21 | 2022-12-29 | Basf Se | Metal-organic frameworks with pyrazole-based building blocks |
EP4119547A1 (en) | 2021-07-12 | 2023-01-18 | Basf Se | Triazole compounds for the control of invertebrate pests |
EP4140986A1 (en) | 2021-08-23 | 2023-03-01 | Basf Se | Pyrazine compounds for the control of invertebrate pests |
EP4140995A1 (en) | 2021-08-27 | 2023-03-01 | Basf Se | Pyrazine compounds for the control of invertebrate pests |
EP4151631A1 (en) | 2021-09-20 | 2023-03-22 | Basf Se | Heterocyclic compounds for the control of invertebrate pests |
WO2023078915A1 (en) | 2021-11-03 | 2023-05-11 | Bayer Aktiengesellschaft | Bis(hetero)aryl thioether (thio)amides as fungicidal compounds |
WO2023092050A1 (en) | 2021-11-20 | 2023-05-25 | Bayer Cropscience Lp | Beneficial combinations with recombinant bacillus cells expressing a serine protease |
WO2023099445A1 (en) | 2021-11-30 | 2023-06-08 | Bayer Aktiengesellschaft | Bis(hetero)aryl thioether oxadiazines as fungicidal compounds |
EP4194453A1 (en) | 2021-12-08 | 2023-06-14 | Basf Se | Pyrazine compounds for the control of invertebrate pests |
EP4198023A1 (en) | 2021-12-16 | 2023-06-21 | Basf Se | Pesticidally active thiosemicarbazone compounds |
EP4198033A1 (en) | 2021-12-14 | 2023-06-21 | Basf Se | Heterocyclic compounds for the control of invertebrate pests |
WO2023110656A1 (en) | 2021-12-15 | 2023-06-22 | Bayer Aktiengesellschaft | Spectroscopic solution for non-destructive quantification of one or more chemical substances in a matrix comprising coating and bulk material in a sample, such as coated seeds, using multivariate data analysis |
EP4238971A1 (en) | 2022-03-02 | 2023-09-06 | Basf Se | Substituted isoxazoline derivatives |
WO2023203066A1 (en) | 2022-04-21 | 2023-10-26 | Basf Se | Synergistic action as nitrification inhibitors of dcd oligomers with alkoxypyrazole and its oligomers |
WO2023208447A1 (en) | 2022-04-25 | 2023-11-02 | Basf Se | An emulsifiable concentrate having a (substituted) benzaldehyde-based solvent system |
WO2024028243A1 (en) | 2022-08-02 | 2024-02-08 | Basf Se | Pyrazolo pesticidal compounds |
CN117567417A (zh) * | 2023-11-17 | 2024-02-20 | 山东绿霸化工股份有限公司 | 一组苯甲酰胺类化合物制备与应用 |
EP4342885A1 (en) | 2022-09-20 | 2024-03-27 | Basf Se | N-(3-(aminomethyl)-phenyl)-5-(4-phenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-amine derivatives and similar compounds as pesticides |
EP4389210A1 (en) | 2022-12-21 | 2024-06-26 | Basf Se | Heteroaryl compounds for the control of invertebrate pests |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003015518A1 (en) * | 2001-08-13 | 2003-02-27 | E.I. Du Pont De Nemours And Company | Method for controlling particular insect pests by applying anthranilamide compounds |
WO2003024222A1 (en) * | 2001-09-21 | 2003-03-27 | E. I. Du Pont De Nemours And Company | Anthranilamide arthropodicide treatment |
WO2004067528A1 (en) * | 2003-01-28 | 2004-08-12 | E.I. Du Pont De Nemours And Company | Cyano anthranilamide insecticides |
WO2005118552A2 (en) * | 2004-04-13 | 2005-12-15 | E.I. Dupont De Nemours And Company | Anthranilamide insecticides |
-
2008
- 2008-04-28 WO PCT/CN2008/070830 patent/WO2008134969A1/zh active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003015518A1 (en) * | 2001-08-13 | 2003-02-27 | E.I. Du Pont De Nemours And Company | Method for controlling particular insect pests by applying anthranilamide compounds |
WO2003024222A1 (en) * | 2001-09-21 | 2003-03-27 | E. I. Du Pont De Nemours And Company | Anthranilamide arthropodicide treatment |
WO2004067528A1 (en) * | 2003-01-28 | 2004-08-12 | E.I. Du Pont De Nemours And Company | Cyano anthranilamide insecticides |
WO2005118552A2 (en) * | 2004-04-13 | 2005-12-15 | E.I. Dupont De Nemours And Company | Anthranilamide insecticides |
Cited By (197)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010003350A1 (zh) * | 2008-07-07 | 2010-01-14 | 中国中化集团公司 | 1-取代吡啶基-吡唑酰胺类化合物及其应用 |
WO2011020579A1 (de) | 2009-08-20 | 2011-02-24 | Bayer Cropscience Ag | Verfahren zur herstellung von 1-phenyl-1,2,4-triazolen |
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JP2014509598A (ja) * | 2011-03-18 | 2014-04-21 | バイエル・インテレクチユアル・プロパテイー・ゲー・エム・ベー・ハー | N−(3−カルバモイルフェニル)−1h−ピラゾール−5−カルボキサミド誘導体及び害虫を防除するためのそれらの使用 |
WO2013136073A1 (en) * | 2012-03-13 | 2013-09-19 | Redx Pharma Limited | Agricultural chemicals |
WO2014005982A1 (de) | 2012-07-05 | 2014-01-09 | Bayer Cropscience Ag | Insektizide und fungizide wirkstoffkombinationen |
WO2014053407A1 (en) | 2012-10-01 | 2014-04-10 | Basf Se | N-thio-anthranilamide compounds and their use as pesticides |
WO2014053405A1 (en) | 2012-10-01 | 2014-04-10 | Basf Se | Pesticidally active mixtures comprising anthranilamide compounds |
WO2014053403A1 (en) | 2012-10-01 | 2014-04-10 | Basf Se | Method of controlling insecticide resistant insects |
WO2014053406A1 (en) | 2012-10-01 | 2014-04-10 | Basf Se | Method of controlling ryanodine-modulator insecticide resistant insects |
WO2014053395A1 (en) | 2012-10-01 | 2014-04-10 | Basf Se | Use of n-thio-anthranilamide compounds on cultivated plants |
WO2014053404A1 (en) | 2012-10-01 | 2014-04-10 | Basf Se | Pesticidally active mixtures comprising anthranilamide compounds |
WO2014053401A2 (en) | 2012-10-01 | 2014-04-10 | Basf Se | Method of improving plant health |
WO2014079774A1 (en) | 2012-11-22 | 2014-05-30 | Basf Se | Pesticidal mixtures |
WO2014079766A1 (en) | 2012-11-22 | 2014-05-30 | Basf Se | Pesticidal mixtures |
WO2014079814A1 (en) | 2012-11-22 | 2014-05-30 | Basf Se | Pesticidal mixtures |
WO2014079764A1 (en) | 2012-11-22 | 2014-05-30 | Basf Se | Pesticidal mixtures |
WO2014079841A1 (en) | 2012-11-22 | 2014-05-30 | Basf Se | Pesticidal mixtures |
WO2014079770A1 (en) | 2012-11-22 | 2014-05-30 | Basf Se | Pesticidal mixtures |
WO2014079772A1 (en) | 2012-11-22 | 2014-05-30 | Basf Se | Pesticidal mixtures |
WO2014079820A1 (en) | 2012-11-22 | 2014-05-30 | Basf Se | Use of anthranilamide compounds for reducing insect-vectored viral infections |
WO2014079804A1 (en) | 2012-11-22 | 2014-05-30 | Basf Se | Pesticidal mixtures |
WO2014079773A1 (en) | 2012-11-22 | 2014-05-30 | Basf Se | Pesticidal mixtures |
WO2014079813A1 (en) | 2012-11-23 | 2014-05-30 | Basf Se | Pesticidal mixtures |
WO2014079752A1 (en) | 2012-11-23 | 2014-05-30 | Basf Se | Pesticidal mixtures |
WO2014090700A1 (en) | 2012-12-14 | 2014-06-19 | Basf Se | Malononitrile compounds for controlling animal pests |
US10117430B2 (en) | 2012-12-14 | 2018-11-06 | Basf Se | Malononitrile compounds for controlling animal pests |
WO2014102244A1 (en) | 2012-12-27 | 2014-07-03 | Basf Se | 2-(pyridin-3-yl)-5-hetaryl-thiazole compounds carrying an imine or imine-derived substituent for combating invertebrate pests |
WO2014128136A1 (en) | 2013-02-20 | 2014-08-28 | Basf Se | Anthranilamide compounds and their use as pesticides |
WO2014170300A1 (en) | 2013-04-19 | 2014-10-23 | Basf Se | N-substituted acyl-imino-pyridine compounds and derivatives for combating animal pests |
WO2014202751A1 (en) | 2013-06-21 | 2014-12-24 | Basf Se | Methods for controlling pests in soybean |
WO2015007682A1 (en) | 2013-07-15 | 2015-01-22 | Basf Se | Pesticide compounds |
WO2015040116A1 (en) | 2013-09-19 | 2015-03-26 | Basf Se | N-acylimino heterocyclic compounds |
WO2015055554A1 (de) | 2013-10-14 | 2015-04-23 | Bayer Cropscience Ag | Wirkstoff für die saatgut- und bodenbehandlung |
US9776967B2 (en) | 2013-10-14 | 2017-10-03 | Bayer Animal Health Gmbh | Carboxamide derivatives as pesticidal compounds |
WO2015055497A1 (en) | 2013-10-16 | 2015-04-23 | Basf Se | Substituted pesticidal pyrazole compounds |
WO2015055757A1 (en) | 2013-10-18 | 2015-04-23 | Basf Se | Use of pesticidal active carboxamide derivative in soil and seed application and treatment methods |
EP3456201A1 (en) | 2013-10-18 | 2019-03-20 | BASF Agrochemical Products B.V. | Use of pesticidal active carboxamide derivative in soil and seed application and treatment meth-ods |
WO2015059088A1 (de) | 2013-10-23 | 2015-04-30 | Bayer Cropscience Ag | Substituierte chinoxalin-derivate als schädlingsbekämpfungsmittel |
EP3075729A4 (en) * | 2013-11-25 | 2017-04-19 | Shenyang Sinochem Agrochemicals R & D Co., Ltd. | Pyrazole amide compound and application thereof |
WO2015091649A1 (en) | 2013-12-18 | 2015-06-25 | Basf Se | N-substituted imino heterocyclic compounds |
WO2015091645A1 (en) | 2013-12-18 | 2015-06-25 | Basf Se | Azole compounds carrying an imine-derived substituent |
WO2015101622A1 (de) | 2014-01-03 | 2015-07-09 | Bayer Cropscience Ag | Neue pyrazolyl-heteroarylamide als schädlingsbekämpfungsmittel |
WO2015104422A1 (en) | 2014-01-13 | 2015-07-16 | Basf Se | Dihydrothiophene compounds for controlling invertebrate pests |
WO2015107133A1 (de) | 2014-01-20 | 2015-07-23 | Bayer Cropscience Ag | Chinolinderivate als insektizide und akarizide |
WO2015134998A1 (en) | 2014-03-07 | 2015-09-11 | Biocryst Pharmaceuticals, Inc. | Human plasma kallikrein inhibitors |
EP4180424A1 (en) | 2014-03-07 | 2023-05-17 | BioCryst Pharmaceuticals, Inc. | Substituted pyrazoles as human plasma kallikrein inhibitors |
WO2015150300A1 (de) | 2014-04-02 | 2015-10-08 | Bayer Cropscience Ag | N-(1-(hetero)aryl-1h-pyrazol-4-yl)-(hetero)arylamid-derivate und ihre verwendung als schädlingsbekämpfungsmittel |
WO2015169776A1 (en) | 2014-05-08 | 2015-11-12 | Bayer Cropscience Ag | Pyrazolopyridine sulfonamides as nematicides |
WO2015185531A1 (de) | 2014-06-05 | 2015-12-10 | Bayer Cropscience Aktiengesellschaft | Bicyclische verbindungen als schädlingsbekämpfungsmittel |
WO2016001119A1 (de) | 2014-07-01 | 2016-01-07 | Bayer Cropscience Aktiengesellschaft | Insektizide und fungizide wirkstoffkombinationen |
WO2016008830A1 (de) | 2014-07-15 | 2016-01-21 | Bayer Cropscience Aktiengesellschaft | Aryl-triazolyl-pyridine als schädlingsbekämpfungsmittel |
US10149477B2 (en) | 2014-10-06 | 2018-12-11 | Basf Se | Substituted pyrimidinium compounds for combating animal pests |
WO2016055096A1 (en) | 2014-10-07 | 2016-04-14 | Bayer Cropscience Ag | Method for treating rice seed |
WO2016071499A1 (en) | 2014-11-06 | 2016-05-12 | Basf Se | 3-pyridyl heterobicyclic compound for controlling invertebrate pests |
WO2016091857A1 (de) | 2014-12-11 | 2016-06-16 | Bayer Cropscience Aktiengesellschaft | Fünfgliedrige c-n-verknüpfte arylsulfid- und arylsulfoxid-derivate als schädlingsbekämpfungsmittel |
WO2016124557A1 (de) | 2015-02-05 | 2016-08-11 | Bayer Cropscience Aktiengesellschaft | 2-(het)aryl-substituierte kondensierte bicyclische heterocyclen-derivate als schädlingsbekämpfungsmittel |
WO2016124563A1 (de) | 2015-02-05 | 2016-08-11 | Bayer Cropscience Aktiengesellschsaft | 2-(het)aryl-substituierte kondensierte bicyclische heterocyclen-derivate als schädlings-bekämpfungsmittel |
US10556844B2 (en) | 2015-02-06 | 2020-02-11 | Basf Se | Pyrazole compounds as nitrification inhibitors |
WO2016128298A1 (de) | 2015-02-09 | 2016-08-18 | Bayer Cropscience Aktiengesellschaft | Substituierte 2-thioimidazolyl-carboxamide als schädlingsbekämpfungsmittel |
WO2016128261A2 (en) | 2015-02-11 | 2016-08-18 | Basf Se | Pesticidal mixture comprising a pyrazole compound, an insecticide and a fungicide |
WO2016142394A1 (de) | 2015-03-10 | 2016-09-15 | Bayer Animal Health Gmbh | Pyrazolyl-derivate als schädlingsbekämpfungsmittel |
WO2016162371A1 (en) | 2015-04-07 | 2016-10-13 | Basf Agrochemical Products B.V. | Use of an insecticidal carboxamide compound against pests on cultivated plants |
WO2016162318A1 (de) | 2015-04-08 | 2016-10-13 | Bayer Cropscience Aktiengesellschaft | Kondensierte bicyclische heterocyclen-derivate als schädlingsbekämpfungsmittel und deren zwischenprodukte |
EP3081085A1 (en) | 2015-04-14 | 2016-10-19 | Bayer CropScience AG | Method for improving earliness in cotton |
WO2016174049A1 (en) | 2015-04-30 | 2016-11-03 | Bayer Animal Health Gmbh | Anti-parasitic combinations including halogen-substituted compounds |
EP2910126A1 (en) | 2015-05-05 | 2015-08-26 | Bayer CropScience AG | Active compound combinations having insecticidal properties |
US11053175B2 (en) | 2015-05-12 | 2021-07-06 | Basf Se | Thioether compounds as nitrification inhibitors |
WO2016180802A1 (de) | 2015-05-13 | 2016-11-17 | Bayer Cropscience Aktiengesellschaft | Insektizide arylpyrrolidine, verfahren zu ihrer herstellung und ihre verwendung als wirkstoffe zur bekämpfung tierischer schädlinge |
WO2016198613A1 (en) | 2015-06-11 | 2016-12-15 | Basf Se | N-(thio)acylimino compounds |
WO2016198611A1 (en) | 2015-06-11 | 2016-12-15 | Basf Se | N-(thio)acylimino heterocyclic compounds |
WO2017005717A1 (en) | 2015-07-06 | 2017-01-12 | Bayer Cropscience Aktiengesellschaft | Heterocyclic compounds as pesticides |
WO2017016883A1 (en) | 2015-07-24 | 2017-02-02 | Basf Se | Process for preparation of cyclopentene compounds |
EP3896066A2 (de) | 2015-08-07 | 2021-10-20 | Bayer CropScience Aktiengesellschaft | 2-(het)aryl-substituierte kondensierte heterocyclen-derivate als schädlingsbekämpfungsmittel |
EP3896065A1 (de) | 2015-08-07 | 2021-10-20 | Bayer CropScience Aktiengesellschaft | 2-(het)aryl-substituierte kondensierte heterocyclen-derivate als schädlingsbekämpfungsmittel |
US11142514B2 (en) | 2015-10-02 | 2021-10-12 | Basf Se | Imino compounds with a 2-chloropyrimidin-5-yl substituent as pest-control agents |
WO2017093163A1 (en) | 2015-11-30 | 2017-06-08 | Basf Se | Mixtures of cis-jasmone and bacillus amyloliquefaciens |
WO2017144497A1 (de) | 2016-02-26 | 2017-08-31 | Bayer Cropscience Aktiengesellschaft | Lösungsmittelfreie formulierungen von niedrig schmelzenden wirkstoffen |
EP3210468A1 (de) | 2016-02-26 | 2017-08-30 | Bayer CropScience Aktiengesellschaft | Lösungsmittelfreie formulierungen von niedrig schmelzenden wirkstoffen |
WO2017153217A1 (en) | 2016-03-09 | 2017-09-14 | Basf Se | Spirocyclic derivatives |
WO2017153218A1 (en) | 2016-03-11 | 2017-09-14 | Basf Se | Method for controlling pests of plants |
WO2017167832A1 (en) | 2016-04-01 | 2017-10-05 | Basf Se | Bicyclic compounds |
WO2017198588A1 (en) | 2016-05-18 | 2017-11-23 | Basf Se | Capsules comprising benzylpropargylethers for use as nitrification inhibitors |
CN105941424A (zh) * | 2016-05-31 | 2016-09-21 | 河北博嘉农业有限公司 | 一种防治水稻稻飞虱的农业杀虫组合物 |
US10653136B2 (en) | 2016-07-11 | 2020-05-19 | Covestro Llc | Aqueous compositions for treating seeds, seeds treated therewith, and methods for treating seeds |
US10653135B2 (en) | 2016-07-11 | 2020-05-19 | Covestro Llc | Methods for treating seeds with an aqueous composition and seeds treated therewith |
WO2018013380A1 (en) | 2016-07-11 | 2018-01-18 | Covestro Llc, Et Al. | Methods for treating seeds with an aqueous compostion and seeds treated therewith |
WO2018013382A1 (en) | 2016-07-11 | 2018-01-18 | Covestro Llc, Et Al | Aqueous compositions for treating seeds, seeds treated therewith, and methods for treating seeds |
US10750750B2 (en) | 2016-07-11 | 2020-08-25 | Covestro Llc | Aqueous compositions for treating seeds, seeds treated therewith, and methods for treating seeds |
WO2018013381A1 (en) | 2016-07-11 | 2018-01-18 | Covestro Llc, Et Al. | Aqueous compositions for treating seeds, seeds treated therewith, and methods for treating seeds |
WO2018011111A1 (de) | 2016-07-12 | 2018-01-18 | Bayer Cropscience Aktiengesellschaft | Bicyclische verbindungen als schädlingsbekämpfungsmittel |
CN106342870A (zh) * | 2016-07-28 | 2017-01-25 | 河北博嘉农业有限公司 | 一种含有n‑(氰烷基)苯甲酰胺类化合物的农业杀虫组合物 |
CN106106469A (zh) * | 2016-08-05 | 2016-11-16 | 河北博嘉农业有限公司 | 一种含有n‑(氰烷基)苯甲酰胺类化合物和异噻菌胺的农业杀虫组合物 |
US11155517B2 (en) | 2016-10-14 | 2021-10-26 | Pi Industries Ltd. | 4-substituted phenylamine derivatives and their use to protect crops by fighting undesired phytopathogenic micoorganisms |
WO2018069841A1 (en) | 2016-10-14 | 2018-04-19 | Pi Industries Ltd | 4-substituted phenylamine derivatives and their use to protect crops by fighting undesired phytopathogenic micoorganisms |
WO2018069842A1 (en) | 2016-10-14 | 2018-04-19 | Pi Industries Ltd | 4-amino substituted phenylamidine derivatives and their use to protect crops by fighting undesired phytopathogenic micoorganisms |
WO2018104500A1 (en) | 2016-12-09 | 2018-06-14 | Bayer Cropscience Aktiengesellschaft | Plant health effect of purpureocillium lilacinum |
WO2018108671A1 (en) | 2016-12-16 | 2018-06-21 | Basf Se | Pesticidal compounds |
WO2018116072A1 (en) | 2016-12-20 | 2018-06-28 | Pi Industries Ltd. | Heterocyclic compounds |
WO2018116073A1 (en) | 2016-12-21 | 2018-06-28 | Pi Industries Ltd. | 1, 2, 3-thiadiazole compounds and their use as crop protecting agent |
WO2018162312A1 (en) | 2017-03-10 | 2018-09-13 | Basf Se | Spirocyclic derivatives |
WO2018166855A1 (en) | 2017-03-16 | 2018-09-20 | Basf Se | Heterobicyclic substituted dihydroisoxazoles |
WO2018177781A1 (en) | 2017-03-28 | 2018-10-04 | Basf Se | Pesticidal compounds |
WO2018177970A1 (en) | 2017-03-31 | 2018-10-04 | Basf Se | Process for preparing chiral 2,3-dihydrothiazolo[3,2-a]pyrimidin-4-ium compounds |
EP3978504A1 (en) | 2017-03-31 | 2022-04-06 | Basf Se | Chiral 2,3-dihydrothiazolo[3,2-a]pyrimidine derivatives for combating animal pests |
WO2018177995A1 (de) | 2017-03-31 | 2018-10-04 | Bayer Cropscience Aktiengesellschaft | Trizyklische carboxamide zur bekämpfung von anthropoden |
WO2018177993A1 (de) | 2017-03-31 | 2018-10-04 | Bayer Cropscience Aktiengesellschaft | Pyrazole zur bekämpfung von arthropoden |
US11825838B2 (en) | 2017-03-31 | 2023-11-28 | Bayer Cropscience Aktiengesellschaft | Tricyclic carboxamides for controlling arthropods |
WO2018192793A1 (en) | 2017-04-20 | 2018-10-25 | Basf Se | Substituted rhodanine derivatives |
US11524934B2 (en) | 2017-04-20 | 2022-12-13 | Pi Industries Ltd | Phenylamine compounds |
WO2018193385A1 (en) | 2017-04-20 | 2018-10-25 | Pi Industries Ltd. | Novel phenylamine compounds |
WO2018197466A1 (en) | 2017-04-26 | 2018-11-01 | Basf Se | Substituted succinimide derivatives as pesticides |
WO2018206479A1 (en) | 2017-05-10 | 2018-11-15 | Basf Se | Bicyclic pesticidal compounds |
EP3400801A1 (en) | 2017-05-10 | 2018-11-14 | Bayer CropScience Aktiengesellschaft | Plant health effect of purpureocillium lilacinum |
WO2018224455A1 (en) | 2017-06-07 | 2018-12-13 | Basf Se | Substituted cyclopropyl derivatives |
WO2018229202A1 (en) | 2017-06-16 | 2018-12-20 | Basf Se | Mesoionic imidazolium compounds and derivatives for combating animal pests |
WO2018234202A1 (en) | 2017-06-19 | 2018-12-27 | Basf Se | SUBSTITUTED PYRIMIDINIUM COMPOUNDS AND DERIVATIVES FOR CONTROLLING HARMFUL ANIMALS |
WO2018234488A1 (en) | 2017-06-23 | 2018-12-27 | Basf Se | SUBSTITUTED CYCLOPROPYL DERIVATIVES |
WO2019007888A1 (de) | 2017-07-06 | 2019-01-10 | Bayer Aktiengesellschaft | Insektizide wirkstoffkombinationen |
WO2019007887A1 (de) | 2017-07-06 | 2019-01-10 | Bayer Aktiengesellschaft | Insektizide und fungizide wirkstoffkombinationen |
WO2019007891A1 (de) | 2017-07-06 | 2019-01-10 | Bayer Aktiengesellschaft | Insektizide wirkstoffkombinationen |
WO2019042932A1 (en) | 2017-08-31 | 2019-03-07 | Basf Se | METHOD FOR CONTROLLING RICE PARASITES IN RICE |
WO2019043183A1 (en) | 2017-08-31 | 2019-03-07 | Basf Se | METHOD FOR CONTROLLING PESTS OF RICE IN RICE |
EP3453706A1 (en) | 2017-09-08 | 2019-03-13 | Basf Se | Pesticidal imidazole compounds |
WO2019072906A1 (en) | 2017-10-13 | 2019-04-18 | Basf Se | IMIDAZOLIDINE PYRIMIDINIUM COMPOUNDS FOR CONTROL OF HARMFUL ANIMALS |
WO2019076744A1 (de) | 2017-10-17 | 2019-04-25 | Bayer Aktiengesellschaft | Wässrige suspensionskonzentrate auf basis von 2-[(2,4-dichlorphenyl)-methyl]-4,4'-dimethyl-3-isoxazolidinone |
EP3473103A1 (de) | 2017-10-17 | 2019-04-24 | Bayer AG | Wässrige suspensionskonzentrate auf basis von 2-[(2,4-dichlorphenyl)-methyl]-4,4'-dimethyl-3-isoxazolidinon |
WO2019121143A1 (en) | 2017-12-20 | 2019-06-27 | Basf Se | Substituted cyclopropyl derivatives |
WO2019123196A1 (en) | 2017-12-20 | 2019-06-27 | Pi Industries Ltd. | Fluoralkenyl compounds, process for preparation and use thereof |
WO2019121159A1 (en) | 2017-12-21 | 2019-06-27 | Basf Se | Pesticidal compounds |
WO2019128871A1 (zh) | 2017-12-29 | 2019-07-04 | 江苏中旗科技股份有限公司 | N-烷基-n-氰基烷基苯甲酰胺类化合物及其应用 |
US11390602B2 (en) | 2017-12-29 | 2022-07-19 | Jiangsu Flag Chemical Industry Co., Ltd. | N-alkyl-N-cyanoalkylbenzamide compound and use thereof |
EP3733660A4 (en) * | 2017-12-29 | 2021-09-15 | Jiangsu Flag Chemical Industry Co., Ltd. | N-ALKYL-N-CYANOALKYLBENZAMIDE COMPOUND AND THE USE OF IT |
WO2019145140A1 (en) | 2018-01-09 | 2019-08-01 | Basf Se | Silylethynyl hetaryl compounds as nitrification inhibitors |
WO2019137995A1 (en) | 2018-01-11 | 2019-07-18 | Basf Se | Novel pyridazine compounds for controlling invertebrate pests |
WO2019150311A1 (en) | 2018-02-02 | 2019-08-08 | Pi Industries Ltd. | 1-3 dithiol compounds and their use for the protection of crops from phytopathogenic microorganisms |
WO2019166561A1 (en) | 2018-02-28 | 2019-09-06 | Basf Se | Use of alkoxypyrazoles as nitrification inhibitors |
WO2019166558A1 (en) | 2018-02-28 | 2019-09-06 | Basf Se | Use of pyrazole propargyl ethers as nitrification inhibitors |
WO2019166560A1 (en) | 2018-02-28 | 2019-09-06 | Basf Se | Use of n-functionalized alkoxy pyrazole compounds as nitrification inhibitors |
WO2019175713A1 (en) | 2018-03-14 | 2019-09-19 | Basf Corporation | New catechol molecules and their use as inhibitors to p450 related metabolic pathways |
WO2019175712A1 (en) | 2018-03-14 | 2019-09-19 | Basf Corporation | New uses for catechol molecules as inhibitors to glutathione s-transferase metabolic pathways |
WO2019185413A1 (en) | 2018-03-27 | 2019-10-03 | Basf Se | Pesticidal substituted cyclopropyl derivatives |
WO2019219529A1 (en) | 2018-05-15 | 2019-11-21 | Basf Se | Mixtures comprising benzpyrimoxan and oxazosulfyl and uses and methods of applying them |
WO2019224092A1 (en) | 2018-05-22 | 2019-11-28 | Basf Se | Pesticidally active c15-derivatives of ginkgolides |
WO2020002189A1 (de) | 2018-06-27 | 2020-01-02 | Bayer Aktiengesellschaft | Wirkstoffkombinationen |
WO2020002472A1 (en) | 2018-06-28 | 2020-01-02 | Basf Se | Use of alkynylthiophenes as nitrification inhibitors |
WO2020020777A1 (en) | 2018-07-23 | 2020-01-30 | Basf Se | Use of substituted 2-thiazolines as nitrification inhibitors |
WO2020020765A1 (en) | 2018-07-23 | 2020-01-30 | Basf Se | Use of a substituted thiazolidine compound as nitrification inhibitor |
WO2020021082A1 (en) | 2018-07-27 | 2020-01-30 | Bayer Aktiengesellschaft | Controlled release formulations for agrochemicals |
WO2020025650A1 (en) | 2018-07-31 | 2020-02-06 | Bayer Aktiengesellschaft | Controlled release formulations with lignin for agrochemicals |
WO2020035826A1 (en) | 2018-08-17 | 2020-02-20 | Pi Industries Ltd. | 1,2-dithiolone compounds and use thereof |
EP3613736A1 (en) | 2018-08-22 | 2020-02-26 | Basf Se | Substituted glutarimide derivatives |
WO2020064480A1 (en) | 2018-09-28 | 2020-04-02 | Basf Se | Pesticidal mixture comprising a mesoionic compound and a biopesticide |
EP3628156A1 (en) | 2018-09-28 | 2020-04-01 | Basf Se | Method for controlling pests of sugarcane, citrus, rapeseed, and potato plants |
WO2020064408A1 (en) | 2018-09-28 | 2020-04-02 | Basf Se | Method of controlling insecticide resistant insects and virus transmission to plants |
WO2020064492A1 (en) | 2018-09-28 | 2020-04-02 | Basf Se | Method of controlling pests by seed treatment application of a mesoionic compound or mixture thereof |
EP3628158A1 (en) | 2018-09-28 | 2020-04-01 | Basf Se | Pesticidal mixture comprising a mesoionic compound and a biopesticide |
EP3628157A1 (en) | 2018-09-28 | 2020-04-01 | Basf Se | Method of controlling insecticide resistant insects and virus transmission to plants |
EP3643705A1 (en) | 2018-10-24 | 2020-04-29 | Basf Se | Pesticidal compounds |
WO2020083733A1 (en) | 2018-10-24 | 2020-04-30 | Basf Se | Pesticidal compounds |
WO2020109039A1 (en) | 2018-11-28 | 2020-06-04 | Basf Se | Pesticidal compounds |
WO2020126591A1 (en) | 2018-12-18 | 2020-06-25 | Basf Se | Substituted pyrimidinium compounds for combating animal pests |
EP3696177A1 (en) | 2019-02-12 | 2020-08-19 | Basf Se | Heterocyclic compounds for the control of invertebrate pests |
WO2020239517A1 (en) | 2019-05-29 | 2020-12-03 | Basf Se | Mesoionic imidazolium compounds and derivatives for combating animal pests |
WO2021013561A1 (en) | 2019-07-19 | 2021-01-28 | Basf Se | Pesticidal pyrazole and triazole derivatives |
EP3766879A1 (en) | 2019-07-19 | 2021-01-20 | Basf Se | Pesticidal pyrazole derivatives |
EP3769623A1 (en) | 2019-07-22 | 2021-01-27 | Basf Se | Mesoionic imidazolium compounds and derivatives for combating animal pests |
WO2021048188A1 (de) | 2019-09-11 | 2021-03-18 | Bayer Aktiengesellschaft | Hochwirksame formulierungen auf basis von 2-[(2;4-dichlorphenyl)-m ethyl|-4,4'-dimethyl- 3-isoxazolidinone sowie vorauflaufherbiziden |
WO2021130143A1 (en) | 2019-12-23 | 2021-07-01 | Basf Se | Enzyme enhanced root uptake of agrochemical active compound |
WO2021170463A1 (en) | 2020-02-28 | 2021-09-02 | BASF Agro B.V. | Methods and uses of a mixture comprising alpha-cypermethrin and dinotefuran for controlling invertebrate pests in turf |
WO2021219513A1 (en) | 2020-04-28 | 2021-11-04 | Basf Se | Pesticidal compounds |
EP3909950A1 (en) | 2020-05-13 | 2021-11-17 | Basf Se | Heterocyclic compounds for the control of invertebrate pests |
WO2022162129A1 (en) | 2021-01-28 | 2022-08-04 | Rhodia Operations | Method for treating rice seed with improved retention of agrochemical, micronutrient and colorant |
WO2022167488A1 (en) | 2021-02-02 | 2022-08-11 | Basf Se | Synergistic action of dcd and alkoxypyrazoles as nitrification inhibitors |
EP4043444A1 (en) | 2021-02-11 | 2022-08-17 | Basf Se | Substituted isoxazoline derivatives |
WO2022243521A1 (en) | 2021-05-21 | 2022-11-24 | Basf Se | Use of ethynylpyridine compounds as nitrification inhibitors |
WO2022243523A1 (en) | 2021-05-21 | 2022-11-24 | Basf Se | Use of an n-functionalized alkoxy pyrazole compound as nitrification inhibitor |
WO2022268810A1 (en) | 2021-06-21 | 2022-12-29 | Basf Se | Metal-organic frameworks with pyrazole-based building blocks |
EP4119547A1 (en) | 2021-07-12 | 2023-01-18 | Basf Se | Triazole compounds for the control of invertebrate pests |
EP4140986A1 (en) | 2021-08-23 | 2023-03-01 | Basf Se | Pyrazine compounds for the control of invertebrate pests |
EP4140995A1 (en) | 2021-08-27 | 2023-03-01 | Basf Se | Pyrazine compounds for the control of invertebrate pests |
EP4151631A1 (en) | 2021-09-20 | 2023-03-22 | Basf Se | Heterocyclic compounds for the control of invertebrate pests |
WO2023078915A1 (en) | 2021-11-03 | 2023-05-11 | Bayer Aktiengesellschaft | Bis(hetero)aryl thioether (thio)amides as fungicidal compounds |
WO2023092050A1 (en) | 2021-11-20 | 2023-05-25 | Bayer Cropscience Lp | Beneficial combinations with recombinant bacillus cells expressing a serine protease |
WO2023099445A1 (en) | 2021-11-30 | 2023-06-08 | Bayer Aktiengesellschaft | Bis(hetero)aryl thioether oxadiazines as fungicidal compounds |
EP4194453A1 (en) | 2021-12-08 | 2023-06-14 | Basf Se | Pyrazine compounds for the control of invertebrate pests |
EP4198033A1 (en) | 2021-12-14 | 2023-06-21 | Basf Se | Heterocyclic compounds for the control of invertebrate pests |
WO2023110656A1 (en) | 2021-12-15 | 2023-06-22 | Bayer Aktiengesellschaft | Spectroscopic solution for non-destructive quantification of one or more chemical substances in a matrix comprising coating and bulk material in a sample, such as coated seeds, using multivariate data analysis |
EP4198023A1 (en) | 2021-12-16 | 2023-06-21 | Basf Se | Pesticidally active thiosemicarbazone compounds |
EP4238971A1 (en) | 2022-03-02 | 2023-09-06 | Basf Se | Substituted isoxazoline derivatives |
WO2023203066A1 (en) | 2022-04-21 | 2023-10-26 | Basf Se | Synergistic action as nitrification inhibitors of dcd oligomers with alkoxypyrazole and its oligomers |
WO2023208447A1 (en) | 2022-04-25 | 2023-11-02 | Basf Se | An emulsifiable concentrate having a (substituted) benzaldehyde-based solvent system |
WO2024028243A1 (en) | 2022-08-02 | 2024-02-08 | Basf Se | Pyrazolo pesticidal compounds |
EP4342885A1 (en) | 2022-09-20 | 2024-03-27 | Basf Se | N-(3-(aminomethyl)-phenyl)-5-(4-phenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-amine derivatives and similar compounds as pesticides |
EP4389210A1 (en) | 2022-12-21 | 2024-06-26 | Basf Se | Heteroaryl compounds for the control of invertebrate pests |
CN117567417A (zh) * | 2023-11-17 | 2024-02-20 | 山东绿霸化工股份有限公司 | 一组苯甲酰胺类化合物制备与应用 |
CN117567417B (zh) * | 2023-11-17 | 2024-09-20 | 山东绿霸化工股份有限公司 | 一组苯甲酰胺类化合物制备与应用 |
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