WO2008133189A1 - 油脂からの脂肪酸アルキルエステル及び／又はグリセリンの製造方法 - Google Patents

油脂からの脂肪酸アルキルエステル及び／又はグリセリンの製造方法 Download PDF

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Publication number
WO2008133189A1
WO2008133189A1 PCT/JP2008/057543 JP2008057543W WO2008133189A1 WO 2008133189 A1 WO2008133189 A1 WO 2008133189A1 JP 2008057543 W JP2008057543 W JP 2008057543W WO 2008133189 A1 WO2008133189 A1 WO 2008133189A1
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WO
WIPO (PCT)
Prior art keywords
catalyst
fat
oil
glycerol
fatty acid
Prior art date
Application number
PCT/JP2008/057543
Other languages
English (en)
French (fr)
Inventor
Takeo Akatsuka
Masanori Nonoguchi
Tomoharu Oku
Original Assignee
Nippon Shokubai Co., Ltd.
Research Institute Of Innovative Technology For The Earth
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Shokubai Co., Ltd., Research Institute Of Innovative Technology For The Earth filed Critical Nippon Shokubai Co., Ltd.
Priority to JP2009511849A priority Critical patent/JPWO2008133189A1/ja
Publication of WO2008133189A1 publication Critical patent/WO2008133189A1/ja

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Fats And Perfumes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

油脂類とアルコールとを反応させて脂肪酸アルキルエステル及び／又はグリセリンを製造する際に、触媒を繰り返し用いても活性金属成分の溶出が起こらず、水の存在下でも優れた触媒活性を長時間維持でき、油脂中に含まれるグリセリド類のエステル交換と遊離脂肪酸のエステル化の両反応に高活性を発揮でき、油脂中に含まれる遊離脂肪酸（ＦＦＡ）等の不純物の存在下でも高い触媒活性を発揮することができる触媒を用いて、触媒の回収工程等の煩雑な工程を簡略化又は不要とし、高効率に食用や燃料等の用途に好適な脂肪酸アルキルエステル及び／又はグリセリンを製造する方法及びその触媒を提供することを目的とする。 油脂類とアルコールとを触媒の存在下に接触させる工程を含んでなる脂肪酸アルキルエステル及び／又はグリセリンの製造方法であって、該触媒は、マンガン化合物並びに４価の金属元素及び／又は４価の半金属元素の化合物を有する脂肪酸アルキルエステル及び／又はグリセリンの製造方法。
PCT/JP2008/057543 2007-04-19 2008-04-17 油脂からの脂肪酸アルキルエステル及び／又はグリセリンの製造方法 WO2008133189A1 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009511849A JPWO2008133189A1 (ja) 2007-04-19 2008-04-17 油脂からの脂肪酸アルキルエステル及び／又はグリセリンの製造方法

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007-110851 2007-04-19
JP2007110851 2007-04-19
JP2007-234773 2007-09-10
JP2007234773 2007-09-10

Publications (1)

Publication Number Publication Date
WO2008133189A1 true WO2008133189A1 (ja) 2008-11-06

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PCT/JP2008/057543 WO2008133189A1 (ja) 2007-04-19 2008-04-17 油脂からの脂肪酸アルキルエステル及び／又はグリセリンの製造方法

Country Status (2)

Country Link
JP (1) JPWO2008133189A1 (ja)
WO (1) WO2008133189A1 (ja)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009066539A1 (en) * 2007-11-22 2009-05-28 Nippon Shokubai Co., Ltd. Method for producing fatty acid alkyl esters and/or glycerin using fat or oil
JP7057552B1 (ja) 2020-10-20 2022-04-20 華北理工大学 触媒及びこの触媒を使用してバイオディ－ゼルを製造する方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08126843A (ja) * 1994-10-28 1996-05-21 Japan Energy Corp 固体酸触媒の製造方法
JP2002294277A (ja) * 2001-03-30 2002-10-09 Rebo International:Kk 低級アルキルエステルの製造方法
JP2006225352A (ja) * 2005-02-21 2006-08-31 Nippon Shokubai Co Ltd 脂肪酸アルキルエステル及び／若しくはグリセリンの製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08126843A (ja) * 1994-10-28 1996-05-21 Japan Energy Corp 固体酸触媒の製造方法
JP2002294277A (ja) * 2001-03-30 2002-10-09 Rebo International:Kk 低級アルキルエステルの製造方法
JP2006225352A (ja) * 2005-02-21 2006-08-31 Nippon Shokubai Co Ltd 脂肪酸アルキルエステル及び／若しくはグリセリンの製造方法

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009066539A1 (en) * 2007-11-22 2009-05-28 Nippon Shokubai Co., Ltd. Method for producing fatty acid alkyl esters and/or glycerin using fat or oil
JP2011504516A (ja) * 2007-11-22 2011-02-10 株式会社日本触媒 油脂からの脂肪酸アルキルエステル及び／又はグリセリンの製造方法
US8093416B2 (en) 2007-11-22 2012-01-10 Nippon Shokubai Co., Ltd. Method for producing fatty acid alkyl esters and/or glycerin using fat or oil
JP7057552B1 (ja) 2020-10-20 2022-04-20 華北理工大学 触媒及びこの触媒を使用してバイオディ－ゼルを製造する方法
JP2022067596A (ja) * 2020-10-20 2022-05-06 華北理工大学 触媒及びこの触媒を使用してバイオディ－ゼルを製造する方法

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Publication number Publication date
JPWO2008133189A1 (ja) 2010-07-22

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