WO2008123316A1 - 重合体組成物およびそれからなる成形品 - Google Patents

重合体組成物およびそれからなる成形品 Download PDF

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Publication number
WO2008123316A1
WO2008123316A1 PCT/JP2008/055758 JP2008055758W WO2008123316A1 WO 2008123316 A1 WO2008123316 A1 WO 2008123316A1 JP 2008055758 W JP2008055758 W JP 2008055758W WO 2008123316 A1 WO2008123316 A1 WO 2008123316A1
Authority
WO
WIPO (PCT)
Prior art keywords
moldings
block copolymer
polymer
polymer composition
mass
Prior art date
Application number
PCT/JP2008/055758
Other languages
English (en)
French (fr)
Inventor
Hiroshi Oshima
Toyoaki Kurihara
Akiko Ide
Kenichi Hamada
Original Assignee
Kuraray Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co., Ltd. filed Critical Kuraray Co., Ltd.
Priority to EP20080738946 priority Critical patent/EP2130869B1/en
Priority to US12/532,638 priority patent/US8129030B2/en
Priority to AT08738946T priority patent/ATE517150T1/de
Priority to KR1020097021949A priority patent/KR101136762B1/ko
Priority to CN2008800093738A priority patent/CN101641407B/zh
Priority to JP2008520665A priority patent/JPWO2008123316A1/ja
Publication of WO2008123316A1 publication Critical patent/WO2008123316A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/026—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising acrylic acid, methacrylic acid or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C08L67/03—Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/02—Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/02—Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners
    • B60R13/0256—Dashboard liners
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/04—External Ornamental or guard strips; Ornamental inscriptive devices thereon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]

Abstract

【課題】塗装性と耐油性を両立させ、薄肉成形性、柔軟性にも優れる重合体組成物、および該組成物を射出成形してなり複合成形体のグリップ、自動車内外装材等に適した成形品を提供する。 【解決手段】ポリブチレンテレフタレート系樹脂（Ａ）３３～６７質量％およびアクリル系ブロック共重合体（Ｂ）６７～３３質量％からなり；アクリル系ブロック共重合体（Ｂ）が、アクリル酸ブチル等のアクリル酸エステル単位からなる重合体ブロック（ｂ１）の両端に２個のメタクリル酸メチル等のメタクリル酸エステル単位からなる重合体ブロック（ｂ２）が結合し、重合体ブロック（ｂ２）の合計質量がアクリル系ブロック共重合体（Ｂ）に対し２０～３５質量％であり、重量平均分子量が５０，０００～１００，０００であり、秩序－無秩序転移温度が１８０～２３０°Cである；重合体組成物および成形品。
PCT/JP2008/055758 2007-03-26 2008-03-26 重合体組成物およびそれからなる成形品 WO2008123316A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP20080738946 EP2130869B1 (en) 2007-03-26 2008-03-26 Polymer composition and moldings thereof
US12/532,638 US8129030B2 (en) 2007-03-26 2008-03-26 Acrylic block copolymer composition and molded article thereof
AT08738946T ATE517150T1 (de) 2007-03-26 2008-03-26 Polymerzusammensetzung und daraus hergestellte formkörper
KR1020097021949A KR101136762B1 (ko) 2007-03-26 2008-03-26 중합체 조성물 및 그것으로 이루어지는 성형품
CN2008800093738A CN101641407B (zh) 2007-03-26 2008-03-26 聚合物组合物及由其制成的成型品
JP2008520665A JPWO2008123316A1 (ja) 2007-03-26 2008-03-26 重合体組成物およびそれからなる成形品

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007079195 2007-03-26
JP2007-079195 2007-03-26

Publications (1)

Publication Number Publication Date
WO2008123316A1 true WO2008123316A1 (ja) 2008-10-16

Family

ID=39830804

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/055758 WO2008123316A1 (ja) 2007-03-26 2008-03-26 重合体組成物およびそれからなる成形品

Country Status (7)

Country Link
US (1) US8129030B2 (ja)
EP (1) EP2130869B1 (ja)
JP (1) JPWO2008123316A1 (ja)
KR (1) KR101136762B1 (ja)
CN (1) CN101641407B (ja)
AT (1) ATE517150T1 (ja)
WO (1) WO2008123316A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012207155A (ja) * 2011-03-30 2012-10-25 Kuraray Co Ltd アクリル系ジブロック共重合体ペレット及びそれを含有する粘着剤組成物
JP2015189844A (ja) * 2014-03-28 2015-11-02 クラレプラスチックス株式会社 摺動性に優れた熱可塑性樹脂組成物
JP2019183033A (ja) * 2018-04-12 2019-10-24 東亞合成株式会社 ポリエステル樹脂組成物

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2862223T3 (es) * 2015-05-22 2021-10-07 Kuraray Co Copolímero acrílico de bloques, composición de resina y cuerpo moldeado que comprende el mismo, y miembro óptico
CN106854344A (zh) * 2016-11-24 2017-06-16 广东美塑塑料科技有限公司 低成本耐老化阻燃增强pbt组合物及其制备方法
CA3115601A1 (en) * 2018-10-10 2020-04-16 Kuraray Co., Ltd. Pellets including block copolymer and shaped articles obtained from such pellets

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0693060A (ja) 1992-09-09 1994-04-05 Mitsubishi Petrochem Co Ltd メタクリル系ブロック共重合体およびその製造方法
JPH0725859B2 (ja) 1989-07-10 1995-03-22 エルフ アトケム ソシエテ アノニム アクリル系三元共重合体と、その製造方法と、そのエラストマー製品製造への応用
JP2817879B2 (ja) 1988-01-28 1998-10-30 三菱化学株式会社 熱可塑性エラストマー組成物
JPH11335432A (ja) 1998-03-23 1999-12-07 Kuraray Co Ltd アクリル系ブロック共重合体の製造方法
JP2003277574A (ja) * 2002-03-27 2003-10-02 Kuraray Co Ltd アクリル系重合体組成物
WO2004041886A1 (ja) * 2002-11-06 2004-05-21 Kuraray Co., Ltd. 熱可塑性重合体粉末
JP2005264069A (ja) * 2004-03-19 2005-09-29 Kaneka Corp 熱可塑性エラストマー組成物の製造方法
JP2006225413A (ja) 2005-02-15 2006-08-31 Kuraray Co Ltd 熱可塑性樹脂組成物

Family Cites Families (7)

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Publication number Priority date Publication date Assignee Title
NZ222383A (en) * 1986-10-30 1990-08-28 Mitsui Petrochemical Ind Laminate and moulded article prepared therefrom
FR2655049B3 (fr) * 1989-11-27 1992-02-21 Norsolor Sa Polymeres comportant des motifs, derives de maleimides a resistance a la chaleur amelioree.
JP2729347B2 (ja) 1993-07-08 1998-03-18 第一工業製薬株式会社 トリス（トリブロモフェノキシ）−ｓ−トリアジンの製造方法
CA2265310C (en) * 1998-03-23 2007-12-18 Kuraray Co., Ltd. Preparation process of acrylic acid ester polymer
EP1398353B1 (en) * 2001-05-14 2010-10-13 Kaneka Corporation Thermoplastic resin composition
AU2003252749A1 (en) * 2002-08-02 2004-02-23 Kaneka Corporation Acrylic block copolymer and thermoplastic resin composition
DE602004018664D1 (de) * 2003-09-30 2009-02-05 Kaneka Corp Thermoplastische elastomerzusammensetzung

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2817879B2 (ja) 1988-01-28 1998-10-30 三菱化学株式会社 熱可塑性エラストマー組成物
JPH0725859B2 (ja) 1989-07-10 1995-03-22 エルフ アトケム ソシエテ アノニム アクリル系三元共重合体と、その製造方法と、そのエラストマー製品製造への応用
JPH0693060A (ja) 1992-09-09 1994-04-05 Mitsubishi Petrochem Co Ltd メタクリル系ブロック共重合体およびその製造方法
JPH11335432A (ja) 1998-03-23 1999-12-07 Kuraray Co Ltd アクリル系ブロック共重合体の製造方法
JP2003277574A (ja) * 2002-03-27 2003-10-02 Kuraray Co Ltd アクリル系重合体組成物
WO2004041886A1 (ja) * 2002-11-06 2004-05-21 Kuraray Co., Ltd. 熱可塑性重合体粉末
JP2005264069A (ja) * 2004-03-19 2005-09-29 Kaneka Corp 熱可塑性エラストマー組成物の製造方法
JP2006225413A (ja) 2005-02-15 2006-08-31 Kuraray Co Ltd 熱可塑性樹脂組成物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
MACROMOL. CHEM. PHYS., vol. 201, 2000, pages 1108 - 1114

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012207155A (ja) * 2011-03-30 2012-10-25 Kuraray Co Ltd アクリル系ジブロック共重合体ペレット及びそれを含有する粘着剤組成物
JP2015189844A (ja) * 2014-03-28 2015-11-02 クラレプラスチックス株式会社 摺動性に優れた熱可塑性樹脂組成物
JP2019183033A (ja) * 2018-04-12 2019-10-24 東亞合成株式会社 ポリエステル樹脂組成物

Also Published As

Publication number Publication date
EP2130869A4 (en) 2010-03-31
KR20090129484A (ko) 2009-12-16
KR101136762B1 (ko) 2012-04-20
ATE517150T1 (de) 2011-08-15
JPWO2008123316A1 (ja) 2010-07-15
CN101641407A (zh) 2010-02-03
US20100119797A1 (en) 2010-05-13
EP2130869A1 (en) 2009-12-09
US8129030B2 (en) 2012-03-06
EP2130869B1 (en) 2011-07-20
CN101641407B (zh) 2011-10-26

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