Classifications

• • A—HUMAN NECESSITIES
  • A62—LIFE-SAVING; FIRE-FIGHTING
  • A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
  • A62B7/00—Respiratory apparatus
• • A—HUMAN NECESSITIES
  • A41—WEARING APPAREL
  • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
  • A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
  • A41D13/05—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
  • A41D13/11—Protective face masks, e.g. for surgical use, or for use in foul atmospheres
  • A41D13/1107—Protective face masks, e.g. for surgical use, or for use in foul atmospheres characterised by their shape
  • A41D13/1138—Protective face masks, e.g. for surgical use, or for use in foul atmospheres characterised by their shape with a cup configuration
  • A41D13/1146—Protective face masks, e.g. for surgical use, or for use in foul atmospheres characterised by their shape with a cup configuration obtained by moulding
• • A—HUMAN NECESSITIES
  • A62—LIFE-SAVING; FIRE-FIGHTING
  • A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
  • A62B23/00—Filters for breathing-protection purposes
  • A62B23/02—Filters for breathing-protection purposes for respirators
  • A62B23/025—Filters for breathing-protection purposes for respirators the filter having substantially the shape of a mask
• • D—TEXTILES; PAPER
  • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
  • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
  • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
  • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
  • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
  • D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
• • D—TEXTILES; PAPER
  • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
  • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
  • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
  • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
  • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
• • D—TEXTILES; PAPER
  • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
  • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
  • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
  • D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
  • D04H3/14—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
• • D—TEXTILES; PAPER
  • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
  • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
  • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
  • D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
  • D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
  • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
  • Y10T428/1362—Textile, fabric, cloth, or pile containing [e.g., web, net, woven, knitted, mesh, nonwoven, matted, etc.]
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/249921—Web or sheet containing structurally defined element or component

Definitions

• This invention relates to molded (e.g., cup-shaped) personal respirators.
• Patents relating to molded personal respirators include U.S. Patent Nos. 4,536,440 (Berg), 4,547,420 (Krueger et al), 5,374,458 (Burgio) and 6,827,764 B2 (Springett et al.).
• Patents relating to breathing mask fabrics include U.S. Patent Nos. 5,817,584 (Singer et al.), 6,723,669 (Clark et al.) and 6,998,164 B2 (Neely et al.).
• Other patents or applications relating to nonwoven webs or their manufacture include U.S. Patent Nos.
• molded respirators may be formed from bilayer webs made by laminating a meltblown fiber filtration layer to a stiff shell material such as a meltspun layer or staple fiber layer. If used by itself, the filtration layer normally has insufficient rigidity to permit formation of an adequately strong cup-shaped finished molded respirator.
• the reinforcing shell material also adds undesirable basis weight and bulk, and limits the extent to which unused portions of the web laminate may be recycled.
• Molded respirators may also be formed from monolayer webs made from bicomponent fibers in which one fiber component can be charged to provide a filtration capability and the other fiber component can be bonded to itself to provide a reinforcing capability.
• the bonding fiber component adds undesirable basis weight and bulk and limits the extent to which unused portions of the bicomponent fiber web may be recycled.
• the bonding fiber component also limits the extent to which charge may be placed on the bicomponent fiber web.
• Molded respirators may also be formed by adding an extraneous bonding material (e.g., an adhesive) to a filtration web, with consequent limitations due to the chemical or physical nature of the added bonding material including added web basis weight and loss of recyclability.
• an extraneous bonding material e.g., an adhesive
• the invention provides in one aspect a process for making a molded respirator comprising: a) forming a monocomponent monolayer nonwoven web containing a bimodal mass fraction/fiber size mixture of intermingled continuous monocomponent polymeric micro fibers and larger size fibers of the same polymeric composition, b) charging the web, and c) molding the charged web to form a cup-shaped porous monocomponent monolayer matrix, the matrix fibers being bonded to one another at at least some points of fiber intersection and the matrix having a King Stiffness greater than 1 N.
• the invention provides in another aspect a molded respirator comprising a cup- shaped porous monocomponent monolayer matrix containing a charged bimodal mass fraction/fiber size mixture of intermingled continuous monocomponent polymeric micro fibers and larger size fibers of the same polymeric composition, the fibers being bonded to one another at at least some points of fiber intersection and the matrix having a King Stiffness greater than 1 N.
• the disclosed cup-shaped matrix has a number of beneficial and unique properties.
• a finished molded respirator may be prepared consisting only of a single layer, but comprising a mixture of micro fibers and larger size fibers. Both the microfibers and larger size fibers may be highly charged.
• the larger size fibers can impart improved moldability and improved stiffness to the molded matrix.
• the microfibers can impart increased fiber surface area to the web, with beneficial effects such as improved filtration performance.
• filtration and molding properties can be tailored to a particular use.
• pressure drops of the disclosed nonwoven webs are kept lower, because the larger fibers physically separate and space apart the microfibers.
• the microfibers and larger size fibers also appear to cooperate with one another to provide a higher particle depth loading capacity. Product complexity and waste are reduced by eliminating laminating processes and equipment and by reducing the number of intermediate materials.
• FIG. 1 is a perspective view, partially in section, of a disposable personal respirator having a deformation-resistant cup-shaped porous monolayer matrix disposed between inner and outer cover layers;
• Fig. 2 through Fig. 4 are schematic side views and
• Fig. 5 is a schematic perspective view, partially in section, of an exemplary process for making a monocomponent monolayer web using meltspinning and separately prepared smaller size fibers of the same polymeric composition;
• Fig. 6 is a schematic side view of an exemplary process for making a monocomponent monolayer web using meltb lowing of larger fibers and separately prepared smaller size fibers of the same polymeric composition;
• Fig. 7 is an outlet end view of an exemplary meltspinning die spinneret having a plurality of larger and smaller orifices
• Fig. 8 is an outlet end perspective view of an exemplary meltblowing die having a plurality of larger and smaller orifices
• Fig. 9 is an exploded schematic view of an exemplary meltspinning die having a plurality of orifices supplied with polymers of the same polymeric composition flowing at different rates or with different viscosities;
• Fig. 10 is a cross-sectional view and
• Fig. 11 is an outlet end view of an exemplary meltblowing die having a plurality of orifices supplied with polymers of the same polymeric composition flowing at different rates or with different viscosities;
• Fig. 12 is a graph showing % NaCl penetration and pressure drop for the molded matrices of Run Nos. 2-1M and 2-4M;
• Fig. 13 and Fig. 14 are photomicrographs of the Run No. 6-8F flat web and the
• Fig. 15 and Fig. 16 are histograms of fiber count (frequency) vs. fiber size in ⁇ m for the Run No. 6-8F flat web and the Run No. 6-8M molded matrix;
• Fig. 17 is a graph showing % NaCl penetration and pressure drop for the molded matrix of Run No. 7-1M;
• Fig. 18, Fig. 19 and Fig. 21 are histograms of mass fraction vs. fiber size in ⁇ m
• Fig. 20 and Fig. 22 are histograms of fiber count (frequency) vs. fiber size in ⁇ m, for a series of webs of Example 10;
• Fig. 23 is a plot of Deformation Resistance DR values vs. basis weight for several webs of Example 10;
• Fig. 24 is a graph showing % NaCl penetration and pressure drop for the molded respirator of Run No. 13- IM and
• Fig. 25 is a similar graph for a commercial N95 respirator made from multilayer filtration media;
• Fig. 26 and Fig. 27 respectively are a photomicrograph of and a histogram of fiber count (frequency) vs. fiber size in ⁇ m for the Run No. 13-1M molded matrix.
• molded respirator means a device that has been molded to a shape that fits over at least the nose and mouth of a person and that removes one or more airborne contaminants when worn by a person.
• cup-shaped when used with respect to a respirator mask body means having a configuration that allows the mask body to be spaced from a wearer's face when worn.
• porous means air-permeable.
• the term "monocomponent" when used with respect to a fiber or collection of fibers means fibers having essentially the same composition across their cross-section; monocomponent includes blends (viz., polymer alloys) or additive-containing materials, in which a continuous phase of uniform composition extends across the cross-section and over the length of the fiber.
• the term "of the same polymeric composition” means polymers that have essentially the same repeating molecular unit, but which may differ in molecular weight, melt index, method of manufacture, commercial form, etc.
• size when used with respect to a fiber means the fiber diameter for a fiber having a circular cross section, or the length of the longest cross-sectional chord that may be constructed across a fiber having a non-circular cross-section.
• continuous when used with respect to a fiber or collection of fibers means fibers having an essentially infinite aspect ratio (viz., a ratio of length to size of e.g., at least about 10,000 or more).
• Effective Fiber Diameter when used with respect to a collection of fibers means the value determined according to the method set forth in Davies, C. N., "The Separation of Airborne Dust and Particles", Institution of Mechanical Engineers, London, Proceedings IB, 1952 for a web of fibers of any cross-sectional shape be it circular or non- circular.
• mode when used with respect to a histogram of mass fraction vs. fiber size in ⁇ m or a histogram of fiber count (frequency) vs. fiber size in ⁇ m means a local peak whose height is larger than that for fiber sizes 1 and 2 ⁇ m smaller and 1 and 2 ⁇ m larger than the local peak.
• bimodal mass fraction/fiber size mixture means a collection of fibers having a histogram of mass fraction vs. fiber size in ⁇ m exhibiting at least two modes.
• a bimodal mass fraction/fiber size mixture may include more than two modes, for example it may be a trimodal or higher-modal mass fraction/fiber size mixture.
• the term "bimodal fiber count/fiber size mixture” means a collection of fibers having a histogram of fiber count (frequency) vs. fiber size in ⁇ m exhibiting at least two modes whose corresponding fiber sizes differ by at least 50% of the smaller fiber size.
• a bimodal fiber count/fiber size mixture may include more than two modes, for example it may be a trimodal or higher-modal fiber count/fiber size mixture.
• nonwoven web means a fibrous web characterized by entanglement or point bonding of the fibers.
• the term "monolayer matrix" when used with respect to a nonwoven web containing a bimodal mass fraction/fiber size mixture of fibers means having (other than with respect to fiber size) a generally uniform distribution of similar fibers throughout a cross-section of the web, and having (with respect to fiber size) fibers representing each modal population present throughout a cross-section of the web.
• Such a monolayer matrix may have a generally uniform distribution of fiber sizes throughout a cross-section of the web or may, for example, have a depth gradient of fiber sizes such as a preponderance of larger size fibers proximate one major face of the web and a preponderance of smaller size fibers proximate the other major face of the web.
• the term "attenuating the filaments into fibers” means the conversion of a segment of a filament into a segment of greater length and smaller size.
• the term “meltspun” when used with respect to a nonwoven web means a web formed by extruding a low viscosity melt through a plurality of orifices to form filaments, quenching the filaments with air or other fluid to solidify at least the surfaces of the filaments, contacting the at least partially solidified filaments with air or other fluid to attenuate the filaments into fibers and collecting a layer of the attenuated fibers.
• meltspun fibers means fibers issuing from a die and traveling through a processing station in which the fibers are permanently drawn and polymer molecules within the fibers are permanently oriented into alignment with the longitudinal axis of the fibers. Such fibers are essentially continuous and are entangled sufficiently that it is usually not possible to remove one complete meltspun fiber from a mass of such fibers.
• orientation when used with respect to a polymeric fiber or collection of such fibers means that at least portions of the polymeric molecules of the fibers are aligned lengthwise of the fibers as a result of passage of the fibers through equipment such as an attenuation chamber or mechanical drawing machine.
• the presence of orientation in fibers can be detected by various means including birefringence measurements and wide- angle x-ray diffraction.
• Nominal Melting Point means the peak maximum of a second-heat, total-heat- flow differential scanning calorimetry (DSC) plot in the melting region of a polymer if there is only one maximum in that region; and, if there is more than one maximum indicating more than one melting point (e.g., because of the presence of two distinct crystalline phases), as the temperature at which the highest-amplitude melting peak occurs.
• DSC differential scanning calorimetry
• meltblown when used with respect to a nonwoven web means a web formed by extruding a fiber-forming material through a plurality of orifices to form filaments while contacting the filaments with air or other attenuating fluid to attenuate the filaments into fibers and thereafter collecting a layer of the attenuated fibers.
• meltblown fibers means fibers prepared by extruding molten fiber- forming material through orifices in a die into a high-velocity gaseous stream, where the extruded material is first attenuated and then solidifies as a mass of fibers.
• microfibers means fibers having a median size (as determined using microscopy) of 10 ⁇ m or less; "ultrafine microfibers” means microfibers having a median size of two ⁇ m or less; and "submicron microfibers” means microfibers having a median size one ⁇ m or less.
• an array of submicron microfibers it means the complete population of microfibers in that array, or the complete population of a single batch of microfibers, and not only that portion of the array or batch that is of submicron dimensions.
• the term "separately prepared smaller size fibers” means a stream of smaller size fibers produced from a fiber- forming apparatus (e.g., a die) positioned such that the stream is initially spatially separate (e.g., over a distance of about 1 inch (25 mm) or more from, but will merge in flight and disperse into, a stream of larger size fibers.
• a fiber- forming apparatus e.g., a die
• the term "charged" when used with respect to a collection of fibers means fibers that exhibit at least a 50% loss in Quality Factor QF (discussed below) after being exposed to a 20 Gray absorbed dose of 1 mm beryllium-filtered 80 KVp X-rays when evaluated for percent dioctyl phthalate ( % DOP) penetration at a face velocity of 7 cm/sec.
• the term "self-supporting" when used with respect to a monolayer matrix means that the matrix does not include a contiguous reinforcing layer of wire, plastic mesh, or other stiffening material even if a molded respirator containing such matrix may include an inner or outer cover web to provide an appropriately smooth exposed surface or may include weld lines, folds or other lines of demarcation to strengthen selected portions of the respirator.
• King Stiffness means the force required using a King Stiffness Tester from J. A. King & Co., Greensboro, North Carolina to push a flat-faced, 2.54 cm diameter by 8.1 m long probe against a molded cup-shaped respirator prepared by forming a test cup-shaped matrix between mating male and female halves of a hemispherical mold having a 55mm radius and a 310 cm ⁇ volume. The molded matrices are placed under the tester probe for evaluation after first being allowed to cool.
• a cup-shaped disposable personal respirator 1 is shown in partial cross-section. Respirator 1 includes inner cover web 2, monocomponent filtration layer 3, and outer cover layer 4.
• Welded edge 5 holds these layers together and provides a face seal region to reduce leakage past the edge of respirator 1. Leakage may be further reduced by pliable dead-soft nose band 6 of for example a metal such as aluminum or a plastic such as polypropylene Respirator 1 also includes adjustable head and neck straps 7 fastened using tabs 8, and exhalation valve 9. Aside from the monocomponent filtration layer 2, further details regarding the construction of respirator 1 will be familiar to those skilled in the art. [0052]
• the disclosed monocomponent monolayer web contains a bimodal mass fraction/fiber size mixture of micro fibers and larger size fibers.
• the micro fibers may for example have a size range of about 0.1 to about 10 ⁇ m, about 0.1 to about 5 ⁇ m or about 0.1 to about 1 ⁇ m.
• the larger size fibers may for example have a size range of about 10 to about 70 ⁇ m, about 10 to about 50 ⁇ m or about 15 to about 50 ⁇ m.
• a histogram of mass fraction vs. fiber size in ⁇ m may for example have a micro fiber mode of about 0.1 to about 10 ⁇ m, about 0.5 to about 8 ⁇ m or about 1 to about 5 ⁇ m, and a larger size fiber mode of more than 10 ⁇ m, about 10 to about 50 ⁇ m, about 10 to about 40 ⁇ m or about 12 to about 30 ⁇ m.
• the disclosed web may also have a bimodal fiber count/fiber size mixture whose histogram of fiber count (frequency) vs. fiber size in ⁇ m exhibits at least two modes whose corresponding fiber sizes differ by at least 50%, at least 100%, or at least 200% of the smaller fiber size.
• the micro fibers may also for example provide at least 20% of the fibrous surface area of the web, at least 40% or at least 60%.
• the web may have a variety of Effective Fiber Diameter (EFD) values, for example an EFD of about 5 to about 40 ⁇ m, or of about 6 to about 35 ⁇ m.
• the web may also have a variety of basis weights, for example a basis weight of about 60 to about 300 grams/m ⁇ or about 80 to about 250 grams/m ⁇ .
• the web When flat (viz., unmolded), the web may have a variety of Gurley Stiffness values, for example a Gurley Stiffness of at least about 500 mg, at least about 1000 mg or at least about 2000 mg.
• the flat web When evaluated at a 13.8 cm/sec face velocity and using an NaCl challenge, the flat web preferably has an initial filtration quality factor QF of at least about 0.4 mm'l H2O and more preferably at least about 0.5 mm'l H2O.
• the molded matrix has a King Stiffness greater than 1 N and more preferably at least about 2 N or more.
• a hemispherical molded matrix sample is allowed to cool, placed cup-side down on a rigid surface, depressed vertically (viz., dented) using an index finger and then the pressure released, a matrix with insufficient King Stiffness may tend to remain dented and a matrix with adequate King Stiffness may tend to spring back to its original hemispherical configuration.
• Deformation Resistance DR
• Model TA-XT2i/5 Texture Analyzer from Texture Technologies Corp.
• 25.4 mm diameter polycarbonate test probe The molded matrix is placed facial side down on the Texture Analyzer stage.
• Deformation Resistance DR is measured by advancing the polycarbonate probe downward at 10 mm/sec against the center of the molded test matrix over a distance of 25 mm.
• the maximum (peak) force is recorded and averaged to establish Deformation Resistance DR.
• Deformation Resistance DR preferably is at least about 75 g and more preferably at least about 200 g.
• the disclosed molded respirator When exposed to a 0.075 ⁇ m sodium chloride aerosol flowing at 85 liters/min, the disclosed molded respirator preferably has a pressure drop less than 20 mm H2O and more preferably less than 10 mm H2O. When so evaluated, the molded respirator also preferably has a % NaCl penetration less than about 5%, and more preferably less than about 1%.
• Fig. 2 through Fig. 9 illustrate a variety of processes and equipment which may be used to make preferred monocomponent monolayer webs.
• the process shown in Fig. 2 through Fig. 5 combines larger size meltspun fibers from a meltspinning die and smaller size meltblown fibers from a meltb lowing die.
• the process shown in Fig. 6 combines larger size and smaller size meltblown fibers from two meltblowing dies.
• the die shown in Fig. 7 produces larger size and smaller size meltspun fibers from a single meltspinning die which may be supplied with liquefied fiber- forming material from a single extruder.
• the die shown in Fig. 8 produces larger size and smaller size meltblown fibers from a single meltblowing die which may be supplied with liquefied fiber-forming material from a single extruder.
• the die shown in Fig. 9 produces larger size and smaller size meltspun fibers from a single meltspinning die which may be supplied with liquefied fiber-forming material from two extruders.
• the die shown in Fig. 10 and Fig. 11 produces larger size and smaller size meltblown fibers from a single meltblowing die which may be supplied with liquefied fiber- forming material from two extruders.
• a process is shown in schematic side view for making a moldable monocomponent monolayer bimodal mass fraction/fiber size web using meltspinning to form larger size fibers and meltblowing to form separately prepared smaller size fibers (e.g., microfibers) of the same polymeric composition. Further details regarding this process and the nonwoven webs so made are shown in U.S. Patent Application Serial No. (Attorney Docket No. 60928US002), filed even date herewith and entitled "FIBROUS WEB COMPRISING MICROFIBERS DISPERSED AMONG
• a fiber-forming material is brought to a melt- spinning extrusion head 10 — in this illustrative apparatus, by introducing a polymeric fiber-forming material into a hopper 11, melting the material in an extruder 12, and pumping the molten material into the extrusion head 10 through a pump 13. Solid polymeric material in pellet or other particulate form is most commonly used and melted to a liquid, pumpable state.
• the extrusion head 10 may be a conventional spinnerette or spin pack, generally including multiple orifices arranged in a regular pattern, e.g., straight-line rows. Filaments 15 of fiber- forming liquid are extruded from extrusion head 10 and conveyed to a processing chamber or attenuator 16.
• the attenuator may for example be a movable- wall attenuator like that shown in U.S. Patent No. 6,607,624 B2 (Berrigan et al.) whose walls are mounted for free and easy movement in the direction of the arrows 50.
• the distance 17 the extruded filaments 15 travel before reaching the attenuator 16 can vary, as can the conditions to which they are exposed.
• Quenching streams of air or other gas 18 may be presented to the extruded filaments to reduce the temperature of the extruded filaments 15.
• the streams of air or other gas may be heated to facilitate drawing of the fibers.
• There may be one or more streams of air or other fluid e.g., a first air stream 18a blown transversely to the filament stream, which may remove undesired gaseous materials or fumes released during extrusion; and a second quenching air stream 18b that achieves a major desired temperature reduction.
• Even more quenching streams may be used; for example, the stream 18b could itself include more than one stream to achieve a desired level of quenching.
• the quenching air may be sufficient to solidify the extruded filaments 15 before they reach the attenuator 16. In other cases the extruded filaments are still in a softened or molten condition when they enter the attenuator. Alternatively, no quenching streams are used; in such a case ambient air or other fluid between the extrusion head 10 and the attenuator 16 may be a medium for any change in the extruded filaments before they enter the attenuator.
• the continuous meltspun filaments 15 are oriented in attenuator 16 which are directed toward collector 19 as a stream 501 of larger size fibers (that is, larger in relation to the smaller size meltspun fibers that will be added to the web; the fibers in attenuated stream 501 are smaller in size than the filaments extruded from extrusion head 10).
• the attenuated larger size fiber stream 501 is intercepted by a stream 502 of meltblown smaller size fibers emanating from meltblowing die 504 to form a merged bimodal mass fraction/fiber size stream 503 of larger and smaller size fibers.
• the merged stream becomes deposited on collector 19 as a self-supporting web 20 containing oriented continuous meltspun larger size fibers with meltblown smaller size fibers dispersed therein.
• the collector 19 is generally porous and a gas-withdrawal device 114 can be positioned below the collector to assist deposition of fibers onto the collector.
• the distance 21 between the attenuator exit and the collector may be varied to obtain different effects.
• the extruded filaments or fibers may be subjected to a number of additional processing steps not illustrated in Fig. 2, e.g., further drawing, spraying, etc.
• the collected mass 20 may be heated and quenched as described in more detail below; conveyed to other apparatus such as calenders, embossing stations, laminators, cutters and the like; or it may merely be wound without further treatment or converting into a storage roll 23.
• the meltblowing die 504 can be of known structure and operated in known ways to produce meltblown smaller size fibers (e.g., micro fibers) for use in the disclosed process.
• meltblown smaller size fibers e.g., micro fibers
• An early description of the basic meltblowing method and apparatus is found in Wente, Van A. "Superfine Thermoplastic Fibers," in Industrial Engineering Chemistry, Vol. 48, pages 1342 et seq. (1956), or in Report No. 4364 of the Naval Research
• the typical meltblowing apparatus includes a hopper 506 and extruder 508 supplying liquefied fiber-forming material to die 504.
• die 504 includes an inlet 512 and die cavity 514 through which liquefied fiber-forming material is delivered to die orifices 516 arranged in line across the forward end of the die and through which the fiber- forming material is extruded; and cooperating gas orifices 518 through which a gas, typically heated air, is forced at very high velocity.
• the high-velocity gaseous stream draws out and attenuates the extruded fiber-forming material, whereupon the fiber- forming material solidifies (to varying degrees of solidity) and forms a stream 502 of meltblown smaller size fibers during travel to its point of merger with the meltspun larger size fiber stream 501.
• Methods for meltb lowing fibers of very small size including submicron sizes are known; see, for example, U.S. Patent No. 5,993,943 (Bodaghi et al), e.g., at column 8, line 11 through column 9, line 25.
• Other techniques to form smaller size fibers can also be used, for example, as described in U.S. Patent Nos.
• the meltblowing die 504 is preferably positioned near the stream 501 of meltspun larger size fibers to best achieve capture of the meltblown smaller size fibers by the meltspun larger size fibers; close placement of the meltblowing die to the meltspun stream is especially important for capture of submicron microf ⁇ bers.
• the distance 520 from the exit of the die 504 to the centerline of the meltspun stream 501 is preferably about 2 to 12 in. (5 to 25 cm) and more preferably about 6 or 8 in. (15 or 20 cm) or less for very small microfibers.
• the stream 502 of meltblown smaller size fibers is preferably disposed at an acute angle ⁇ with respect to the horizontal, so that a vector of the meltblown stream 502 is directionally aligned with the meltspun stream 501.
• ⁇ is between about 0 and about 45 degrees and more preferably between about 10 and about 30 degrees.
• the distance 522 from the point of joinder of the meltblown and meltspun streams to the collector 19 is typically at least about 4 in. (10 cm) but less than about 16 in. (40 cm) to avoid over-entangling and to retain web uniformity.
• the distance 524 is sufficient, generally at least 6 in.
• meltblown stream 502 (15 cm), for the momentum of the meltspun stream 501 to be reduced and thereby allow the meltblown stream 502 to better merge with the meltspun stream 501.
• the meltblown fibers become dispersed among the meltspun fibers.
• a rather uniform mixture is obtained, especially in the x-y (in-plane web) dimensions, with the distribution in the z dimension being controlled by particular process steps such as control of the distance 520, the angle ⁇ , and the mass and velocity of the merging streams.
• the merged stream 503 continues to the collector 19 and there is collected as the web-like mass 20.
• meltspun and meltblown fibers Depending on the condition of the meltspun and meltblown fibers, some bonding may occur between the fibers during collection. However, further bonding between the meltspun fibers in the collected web may be needed to provide a matrix having a desired degree of coherency and stiffness, making the web more handleable and better able to hold the meltblown fibers within the matrix. However, excessive bonding should be avoided so as to facilitate forming the web into a molded matrix.
• Conventional bonding techniques using heat and pressure applied in a point- bonding process or by smooth calender rolls can be used, though such processes may cause undesired deformation of fibers or compaction of the web. A more preferred technique for bonding the meltspun fibers is taught in U.S. Patent Application Serial No.
• this preferred technique involves subjecting a collected web of oriented semicrystalline meltspun fibers which include an amorphous-characterized phase, intermingled with meltblown fibers of the same polymeric composition, to a controlled heating and quenching operation that includes a) forcefully passing through the web a fluid heated to a temperature high enough to soften the amorphous-characterized phase of the meltspun fibers (which is generally greater than the onset melting temperature of the material of such fibers) for a time too short to melt the whole meltspun fibers (viz., causing such fibers to lose their discrete fibrous nature; preferably, the time of heating is too short to cause a significant distortion of the fiber cross-section), and b) immediately quenching the web by forcefully passing through the web a fluid having sufficient heat capacity to solidify the softened fibers (viz., to solidify the amorphous-characterized phase of the fibers softened during heat treatment).
• the fluids passed through the web are gaseous streams, and preferably they are air.
• passing a fluid or gaseous stream through a web means that a force in addition to normal room pressure is applied to the fluid to propel the fluid through the web.
• the disclosed quenching step includes passing the web on a conveyor through a device we term a quenched flow heater, or, more simply, quenched heater.
• such a quenched flow heater provides a focused or knife-like heated gaseous (typically air) stream issuing from the heater under pressure and engaging one side of the web, with a gas-withdrawal device on the other side of the web to assist in drawing the heated gas through the web; generally the heated stream extends across the width of the web.
• the heated stream is much like the heated stream from a conventional "through-air bonder" or “hot-air knife,” but it is subjected to special controls that modulate the flow, causing the heated gas to be distributed uniformly and at a controlled rate through the width of the web to thoroughly, uniformly and rapidly heat and soften the meltspun fibers to a usefully high temperature.
• the gas-withdrawal device is positioned downweb from the heated gaseous stream so as to draw a cooling gas or other fluid, e.g., ambient air, through the web promptly after it has been heated and thereby rapidly quench the fibers.
• a cooling gas or other fluid e.g., ambient air
• the length of heating is controlled, e.g., by the length of the heating region along the path of web travel and by the speed at which the web is moved through the heating region to the cooling region, to cause the intended melting/softening of the amorphous-characterizing phase without melting whole meltspun fiber.
• the mass 20 of collected meltspun and meltblown fibers is carried by the moving collector 19 under a controlled-heating device 200 mounted above the collector 19.
• the exemplary heating device 200 comprises a housing 201 which is divided into an upper plenum 202 and a lower plenum 203.
• the upper and lower plenums are separated by a plate 204 perforated with a series of holes 205 that are typically uniform in size and spacing.
• a gas typically air
• the plate 204 functions as a flow-distribution means to cause air fed into the upper plenum to be rather uniformly distributed when passed through the plate into the lower plenum 203.
• Other useful flow- distribution means include fins, baffles, manifolds, air dams, screens or sintered plates, vzz., devices that even the distribution of air.
• the gas-withdrawal device 114 preferably extends sufficiently to lie under the slot 209 of the heating device 200 (as well as extending downweb a distance 218 beyond the heated stream 210 and through an area marked 220, as will be discussed below). Heated air in the plenum is thus under an internal pressure within the plenum 203, and at the slot 209 it is further under the exhaust vacuum of the gas-withdrawal device 114.
• a perforated plate 211 may be positioned under the collector 19 to impose a kind of back pressure or flow-restriction means which assures the stream 210 of heated air will spread to a desired extent over the width or heated area of the collected mass 20 and be inhibited in streaming through possible lower-density portions of the collected mass.
• Other useful flow-restriction means include screens or sintered plates.
• the number, size and density of openings in the plate 211 may be varied in different areas to achieve desired control. Large amounts of air pass through the fiber- forming apparatus and must be disposed of as the fibers reach the collector in the region 215. Sufficient air passes through the web and collector in the region 216 to hold the web in place under the various streams of processing air.
• the heating apparatus is operated to maintain a steady temperature in the stream over time, e.g., by rapidly cycling the heater on and off to avoid over- or under-heating.
• the mass 20 is subjected to quenching quickly after the application of the stream 210 of heated air.
• quenching can generally be obtained by drawing ambient air over and through the mass 20 immediately after the mass leaves the controlled hot air stream 210.
• Numeral 220 in Fig. 4 represents an area in which ambient air is drawn through the web by the gas-withdrawal device 114 after the web has passed through the hot air stream. Actually, such air can be drawn under the base of the housing 201, e.g., in the area 220a marked on Fig.
• the gas- withdrawal device 114 may extend along the collector 19 for a distance 218 beyond the heating device 200 to assure thorough cooling and quenching of the whole mass 20.
• the combined heating and quenching apparatus is termed a quenched flow heater.
• the amount and temperature are chosen so that the larger size fibers are heated to a) cause melting/softening of significant molecular portions within a cross- section of the fiber, e.g., the amorphous-characterized phase of the fiber, but b) will not cause complete melting of another significant phase, e.g., the crystallite-characterized phase.
• melting/softening because amorphous polymeric material typically softens rather than melts, while crystalline material, which may be present to some degree in the amorphous-characterized phase, typically melts. This can also be stated, without reference to phases, simply as heating to cause melting of lower-order crystallites within the fiber.
• the larger size fibers as a whole remain unmelted, e.g., the fibers generally retain the same fiber shape and dimensions as they had before treatment.
• Substantial portions of the crystallite-characterized phase are understood to retain their pre-existing crystal structure after the heat treatment.
• Crystal structure may have been added to the existing crystal structure, or in the case of highly ordered fibers crystal structure may have been removed to create distinguishable amorphous-characterized and crystallite-characterized phases.
• One aim of the quenching is to withdraw heat before undesired changes occur in the smaller size fibers contained in the web.
• Another aim of the quenching is to rapidly remove heat from the web and the larger size fibers and thereby limit the extent and nature of crystallization or molecular ordering that will subsequently occur in the larger size fibers.
• the mass 20 is cooled by a gas at a temperature at least 5O 0 C less than the Nominal Melting Point or the larger size fibers; also the quenching gas is desirably applied for a time on the order of at least one second. In any event the quenching gas or other fluid has sufficient heat capacity to rapidly solidify the fibers.
• An advantage of the disclosed quenched flow heater is that the smaller size meltblown fibers held within the disclosed web are better protected against compaction than they would be if present in a layer made up entirely of smaller size fibers (e.g., entirely of micro fibers).
• the oriented meltspun fibers are generally larger, stiffer and stronger than the meltblown smaller size fibers, and the presence of the meltspun fibers between the meltblown fibers and an object applying pressure limits application of crushing force on the smaller size meltblown fibers.
• the increased resistance against compaction or crushing provided by the larger size fibers offers an important benefit.
• meltblown smaller size fibers do not substantially melt or lose their fiber structure during the bonding operation, but remain as discrete smaller size fibers with their original fiber dimensions.
• meltblown fibers have a different, less crystalline morphology than meltspun fibers, and we theorize that the limited heat applied to the web during the bonding and quenching operation is exhausted in developing crystalline growth within the meltblown fibers before melting of the meltblown fibers occurs. Whether this theory is correct or not, bonding of the meltspun fibers without substantial melting or distortion of the meltblown smaller size fibers does occur and is beneficial to the properties of the finished bimodal mass fraction/fiber size web.
• Fig. 6 another process is shown in schematic side view for making a moldable monocomponent monolayer bimodal mass fraction/fiber size web using meltblowing to form both larger size fibers and separately prepared smaller size fibers of the same polymeric composition.
• the Fig. 6 another process is shown in schematic side view for making a moldable monocomponent monolayer bimodal mass fraction/fiber size web using meltblowing to form both larger size fibers and separately prepared smaller size fibers of the same polymeric composition.
• Die 600 is supplied with liquefied fiber- forming material fed from hopper 604, extruder 606 and conduit 608.
• Die 602 may also be supplied with liquefied fiber-forming material from extruder 606 via optional conduit 610.
• die 602 may be separately supplied with liquefied fiber- forming material of the same polymeric composition fed from optional hopper 612, extruder 614 and conduit 616.
• the apparatus shown in Fig. 6 may be operated in several modes to provide a stream of larger size fibers from one die and smaller size fibers from the other die.
• the same polymer may be supplied from a single extruder to die 600 and die 602 with larger size orifices being provided in die 600 and smaller size orifices being provided in die 602 so as to enable production of larger size fibers at die 600 and smaller size fibers at die 602.
• Identical polymers may be supplied from extruder 606 to die 600 and from extruder 614 to die 602, with extruder 614 having a larger diameter or higher operating temperature than extruder 606 so as to supply the polymer at a higher flow rate or lower viscosity into die 602 and enable production of larger size fibers at die 600 and smaller size fibers at die 602.
• Similar size orifices may be provided in die 600 and die 602 with die 600 being operated at a low temperature and die 602 being operated at a high temperature so as to produce larger size fibers at die 600 and smaller size fibers at die 602.
• Polymers of the same polymeric composition but different melt indices may be supplied from extruder 606 to die 600 and from extruder 614 to die 602 (using for example a low melt index version of the polymer in extruder 606 and a high melt index of the same polymer in extruder 614) so as to produce larger size fibers at die 600 and smaller size fibers at die 602.
• Those having ordinary skill in the art will appreciate that other techniques (e.g., the inclusion of a solvent in the stream of liquefied fiber-forming material flowing to die 602, or the use of die cavities with a shorter flow path in die 600 and a longer flow path in die 602) and combinations of such techniques and the various operating modes discussed above may also be employed.
• the meltblowing dies 600 and 602 preferably are positioned so that the larger size fiber stream 618 and smaller size fiber stream 620 adequately intermingle.
• the distance 628 from the exit of larger size fiber die 600 to the centerline of the merged fiber stream 622 is preferably about 2 to about 12 in. (about 5 to about 25 cm) and more preferably about 6 to about 8 in. (about 15 to about 20 cm).
• the distance 630 from the exit of smaller size fiber die 602 to the centerline of the merged fiber stream 622 preferably is about 2 to about 12 in. (about 5 to about 25 cm) and more preferably about 6 to about 8 in. (about 15 to about 20 cm) or less for very small micro fibers.
• the distances 628 and 630 need not be the same.
• the stream 618 of larger size fibers is preferably disposed at an acute angle ⁇ ' to the stream 620 of smaller size fibers.
• ⁇ ' is between about 0 and about 45 degrees and more preferably between about 10 and about 30 degrees.
• the distance 632 from the approximate point of joinder of the larger and smaller size fiber streams to the collector drum 624 is typically at least about 5 in. (13 cm) but less than about 15 in. (38 cm) to avoid over-entangling and to retain web uniformity.
• a meltspinning die spinneret 700 for use in making a moldable monocomponent monolayer bimodal mass fraction/fiber size web via yet another process is shown in outlet end view.
• Spinneret 700 includes a body member 702 held in place with bolts 704.
• An array of larger orifices 706 and smaller orifices 708 define a plurality of flow passages through which liquefied fiber-forming material exits spinneret 700 and forms filaments.
• the larger orifices 706 and smaller orifices 708 have a 2:1 size ratio and there are 9 smaller orifices 708 for each larger orifice 706.
• Other ratios of larger: smaller orifice sizes may be used, for example ratios of 1 : 1 or more, 1.5 : 1 or more, 2: 1 or more, 2.5 : 1 or more, 3 : 1 or more, or 3.5:1 or more.
• ratios of the number of smaller orifices per larger orifice may also be used, for example ratios of 5:1 or more, 6:1 or more, 10:1 or more, 12:1 or more, 15:1 or more, 20: 1 or more or 30: 1 or more.
• ratios of 5:1 or more, 6:1 or more, 10:1 or more, 12:1 or more, 15:1 or more, 20: 1 or more or 30: 1 or more may be used, for example ratios of 5:1 or more, 6:1 or more, 10:1 or more, 12:1 or more, 15:1 or more, 20: 1 or more or 30: 1 or more.
• the number of smaller orifices per larger orifice and the number of smaller size fibers (e.g., microfibers under appropriate operating conditions) per larger size fiber in the collected web.
• a meltblowing die 800 for use in making a moldable monocomponent monolayer bimodal mass fraction/fiber size web via yet another process is shown in outlet end perspective view, with the secondary attenuating gas deflector plates removed.
• Die 800 includes a projecting tip portion 802 with a row 804 of larger orifices 806 and smaller orifices 808 which define a plurality of flow passages through which liquefied fiber-forming material exits die 800 and forms filaments.
• Holes 810 receive through-bolts (not shown in Fig. 8) which hold the various parts of the die together.
• the larger orifices 806 and smaller orifices 808 have a 2: 1 size ratio and there are 9 smaller orifices 808 for each larger orifice 806.
• ratios of larger: smaller orifice sizes may be used, for example ratios of 1.5:1 or more, 2:1 or more, 2.5:1 or more, 3:1 or more, or 3.5:1 or more.
• Other ratios of the number of smaller orifices per larger orifice may also be used, for example ratios of 5 : 1 or more, 6:1 or more, 10:1 or more, 12:1 or more, 15:1 or more, 20:1 or more or 30:l or more.
• a meltspinning die 900 for use in making a moldable monocomponent monolayer bimodal mass fraction/fiber size web via yet another process is shown in exploded schematic view.
• Die 900 may be referred to as a "plate die”, “shim die” or “stack die”, and includes an inlet plate 902 whose fluid inlets 904 and 906 each receive a stream of liquefied fiber- forming material.
• the streams have the same polymeric composition but different flow rates or different melt viscosities.
• the polymer streams flow through a series of intermediate plates 908a, 908b, etc. whose passages 910a, 910b, etc. repeatedly divide the streams.
• the thus serially-divided streams flow through a plurality (e.g., 256, 512 or some other multiple of the number of fluid inlets) of fluid outlet orifices 914 in outlet plate 916.
• the various plates may be fastened together via bolts or other fasteners (not shown in Fig. 9) through holes 918.
• Each fluid outlet orifice 914 will communicate via a unique flow path with one or the other of the fluid inlets 904 or 906.
• meltspinning apparatus will be familiar to those having ordinary skill in the art, and may be used to process the liquefied fiber-forming materials into a nonwoven web of meltspun filaments having a bimodal mass fraction/fiber size mixture of intermingled larger size fibers and smaller size fibers of the same polymeric composition.
• meltblowing die 1000 for use in making a moldable monocomponent monolayer bimodal mass fraction/fiber size web via yet another process is shown in cross-sectional and outlet end view.
• Die 1000 is supplied with liquefied fiber-forming material fed from hopper 1004, extruder 1006 and conduit 1008 at a first flow rate or first viscosity.
• Die 1000 is separately supplied with liquefied fiber- forming material of the same polymeric composition fed from hopper 1012, extruder 1014 and conduit 1016 at a second, different flow rate or viscosity.
• the conduits 1008 and 1016 are in respective fluid communication with first and second die cavities 1018 and
• die cavities 1018 and 1020 located in first and second generally symmetrical parts 1022 and 1024 which form outer walls for die cavities 1018 and 1020.
• First and second generally symmetrical parts 1026 and 1028 form inner walls for die cavities 1018 and 1020 and meet at seam 1030. Parts 1026 and 1028 may be separated along most of their length by insulation 1032.
• die cavities 1018 and 1020 are in respective fluid communication via passages 1034, 1036 and 1038 with a row 1040 of orifices 1042 and 1044.
• filaments of larger and smaller sizes may be extruded through the orifices 1042 and 1044, thereby enabling formation of a nonwoven web containing a bimodal mass fraction/fiber size mixture of intermingled larger size fibers and smaller size fibers of the same polymeric composition.
• the remaining portions of the associated me ltb lowing apparatus will be familiar to those having ordinary skill in the art, and may be used to process the liquefied fiber-forming materials into a nonwoven web of meltblown filaments having a bimodal mass fraction/fiber size mixture of intermingled larger size fibers and smaller size fibers of the same polymeric composition.
• the orifices 1042 and 1044 are arranged in alternating order and are in respective fluid communication with the die cavities 1018 and 1020.
• other arrangements of the orifices and other fluid communication ratios may be employed to provide nonwoven webs with altered fiber size distributions.
• Persons having ordinary skill in the art will also appreciate that other operating modes and techniques (e.g., like those discussed above in connection with the Fig. 6 apparatus) and combinations of such techniques and operating modes may also be employed.
• the disclosed nonwoven webs may have a random fiber arrangement and generally isotropic in-plane physical properties (e.g., tensile strength), or if desired may have an aligned fiber construction (e.g., one in which the fibers are aligned in the machine direction as described in the above-mentioned Shah et al. U.S. Patent No. 6,858,297) and anisotropic in-plane physical properties.
• isotropic in-plane physical properties e.g., tensile strength
• polymeric fiber-forming materials may be used in the disclosed process.
• the polymer may be essentially any thermoplastic fiber-forming material capable of providing a charged nonwoven web which will maintain satisfactory electret properties or charge separation.
• Preferred polymeric fiber-forming materials are non- conductive resins having a volume resistivity of 1014 ohm-centimeters or greater at room temperature (22° C). Preferably, the volume resistivity is about 10 ⁇ " ohm-centimeters or greater. Resistivity of the polymeric fiber- forming material may be measured according to standardized test ASTM D 257-93.
• the polymeric fiber- forming material also preferably is substantially free from components such as antistatic agents that could significantly increase electrical conductivity or otherwise interfere with the fiber's ability to accept and hold electrostatic charges.
• Some examples of polymers which may be used in chargeable webs include thermoplastic polymers containing polyolefms such as polyethylene, polypropylene, polybutylene, poly(4-methyl-l-pentene) and cyclic olefin copolymers, and combinations of such polymers.
• polymers which may be used but which may be difficult to charge or which may lose charge rapidly include polycarbonates, block copolymers such as styrene-butadiene-styrene and styrene-isoprene-styrene block copolymers, polyesters such as polyethylene terephthalate, polyamides, polyurethanes, and other polymers that will be familiar to those skilled in the art.
• the fibers preferably are prepared from poly-4-methyl-l pentene or polypropylene. Most preferably, the fibers are prepared from polypropylene homopolymer because of its ability to retain electric charge, particularly in moist environments.
• Electric charge can be imparted to the disclosed nonwoven webs in a variety of ways. This may be carried out, for example, by contacting the web with water as disclosed in U.S. Patent No. 5,496,507 to Angadjivand et al., corona-treating as disclosed in U.S. Patent No. 4,588,537 to Klasse et al., hydrocharging as disclosed, for example, in U.S. Patent No. 5,908,598 to Rousseau et al., plasma treating as disclosed in U.S. Patent No. 6,562,112 B2 to Jones et al. and U.S. Patent Application Publication No.
• Additives may be added to the polymer to enhance the web's filtration performance, electret charging capability, mechanical properties, aging properties, coloration, surface properties or other characteristics of interest.
• Representative additives include fillers, nucleating agents (e.g., MILLADTM 3988 dibenzylidene sorbitol, commercially available from Milliken Chemical), electret charging enhancement additives (e.g., tristearyl melamine, and various light stabilizers such as CHIMASSORBTM 119 and CHIMASSORB 944 from Ciba Specialty Chemicals), cure initiators, stiffening agents (e.g., poly(4-methyl-l -pentene)), surface active agents and surface treatments (e.g., fluorine atom treatments to improve filtration performance in an oily mist environment as described in U.S. Patent Nos.
• nucleating agents e.g., MILLADTM 3988 dibenzylidene sorbitol, commercially available from Milliken Chemical
• electret charging enhancement additives e.g., tristearyl melamine, and various light stabilizers such as CHIMASSORBTM 119 and CHIMASSORB 944 from Cib
• electret charging enhancement additives are generally present in an amount less than about 5 wt. % and more typically less than about 2 wt. %.
• the disclosed nonwoven webs may be formed into cup-shaped molded respirators using methods and components that will be familiar to those having ordinary skill in the art.
• the disclosed molded respirators may if desired include one or more additional layers other than the disclosed monolayer matrix.
• inner or outer cover layers may be employed for comfort or aesthetic purposes and not for filtration or stiffening.
• one or more porous layers containing sorbent particles may be employed to capture vapors of interest, such as the porous layers described in U.S. Patent Application Serial No. 11/431,152 filed May 8, 2006 and entitled PARTICLE- CONTAINING FIBROUS WEB, the entire disclosure of which is incorporated herein by reference.
• Other layers including stiffening layers or stiffening elements
• Molded matrix properties may be evaluated by forming a test cup-shaped matrix between mating male and female halves of a hemispherical mold having a 55mm radius and a 310 cm ⁇ volume.
• EFD may be determined (unless otherwise specified) using an air flow rate of
• Gurley Stiffness may be determined using a Model 4171 E GURLEYTM Bending Resistance Tester from Gurley Precision Instruments. Rectangular 3.8 cm x 5.1 cm rectangles are die cut from the webs with the sample long side aligned with the web transverse (cross-web) direction. The samples are loaded into the Bending Resistance Tester with the sample long side in the web holding clamp. The samples are flexed in both directions, viz., with the test arm pressed against the first major sample face and then against the second major sample face, and the average of the two measurements is recorded as the stiffness in milligrams. The test is treated as a destructive test and if further measurements are needed fresh samples are employed.
• Taber Stiffness may be determined using a Model 150-B TABERTM stiffness tester (commercially available from Taber Industries). Square 3.8 cm x 3.8 cm sections are carefully vivisected from the webs using a sharp razor blade to prevent fiber fusion, and evaluated to determine their stiffness in the machine and transverse directions using 3 to 4 samples and a 15° sample deflection.
• Percent penetration, pressure drop and the filtration Quality Factor QF may be determined using a challenge aerosol containing NaCl or DOP particles, delivered (unless otherwise indicated) at a flow rate of 85 liters/min, and evaluated using a TSITM Model 8130 high-speed automated filter tester (commercially available from TSI Inc.).
• the particles may generated from a 2% NaCl solution to provide an aerosol containing particles with a diameter of about 0.075 ⁇ m at an airborne concentration of about 16-23 mg/m ⁇ , and the Automated Filter Tester may be operated with both the heater and particle neutralizer on.
• the aerosol may contain particles with a diameter of about 0.185 ⁇ m at a concentration of about 100 mg/m ⁇ , and the Automated Filter Tester may be operated with both the heater and particle neutralizer off.
• the samples may be loaded to the maximum NaCl or DOP particle penetration at a 13.8 cm/sec face velocity for flat web samples or an 85 liters/min flowrate for molded matrices before halting the test.
• Calibrated photometers may be employed at the filter inlet and outlet to measure the particle concentration and the % particle penetration through the filter.
• An MKS pressure transducer (commercially available from MKS Instruments) may be employed to measure pressure drop ( ⁇ P, mm H2O) through the filter. The equation:
• AP may be used to calculate QF.
• Parameters which may be measured or calculated for the chosen challenge aerosol include initial particle penetration, initial pressure drop, initial Quality Factor QF, maximum particle penetration, pressure drop at maximum penetration, and the milligrams of particle loading at maximum penetration (the total weight challenge to the filter up to the time of maximum penetration).
• the initial Quality Factor QF value usually provides a reliable indicator of overall performance, with higher initial QF values indicating better filtration performance and lower initial QF values indicating reduced filtration performance.
• Deformation Resistance DR may be determined using a Model TA-XT2i/5 Texture Analyzer (from Texture Technologies Corp.) equipped with a 25.4 mm diameter polycarbonate test probe. A molded test matrix (prepared as described above in the definition for King Stiffness) is placed facial side down on the Texture Analyzer stage. Deformation resistance is measured by advancing the polycarbonate probe downward at
• meltspun fibers were prepared from TOTALTM 3860 polypropylene having a melt flow index of 70 from Total Petrochemicals, to which was added 0.75 wt. % of CHIMASSORB 944 hindered-amine light stabilizer from Ciba Specialty Chemicals.
• the extrusion head 10 had 16 rows of orifices, with 32 orifices in a row, making a total of 512 orifices.
• the orifices were arranged in a square pattern (meaning that orifices were in alignment transversely as well as longitudinally, and equally spaced both transversely and longitudinally) with 0.25 inch (6.4 mm) spacing.
• the polymer was fed to the extrusion head at different rates, noted below in Table IA, where the polymer was heated to a temperature of 235° C (455° F).
• Two quenching air streams (18b in Fig. 2; stream 18a was not employed) were used.
• a first, upper quenching air stream was supplied from quench boxes 16 in. (406 mm) in height at an approximate face velocity of 83 ft/min (0.42 m/sec) for Run Nos.
• Collection belt 19 was made from 20-mesh stainless steel and moved at a rate of 29 ft/min (about 8.8 meters/min) for Run Nos. 1-1 through 1-3 and 47 ft/min (about 14.3 meters/min) for Run No. 1-4. Based on similar samples, the meltspun fibers of Run Nos. 1-1 through 1-3 were estimated to have a median fiber diameter of approximately 11 ⁇ m. The meltspun fibers of Run No. 1-4 were measured with scanning electron microscopy (SEM) and found to have a median diameter (44 fibers measured) of 15 ⁇ m.
• SEM scanning electron microscopy
• the meltblown fibers were prepared from TOTAL 3960 polypropylene having a melt flow index of 350 from Total Petrochemicals, to which was added 0.75wt. % CHIMASSORB 944 hindered-amine light stabilizer.
• the polymer was fed into a drilled- orifice meltb lowing die (504 in Fig. 2 and Fig. 3) having a 10-inch- wide (254 mm) nosetip, with twenty-five 0.015 in. diameter (0.38 mm) orifices per inch (one orifice per mm), at a rate of 10 pounds per hour (4.54 kg per hour).
• the die temperature was 325° C (617° F) and the primary air stream temperature was 393° C (740° F).
• the flow of air in the primary air stream was estimated to be about 250 scfm (7.1 standard m-V min).
• the relationship of the meltb lowing die to the spunbond fiber stream 1 was as follows: the distance 520 was 4 in. (about 10 cm); the distance 522 was 8.5 in. (about 22 cm); the distance 524 was 19 in. (about 48 cm); and the angle ⁇ was 20°.
• the meltblown fiber stream was deposited on the collection belt 19 at a width of about 12 in. (about 30 cm).
• the meltblown fibers of Run No. 1-4 were measured with SEM and found to have a median diameter (270 fibers measured) of 1.13 ⁇ m.
• the vacuum under collection belt 19 was estimated to be in the range of 6-12 in. H2O (1.5-3 kPa).
• the region 215 of the plate 211 had 0.062-inch-diameter (1.6 mm) openings in a staggered spacing resulting in 23% open area; the web hold-down region 216 had 0.062-inch-diameter (1.6 mm) openings in a staggered spacing resulting in 30 % open area; and the heating/bonding region 217 and the quenching region 218 had 0.156- inch-diameter (4.0 mm) openings in a staggered spacing resulting in 63% open area.
• Air was supplied through the conduits 207 at a rate sufficient to present 500 ft.-Vniin (about 14.2 m ⁇ /min) of air at the slot 209, which was 1.5 in. by 22 in.
• the webs were next formed into smooth, cup-shaped molded respirators using a heated, hydraulic molding press and a 0.20 in. (5.1 mm) mold gap.
• the webs were molded with the collector side of the web (the side of the web that directly contacted the collector surface during web collection) both up and down, to examine whether fiber intermixing or the collection surface affected the loading behavior.
• the resulting cup- shaped molded matrices had an approximate external surface area of 145 cm 2 and good stiffness as evaluated manually.
• a molded respirator made from the Run No. 1-2F web was evaluated to determine its King Stiffness value, and found to have a King Stiffness of 0.68 N (0.152 Ib). Based on similar samples and the data in Example 10 and Fig. 23 (discussed below), a modest basis weight increase of about 20 to 50 gsm should increase the molded matrix King Stiffness to more than 1 N.
• 1-23M was made from a web formed at a significantly higher collector speed, has low initial pressure drop, and has maximum penetration less than 5%.
• Other preferred embodiments in Table 1C include Run Nos. 1-5M, 1-1 IM, 1-13M and 1-24M, because they exhibit initial pressure drop of less than 10 mm H2O, maximum penetrations of less than 5%, and moderate NaCl challenge at maximum penetration (meaning that they do not plug up too rapidly).
• a Zenith 10 cc/rev melt pump metered the flow of polymer to a 10 in. (25.4 cm) wide drilled orifice meltblowing die whose original 0.012 in. (0.3 mm) orifices had been modified by drilling out every 21st orifice to 0.025 in. (0.6 mm), thereby providing a 20:1 ratio of the number of smaller size to larger size holes and a 2:1 ratio of larger hole size to smaller hole size.
• the line of orifices had 25 holes/inch (10 holes/cm) hole spacing. Heated air attenuated the fibers at the die tip.
• the airknife employed a 0.010 in. (0.25 mm) positive set back and a 0.030 in. (0.76 mm) air gap.
• Table 2A The Table 2A webs were next molded to form cup-shaped molded matrices for use as personal respirators.
• the top mold was heated to about 235° F (113° C)
• the bottom mold was heated to about 240° F (116° C)
• a mold gap of 0.050 in. (1.27 mm) was employed and the web was left in the mold for about 9 seconds.
• the matrix Upon removal from the mold, the matrix retained its molded shape.
• Table 2B Set out below in Table 2B are the Run Number, King Stiffness, initial pressure drop, and the initial (and for Run Nos. 2- IM and 2-4M, the maximum loading) NaCl penetration values for the molded matrices. Table 2B
• Fig. 12 is a graph showing % NaCl penetration and pressure drop for the molded matrices of Run Nos. 2-1M and 2-4M. Curves A and B respectively are the % NaCl penetration results for Run Nos. 2-1M and 2-4M, and Curves C and D respectively are the pressure drop results for Run Nos. 2-1M and 2-4M. Fig. 12 shows that the molded matrices of Run Nos. 2- IM and 2-4M provide monocomponent, monolayer molded matrices which pass the N95 NaCl loading test of 42 C.F.R. Part 84.
• Table 3 A webs were next molded using the method of Example 2 to form cup-shaped molded matrices for use as personal respirators.
• Table 3B are the Run Number, King Stiffness, initial pressure drop, and initial NaCl penetration for the molded matrices.
• Table 4A webs were next molded using the method of Example 2 to form cup-shaped molded matrices for use as personal respirators.
• Table 4B are the Run Number, King Stiffness, initial pressure drop, and initial NaCl penetration for the molded matrices.
• Table 5 A webs were next molded using the method of Example 2 to form cup-shaped molded matrices for use as personal respirators.
• Table 5B are the Run Number, King Stiffness, initial pressure drop, and initial NaCl penetration for the molded matrices.
• Example 6 [00110] Using the method of Example 3, webs were made from EXXONTM PP3746G
• Table 6 A webs were next molded using the method of Example 2 to form cup-shaped molded matrices for use as personal respirators.
• Table 6B are the Run Number, King Stiffness, initial pressure drop, and initial NaCl penetration for the molded matrices.
• the Run No. 6-8F flat web and 6-8M molded matrix were analyzed using scanning electron microscopy (SEM), at magnifications of 50 to l,000X made using a LEO VP 1450 electron microscope (from the Carl Zeiss Electron Microscopy Group), operated at 15 kV, 15 mm WD, 0° tilt, and using a gold/palladium-coated sample under high vacuum.
• Fig. 13 and Fig. 14 are photomicrographs of the Run No. 6-8F flat web and the Run No. 6-8M molded matrix. Histograms of fiber count (frequency) vs.
• Fig. 15 and Fig. 16 are histograms of fiber count (frequency) vs. fiber size in ⁇ m for the Run No. 6-8F flat web and the Run No. 6- 8M molded matrix. Further details regarding the fiber size analyses for these webs are shown below in Table 6C: Table 6C
• Table 7A The Table 7A webs were next molded using the method of Example 2 to form cup-shaped molded matrices for use as personal respirators. Set out below in Table 7B are the Run Number, King Stiffness, initial pressure drop, and initial NaCl penetration for the molded matrices. Table 7B
• Fig. 17 is a graph showing % NaCl penetration and pressure drop for the molded matrix of Run No. 7- IM. Curves A and B respectively are the % NaCl penetration and pressure drop results. Fig. 17 and the data in Table 7B show that the molded matrix of Run No. 7- IM provides a monocomponent, monolayer molded matrix which passes the N95 NaCl loading test of 42 C.F.R. Part 84.
• Table 8A webs were next molded using the method of Example 2 to form cup-shaped molded matrices for use as personal respirators.
• Table 8B are the Run Number, King Stiffness, initial pressure drop, and the initial (and, for Run No. 8- 3M, the maximum loading) NaCl penetration values for the molded matrices.
• the respirators included a blown microf ⁇ ber outer cover layer web, a PE85-12 thermoplastic nonwoven adhesive web from Bostik Findley, the flat web of this Example 9, another PE85-12 thermoplastic nonwoven adhesive web and another blown microf ⁇ ber inner cover layer web.
• the layers were formed into a cup-shaped respirator using a mold like that described above but having a ribbed front surface.
• the resulting molded respirators were evaluated according to ASTM F- 1862-05, "Standard Test Method for Resistance of Medical Face Masks to Penetration by Synthetic Blood (Horizontal Projection of Fixed Volume at a Known Velocity)", at test pressures of 120 mm Hg and 160 mm Hg.
• the 120 mm Hg test employed a 0.640 sec.
• the 160 mm Hg test employed a 0.554 sec. valve time and a 0.052 MPa tank pressure.
• the respirators passed the test at both test pressures.
• Table 9 Set out below in Table 9 are the Run Number, and the basis weight, EFD, thickness, initial pressure drop and initial NaCl penetration for the molded monocomponent web.
• Example 10 [00120] Using the method of Comparative Example 3 of U.S. Patent No. 6,319,865 Bl
• the die also had a 0.20 mm air slit width, a 60° nozzle edge angle, and a 0.58 mm air lip opening.
• a fine mesh screen moving at 1 to 50 m/min was employed to collect the fibers.
• the other operating parameters are shown below in Table 1OA:
• Fig. 18 is a histogram of mass fraction vs. fiber size in ⁇ m for the 200 gsm web.
• the web exhibited modes at 2 and 7 ⁇ m. Local peaks also appeared at 4 and 10 ⁇ m.
• the 4 ⁇ m peak did not have a larger height than fiber sizes 2 ⁇ m smaller and 2 ⁇ m larger and did not represent a mode
• the 10 ⁇ m peak did not have a larger height than fiber sizes 2 ⁇ m smaller and did not represent a mode.
• the web did not have a larger size fiber mode greater than 10 ⁇ m.
• the 200 gsm web was molded using the general method of Example 2 to form a cup-shaped molded matrix.
• the heated mold was closed to a 0.5 mm gap and an approximate 6 second dwell time was employed.
• the molded matrix was allowed to cool, and found to have a King Stiffness value of 0.64 N.
• Fig. 19 is a histogram of mass fraction vs. fiber size in ⁇ m for the 200 gsm web. The web exhibited modes at 4, 10, 17 and 22 ⁇ m. Local, non-modal peaks also appeared at 8 and 13 ⁇ m. As shown in Fig. 19, the web had larger size fiber modes greater than 10 ⁇ m.
• Fig. 20 is a histogram of fiber count (frequency) vs. fiber size in ⁇ m for the same 200 gsm web.
• the 200 gsm web was molded using the general method of Example 2 to form a cup-shaped molded matrix.
• the heated mold was closed to a 0.5 mm gap and an approximate 6 second dwell time was employed.
• the molded matrix was allowed to cool, and found to have a King Stiffness value of 0.98 N.
• the larger orifices had a 0.63 mm diameter (Da), the smaller orifices had a 0.3 mm diameter (Db), the orifice diameter ratio R (Da/Db) was 2.1, there were 9 smaller orifices between each pair of larger orifices and the orifices were spaced at 25 orifices/in. (9.8 orifices/cm).
• a single screw extruder with a 50 mm diameter screw and a lOcc melt pump were used to supply the die with polymer.
• the die also had a 0.76 mm air slit width, a 60° nozzle edge angle, and a 0.86 mm air lip opening.
• a fine mesh screen moving at 1 to 50 m/min and the operating parameters shown below in Table 1OC were employed to collect webs at 60, 100, 150 and 200 gsm:
• Fig. 21 is a histogram of mass fraction vs. fiber size in ⁇ m for the 200 gsm 100 MFR web. The web exhibited modes at 15, 30 and 40 ⁇ m. As shown in Fig. 21, the web had a larger size fiber mode greater than 10 ⁇ m.
• Fig. 22 is a histogram of fiber count (frequency) vs. fiber size in ⁇ m for the same 200 gsm web.
• Fig. 23 shows a plot of Deformation Resistance DR values vs. basis weight.
• Curves A, B, C and D respectively show webs made according to Table 1OA (37 gsm, 5:1 Db/Da ratio), Table 1OB and Table 1OC (37 gsm) and Table 1OC (100 gsm).
• Table 1OD and Fig. 23 webs made according to Mikami et al. Comparative Example 5 using a polymer like the 40 melt flow rate polymer employed by Mikami et al. had relatively low Deformation Resistance DR values.
• Employing a higher melt flow rate polymer than the Mikami et al. polymer or using a die with a greater number of smaller orifices per larger orifice than the Mikami et al. dies provided webs having significantly greater Deformation Resistance DR values.
• a monocomponent monolayer web was formed using meltblowing of larger fibers and separately prepared smaller size fibers of the same polymeric composition.
• the larger size fibers were formed using TOTAL 3960 polypropylene (a 350 melt flow rate polymer) to which had been added 0.8 % CHIMASSORB 944 hindered amine light stabilizer as an electret charging additive and 1 % POLYONETM No. CC 10054018WE blue pigment from PolyOne Corp. to aid in assessing the distribution of larger size fibers in the web.
• the resulting blue polymer blend was fed to a Model 20 DAVIS STANDARDTM 2 in. (50.8mm) single screw extruder from the Davis Standard
• the extruder had a 60 in. (152 cm) length and a 30/1 length/diameter ratio.
• the smaller size fibers were formed using EXXON PP3746 polypropylene (a 1475 melt flow rate polymer) available from Exxon Mobil Corporation to which had been added 0.8 % CHIMASSORB 944 hindered amine light stabilizer. This latter polymer was white in color and was fed to a KILLI ONTM 0.75 in. (19 mm) single screw extruder from the Davis Standard Division of Crompton & Knowles Corp. Using 10 cc/rev ZENITHTM melt pumps from Zenith Pumps, the flow of each polymer was metered to separate die cavities in a 20 in.
• the Table 1 IA web was next molded to form a cup-shaped molded matrix for use as a personal respirator.
• the top mold was heated to about 235° F (113° C)
• the bottom mold was heated to about 240° F (116° C)
• a mold gap of 0.020 in. (0.51 mm) was employed and the web was left in the mold for about 6 seconds.
• the matrix retained its molded shape.
• Table 1 IB are the Run Number, King Stiffness, initial pressure drop, initial NaCl penetration and maximum loading penetration for the molded matrix.
• Example 11 was repeated without using the electret charging additive in either the larger size or smaller size fibers.
• the web was plasma charged according to the technique taught in U. S. Patent No. 6,660,210 (Jones et al.) and then hydrocharged with distilled water according to the technique taught in U. S. Patent No. 5,496,507 (Angadjivand et al. '507) and allowed to dry.
• Table 12A are the Run Number, basis weight, EFD, web thickness, initial pressure drop, initial NaCl penetration and Quality Factor QF for the flat web at a 13.8 cm/sec face velocity: Table 12A
• Table 12A web was next molded according to the method of Example 11. Upon removal from the mold, the matrix retained its molded shape. Set out below in Table 12B are the Run Number, King Stiffness, initial pressure drop, initial NaCl penetration and maximum loading penetration for the molded matrix.
• Example 11 Using the method of Example 11 , a monocomponent monolayer web was formed.
• the larger size fibers were formed using TOTAL 3868 polypropylene (a 37 melt flow rate polymer) to which had been added 0.8 % CHIMASSORB 944 hindered amine light stabilizer from Ciba Specialty Chemicals as an electret charging additive and 2 % POLYONETM No. CC 10054018WE blue pigment.
• the smaller size fibers were formed using EXXON PP3746G polypropylene to which had been added 0.8 % CHIMASSORB 944 hindered amine light stabilizer.
• the polymer output rate from the extruders was 1.5 lbs/in/hr (0.27 kg/cm/hr), the DCD (die-to-collector distance) was 13.5 in. (34.3 cm) and the polymer rate from each extruder was adjusted to provide a web with 65% larger size fibers and 35% smaller size fibers.
• the web was hydrocharged with distilled water according to the technique taught in U. S. Patent No. 5,496,507 (Angadjivand et al. '507) and allowed to dry.
• Table 13A are the Run Number, basis weight, EFD, web thickness, initial pressure drop, initial NaCl penetration and Quality Factor QF for the flat web at a 13.8 cm/sec face velocity:
• Table 13A The Table 13A web was next molded to form a cup-shaped molded matrix for use as a personal respirator.
• the top and bottom of the mold were both heated to about 230° F (110° C), a mold gap of 0.040 in. (1.02 mm) was employed and the web was left in the mold for about 9 seconds.
• the matrix Upon removal from the mold, the matrix retained its molded shape.
• Table 13B Set out below in Table 13B are the Run Number, King Stiffness, initial pressure drop, initial NaCl penetration and maximum loading penetration for the molded matrix.
• Fig. 24 is a graph showing % NaCl penetration and pressure drop for the molded respirator of Run No. 13- IM and Fig. 25 is a similar graph for a commercial N95 respirator made from multilayer filtration media. Curves A and B respectively are the % NaCl penetration and pressure drop results for the Run No. 13-1M respirator, and Curves C and D respectively are the % NaCl penetration and pressure drop results for the commercial respirator. Fig. 24 and the data in Table 13B show that the molded matrix of Run No. 13- IM provides a monocomponent, monolayer filtration layer which passes the N95 NaCl loading test of 42 C.F.R. Part 84, and which may offer longer filter life than the commercial respirator.
• Fig. 26 and Fig. 27 respectively are a photomicrograph of and a histogram of fiber count (frequency) vs. fiber size in ⁇ m for the Run No. 13-1M molded matrix.
• Table 13C is a summary of the fiber size distribution counts
• Table 13D is a summary of fiber size statistics for the Run No. 13-1M molded matrix.
• Fig. 26 shows that the matrix fibers are bonded to one another at at least some points of fiber intersection.
• Fig. 27 and the data in Table 13C show that the mixture of larger size fibers and smaller size fibers was polymodal, with at least three local modes.
• the line of orifices had 25 holes/inch (10 holes/cm) hole spacing. Heated air attenuated the fibers at the die tip.
• the airknife employed a 0.010 in. (0.25 mm) positive set back and a 0.030 in. (0.76 mm) air gap. No to moderate vacuum was pulled through a medium mesh collector screen at the point of web formation.
• the polymer output rate from the extruder was varied from 2.0 to 3.0 lbs/in/hr (0.18 to 0.54 kg/cm/hr), the DCD (die-to-collector distance) was varied from 18.0 to 20.5 in. (45.7 to 52.1 cm) and the air pressure was adjusted as needed to provide webs with a basis weight and EFD as shown below in Table 14A.
• Example 14-3F For Example 14-3F, a 20 in. (50.8 cm) wide drilled orifice meltblowing die with 0.015 in. (0.38 mm) orifices at 25 holes/inch (10 holes/cm) hole spacing was used.
• the polymer output rate from the extruder was 3.0 lbs/in/hr (0.54 kg/cm/hr)
• the DCD die-to-collector distance
• the air pressure was adjusted as needed to provide webs with a basis weight and EFD as shown below in Table 14 A.

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