WO2008078754A1 - 水性ポリウレタン樹脂エマルジョン被覆剤組成物及びその製造方法 - Google Patents

水性ポリウレタン樹脂エマルジョン被覆剤組成物及びその製造方法 Download PDF

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Publication number
WO2008078754A1
WO2008078754A1 PCT/JP2007/074881 JP2007074881W WO2008078754A1 WO 2008078754 A1 WO2008078754 A1 WO 2008078754A1 JP 2007074881 W JP2007074881 W JP 2007074881W WO 2008078754 A1 WO2008078754 A1 WO 2008078754A1
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polyurethane resin
resin emulsion
aqueous polyurethane
emulsion coating
coating composition
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PCT/JP2007/074881
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English (en)
French (fr)
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Koji Izumiji
Takaki Jono
Naotaka Izumi
Ryusuke Kishimoto
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Nippon Polyurethane Industry Co., Ltd.
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Publication of WO2008078754A1 publication Critical patent/WO2008078754A1/ja

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0804Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/34Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348Hydroxycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4854Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • C08G18/6692Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/34
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/721Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • C08G18/725Combination of polyisocyanates of C08G18/78 with other polyisocyanates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/7806Nitrogen containing -N-C=0 groups
    • C08G18/7818Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7837Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing allophanate groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/79Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes

Abstract

 耐水性や耐溶剤性などの各種の物性を低下させることなく、常温での成膜性(被覆層の均一性や耐久性など)を改良する水性ポリウレタン樹脂エマルジョン被覆剤であって、アロファネート変性ジイソシアネート(a1)及び有機ジイソシアネート(a2)を含有するポリイソシアネート(A)、高分子ポリオール(B)、カルボキシル基含有低分子グリコール(C)を反応させて得られるウレタンプレポリマー(D)と、多官能ポリイソシアネート(E)を混合し、中和処理後に水と混合して乳化分散させた後に、鎖延長剤(F)と反応させたポリウレタン樹脂を主剤とする、水性ポリウレタン樹脂エマルジョン組成物。
PCT/JP2007/074881 2006-12-25 2007-12-25 水性ポリウレタン樹脂エマルジョン被覆剤組成物及びその製造方法 WO2008078754A1 (ja)

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JP2006-347399 2006-12-25
JP2006347399A JP5452794B2 (ja) 2006-12-25 2006-12-25 水性ポリウレタン樹脂エマルジョン被覆剤組成物及びその製造方法

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WO2008078754A1 true WO2008078754A1 (ja) 2008-07-03

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CN (1) CN101553534A (ja)
WO (1) WO2008078754A1 (ja)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009028210A1 (ja) * 2007-08-31 2009-03-05 Nippon Polyurethane Industry Co., Ltd. アクリル・ウレタンブロック共重合体水性エマルジョンおよびその製造方法ならびに水性コーティング材
EP2402380A1 (en) * 2009-02-26 2012-01-04 Ube Industries, Ltd. Aqueous polyurethane resin dispersion and method for producing same
EP2433974A1 (en) * 2009-02-26 2012-03-28 Ube Industries, Ltd. Aqueous polyurethane resin dispersion and manufacturing method thereof
US8552109B2 (en) 2008-05-29 2013-10-08 Ube Industries, Ltd. Aqueous polyurethane resin dispersion, preparation method of the same, and coating composition containing the same
US8841381B2 (en) 2009-08-20 2014-09-23 Ube Industries Ltd. Aqueous polyurethane resin dispersion and process for preparing the same
CN112391104A (zh) * 2020-10-28 2021-02-23 华南理工大学 一种耐溶剂型水性聚氨酯塑料涂料及其制备方法

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2500370A1 (en) * 2009-11-10 2012-09-19 Ube Industries, Ltd. Aqueous polyurethane resin dispersion, process for production thereof, and use thereof
JP5849945B2 (ja) * 2010-02-19 2016-02-03 宇部興産株式会社 ポリオキシアルキレンアルコール及びポリウレタン樹脂並びにそれを含有するコーティング剤
IT1399424B1 (it) * 2010-04-08 2013-04-16 Lamberti Spa Dispersioni acquose di poliuretani anionici
JP5587282B2 (ja) * 2010-12-16 2014-09-10 キヤノン株式会社 インクジェット用インク、インクカートリッジ、及びインクジェット記録方法
JP5912588B2 (ja) * 2012-01-31 2016-04-27 第一工業製薬株式会社 水性ポリウレタン樹脂組成物の製造方法
JP5981547B2 (ja) * 2012-07-09 2016-08-31 Ykk株式会社 ファスナーテープ、当該ファスナーテープを備えたスライドファスナー、及びファスナーテープの製造方法
WO2014188865A1 (ja) * 2013-05-24 2014-11-27 ニチバン株式会社 ポリウレタン系粘着剤シートの製造方法及び熱解離結合含有ポリウレタン
JP6303657B2 (ja) * 2014-03-17 2018-04-04 東ソー株式会社 自己修復型形成性エマルジョン組成物、該組成物を用いた自己修復型形成塗膜
JP6578636B2 (ja) * 2014-08-22 2019-09-25 東ソー株式会社 水性ポリウレタン樹脂エマルジョン組成物、該組成物を用いた合成皮革、人工皮革用表面処理剤
JP6607269B2 (ja) * 2018-02-01 2019-11-20 亜細亜工業株式会社 塗料組成物
CN112322169A (zh) * 2020-11-17 2021-02-05 常州正邦数码科技有限公司 水性聚氨酯乳液及制备方法、涂层溶液、pvc功能膜
CN114656732B (zh) * 2022-04-25 2023-07-04 广东天进新材料有限公司 Pvc装饰材料及其制备方法、复合装饰材料及其制备方法

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JP2004075782A (ja) * 2002-08-13 2004-03-11 Nippon Polyurethane Ind Co Ltd 自己乳化型ブロックポリイソシアネート組成物及びそれを用いた水性塗料
JP2004285287A (ja) * 2003-03-25 2004-10-14 Nippon Polyurethane Ind Co Ltd 水性一液コーティング剤及びそれを用いたコーティング方法
JP2005194375A (ja) * 2004-01-07 2005-07-21 Nippon Polyurethane Ind Co Ltd 水性一液コーティング剤用ポリウレタンエマルジョンの製造方法
JP2006022133A (ja) * 2004-07-06 2006-01-26 Nippon Polyurethane Ind Co Ltd 水性ポリウレタンエマルジョン、並びにその製造方法及びその用途
JP2006307078A (ja) * 2005-04-28 2006-11-09 Nippon Polyurethane Ind Co Ltd 水性ポリウレタン樹脂エマルジョン組成物及びその製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004075782A (ja) * 2002-08-13 2004-03-11 Nippon Polyurethane Ind Co Ltd 自己乳化型ブロックポリイソシアネート組成物及びそれを用いた水性塗料
JP2004285287A (ja) * 2003-03-25 2004-10-14 Nippon Polyurethane Ind Co Ltd 水性一液コーティング剤及びそれを用いたコーティング方法
JP2005194375A (ja) * 2004-01-07 2005-07-21 Nippon Polyurethane Ind Co Ltd 水性一液コーティング剤用ポリウレタンエマルジョンの製造方法
JP2006022133A (ja) * 2004-07-06 2006-01-26 Nippon Polyurethane Ind Co Ltd 水性ポリウレタンエマルジョン、並びにその製造方法及びその用途
JP2006307078A (ja) * 2005-04-28 2006-11-09 Nippon Polyurethane Ind Co Ltd 水性ポリウレタン樹脂エマルジョン組成物及びその製造方法

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009028210A1 (ja) * 2007-08-31 2009-03-05 Nippon Polyurethane Industry Co., Ltd. アクリル・ウレタンブロック共重合体水性エマルジョンおよびその製造方法ならびに水性コーティング材
US8552109B2 (en) 2008-05-29 2013-10-08 Ube Industries, Ltd. Aqueous polyurethane resin dispersion, preparation method of the same, and coating composition containing the same
EP2433974A1 (en) * 2009-02-26 2012-03-28 Ube Industries, Ltd. Aqueous polyurethane resin dispersion and manufacturing method thereof
CN102333806A (zh) * 2009-02-26 2012-01-25 宇部兴产株式会社 水性聚氨酯树脂分散体及其制造方法
EP2402380A4 (en) * 2009-02-26 2012-08-22 Ube Industries AQUEOUS POLYURETHANE-DISPERSION AND METHOD FOR THE PRODUCTION THEREOF
EP2433974A4 (en) * 2009-02-26 2012-08-22 Ube Industries AQUEOUS POLYURETHANE-DISPERSION AND METHOD FOR THE PRODUCTION THEREOF
EP2402380A1 (en) * 2009-02-26 2012-01-04 Ube Industries, Ltd. Aqueous polyurethane resin dispersion and method for producing same
CN102333806B (zh) * 2009-02-26 2014-06-04 宇部兴产株式会社 水性聚氨酯树脂分散体及其制造方法
US8859676B2 (en) 2009-02-26 2014-10-14 Ube Industries, Ltd. Aqueous polyurethane resin dispersion and process for preparing the same
US8912280B2 (en) 2009-02-26 2014-12-16 Ube Industries, Ltd. Aqueous polyurethane resin dispersion and process for preparing the same
US8841381B2 (en) 2009-08-20 2014-09-23 Ube Industries Ltd. Aqueous polyurethane resin dispersion and process for preparing the same
CN112391104A (zh) * 2020-10-28 2021-02-23 华南理工大学 一种耐溶剂型水性聚氨酯塑料涂料及其制备方法
CN112391104B (zh) * 2020-10-28 2022-02-15 华南理工大学 一种耐溶剂型水性聚氨酯塑料涂料及其制备方法

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JP5452794B2 (ja) 2014-03-26
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