WO2008031385A2 - Schmierstoff für hochtemperatur-bandpressen - Google Patents
Schmierstoff für hochtemperatur-bandpressen Download PDFInfo
- Publication number
- WO2008031385A2 WO2008031385A2 PCT/DE2007/001401 DE2007001401W WO2008031385A2 WO 2008031385 A2 WO2008031385 A2 WO 2008031385A2 DE 2007001401 W DE2007001401 W DE 2007001401W WO 2008031385 A2 WO2008031385 A2 WO 2008031385A2
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- WIPO (PCT)
- Prior art keywords
- esters
- synthetic
- weight
- temperature
- lubricant
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- C10M2207/301—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids used as base material
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
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- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/083—Dibenzyl sulfide
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- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/102—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon only in the ring
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/108—Phenothiazine
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- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2223/04—Phosphate esters
- C10M2223/041—Triaryl phosphates
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2223/04—Phosphate esters
- C10M2223/043—Ammonium or amine salts thereof
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- C10M2223/045—Metal containing thio derivatives
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/02—Pour-point; Viscosity index
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/36—Seal compatibility, e.g. with rubber
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/74—Noack Volatility
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/38—Conveyors or chain belts
Definitions
- the present invention relates to a lubricant for high-temperature belt presses, in particular for high-temperature belt presses used in chipboard production, having the features specified in the preamble of patent claim 1. ,
- Chipboard and fiberboard are typically made by hot pressing blends of wood chips or wood fibers with a binder of, for example, synthetic resin (e.g., urea or melamine-formaldehyde resins).
- synthetic resin e.g., urea or melamine-formaldehyde resins
- high-temperature belt presses are used for this hot pressing, which comprise a circulating lower belt and a circulating upper belt, between which the mixture of wood shavings and binders is fed.
- the lower band and the upper band are then usually made of about 5 mm thick, endless steel bands and their distance from one another decreases in the transport direction to the desired thickness of the chipboard to be produced.
- the horizontal distance between the two endchangingrtigen pulleys of the lower belt and the upper belt is about 100 m to 200 m.
- the widths of the upper band and the lower band are each about 2.5 m.
- the upper belt is heated in its downstream region, in which it maintains a distance to the lower belt, which corresponds to the desired thickness of the chipboard to be produced, preferably by a multi-stage heating coil to temperatures in the range of 220 0 C to 260 0 C.
- the diameters of the two endward deflection rollers of the upper and lower belt are, for example, about 1.0 m, and the running speeds of the upper and lower belts are for example in the range of about 600 mm / sec. up to 1,500 mm / sec. ,
- the sub-belt is supported vertically with respect to the weight of the chipboard mixture to be pressed by horizontally oriented rolling rods.
- the pulleys facing inner sides of the lower belt and the upper belt each require lubrication with a lubricant. Excess lubricant evaporates there or drips off there. Solid residues are usually removed there by means acting on the insides of the two bands band scraper.
- Object of the present invention is therefore to provide a lubricant for the lubrication of the inner sides of the bands of high-temperature belt presses, which even at the high temperatures of a high-temperature belt press the formation of solid deposits, incrustations, Laking and caking on the pulleys or rolling bars safely prevented.
- the synthetic high temperature lubricant of the present invention for the lubrication of high temperature belt presses comprises a synthetic base oil blend [A)] comprising at least one base [a)] based on naphthalene or a naphthalene derivative whose structure is the general one formula
- radicals R are the same or different and each represents a hydrogen atom or an alkyl group.
- the synthetic base oil mixture [A)] further comprises a polyol ester base [b)] and a complex ester base [c) j.
- the additive package [B]] of the synthetic high-temperature lubricant according to the invention for the lubrication of high-temperature belt presses generally comprises one or more corrosion inhibitors [a)], which are selected, for example, from the group consisting of dicarboxylic acid esters, succinimide half esters, alkylated succinimide half esters, Succinimide derivatives, alkylated succinimide derivatives, amino-neutralized succinimide derivatives, esters of phosphoric acid with alcohols or phenols, organic phosphates, amineutralized mono-, di- or triesters of orthophosphoric acid, amino-neutralized phosphoric acid esters, amino-neutralized phosphoric acid partial esters, ashless amino-neutralized phosphoric acid partial esters, amino-neutralized phosphoric acid esters, naphthenic acids, calcium naphthalene sulfonate / carboxylate complexes, diamides, fatty acid amides,
- the additive package [B]] may further comprise one or more high-pressure additives [b)] which are selected, for example, from the group consisting of esters of phosphoric acid with alcohols or Phenols, organic phosphates, arylphosphoric acid esters, alkylphosphoric esters, mixed phosphoric esters, phosphoric esters, diphosphoric esters, and tri-phosphoric acid esters, monoesters, diesters or triesters of phosphoric acid, dithiophosphoric acid esters, dialkyldithiophosphate, triarylphosphoric acid esters, alkylated triarylphosphoric acid esters, triarylphosphoric acid esters substituted by sterically hindering groups , isopropylated triarylphosphoric acid esters, isobutylated triarylphosphoric acid esters, trioctylphosphate, tric
- the additive package [B]] may further comprise one or more antioxidants [c)] and one or more non-ferrous metal deactivators [d)]; metal deactivators [d)] are for example selected from the group comprising nitrogen heterocycles having 2 or 3 nitrogen atoms in the 5-membered ring or in the 6-membered ring, azoles, triazoles, triazole derivatives, triazone, triazolines, triazophos, ashless amino-neutralized phosphoric acid partial esters , Triazolamines, triazole derivatives, benzotriazoles, benzotriazole derivatives, toluyltriazole, tolutriazole derivatives, neutral synthesized triaryl phosphates, benzotriazolemethanamine, benzothiazoles, benzosulfimide, benzothiazole derivatives, benzothiophene, dimercap
- the additive package [B]] may further comprise one or more means [e]] for reducing the wear.
- the base oil mixture [A)] can be mixed with the additive package [B]] to obtain a synthetic high-temperature lubricant for high-temperature belt presses, which a corrosion effect on copper according to DIN EN ISO 2160 at 150 0 C after 24 hours with a Corrosion grade of 1 and which is a corrosion test against steel according to DIN ISO 7120.
- High-temperature belt presses usually keeps even in the case of thermal stress in the range of 240 0 C to 270 0 C its liquid state, while avoiding laking and / or caking and / or encrustations.
- the evaporation loss is in a tallschale at a furnace residence time of 48 hours at 260 0 C, for example, only in the range of 25% to 33%, based on the weight of the high temperature lubricant used at the beginning of the furnace test, wherein a liquid state is maintained and encrustations and / or laking and / or caking do not occur.
- the kinematic viscosity is, for example, in the range of 100 mm 2 / sec. up to 400 mm 2 / se ⁇ , preferably in the range of 150 mnrvVsec. up to 350 mm z / se ⁇ , in particular in the range of 200 mm 2 / sec. up to 300 mm 2 / sec. ,
- the polyol ester base [b)] of the synthetic base oil [A] may be selected, for example, from the group comprising sterically hindered polyol esters, saturated neopentyl esters, saturated trimethylolpropane esters or saturated pentaerythritol esters, or mixtures thereof.
- the synthetic base oil [A)] may further comprise one or more polyalphaolefin raw materials [d)], the structure of this polyalphaolefin (POA) being generally of the general formula
- y is an integer between 2 to 15, preferably between 3 to 8.
- the polyol ester base [b)] can not carry any hydrogen atoms on the ⁇ -carbon atoms adjacent to the functional groups.
- the terminal polar functional groups of the polyolester base [b)] may optionally be adsorbable to metal surfaces to form a protective film.
- the complex ester base [c)] of the synthetic base oil blend [A)] may be selected from the group consisting of polyol esters, sterically hindered substituted polyol esters, cross linked polyol esters, polyvalent ones Alcohols cross-linked with each other polyol esters and cross-linked with each other by acid polyolester, and mixtures thereof, wherein the complex ester [c)] serves as a thickener.
- the additive package [B)] may comprise one or more antioxidants [c]], which are selected, for example from the group, the phenols hindered by sterically hindering groups, sterically hindered, sulfur-containing or Sulfur-free phenols, high molecular weight hindered phenols, hindered phenols with thioether group, sterically hindered phenols with organic sulfide group, phenolic ethers, hydroxyphenolic ethers, alkylphenols, alkylated thiophenols, butylated hydroxytoluene (BHT), 2,6-di-tert-butyl-4- paracresol (DBPC), butylated hydroxyanisole (BHA), tris (nonylphenyl) phosphite, 2,6-di-tert-butylphenol (DTBP), aromatic amines (primary,
- the additive package [B)] may further comprise one or more agents for reducing the wear [e], which are for example selected from the group consisting of trialkyl phosphates, triaryl phosphates, neutral synthesized triaryl phosphates, tri-cresyl phosphate, phosphoric acid esters, aminophosphates, dialkylphosphoric acid esters, dialkyldithiophosphoric acid esters, neutralized phosphoric acid esters, neutralized phosphoric acid amines, thiophosphates, phosphoric acid derivatives, phosphorus-sulfur-nitrogen compounds, phosphites, dicarbamates, dithiophosphates, thiadiazoles, dialkyl phosphite, octadecane acids, stearic acid, octadecenoic acids, oleic acid, fatty acid esters, fatty acid
- High temperature belt presses may, in preferred embodiments, comprise the synthetic base oil blend [A)] in the range of, for example, 90.0 wt%. to 98.0% by weight and the additive package [B]], for example in the range of 2.1% by weight to 15.3% by weight.
- the synthetic base oil mixture [A)] may be 20.0 wt% to 80 wt% of naphthalene base [a)] and 10.0 wt% to 80.0 %
- polyolester base [b)] By weight of polyolester base [b)] and from 1.0% by weight to 20.0% by weight of complex ester base [c)] and from 0.0% by weight to 50.0% by weight of polyalphaolefin base [d)].
- the additive package [B)] may, for example, be 0.01% by weight to 3.5% by weight of corrosion inhibitor [a)] and 0.2% by weight to 5.0% by weight.
- the present invention provides for the first time a lubricant for the lubrication of the inner surfaces of the upper band and the lower band of a high-temperature belt press, which even at the high temperatures of a high-temperature belt press - up to the strip speed high speed range of 1,500 mm / sec. - And even in the presence of wood shavings, the formation of solid deposits, encrustations, laking and caking on the pulleys and the bars safely prevented.
- Another serious advantage of the lubricant according to the invention is that it even dissolves previously formed solid deposits on the pulleys and rolling rods by the earlier use of a known from the prior art lubricant, whereby a removal of these solid residues in normal and scheduled maintenance on particularly fast , simple and effortless way is possible.
- a particular advantage of the lubricant according to the invention is furthermore that the high-temperature belt presses operated under its use must be switched off much less frequently for cleaning purposes in comparison to high-temperature belt presses which are operated from lubricants known from the prior art Standstill due to production loss significantly increases the efficiency of the belt presses operated with the lubricant according to the invention.
- the cost-effectiveness of a high-temperature belt press operated with the lubricant according to the invention is further enhanced by a consumption of lubricant which is about 45% lower than that of a belt press operated using a lubricant known from the prior art.
- Another advantage of the lubricant according to the invention is that it causes a particularly low-lying metal abrasion, which is why the life of the upper belt and the lower belt and the pulleys and the rolling rods in a belt press, which is operated using the lubricant according to the invention, is significantly higher than that Life of the upper belt and the lower belt and the pulleys and the RoII- rods of a belt press, which is operated with a known from the prior art lubricant.
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- Chemical & Material Sciences (AREA)
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- Lubricants (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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DE112007002754T DE112007002754A5 (de) | 2006-09-13 | 2007-08-07 | Schmierstoff für Hochtemperatur-Bandpressen |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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DE202006014282U DE202006014282U1 (de) | 2006-09-13 | 2006-09-13 | Hochtemperaturschmierstoff für Ketten |
DE202006014282.7 | 2006-09-13 | ||
DE202006019075.9 | 2006-12-15 | ||
DE202006019075U DE202006019075U1 (de) | 2006-09-13 | 2006-12-15 | Hochtemperaturschmierstoff für Ketten |
Publications (2)
Publication Number | Publication Date |
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WO2008031385A2 true WO2008031385A2 (de) | 2008-03-20 |
WO2008031385A3 WO2008031385A3 (de) | 2008-06-26 |
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PCT/DE2007/001401 WO2008031385A2 (de) | 2006-09-13 | 2007-08-07 | Schmierstoff für hochtemperatur-bandpressen |
PCT/DE2007/001566 WO2008031393A2 (de) | 2006-09-13 | 2007-09-01 | Hochtemperaturschmierstoff für ketten |
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PCT/DE2007/001566 WO2008031393A2 (de) | 2006-09-13 | 2007-09-01 | Hochtemperaturschmierstoff für ketten |
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WO (2) | WO2008031385A2 (de) |
Cited By (4)
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CN101987980A (zh) * | 2009-07-30 | 2011-03-23 | 中国石油化工股份有限公司 | 添加剂组合物和柴油组合物及提高生物柴油氧化安定性的方法 |
CN101724489B (zh) * | 2008-10-15 | 2012-10-17 | 中国石油天然气股份有限公司 | 空气压缩机油组合物 |
CN107353965A (zh) * | 2016-12-26 | 2017-11-17 | 中国林业科学研究院林产化学工业研究所 | 一种蓖麻油基极压水性润滑添加剂的制备方法 |
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CN101696369A (zh) * | 2009-10-26 | 2010-04-21 | 益田润石(北京)化工有限公司 | 一种高温链条油组合物 |
CN101812356A (zh) * | 2009-12-18 | 2010-08-25 | 益田润石(北京)化工有限公司 | 一种稠化型高温链条润滑剂组合物 |
CN101812358A (zh) * | 2009-12-18 | 2010-08-25 | 益田润石(北京)化工有限公司 | 一种混合基础油高温链条油组合物 |
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CN114657008A (zh) * | 2021-12-25 | 2022-06-24 | 科特龙流体科技(扬州)有限公司 | 开式齿轮合成润滑剂及其制备方法 |
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- 2007-08-07 WO PCT/DE2007/001401 patent/WO2008031385A2/de active Application Filing
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101724489B (zh) * | 2008-10-15 | 2012-10-17 | 中国石油天然气股份有限公司 | 空气压缩机油组合物 |
CN101987980A (zh) * | 2009-07-30 | 2011-03-23 | 中国石油化工股份有限公司 | 添加剂组合物和柴油组合物及提高生物柴油氧化安定性的方法 |
CN101987980B (zh) * | 2009-07-30 | 2013-03-27 | 中国石油化工股份有限公司 | 添加剂组合物和柴油组合物及提高生物柴油氧化安定性的方法 |
CN101812357A (zh) * | 2009-12-18 | 2010-08-25 | 益田润石(北京)化工有限公司 | 一种压缩机浓缩调理剂 |
CN107353965A (zh) * | 2016-12-26 | 2017-11-17 | 中国林业科学研究院林产化学工业研究所 | 一种蓖麻油基极压水性润滑添加剂的制备方法 |
CN107353965B (zh) * | 2016-12-26 | 2020-08-25 | 中国林业科学研究院林产化学工业研究所 | 一种蓖麻油基极压水性润滑添加剂的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
WO2008031393A3 (de) | 2008-07-10 |
WO2008031393A2 (de) | 2008-03-20 |
DE112007002754A5 (de) | 2009-08-20 |
WO2008031385A3 (de) | 2008-06-26 |
DE202006019075U1 (de) | 2007-04-12 |
DE112007002768A5 (de) | 2009-08-20 |
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