WO2008017723A1 - Temperbares solar control schichtsystem und verfahren zu seiner herstellung - Google Patents
Temperbares solar control schichtsystem und verfahren zu seiner herstellung Download PDFInfo
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- WO2008017723A1 WO2008017723A1 PCT/EP2007/058328 EP2007058328W WO2008017723A1 WO 2008017723 A1 WO2008017723 A1 WO 2008017723A1 EP 2007058328 W EP2007058328 W EP 2007058328W WO 2008017723 A1 WO2008017723 A1 WO 2008017723A1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/0641—Nitrides
- C23C14/0652—Silicon nitride
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3652—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3694—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer having a composition gradient through its thickness
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/0641—Nitrides
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/0676—Oxynitrides
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
- C23C28/048—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material with layers graded in composition or physical properties
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
- C23C28/322—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
- C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/36—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including layers graded in composition or physical properties
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/90—Other aspects of coatings
- C03C2217/91—Coatings containing at least one layer having a composition gradient through its thickness
Definitions
- the invention relates to a temperable solar control
- Such layer systems applied to glass by vacuum coating, are mainly used in window and facade design architecture and in the automotive industry. In both applications, the coating systems must be chemically resistant and mechanically stable, with standardized tests for the comparative assessment of these properties, such as boiling in 5% hydrochloric acid and various abrasion tests.
- the layer systems must have a high degree of transmission of visible light (transmission), preferably transmission values of about 75% to 80%, and a high degree of reflectivity for radiation in the wavelength range of a few ⁇ m, the so-called near-infrared region .
- transmission preferably transmission values of about 75% to 80%
- reflectivity for radiation in the wavelength range of a few ⁇ m, the so-called near-infrared region .
- Another essential characteristic of the glass-applied solar control layer system concerned is the possibility of heat treatment, such as, for example, in tempering for the production of architectural safety glass and the vehicle industry or in the shaping of glass used for windshields. Since it is necessary in various applications to carry out the coating before the heat treatment for the cost-effective production and achievement of homogeneous layers, the layer systems must have mechanical, chemical and optical properties which are different for different heat treatments with different temperature and time regimes depending on the application not or not significantly worsen.
- No. 6,159,607 describes a layer system which substantially meets these requirements. Thereafter, a metal layer of nickel or an alloy thereof, which has the required reflection properties for the infrared radiation, covered by a stoichiometric silicon nitride layer (Si 3 N 4 ), which in turn makes the layer system mechanically and chemically resistant.
- the nickel-containing metal layer has no deterioration of the emissivity due to the heat treatment.
- diffusion processes in particular of the nitrogen from the silicon nitride layer into the metal layer and the nickel in the reverse direction, take place.
- the nitriding of the reflective metal layer reduces the described diffusion processes in the layer system, in particular of the nitrogen, and thus its color shifts, at least within the framework of the described heat treatments of 10 minutes at 625 ° C.
- a comparison serves a layer system which comprises the same, but nitride-free metal layer and was subjected to the same heat treatment.
- the nitriding of the metal is accompanied by a deterioration in the reflection properties, especially in the infrared range.
- the reduced resistance can be compensated for by modifying the silicon nitride layers, in any case this in turn involves a change in the optical properties, so that a compromise between the color shift and the resistance can be found.
- the temperable, visible light reflecting and absorbing layer system for coating dielectric substrates SO contains on the substrate SO in this order at least one transparent, high refractive dielectric layer S2, a functional metallic reflection and absorption layer S4 and a transparent, high refractive dielectric layer S6.
- the solar control layer system according to the invention makes it possible to adjust the reflection color and the transmission.
- the refractive index of at least one of the layers S2 and S6 in light of the wavelength 550 nm is between 2.0 and 2.5.
- the layer S2 consists of an oxide or nitride of a metal, a semiconductor or a semiconductor alloy.
- a further embodiment of the invention provides that the layer S6 contains silicon.
- the layer system according to the invention can be designed so that at least one of the layers S2 and S6 consists of at least two partial layers of different materials.
- At least one of the layers S2 and S6 contains an oxide or nitride of a metal, a semiconductor or a semiconductor alloy.
- a further embodiment of the invention provides that the Layer S6 contains silicon.
- At least one of the layers S2 and S6 contains SnO2 and Si3N4.
- the layer S4 consists of chromium or a chromium compound, for example CrNx.
- the layer S4 consists of titanium or a titanium compound, for example TiNx.
- the layer S4 consists of NiCr or a NiCr compound.
- a transparent, medium to low-refractive dielectric barrier and / or adhesive layer S1 is arranged between the substrate SO and the layer S2.
- the refractive index of the layer S1 with light of wavelength 550 nm is between 1.60 and 1.75.
- a transparent, medium to low-refractive dielectric barrier and / or adhesive layer S7 is arranged on the layer S6.
- the refractive index of the layer S7 at light of wavelength 550 nm is between 1.60 and 1.85.
- At least one of the layers S1 and S7 contains an oxynitride of a metal, of a semiconductor or of a semiconductor alloy.
- a blocking layer S3 is inserted between the layers S2 and S4.
- At least one of the layers S3 and S5 may contain SiOxNy, substoichiometric NiCrOx or NiCrNx.
- At least one further metallic reflection and absorber layer is provided.
- At least one further metallic reflection and absorber layer contains chromium or titanium.
- At least one further metallic reflection and absorber layer contains nitrogen.
- At least one further metallic reflection and absorber layer is a nitrogen-containing chromium gradient compound, wherein the nitrogen content in at least one edge region of the layer is greatest and decreases inwardly.
- the inventive method for producing one of the type is characterized in that at least one layer by sputtering, preferably DC or MF magnetron sputtering is applied.
- At least one of the layers S1 and S7 is advantageously applied by CVD or plasma-assisted CVD processes.
- At least one of the layers S1 and S7 is preferably applied by reactive magnetron sputtering of silicon or silicon-aluminum alloys in an oxygen- and / or nitrogen-containing atmosphere.
- At least one of the layers S1 and S7 is particularly preferably produced by reactive magnetron sputtering of silicon or silicon-aluminum alloys in oxygen and / or nitrogen oxides. deposited argon atmosphere.
- At least one of the layers S1 and S7 is applied as gradient layers with different stoichiometries by reactive magnetron sputtering of silicon or silicon-aluminum alloys in oxygen and / or nitrogen and / or argon-containing atmospheres.
- the transmission of the layer system can be adjusted.
- CrNx compounds of different thicknesses to achieve the desired transmission and very specific stoichiometries to achieve the temperability, the color shift after annealing can be kept very low.
- CrNx is a good absorber layer.
- Another advantage of using CrNx instead of the typically used NiCr or NiCr compounds (NiCrOx) is the small haze magnification after annealing, which is otherwise due, inter alia, to the diffusion of nickel in the neighboring layers are caused.
- the high-index layer which lies under the absorber layer (sub-strate side) and, depending on the desired reflection color, may be constructed of metal oxide layers instead of Si3N4 alone. Between the oxide layer and the absorber layer then a thin blocking layer is necessary. Due to this possible use With additional coating materials, the cycle times can be significantly reduced for a given coater configuration and target placement.
- the optional layer Sl represents a barrier layer which prevents the diffusion of Na + from the glass substrate into the substrate
- the deposition of the layer Sl removes the water introduced from the glass substrate into the coating installation from the substrate.
- the likewise optional layer S7 with its lower refractive index relative to the usual covering layer S6, represents an antireflection coating which significantly increases the transmission of the coating system in the case of a desired high transmission.
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- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
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- Surface Treatment Of Glass (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007800295701A CN101535193B (zh) | 2006-08-11 | 2007-08-10 | 能回火的日光控制层体系及用于制备该层体系的方法 |
JP2009523303A JP5328650B2 (ja) | 2006-08-11 | 2007-08-10 | 焼入れ可能なソーラーコントロール層系およびその製造方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE102006037912.8 | 2006-08-11 | ||
DE102006037912.8A DE102006037912B4 (de) | 2006-08-11 | 2006-08-11 | Temperbares Solar-Control-Schichtsystem und Verfahren zu seiner Herstellung |
Publications (1)
Publication Number | Publication Date |
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WO2008017723A1 true WO2008017723A1 (de) | 2008-02-14 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/EP2007/058328 WO2008017723A1 (de) | 2006-08-11 | 2007-08-10 | Temperbares solar control schichtsystem und verfahren zu seiner herstellung |
Country Status (4)
Country | Link |
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JP (1) | JP5328650B2 (de) |
CN (1) | CN101535193B (de) |
DE (1) | DE102006037912B4 (de) |
WO (1) | WO2008017723A1 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018129135A1 (en) | 2017-01-05 | 2018-07-12 | Guardian Glass, LLC | Heat treatable coated article having titanium nitride based ir reflecting layer(s) |
FR3118440A1 (fr) | 2020-12-31 | 2022-07-01 | Saint-Gobain Glass France | Vitrage antisolaire comprenant une couche mince à base de nitrure de titane et une couche de nitrure de silicium sous-stœchiométriques en azote. |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9796619B2 (en) * | 2010-09-03 | 2017-10-24 | Guardian Glass, LLC | Temperable three layer antirefrlective coating, coated article including temperable three layer antirefrlective coating, and/or method of making the same |
DE102012109691B4 (de) * | 2012-10-11 | 2014-08-07 | Von Ardenne Anlagentechnik Gmbh | Solarabsorber-Schichtsystem mit Gradientenschicht und Verfahren zu dessen Herstellung |
FR3004710B1 (fr) * | 2013-04-19 | 2017-01-27 | Saint Gobain | Vitrage de controle solaire comprenant deux couches metalliques a base de nickel |
DE102014002965A1 (de) * | 2013-07-30 | 2015-02-05 | Leybold Optics Gmbh | Schichtsystem eines transparenten Substrats sowie Verfahren zur Herstellung eines Schichtsystems |
KR102075076B1 (ko) * | 2017-02-22 | 2020-02-07 | (주)엘지하우시스 | 저투과 및 저반사 코팅유리 |
CN106995281A (zh) * | 2017-04-01 | 2017-08-01 | 佛山市翔硕宇玻璃科技有限公司 | 一种可钢化抗氧化耐腐蚀彩色镀膜玻璃 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018129135A1 (en) | 2017-01-05 | 2018-07-12 | Guardian Glass, LLC | Heat treatable coated article having titanium nitride based ir reflecting layer(s) |
EP3565791B1 (de) * | 2017-01-05 | 2022-09-21 | Guardian Glass, LLC | Wärmebehandelbarer beschichteter artikel mit ir-reflexionsschicht(en) auf titannitridbasis |
FR3118440A1 (fr) | 2020-12-31 | 2022-07-01 | Saint-Gobain Glass France | Vitrage antisolaire comprenant une couche mince à base de nitrure de titane et une couche de nitrure de silicium sous-stœchiométriques en azote. |
WO2022144518A1 (fr) | 2020-12-31 | 2022-07-07 | Saint-Gobain Glass France | Vitrage antisolaire comprenant une couche mince a base de nitrure de titane et une couche de nitrure de silicium sous-stoechiometriques en azote |
Also Published As
Publication number | Publication date |
---|---|
CN101535193A (zh) | 2009-09-16 |
DE102006037912B4 (de) | 2017-07-27 |
CN101535193B (zh) | 2012-07-04 |
JP2010500271A (ja) | 2010-01-07 |
DE102006037912A1 (de) | 2008-02-14 |
JP5328650B2 (ja) | 2013-10-30 |
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