WO2007052705A1 - 硬化性シロアリ防除組成物およびシロアリ防除方法 - Google Patents

硬化性シロアリ防除組成物およびシロアリ防除方法 Download PDF

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Publication number
WO2007052705A1
WO2007052705A1 PCT/JP2006/321866 JP2006321866W WO2007052705A1 WO 2007052705 A1 WO2007052705 A1 WO 2007052705A1 JP 2006321866 W JP2006321866 W JP 2006321866W WO 2007052705 A1 WO2007052705 A1 WO 2007052705A1
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WIPO (PCT)
Prior art keywords
termite control
curable
weight
termite
control composition
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Application number
PCT/JP2006/321866
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English (en)
French (fr)
Japanese (ja)
Inventor
Shinji Yoshida
Saburou Yamato
Toyoharu Obata
Tadashi Nakagaki
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Japan Envirochemicals, Ltd.
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Application filed by Japan Envirochemicals, Ltd. filed Critical Japan Envirochemicals, Ltd.
Publication of WO2007052705A1 publication Critical patent/WO2007052705A1/ja

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10Macromolecular compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00Stationary means for catching or killing insects
    • A01M1/20Poisoning, narcotising, or burning insects
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00Stationary means for catching or killing insects
    • A01M1/24Arrangements connected with buildings, doors, windows, or the like
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M29/00Scaring or repelling devices, e.g. bird-scaring apparatus
    • A01M29/12Scaring or repelling devices, e.g. bird-scaring apparatus using odoriferous substances, e.g. aromas, pheromones or chemical agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/12Nitrogen containing compounds organic derivatives of hydrazine
    • C04B24/14Peptides; Proteins; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/72Pest control

Definitions

  • the present invention relates to a curable termite control composition and a termite control method using the same.
  • Patent Document 1 describes a curable termite control composition in which a hydraulic component, a sediment component, and a termite control component are blended and kneaded, and this curable termite control composition is described. For example, it is described that termite is prevented from entering by forming a dense termite control layer by laying it on the foundation of a building.
  • Patent Document 2 describes a termite control method using a granular carrier containing a non-repellent insecticide.
  • Patent Document 1 International Publication No. 2005Z032253 Pamphlet
  • Patent Document 2 JP 2005-154364 A
  • a granular carrier having a large particle diameter of 3 mm to 8 mm or a granular carrier having the above large particle diameter and a longest particle diameter of 1 mm to less than 3 mm A mixture with a granular carrier is used!
  • Patent Document 1 when a gravel component having a particle diameter of 2 mm or more is blended as an earth and sand component, a termite control layer having a small thickness is used to prevent variation in thickness and coating film defects. It becomes difficult to form without causing it.
  • Patent Document 2 an attempt is made to control termites with a layer of granular carrier formed by spreading the granular carrier.
  • the granular carrier with large particle size as described above can physically prevent the penetration of termites when forming a layer, but, for example, a gap between a double foundation (existing building by renovation and an extension building foundation). And the gap between the outer insulation and the foundation joint cannot be formed, and a sufficient ant barrier layer cannot be formed, and the particle size is large for the concrete seam where termites are supposed to enter. There is a problem that it is difficult to treat sufficiently and an effective control effect cannot be obtained.
  • an object of the present invention is to provide a curable termite control composition that has an excellent termite control effect and can form a uniform layer with thickness and strength when cured, and a termite using the same. It is to provide a method for controlling ants.
  • a curable termite comprising a hydraulic component and an earth and sand component, wherein the weight ratio of the earth and sand component having a particle diameter of 1.5 mm or less to the total amount of the earth and sand component is 95% by weight or more.
  • the earth / sand component contains earth / sand having a particle size of 0.15 mm or more and lmm or less, and Z or earth / sand having a particle diameter of less than 0.15 mm, as described in (1) or (2) above Curable termite control composition,
  • the termite control component is prepared as a microencapsulating agent.
  • the termite control component is at least one selected from the group consisting of neonicotinoid compounds, pyrethroid compounds, and ferrovirazole compounds, (4) or (5 ) Curable termite control composition according to claim 1,
  • the compression strength of the cured product obtained by curing the kneaded product of the curable termite control composition according to any one of (1) to (7) and water is 1 to 20 NZmm 2.
  • the curable termite control composition according to any one of (1) to (8) is sprayed or injected into a site for controlling damage caused by termites.
  • Termite control characterized in that it has a solidifying step in which the hardened termite control composition sprayed or injected is solidified by spraying or injection of a hardening liquid or by moisture in air or soil.
  • a termite control method comprising: a molding step; and an embedding step of embedding the molded body obtained in the molding step in a site for controlling damage caused by termites.
  • the curable termite control composition according to any one of the above (1) to (8) is sprayed or injected into a site for controlling damage caused by termites, and the spraying / injecting step and the spraying / injecting step.
  • the kneaded mixture of the curable termite control composition according to any one of the above (1) to (8) and a curing liquid is applied to a region where the curable termite control composition is sprayed or injected.
  • Termite control method characterized by having a coating process of 1.
  • a curable liquid spraying process in which a curable liquid is sprayed on a site that controls damage caused by termites, and the regions of the curable liquid sprayed process in which the curable liquid is sprayed are shifted in the above (1) to (8).
  • a termite control method comprising: a second coating step of applying a kneaded product of the curable termite control composition according to claim 1 and a curing liquid,
  • the curable termite control composition of the present invention since sand having a specific particle size is used as the earth and sand component, it is a uniform and small-sized white paper having a small thickness when cured. A protective layer can be formed.
  • the termite control layer thus obtained can sufficiently exert the termite control effect of the termite control component, and even when the termite control component is not included, the termite control layer has an appropriate hardness. Therefore, it is possible to cover the termites that have eaten them to penetrate the termite control layer.
  • the hydraulic component in the curable termite control composition is often a strong alkali component. Therefore, when a termite eats the termite control layer, a large amount of the strong alkali component is taken into the termite body.
  • the termite body environment (acidity) is destroyed, and termites can be killed. That is, as a result, the infestation of termites by termites can be highly suppressed.
  • FIG. 1 is a cross-sectional view showing an example of a region to be treated of a curable termite control composition.
  • FIG. 2 is a cross-sectional view showing another example of the area to be treated of the curable termite control composition.
  • FIG. 3 is a cross-sectional view showing still another example of the area to be treated of the curable termite control composition.
  • FIG. 4 is a perspective view showing a test apparatus used for the penetration test.
  • FIG. 5 is a perspective view showing a test apparatus used for a scooping test.
  • FIG. 6 shows the test apparatus used in the construction test 3, (a) is a perspective view of the entire test apparatus, and (b) is a left side view of the concrete block 30.
  • FIG. 7 is a perspective view showing a test apparatus used in construction test 4.
  • FIG. 8 is a perspective view showing the bonding surface of the concrete block 40 used in the construction test 4.
  • FIG. 9 is a perspective view showing an adhesive surface of the concrete block 40 after storage in the construction test 5.
  • FIG. 10 is a cross-sectional view showing a sprayed state of the curable termite control composition in construction test 25.
  • FIG. 11 is a cross-sectional view showing a sprayed state of the curable termite control composition in construction test 26.
  • the first curable termite control composition of the present invention comprises a hydraulic component and an earth and sand component, and a weight ratio force of an earth and sand component having a particle size of 1.5 mm or less with respect to the total amount of the earth and sand component. It is characterized by being over% by volume.
  • the second curable termite control composition of the present invention contains arabesque and termite control components. That is, it contains a hydraulic component and an earth and sand component, the weight ratio of the earth and sand component having a particle size of 1.5 mm or less to the total amount of the earth and sand component is 95% by weight or more, and contains a termite control component. ing.
  • the termites to be controlled by the curable termite control composition are not particularly limited except that they are insects belonging to the order of the termites, but specifically, for example, Examples include those belonging to the family of termites termites such as formosanus, yamaton mouth? (Reticulitermessperatus), and those belonging to the family of white termites such as the American ants termites and scallop termites.
  • the hydraulic component is an essential component of the first and second curable termite control compositions.
  • the hydraulic component is not particularly limited, except that the earth and sand component can be dispersed, or the earth and sand component and the termite control component can be dispersed to form a curable termite control composition. Or various materials used as concrete forming materials A hydraulic component is mentioned.
  • a pneumatic cement for example, a pneumatic simple cement, a pneumatic mixed cement, etc.
  • a hydraulic cement for example, a hydraulic simple cement, a hydraulic mixed comment, etc.
  • air-solid simple cement examples include secocto such as baked gypsum and anhydrous gypsum plaster, and lime such as slaked lime and dolomite plaster.
  • pneumatic mixed cement examples include magnesia cement.
  • Examples of the hydraulic simple cement include Portland cements such as Portland cement and early-strength Portland cement, and alumina cements such as alumina cement and lime alumina cement.
  • Examples of hydraulic mixed comments include lime-mixed cements such as lime slag cement and lime volcanic ash cement, for example, mixed Portland cements such as blast furnace cement, siri-force cement, pozzolanic cement and fly ash cement, such as high sulfate.
  • Examples include slag cements.
  • the earth and sand component is an essential component of the first and second curable termite control compositions, and is 95% by weight or more, preferably 98% by weight or more of the total amount of the earth and sand component. Sediment component of 5mm or less. More preferably, all of the earth and sand components are earth and sand components having a particle diameter of 1.5 mm or less.
  • Examples of the earth and sand constituting the earth and sand component having a particle size of 1.5 mm or less include sand (coarse sand, fine sand), silt (fine sand), and clay. These earth and sand can be used alone or in combination of two or more.
  • the earth and sand is based on the content of sand, silt and clay, for example, sand and earth (for example, loamy sand and sand), loam (for example, loam, sand and loam, fine sandy loam), Pyongyang
  • the soil is classified into a loam soil, a sandy loam soil, a fine sandy loam soil, and a dredged soil (for example, a light soil, a sandy soil, a fine sandy soil, and a heavy sand soil).
  • the classification of these sediments is based on the soil classification of the International Soil Society Law.
  • the earth and sand may belong to only one category of the earth and sand, or may belong to two or more categories.
  • the earth and sand for example, sand (for example, sand, river sand, sea sand, beach sand, mountain sand, etc.), earth (for example, pure sand formed by granite weathering) ,
  • sand for example, sand, river sand, sea sand, beach sand, mountain sand, etc.
  • earth for example, pure sand formed by granite weathering
  • volcanic ash soil such as red soil, black soil, shirasu, etc., for example, sedimentary soil of rivers, etc.
  • rhyolite metamorphic rocks
  • metamorphic rocks such as quartzite and crystalline limestone
  • sedimentary rocks such as mudstone and sandstone
  • the sands are generally classified as sandy soil, true sandy soils are generally classified as loamy sandy soils or loams, and volcanic ash soils are generally classified as loamy soils or dredged soils.
  • sandy soils such as loamy sandy soil, loams such as loam soil, sandy loam soil, fine sandy loam soil, and specific materials are listed.
  • a pure sand soil and a silica sand are mentioned.
  • the earth and sand component may be composed of waste crushed material and the above earth and sand, which may be composed of waste crushed material.
  • Waste includes artificial and natural waste.
  • Artificial objects include, for example, artificial structures or structures (eg bricks, straw, concrete building materials, mortar building materials, concrete blocks, concrete roads, asphalt roads, window glass, etc.), daily necessities (flower pots, cups, pottery, etc.) Etc.).
  • natural products include shells (such as clams, swordfish, roe, madari, and scallop shells), and bones (such as sea bream, pigs, and scallop bones).
  • the waste may be crushed to the same particle size as the earth and sand. Moreover, the said waste can be used individually or in combination of 2 or more types.
  • the earth and sand component preferably contains 80% by weight or more of earth and sand having a particle diameter of 1 mm or less.
  • the earth and sand component preferably contains 80% by weight or more, more preferably 95% by weight or more of earth and sand having a particle size of 0.25 mm or less.
  • the earth and sand component contains earth and sand having a particle size of lmm or less in a proportion of 80% by weight or more, preferably, when earth or sand having a particle size of 0.25 mm or less is contained in a proportion of 80% by weight or more,
  • the content ratio of earth and sand components having a particle size exceeding lmm is relatively decreased, and preferably the content ratio of earth and sand components exceeding 0.25 mm is relatively decreased to harden the curable termite control composition.
  • the density of the termite control layer obtained in this way can be further improved.
  • the earth and sand component more preferably contains earth and sand having a particle size of 0.15 mm or more and 1 mm or less and Z or earth and sand having a particle size of less than 0.15 mm, and more preferably, the particle size is 0. It contains earth and sand having a particle size of 15 mm or more and 0.25 mm or less and earth and sand having a particle size of less than 0.15 mm in a weight ratio of 5:95 to 20:80.
  • the above-mentioned earth and sand component contains either one or both of earth and sand having a particle size of 0.15 mm or more and lmm or less and earth and sand having a particle size of less than 0.15 mm, preferably the particle diameter is 0.15 mm or more and 0.25 mm.
  • termite control obtained by curing the curable termite control composition The denseness of the layer can be further improved.
  • the earth and sand component contains both earth and sand having a particle diameter of 0.1 to 15 mm and earth and sand having a particle diameter of less than 0.15 mm
  • the earth and sand having a particle diameter of 0.15 to 1 mm and The weight ratio with the earth and sand having a particle size of less than 0.15 mm is preferably 99: 1 to 1:99, more preferably 96: 4 to 5:95.
  • the termite control component is an optional component of the first curable termite control composition and an essential component of the second termite control composition.
  • Examples of this termite control component include neonicotinoid compounds, pyrethroid compounds, organochlorine compounds, organophosphorus compounds, strong rubamate compounds, pyrrole compounds, fluorbiazole compounds, oxadiazine compounds, semicarbazones. System compounds, plants, processed products or derivatives thereof.
  • the above-described termite control components may be used alone or in combination of two or more.
  • neonicotinoid compounds More preferably, it is a neonicotinoid compound and Z or a pyrethroid compound, and more preferably a neodystinoid compound and Z or a pyrethroid compound. It is a nicotinoid compound.
  • Examples of neonicotinoid compounds include (E) -1 (2 chloro-1,3 thiazol-5-ylmethyl) -3-methyl-2-trologazine (generic name: clothiazine). ⁇ N-Acetyl-N— (2-Clo-Thiazole-5-yl) methyl-N, -Methyl-N "-troguazine, N- (2-Clo-Thiazole-5-yl) methyl-N-methoxycal Bor N, 1-methyl 1-N "-trologazine, 1— (6—Black 1-Pyridylmethyl) — N-Tromidazoline 1—Iridenamine (generic name: Imidacloprid), 3— (2-Black thiazole) 5—ylmethyl) -5- [1, 3, 5] oxadiazinane-4-ylindene 1 thoramine (generic name: thiamethoxam), (RS) 1-methinol 1 2
  • neonicotinoid compounds may be used alone or in combination of two or more. Moreover, clothiazine is preferable.
  • pyrethroid compounds include allethrin, permethrin, tralomethrin, bifentone, acrinatrin, alpha cypermethrin, sifluthrin, siphenothrin, praretrin, etofenprox, silafluophene, fenvalerate, and the like. Examples include noremethrin, bifenthrin, siphenothrin, etofenprox, and shirafunore.
  • organic chlorine-based compound examples include Kelsen.
  • organophosphorus compounds include phoxime, pyridafenthione, fe-trothion (MEP), tetrachlorvinphos, diclofenthion, propetanephos, and the like. Mouth poxle and the like.
  • Examples of the pyrrole compound include chlorfenavir.
  • Examples of the ferrovirazole-based compound include fiprole.
  • Examples of the oxaziazine compound include indoxacarp.
  • Examples of the semicarbazone compound include ⁇ - ( ⁇ , a, a-trifluoro-m-toluoyl) p trinitryl 41- (p trifluoromethoxyphenol) semicarbazone.
  • plants or treated products or derivatives thereof include those described in JP 2002-307406, JP 2003-252708, and JP 2005-74776.
  • ite control component is not particularly limited as to its formulation form, and is prepared, for example, as a microencapsulating agent, powder, granule, liquid, flowable, or emulsion.
  • a termite control component as a microencapsulating agent.
  • a termite control component as a microencapsulating agent, for example, interfacial polymerization method, in situ polymerization method (interfacial reaction method), coacervation method, submerged drying method, melt dispersion cooling method, submerged A cured film method, a coating method (in-air suspension method), a spray drying method, an electrostatic coalescence method, a vacuum deposition method, and the like can be used.
  • interfacial polymerization method in situ polymerization method (interfacial reaction method), coacervation method, submerged drying method, melt dispersion cooling method, submerged A cured film method, a coating method (in-air suspension method), a spray drying method, an electrostatic coalescence method, a vacuum deposition method, and the like
  • interfacial polymerization method in situ polymerization method
  • coacervation method submerged drying method
  • melt dispersion cooling method submerged A cured film method
  • a coating method in-air suspension method
  • spray drying method an electrostatic
  • the termite control component is, for example, a hardly soluble neonicotinoid compound, for example, the method described in JP-A-2000-247821 can be used.
  • the microencapsulating agent preferably has an average particle diameter of 6 to: LOO ⁇ m, preferably 10 to 50 ⁇ m.
  • the particle size and average particle size of the microencapsulating agent can be determined, for example, by measuring the particle size and its distribution state (particle size distribution) using a commercially available laser diffraction Z-scattering particle size distribution device. Can be sought.
  • the termite control component is prepared as a microencapsulating agent, the above-described hydraulic component, the earth and sand component, and in addition, if necessary, a dispersant, a surfactant, A hardenable termite control composition can be obtained by appropriately blending, mixing and dispersing other additives such as an anti-settling agent.
  • the termite control component is dissolved and dispersed in an appropriate solvent, and is then powdered or granulated by means such as spray drying. The method can be used.
  • the average particle diameter of the powder or granule is preferably adjusted to 6-1500 ⁇ m, preferably 20-500 ⁇ m.
  • the particle size and average particle size of the powder or granule can be determined, for example, in the same manner as in the case of the microencapsulating agent.
  • the termite control component is prepared as a powder or a granule
  • the above-mentioned hydraulic component and the earth and sand component are blended in a state where the obtained powder or granule is dried.
  • Curing termite control by mixing, dispersing, and mixing other additives such as hardening accelerators (including surfactants), concrete reinforcing agents such as polypropylene, polyethylene, and aramide resin.
  • a composition can be obtained.
  • the termite control component is dissolved or suspended in an appropriate solvent (water or organic solvent) with a surfactant or emulsifier as necessary. What is necessary is just to make it turbid or emulsified.
  • the termite control component When the termite control component is prepared as a solution, flowable agent or emulsion, the resulting solution, flowable agent or emulsion and the above earth and sand component are blended, mixed and dispersed, and then the resulting mixture is dried. In such a state, the above-mentioned hydraulic component and, if necessary, other additives such as a dispersant, a surfactant and an anti-settling agent are appropriately blended, mixed and dispersed, thereby controlling curable termites. A composition can be obtained.
  • the content ratio of the hydraulic component in the first and second curable termite control compositions is not particularly limited, but is preferably 1 to 99% by weight, more preferably 1 -80% by weight, more preferably 5-30% by weight.
  • the content ratio of the earth and sand component in the first curable termite control composition is particularly limited. However, it is preferably 1 to 99% by weight, more preferably 20 to 99% by weight, and still more preferably 70 to 95% by weight.
  • the content ratio of the earth and sand component in the second curable termite control composition is not particularly limited, but is preferably 0.9 to 99% by weight, and more preferably 19.9 to 99% by weight. %, More preferably 69.9 to 95% by weight.
  • the content ratio of the earth and sand component in the first and second curable termite control compositions is preferably 1 to 20000 parts by weight with respect to 100 parts by weight of the hydraulic component. More preferably, 10 to: LOOOO parts by weight, and still more preferably 25 to 5000 parts by weight.
  • the content ratio of the termite control component in the curable termite control composition is not particularly limited, but in the first curable termite control composition, it is preferably 0 to 50% by weight, and more preferably. Is 0 to: LO wt%. Further, in the second curable Shiroa Li control composition, preferably, from 0.00001 to 50 weight 0/0, more preferably 0.001 to 10 wt%.
  • the content ratio of the earth and sand component in the first curable termite control composition is preferably 10000 parts by weight or less with respect to 100 parts by weight of the hydraulic component, more preferably 10-: LOOOO parts by weight, more preferably 25-5000 parts by weight.
  • the content ratio of the earth and sand component in the second curable termite control composition is preferably 1 to 20000 parts by weight, more preferably 10 to 100 parts by weight with respect to 100 parts by weight of the hydraulic component.
  • the amount is 10,000 parts by weight, and more preferably 25 to 5000 parts by weight.
  • the content of other additives in the first and second curable termite control compositions is not particularly limited, but is preferably 0 to 20% by weight, more preferably 0 to : LO weight%.
  • the first and second curable termite control compositions are kneaded with water and cured to obtain a cured product obtained from JIS R 5201 “Cement physical test method” or
  • the compression strength of the cured product obtained by curing the kneaded product of the curable termite control composition and water satisfies the above range
  • the hardness of the cured product is, for example, that of concrete.
  • termites While termites are not hard enough to damage, termites that are not soft enough to penetrate the termites easily while moving straight, such as in normal soil, are suitable for damage. It will have resistance. For this reason, termites that harm the cured product take in a large amount of the composition in the harmed area into the body, resulting in a life-sustaining problem. Moreover, this will cause termites from falling to death, or termites that repel the cured product will appear prominently.
  • Examples of the area to be treated of the curable termite control composition include sites that control termite damage. Specifically, for example, there are sites that need to control termite damage, such as sites where termites may invade (sites where termite damage is expected) and sites where termite damage is actually occurring. Can be mentioned.
  • control of damage caused by termites means prevention and extermination. That is, the term “control” of damage caused by termites includes the case of extermination of termites. Hereinafter, these may be simply referred to as “controlling damage caused by termites”.
  • parts that control termite damage include, for example, basic structures, superstructures, and underground structures in buildings (buildings; that is, houses, warehouses, gates, fences, and their ancillary equipment).
  • buildings buildings; that is, houses, warehouses, gates, fences, and their ancillary equipment.
  • underground buried objects as ancillary equipment of buildings for example, ground surfaces, for example, termite inhabiting areas.
  • Examples of the basic structure of the building include foundations (independent foundations, cloth foundations, solid foundations, etc.), grounding (cobblestones, quarry stones, sands, etc.), foundation beams, ground Examples include medium beams, foundation stones, foundations (wooden foundations for placing pillars, etc.), pillars, floor bundles, large pulls, rooting, joists, and foundation heat insulation materials.
  • Examples of superstructures of buildings include pillars, floors (upper floors, lower floors; for example, floor slabs, floorboards, underfloor insulation, etc.), wall parts (outer walls, inner walls, partition walls, etc.), and heat insulation. Wood (outer wall insulation, inner wall insulation, etc.), ceiling, beam (girder), window frame, fence, eaves, eaves, roofboard, wall, wall fence (wall fence surface, dog runner, pasted stone, etc. ) And the like.
  • Examples of the underground structure part of the building include, for example, a pillar, a floor part, and an outer part of the basement part of the building.
  • Examples of underground structures as ancillary equipment for buildings (buildings) include surroundings of cables (electric cable, optical fiber cable, etc.) and piping (water pipes, gas pipes, etc.). Can be mentioned.
  • ground surface examples include the ground surface in the vicinity of the foundation structure outside the building (such as the outer periphery of the building and the dog-running part of the wall fence), and the ground surface in the building (lower floor).
  • termite habitat generation areas include termite nests, ant tracts, and injuries.
  • Examples of sites where termites may intrude include cracks (cracks, etc.), gaps, drills, etc. in buildings (the above-mentioned basic structure, upper structure, and underground structure) and underground structures. For example, a portion perforated by.
  • the amount of the curable termite control composition may be appropriately set according to the area to be treated.
  • the first and second curable termite control compositions are directly applied to a site (specifically, the ground surface, etc.) that controls termite damage.
  • a site specifically, the ground surface, etc.
  • the thickness of the layer that also has a curable termite control composition force is 0.1 to 5 cm, preferably over the entire area to which the damage caused by termites is controlled or water is sprayed. Applying (spreading, etc.) so as to be 0.1-3 cm, for example, curable termite control composition force, layer thickness force 0.25 mm-3 cm, width force 1-30 cm, preferably 3-20 cm Apply (spray etc.) so that
  • the kneaded mixture of the first and second curable termite control compositions and water or a termite control solution containing a termite control component is used to control the damage caused by termites (specifically In particular, when applied to building foundations, more specifically pillars, insulation, etc.) (specifically, coating, injection, etc.), for example, damage caused by termites
  • the thickness of the layer, which is the above-mentioned kneaded product force, on the surface of the part to be protected is 0.25mn! Apply (coating, pouring) so that it is ⁇ 3cm.
  • the kneaded material is, for example, the entire surface of the basic rising portion You may apply to.
  • the length in the height direction from the boundary between the foundation portion and the wall surface is l to 40 cm, preferably 1 to 2 Ocm, and the thickness Apply the above kneaded product so that the force is 0.25 mm to 5 cm, preferably 0.25 mm to 3 cm, more preferably 0.25 mm to 1 cm, and the weight per unit area is 200 gZm 2 to 60 kgZm 2 ( Coating and pouring).
  • the curable termite control composition can be applied to the above-mentioned treated area by various methods.
  • the first termite control method of the present invention includes a kneading step of kneading the first or second curable termite control composition and a curable liquid, and the kneaded material obtained in the kneading step controls damage caused by termites. And a curing step in which it is applied to the site to be cured and cured.
  • the first or second curable termite control composition and the curable liquid are combined and kneaded to obtain a kneaded product.
  • the curable liquid is a liquid used when the first or second curable termite control composition is cured.
  • a termite control solution containing a termite control component examples thereof include a liquid containing a polymer.
  • termite control component of the termite control solution (hereinafter simply referred to as “termite control solution”), which contains a termite control component, is an optional component of the first curable termite control composition or the above
  • termite control component exemplified as the essential component of the second termite control composition may be mentioned.
  • Examples of the solvent or dispersion medium for the termite control solution include water, methanol, ethanol, propylene glycol, and the like.
  • a kneaded product with the first or second curable polymer or a liquid containing the polymer itself is applied to a site to prevent damage caused by termites.
  • EVA ethylene vinyl alcohol
  • acrylic resin For example, acrylic acid ester and methacrylic acid ester.
  • SBR styrene-butadiene rubber
  • liquid solvent or dispersion containing the polymer examples include water.
  • the liquid containing the polymer is specifically supplied as a dispersion, suspension, or emulsion containing the polymer, and more specifically, for example, as a resin emulsion or rubber latex.
  • the mixing ratio of the first or second curable termite control composition and the curing liquid may be within a range in which the kneaded product is cured to form a termite control mortar. Therefore, although not particularly limited, for example, with respect to water, solvent or dispersion contained in the curable liquid, the blending amount is preferably based on 100 parts by weight of the first or second curable termite control composition. Is 15 to 65 parts by weight, more preferably 15 to 45 parts by weight, and still more preferably 15 to 35 parts by weight.
  • the first or second curable termite-controlling composition and the curable liquid may be kneaded, for example, with a mixer or by hand.
  • the kneading method include a method in which a curable liquid is put in a container in advance and the curable termite control composition is gradually added while stirring the solution.
  • the kneaded product obtained in the kneading step is applied to a site that prevents damage caused by, for example, termites, and then allowed to stand in a state where contact with the surface of the applied kneaded product is cut off. Thereafter, the kneaded product is cured by being left still or by absorbing moisture in the air or soil. As a result, termite control mortar is formed.
  • Specific examples of the application of the kneaded product include coating, spreading, spraying, pouring, and embedding of the kneaded product.
  • the specific method of the construction is not particularly limited, for example, a method of applying the kneaded material with a tool such as a spatula or a spatula, a machine device such as a sprayer, a sprayer, a pump, etc. Spraying the above-mentioned kneaded material etc. manually, spraying the above-mentioned kneaded material with a spray gun, spraying the above-mentioned kneaded material, etc. .
  • the above kneaded material or the like can be sprayed from the tip of the hose in a certain amount, so that, for example, particularly when applying a termite control composition under the floor of an existing house.
  • the working efficiency can be increased.
  • spray gun when a spray gun is used, spray coating of the above kneaded material or the like can be performed, and the work force can be applied with a uniform thickness.
  • work efficiency can be improved even in construction where the construction area is extremely narrow, such as a double foundation.
  • the curable termite control composition used in the kneading step of the first termite control method described above does not contain a termite control component (first curable termite control composition) and may be a termite control. It contains a component (second curable termite control composition).
  • the termite control composition does not contain a termite control component
  • the curing liquid used in the kneading step is a termite control liquid
  • a cured product obtained by curing the kneaded product is contained in the termite-control mortar, so that the termite-controlling effect can be surely exhibited.
  • the termite-controlling composition does not contain a termite-controlling component and the curing liquid is a liquid containing water or a polymer, a cured product (termite-controlling mortar) is used.
  • the termites that damage the cured product exhibit a termite control effect by incorporating a large amount of the cured product in the affected area as described above. be able to.
  • the construction area when the kneaded product obtained in the kneading step is applied, sprayed, or sprayed is a site that controls (including extermination) damage caused by termites.
  • the kneaded product is a region suitable for coating, spreading, or spraying.
  • the construction area preferably, for example, the surface of the foundation structure part, the upper structure part and the underground structure part of the building, the cracked part, the gap part and the perforated part, for example, the surface (outer peripheral surface) in the underground buried object, Examples include cracks and gaps.
  • the construction area when the kneaded product obtained in the kneading step is poured is a site for controlling damage (including extermination) due to termites.
  • the region is suitable for injecting the kneaded material.
  • the construction (injection) area is preferably, for example, a cracked part, a gap part or a perforated part in a foundation structure part, a superstructure part or an underground structure part of a building, for example, a cracked part in an underground buried object and Examples include gaps such as termite nests, ant trails, and injured parts.
  • the second termite control method of the present invention includes a spraying / injecting step of spraying or injecting the first or second curable termite control composition into a site for controlling damage caused by termites, and the above-mentioned spraying / injecting process. And a solidifying process in which the curable termite control composition sprayed or injected in the process is solidified by dispersing or injecting a hardening liquid, or by moisture in air or soil.
  • the first or second curable termite-controlling composition is sprayed or injected into a site where damage caused by termites is controlled.
  • the method of spraying or injecting is not particularly limited as long as the first or second curable termite control composition is sprayed or injected into a site that controls termite damage.
  • the first or second curable termite control agent is sprayed or injected using a container such as an oil bottle, or a nebulizer, to the part to control the damage caused by termites.
  • Examples of the method include spraying or injecting by spraying.
  • the solidification step moisture is supplied to the first or second curable termite control composition sprayed or injected in the termite control composition spraying / injection step by spraying or injecting a hardening liquid. Or supply air or soil moisture from the air or soil.
  • the first or second curable termite control composition is solidified and cured to form a termite control mortar.
  • Examples of the curable liquid include those similar to those exemplified in the first termite control method.
  • the amount of water supplied by spraying or injecting (for example, watering) of the curable liquid may be the first or the second. 2 curable termite control compositions can cure to form termite control mortar.
  • the blending ratio is 100 parts by weight with respect to 100 parts by weight of the first or second curable termite control composition.
  • the amount is preferably 15 to 65 parts by weight, more preferably 15 to 45 parts by weight, and still more preferably 15 to 35 parts by weight.
  • an appropriate method is used, for example, water is sprayed once or water is divided into a plurality of times.
  • the curable termite control composition sprayed or injected in the spraying step of the second termite control method described above does not contain a termite control component (first curable termite control composition) It may be a material containing a termite control component (second curable termite control composition).
  • the termite-controlling composition does not contain a termite-controlling component
  • the termite-controlling composition is used when the curing solution sprayed or injected in the above-mentioned spraying step is a termite-controlling solution.
  • a cured product (termite-controlling mortar) obtained by curing contains a termite-controlling component, so that the termite-controlling effect can be reliably exhibited.
  • the termite-controlling composition does not contain a termite-controlling component, and it is a liquid that contains water or polymer!
  • the termite-controlling component is not contained in the cured product (termite-controlling mortar) obtained by curing the termite-controlling composition.
  • the termite control effect can be exerted.
  • the application area when the first or second curable termite control composition is sprayed is a portion for controlling (including extermination) damage caused by termites.
  • the region is suitable for spraying the first or second curable termite control composition.
  • the construction (spreading) area is preferably, for example, a surface of a building foundation structure, an upper structure, or an underground structure, a cracked part, a gap part, or a perforated part, for example, a surface of an underground buried object ( Outer peripheral surface), cracked part and gap part.
  • the construction area in the case of injecting the first or second curable termite control composition is a site that controls (including extermination) damage caused by termites.
  • the region is suitable for injecting the first or second curable termite control composition.
  • the construction (injection) area is preferably, for example, a cracked part, a gap part or a perforated part in a foundation structure part, an upper structure part or an underground structure part of a building, for example, a cracked part in an underground structure.
  • a gap part for example, a termite nest, an ant road, a harm part, etc., can be mentioned.
  • the first or second curable termite control composition and the curable liquid are combined and kneaded to obtain a kneaded product.
  • Examples of the curable liquid include those similar to those exemplified in the first termite control method.
  • the mixing ratio of the first or second curable termite control composition and the curable liquid is as follows.
  • the setting should be the same as in the case of the serial control method.
  • the kneading of the first or second curable termite control composition and the curable liquid may be carried out in the same manner as in the first termite control method.
  • the kneaded product obtained in the kneading step is molded into a predetermined shape and fixed. Make it. Thereby, the mortar of a predetermined shape is obtained.
  • a method of pouring the kneaded material into a plastic container or a wooden frame to solidify it and taking it out is used.
  • the kneaded product can be molded and solidified according to the shape of the portion actually damaged by termites or the shape of the portion drilled by a drill or the like.
  • the molded body obtained in the molding and solidification process may be damaged by termites, particularly the parts that are actually damaged by termites (damaged parts).
  • Implant and fix in the site for example, an adhesive, a string, a metal fitting, or the like is used for fixing the molded body.
  • the curable termite control composition used in the kneading step of the above third termite control method may be a termite control composition that does not contain a termite control component (first curable termite control composition). It contains a component (second curable termite control composition).
  • the termite control composition does not contain a termite control component
  • the curing liquid used in the kneading step is a termite control liquid
  • a cured product obtained by curing the kneaded product is contained in the termite-control mortar, so that the termite-controlling effect can be surely exhibited.
  • the termite-controlling composition does not contain a termite-controlling component and the curing liquid is a liquid containing water or a polymer, a cured product (termite-controlling mortar) is used.
  • the termites that damage the cured product exhibit a termite control effect by incorporating a large amount of the cured product in the affected area as described above. be able to.
  • the embedded region in which the molded body molded and solidified into a predetermined shape in the molding step is embedded is a site for controlling (including extermination) damage from termites.
  • the region is suitable for embedding the molded body.
  • the embedded region preferably, for example, a foundation structure portion of a building, Examples include cracked portions, gap portions and perforated portions in the superstructure portion and underground structure portion, for example, cracked portions and gap portions of underground buried objects, such as termite ant roads.
  • the fourth termite control method of the present invention includes a spraying / injecting step of spraying or injecting the first or second curable termite control composition to a site for controlling damage caused by termites, A first coating step of applying a kneaded product of the first or second curable termite control composition and the curing liquid to the region where the curable termite control composition is sprayed or injected in the step; ,have.
  • the site where damage caused by termites is controlled particularly the site that is actually damaged by termites (the damaged part) may be damaged by termites.
  • Examples of the curable liquid include those exemplified in the first termite control method.
  • the spraying or injecting method described above is a site where the first or second termite control composition controls the damage caused by termites.
  • an appropriate method for example, spraying or injecting the termite control solution at a time, or spraying or injecting the termite control solution in multiple times.
  • the amount of the termite control solution sprayed is not particularly limited as long as the pre-spread / injected termite control composition does not flow out, and is usually set to the general amount of the termite control component. .
  • the spray rate of the termite control solution is set to 3 to 5 L / m 2 when, for example, spraying on soil, for example, 0.05 to Set to 5L.
  • the first or second termite control composition is applied to the region where the first or second termite control composition is sprayed or injected in the spraying and injection step. And kneaded product of curable liquid was applied, and then contact with the surface of the applied kneaded product was refused Leave in a state. As a result, the kneaded material is cured and pre-spread or injected.
  • a termite control mortar in which the kneaded product is cured is further formed.
  • the blending ratio of the first or second curable termite control composition and the curing liquid may be within a range in which the kneaded product is cured to form a termite control mortar. Therefore, although not particularly limited, for example, with respect to water, solvent or dispersion contained in the curable liquid, the mixing ratio is preferably 100 parts by weight of the first or second curable termite control composition. 15 to 65 parts by weight, more preferably 15 to 45 parts by weight, and still more preferably about 15 to 35 parts by weight.
  • the curable termite control composition sprayed or injected in the injection step does not contain a termite control component (first curable termite control composition) It may be a material containing a termite control component (second curable termite control composition).
  • the termite-controlling composition does not contain a termite-controlling component
  • the termite-controlling composition is used when the curing solution sprayed or injected in the above-mentioned spraying step is a termite-controlling solution.
  • a cured product (termite-controlling mortar) obtained by curing contains a termite-controlling component, so that the termite-controlling effect can be reliably exhibited.
  • the termite-controlling composition does not contain a termite-controlling component, and it is a liquid that contains water or polymer!
  • the termite-controlling component is not contained in the cured product (termite-controlling mortar) obtained by curing the termite-controlling composition.
  • the termite control effect can be exerted.
  • the region is suitable for injecting the cloth and applying the kneaded material.
  • the spraying / injecting area and the coating area preferably, for example, the surface, cracked part, gap part and perforated part of the foundation structure part, superstructure part and underground structure part of the building, for example, underground burial Examples include the surface (peripheral surface) of objects, cracks and gaps, such as termite nests and ant roads.
  • the fifth termite control method of the present invention includes a curable liquid spraying process in which a curable liquid is sprayed on a site where damage caused by termites is controlled, and an area in which the curable liquid is sprayed in the curable liquid spraying process. And a termite control composition spraying step of spraying the first or second curable termite control composition.
  • the curable liquid spraying step the curable liquid is sprayed on the part where damage caused by termites is to be controlled, especially the part that is actually damaged by termites and that may be damaged by termites.
  • Examples of the curable liquid include the same ones as exemplified in the first termite control method.
  • the curable liquid may be sprayed, for example, by spraying the termite control liquid at one time or by dividing it into multiple times. An appropriate method such as cloth is used.
  • the amount of the curable liquid sprayed is, for example, such that the first or second curable termite control composition sprayed in the termite control composition spraying process described below is sufficiently cured and can adhere to the sprayed area. If so,
  • the first or second curable termite control composition is sprayed on the region where the curing solution is dispersed in the curing solution spraying step.
  • the first or second curable termite control composition absorbs water, a solvent, or a dispersion in a curable liquid that has been sprayed in advance on a site that controls damage caused by termites, or, further, in the air Solidifies and hardens by absorbing moisture.
  • termite control mortar is formed.
  • the application amount of the first or second curable termite control composition may be within a range in which the termite control effect is exhibited and can be fixed in the region where the curable liquid is applied. Therefore, although not particularly limited, for example, preferably 200 gZm 2 to 60 kgZ m 2 , more preferably 200 g / m 2 to 30 kg / m 2 .
  • the curing liquid sprayed in the curing liquid spraying step of the fifth termite control method may contain a termite control component that does not contain a termite control component (water or a liquid containing a polymer). It may be a termite control solution.
  • the curable termite control composition sprayed in the termite control composition spraying step contains a termite control component (
  • the cured product (termite control mortar) contains the termite control component, so that the termite control effect can be surely exhibited.
  • the curable liquid does not contain a termite control component
  • the sprayed curable termite control composition does not contain a termite control component (the first curable termite control composition). In this case, the termite-controlling component is not contained in the cured product (termite-controlling mortar).
  • the termites that harm the cured product have a large amount of the cured product in the affected area.
  • the termite control effect can be exhibited.
  • the application area of the first or second curable termite control composition is a site for controlling (including extermination) damage caused by termites, and the first or second termite control method. 2 is not particularly limited except that it is an area suitable for spraying the curable termite control composition, preferably, for example, the surface of a building foundation structure, superstructure, and underground structure, cracks.
  • a gap portion and a perforated portion for example, a surface (outer peripheral surface) of an underground buried object, a crack portion, a gap portion, and the like can be given.
  • the sixth termite control method of the present invention includes a curable liquid spraying process in which a curable liquid is sprayed on a site where damage caused by termites is controlled, and an area in which the curable liquid is sprayed in the curable liquid spraying process. And a second coating step of coating a kneaded product of the first or second curable termite control composition and the curing liquid.
  • curable liquid spraying process there is a risk of damage caused by termites, in particular, parts that are actually damaged by termites and damaged by termites. Spread the curable liquid on a certain part.
  • Examples of the curing liquid include the same ones as exemplified in the first termite control method.
  • the spraying method and the amount of the curing liquid may be set in the same manner as in the fifth termite control method. .
  • a kneaded product of the first or second curable termite control composition and the curing solution is applied to the region where the curing solution is dispersed in the curing solution spraying step, Harden.
  • Examples of the curable liquid include those similar to those exemplified in the first termite control method. In the kneading of the first or second termite control composition and the curable liquid, these are mixed. A kneaded product is obtained by kneading.
  • the kneaded material is solidified and cured by being applied to the region where the curable liquid is dispersed in the curable liquid spraying step.
  • termite control mortar is formed.
  • the mixing ratio of the first or second termite control composition and the curing liquid may be within a range in which the kneaded product can be cured to form a termite control mortar.
  • the termite control liquid or The proportion of water is preferably 15 to 65 parts by weight, more preferably 15 to 45 parts by weight, with respect to 100 parts by weight of the first or second curable termite control composition. Preferably, it is about 15 to 35 parts by weight.
  • the curable liquid sprayed in the curable liquid spraying step of the sixth termite control method may contain no termite control component (water or polymer-containing liquid). It may be a termite control solution containing a component.
  • the curable termite control composition sprayed in the above termite control composition spraying step contains a termite control component (No. 1).
  • the termite control component is contained in the cured product (termite control mortar), so that the termite control effect can be surely exhibited.
  • the curable liquid does not contain a termite control component, and the curable termite control composition to be sprayed contains a termite control component.
  • the cured product does not contain a termite control component, but as described above, the cured product is harmed.
  • Termites can exert the termite control effect by taking in a large amount of the cured product in the affected area.
  • the coating area of the kneaded product is a site for controlling damage (including extermination) due to termites, and is an area suitable for coating the kneaded product.
  • it is not specifically limited except that it is a zone,
  • the surface in the foundation structure part of the building, the upper structure part, and the underground structure part for example, the surface (outer peripheral surface) of the underground buried object, and the like can be mentioned.
  • FIG. 1, FIG. 2 and FIG. 3 are cross-sectional views showing an example of a region to be treated of the curable termite control composition.
  • Fig. 1 shows a solid foundation 20, a foundation body 21 provided on the upper surface of the end of the foundation foundation 20, a foundation insulation 22 provided on the outer surface of the foundation body 21, Makeup mortar 23 covering the outer surface of the foundation insulation 22, wooden base 24 provided on the foundation body 21, pillar 25 standing on the foundation 24, and foundation insulation
  • the outer heat insulating material 26 provided on the top 22 is included.
  • the cosmetic mortar 23 may be a mortar (termite control layer) formed by using a force-curable termite control composition.
  • the above-mentioned curable termite control composition is also applied to the gap between the base body 21 and the base heat insulating material 22 to form the termite control mortar 29.
  • a kneaded mixture of the curable termite control composition and water is injected into the above-mentioned construction portion, that is, the gap between the base body 21 and the base heat insulating material 22, and
  • F After the curable termite control composition is injected, the water is sprayed, (G) After the curable termite control composition is injected, the above termite control solution is sprayed, or (H) water, the above The termite-controlling mortar 29 is formed by spraying the curable termite-controlling composition after spraying at least one liquid selected from the group consisting of the termite control solution and the liquid power containing the polymer. Is done.
  • FIGs. 2 and 3 show the fabric foundation 50 and foundation body 52 (protrusions of the fabric foundation 50, where the foundation 24 and pillars 25 are placed) among the foundation structure of the building.
  • the outer heat insulating material 26 provided on the heat insulating material 22 is included.
  • concrete (concrete concrete) 51 is further provided on the surface of the ground 27.
  • the portion of the foundation main body 52 whose surface is exposed to the outside (a part of the top surface and the side), the upper portion of the foundation insulation 22, and the wooden base 24
  • the above-mentioned curable termite control composition is applied to the surface, the boundary between the end surface of the foundation main body 52, the ground 27 and the soil concrete 51, and the surfaces of the pillar 25 and the outer heat insulating material 26.
  • the termite control mortar 28 is formed in the construction portion in the same manner as the above (A) to (D).
  • the cosmetic mortar 23 itself may be a mortar formed using a curable termite control composition.
  • the above-mentioned curable termite control composition is also applied to the gap between the base body 52 and the base heat insulating material 22 to form the termite control mortar 29.
  • the termite-controlling mortar 29 is formed in the above-mentioned construction portion in the same manner as in the above (E) to (H).
  • the curable silicone is controlled in the gap between the cracks.
  • the composition may be injected.
  • the curable termite control composition 95% by weight or more with respect to the total amount of the earth and sand component is earth and sand having a small particle size of 1.5 mm or less. Therefore, water is added to the curable termite control composition.
  • the kneaded product obtained by kneading is applied to the base of a building, even if the thickness of the curable termite control composition is thin, it prevents termite penetration and is excellent. The termite control effect can be exhibited.
  • KMC—113 (diisopropylnaphthalene, boiling point 300 ° C, Kureha Chemical Co., Ltd.) 360 g, Alkene L (alkylbenzene, distillation range 285-309 ° C, Nippon Petrochemical Co., Ltd.) 2 30 g, Disperbyk-164 (Tertiary amine-containing polyester-modified polyurethane polymer, molecular weight 10000-50000, manufactured by Big Chemie Co., Ltd.) Stir 10 g until homogenous, add 400 g of clothiazine to the resulting mixed solution, TK Auto Slurry A was obtained by stirring with a homodisper (made by Tokushu Kika Kogyo Co., Ltd.).
  • the obtained slurry A was wet-ground for 20 minutes in a bead mill (Dynomill KDL A type, glass bead diameter 1.5 mm).
  • the average particle diameter of clothiazine in the slurry A obtained at this time was 840 nm.
  • aqueous dispersion was reacted in a 60 ° C constant temperature bath with gentle stirring for 6 hours to obtain a termite control component A of the aqueous dispersion containing microcapsules.
  • the active ingredient concentration of the obtained termite controlling component A was 15% by weight, and the average particle size of the microcapsule was 25 ⁇ m.
  • Silica sand No. 6 (comprising silica sand with a particle size of lmm or less, silica sand with a particle size of more than 0.4mm and lmm or less of 11wt%, particle size of more than 0.3mm and silica sand of 0.4mm or less Containing 40% by weight of silica sand having a particle size of 0.15 mm or more and 0.3 mm or less and 4% by weight of silica sand having a particle size of less than 0.1 mm.) 100 parts by weight
  • 3 parts by weight of the termite control component A (active ingredient concentration: 15% by weight) obtained in Reference Example 1 was blended and uniformly mixed while drying to obtain a mixture.
  • the obtained mixture was diluted about 10 times with the above silica sand No. 6, and further diluted about 10 times with the above dry earth and sand A to obtain a diluted product.
  • the active ingredient concentration of the obtained dilution was 0.004% by weight.
  • Kagalite 4M Kagalite Kogyo Co., Ltd., pumice fine granules
  • carrier A having a particle size of 0.15 mm or less.
  • 10 parts by weight of the termite control component A active ingredient concentration: 15% by weight obtained in Reference Example 1 above was blended and uniformly mixed while drying to obtain a mixture. .
  • the resulting mixture was diluted about 10 times with earth and sand (true sand earth) having a particle size of 0.15 mm or less to obtain a termite control component B. Further, the process of diluting the obtained termite control component B with soil (sand sand) with a particle size of 0.15 mm or less about 10 times was repeated twice to obtain a diluted product (termite control component C). .
  • the effective concentration of the obtained termite control component C is 0.0001% by weight.
  • a termite control component C85 parts by weight and a blast furnace cement type B (manufactured by Taiheiyo Cement Co., Ltd.) 15 parts by weight were blended and mixed uniformly to obtain a curable termite control composition.
  • a methanol solution of chlorfenavir was prepared by blending 1 part by weight of chlorfinapill (manufactured by Wako Pure Chemical Industries, Ltd.) and 99 parts by weight of methanol. 4 parts by weight of the methanol solution of chlorfenavir obtained and 10 parts by weight of silica sand No. 6 were blended and mixed uniformly while drying to obtain a mixture. The active ingredient (chlorfenavir) concentration in the obtained mixture was 0.4% by weight.
  • Back Top MC (15% microcapsule of active ingredient bather (including MEP and BPMC), manufactured by Sumitomo Chemical Co., Ltd.) 1 part by weight and 19 parts by weight of the above dry earth and sand A, and dried. The resulting mixture was mixed uniformly to obtain a mixture. The active ingredient concentration of the obtained mixture was 0.76% by weight.
  • Grenade MC (2.5% microcapsule of active ingredient fiprole, manufactured by Sumitomo Chemical Co., Ltd.) 1 part by weight and 10 parts by weight of the above-mentioned dry earth and sand A and mixed uniformly while drying To obtain a mixture. Furthermore, the above-mentioned dry earth and sand A was blended with the obtained mixture and diluted 12.5 times to obtain a diluted product. The effective main component concentration of the obtained dilution is 0.02 The amount was%.
  • Lalap MC 10% microcapsule of active ingredient Shifunotrin, manufactured by Sumitomo Chemical Co., Ltd.
  • 10 parts by weight of the above-mentioned dry earth and sand were mixed uniformly while drying to obtain a mixture.
  • the above-mentioned dry earth and sand A was blended into the obtained mixture and diluted 10 times to obtain a diluted product.
  • the concentration of the active ingredient in the obtained dilution was 0.1% by weight.
  • Permethrin manufactured by Herbert-Heinz Winkler GmbH
  • 99 parts by weight of methanol were blended to prepare a methanol solution of permethrin.
  • 1 part by weight of the obtained methanol solution of permethrin and 10 parts by weight of the above dry earth and sand A were blended and uniformly mixed while drying to obtain a mixture.
  • the active ingredient (permethrin) concentration in the resulting mixture was 0.1% by weight.
  • Silafluorene methanol solution (manufactured by Wako Pure Chemical Industries, Ltd.) was mixed with 1 part by weight of 99 parts by weight of methanol to prepare a methanol solution of silaflufen.
  • Meta of silafluophene obtained 2 parts by weight of the Nord solution and 10 parts by weight of the above-mentioned dry earth and sand A were blended and mixed uniformly while drying to obtain a mixture.
  • the active ingredient (silafluophene) concentration of the obtained mixture was 0.2% by weight.
  • Bifenthrin (manufactured by Wako Pure Chemical Industries, Ltd.) 1 part by weight and 99 parts by weight of methanol were blended to prepare a methanol solution of bifenthrin. 1 part by weight of the methanol solution of bifenthrin thus obtained and 10 parts by weight of the above dry earth and sand A were uniformly mixed while drying to obtain a mixture. Furthermore, the obtained mixture was diluted 10 times with the above-mentioned dry earth and sand A to obtain a diluted product. The active ingredient (bifunthrin) concentration of the obtained dilution was 0.01% by weight.
  • Etofenprox manufactured by Wako Pure Chemical Industries, Ltd. 1 part by weight and 99 parts by weight of methanol were combined to prepare a solution of etofenprox in methanol. 2 parts by weight of the obtained methanol solution of etofenpox and 10 parts by weight of the dry earth and sand A were uniformly mixed while drying to obtain a mixture. The active ingredient (ethofenprox) concentration in the obtained mixture was 0.2% by weight.
  • Example 13 Termite control component C obtained in Example 4 (diluted product) 82.5 parts by weight, blast furnace cement type B (manufactured by Taiheiyo Cement Co., Ltd.) 15 parts by weight, ethylene bulal alcohol (EVA) rosin (trade name) “Sumikaflex RP-100S” (manufactured by Sumitomo Chemical Co., Ltd.) 2. 5 parts by weight were blended and mixed uniformly to obtain a curable termite control composition blended with the oil component.
  • EVA ethylene bulal alcohol
  • the termite control component B obtained in Example 4 was diluted about 3 times with earth and sand (true sand earth) having a particle size of 0.15 mm or less, and mixed uniformly to obtain a diluted product.
  • the active ingredient concentration of the obtained dilution was 0.05% by weight.
  • curable termite control composition 100 parts by weight of the obtained curable termite control composition, 6 parts by weight of acrylic resin emulsion (trade name “Crosslen CMX-02”, manufactured by Ganz Kasei Co., Ltd.) and 15 parts by weight of water were added.
  • acrylic resin emulsion trade name “Crosslen CMX-02”, manufactured by Ganz Kasei Co., Ltd.
  • the resulting curable termite control composition was applied at about 300 gZm 2 under the floor between 6 tatami mats in a private house in Nara Island to form a termite control layer.
  • a curable termite control composition obtained in Example 14 100 parts by weight and 20 parts by weight of water were kneaded, and a cube of about 1 cm was made from the kneaded product and solidified. .
  • a 3cm pine sapwood cube was drilled with a height of about 1cm, a width of about 1cm, and a depth of about 2cm.
  • Kagalite 4M (Kagalite Kogyo Co., Ltd., pumice fine granules) was passed through a sieve to obtain carrier A having a particle size of 0.15 mm or less.
  • the obtained carrier A is diluted about 10 times with earth and sand having a particle size of 0.15 mm or less (true sand soil), and further diluted about 10 times with earth and sand having a particle size of 0.15 mm or less (true sand earth).
  • a curable termite-controlling composition was prepared by mixing 98 parts by weight of the dilution obtained in the same manner as in Example 16 and 2 parts by weight of blast furnace cement type B (manufactured by Taiheiyo Cement Co., Ltd.).
  • the compression strength (JIS R 5201) of the cured product obtained by kneading and curing 100 parts by weight of the obtained curable termite control composition and 20 parts by weight of water was about 2 NZmm 2. It was.
  • Example 2 To 100 parts by weight of the dry earth B obtained in Example 2, 10 parts by weight of the termite control component A (active ingredient (crothia-zine) concentration of 15% by weight) obtained in Reference Example 1 is blended and dried. The resulting mixture was mixed uniformly to obtain a mixture. Furthermore, the operation of diluting the obtained mixture about 10 times with the above dry earth and sand B was repeated 3 times to obtain a diluted product. The active ingredient concentration of the obtained dilution was 0.0012% by weight.
  • the active ingredient concentration in the resulting curable termite control composition was about 0.1% by weight.
  • 100 parts by weight of the obtained curable termite control composition and 20 parts by weight of water were kneaded and cured, and the compression strength (JIS R 5201) of the cured product was about lONZmm 2.
  • Example 20 50 parts by weight of the termite control agent B obtained in Example 4 and 50 parts by weight of the dry earth and sand A obtained in Example 1 were blended and mixed uniformly to obtain a mixture. Furthermore, 85 parts by weight of the obtained mixture and 15 parts by weight of blast furnace cement type B (manufactured by Taiheiyo Cement Co., Ltd.) were blended and mixed uniformly to obtain a curable termite control composition. The active ingredient concentration in the resulting curable termite control composition was about 0.05% by weight.
  • the obtained cured termite controlling composition 100 parts by weight, kneading the water 20 parts by weight, compressive strength of the cured product obtained by curing is about LONZmm 2 Ah
  • the obtained cured termite controlling composition 100 parts by weight, kneading the water 20 parts by weight, compressive strength of the cured product obtained by curing is about LONZmm 2 Ah
  • the obtained cured termite controlling composition 100 parts by weight, kneading the water 20 parts by weight, compressive strength of the cured product obtained by curing is about LONZmm 2 Ah
  • Termite control component A active ingredient (crothiazidine) concentration of 15 wt%) obtained in Reference Example 1 above was blended with 10 parts by weight of C100 parts by weight of the obtained dry earth and sand. Mix together to obtain a mixture. Further, the operation of diluting the obtained mixture with the dry earth and sand C about 10 times was repeated 3 times to obtain a diluted product. The active ingredient concentration of the resulting dilution was 0.0012% by weight.
  • Chlorfenavir methanol solution was prepared by blending 1 part by weight of chlorfinapill (manufactured by Wako Pure Chemical Industries, Ltd.) and 99 parts by weight of methanol. 4 parts by weight of the obtained methanol solution of chlorfenavir and 10 parts by weight of the above-mentioned dry earth and sand C were mixed and mixed uniformly while drying to obtain a mixture.
  • the active ingredient (chlorfenavir) concentration of the obtained mixture was 0.4% by weight.
  • Kagalite No. 0 manufactured by Kagalite Kogyo Co., Ltd., fine pumice granule, particle size of about 4.8 mm to 2.4 mm
  • Takelock MC50E active ingredient clothiazine 5%, Nippon Chemicals Co., Ltd. 1 part by weight was mixed, kneaded and dried to obtain a termite control granule
  • the active ingredient concentration of the obtained termite control granules was 0.05% by weight.
  • Chlorpyrifos (manufactured by Wako Pure Chemical Industries, Ltd.) 5 parts by weight and 95 parts by weight of methanol were blended to prepare a methanol solution of chlorpyrifos. 2 parts by weight of the resulting chloropyrifos methanol solution and 10 parts by weight of kagarite No. 0 (pumice fine granules) were blended and mixed uniformly while drying to obtain a mixture.
  • the active ingredient (chlorpyrifos) concentration in the obtained mixture was 1% by weight.
  • the penetration test is a test to confirm the penetration effect of the curable termite control composition in the penetration direction, for example, to confirm the efficacy in the penetration direction when the curable termite control composition is applied under the floor and on the soil. be able to.
  • FIG. 4 is a perspective view showing a test apparatus used for the penetration test.
  • untreated hydrous sand (water content 10% by weight) was spread in a petri dish 9cm in diameter to form a hydrous siliceous layer 2 having a thickness of lcm.
  • untreated silica sand was spread inside the cylinder 3 to form a silica sand layer 4 having a thickness of 3 cm.
  • V was used in the same manner as in the case of using the termite control composition of Example 1. Then, the test sample layer 5 was formed, and the penetration of the test sample layer 5 was observed in the same manner as described above.
  • Mixture B 1 part by weight of calcium hydroxide, sand !, sand No. 6 (grain size less than lmm !, made of sand, 11% by weight of sand with a particle size of more than 0.4mm and less than lmm Silica sand with a particle size of more than 0.3 mm and less than 0.4 mm is 45% by weight, silica sand with a particle size of 0.1 to 0.3 mm is 40% by weight, and silica with a particle size of less than 0.15 mm Contains 4% by weight of sand.) 99 parts by weight and adjusted to a moisture content of 10% by weight.
  • Mixture C Instant cement (Osaka Sunhome Co., Ltd.) 100 parts by weight, prepared by adding 20 parts by weight of water (compressive strength (JIS R 5201) approx. 28NZmm 2 ).
  • a 1.5 cm square cube was cut out from a recast unreinforced concrete flat plate (compressive strength> 30 NZmm 2 ), and an acrylic plate was bonded to the side of the resulting cube so that no gap was formed.
  • the acrylic plate was bonded to the cube so that it protruded 3 cm on the bottom side and lcm on the top side.
  • a test specimen was obtained by filling untreated hydrous siliceous sand into the part where the acrylic plate protruded from the bottom side of the cube (width and depth: 1.5 cm each, height: 3 cm space). .
  • the pine litter of pine lcm x lcm and length 2 cm An untreated specimen was installed.
  • test sample layer 5 was not penetrated, several mm perforations were observed. However, in both Examples 16 and 17, all termites died one week after the release.
  • the hardness of the test sample layer and the particle size of the earth and sand component in the curable termite control composition forming the test sample layer should be set within a range suitable for termites to harm. As a result, a certain termite control effect can be obtained.
  • the termite control composition of Example 1 was used except that the test sample layer 5 was formed using only untreated silica sand. Similarly, in the penetration test, it was observed that the termite 7 reached the pine feed tree (untreated specimen) 6 one day after the release.
  • the effectiveness of the termite control agent on the surface should be checked. It is possible to confirm the effectiveness of a test that can be performed, for example, when it is constructed on the rising surface of the foundation part under the floor.
  • FIG. 5 is a front view showing a test apparatus used for the scooping test.
  • an untreated hydrous sand (water content 10% by weight) is spread on a polycup (with a capacity of 500 mL) 10 with a bottom diameter of about 8 cm, and a 3 cm thick hydrous sand layer.
  • the curability obtained in Examples 1 to 13 and 18 to 23 and Comparative Examples 1 and 2 and 4 are set in a region having a width of 50 mm from the edge on the top surface side to the bottom surface side.
  • Each of the termite control compositions was applied to form monoletanol 13.
  • the curable termite control composition was mixed with 20 parts by weight of water with respect to 100 parts by weight of the curable termite control composition, and after 2 hours with occasional stirring, it was applied to the side of the concrete block 12. did. Also, after application, the concrete block 12 was stored at 40 ° C for 2 weeks and then used for the scooping test.
  • the coating amount of the curable termite control composition was adjusted to be 300 gZm 2 .
  • the termite control component was prevented from eluting into the hydrous dredged sand layer 11 in the 10 mm wide area from the bottom edge to the top side of the side surface of the concrete block 12. In addition, no treatment was performed.
  • Table 1 shows the results of the rising test. [0157] [Table 1] Table 1
  • Example 5 About 50% was feffil and the rest was repelled.
  • Example 6 About 20% was ⁇ ! And the rest was avoided.
  • Example 7 About 10% ⁇ a and the remainder was avoided.
  • Example 8 100% repellent.
  • Example 9 100% repellent.
  • Example 10 It was almost healthy. Several movements were observed.
  • Example 11 Almost avoided. Several movements were observed.
  • Example 12 100% repellent.
  • Example 18 The vehicle fell over 100%.
  • Example 21 A 100% vehicle was used.
  • Example 22 The vehicle fell over 100%.
  • Example 23 Defeated 100%.
  • the construction site is not particularly limited as long as it is a place where termites are generated or a place where there is a possibility of occurrence.
  • Gaps such as concrete cracks, for example, thermal insulation in walls, for example, xylem that forms the foundation part of the foundation, for example, xylem that forms the underfloor, such as Ojiki, jota, floor bundle, rooting, for example, Wooden parts that make up living spaces such as door frames, pillars, closets, etc., for example, wooden parts that make up the ceiling of the waistline, second floor, etc., for example, wooden parts that make up the back of the shed such as sheds and haze
  • a wooden part such as a door pocket, eaves, window frame, entrance, kitchen, etc., part or all of which is exposed outside), for example, an underground structure part of a building (for example, a wooden part or A cracked part of concrete), for example, as an ancillary facility of a building Underground buried object (
  • a concrete block (a rectangular parallelepiped with a thickness of 3 cm, a width of 10 cm, and a height of 10 cm).
  • An adhesive (Super X, manufactured by Cemedine Co., Ltd.) 31 was applied to the 5 cm portion at a length of 1 cm and a length of 2 cm from both ends of the concrete block 30.
  • the concrete block 30 and a heat insulating material 32 (Kanelite Foam FI, manufactured by Riki Neka Co., Ltd.) having the same size as the concrete block 30 were bonded with the adhesive 31 interposed therebetween.
  • a gap 33 of 0.5 mm was formed between the heat insulating material 32 and the concrete block 30.
  • the adhesive made of the concrete block 30 and the heat insulating material 32 has no gap on its surface (excluding the surface of the heat insulating material 32 that faces the bonding surface with the concrete block 30).
  • a 2 mm acrylic plate 34 was bonded.
  • the part above 2mm from the bottom should protrude so that the top protrudes lcm, and the bottom protrudes 3cm toward the heat insulating material.
  • the side was bonded with an acrylic plate 34 so that the bottom on the heat insulating material side protruded 3cm in height and 3cm in width, and the upper part protruded lcm.
  • Acrylic plate 34 was bonded to the bottom of the bottom and the side that protruded from the side, with the front protruding.
  • An untreated hydrated siliceous sand (water content 10% by weight) 35 was spread over the part that protruded over the entire surface.
  • Double foundations by renovation tend to cause gaps and quickly become termite entry routes.
  • cracks and other gaps in the underfloor concrete, including the gaps in the double foundation are not attacked by external enemies and require less labor to build ant roads, making it easier for termites to enter.
  • the curable termite control composition obtained in Comparative Example 1 was sprayed in the gap 41 between the pair of concrete blocks 40.
  • Example 4 As a result, as shown in FIG. 8 (a), in Example 4, the curable termite control composition was formed in the gap 41. It was observed that object 42 was treated uniformly.
  • Comparative Example 1 As shown in FIG. 8 (b), the large particles 43 became an obstacle, and the amount of the termite control composition 42 in the gap 41 was small.
  • Comparative Example 3 As shown in FIG. 8 (c), the termite control composition was not observed in the gap 41.
  • the carrier A was treated uniformly as in Example 4 (see FIG. 8 (a)). Since the water 44 is absorbed in a large amount in the upper part of the concrete block 40, the water 44 has a degree of dripping and cannot be uniformly treated (see FIG. 8 (d)).
  • test specimen (a pair of concrete blocks 40) treated in Example 4 and carrier A in the construction test 4 in the gap was placed on the tray as it was, under the conditions of humidity 100% RH and temperature 28 ° C. Stored for 1 month. One month later, when the sample was lifted from the tray, as shown in FIG. 9, it was observed that a large amount of the processed material 45 spilled from the adhesion surface of the specimen (concrete block 40) treated with the carrier A. On the other hand, in Example 4, no spilling-down state was observed, and a state in which a uniform treatment layer was formed while remaining solidified in the gap was observed. This is because the ground is opened by other organisms such as moles under the surface of the treatment, and the ground is washed away by the infiltration of rainwater. Show that the treated layer will not be lost, but the formulation that does not solidify may collapse and dissipate! /
  • a non-treated hydrous silica sand (water content 10% by weight) is spread on a polycup 10 (with an internal volume of 500 mL) with a bottom diameter of about 8 cm to form a hydrous siliceous layer with a thickness of 3 cm. ! /,
  • the specimen obtained in Example 15 was placed in the center of the sand layer.
  • a heat insulating material (Kanelite Foam FI, manufactured by Kaneiki Co., Ltd.) is cut into 3 cm squares, and a kneaded mixture of 100 parts by weight of the curable termite control composition obtained in Example 4 and 20 parts by weight of water from above. Was coated at a rate of 200 g / m 2 and dried.
  • a heat insulating material (Kanelite Foam FI, manufactured by Kaneiki Co., Ltd.) was cut into a length of 5 cm, a width of 5 cm and a height of 40 cm, and 100 parts by weight of the curable termite control composition obtained in Example 4 was formed on the surface.
  • a kneaded product of 20 parts by weight of water was applied at a rate of 3 kgZm 2 and dried to obtain a test specimen.
  • Example 4 Cut the cedar sapwood into 3cm squares and control the curable termites obtained in Example 4 from above. A kneaded mixture of 100 parts by weight of the composition and 20 parts by weight of water was applied at a rate of 2 kgZm 2 and dried to obtain a test specimen.
  • this test body was placed in place of the test body obtained in Example 15 in the construction test 6, and the test was performed in the same manner as the construction test 6.
  • Example 4 Using a drill with a blade diameter of 8 mm, drill a hole about 1.5 cm deep in a cedar sap cut into a 3 cm square, and in that hole 100 parts by weight of the curable termite control composition obtained in Example 4 Then, a kneaded mixture of 20 parts by weight of water was injected to obtain a test specimen.
  • this test body was installed in place of the test body obtained in Example 15 in the construction test 6, and the test was performed in the same manner as the construction test 6.
  • this test body was placed in place of the test body obtained in Example 15 in the construction test 6, and the test was performed in the same manner as the construction test 6.
  • Example 4 Using a drill with a blade diameter of 8 mm, drill a hole with a depth of about 1.5 cm in a cedar sap cut into a 3 cm square, and inject the curable termite control composition obtained in Example 4 into the hole. Further, water was sprinkled from above and solidified to obtain a test specimen.
  • this test body was installed in place of the test body obtained in Example 15 in the construction test 6, and the test was performed in the same manner as the construction test 6. As a result, all termite falls were observed 1 day after the start of the study, and all animals died 3 days later.
  • the curable termite control composition obtained in Example 4 was sprayed at a rate of 2 kgZm 2 on the upper surface of the cedar sap cut into 3 cm square, and further watered from above to solidify. Furthermore, the other five surfaces of the cedar sapwood were similarly sprayed with a curable termite control composition and solidified by watering to obtain a test specimen.
  • this test body was placed in place of the test body obtained in Example 15 in the construction test 6, and the test was performed in the same manner as the construction test 6.
  • Insulation (Kanelite Foam FI, manufactured by Kaneiki Co., Ltd.) is cut into 3cm squares, and this is tested. And installed in place of the untreated specimen in construction test 6 and tested in the same manner as construction test 6.
  • Insulation (Kanelite Foam FI, manufactured by Kanechi Co., Ltd.) is cut into 3 cm squares, which are used as test specimens and installed in place of the untreated specimens in construction test 6, and the same as construction test 6. A test was conducted.
  • the ant road was broken over a height of lcm, and the curable white base control composition lg obtained in Example 19 was sprayed in the ant road.
  • the termites that were healthy until 3 weeks after the test started were killed 2 days after the application of the curable termite control composition, and were exterminated by construction in the ant canal. I was able to.
  • the curable termite control composition was found to be cured after 1 day.
  • a run-up test was conducted in the same manner as the construction test 18, and a dovetail was constructed on the wall of the concrete block. Next, this ant road was destroyed over a height of 1 cm, and a kneaded mixture of 100 parts by weight of the curable termite control composition obtained in Example 19 and 20 parts by weight of water was added to the part thus destroyed. It was coated at a rate of 5kgZm 2.
  • Yamato termites collected in Osaka Prefecture were bred in a 10-liter plastic bucket using pine as a feeding tree, and it was confirmed that a nest containing eggs, larvae, craft ants, soldier ants, and reproductive worms was formed. .
  • the curable termite control composition was cured when observed after 2 weeks.
  • a kneaded mixture of 100 parts by weight and 20 parts by weight of water was applied over a range of 20 cm 2 at a ratio of 10 kgZm 2 .
  • a PVC pipe having a diameter of about 3 cm was cut to a length of 10 cm, and pine bait trees were packed inside the pipe and covered with a wrap to obtain a test specimen.
  • a sandy sand No. 6 having a water content of 10% by weight was attached so as to have a thickness of about 3 cm, and the curable termite control composition obtained in Example 19 was further provided therearound.
  • a treatment layer was formed by spraying at a thickness of 2 mm.
  • the above-mentioned test specimen was placed in a container of about 13 cm X 20 cm X I 5 cm in which Key Sand No. 6 was spread with a thickness of 1 cm, and the surroundings were further filled with Key Sand No. 6.
  • the thickness of the upper key sand was about lcm. From this silica sand, 500 ants of termite ants were thrown in and the state was observed.
  • the curable termite control composition obtained in Example 20 was applied to the surface of the soil concrete 51 and the foundation body 52 to which the adhesive 'compound was applied. 53 was sprayed so that the width w was 10 cm and the height h of the foundation rising part was 2 cm (about 20 kgZm 2 ), and water was sprayed from above.
  • the curable termite control composition 53 obtained in Example 20 was applied to the surface of the soil concrete 51 and the foundation main body 52 to which the adhesive 'compound was applied. Scattered so that the height h of the rising part was 2 cm (about 20 kgZm 2
  • a termite control agent was sprayed on the first floor of the same wooden house under another 6 tatami mats in the same manner as described above, and 100 parts by weight of the curable termite control composition obtained in Example 19 was used. And kneaded with 20 parts by weight of water so that the width w is force cm and the height h of the foundation rising part is 2 cm.
  • a spray gun (“TPG-19S type” manufactured by Yusei Kenki Co., Ltd.) is connected to the tip of the above hose, and an air compressor (“0. -8. 5SA6 type ”) was connected to the curable termite control composition obtained in Example 19 for spray coating.
  • spray coating is applied to the surface of two blocks of concrete blocks (the foundation of the building) and 9 cm square wood (the foundation of the building), which are installed on the concrete road surface.
  • the coating weight was adjusted to about 3kgZm 2.
  • the spray coating is performed by applying the above-mentioned curable termite-controlling composition (compounded with rosin emulsion) to the surface of the above-mentioned two concrete blocks (pseudo foundation) and the above-mentioned wood (pseudo-base).
  • the spraying amount (coating amount) of the curable termite control composition was adjusted to be about 3 kgZm 2 .
  • the curable termite control composition of the present invention is widely applied to sites that control termite damage (for example, sites where termites may invade or sites where termites are actually damaged). Can be used.
  • the curable termite control composition of the present invention includes, for example, the foundation structure part, the superstructure part and the underground structure part in the building, the underground buried object as the ancillary facility of the building, the ground surface, and the termite inhabiting generation. In areas and the like, it can be suitably used for the application of termite control.
  • the termite control method of the present invention is suitable for use in a site that widely controls damage caused by termites.

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7931742B2 (en) * 2005-11-02 2011-04-26 Basf Se Biocidal Structural Barrier (BSB)
FR2970963A1 (fr) * 2011-02-02 2012-08-03 Financ Vm Beton Beton ou mortier anti-termites et son procede de fabrication
US8597725B2 (en) 2009-06-19 2013-12-03 Termortar Pty Ltd Method of termite proofing a building structure
EP2774959A1 (de) * 2013-03-07 2014-09-10 STO SE & Co. KGaA Zementäre Beschichtungszusammensetzung und Verfahren zur antimikrobiellen Ausrüstung einer zementären Beschichtungszusammensetzung
CN111978023A (zh) * 2020-08-31 2020-11-24 浙江交工国际工程有限公司 一种防蚁砂浆及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0451506U (enrdf_load_stackoverflow) * 1990-09-04 1992-04-30
JPH07291699A (ja) * 1994-04-15 1995-11-07 Kuraray Chem Corp 白アリ防除コンクリート

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0451506U (enrdf_load_stackoverflow) * 1990-09-04 1992-04-30
JPH07291699A (ja) * 1994-04-15 1995-11-07 Kuraray Chem Corp 白アリ防除コンクリート

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7931742B2 (en) * 2005-11-02 2011-04-26 Basf Se Biocidal Structural Barrier (BSB)
US8597725B2 (en) 2009-06-19 2013-12-03 Termortar Pty Ltd Method of termite proofing a building structure
FR2970963A1 (fr) * 2011-02-02 2012-08-03 Financ Vm Beton Beton ou mortier anti-termites et son procede de fabrication
EP2774959A1 (de) * 2013-03-07 2014-09-10 STO SE & Co. KGaA Zementäre Beschichtungszusammensetzung und Verfahren zur antimikrobiellen Ausrüstung einer zementären Beschichtungszusammensetzung
CN111978023A (zh) * 2020-08-31 2020-11-24 浙江交工国际工程有限公司 一种防蚁砂浆及其制备方法

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