WO2007023119A1 - Mesoporöses metallorganisches gerüstmaterial - Google Patents
Mesoporöses metallorganisches gerüstmaterial Download PDFInfo
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- WO2007023119A1 WO2007023119A1 PCT/EP2006/065346 EP2006065346W WO2007023119A1 WO 2007023119 A1 WO2007023119 A1 WO 2007023119A1 EP 2006065346 W EP2006065346 W EP 2006065346W WO 2007023119 A1 WO2007023119 A1 WO 2007023119A1
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- framework material
- framework
- organic compound
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- 239000013337 mesoporous metal-organic framework Substances 0.000 title 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 24
- 125000001424 substituent group Chemical group 0.000 claims abstract description 15
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- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- UQMOLLPKNHFRAC-UHFFFAOYSA-N tetrabutyl silicate Chemical compound CCCCO[Si](OCCCC)(OCCCC)OCCCC UQMOLLPKNHFRAC-UHFFFAOYSA-N 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- NPFVOOAXDOBMCE-UHFFFAOYSA-N trans-3-hexenyl acetate Natural products CCC=CCCOC(C)=O NPFVOOAXDOBMCE-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- UCSBCWBHZLSFGC-UHFFFAOYSA-N tributoxysilane Chemical compound CCCCO[SiH](OCCCC)OCCCC UCSBCWBHZLSFGC-UHFFFAOYSA-N 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 1
- 239000013138 trimesic acid-based metal-organic framework Substances 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- OZWKZRFXJPGDFM-UHFFFAOYSA-N tripropoxysilane Chemical compound CCCO[SiH](OCCC)OCCC OZWKZRFXJPGDFM-UHFFFAOYSA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
- B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0015—Organic compounds; Solutions thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0026—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof of one single metal or a rare earth metal; Treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/418—Preparation of metal complexes containing carboxylic acid moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
Definitions
- the present invention relates to a porous organometallic framework material and a process for its preparation and its use.
- Porous organometallic frameworks are known in the art.
- organometallic frameworks are described, for example, in US Pat. No. 5,648,508, EP-A 0 790 253, M. O. Keefe, J. SoI. State Chem. 152 (2000), 3-20; Li, H., et al., Nature 402 (1999), 276; M. Eddaoudi, Topics in Catalysis 9 (1999), 105-111; Chen et al., Science 291 (2001), 1021-1023 and DE-A 101 11 230.
- MOF organometallic frameworks
- organometallic framework materials investigated in the prior art are suitable in many ways. These can be used, for example, for storage, for separation or in the chemical conversion of substances. In particular, these can be used as carriers for catalysts or catalysts.
- organometallic frameworks in which the metal ion is a main group element of the periodic system have come into focus.
- the X-ray diffractograms of the framework according to the invention in comparison to the above-mentioned known in the prior art framework materials hardly characteristic of known frameworks sharp signals between 5 and 30 ° (2 ⁇ ), in particular between 5 and 12 °.
- the framework material may also occur in the framework material, other organic compounds, in particular one or more monodentate ligands.
- the molar fraction of the first-mentioned organic compound which must be present is at least 50%, more preferably at least 75% and particularly preferably at least 90% of the total amount of the organic compounds in the framework.
- ring A is a benzene, pyridine, pyridazine, pyrimidine, pyrazine or triazine ring.
- A is preferably benzene.
- ring A has three substituents X. These are the carboxylate group and their thio analogs. At least part of the carboxylate groups and / or thio analogs occurring in the framework material A can be present in protonated form.
- the ring A may have one or more further substituents.
- R, NRR ', OR, SR, F, Cl, and Br are the functional groups R, NRR ', OR, SR, F, Cl, and Br, where R and R' independently of one another may be hydrogen, methyl or ethyl.
- the methyl and the ethyl group may also be mono- or polyfluorinated.
- ring A has no further substituents except for X.
- the organic compound is particularly preferably 1,2,3-, 1,2,4- or 1,3,5-benzene tricarboxylate or their at least partially protonated analogs. Particularly preferred is 1, 3,5-benzenetricarboxylate.
- the organometallic framework according to the invention contains pores, in particular micropores and / or mesopores.
- Micropores are defined as those with a diameter of 2 nm or smaller and mesopores are defined by a diameter in the range of 2 to 50 nm, each according to the definition as described in Pure Applied Chemistry 57 (1985), pages 603- 619, in particular stated on page 606 is.
- the presence of micro- and / or mesopores can be checked by means of sorption measurements, these measurements determining the absorption capacity of the organometallic frameworks for nitrogen at 77 K in accordance with DIN 66131 and / or DIN 66134.
- the organometallic framework material according to the invention preferably has an average pore diameter of 2 to 10 nm, particularly preferably 3 to 9 nm.
- the distribution of the pore size is a maximum of +/- 5 nm.
- the most frequently occurring pore diameter is preferably in the range from 3 to 9 nm.
- the specific surface area - calculated according to the Langmuir model according to DIN 66135 (DIN 66131, 66134) for an inventive organometallic framework in powder form is at least 800 m 2 / g. More preferably, the specific surface area is at least 1000 m 2 / g, and more preferably at least 1300 m 2 / g. Most preferably, the specific surface area is at least 1500 m 2 / g.
- the pore volume be formed by pores having a pore diameter of 2 to 10 nm (mesopores).
- the proportion of the pore volume is at least 65%, most preferably at least 80%.
- the pore volume is preferably at least 0.8 ml / g, more preferably at least 1.1 ml / g.
- MOF shaped bodies can have a low specific surface area. However, this is preferably more than 10 m 2 / g, more preferably more than 50 m 2 / g and more preferably more than 500 m 2 / g.
- pores whose size distribution may vary.
- more than 50% of the total pore volume, in particular more than 75%, of pores having a pore diameter of up to 1000 nm is formed.
- a majority of the pore volume is formed by pores of two diameter ranges. It is therefore further preferred if more than 25% of the total pore volume, in particular more than 50% of the total pore volume, is formed by pores which are in a diameter range of 100 nm to 800 nm and if more than 15% of the total pore volume, in particular more than 25% of the total pore volume is formed by pores ranging in diameter up to 10 nm.
- the pore distribution can be determined by means of mercury porosymmetry.
- Another object of the present invention is a process for preparing a framework according to the invention comprising the step
- the reaction takes place in a non-aqueous organic solvent with stirring at a pressure of at most 2 bar (absolute).
- the pressure is at most 1230 mbar (absolute). More preferably, the reaction takes place under atmospheric pressure.
- the organometallic framework according to the invention can also be prepared in water as a solvent with the addition of a base.
- the base can be dispensed with.
- a base can also be added.
- the organic solvent itself can also serve as a base.
- Preferred starting materials when using an aluminum salt in the synthesis are the hydrates of aluminum chloride or nitrate, in particular the chloride is preferred.
- the metal compound used to produce the porous organometallic framework according to the invention may be non-ionic and / or the counterion to the Al '' cation may be derived from a protic solvent,
- a non-ionic compound it may be avoided, if appropriately selected be that in the implementation of the porous organometallic framework material, the metal is present in the form of a salt and thus possibly difficulties in the removal of the corresponding anion in the metal salt can be avoided, provided by the metal compound in the reaction no other interfering salts are generated.
- the counterion represents a solvent anion, this may, if suitably chosen after reaction, be present as solvent, which may be the same as or different from the non-aqueous organic solvent used. In the latter case, it is preferred if this solvent is at least partially miscible with the non-aqueous organic solvent.
- nonionic compounds or counterions to the metal cation which can be derived from protic solvents can be, for example, metal alkoxides, for example methanolates, ethanolates, propanolates, butanolates.
- oxides or hydroxides are conceivable.
- the non-aqueous organic solvent is preferably a Ci -6 alkanol, dimethyl sulfoxide (DMSO), NN-dimethylformamide (DMF), N, N-diethylformamide (DEF), acetonitrile, toluene, dioxane, benzene, chlorobenzene, methyl ethyl ketone ( MEK), pyridine, tetrahydrofuran (THF), ethyl acetate, optionally halogenated C.sub.2O.sub.O alkane, sulfolane, glycol, N-methylpyrrolidone (NMP), .gamma.-butyrolactone, alicyclic alcohols, such as cyclohexanol, ketones, such as acetone or acetylacetone, Cycloketones, such as cyclohexanone, sulfolene or mixtures thereof.
- DMSO dimethyl sulfox
- a d- 6- alkanol refers to an alcohol having 1 to 6 carbon atoms. Examples of these are methanol, ethanol, n-propanol, i-propanol, n-butanol, i-butanol, t-butanol, penthanol, hexanol and mixtures thereof.
- Ci -2 oo-alkane is an alkane having 1 to 200 carbon atoms, wherein one or more may be up to all hydrogen atoms substituted by halogen, preferably chlorine or fluorine, in particular chlorine, replaced back. Examples thereof are chloroform, dichloromethane, tetrachloromethane, dichloroethane, hexane, heptene, octane and mixtures thereof.
- Preferred solvents are DMF, DEF and NMP. Particularly preferred is DMF.
- non-aqueous preferably refers to a solvent having a maximum water content of 10% by weight, more preferably 5% by weight, still more preferably 1% by weight, further preferably 0.1% by weight. , particularly preferably 0.01 wt .-% based on the total weight of the solvent does not exceed.
- the maximum water content during the reaction is 10% by weight, more preferably 5% by weight, and still more preferably 1% by weight.
- solvent refers to pure solvents as well as mixtures of different solvents.
- the step of reacting the at least one metal compound with the at least one at least bidentate organic compound is followed by a calcination step.
- the temperature set is typically more than 250 ° C, preferably 300 to 400 0 C.
- the ligand present in the pores can be removed.
- the removal of ligand from the pores of the porous organometallic framework material may be accomplished by treatment of the resulting framework with a nonaqueous solvent.
- the ligand is removed in a kind of "extraction process" and optionally replaced in the framework by a solvent molecule.
- the extraction process takes place before calcination, when the latter is provided.
- the treatment is preferably at least 30 minutes and may typically be up to two days. This can be done at room temperature or elevated temperature. This is preferably carried out at elevated temperature, for example at at least 40 ° C., preferably 60 ° C. Also preferred is a reaction at the boiling point of the solvent (reflux).
- the treatment can be carried out in a simple boiler by slurrying and stirring the framework material. It is also possible to use extraction apparatuses such as Soxhlet apparatuses, in particular technical extraction apparatuses.
- Ci -6 - alkanol DMSO, DMF, DEF, acetonitrile, toluene, dioxane, benzene, chlorobenzene, MEK, pyridine, THF, ethyl acetate, optionally halogenated Ci -2O o-alkane, Sulfoles, glycol, NMP or mixtures thereof.
- the solvent used for the extraction may be the same as or different from that for the reaction of the at least one metal compound with the at least one at least bidentate organic compound.
- extraction does not necessarily require the solvent to be anhydrous.
- a preferred extraction solvent is methanol, ethanol, acetone, MEK or a mixture thereof. Particularly preferred is methanol.
- Another object of the present invention is a process for the preparation of the organometallic framework according to the invention, in which AI 1 "is provided by anodic oxidation for the reaction.
- organometallic frameworks by electrochemical means is described in WO-A 2005/049892.
- the organometallic framework according to the invention can be present in powder form or as an agglomerate.
- the framework material may be used as such or it may be converted into a shaped body. Preferred methods here are the extrusion or tableting. In the production of moldings, the
- Framework material other materials, such as binders, lubricants or others
- the framework material has other constituents, such as for example
- Adsorbents such as activated carbon or the like.
- pellets such as disc-shaped pellets, pills, spheres, granules, extrudates such as strands, honeycomb, mesh or hollow body may be mentioned.
- suitable method such as extruding; optionally washing and / or drying and / or calcining the extrudate; optional assembly.
- the framework material can then be further processed according to the method described above to give a shaped body.
- Kneading / mulling and shaping can be carried out according to any suitable method, as described, for example, in Ullmanns Enzyklopadie der Technischen Chemie, 4th edition, volume 2, p. 313 et seq. (1972).
- the kneading / hulling and / or shaping by means of a reciprocating press, roller press in the presence or absence of at least one binder material, compounding, pelleting, tableting, extrusion, co-extruding, foaming, spinning, coating, granulation, preferably spray granulation, spraying, spray drying or a combination of two or more of these methods.
- pellets and / or tablets are produced.
- Kneading and / or shaping may be carried out at elevated temperatures, for example in the range from room temperature to 300 ° C. and / or at elevated pressure, for example in the range from atmospheric pressure to several hundred bar and / or in a protective gas atmosphere such as in the presence of at least one Noble gas, nitrogen or a mixture of two or more thereof.
- binders for the purposes of the present invention may be both viscosity-increasing and viscosity-reducing compounds.
- Preferred binders include, for example, alumina or alumina-containing binders, as described, for example, in WO 94/29408, silicon dioxide, as described, for example, in EP 0 592 050 A1, mixtures of silica and alumina, such as those described in US Pat WO 94/13584, clay minerals, as described, for example, in JP 03-037156 A, for example montmorillonite, kaolin, bentonite, halloysite, dickite, nacrit and anauxite, alkoxysilanes, as described, for example, in EP 0 102 544 B1, for example, tetraalkoxysilanes such as tetramethoxysilane, tetraethoxysilane, tetrapropoxysilane, tetrabutoxysilane, or for example trialkoxysilanes such as trimethoxysilane, triethoxysilane, tripropoxys
- an organic compound and / or a hydrophilic polymer such as cellulose or a cellulose derivative such as methylcellulose and / or a polyacrylate and / or a polymethacrylate and / or a polyvinyl alcohol and / or a polyvinylpyrrolidone and / or a polyisobutene and / or a polytetrahydrofuran and / or a polyethylene oxide.
- a pasting agent inter alia, preferably water or at least one alcohol such as a monoalcohol having 1 to 4 carbon atoms such as methanol, ethanol, n-propanol, iso-propanol, 1-butanol, 2-butanol, 2-methyl-1 propanol or 2-methyl-2-propanol or a mixture of water and at least one of said alcohols or a polyhydric alcohol such as a glycol, preferably a water-miscible polyhydric alcohol alone or as a mixture with water and / or at least one of said monovalent Alcohols are used.
- a monoalcohol having 1 to 4 carbon atoms such as methanol, ethanol, n-propanol, iso-propanol, 1-butanol, 2-butanol, 2-methyl-1 propanol or 2-methyl-2-propanol or a mixture of water and at least one of said alcohols or a polyhydric alcohol such as a glycol, preferably a water
- the order of the additives such as template compound, binder, pasting agent, viscosity-increasing substance in the molding and kneading is basically not critical.
- the molding obtained according to kneading and / or molding is subjected to at least one drying, which is generally carried out at a temperature in the range of 25 to 300 ° C, preferably in the range of 50 to 300 ° C and more preferably in the range of 100 to 300 ° C is performed. It is also possible to dry in vacuo or under a protective gas atmosphere or by spray drying. According to a particularly preferred embodiment, as part of this drying process, at least one of the compounds added as additives is at least partially removed from the shaped body.
- Another object of the present invention is the use of the porous organometallic framework according to the invention for receiving at least one substance for its storage, separation, controlled release or chemical reaction and as a carrier material, for example for metals, metal oxides, metal sulfides or other framework structures, and in catalysis.
- the at least one substance may be a gas or a liquid.
- the substance is a gas.
- gas and liquid are used in a simplified manner, but here too gas mixtures and liquid mixtures or liquid solutions are to be understood by the term “gas” or "liquid”.
- Preferred gases are hydrogen, hydrocarbons, in particular methane, ethane, ethene, acetylene, propane, n-butane and i-butane, carbon monoxide, carbon dioxide, nitrogen oxides, oxygen, sulfur oxides, halogens, halogenated hydrocarbons, NF 3 , SF 6 , ammonia, boranes , Phosphenes, hydrogen sulfide, amines, formaldehyde, edegases, in particular helium, neon, argon, krypton and xenon.
- an organometallic framework according to the invention for hydrogen storage and for the diffusion-limited reaction with large volume reactants.
- the above-mentioned reactions may be hydrogenations, liquid phase oxidation, liquid phase metathesis, alkoxylations, etherifications, transfers, alkylation, hydrolyzation or similar reactions.
- Typical large reactants in diffusion-limited reactions may be, for example, polyols, substituted benzenes, dyes or other compounds.
- the at least one substance may also be a liquid as described above.
- a liquid examples of such a liquid are disinfectants, organic or organic solvents, fuels - in particular gasoline or diesel, hydraulic, radiator, brake fluid or an oil, in particular machine oil.
- the liquid may be halogenated aliphatic or aromatic, cyclic or acyclic hydrocarbons or mixtures thereof.
- the at least one substance may be an odorant.
- the odorant is a volatile organic or inorganic compound containing at least one of nitrogen, phosphorus, oxygen, sulfur, fluorine, chlorine, bromine or iodine or an unsaturated or aromatic hydrocarbon or a saturated or unsaturated aldehyde or a Ketone is. More preferred elements are nitrogen, oxygen, phosphorus, sulfur, chlorine, bromine; especially preferred are nitrogen, oxygen, phosphorus and sulfur.
- the odorant is ammonia, hydrogen sulfide, sulfur oxides, nitrogen oxides, ozone, cyclic or acyclic amines, thiols, thioethers and aldehydes, ketones, esters, ethers, acids or alcohols.
- ammonia hydrogen sulphide
- organic acids preferably acetic acid, propionic acid, butyric acid, isobutyric acid, valeric acid, isovaleric acid, caproic acid, heptanoic acid, lauric acid, pelargonic acid
- cyclic or acyclic hydrocarbons which contain nitrogen or sulfur and saturated or unsaturated aldehydes, such as hexanal, heptanal, octanal, nonanal, decanal, octenal or notenal and in particular volatile aldehydes such as butyraldehyde, propionaldehyde, acetaldehyde and formaldehyde and also fuels such as gasoline, diesel (ingredients).
- the odorous substances may also be fragrances which are used, for example, for the production of perfumes.
- fragrances or oils which release such fragrances include essential oils, basil oil, geranium oil, mint oil, cananga oil, cardamom oil, lavender oil, peppermint oil, nutmeg oil, camomile oil, eucalyptus oil, rosemary oil, lemon oil, lime oil, orange oil, bergamot oil, clary sage oil, coriander oil, cypress oil, 1,1-dimethoxy-2-pherylethane, 2,4-dimethyl-4-phenyltetrahydrofuran, dimethyltetrahydrobenzaldehyde, 2,6- Dimethyl-7-octene-2-ol, 1,2-diethoxy-3,7-dimethyl-2,6-octadiene, phenylacetaldehyde, rose oxide, ethyl 2-methyl-pentanoate, 1- (2,6- J- 6-trimethyl
- a volatile odorant preferably has a boiling point or boiling point range of less than 300 ° C. More preferably, the odorant is a volatile compound or mixture. In particular, preferably, the odor substance has a boiling point or boiling range below 250 ° C, more preferably less than 230 ° C, particularly preferably less than 200 0 C.
- odors which have a high volatility.
- a volatile odorant preferably has a vapor pressure greater than 0.001 kPa (20 ° C). More preferably, the odorant is a volatile compound or mixture. More preferably, the odorant has a vapor pressure of greater than 0.01 kPa (20 ° C.), more preferably a vapor pressure greater than 0.05 kPa (20 ° C.). Most preferably, the odors have a vapor pressure of greater than 0.1 kPa (20 ° C).
- TEM Transmission electron microscope
- the TEM image is taken by adding a little ethanol to the sample and grinding between 2 glass slides. Then it is thinly spread and dabbed with a Formvar / charcoal-coated refparatträgemetzchen. The images were taken with a 200 kV FEG-TEM from FEI. Device name: Tecnai G 2 .
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- General Health & Medical Sciences (AREA)
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020087004873A KR101423784B1 (ko) | 2005-08-22 | 2006-08-16 | 메조다공성 금속-유기 골격구조체 |
CA002618869A CA2618869A1 (en) | 2005-08-22 | 2006-08-16 | Mesoporous metal-organic framework |
AT06792831T ATE489353T1 (de) | 2005-08-22 | 2006-08-16 | Mesoporöses metallorganisches gerüstmaterial |
CN2006800303351A CN101243034B (zh) | 2005-08-22 | 2006-08-16 | 中孔的金属-有机框架 |
DE502006008393T DE502006008393D1 (de) | 2005-08-22 | 2006-08-16 | Mesoporöses metallorganisches gerüstmaterial |
EP06792831A EP1917228B1 (de) | 2005-08-22 | 2006-08-16 | Mesoporöses metallorganisches gerüstmaterial |
JP2008527444A JP5455367B2 (ja) | 2005-08-22 | 2006-08-16 | メソ孔の金属有機骨格材料 |
US11/996,976 US7842827B2 (en) | 2005-08-22 | 2006-08-16 | Mesoporous metal-organic framework |
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DE102005039654.2 | 2005-08-22 | ||
DE102005039654A DE102005039654A1 (de) | 2005-08-22 | 2005-08-22 | Mesoporöses metallorganisches Gerüstmaterial |
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US (1) | US7842827B2 (de) |
EP (1) | EP1917228B1 (de) |
JP (1) | JP5455367B2 (de) |
KR (1) | KR101423784B1 (de) |
CN (1) | CN101243034B (de) |
AT (1) | ATE489353T1 (de) |
CA (1) | CA2618869A1 (de) |
DE (2) | DE102005039654A1 (de) |
ES (1) | ES2356130T3 (de) |
WO (1) | WO2007023119A1 (de) |
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JP2009096722A (ja) * | 2007-10-12 | 2009-05-07 | Nippon Oil Corp | 多孔性金属錯体及びその製造方法 |
JP2009196960A (ja) * | 2008-02-25 | 2009-09-03 | Honda Motor Co Ltd | 水素貯蔵材 |
WO2009128636A3 (en) * | 2008-04-17 | 2010-01-14 | Korea Reserach Institute Of Chemical Technology | New porous nanohybrid materials formed by covalent hybridization between metal-organic frameworks and gigantic mesoporous materials |
WO2010058123A1 (fr) | 2008-11-18 | 2010-05-27 | Centre National De La Recherche Scientifique -Cnrs- | Procede de preparation hydrothermale de carboxylates d'aluminium poreux cristallises de type "metal-organic framework" |
WO2010058124A1 (fr) | 2008-11-18 | 2010-05-27 | Centre National De La Recherche Scientifique -Cnrs- | Procede de preparation d'azocarboxylates aromatiques d'aluminium poreux et cristallises de type "metal-organic framework" |
WO2012028989A1 (en) * | 2010-09-01 | 2012-03-08 | Basf Se | Process for producing carbon-comprising composite |
CN106397491A (zh) * | 2016-08-31 | 2017-02-15 | 太原理工大学 | 一种利用助剂二甲胺合成Ni‑BTC的方法 |
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- 2005-08-22 DE DE102005039654A patent/DE102005039654A1/de not_active Withdrawn
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2006
- 2006-08-16 ES ES06792831T patent/ES2356130T3/es active Active
- 2006-08-16 US US11/996,976 patent/US7842827B2/en active Active
- 2006-08-16 CA CA002618869A patent/CA2618869A1/en not_active Abandoned
- 2006-08-16 AT AT06792831T patent/ATE489353T1/de active
- 2006-08-16 WO PCT/EP2006/065346 patent/WO2007023119A1/de active Application Filing
- 2006-08-16 KR KR1020087004873A patent/KR101423784B1/ko active IP Right Grant
- 2006-08-16 EP EP06792831A patent/EP1917228B1/de active Active
- 2006-08-16 JP JP2008527444A patent/JP5455367B2/ja active Active
- 2006-08-16 DE DE502006008393T patent/DE502006008393D1/de active Active
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2009096722A (ja) * | 2007-10-12 | 2009-05-07 | Nippon Oil Corp | 多孔性金属錯体及びその製造方法 |
JP2009196960A (ja) * | 2008-02-25 | 2009-09-03 | Honda Motor Co Ltd | 水素貯蔵材 |
KR101034988B1 (ko) * | 2008-04-17 | 2011-05-17 | 한국화학연구원 | 유무기 혼성체 및 거대 메조세공 물질의 공유결합에 의하여 형성된 초다공성 유무기 나노세공 복합체 |
WO2009128636A3 (en) * | 2008-04-17 | 2010-01-14 | Korea Reserach Institute Of Chemical Technology | New porous nanohybrid materials formed by covalent hybridization between metal-organic frameworks and gigantic mesoporous materials |
US8907114B2 (en) | 2008-11-18 | 2014-12-09 | Centre National de la Recherche Scientifique—CNRS— | Method for preparing metal-organic framework crystallised and porous aluminium aromatic azocarboxylates |
WO2010058124A1 (fr) | 2008-11-18 | 2010-05-27 | Centre National De La Recherche Scientifique -Cnrs- | Procede de preparation d'azocarboxylates aromatiques d'aluminium poreux et cristallises de type "metal-organic framework" |
JP2012509360A (ja) * | 2008-11-18 | 2012-04-19 | セントレ ナショナル デ ラ リシェルシェ サイエンティフィック(セ・エン・エル・エス) | 金属有機構造体型結晶性ポーラスアルミニウムカルボキシラートの水熱製造方法 |
EP2376504B1 (de) * | 2008-11-18 | 2013-07-31 | Centre National de la Recherche Scientifique - CNRS | Verfahren zur herstellung von in einem organometallischen rahmen kristallisierten und porösen aromatischen aluminiumazocarboxylaten |
WO2010058123A1 (fr) | 2008-11-18 | 2010-05-27 | Centre National De La Recherche Scientifique -Cnrs- | Procede de preparation hydrothermale de carboxylates d'aluminium poreux cristallises de type "metal-organic framework" |
WO2012028989A1 (en) * | 2010-09-01 | 2012-03-08 | Basf Se | Process for producing carbon-comprising composite |
CN106397491A (zh) * | 2016-08-31 | 2017-02-15 | 太原理工大学 | 一种利用助剂二甲胺合成Ni‑BTC的方法 |
WO2019057050A1 (zh) * | 2017-09-19 | 2019-03-28 | 太原理工大学 | 一种多孔复合骨架材料的浆态合成方法 |
WO2023002141A1 (fr) | 2021-07-23 | 2023-01-26 | Centre National De La Recherche Scientifique | Procede de preparation d'un tetracarboxylate d'aluminium poreux cristallise de type mof, et utilisations de celui-ci |
Also Published As
Publication number | Publication date |
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CN101243034A (zh) | 2008-08-13 |
JP5455367B2 (ja) | 2014-03-26 |
EP1917228B1 (de) | 2010-11-24 |
US7842827B2 (en) | 2010-11-30 |
CN101243034B (zh) | 2011-04-20 |
JP2009504797A (ja) | 2009-02-05 |
KR20080038191A (ko) | 2008-05-02 |
KR101423784B1 (ko) | 2014-07-25 |
US20080188677A1 (en) | 2008-08-07 |
ATE489353T1 (de) | 2010-12-15 |
DE502006008393D1 (de) | 2011-01-05 |
ES2356130T3 (es) | 2011-04-05 |
DE102005039654A1 (de) | 2007-03-01 |
EP1917228A1 (de) | 2008-05-07 |
CA2618869A1 (en) | 2007-03-01 |
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