WO2007014530A1 - Alliage de brasage sans plomb contenant un systeme sn-ag-cu-ni-al - Google Patents

Alliage de brasage sans plomb contenant un systeme sn-ag-cu-ni-al Download PDF

Info

Publication number
WO2007014530A1
WO2007014530A1 PCT/CN2006/001943 CN2006001943W WO2007014530A1 WO 2007014530 A1 WO2007014530 A1 WO 2007014530A1 CN 2006001943 W CN2006001943 W CN 2006001943W WO 2007014530 A1 WO2007014530 A1 WO 2007014530A1
Authority
WO
WIPO (PCT)
Prior art keywords
solder alloy
lead
free
alloy
solder
Prior art date
Application number
PCT/CN2006/001943
Other languages
English (en)
French (fr)
Inventor
Jusheng Ma
Original Assignee
Jusheng Ma
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jusheng Ma filed Critical Jusheng Ma
Priority to JP2008524347A priority Critical patent/JP2009502513A/ja
Publication of WO2007014530A1 publication Critical patent/WO2007014530A1/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C13/00—Alloys based on tin

Definitions

  • the present invention relates to a tin-silver-copper-nickel-aluminum-based lead-free solder alloy, and more particularly to a lead-free solder suitable for use in soldering solders for electronic assembly and packaging, and in the fields of electronics, electrical equipment, communication equipment, automobiles, and the like. Electronic materials and electronic preparation technology. Background technique
  • Sn-Pb alloy plays a dominant role in the assembly of electronic components.
  • Sn-Pb alloy has excellent wettability and weldability, electrical conductivity, mechanical properties, low cost, etc., due to the toxicity of Pb and Pb compounds, improper use can pollute the environment and damage the health of workers.
  • the protection laws are becoming more sophisticated and strict, and the call for the use of lead is increasing.
  • Sn-Ag-Cu alloys have good application prospects in current lead-free solders, and have been recommended by NEMI, UK OTI, Soldertec, etc.
  • U.S. Patent No. 4,778,733 the disclosure of which is incorporated herein by reference to U.S. Patent No. 4, 778, 733, which is incorporated herein by reference.
  • US Patent 4, 758, 407 adds element Ni to Sn-AS (0-5.
  • the object of the present invention is to provide a tin-silver-copper-nickel-aluminum-based lead-free solder alloy to optimize the microstructure of the solder alloy and improve the application characteristics of the solder.
  • the balance is Sn and unavoidable impurities.
  • the tin-silver-copper-nickel-aluminum-based lead-free solder alloy proposed by the present invention can obtain various physical forms such as a paste, a powder, a block, a rod, a ball and a wire by a general production method known in the prior art, and further Welding processes, such as reflow, wave soldering and hand soldering, meet a variety of needs.
  • the tin-silver-copper-nickel-aluminum-based lead-free solder alloy prepared by the method of the invention has the advantages of improving the spreading rate of the alloy solder, that is, the solder has good wettability on the soldering member; second, the oxidation resistance is good, the lead-free solder Ni in the alloy improves the oxidation resistance of the alloy.
  • A1 easily forms a deep oxide film on the surface of the solder, protects the alloy, and removes the oxide film by using a solvent during welding, so that the joint strength is high, the structure is uniform, and the defects are few; The stability of the solder is improved, and the soldering characteristics of the solder are not deteriorated. ⁇ Detailed implementation
  • each additive element in the present invention has its optimum content.
  • Ag can form a Sn-Ag eutectic with the Sn matrix to lower the melting point of the solder and improve the mechanical properties of the solder, especially the Sn-Ag solder and the conventional Sn- Pb eutectic has excellent creep fatigue resistance. If the amount of Ag added is less than 0.5%, these effects will not be obvious. Adding more than 5.0% of Ag causes the liquidus temperature of the solder alloy to rise sharply, resulting in an increase in the soldering temperature, which may cause thermal damage to the electronic components. 5 ⁇ 4. 0% ⁇ The Ag content is preferably 1. 5 ⁇ 4. 0%.
  • the addition of Cu forms a ternary eutectic between Sn-Ag-Cu to further reduce the melting point of the solder.
  • the Cu element can also improve the wettability of the Sn-Ag system.
  • the presence of Cu element can also increase the strength of the solder to compensate for the shortcomings of insufficient strength of the Sn-Ag solder.
  • Sn-Ag-Cu eutectic solders also have higher strength.
  • the Cu present in the molten solder pot has a tendency to inhibit copper from melting in the copper foil wire.
  • the additional effect of solder pot diffusion The ratio of the Cu content is 0.1 to 2. 0%.
  • the element Ni suppresses dissolution of Cu into the molten solder, and reduces the rate of dissolution of Cu into the molten solder and the possibility of bridging.
  • Ni controls intermetallic compounds such as Ct-Sn5 and Cu3Sn formed as a result of the reaction of Sn and Cu, and dissolves the formed compounds.
  • A1 Anti-oxidation micro-mechanism analysis Since A1 is a face-centered cubic structure, it has isotropic characteristics, so the solder When the alloy is solidified, A1 is precipitated in the form of highly dispersed microscopic dots and distributed in the alloy matrix. Each tiny particle has an antioxidant protection effect on the alloy matrix in a certain range. Thus, with a smaller amount of A1, the desired antioxidant effect can be achieved.
  • each of the examples can be produced by a general method of casting, that is, weighing a metal raw material, and heating and stirring in air in a crucible or a crucible.
  • the raw material metal is melted in the air, and impurities or non-metals in the raw material metal and alloy react with the air, and as a result, a soluble gas such as soluble nitrogen or oxygen remains in the tantalum alloy to lower the weldability. Therefore, the lead-free alloy of the present invention is preferably smelted in a vacuum or in an inert gas.
  • the weight percentage of each chemical component in the lead-free solder alloy is: Ag: 3.8, Cu: 0.3, Al: 0.1, Ni: 0.02, and the balance is Sn.
  • the obtained solder alloy had a solidus temperature of 216.13 ° C, a liquidus temperature of 219.53 ⁇ , and a spread ratio of 91.3%.
  • the weight percentage of each chemical component in the lead-free solder alloy is: Ag: 3.5, Cu: 0.7, Al: 0.2, Ni: 0.10, and the balance is Sn.
  • the obtained solder alloy had a solidus temperature of 216.13 ° C, a liquidus temperature of 219.53 ⁇ , and a spread ratio of 91.3%.
  • the weight percentage of each chemical component in the lead-free tantalum alloy is: Ag: 3.0, Cu: 1, Al: 0.3, Ni: 0.40, and the balance is Sn.
  • the obtained solder alloy had a solidus temperature of 216.96 ° C, a liquidus temperature of 220.20 ° C, and a spreading ratio of 94.3%.
  • the weight percentage of each chemical component in the lead-free solder alloy is: Ag: 2.0, Cu: 1.5, Al: 0.4, Ni: 0.70, and the balance is Sn.
  • the obtained solder alloy had a solidus temperature of 220.66 ° C, a liquidus temperature of 223.12 ° C, and a spreading ratio of 87.1%.
  • the weight percentage of each chemical component in the lead-free solder alloy is: Ag: 2.5, Cu: 1.5, Al: 0.5, Ni: 1.00, and the balance is Sn.
  • the obtained solder alloy had a solidus temperature of 219.81 ° C, a liquidus temperature of 222.47 ° C, and a spreading ratio of 87.7%.
  • the weight percentage of each chemical component in the lead-free solder alloy is: Ag: 3.5, Cu: 0.75, Al: 0.001, Ni: 0.1, and the balance is Sn.
  • the resulting solder alloy had a solidus temperature of 217 ° C and a liquidus temperature of 219. C, the spread rate is 88.5%.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electric Connection Of Electric Components To Printed Circuits (AREA)

Description

一种锡银铜镍铝系无铅焊料合金 技术领域 '
本发明涉及一种锡银铜镍铝系无铅焊料合金， 更具体地涉及一种适合用于电子组装 与封装及电子、 电气设备、 通讯器材、 汽车等领域钎焊焊料的无铅焊料， 属于电子材料 及电子制备技术领域。 背景技术
Sn-Pb合金作为现代电子工业的主要封接材料，在电子部件的装配上占着主导地位。 虽然 Sn-Pb合金具有优异的润湿性及焊接性、 导电性、 力学性能、 成本低等特点， 但是 由于 Pb及 Pb化合物具有毒性， 使用不当会污染环境且损害工人的身体健康， 随着环境 保护法规的日趋完善和严格， 禁止使用铅的呼声日益高涨。
因此， 各国纷纷出台有关禁止含铅焊料在电子产业中使用的法令。 2000年 6月： 美 国 IPCLead- FreeRoadmap第 4版发表， 建议美国企业界于 2001年推出无铅化电子产品， 2004年实现全面无铅化： 欧洲则在推动无铅立法上采取了更为积极的态度， 2003年 2 月 13日， 欧盟在其 《官方公报》上公布 {关于在电子电气设备中禁止使用某些有害物质 指 令 》 ， 正 式 批 准 WEEE(WasteElectricalandElectronicEquipment) 和 Rolls (RestrictionofHazardousSubstances)的官方指令生效， 强制要求自 2006年 7月 1 日起， 在欧洲市场上销售的电子产品必须为无铅的电子产品； 亚洲方面， 日本政府从 2003年 1月开始全面推行无铅化， 并以 "无铅"牌阻止或限制美、 中、 韩、 台湾地区及 欧洲有铅电子产品的进口； 中国政府已于 2003年 3月由信息产业部拟定《电子信息产 品生产污染防治管理法》 自 2006年 7月 1日禁止电子产品含铅。
在当前的的无铅焊料中 Sn-Ag- Cu系合金具有较好的应用前景， 得到了美国 NEMI、 英 国 OTI、 Soldertec等的推荐。基于 Sn- Ag-Cu系，美国专利 4， 778， 733提出由 Sn-Ag (0. 05_3 % ) -cu (0. 7- 6 % ) 组成的无铅焊料； 美国专利 5， 527, 628叙述了组成为 93. 6Sn- 4. 7Ag- 1. 7Cu的合金； 美国专利 5， 863， 493给出了 Sn- Ag (2. 0-5. 0%) -cu (0-2. 9%) 的无铅焊料： 另外， 美国专利 4， 758, 407在 Sn- AS (0-5. 0 ) -cu (3. 0-5. 0 %)的基础上添 加元素 Ni ; 美国专利 6， 179, 935则在 Sn- As (0-4. 0 % ) - Cu (0- 2. 0 % )的基础上添加 微量元素 M和 Ge。 对于 Sn- Ag- Cu系焊料合金来说， 综合性能比较优越， 但也具 有润湿性较差， 合金组织粗大、 分布不均匀等缺点。 发明内容 本发明的目的是提出一种锡银铜镍铝系无铅焊料合金， 以优化焊料合金的微观结 构， 提高焊料的应用特性。
本发明提出的锡银铜镍铝系无铅焊料合金， 其中各化学成分的重量百分比为：
Ag 1· 5〜4. 0
Cu 0· 1〜2. 0
Al 0. 001〜0· 5
Ni 0. 01〜1· 0
余量为 Sn和不可避免的杂质。
本发明提出的锡银铜镍铝系无铅焊料合金， 可以通过现有技术中已知的一般制 作方法获得各种物理形式， 如膏、 粉、 块、 棒、 球和丝等， 进而进行多种焊接工 艺， 如再流焊、 波峰焊和手工焊等， 满足多种需要。
利用本发明方法制备的锡银铜镍铝系无铅焊料合金，其优点一是提高了合金焊料 的铺展率， 即焊料在焊接件上的浸润性好； 二是抗氧化性好， 无铅焊料合金中的 Ni提高 合金的抗氧化性， 其中的 A1易于在焊料表面形成深的氧化膜， 保护合金， 焊接时利用溶 剂将氧化膜去除， 使焊接点结合强度高， 组织均匀， 缺陷少； 三是焊料的稳定性提高， 焊料的焊接特性不会恶化。 ^ 具体实施方式
下面详细说明本发明中各添加元素的作用及其最佳含量： Ag可以与 Sn基体形 成 Sn- Ag共晶以降低焊料的熔点、 提高焊料的力学性能， 尤其 Sn- Ag系焊料与传统 Sn-Pb共晶相比有着优异的抗蠕变疲劳性能。 如果 Ag的加入量少于 0. 5 % , 这些作 用就将不明显。 加入 5. 0 %以上的 Ag会使焊料合金的液相线温度急剧升高， 导致 钎焊温度的升高从而使电子元器件可能会遭受热损伤。 Ag含量优选的是 1. 5〜4. 0 %。 加 Cu可以使 Sn- Ag- Cu间形成三元共晶以进一步降低焊料的熔点。 Cu元素还 可以提高 Sn- Ag系悍料的浸润性。 Cu元素的存在也可以提高焊料的强度以弥补 Sn - Ag焊料强度不足这一缺点。 Sn- Ag- Cu共晶焊料也有着更高的强度。 并且， 当通 过在熔融的焊料锅中浸焊的方式， 向敷有铜箔导线的的印刷电路板上钎焊电子元 件时， 熔融焊料锅中存在的 Cu具有抑制铜箔导线中的铜向熔融焊料锅扩散的额外 作用。 Cu含量的优选是 0. 1~2 . 0 %。 元素 Ni可以抑制 Cu向熔融焊料中的溶解， 降 低 Cu向熔融焊料中的溶解速度以及桥连发生的可能性。 Ni控制由于 Sn和 Cu反应的 结果而形成的金属间化合物如 Ct— Sn5和 Cu3Sn， 并使这些形成的化合物溶解。 A1 抗氧化微观机理解析： 由于 A1是面心立方结构， 具有各向同性的特征， 所以焊料 合金在凝固时， A1是以高度弥散的微小质点的形式析出并分布于合金基体中， 每 一个微小质点都对周围一定范围内的合金基体产生抗氧化保护作用。 这样， 用较 少量的 A1, 就能起到理想的抗氧化效果。
以下是本发明的实施例， 各实施例可以通过一般方法浇铸制造， 即称重金属 原料， 并在坩埚或熔锅中在空气中加热并搅拌。 但是， 在空气中熔化原料金属， 原料金属及合金中的杂质或非金属物与空气发生反应， 其结果是可溶性气体， 诸 如可溶性氮或氧存留在悍料合金中， 降低焊接性能。 因此， 本发明的无铅含量合 金最好在真空中或者在惰性气体中冶炼。
实施例 1
无铅焊料合金中各化学成分的重量百分比为： Ag: 3.8， Cu: 0.3， Al: 0.1， Ni: 0.02, 余量为 Sn。 所得焊料合金的固相线温度为 216.13°C， 液相线温度为 219.53Ό， 铺展率为 91.3%。 实施例 2
无铅焊料合金中各化学成分的重量百分比为： Ag: 3.5， Cu: 0.7, Al: 0.2， Ni: 0.10, 余量为 Sn。 所得焊料合金的固相线温度为 216.13°C， 液相线温度为 219.53Ό， 铺展率为 91.3%。 实施例 3
无铅悍料合金中各化学成分的重量百分比为: Ag: 3.0， Cu: 1， Al: 0.3, Ni: 0.40, 余量为 Sn。 所得焊料合金的固相线温度为 216.96°C， 液相线温度为 220.20°C， 铺展率 为 94.3%。 实施例 4
无铅焊料合金中各化学成分的重量百分比为： Ag: 2.0， Cu: 1.5， Al: 0.4， Ni: 0.70, 余量为 Sn。 所得焊料合金的固相线温度为 220.66°C， 液相线温度为 223.12°C， 铺展率为 87.1%。 实施例 5
无铅焊料合金中各化学成分的重量百分比为： Ag: 2.5， Cu: 1.5， Al: 0.5, Ni: 1.00， 余量为 Sn。 所得焊料合金的固相线温度为 219.81°C， 液相线温度为 222.47°C， 铺展率为 87.7%。 实施例 6
无铅焊料合金中各化学成分的重量百分比为： Ag: 3.5, Cu: 0.75, Al: 0.001， Ni: 0.1， 余量为 Sn。所得焊料合金的固相线温度为 217°C， 液相线温度为 219。C， 铺展率为 88.5%。

Claims

权利要求书
1、一种锡银铜镍铝系无铅焊料合金，其特征在于焊料合金中各化学成分的重」 分比为： Ag 1.5〜4.0
Cu 0.1〜2.0
A1 0.001〜0.5
Ni 0.01〜1.0
余量为 Sn。
PCT/CN2006/001943 2005-08-02 2006-08-02 Alliage de brasage sans plomb contenant un systeme sn-ag-cu-ni-al WO2007014530A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2008524347A JP2009502513A (ja) 2005-08-02 2006-08-02 Ｓｎ−Ａｇ−Ｃｕ−Ｎｉ−Ａｌ系無鉛はんだ合金

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN200510087383.1 2005-08-02
CNB2005100873831A CN1313631C (zh) 2005-08-02 2005-08-02 一种锡银铜镍铝系无铅焊料合金

Publications (1)

Publication Number Publication Date
WO2007014530A1 true WO2007014530A1 (fr) 2007-02-08

Family

ID=35930745

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2006/001943 WO2007014530A1 (fr) 2005-08-02 2006-08-02 Alliage de brasage sans plomb contenant un systeme sn-ag-cu-ni-al

Country Status (3)

Country Link
JP (1) JP2009502513A (zh)
CN (1) CN1313631C (zh)
WO (1) WO2007014530A1 (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103547407A (zh) * 2011-04-08 2014-01-29 日本斯倍利亚社股份有限公司 焊锡合金

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1313631C (zh) * 2005-08-02 2007-05-02 马莒生 一种锡银铜镍铝系无铅焊料合金
JP2017213602A (ja) * 2016-05-31 2017-12-07 株式会社日本スペリア社 はんだ付け方法及びはんだ継手
TW202403062A (zh) * 2018-12-27 2024-01-16 美商阿爾發金屬化工公司 無鉛焊料組成物
CN111112870A (zh) * 2019-12-20 2020-05-08 深圳市镱豪金属有限公司 一种环保锡条

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5863493A (en) * 1996-12-16 1999-01-26 Ford Motor Company Lead-free solder compositions
JPH11129091A (ja) * 1997-10-28 1999-05-18 Ngk Spark Plug Co Ltd 半田合金
CN1262159A (zh) * 1999-01-28 2000-08-09 株式会社村田制作所 无铅焊料和焊接制品
CN1443626A (zh) * 2003-04-16 2003-09-24 浙江大学 一种具有优越性价比的无铅焊料
CN1718797A (zh) * 2005-08-02 2006-01-11 马莒生 一种锡银铜镍铝系无铅焊料合金
CN1775455A (zh) * 2005-12-12 2006-05-24 黄德欢 一种Ag－Al－Cu－Ni－Sn系无铅焊锡

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4778733A (en) * 1986-07-03 1988-10-18 Engelhard Corporation Low toxicity corrosion resistant solder
US4758407A (en) * 1987-06-29 1988-07-19 J.W. Harris Company Pb-free, tin base solder composition
US5527628A (en) * 1993-07-20 1996-06-18 Iowa State University Research Foudation, Inc. Pb-free Sn-Ag-Cu ternary eutectic solder
US6179935B1 (en) * 1997-04-16 2001-01-30 Fuji Electric Co., Ltd. Solder alloys
JP2002283093A (ja) * 2001-03-27 2002-10-02 Toshiba Corp 非鉛系接合用合金
CN1176779C (zh) * 2001-11-27 2004-11-24 深圳市格林美环境材料有限公司 一种无铅焊料及其制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5863493A (en) * 1996-12-16 1999-01-26 Ford Motor Company Lead-free solder compositions
JPH11129091A (ja) * 1997-10-28 1999-05-18 Ngk Spark Plug Co Ltd 半田合金
CN1262159A (zh) * 1999-01-28 2000-08-09 株式会社村田制作所 无铅焊料和焊接制品
CN1443626A (zh) * 2003-04-16 2003-09-24 浙江大学 一种具有优越性价比的无铅焊料
CN1718797A (zh) * 2005-08-02 2006-01-11 马莒生 一种锡银铜镍铝系无铅焊料合金
CN1775455A (zh) * 2005-12-12 2006-05-24 黄德欢 一种Ag－Al－Cu－Ni－Sn系无铅焊锡

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
WANG W. ET AL.: "Effects of Addition Small Amount High Melting Point Metal on Properties of Lead-free Solders", ELECTRONIC COMPONENTS & MATERIALS, vol. 24, no. 9, September 2005 (2005-09-01), XP008076117 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103547407A (zh) * 2011-04-08 2014-01-29 日本斯倍利亚社股份有限公司 焊锡合金
US20140030140A1 (en) * 2011-04-08 2014-01-30 The University Of Queensland Solder alloy
EP2695701A1 (en) * 2011-04-08 2014-02-12 Nihon Superior Co., Ltd. Solder alloy
EP2695701A4 (en) * 2011-04-08 2014-09-24 Nihon Superior Co Ltd solder alloy
US9999945B2 (en) * 2011-04-08 2018-06-19 Nihon Superior Co., Ltd. Solder alloy

Also Published As

Publication number Publication date
JP2009502513A (ja) 2009-01-29
CN1313631C (zh) 2007-05-02
CN1718797A (zh) 2006-01-11

Similar Documents

Publication Publication Date Title
TWI383052B (zh) Low silver solder alloy and solder paste composition
JP4613823B2 (ja) ソルダペーストおよびプリント基板
GB2421030A (en) Solder alloy
TW201615854A (zh) 用於焊料層次的低溫高可靠度合金
EP2589459B1 (en) Bi-Sn-BASED HIGH-TEMPERATURE SOLDER ALLOY
CN103042315B (zh) 耐热耐湿低熔点无铅焊料合金
JPH09216089A (ja) はんだ合金、クリームはんだ、及びはんだ付け方法
CN102699563A (zh) 一种低银无铅软钎料
WO2007014529A1 (fr) Alliage de brasage sans plomb a point de fusion bas
JP2011156558A (ja) 鉛フリーはんだ合金
CN111230355B (zh) 无铅焊料合金
WO2010087241A1 (ja) 無鉛はんだ合金及び該はんだ合金を含む耐疲労性はんだ接合材並びに該接合材を使用した接合体
US20060210420A1 (en) Sn-zn lead-free solder alloy, its mixture, and soldered bond
CN111940945A (zh) 一种Sn-Zn-In-Ga无铅焊料及其制备方法
WO2007014530A1 (fr) Alliage de brasage sans plomb contenant un systeme sn-ag-cu-ni-al
EP1707302B1 (en) Pb-free solder alloy compositions comprising essentially tin (Sn), silver (Ag), copper (Cu), and phosphorus (P)
JP2019058950A (ja) 鉛フリーはんだ合金、電子回路基板及び電子制御装置
JP2004141926A (ja) 鉛非含有はんだ、および鉛非含有の継手
CA2540486A1 (en) Pb-free solder alloy compositions comprising essentially tin (sn), silver (ag), copper (cu), nickel (ni), phosphorus (p) and/or rare earth: cerium (ce) or lanthanum (la)
WO2019053866A1 (ja) 鉛フリーはんだ合金、電子回路基板及び電子制御装置
TWI236395B (en) Tin-zinc system lead-free solder alloy, and solder junction portion
US6936219B2 (en) Lead-free alloy
CN107614187A (zh) 焊料合金
KR100445350B1 (ko) 납땜용 무연합금
KR100666007B1 (ko) 필름콘덴서용 틴징크 솔더 와이어

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2008524347

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 06761618

Country of ref document: EP

Kind code of ref document: A1