WO2006069701A1 - Fungizide mischungen enthaltend enestroburin und mindestens einen wirkstoff der gruppe der azole - Google Patents
Fungizide mischungen enthaltend enestroburin und mindestens einen wirkstoff der gruppe der azole Download PDFInfo
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- WO2006069701A1 WO2006069701A1 PCT/EP2005/013782 EP2005013782W WO2006069701A1 WO 2006069701 A1 WO2006069701 A1 WO 2006069701A1 EP 2005013782 W EP2005013782 W EP 2005013782W WO 2006069701 A1 WO2006069701 A1 WO 2006069701A1
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
Definitions
- the present invention relates to fungicidal mixtures containing as active components
- Bitertanol bromuconazole, cyproconazole, difenoconazole, diniconazole, enilconazole, epoxiconazole, fluquinconazole, fenbuconazole, flusilazole, flutriafol,
- the invention relates to a method for controlling harmful fungi with mixtures of the compound I with active compounds II and the use of the compound I with active compounds II for the preparation of such mixtures and compositions containing these mixtures.
- the active ingredients II mentioned above as component 2 their preparation and their
- Prothioconazole 2- [2- (1-Chloro-cyclopropyl) -3- (2-chloro-phenyl) -2-hydroxypropyl] -2,4-dihydro- [1,2,4] triazole-3-thione (WO 96/16048); Simeconazole, ⁇ - (4-fluorophenyl) - ⁇ - [(trimethylsilyl) methyl] -1H-1, 2,4-triazole-1-ethanol
- Triticonazole (5 lbs) -5 - [(4-chlorophenyl) methylene] -2,2-dimethyl-1- (1 / 7-1 ) 2,4-triazol-1-ylmethoxycyclopentanol (FR 26 41 277),
- Cyazofamide 4-chloro-2-cyano- ⁇ /, ⁇ / -dimethyl-5- (4-methylphenyl) -1H-imidazole-1-sulfonamide (CAS RN 120116-88-3],
- Hymexazole 5-methyl-1,2-oxazol-3-ol (JP 518249, JP 532202).
- the present inventions were mixtures as an object that show an improved action against harmful fungi, especially for certain indications with reduced total amount of applied drugs.
- the mixtures of the compound I and of an active compound II or the simultaneous joint or separate use of the compound I and of an active compound II are distinguished by outstanding activity against a broad spectrum of phytopathogenic fungi, in particular from the class of the Ascomycetes, Deutero - mycetes, oomycetes and basidiomycetes. They are in part systemically effective and can be used in crop protection as foliar and soil fungicides.
- mixtures of compound I and of an active compound II are particularly suitable for combating Alternaria and Bofryf / s species.
- the compound I and active compounds II can be applied simultaneously together or separately or in succession, the sequence in the case of separate application generally having no effect on the control result.
- the pure active ingredients which, as required, are further active substances against harmful fungi or other pests such as insects, spider animals or nematodes, or else herbicidal or growth-promoting agents.
- gulierende agents or fertilizers can add as further active components.
- mixtures of compound I with an active ingredient If are used. Under certain circumstances, however, mixtures of compound I with two or optionally several active components may be advantageous.
- the compound I and the active compound II are usually employed in a weight ratio of 100: 1 to 1: 100, preferably 20: 1 to 1:20, in particular 10: 1 to 1:10.
- the further active components are added to the compound I in a ratio of from 20: 1 to 1:20.
- the application rates of the mixtures according to the invention are from 5 g / ha to 2000 g / ha, preferably from 50 to 900 g / ha, in particular from 50 to 750 g / ha.
- the application rates for the compound I are accordingly generally 1 to 1000 g / ha, preferably 10 to 900 g / ha, in particular 20 to 750 g / ha.
- the application rates for the active compound II are correspondingly generally 1 to 2000 g / ha, preferably 10 to 900 g / ha, in particular 40 to 500 g / ha.
- application rates of mixture of 1 to 1000 g / 100 kg of seed preferably 1 to 750 g / 100 kg, in particular 5 to 500 g / 100 kg, are generally used.
- the method for controlling harmful fungi is carried out by the separate or combined application of the compound I and the active compound II or the mixtures of the compound I and the active ingredient II by spraying or dusting the seeds, the plants or the soil before or after sowing the plants or before or after emergence of the plants.
- the mixtures according to the invention or the compound I and the active compound II can be converted into the customary formulations, for example solutions, emulsions, Suspensions, dusts, powders, pastes and granules.
- the application form depends on the respective purpose; It should in any case ensure a fine and uniform distribution of the compound according to the invention.
- the formulations are prepared in a known manner, e.g. by stretching the active ingredient with solvents and / or carriers, if desired using emulsifiers and dispersants.
- Suitable solvents / auxiliaries are essentially:
- aromatic solvents eg Solvesso products, xylene
- paraffins eg petroleum fractions
- alcohols eg methanol, butanol, pentanol, benzyl alcohol
- ketones eg cyclohexanone, gamma-butyrolactone
- pyrrolidones NMP, NOP
- Acetates glycols, dimethyl fatty acid amides, fatty acids and fatty acid esters.
- solvent mixtures can also be used
- Excipients such as ground natural minerals (e.g., kaolins, clays, talc, calks) and ground synthetic minerals (e.g., fumed silica, silicates); Emulsifiers such as nonionic and anionic emulsifiers (for example polyoxyethylene fatty alcohol ethers, alkyl sulfonates and arylsulfonates) and dispersants such as lignin liquors and methylcellulose.
- ground natural minerals e.g., kaolins, clays, talc, calks
- ground synthetic minerals e.g., fumed silica, silicates
- Emulsifiers such as nonionic and anionic emulsifiers (for example polyoxyethylene fatty alcohol ethers, alkyl sulfonates and arylsulfonates) and dispersants such as lignin liquors and methylcellulose.
- the surface-active substances used are alkali metal, alkaline earth metal, ammonium salts of lignin sulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalenesulfonic acid, alkylarylsulfonates, alkyl sulfates, alkyl sulfonates, fatty alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers, and condensation products of sulfonated naphthalene and naphthalene derivatives with formaldehyde , Condensation products of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenol polyglycol ethers, tributylphenyl
- emulsions, pastes or oil dispersions mineral oil fractions of medium to high boiling point, such as kerosine or diesel oil, coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, eg toluene, Xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes or derivatives thereof, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, strongly polar solvents, for example dimethylsulfoxide, N-methylpyrrolidone or water.
- Powders, dispersants and dusts may be prepared by mixing or co-grinding the active substances with a solid carrier.
- Granules e.g. Coated, impregnated and homogeneous granules can be prepared by binding the active compounds to solid carriers.
- Solid carriers are e.g. Mineral earths, such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bolus, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulphate, magnesium oxide, ground plastics, fertilizers, e.g. Ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas and vegetable products such as cereal flour, tree bark, wood and nutshell flour, cellulose powder and other solid carriers.
- Mineral earths such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bolus, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulphate, magnesium oxide, ground plastics
- the formulations generally contain between 0.01 and 95 wt .-%, preferably between 0.1 and 90 wt .-% of the active ingredients.
- the active compounds are used in a purity of 90% to 100%, preferably 95% to 100% (according to NMR spectrum).
- the formulations in question give, after dilution of from two to ten times, active compound concentrations of from 0.01 to 60% by weight, preferably from 0.1 to 40% by weight, in the ready-to-use preparations.
- formulations according to the invention are: 1. Products for dilution in water
- a Water-soluble concentrates (SL, LS)
- the active compounds 20 parts by weight are dissolved in 70 parts by weight of cyclohexanone with the addition of 10 parts by weight of a dispersant, e.g. Polyvinylpyrrolidone dissolved. Dilution in water gives a dispersion.
- a dispersant e.g. Polyvinylpyrrolidone dissolved. Dilution in water gives a dispersion.
- the active ingredient content is 20% by weight
- the active compounds 25 parts by weight of the active compounds are dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight).
- This mixture is added to water by means of an emulsifying machine (e.g., Ultraturax) in 30 parts by weight and made into a homogeneous emulsion. Dilution in water results in an emulsion.
- the formulation has an active ingredient content of 25% by weight.
- the active ingredients 20 parts by weight of the active ingredients are comminuted with the addition of 10 parts by weight of dispersants and wetting agents and 70 parts by weight of water or an organic solvent in a stirred ball mill to a fine active substance suspension. Dilution in water results in a stable suspension of the active ingredient.
- the active ingredient content in the formulation is 20% by weight.
- the active ingredients are finely ground with the addition of 50 parts by weight of dispersants and wetting agents and prepared by means of technical equipment (for example extrusion, spray tower, fluidized bed) as water-dispersible or water-soluble granules. Dilution in water results in a stable dispersion or solution of the active substance.
- the formulation has an active ingredient content of 50% by weight.
- WP 1 SP, SS, WS Water-dispersible and water-soluble powders 75 parts by weight of the active compounds are ground in a rotor-stator mill with the addition of 25 parts by weight of dispersing and wetting agents and silica gel. Dilution in water results in a stable dispersion or solution of the active ingredient.
- the active ingredient content of the formulation is 75% by weight.
- 0.5 parts by weight of the active ingredients are finely ground and combined with 99.5 parts by weight of carriers. Common processes are extrusion, spray drying or fluidized bed. This gives a granulate for direct application with 0.5 wt .-% active ingredient content.
- LS water-soluble concentrates
- FS suspensions
- DS dusts
- WS water-dispersible and water-soluble powders
- ES emulsions
- EC emulsifiable concentrates
- gel formulations GF
- FS formulations for seed treatment Preference is given to using FS formulations for seed treatment.
- such formulations contain 1 to 800 g / l active ingredient, 1 to 200 g / l surfactants, 0 to 200 g / l antifreeze, 0 to 400 g / l binder, 0 to 200 g / l dyes and solvents, preferably water.
- the active compounds may be used as such, in the form of their formulations or the forms of use prepared therefrom, e.g. in the form of directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dusts, scattering agents, granules by spraying, misting, dusting, scattering or pouring.
- the forms of application depend entirely on the intended use; In any case, they should ensure the finest possible distribution of the active compounds according to the invention.
- Aqueous application forms can be prepared from emulsion concentrates, pastes or wettable powders (wettable powders, oil dispersions) by adding water.
- the substances as such or dissolved in an oil or solvent, can be homogenized in water by means of wetter, tackifier, dispersant or emulsifier. But it can also be made of effective substance wetting, adhesion, dispersing or emulsifying and possibly solvent or oil concentrates, which are suitable for dilution with water.
- the active compound concentrations in the ready-to-use preparations can be varied within wide ranges. In general, they are between 0.0001 and 10%, preferably between 0.01 and 1%.
- the active ingredients can also be used with great success in the ultra-low-volume (ULV) process, it being possible to apply formulations containing more than 95% by weight of active ingredient or even the active ingredient without additives.
- UUV ultra-low-volume
- wetting agents To the active ingredients oils of various types, wetting agents, adjuvants, herbicides, fungicides, other pesticides, bactericides, optionally also just before use (tank mix), are added. These agents can be added to the compositions according to the invention in a weight ratio of 1: 100 to 100: 1, preferably 1:10 to 10: 1.
- adjuvants in this sense are in particular: organically modified polysiloxanes, eg Break Thru S 240 ® ; Alcohol alkoxylates, eg. As Atplus 245 ®, Atplus MBA 1303 ®, Plurafac LF 300 ® and Lutensol ON 30 ®; EO-PO block polymers, eg. B. Pluro- nic RPE 2035 ® and Genapol B ®; Alcohol ethoxylates, eg. As Lutensol XP 80 ®; and sodium dioctylsulfosuccinate, e. B. Leophen RA ®.
- organically modified polysiloxanes eg Break Thru S 240 ®
- Alcohol alkoxylates eg. As Atplus 245 ®, Atplus MBA 1303 ®, Plurafac LF 300 ® and Lutensol ON 30 ®
- EO-PO block polymers eg. B. Pluro
- the compounds I and II, or the mixtures or the corresponding formulations are applied by mixing the harmful fungi, the plants, seeds, soils, areas, materials or spaces to be kept free of them with a fungicidally effective amount of the mixture or of the compounds I and II when applied separately.
- the application can be made before or after the attack by the harmful fungi.
- the active ingredients were formulated separately as stock solution with a concentration of 10,000 ppm in DMSO.
- the active compounds were prepared separately or together as a stock solution with 25 mg of active ingredient, which with a mixture of acetone and / or DMSO and the emulsifier Uniperol® EL (wetting agent with emulsifying and dispersing action based on ethoxylated alkylphenols) in the volume Ratio solvent emulsifier of 99 to 1 ad 10 ml was filled. Subsequently was 100 ml with water. This stock solution was diluted with the described solvent-emulsifier-water mixture to the drug concentration given below.
- Uniperol® EL wetting agent with emulsifying and dispersing action based on ethoxylated alkylphenols
- the measured parameters were compared with the growth of the drug-free control variant and the fungus-free and active substance-free blank to determine the relative growth in% of the pathogens in the individual active ingredients.
- the efficiency (W) is calculated according to the formula of Abbot as follows:
- o corresponds to the fungal infestation of the treated plants in% and ß corresponds to the fungal infestation of the untreated (control) plants in%
- the infestation of the treated plants corresponds to that of the untreated control plants; at an efficiency of 100, the treated plants have no infestation.
- the stock solutions were mixed according to the ratio, pipetted into a microtiter plate (MTP) and diluted with an aqueous fungus nutrient medium based on malt to the stated active compound concentration. This was followed by the addition of an aqueous spore suspension of Botrytis cinerea.
- MTP microtiter plate
- the plates were placed in a water vapor saturated chamber at temperatures of 18 ° C. Using an absorption photometer, the MTPs were measured at 405 nm on the 7th day after inoculation.
- the stock solution was pipetted into a microtiter plate (MTP) and diluted to the indicated drug concentration with a pea-based aqueous fungal nutrient medium. This was followed by the addition of an aqueous zoospore suspension of Phytophthora infestans.
- MTP microtiter plate
- the plates were placed in a water vapor saturated chamber at temperatures of 18 ° C. With an absorption photometer, the MTPs were measured at 405 nm on the 7th day after inoculation.
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
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Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/793,789 US20080125318A1 (en) | 2004-12-23 | 2005-12-21 | Fungicidal Mixtures Containing Enestroburin and at Least One Active Substance from the Group of Azoles |
BRPI0519700-7A BRPI0519700A2 (pt) | 2004-12-23 | 2005-12-21 | misturas fungicidas, agente, processo para combater fungos nocivos fitopatogênicos, semente, uso dos compostos |
CA002590244A CA2590244A1 (en) | 2004-12-23 | 2005-12-21 | Fungicidal mixtures containing enestroburin and at least one active substance from the group of azoles |
EP05824105A EP1835804A1 (de) | 2004-12-23 | 2005-12-21 | Fungizide mischungen enthaltend enestroburin und mindestens einen wirkstoff der gruppe der azole |
JP2007547338A JP2008525349A (ja) | 2004-12-23 | 2005-12-21 | エネストロブリン、およびアゾール類の群から選択される少なくとも1種の活性物質を含有する殺菌剤混合物 |
AU2005321567A AU2005321567A1 (en) | 2004-12-23 | 2005-12-21 | Fungicidal mixtures containing enestroburin and at least one active substance from the group of azoles |
IL183679A IL183679A0 (en) | 2004-12-23 | 2007-06-05 | Fungicidal mixtures containing enestroburin and at least one active substance from the group of azoles |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004063303 | 2004-12-23 | ||
DE102004063303.7 | 2004-12-23 |
Publications (1)
Publication Number | Publication Date |
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WO2006069701A1 true WO2006069701A1 (de) | 2006-07-06 |
Family
ID=35840320
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2005/013782 WO2006069701A1 (de) | 2004-12-23 | 2005-12-21 | Fungizide mischungen enthaltend enestroburin und mindestens einen wirkstoff der gruppe der azole |
Country Status (10)
Country | Link |
---|---|
US (1) | US20080125318A1 (de) |
EP (1) | EP1835804A1 (de) |
JP (1) | JP2008525349A (de) |
KR (1) | KR20070093120A (de) |
CN (1) | CN101087525A (de) |
AU (1) | AU2005321567A1 (de) |
BR (1) | BRPI0519700A2 (de) |
CA (1) | CA2590244A1 (de) |
IL (1) | IL183679A0 (de) |
WO (1) | WO2006069701A1 (de) |
Cited By (8)
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WO2009043686A2 (de) * | 2007-09-27 | 2009-04-09 | Basf Se | Fungizide mischungen |
WO2009098210A2 (en) * | 2008-02-05 | 2009-08-13 | Basf Se | Pesticidal mixtures |
CN101258852B (zh) * | 2008-04-10 | 2010-12-22 | 江苏宝灵化工股份有限公司 | 氯啶菌酯、咪鲜胺杀菌组合物 |
WO2010061943A3 (en) * | 2008-11-25 | 2011-05-26 | Sumitomo Chemical Company, Limited | Composition and method for controlling plant diseases |
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US8691727B2 (en) | 2005-05-03 | 2014-04-08 | Syngenta Crop Protection, Llc | Pesticidal compositions |
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JP5365158B2 (ja) * | 2008-11-25 | 2013-12-11 | 住友化学株式会社 | 植物病害防除用組成物及び植物病害の防除方法 |
CN101485307B (zh) * | 2009-02-09 | 2013-02-13 | 吉林省八达农药有限公司 | 一种含有丁香菌酯与三唑类杀菌剂的农用杀真菌组合物 |
CN101647447B (zh) * | 2009-07-06 | 2012-07-04 | 东莞市瑞德丰生物科技有限公司 | 杀菌组合物 |
CN101622997B (zh) * | 2009-08-12 | 2012-08-22 | 深圳诺普信农化股份有限公司 | 一种增效农药组合物 |
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Also Published As
Publication number | Publication date |
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KR20070093120A (ko) | 2007-09-17 |
CN101087525A (zh) | 2007-12-12 |
AU2005321567A1 (en) | 2006-07-06 |
IL183679A0 (en) | 2007-09-20 |
BRPI0519700A2 (pt) | 2009-07-14 |
EP1835804A1 (de) | 2007-09-26 |
CA2590244A1 (en) | 2006-07-06 |
JP2008525349A (ja) | 2008-07-17 |
US20080125318A1 (en) | 2008-05-29 |
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