WO2006064949A1 - キャピラリーエレクトロウェッティング現象を用いたバルブ及びアクチュエータ - Google Patents
キャピラリーエレクトロウェッティング現象を用いたバルブ及びアクチュエータ Download PDFInfo
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- WO2006064949A1 WO2006064949A1 PCT/JP2005/023300 JP2005023300W WO2006064949A1 WO 2006064949 A1 WO2006064949 A1 WO 2006064949A1 JP 2005023300 W JP2005023300 W JP 2005023300W WO 2006064949 A1 WO2006064949 A1 WO 2006064949A1
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- passage
- electrode
- liquid
- voltage
- valve
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16K—VALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
- F16K13/00—Other constructional types of cut-off apparatus; Arrangements for cutting-off
- F16K13/08—Arrangements for cutting-off not used
- F16K13/10—Arrangements for cutting-off not used by means of liquid or granular medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/165—Prevention or detection of nozzle clogging, e.g. cleaning, capping or moistening for nozzles
- B41J2/16505—Caps, spittoons or covers for cleaning or preventing drying out
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/17—Ink jet characterised by ink handling
- B41J2/175—Ink supply systems ; Circuit parts therefor
- B41J2/17503—Ink cartridges
- B41J2/17513—Inner structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/17—Ink jet characterised by ink handling
- B41J2/175—Ink supply systems ; Circuit parts therefor
- B41J2/17596—Ink pumps, ink valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16K—VALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
- F16K99/00—Subject matter not provided for in other groups of this subclass
- F16K99/0001—Microvalves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16K—VALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
- F16K99/00—Subject matter not provided for in other groups of this subclass
- F16K99/0001—Microvalves
- F16K99/0003—Constructional types of microvalves; Details of the cutting-off member
- F16K99/0017—Capillary or surface tension valves, e.g. using electro-wetting or electro-capillarity effects
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16K—VALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
- F16K99/00—Subject matter not provided for in other groups of this subclass
- F16K99/0001—Microvalves
- F16K99/0003—Constructional types of microvalves; Details of the cutting-off member
- F16K99/0019—Valves using a microdroplet or microbubble as the valve member
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16K—VALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
- F16K99/00—Subject matter not provided for in other groups of this subclass
- F16K99/0001—Microvalves
- F16K99/0034—Operating means specially adapted for microvalves
- F16K99/0042—Electric operating means therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/14—Structure thereof only for on-demand ink jet heads
- B41J2002/14395—Electrowetting
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16K—VALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
- F16K99/00—Subject matter not provided for in other groups of this subclass
- F16K2099/0082—Microvalves adapted for a particular use
- F16K2099/0092—Inkjet printers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/206—Flow affected by fluid contact, energy field or coanda effect [e.g., pure fluid device or system]
- Y10T137/218—Means to regulate or vary operation of device
- Y10T137/2191—By non-fluid energy field affecting input [e.g., transducer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/206—Flow affected by fluid contact, energy field or coanda effect [e.g., pure fluid device or system]
- Y10T137/218—Means to regulate or vary operation of device
- Y10T137/2202—By movable element
- Y10T137/2213—Electrically-actuated element [e.g., electro-mechanical transducer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/206—Flow affected by fluid contact, energy field or coanda effect [e.g., pure fluid device or system]
- Y10T137/218—Means to regulate or vary operation of device
- Y10T137/2202—By movable element
- Y10T137/2218—Means [e.g., valve] in control input
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/206—Flow affected by fluid contact, energy field or coanda effect [e.g., pure fluid device or system]
- Y10T137/2224—Structure of body of device
Definitions
- the present invention relates to a valve capable of opening and closing a passage that connects two spaces separated from each other, and more particularly, to a valve and an actuator using a capacitive electrowetting phenomenon.
- An inkjet printer has an ink cartridge that supplies ink to an inkjet head that ejects ink.
- This ink cartridge is provided with an air communication path for allowing the air to flow into the ink cartridge by the reduced amount of the ink that has flowed out of the ink supply loca- tion for the purpose of smoothly supplying ink to the ink jet head.
- the ink inside the ink cartridge gradually evaporates and its viscosity increases.
- an ink cartridge (ink tank) is proposed in which the atmosphere communication passage is formed into a labyrinth structure that is narrowed and folded many times to reduce the ink evaporation rate. (For example, see Patent Document 1).
- Patent Document 1 Japanese Patent Laid-Open No. 11-105305 (FIG. 1)
- a general structure such as an electromagnetic valve capable of opening and closing the atmosphere communication path in the ink cartridge It is possible to prevent ink drying by opening the valve only when ink jet head force ink is ejected and closing the valve otherwise.
- a general valve such as a solenoid valve has a mechanism that drives a valve element that contacts the valve seat, and the structure is relatively complicated. , Ink cartridge manufacturing costs will be quite high
- a first passage that communicates two spaces separated from each other, and a second passage that branches from the first passage.
- a first electrode provided on a wall surface forming the second passage and a surface of the first electrode.
- a predetermined voltage is applied, a predetermined voltage is applied.
- a valve having a first insulating film in which the wetting angle of the first liquid on the surface thereof is lower than in a state where no voltage is applied.
- the valve may further include a voltage application unit that applies a predetermined voltage to the first electrode.
- This valve applies a predetermined voltage to the first electrode!
- the wetting angle of the first liquid on the surface of the first insulating film is changed, and the first liquid is moved between the first passage and the second passage.
- the first passage can be opened and closed. Therefore, the valve structure is simple with no moving parts, and the manufacturing cost can be kept low. In addition, noise and energy consumption during valve operation are reduced.
- the first liquid moves to the surface of the first insulating film in the second passage, and the first liquid moves to the first passage.
- the passage is opened and the application of the voltage to the first electrode is released, the first liquid moves from the first insulating film of the second passage to the force first passage and moves to the first passage. Is configured to be closed It may be.
- the wetting angle of the first liquid with respect to the first electrode in a state where a predetermined voltage is applied to the first electrode, the wetting angle of the first liquid with respect to the first electrode is less than 90 °, and the first electrode
- the wetting angle of the first liquid with respect to the first electrode can be 90 ° or more.
- the liquid wetting angle with respect to the surface of the first electrode is less than 90 °, so that the liquid is reliably moved from the first passage to the second passage. be able to.
- the wetting angle with respect to the surface of the first electrode becomes 90 ° or more, so that the liquid can be reliably moved from the second passage to the first passage.
- the first electrode and the first insulating film are formed at positions separated from the branching position force of the wall surface forming the second passage, and the wall surface forming the second passage is
- the wetting angle of the first liquid with respect to the vicinity of the branch position can be lower than the wetting angle of the first liquid with respect to the first insulating film in a state where the predetermined voltage is not applied to the first electrode.
- the first liquid partially enters the second passage in the vicinity of the branch position in a state where a predetermined voltage is not applied to the first electrode. Therefore, when a predetermined voltage is applied to the first electrode, the first liquid can easily move to the first passage force and the second passage, and the first passage is reliably opened.
- the valve of the present invention includes a second electrode provided on the wall surface forming the first passage, and a second insulating film provided on the surface of the second electrode.
- the unit may be configured to apply a voltage to the second electrode only when the predetermined voltage is not applied to the first electrode.
- a voltage is applied to the second electrode, the liquid wetting angle with respect to the second insulating film on the surface of the second electrode is reduced, so that the liquid easily flows from the second passage to the first passage.
- the passage can be closed more reliably.
- the voltage application state to the second electrode is released, the liquid wetting angle in the second insulating film of the first passage increases, so that the liquid flows into the first passage force second passage.
- the first passage can be opened more reliably.
- the responsiveness of the opening and closing operation of the valve becomes faster.
- a third electrode may be provided on a wall surface that forms an internal passage so as to be kept at a predetermined constant potential and to always contact the first liquid. According to this, since a potential difference is surely generated between the liquid in contact with the third electrode and the first electrode when a predetermined voltage is applied to the first electrode, the liquid on the surface of the first electrode The wetting angle is reliably reduced and the liquid is reliably transferred from the first passage to the second passage. Furthermore, when a predetermined voltage is applied to the second electrode, a potential difference is surely generated between the second electrode and the first liquid, so that the liquid wetting angle on the surface of the second electrode is reliably reduced. Thus, the first liquid can be reliably moved from the second passage to the first passage.
- the third electrode may be formed in the vicinity of the branch position of the wall surface forming the second passage.
- the first liquid can always be brought into contact with the third electrode, and the first liquid can be more reliably held at a predetermined constant potential.
- the passage area of the first passage may be larger than the passage area of the second passage. According to this, since the capillary force generated in the second passage is larger than the capillary force generated in the first passage, the first liquid can easily move from the first passage to the second passage, It can be opened more reliably. In addition, the responsiveness of the opening / closing operation becomes faster.
- the surface of the portion that is not in contact with the wall surface of the internal passage of the first liquid may be covered with a second liquid having non-volatility. According to this, the first liquid can be prevented from evaporating by covering with the non-volatile second liquid.
- a liquid supply source connected to the internal passage and supplying the first liquid to the internal passage may be provided. According to this, even when the first liquid in the internal passage evaporates and the amount thereof decreases, the first liquid can be supplied into the liquid supply source internal passage.
- the valve of the present invention is provided in an ink cartridge having an ink storage space formed therein and an air communication path that connects the ink storage space and the atmosphere, and the air communication path can be opened and closed. It may be configured. Therefore, when the ink in the ink storage space decreases, the air communication path is opened by the valve, so that the ink can be reduced. Since air can be introduced into the ink storage space from the outside, the ink can be smoothly supplied to the ink jet head. In addition, when ink is not supplied to the ink jet head, the air communication path is closed by a valve, so that the ink inside the ink cartridge can be prevented from drying up and increasing in viscosity. According to the present invention, an ink cartridge comprising such a valve is also provided.
- the valve of the present invention has a communication path that can be mounted on the ink discharge surface of an ink jet head that discharges ink to a recording medium, and communicates the space on the ink discharge surface side with the outside.
- the cap may be provided so that the communication path can be opened and closed. According to this, by opening the communication path with the valve and pressing the cap against the ink ejection surface of the inkjet head, the change in atmospheric pressure inside the cap is eliminated by the change in atmospheric pressure inside the cap, and the meniscus of the nozzle is damaged. Can be prevented. Furthermore, by closing the communication path with a valve after pressing the cap, it is possible to prevent the ink in the nozzle from drying. According to the present invention, a cap for an inkjet head comprising such a nozzle is also provided.
- the voltage application unit is configured to periodically apply a predetermined voltage to the first electrode. Also good. In this case, by opening and closing the passage with a valve every time a certain period of time elapses, the air present inside the ink cartridge or between the cap and the ink ejection surface due to a change in temperature or pressure of the outside air expands or It is possible to prevent shrinkage.
- the valve of the present invention further includes a third passage branched from the first passage, the second electrode is formed on the wall surface forming the first passage, and the second wall is formed on the wall surface forming the third passage. 3 electrodes are formed, the first passage communicates with the first space and the fourth space, the third passage communicates with the first space and the third space, and the second passage communicates with the first space. And the second space may communicate.
- the valve of the present invention functions as a multi-way valve.
- the first space is connected to the second space by applying a predetermined voltage to the third electrode without applying a voltage to the first electrode, and the predetermined voltage is applied to the first electrode without applying a voltage to the third electrode.
- a passage having an open end opened to a predetermined space, a plurality of electrodes provided in the passage, an insulating layer formed on the electrode, and movable in the passage And a conductive liquid is loaded in the passage so as to contact the plunger and the insulating layer.
- the actuator of the present invention is a new actuator that utilizes a phenomenon electrowetting phenomenon.
- a voltage By applying a voltage to a predetermined electrode, the wetting angle of the conductive liquid in the region of the insulating film formed on the electrode is reduced, and the conductive liquid moves to that region. Accordingly, the plunger can move in the passage in contact with the conductive liquid.
- the end opposite to the end of the plunger facing the predetermined space may be in contact with the liquid in the passage. Further, the plunger may be enclosed in the passage and contained in the liquid.
- the actuator of the present invention further includes a spindle, the electrode and the insulating layer are provided on the spindle, the plunger has a hollow portion, the spindle is accommodated in the hollow portion, and the plunger is It may be movable on the spindle via liquid.
- the actuator of the present invention may further include a voltage applying device that selectively applies a voltage to the plurality of electrodes.
- the actuator of the present invention and a wall provided at a predetermined interval from the opening end of the passage are provided, and a flow path is defined between the wall and the opening end.
- a flow path closing mechanism is provided in which the flow path is closed when the plunger protrudes from the opening end force and contacts the wall.
- the flow path opening / closing mechanism of the present invention can effectively control the flow of fluid using the actuator of the present invention.
- An engaging portion is formed at the tip of the plunger of the actuator, and an engaged portion that engages with the engaging portion is formed on the wall! ⁇ ⁇ Brief Description of Drawings
- FIG. 1 is a schematic configuration diagram of an ink jet printer according to a first embodiment.
- FIG. 2 is a perspective view of an ink cartridge.
- FIG. 3 is a cross-sectional view of an ink cartridge.
- FIG. 4 is an enlarged view of the vicinity of the valve in FIG.
- FIG. 5 is an enlarged sectional view of the valve.
- FIG. 6 is a block diagram showing an electrical configuration of the ink jet printer.
- FIG. 7 is a flowchart of a series of operations of the ink jet printer when printing is performed.
- ⁇ 8] A sectional view of the valve in a state where the first passage is closed.
- FIG. 10 is a cross-sectional view corresponding to FIG.
- FIG. 11 is a cross-sectional view corresponding to FIG.
- FIG. 12 is a cross-sectional view corresponding to FIG.
- FIG. 13 is a cross-sectional view corresponding to FIG.
- FIG. 14 is a schematic configuration diagram of an ink jet printer according to a second embodiment.
- FIG. 15 is a longitudinal sectional view of an ink jet head with a nozzle cap attached.
- FIG. 16 is an enlarged cross-sectional view of the valve of FIG.
- FIG. 17 is a block diagram showing an electrical configuration of the ink jet printer according to the second embodiment.
- FIG. 18 is a flowchart of a series of operations including a printing operation of the inkjet printer.
- FIG. 19 (a) is a cross-sectional view showing a state where a nozzle cap is attached to the ink jet head, and (b) is an enlarged cross-sectional view of the valve of (a).
- FIG. 20 (a) is a sectional view showing a state immediately before the nozzle cap is mounted on the ink jet head, and (b) is an enlarged sectional view of the valve of (a).
- FIG. 21 is a diagram conceptually showing a channel structure according to a third embodiment.
- FIG. 22 is a plan view of the flow path (lower plate) of the flow path structure according to the third embodiment, showing a state where gas cannot communicate.
- FIG. 23 is a plan view of the flow path (lower plate) of the flow path structure according to the third embodiment, showing a state in which the first flow path and the third flow path are in communication!
- FIG. 24 is a plan view of the flow path (lower plate) of the flow path structure according to the third embodiment, showing a state where the first flow path and the fourth flow path are in communication!
- This is a modification of the flow path structure of the third embodiment, and shows a flow path structure in which a plurality of flow paths are three-dimensionally connected.
- FIG. 26 is a diagram conceptually showing an open state of an opening / closing mechanism of a fourth embodiment.
- FIG. 27 is a diagram conceptually showing a closed state of the opening / closing mechanism of the fourth embodiment.
- FIG. 28 It is a diagram conceptually showing an open state of the opening / closing mechanism of Modification 1 of the fourth embodiment.
- FIG. 29 A diagram conceptually showing a closed state of the opening / closing mechanism of the first modification of the fourth embodiment.
- FIG. 30 It is a diagram conceptually showing an open state of the opening / closing mechanism of Modification 2 of the fourth embodiment.
- FIG. 31 is a diagram conceptually showing a closed state of the opening / closing mechanism of Modification 2 of the fourth embodiment.
- FIG. 32 It is a diagram explaining the capillary phenomenon, Fig. 32 (a) is a diagram showing the capillary phenomenon when the wetting angle is less than 90 °, and Fig. 32 (b) is the wetting angle larger than 90 °. It is a figure showing the capillary phenomenon in a case.
- Fig. 33 (a) is a schematic cross-sectional view when a droplet is placed on a liquid-repellent insulating film
- Fig. 33 (b) shows the application of a voltage between the droplet and the electrode.
- FIG. 6 is a schematic cross-sectional view showing an electrowetting phenomenon that occurs in the case of this.
- CEW phenomenon a chiral electrowetting phenomenon used for transporting and moving a liquid found by the present inventor, which is used in the novere and the actuator of the present invention.
- FIGS. 32 (a) and 32 (b) when a thin tube (capillary tube) is set up in the liquid, the liquid level in the tube rises or falls below the liquid level outside the tube (capillary phenomenon). .
- the liquid level rises and does not wet (wet) when the liquid wets the tube (wetting angle is less than 90 °) due to the magnitude relationship between the cohesive force between the liquid molecules and the adhesion between the liquid and the tube wall.
- the liquid level falls when the angle is greater than 90 °.
- the wetting angle between the tube 450 and the liquid level is smaller than the ⁇ force
- the difference in height between the liquid levels inside and outside the tube 450 is the resultant force F of the surface tension F1 acting on the liquid level of the liquid in the tube 450. It is determined by the balance with the gravity G acting on the liquid above the liquid level outside the tube (see Fig. 32 (a)).
- the wetting angle is greater than ⁇ force
- the difference in the height of the liquid level inside and outside the pipe h is the resultant force F of the surface tension F1 exerted on the liquid level inside the pipe and the liquid level inside the pipe due to the descent of the liquid level inside the pipe. It is determined by the balance with buoyancy f acting on the body (see Fig. 32 (b)).
- the rise in the liquid level in the tube is about lcm, whereas the inner diameter of the tube is 0.1 mm. In this case, the rise of the liquid level in the pipe is about 28cm.
- the inventors of the present application have conducted thoughts and experiments to establish a method capable of freely controlling the rise and fall of the liquid level and the height of the liquid level in the capillary.
- the electrowetting phenomenon and the capillary By combining the phenomena, we have an electrowetting current I found a new phenomenon that should be called an elephant.
- the electrowetting phenomenon for example, as shown in FIGS. 33 (a) and 33 (b), a liquid liquid having conductivity is formed on the water-repellent thin film 1402 provided on the plate electrode 1401.
- a droplet 1403 is placed and a fine wire-like electrode 1404 is inserted into this droplet, the state before voltage is applied between the droplet 1403 and the plate electrode 1401 (Fig. 33 (a))
- the wettability of the thin film 1402 increases after the voltage is applied, and the wetting angle ⁇ between the thin film 1402 and the droplet 1403 decreases (see Fig. 33 (b)).
- the inventor of the present application pays particular attention to the fact that the wetting angle greater than 90 ° can be lowered to less than 90 ° in the electrowetting phenomenon, and controls the wettability of the wall surface of the capillary using the electrowetting phenomenon.
- CEW phenomenon the movement of the liquid surface in the capillary phenomenon can be controlled freely and instantaneously (CEW phenomenon). That is, by providing an electrode on the wall surface of the capillary, coating the electrode and the wall surface with a predetermined water-repellent thin film, and applying a voltage between the conductive liquid and the electrode, the magnitude and voltage of the voltage can be reduced. It is possible to control the movement of the liquid level according to the application range.
- the inventor of the present application has completed a valve, an actuator, and an opening / closing mechanism including the actuator that can be applied to various applications.
- the inner diameter (width) of the capillary (passage) is preferably 4 mm or less! /.
- the first embodiment is an example in which the present invention is applied to an ink cartridge that stores ink supplied to an inkjet head.
- FIG. 1 is a schematic configuration diagram of an inkjet printer 1 according to the present embodiment.
- the inkjet printer 1 includes an inkjet head 3 that ejects ink onto recording paper, an ink cartridge 2 that is connected to the inkjet head 3 via a tube 5, and an ink ejection operation by the inkjet head 3.
- a control device 40 (see FIG. 6) for controlling various operations of the inkjet printer 1 is provided.
- the ink jet printer 1 then supplies ink from the ink cartridge 2 to the ink jet head 3 through the tube 5. Then, ink is ejected from a plurality of nozzles (not shown) formed on the ink ejection surface 3a of the inkjet head 3, and an image is recorded on the recording paper.
- FIGS. 2 is a perspective view of the ink cartridge 2 of FIG. 1, and FIG. 3 is a cross-sectional view of the ink cartridge 2.
- the back side in FIG. 2 is defined as the upper side
- the horizontal direction in FIG. 2 is defined as the horizontal direction.
- the ink cartridge 2 is configured to open and close the cartridge main body 10 having the ink containing space 22 and the atmosphere communication path 24 that communicates the ink containing space 22 with the atmosphere, and the atmosphere communication path 24. With possible valve 25.
- the cartridge body 10 has two flat plate members (a first plate member 11 and a second plate member 12) formed of a synthetic resin material (for example, polypropylene) excellent in ink wettability. These two plate members 11 and 12 are formed so as to have the same planar shape, and are joined together by welding or the like while facing each other.
- a synthetic resin material for example, polypropylene
- the outer edge of the first plate member 11 has an upper wall portion l la, left and right side wall portions l ib, l lc and so as to surround the center portion thereof.
- a bottom wall portion l id is formed.
- a partition wall ie extending from the bottom wall portion id to the right after extending upward is further formed.
- the space surrounded by the upper wall portion l la of the first plate member 11, the left and right side wall portions l ib and 1 lc, the bottom wall portion l id and the second plate member 12 is left and right by the partition wall l ie.
- the ink containing space 22 is formed on the left side of the partition wall l ie and the air communication path 24 is formed on the right side of the partition wall l ie.
- a communication path 26 is formed between the partition wall ie and the upper wall portion 11a so as to communicate the upper part of the ink containing space 22 and the upper part of the atmospheric communication path 24.
- a first passage (see FIGS. 4 and 5), which will be described later, communicates with the atmosphere communication passage 24 and is formed in the right side portion of the bottom wall portion id in a penetrating manner.
- the second passage 32 of the valve 25 branched from 31 is also formed in the bottom wall portion 1 Id.
- the left portion of the bottom wall portion id of the first plate member 11 is formed with a protruding portion 1 If that protrudes downward.
- a portion of the second plate member 12 facing the protruding portion 1 If is also formed with a protruding portion 12f having the same planar shape as the protruding portion 1 If and joined to the protruding portion 1 If. .
- a tube 5 is connected to these protrusions 1 If, 12f via an annular seal member 15, and the protrusions In the inks lf and 12f, an ink supply path 23 is formed to connect the ink containing space 22 and the tube 5.
- FIG. 4 is a perspective view of the valve 25, and FIG. 5 is an enlarged sectional view of the valve 25.
- This valve 25 opens the atmosphere communication path 24 when ink is supplied from the ink cartridge 2 to the ink jet head 3, while ink is not supplied from the ink cartridge 2 to the ink jet head 3. In this case, the air communication path 24 is closed to prevent the ink I in the ink storage space 22 from drying.
- the valve 25 includes a first passage 31 that allows the atmosphere communication passage 24 and the outside of the cartridge body 10 to communicate with each other, and a second passage 32 that branches from the first passage 31.
- the passage 3 3 internal passage
- the electrode 35 first electrode
- the electrode 37 second electrode
- a driver IC 44 voltage application unit: see FIG. 6
- a predetermined voltage to either one of the types of electrodes 35 and 37
- an insulating film 36 provided on the surface of the electrode 35, and a surface of the electrode 37 And an insulating film 38 provided.
- the first passage 31 is formed so as to penetrate the bottom wall portion 11 d in the vertical direction by a groove l lg formed in the bottom wall portion l id of the first plate member 11.
- the second passage 32 is formed by a groove l lh that branches from the center in the vertical direction of the groove l lg to the right and further extends upward, and communicates with both the first passage 31 and the atmosphere communication passage 24. is doing.
- the first passage 31 and the second passage 32 have a rectangular cross section.
- the cross-sectional area of the first passage 31 is larger than the cross-sectional area of the second passage 32. For example, as shown in FIG.
- the width of the second path 32 is desirably 4 mm or less in order to make the second electrowetting phenomenon manifest in the second path 32.
- a conductive liquid 34 that opens and closes the first passage 31 by moving between the first passage 31 and the second passage 32 is provided.
- the conductive liquid 34 for example, water or an aqueous solution in which dariserine or the like is dissolved in water can be used.
- an ionic liquid room temperature molten salt
- this ionic liquid is generally non-volatile, it has the advantage that it does not evaporate when exposed to the atmosphere.
- the wall surface of the groove l lh that forms a portion extending from the first passage 31 and extending to the right of the second passage 32, there is an upper and lower 1 at a position away from the branch position by a predetermined distance.
- a pair of electrodes 35 is formed.
- the electrode 35 is connected to the driver IC 44 (see FIG. 6) via the connection portion 35a.
- an electrode 37 is formed at a position of the groove l lg forming the first passage 31 facing the portion where the second passage on the left wall surface branches.
- the electrode 37 is connected to the driver IC 44 by a connection portion 37a.
- a predetermined voltage is applied to either one of these two types of electrodes 35 and 37 from the driver IC 44.
- the electrodes 35 and 37 to which no voltage is applied are held at the ground potential via the connecting portions 35a and 37a.
- These three types of electrodes 35, 37, 39 can be formed by known methods such as vapor deposition, sputtering, and printing.
- an insulating film 36 made of a fluorinated resin such as ethylene tetrafluoride is formed on the wall surface of the groove l lh including the surface of the electrode 35 of the second passage 32 except for the vicinity of the branch position. It is formed entirely.
- the liquid repellency of the surface of the insulating film 36 is higher than that of the portion where the insulating film 36 is not formed.
- the insulating film 36 is formed, and the wetting angle force of the liquid 34 near the branching position is lower than the wetting angle of the liquid 34 on the surface of the insulating film 36.
- the liquid repellency of the portion of the insulating film 36 on the surface of the electrode 35 (corresponding to the first insulating film of the present application) is partially reduced.
- the wetting angle of the liquid 34 on the surface is reduced (electrowetting phenomenon).
- this liquid repellency The high insulating film 36 is formed from the wall surface forming the second passage 32 to a portion further back than the electrode 35. Therefore, even if a pressure difference between the inside and outside of the cartridge body 10 occurs, the liquid 34 does not move deeper than the electrode 35.
- an insulating film 38 having the same material (for example, fluorine-based grease) force as that of the above-described insulating film 36 is entirely formed on the wall surface of the groove l lg including the surface of the electrode 37 in the first passage 31.
- the liquid repellency of the surface of the insulating film 38 is higher than that of the portion where the insulating film 38 is not formed.
- a voltage is applied from the driver IC 44 to the electrode 37, an electrowetting phenomenon occurs as in the case of the insulating film 36 described above, and a portion of the insulating film 38 on the surface of the electrode 37 (in the second insulating film of the present application). The liquid repellency of the liquid 34 on the surface is reduced.
- the highly liquid-repellent insulating film 38 is also formed on the upper and lower portions of the wall surface of the first passage 31 where the electrode 37 is formed. For this reason, the liquid 34 is not sucked into the atmospheric passage 24 or dropped due to the pressure difference between the inside and outside of the cartridge body 10 and the influence of gravity.
- These insulating films 36 and 38 can be formed on the walls of the grooves llg and the grooves llh forming the first passage 31 and the second passage 32 by a method such as spin coating or sputtering.
- the nozzle 25 changes the wetting angle of the liquid 34 with respect to the surfaces of the insulating films 36 and 38 by applying a predetermined voltage from the driver IC 44 to one of the electrodes 35 and 37, and thereby the liquid body It is possible to open and close the first passage 31 by moving 34 between the first passage 31 and the second passage 32.
- the opening / closing operation of the first passage 31 will be described in detail later.
- the insulating film 36 is not formed on the surface of the electrode 39 that is formed in the vicinity of the branch position and is always kept at the ground potential. Therefore, the liquid 34 is always in contact with the electrode 39 and is held at the ground potential. Therefore, when a predetermined voltage is applied to the electrode 35 or the electrode 37, a predetermined potential difference is always generated between these electrodes and the liquid 34. Therefore, the insulating films 36 and 38, the electrodes 35 and 37 It is possible to reliably reduce the wetting angle of the liquid 34 in the surface portion.
- the control device 40 includes a central processing unit (CPU) and various programs for controlling the overall operation of the inkjet printer 1. It includes ROM (Read Only Memory) that stores RAM and data, and RAM (Random Access Memory) that temporarily stores data processed by the CPU. Also, as shown in FIG. 6, the control device 40 controls the ink discharge operation by the ink jet head 3 and the valve control that controls the opening / closing operation of the air communication path 24 of the ink cartridge 2 by the valve 25. Part 42.
- CPU central processing unit
- ROM Read Only Memory
- RAM Random Access Memory
- the head control unit 41 controls the ink jet head 3 based on the print data input from the PC 100 to the control device 40 to eject ink onto the recording paper, thereby causing the recording paper to perform predetermined printing. . Further, the valve control unit 42 opens the atmosphere communication path 24 before the ink discharge operation by the inkjet head 3 is performed when a print command is input from the PC 100, and the atmosphere connection when the ink discharge operation by the inkjet head 3 is completed. The driver IC 44 of the valve 25 is controlled so that the passage 24 is closed.
- the head control unit 41 and the valve control unit 42 are configured by a CPU, a ROM, a RAM, and the like, respectively.
- FIG. 8 shows a state where the first passage 31 communicating with the atmospheric communication passage 24 is closed
- FIG. 9 shows a state where the first passage 31 is opened.
- “+” of the connection portion 35a of the electrode 35 and the connection portion 37a of the electrode 37 represents that a predetermined voltage is applied to these electrodes 35 and 37.
- “GND” of the connection portion 35a of the electrode 35, the connection portion 37a of the electrode 37, and the connection portion 39a of the electrode 39 indicates that these electrodes 35, 37, and 39 are at the ground potential.
- the electrode 35 in the second passage is held at the ground potential, and the liquid 34 is wetted with the insulating film 36.
- the insulating film 36 in the vicinity of the branch position is formed at the corner, and the corner is larger than the wetting angle of the liquid 34 with respect to the portion (high liquid repellency).
- a predetermined voltage is applied to the electrode 37 in the first passage, and the wetting angle of the liquid 34 with respect to the surface portion of the electrode 37 of the insulating film 36 is partially lowered (low liquid repellency). ). Therefore, the liquid 34 is held in the vicinity of the branch position in the first passage 31, and a part of the liquid 34 is completely separated from the second passage 32. It is in a state where it has entered a portion where the edge film 36 is not formed. Then, the first passage 31 is closed by the liquid 34 and the atmosphere communication passage 24 is closed to prevent the ink in the ink containing space 22 from being dried.
- the driver IC 44 applies a predetermined voltage to the electrode 35 and cancels the application of the voltage to the electrode 37.
- 37 is set to the ground potential (S 10).
- S 10 ground potential
- the wetting angle ⁇ of the liquid 34 at the surface portion of the electrode 35 of the insulating film 36 decreases, and the liquid force is generated by the capillary force generated in the second passage 32.
- 34 moves from the first passage 31 to the second passage 32. Since the liquid repellency of the portion near the branch position in the wall surface forming the second passage 32 is always low, the liquid 34 moved to the second passage 32 is separated from the portion near the branch position and the electrode. The liquid repellency is temporarily lowered by the voltage application to the insulating film 38 and is held over the surface portion of the electrode 37.
- the movement of the liquid 34 to the second passage 32 opens the first passage 31 that has been blocked by the liquid 34, so that the atmosphere communication passage 24 communicates with the atmosphere.
- the wetting angle ⁇ of the liquid 34 at the surface portion of the electrode 37 of the insulating film 38 increases, and the liquid 34 flows from the first passage 31 to the second passage.
- Easy to move to 32 Since the cross-sectional area of the second passage 32 is smaller than the cross-sectional area of the first passage 31, the capillary force in the second passage is larger than the capillary force generated in the first passage 31, and the liquid 34 It is easier to move from the first passage 31 to the second passage 32.
- the atmosphere communication path 24 As described above, after the atmosphere communication path 24 is opened, printing is performed on the recording paper by the inkjet head 3 based on the print data input from the PC 100 (Sl l). At this time, since the atmosphere communication path 24 is open, the atmosphere is introduced into the ink accommodation space 22 from the atmosphere communication path 24 according to the amount of ink supplied from the ink accommodation space 22 to the inkjet head 3. Therefore, the ink supply to the inkjet head 3 is performed smoothly.
- the driver IC 44 cancels the application of the voltage to the electrode 35 to bring the electrode 35 to the ground potential, and applies a predetermined voltage to the electrode 37 (S12). Then, as shown in FIG. 8, the wetting angle ⁇ of the liquid 3 4 at the surface portion of the electrode 35 of the insulating film 36 increases, so that the liquid 34 moves from the second passage 32 to the first passage 31 and again. The liquid 34 is held in the vicinity of the branch position in the first passage 31. Accordingly, the first passage 31 is blocked by the liquid 34 and the atmosphere communication passage 24 is closed.
- the wetting angle ⁇ of the liquid 34 with respect to the portion of the insulating film 36 located on the surface of the electrode 35 is When the voltage is applied to the electrode 35, it is preferably less than 90 °. In this case, the liquid 34 can be reliably moved from the first passage 31 to the second passage 32. Further, it is preferable that the wetting angle ⁇ force is 90 ° or more when no voltage is applied to the electrode 35. In this case, the liquid 34 can be reliably moved from the second passage 32 to the first passage 31.
- the atmosphere communication path 24 is opened by the valve 25 before the printing operation by the inkjet head 3, and the atmosphere communication path 24 is closed by the valve 25 after the completion of the printing operation. . Therefore, during the printing operation, ink can be supplied from the ink cartridge 2 to the ink jet head 3 while introducing air into the ink containing space 22 from the air communication path 24, and ink can be supplied smoothly. . Further, when the printing operation is not performed, the atmosphere communication path 24 is closed, and the ink in the ink storage space 22 can be reliably prevented from drying.
- the nove 25 reduces the wetting angle of the liquid 34 on the surfaces of the insulating films 36 and 38 by applying a voltage to the electrode 35 or the electrode 37, whereby the first passage 31 and the second passage 32 are connected.
- the liquid 34 is moved between the first passage 31 and the first passage 31 is opened and closed. Therefore, the structure is simple and has no moving parts, unlike general solenoids such as solenoid valves. Therefore, the manufacturing cost of the ink cartridge 2 can be kept low. In addition, noise / J is reduced when the valve is activated.
- the insulating film 36 is not formed in the vicinity of the branch position on the wall surface forming the second passage 32. If the insulating film 36 is formed, the liquid 34 is wet with respect to the vicinity of the branch position. When a voltage is applied to the angular force electrode 35, the wetting angle of the liquid 34 on the surface of the insulating film 36 in the state is lower. Therefore, the liquid 34 always enters the second passage 32 in the vicinity of the branch position. Therefore, when a predetermined voltage is applied to the electrode 35, the liquid 34 easily moves from the first passage 31 to the second passage 32, and the first passage 31 31 is definitely opened.
- An electrode 39 is provided in the vicinity of the branch position on the wall surface forming the second passage 32, and the liquid 34 is always in contact with the electrode 39 and held at the ground potential. Accordingly, when a predetermined voltage is applied to the electrode 35 or the electrode 37, a predetermined potential difference is always generated between these electrodes and the liquid 34. Therefore, the surfaces of the insulating films 36 and 38, the surfaces of the electrodes 35 and 37, It is possible to reliably reduce the wetting angle of the liquid 34 in this portion. That is, since the liquid 34 can be reliably moved between the first passage 31 and the second passage 32, the reliability of the opening / closing operation of the valve 25 is increased. In addition, the responsiveness becomes faster.
- the liquid acts as a valve, if the wettability (liquid wetting angle) of the insulating film in the first passage is set appropriately, the cross-sectional shape of the first passage is complicated. Therefore, it can be closed easily and securely without considering special designs.
- the positions of the electrodes 35, 37, 39 on the wall surfaces forming the first passage 31 and the second passage 32 are not limited to the positions in the first embodiment.
- the electrode 35 may be formed only on either the upper inner surface or the lower inner surface of the groove l lh.
- the electrodes 37A may be formed on the left and right wall surfaces forming the first passage 31, respectively. In this case, since the capillary force generated in the first passage 31 when a voltage is applied to the electrode 37A increases, the liquid 34 easily moves from the second passage 32 to the first passage 31.
- the insulating films 36 and 38 do not necessarily have to be formed entirely on the wall surfaces forming the first passage 31 and the second passage 32, and it is only necessary that the insulating films 36 and 38 be formed on at least the surfaces of the electrodes 35 and 37, respectively. Yes.
- the electrode 37 of the first passage 31 can be omitted. Even in this case, the liquid 34 is moved to the second passage 32 by applying a voltage to the electrode 35 in the second passage 32, and the liquid 34 is moved to the first passage 31 by releasing the application of the voltage to the electrode 35.
- the first passage 31 (atmospheric communication passage 24) can be opened and closed.
- the liquid 34 is made of a volatile liquid such as water, as shown in the valve 25C in FIG. Of the liquid). In this case, evaporation of the volatile liquid 34 can be prevented by the liquid 45, and the life of the valve 25C is extended.
- a configuration may be provided in which the nozzle replenishes the liquid 34.
- the valve 25D of FIG. 13 has a liquid storage chamber 46 (liquid supply source) that stores the liquid 34, and the liquid storage chamber 46 is connected to the second passage 32 by a liquid supply passage 47.
- the liquid 34 is replenished from the liquid storage chamber 46 via the liquid supply path 47.
- a predetermined voltage is periodically applied to the electrode 35 by the NORB 25 force driver IC 44 only for a predetermined time. If printing is performed for a long time, the air communication path 24 is not opened for a long time by the valve 25. Therefore, the ink in the cartridge body 10 is caused by a change in atmospheric temperature or pressure. The pressure in the storage space 22 becomes excessively high or becomes negative. Therefore, for example, when the control device 40 of the ink jet printer 1 determines that the predetermined time has passed, the driver IC 44 applies a predetermined voltage to the electrode 35 for a predetermined time. When configured to be applied, it is possible to regularly open the atmosphere communication path 24 to always reduce the pressure difference between the inside and outside of the force cartridge body 10.
- the first embodiment described above is an example in which the present invention is applied to a valve that opens the atmosphere communication path of the ink force cartridge, but the application target of the present invention is not limited to the ink cartridge.
- the second embodiment described below is an example in which the valve of the present invention is applied to a nozzle cap that is attached to the ink ejection surface of an inkjet head and prevents the ink in the nozzle from drying.
- FIG. 14 is a schematic perspective view of an ink jet printer 80 according to the second embodiment.
- the inkjet printer 80 includes a carriage 81 that can reciprocate in the left-right direction in FIG. 14 and a serial inkjet that is provided on the carriage 81 and ejects ink onto the recording paper P.
- Ink jet printer 80 includes a head 60, a transport roller 82 that transports recording paper P forward in FIG. 1, and an ink ejection operation by ink jet head 60, a reciprocating operation of carriage 81, a paper transport operation by transport opening roller 82, and the like. It is equipped with a control device 51 (see Fig. 17) that controls various operations.
- the inkjet head 60 moves in the left-right direction (scanning direction) integrally with the carriage 81 driven by the carriage drive unit 58 (see FIG. 17), and has a plurality of nozzles formed on the lower surface of the ink ejection surface 60a. 63 (Refer to Fig. 15) Ejection ink is ejected to the recording paper P. Then, the recording paper P recorded by the ink jet head 60 is discharged forward (paper feeding direction) by the transport roller 82.
- the carriage 81 retreats the area further in the width direction (left and right direction in FIG. 14) outside the area (for example, the right end in FIG. 14) than the area (paper conveyance area) in which the recording paper P is conveyed. It is configured to be movable to a position.
- a nozzle cap 64 (see FIG. 15) is disposed at the retracted position, and the nozzle cap 64 is configured to be driven up and down by a cap drive unit 59 (see FIG. 17).
- the ink jet head 60 is moved to the retracted position together with the carriage 81, and the nozzle cap 64 covers the ink ejection surface 60a from below at the retracted position. 60 is detachably attached.
- FIG. 15 is a longitudinal sectional view of the inkjet head 60 with the nozzle cap 64 attached.
- the inkjet head 60 has a flow path unit 90 connected to an ink force cartridge (not shown) via a tube 83.
- the flow path unit 90 is composed of three laminated plates 91, 92, 93 joined together.
- the uppermost plate 91 is formed with a mould 61 and an ink supply path 94 that allows the mould 61 and the tube 83 to communicate with each other.
- the central plate 92 is formed with a plurality of ink flow paths 62 branched from the holder 61 and extending downward.
- a plurality of nozzles 63 communicating with the plurality of ink flow paths 62 are formed in the lowermost plate 93, and the lower surface of the plate 93 is an ink ejection surface 60a where the nozzles 63 are opened. .
- the ink that has flowed into the holder 61 from the tube 83 is ejected from the plurality of nozzles 63 via the plurality of ink flow paths 62.
- the nozzle cap 64 has a substantially the same area as the ink discharge surface 60a and covers the nozzle 63 from below, and extends upward from the peripheral edge of the cap portion 64a to the nozzle of the ink discharge surface 60a. It has a contact part 64b that can be brought into close contact with the region around the outlet 63, and a base part 64c that supports the cap part 64a also with a downward force.
- the cap part 64a and the contact part 64b are formed of a material having elasticity such as a synthetic resin. Further, inside the base portion 64c, there is a space 95 (see FIG.
- a communication path 65 communicating with the outside of the nozzle cap 64 is formed. Further, a valve 66 capable of opening and closing the communication path 65 is provided at the base c.
- the valve 66 has the same configuration as the valve 25 (see FIG. 5) of the first embodiment described above, and the configuration will be briefly described below.
- the valve 66 has a passage 73 (internal passage) having a first passage 71 for communicating the communication passage 65 and the outside of the nozzle cap 64 and a second passage 72 for branching the force of the first passage 71.
- a driver IC 57 (voltage application section: see FIG. 17) for selectively applying a predetermined voltage to one of these two types of electrodes 75 and 77, and an insulating film 76 provided on the surface of the electrode 75 And an insulating film 78 provided on the surface of the electrode 77.
- a liquid 74 having conductivity is sealed in the passage 73, and the nozzle 66 moves the first passage 71 between the first passage 71 and the second passage 72 by moving the liquid 74 between the first passage 71 and the second passage 72. Open and close. Electric
- the pole 75 and the electrode 77 are connected to the driver IC 57 (see FIG. 17) via the contact part 75a and the contact part 77a. Then, a predetermined voltage is applied from the driver IC 57 to one of the electrode 75 and the electrode 77, and the electrode to which no voltage is applied is held at the ground potential.
- An electrode 79 (third electrode) is also formed in the vicinity of the branch position in the wall surface forming the second passage 72, and this electrode 79 is always held at the ground potential via the contact portion 79a. ing.
- the insulating films 76 and 78 have the same function as the insulating films 36 and 38 of the first embodiment. That is, when a predetermined voltage is applied to the electrode 75, the wetting angle of the liquid 74 with respect to the surface portion of the insulating film 76 of the electrode 75 (corresponding to the first insulating film of the present application) decreases. In addition, when a predetermined voltage is applied to the electrode 77, the wetting angle of the liquid 74 with respect to the surface portion of the insulating film 78 on the surface of the electrode 77 (corresponding to the second insulating film of the present application) decreases.
- the valve 66 applies a predetermined voltage to the electrode 75 from the driver IC 57, thereby reducing the wetting angle of the liquid 74 with respect to the surface portion of the electrode 75 of the insulating film 76, and causing the liquid 74 to
- the first passage 71 is opened by moving from the first passage 71 to the second passage 72. Further, by applying a predetermined voltage from the driver IC 57 to the electrode 77, the wetting angle of the liquid 74 with respect to the surface portion of the electrode 77 of the insulating film 78 is reduced, and the liquid 74 is discharged from the second passage 72 to the first passage. Move to 71 and close the first passage 71.
- the control device 51 includes a CPU that is a central processing unit, a ROM that stores various programs and data for controlling the overall operation of the printer 80, and a RAM that temporarily stores data processed by the CPU. Etc. As shown in FIG. 17, the control device 51 includes a head control unit 52 that controls the ink ejection operation by the inkjet head 60, a carriage control unit 53 that controls the reciprocating operation of the carriage 81 by the carriage drive unit 58, and a cap. A cap control unit 54 that controls the raising / lowering operation of the nozzle cap 64 by the drive unit 59 and a valve control unit 55 that controls the opening / closing operation of the communication path 65 of the nozzle cap 64 by the valve 66 are provided.
- the carriage control unit 53 controls the carriage drive unit 58 to reciprocate the carriage 81.
- the head control unit 52 The ink jet head 60 is controlled to eject ink onto the recording paper.
- the cap control unit 54 controls the cap driving unit 59 to mount the nozzle cap 64 on the ink discharge surface 60a of the ink jet head 60 that has moved up to the retracted position after the nozzle cap 64 has been moved up after printing.
- the nozzle cap 64 is lowered to remove the nozzle cap 64 from the ink ejection surface 60a.
- valve control unit 55 controls the driver IC 44 of the valve 25 so that the communication path 65 is opened before the nozzle cap 64 is mounted and the communication path 65 is closed when the mounting is completed.
- the head control unit 52, the carriage control unit 53, the cap control unit 54, and the valve control unit 55 are configured by a CPU, a ROM, a RAM, and the like, respectively.
- the nozzle cap 64 is lowered by the cap drive unit 59 to separate the nozzle cap 64 from the ink discharge surface 60 a, and the ink discharge surface The state pressed against 60a is released (S20). Then, the carriage 81 is also moved in the retracting position so that the ink jet head 60 faces the paper conveyance area ( S21), a printing operation is executed by the inkjet head 60 and the carriage 81 (S22). When printing is completed, the carriage 81 is moved again to the retracted position (S23).
- the driver IC 57 applies a predetermined voltage to the electrode 75 and cancels the state in which the voltage is applied to the electrode 77 (S24). Then, while the wetting angle of the liquid 74 with respect to the surface portion of the electrode 75 of the insulating film 76 is reduced, the wetting angle of the liquid 74 with respect to the portion of the surface of the electrode 77 of the insulating film 78 is increased. Moving from the first passage 71 to the second passage 72, the first passage 71 (communication passage 65) is opened.
- the nozzle cap 64 is raised by the cap driving unit 59, the nozzle cap 64 is pressed against the ink discharge surface 60a (S25), and the contact portion 64b is brought into close contact with the ink discharge surface 60a.
- the communication path 65 is opened, the pressure increase in the space 95 caused by the mounting operation of the nozzle cap 64 is alleviated. Therefore, it is possible to prevent the meniscus of the nozzle 63 from being destroyed by this pressure increase.
- the driver IC 57 cancels the state in which the voltage is applied to the electrode 75, and applies a predetermined voltage to the electrode 77 (S26). ).
- the wetting angle ⁇ of the liquid 74 with respect to the surface portion of the electrode 75 of the insulating film 76 increases, while the wetting angle of the liquid 74 with respect to the surface portion of the electrode 77 of the insulating film 78 decreases.
- the second passage 72 moves from the first passage 71 to the first passage 71, and the first passage 71 is closed with the liquid 74.
- the communication path 65 is closed and the space 95 is hermetically sealed, and the ink in the nozzle 63 is prevented from drying.
- the first passage 71 is opened before the nozzle cap 64 is separated from the ink discharge surface 60a after the printing command is input to the control device 51 (S20), and the first passage is opened immediately after S20. 71 may be closed.
- the pressure fluctuation in the space 95 can be reduced at the moment when the nozzle cap 64 is separated from the ink discharge surface 60a, and the meniscus formed in the nozzle 63 can be prevented from being destroyed.
- the nozzle cap 64 is attached to the ink discharge surface 60a of the ink jet head 60 at the end of printing.
- Cap 65a when the nozzle cap 64 is installed to open the passage 65 and press the nozzle cap 64 against the ink discharge surface 60a.
- the pressure increase in the space 95 between the ink discharge surface 60a can be reduced.
- the communication path 65 is closed by the valve 66 after the nozzle cap 64 is attached, the ink in the nozzle 63 can be prevented from drying.
- opening and closing of the first passage is controlled by changing the capillary force or wetting angle of the liquid in the second passage.
- a flow path structure having a plurality of flow paths and including an opening / closing mechanism that selectively controls the flow of fluid in the flow paths will be described.
- the channel structure 101 is configured by superposing an upper plate 103 and a lower plate 105, and a cross-shaped channel 107 is formed on the upper surface 105a of the lower plate 105.
- the flow path 107 has a recess (intersection) 115 in the center of the upper surface 105a of the upper plate 103, and from there, the first groove (first flow path) radially (crosswise) at intervals of 90 degrees.
- Each groove has a rectangular channel cross-sectional shape and the same cross-sectional area.
- the first channel 111 communicates with the first space 1S
- the second channel 112 communicates with the fourth space 4S
- the third channel 113 communicates with the second space 2S
- the fourth channel 114 communicates with the third space 1S. It communicates with space 3S.
- the first electrode 11 la is embedded in the opposing side wall of the first flow path 111
- the second electrode 112 a is embedded in the opposing side wall of the second flow path 112.
- the third electrode 113a is embedded in the opposite side wall of the third channel 113
- the fourth electrode 114a is embedded in the opposite side wall of the fourth channel 114.
- a fifth electrode 115a is formed so as to extend from the side wall (peripheral wall) of the intersecting portion 115 to a part of the first flow path 111 to the fourth flow path 114 therefrom.
- the first channel 111 to the fourth channel 114 and the intersecting portion 115 are formed with an insulating film 118 made of tetrafluorinated titanium so as to cover the electrodes 11 la to L 15a! .
- a predetermined voltage is selectively applied to these electrodes 11 la to l 15 a from a voltage application section (not shown) (for example, “driver IC” in FIG. 6) or a power source.
- the flow path 107 is filled with water W as a conductive liquid! [0093] As shown in FIG.
- the first to fourth currents Since the cross-sectional areas of the channels 111 to 114 are equal, the capillary forces in the flow channels 111 to 114 are equal, and the water W is equal in length to the intersection 115 and the force is also along the flow channels 111 to 114. Fills part of channel 111-114. Since the intersection 115 is filled with water W, the gas cannot move to the other flow path. That is, since the first channel 111 to the fourth channel 114 are separated from each other by the water W, the first space S1 to the fourth space S4 do not circulate with each other.
- the first flow path 111 and the third flow path 113 are in communication with each other via a gap formed at the intersection 115. Based on this principle, by applying a predetermined voltage to the second electrode 112a and the fourth electrode 114a, the first space S1 and the second space S2 are circulated through the first channel 111 and the third channel 113. (See the arrow in the figure).
- the insulating film formed on the second electrode 112a and the third electrode 113a is electrically insulated.
- the liquid repellency of the region of the film 118 is lowered, and the wetting angle force of the water W on the insulating film 118 in the region is reduced.
- the water W moves toward the fourth space and the third space S3 along the second flow path 112 and the third flow path 113, which act as a fly. Therefore, as shown in FIG. 24, the water present in the intersection 115 moves to the second flow path 112 and the third flow path 113, and the intersection 115 is partially free of water W. Is formed.
- the first flow path 111 and the fourth flow path 114 communicate with each other through a gap formed in the intersection 115.
- the first space S1 and the third space S3 are circulated through the first flow path 111 and the fourth flow path 114.
- the passage made up of the first passage 111 and the second passage 112, the third passage 113 and the fourth passage 114 are respectively referred to as the “first passage” and the “second passage” in the present invention.
- the gas flow flowing into the first flow path 111 is applied to the third flow path 111. It is possible to flow out into a desired space through either the channel 113 or the fourth channel 114.
- This channel structure 101 can function as a two-way nore. Note that a voltage is applied only to the second electrode 112a or the third electrode 113a, and gas is allowed to flow into two flow paths, for example, the second and fourth flow paths, thereby changing the first space S1 to the second space S2 and the second space S2. It is also possible to communicate with 4 spaces S4.
- the force given as an example having four flow paths may be formed by extending the cross section force radially by using five or more flow paths.
- the force given as an example having four flow paths may be formed by extending the cross section force radially by using five or more flow paths.
- the first to fourth flow paths are formed in a plane parallel to the surfaces of the upper plate and the lower plate.
- a fifth flow path 127 and a sixth flow path 128 You may have.
- the fifth flow path 127 communicates with the intersecting portion 115 and is formed in the upper plate 123 so as to extend in a direction orthogonal to the surface of the upper plate 123.
- the sixth flow path 128 communicates with the intersection 115 and is formed in the lower plate 125 so as to extend in a direction perpendicular to the surface of the lower plate 125. That is, in this modification, the plurality of flow paths are formed in a three-dimensional manner, and it is possible to flow liquid from a specific flow path to a desired flow path (multivalve).
- the opening / closing mechanism 201 has a first passage 31 and a second passage 32 (passage diameter (width) of about 4 mm) by grooves l lg and l lh formed in the first plate member. Is defined.
- An electrode 235 comprising a plurality of pairs of electrodes 235a to 235f is embedded in the side wall of the second flow path 32. These electrodes 235a to 235f are connected to a driver IC (see FIG. 6), and can individually apply a voltage.
- An insulating film 36 is formed on the side wall of the second flow path 32 so as to cover the plurality of electrodes 235a to 235f.
- the second flow path 32 is charged with a conductive liquid, here water W, in an amount that fills a part of the second flow path 32, and the elongated water tube WT is provided.
- Plunger 205 is loaded in the second channel 32 closer to the first channel 31 than the water W.
- the plunger 205 is a rod-shaped body (rectangular body) having a rectangular cross section, and in this example, a plastic cover is also formed.
- the plunger 205 has a length longer than the width (diameter) of the first flow path.
- the plunger 205 can move smoothly in the second flow path 32 and is slightly smaller than the inner diameter of the second flow path 32 so that water W does not enter between the plunger 205 and the wall surface of the second flow path 32.
- One end surface 205a of the plunger 205 is flat, and a recess 205c is formed on the other end surface 205b.
- the plunger 205 is loaded in the second flow path 32 so that the end face 205b formed with the recess 205c faces the first flow path 31 side.
- the end face 205a of the plunger 205 is joined to the end face of the water tube WT confined in the second flow path 32 by the surface tension of the water W.
- the end surface 205a of the plunger 205 may be subjected to a hydrophilic treatment.
- a convex portion l lg that engages with the concave portion 205 c of the plunger 205 is formed on the wall surface portion of the first flow channel 31 that faces the second flow channel 32.
- the end face 205a of the plunger 205 is Since it is joined to the motor tube WT, the plunger 205 is inserted into the second flow path 36 and as a result, the first flow path 31 is opened. That is, the interior of the ink cartridge communicates with the external atmosphere (predetermined space) through the first flow path 31.
- the movement amount of the plunger 205 is changed. It is possible to adjust the flow rate of the gas flowing through the first flow path 31 by adjusting (the degree of opening and closing of the first flow path 31). By doing so, the opening / closing mechanism 201 can also function as a flow rate adjusting valve.
- the electrode 235, the insulating film 36, the plunger 205, and the water W in the opening / closing mechanism 201 constitute a novel activator.
- the flow path can be opened and closed instantaneously with a small amount of power through the movement control of the plunger 205 by the water tube WT. Further, when the flow path is closed by the plunger 205, the tightness or certainty of the closing is that of the water W as the liquid. It depends on the strength of the plunger 205, not the surface tension. Therefore, the opening / closing mechanism 201 can act as a very strong locking mechanism. Therefore, although the fluid flowing in the flow path is a gas in this embodiment, the opening / closing mechanism may be used for another application, for example, an application for reliably stopping the flow of high-pressure gas, liquid, or solid. it can.
- the water tube WT urges the end surface 205a of the plunger 205 or The movement of the plunger 205 was controlled by retracting.
- the outer diameter Dp of the plunger 305 is such that the water W can enter between the second flow path 32 and the plunger 305. It is smaller than the inner diameter Do of the path 32.
- the diameter of the plunger 305 (the width in the direction perpendicular to the longitudinal direction) is made shorter than the diameter of the second flow path 32 by about 100 / ⁇ ⁇ to 8 ⁇ .
- the plunger 305 is maintained in the water tube WT of the water W, and in particular, the side surface of the plunger 305 can be supported by the water tube WT by the surface tension of the water W. Further, as shown in FIG. 28, the liquid repellent film is formed on the side wall of the region near the end 305b where the recess 305c of the plunger 305 is formed so that only the region close to the end surface 305a of the plunger 305 is in contact with water. 305d is formed.
- the other structure of the opening / closing mechanism 301 is the same as that of the opening / closing mechanism 201 in the fourth embodiment.
- the portion of the side surface of the plunger 305 having low liquid repellency (the portion where the liquid repellent film 305d is not formed) is supported in the water tube WT, and therefore the plunger 305 is in the second flow path 36. As a result, the first flow path 31 is opened.
- the plunger 305 By this movement of the water tube WT, the plunger 305 is pushed out from the second flow path 32 toward the first flow path 31 while being supported in the water tube WT, and the end surface 305b of the plunger 305 is pushed to the first flow path 31.
- the concave portion 305c of the plunger 305 is engaged with the convex portion l li.
- the first flow path 31 is completely closed by the plunger 305.
- the liquid repellent film 305d blocks the first flow path 31, when the first flow path 31 is a liquid flow path, the liquid repellent film 305d of the plunger 305 prevents liquid leakage. It works effectively.
- a spindle 407 that supports a plunger 405 so as to be slidable through water W is fixed. Inside the spindle 407, a plurality of electrodes 435a to 435f are provided at predetermined intervals along the longitudinal direction. An insulating film 436 is formed on the surface of the spindle 407 so as to cover all the electrodes 435a to 435f.
- the plunger 405 is hollow, and the spindle 407 is accommodated therein through water W.
- a liquid repellent film 405d is formed on a part of the inner wall 405 of the plunger 405 (region close to the first flow path side). Therefore, the water W is supported by the surface tension in the inner wall region where the liquid repellent film 405d is not formed.
- a cylinder member 403 that defines a first passage 31 is fixed to the first plate member 11, and a through passage 403a having an open end that communicates with the first passage 31 is formed in the cylinder member 403. Has been.
- the outer peripheral portion of the plunger 405 is supported by the through passage 403a of the cylinder member 403 so as to be slidable.
- the through passage 403 of the cylinder member 403 is In addition, it acts as a passage for the plunger 405, water W as a liquid is accommodated in the through passage 403, and an electrode 435 is provided.
- a protrusion 1 lj that engages with the inner wall 405 of the plunger 405 is formed on the wall surface of the first passage 31 that faces the plunger 405.
- the portion of the side surface of the plunger 405 having low liquid repellency (the portion where the liquid repellent film 405d is formed) is inserted into the region of the insulating layer 436 covering the electrodes 435c to 435f via the water tube WT.
- the plunger 405 is positioned away from the protrusion l lj.
- a predetermined voltage is applied to the electrodes 435a to 435d of the spindle 407, and the voltage application to the electrodes 435e and 435f is interrupted. To ground potential. Then, the wettability with respect to water W in the region of the insulating layer 436 covering the electrodes 435a to 435d is higher than the wettability with respect to the water W in the region of the insulating layer 436 covering the electrodes 435e and 435f (the liquid repellency is increased). Lower).
- the water tube WT instantaneously moves on the region of the insulating layer 436 covering the electrodes 435a to 435d inside the plunger 405 based on the capillary electrowetting phenomenon. Due to the movement of the water tube WT, the plunger 405 is pushed out toward the first flow path 31 with respect to the spindle 407 while being supported in the water tube WT, and the end surface 405b of the plunger 405 is pushed out of the first flow path 31. Joined to the wall surface, the inner wall 405c of the plunger 405 engages with the convex portion l lj. As a result, the first flow path 31 is completely closed by the plunger 405. It can be seen that among the opening / closing mechanism 401 in this modification, the cylinder member 403 (passage), the electrode 435, the insulating film 436, the plunger 405, the spindle 407, and the water W constitute a novel actuator.
- the inside of the spindle 407 is formed hollow, and a plurality of holes communicating the inside and outside of the spindle 407 are formed on the surface of the spindle 407. You can. If water W (conductive liquid) is filled inside the spindle 407, the water W oozes out of the spindle 407 through these holes, which may make up for the lack of water W held inside the plunger 405. In addition, the entire outer periphery of the spindle 407 can be kept wet with water W.
- water W conductive liquid
- the liquid repellent film is provided on the plunger, but instead, the area where the liquid repellent film is not provided is lyophilic (high wettability). Processing may be applied.
- the plunger has a physical surface treatment, such as wettability improvement by adjusting the surface roughness of the plunger, or a coating that improves the wettability by applying a chemical action to the liquid (water W). It may be applied to the surface.
- the plunger is a plastic material, but any synthetic resin material such as urethane foam, metal, rubber-based material, glass material or ceramic may also be used. good. Since the plunger used in Modification 1 is held in a floating state in the liquid (water W), it is desirable to mold it with a material having a specific gravity approximately equal to that of the liquid used. Alternatively, if a closed hollow chamber is formed inside the plunger, it can be formed using a material having a relatively high specific gravity. For example, a metal material having a hollow inside may be used.
- the surface of the plunger should be Teflon (registered trademark), silicon coating, glass material, etc. to prevent wear due to friction and leakage due to the friction. It is desirable to provide a plunger with such material force. Alternatively, lubrication oil may be applied to the outer surface of the plunger.
- the first passage is reliably closed by the engagement of the concave portion of the plunger and the convex portion of the wall surface of the first passage.
- the concave portion is formed on the wall surface, and the plunger A convex part may be formed on (for example, the tip of the plunger is tapered).
- both the plunger and the wall surface of the first passage may be provided with concave and convex portions that engage or fit with each other.
- the uneven portion may be sealed with Teflon (registered trademark) or the like.
- the fourth embodiment and its modifications a specific number of electrodes is provided.
- the number of electrodes can be arbitrarily changed, and a single electrode can be operated.
- the second passage 32 is opposite to the first passage 31.
- the opposite end need not be an open end and may be sealed to form a closed space.
- the longitudinal shape and the cross-sectional shape of the passage may be arbitrary, and in particular, the cross-sectional shape can be circular considering the movement resistance of the plunger, and the cross-sectional shape of the plunger can also be circular according to this.
- valve of the present invention is applied to an ink jet printer.
- liquids such as a chemical solution and a biochemical solution are used inside a micro total analysis system ( ⁇ TAS).
- ⁇ TAS micro total analysis system
- the valve of the present invention can also be applied to an apparatus for transferring a conductive liquid other than ink, such as an apparatus for transferring a liquid, an apparatus for transferring a liquid such as a solvent or a chemical solution within a microchemical system, and the like.
- the open / close mechanism of the fourth embodiment and its modification is mechanically strong in the blocking by the plunger. Therefore, the flow path through which the liquid or solid (powder) flows in the first passage It is also effective for the structure.
- the gap between the plunger and the second flow path can be reduced, it is also effective in blocking a passage where high pressure is applied to the fluid.
- the plunger since the plunger can be enlarged, it can be applied to a gas valve for city gas piping, a valve for an automatic valve, and the like. It can also be used as a regulator valve in fuel transportation pipes in automobiles. It can also be used in drug supply systems for medical devices.
- the plunger can use the operation of contacting the wall surface of the first passage of the plunger for a switch or a display operation.
- a plurality of plungers may be arranged along the first passage with respect to the wall surface of the first passage, or may be arranged in a two-dimensional array with respect to the wall surface of the first passage.
- any object can be used as long as it is an object that moves with the liquid due to the cupillary electrowetting phenomenon, regardless of its name.
- the present invention has been described as a structure for opening and closing a fluid flow.
- the valve and the actuator of the present invention are not limited thereto, and sound waves, electromagnetic waves, light, magnetic fields are not limited thereto.
- a switch that selectively shuts off the switch or a lock mechanism it can be used for any application as a mechanism for selectively stopping or directing the movement (or flow) of the moving body (or wave).
- due to the nature of the one-elect mouth fitting phenomenon it is expected to be used in water or in space where there is no influence of gravity or gravity.
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Ink Jet (AREA)
- Electrically Driven Valve-Operating Means (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
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JP2006520531A JP4784510B2 (ja) | 2004-12-17 | 2005-12-19 | キャピラリーエレクトロウェッティング現象を用いたバルブ及びアクチュエータ |
US11/721,962 US8172375B2 (en) | 2004-12-17 | 2005-12-19 | Valve and actuator employing capillary electrowetting phenomenon |
EP20050816950 EP1835213B1 (en) | 2004-12-17 | 2005-12-19 | Valve and actuator employing capillary electrowetting phenomenon |
US13/433,024 US8348391B2 (en) | 2004-12-17 | 2012-03-28 | Valve and actuator employing capillary electrowetting phenomenon |
Applications Claiming Priority (2)
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JP2004365896 | 2004-12-17 | ||
JP2004-365896 | 2004-12-17 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
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US11/721,962 A-371-Of-International US8172375B2 (en) | 2004-12-17 | 2005-12-19 | Valve and actuator employing capillary electrowetting phenomenon |
US13/433,024 Division US8348391B2 (en) | 2004-12-17 | 2012-03-28 | Valve and actuator employing capillary electrowetting phenomenon |
Publications (1)
Publication Number | Publication Date |
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WO2006064949A1 true WO2006064949A1 (ja) | 2006-06-22 |
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US (2) | US8172375B2 (ja) |
EP (1) | EP1835213B1 (ja) |
JP (1) | JP4784510B2 (ja) |
WO (1) | WO2006064949A1 (ja) |
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- 2005-12-19 WO PCT/JP2005/023300 patent/WO2006064949A1/ja active Application Filing
- 2005-12-19 EP EP20050816950 patent/EP1835213B1/en not_active Ceased
- 2005-12-19 US US11/721,962 patent/US8172375B2/en not_active Expired - Fee Related
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2012
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110645408A (zh) * | 2019-11-08 | 2020-01-03 | 广州大学 | 一种电润湿驱动液滴微阀控制液体流通装置 |
JP2021076247A (ja) * | 2019-11-08 | 2021-05-20 | ▲広▼州大学 | エレクトロウェッティングによる液滴駆動マイクロバルブ制御液体流通装置 |
Also Published As
Publication number | Publication date |
---|---|
US20080094448A1 (en) | 2008-04-24 |
US20120180894A1 (en) | 2012-07-19 |
EP1835213A1 (en) | 2007-09-19 |
US8348391B2 (en) | 2013-01-08 |
JP4784510B2 (ja) | 2011-10-05 |
JPWO2006064949A1 (ja) | 2008-06-12 |
US8172375B2 (en) | 2012-05-08 |
EP1835213B1 (en) | 2012-03-07 |
EP1835213A4 (en) | 2009-12-02 |
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