WO2006042833A1 - Formmasse für die herstellung schwer entflammbarer gegenstände, pigment hierfür und dessen verwendung - Google Patents
Formmasse für die herstellung schwer entflammbarer gegenstände, pigment hierfür und dessen verwendung Download PDFInfo
- Publication number
- WO2006042833A1 WO2006042833A1 PCT/EP2005/055285 EP2005055285W WO2006042833A1 WO 2006042833 A1 WO2006042833 A1 WO 2006042833A1 EP 2005055285 W EP2005055285 W EP 2005055285W WO 2006042833 A1 WO2006042833 A1 WO 2006042833A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- pigment
- molding composition
- composition according
- melamine
- anions
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/267—Marking of plastic artifacts, e.g. with laser
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
Definitions
- the object underlying the invention was thus to obtain plastic molding compounds that provide plastic objects with laser writing, without the properties of the plastic are significantly deteriorated.
- the molding composition according to the invention for the production of flame retardant articles with a matrix of a thermoplastic and dispersed therein particulate flame retardant pigment is characterized in that the pigment under the influence of laser light changes its color or the color of the plastic matrix and that the pigment is a reaction product at least one halogen-free flame-retardant organic nitrogen base with a salt or salt mixture which can be reacted with the organic nitrogen base.
- AIs matrix material all known thermoplastics, optionally glass fiber reinforced, can be used, which are described for example in Ullmann's Encyclopedia of Industrial Chemistry (Volume 15, page 457) and some of which have previously been used for laser marking. Suitable plastics are z.
- Polyethylene Polypropylene, polyamide, polyester, polyphenylene oxide, polyacetal, polybutylene terephthalate, polymethacrylate, polyoxymethylene, polyvinyl acetal, polystyrene, acrylic-butadiene-styrene (ABS), acrylonitrile-styrene-acrylic ester (ASA), polycarbonate, polyethersulfone, Polyethyletherketone, polyvinyl chloride and thermoplasti ⁇ cal polyurethane.
- ABS acrylic-butadiene-styrene
- ASA acrylonitrile-styrene-acrylic ester
- thermoplastic polymers having recurring ester units in the main chain are preferable.
- examples are polycondensation products of naphthalenedicarboxylic acids, terephthalic acid, isophthalic acid, adipic acid, azelaic acid, sebacic acid, dodecanedioic acid and cyclohexanedicarboxylic acid with dihydric alcohols such as ethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,4-butenediol and 1,6 Hexanediol, 1,4-hexanediol, 1,4-cyclohexanediol, 1,4-di- (hydroxymethyl) -cyclohexane, bisphenol A, neopentyl glycol, oligo- or polyethylene glycols, oligo- or polypropylene glycols, oligo- or poly- ( tetramethylene) -glycol
- Suitable polyamides are thermoplastic polymers having repeating acid amide groups in the main chain, namely homopolymers as well as copolymers with further comonomer groups.
- Examples thereof are polyhexamethyleneadipamide, polyhexamethyleneazelamide, polyhexamethylenesebacamide, polyhexamethylenedodecanediamide, poly-11-aminoundecanamide and bis (p-aminocyclohexyl) -methanodecanoic acid amide or by ring opening of lactams, e.g. B. polycaprolactam or Polylaurinlactam Pro ⁇ products.
- polyamides based on terephthalic or isophthalic acid as the acid component and / or trimethylhexamethylenediamine or bis (p-aminocyclohexyl) -propane as the diamine component and polyamide base resins which have been prepared by copolymerization of two or more of the abovementioned polymers or their components , are suitable.
- Thermoplastic polymers as mixture partners for the matrix material may be any semi-crystalline, liquid-crystalline and amorphous polymers.
- Polyurethane is particularly suitable because of its high-quality mechanical properties and the cost-effective processing methods.
- Thermoplastic polyurethanes have long been known from numerous literature publications and patents.
- This pigment which, on the one hand, has flame-retardant properties and, on the other hand, results in the laser describability by absorption of laser light.
- This pigment is a reaction product issued ⁇ least one halogen-free flame retardant organic nitrogen base with a reactive salt or salt mixture that can react with the nitrogen base.
- the organic nitrogen base is suitably melamine or a melamine derivative such as melamine cyanurate, melamine di-phosphate, dimelamine orthophosphate, melamine pyrophosphate, melamine polyphosphate, melamine borate, melamine salt of partial phosphoric acid ester, one or more of the phosphoroxy compounds, ammonium polyphosphate, boron phosphate and combinations thereof.
- the flame retardants used can also be used in triazine polymers, meyers, melam, urea, guanidine, etc.
- a salt is understood to mean compounds which dissociate in water at least partially into cations and anions or consist of an acid radical and a base radical.
- a change in color can be a change from one hue to another, for example from yellow to red or from transparent to black.
- this term is also understood to mean a change in brightness, for example from light brown to dark brown, and also a color change in the plastic matrix.
- the term "particulate" mean that the pigment is vor ⁇ in the form of fine solid particles, said quantitative information on the average particle size (d 5 o) and upon the size of the primary apply Operachen ⁇ .
- the size of the primary particles is in the nanometer Suitable primary particles have an average particle size (d 50 ) smaller than 10 ⁇ m, preferably smaller than 5 ⁇ m. - A -
- the pigments according to the invention may, without departing from the spirit of the invention, additionally contain further cations, in particular those of elements of the 2nd to 5th periods of the main group I. It is also possible to additionally add to the pigments inorganic oxides and / or further coloring additives and / or customary additives which modify certain properties, such as UV stabilizers, weathering stabilizers, for improving hydrolytic and acidolytic resistance, lubricants, mold release agents, Nucleating agents, fillers, plasticizers and other additives.
- the salts are selected such that they have the greatest possible absorption in the wavelength range of the available laser light.
- Suitable lasers have, for example, a wavelength in the range of 157 nm to 10.6 mm.
- Typical excimer lasers have the following wavelength: F 2 excimer laser (157 nm), ArF excimer laser (193 nm), XeCl excimer laser (308 nm), XeF excimer laser (351 nm), frequency-multiplied Nd: YAG lasers with wavelengths of 532 nm (frequency doubled) of 355 nm (frequency tripled) or 265 nm (frequency quadrupled). Particular preference is given to using Nd: YAG lasers (1064 or 532 nm) and CO 2 lasers.
- the energy densities of the lasers used according to the invention are generally in the range from 0.3 mj / cm 2 to 50 J / cm 2 , preferably 0.3 mJ / cm 2 to 10 J / cm 2 .
- the pulse frequency is generally in the range of 1 to 30 kHz.
- Pigments in the sense of this description are organic or inorganic salt-like compounds or mixtures of salt-like compounds which change their color under the influence of a laser light source at the exposed position.
- These compounds may be classical salts of defined stoichiometry of one or more anions with cations derived from one or more elements, but may also be non-stoichiometric compounds.
- Anions of the organic carboxylic acids and carbonic acid are preferred.
- the anions are not limited, but are anions of organic carboxylic acids and oxoanions, with the exception of phosphinates and diphosphinates and / or de ⁇ ren polymers and / or anions of carbonic acid.
- Preference is furthermore given to those combinations in which the intrinsic color of the unexposed compound can be adjusted by varying the molar ratios of the cations.
- the unexposed compound has the highest possible brightness and the lowest possible intrinsic color.
- the lighted compound should have as low a brightness as possible and still have the lowest possible protein color.
- the unexposed component should have the highest possible brightness and the lowest possible intrinsic color, while the exposed component should have the most distinct natural color possible.
- the pigment has at least one combination of two different elements of the group consisting of copper, tin, antimony and iron.
- the pigment comprises anions of phosphorus (V) and / or phosphoric (III) acid, their condensation products or optionally with further hydroxide ions and as cations Cu and Fe or Cu and Sn or Cu and Sb or Sn and Fe on.
- metal salts which have a particularly high thermal stability so that no decomposition takes place on account of the incorporation of the combination product produced by doping into the polymer.
- Be used salts or ligand having a thermal stability of about 200 0 C (2% weight loss), preferably with a stability of over 250 ° C (2% wt .-% loss), more preferably with a stability of more than 300 0 C (2% weight loss).
- Doping means both the preparation of mixtures of one or more of the abovementioned solid constituents in the pulverulent state and the mixing of one or more of the abovementioned solid constituents in dissolved or suspended form with subsequent drying of the pulverulent product.
- the products according to the invention all have both flame-retardant and laser-writable properties.
- the invention also relates to the pigments for the production of simultaneously flame-retardant and laser-inscribable plastic articles having the characteristics given above for the molding compositions. Likewise, the invention relates to the use of pigments having the given characteristics for the production of flame-retardant and at the same time laser-inscribable plastic articles, in particular those made of thermoplastics.
- Example 1 Pigment for a molding composition according to the invention was prepared as follows:
- a molding composition according to the invention was obtained from the pigment obtained.
- the flame resistance and laser writability were determined.
- the laser a commercially available Nd-YAG laser (wavelength 1064 nm) was used.
- the contrast values were determined by means of a digital camera mounted on a microscope and an image evaluation software.
- the flame resistance was determined using a UL box according to UL 94.
- the CTI values were checked in accordance with DIN IEC 601 12 / VDE 0303 Part 1, RAL 7035.
- thermoplastic molding compositions are characterized by their excellent flame resistance (self-extinguishing) as well as high contrast values (K value) in laser marking.
- Example 2 Pigment for a molding composition according to the invention was prepared as follows:
- a 50 l reactor with stirrer is filled with 29.25 l of pure water.
- Orthophosphoric acid 74.75 mol
- melamine 74.75 mol
- agglutination is prevented.
- copper hydroxide 7.47 mol
- the entire mixture is stirred for 1 h at 100 9 C, then the temperature is raised and dried under vacuum.
- the thus obtained doped melamine orthophosphate was reacted aminpolyphosphat in an oven at 340 0 C to MEI.
- the product was then ground to a fineness of 5 microns.
- This molding composition also gave excellent flame resistance and laser inscribability (K value).
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Liquid Developers In Electrophotography (AREA)
- Disintegrating Or Milling (AREA)
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2005800353619A CN101044027B (zh) | 2004-10-15 | 2005-10-14 | 用于产生高耐燃性制品的模塑材料、用于该材料的颜料及其用途 |
JP2007536192A JP2008517088A (ja) | 2004-10-15 | 2005-10-14 | 高難燃性製品製造用成形材、そのための顔料及びその用途 |
KR1020077010780A KR101282216B1 (ko) | 2004-10-15 | 2005-10-14 | 고도의 방염 제품의 제조를 위한 성형 물질, 이를 위한안료 및 상기 물질의 용도 |
US11/665,364 US7737201B2 (en) | 2004-10-15 | 2005-10-14 | Moulded mass for producing objects that are poorly inflammable, pigment therefor, and use of the same |
DE502005005053T DE502005005053D1 (de) | 2004-10-15 | 2005-10-14 | Formmasse für die herstellung schwer entflammbarerg |
AU2005296851A AU2005296851B2 (en) | 2004-10-15 | 2005-10-14 | Moulded mass for producing objects that are poorly inflammable, pigment therefor, and use of the same |
EP05801643A EP1817174B1 (de) | 2004-10-15 | 2005-10-14 | Formmasse für die herstellung schwer entflammbarer gegenstände, pigment hierfür und dessen verwendung |
HK08101204.2A HK1110555A1 (en) | 2004-10-15 | 2008-01-31 | Moulded mass for producing objects that are poorly inflammable, pigment therefor, and use of the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004050478A DE102004050478A1 (de) | 2004-10-15 | 2004-10-15 | Formmasse für die Herstellung schwer entflammbarer Gegenstände, Pigment hierfür und dessen Verwendung |
DE102004050478.4 | 2004-10-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006042833A1 true WO2006042833A1 (de) | 2006-04-27 |
Family
ID=35431671
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2005/055285 WO2006042833A1 (de) | 2004-10-15 | 2005-10-14 | Formmasse für die herstellung schwer entflammbarer gegenstände, pigment hierfür und dessen verwendung |
Country Status (12)
Country | Link |
---|---|
US (1) | US7737201B2 (de) |
EP (1) | EP1817174B1 (de) |
JP (1) | JP2008517088A (de) |
KR (1) | KR101282216B1 (de) |
CN (1) | CN101044027B (de) |
AT (1) | ATE404380T1 (de) |
AU (1) | AU2005296851B2 (de) |
DE (2) | DE102004050478A1 (de) |
ES (1) | ES2309809T3 (de) |
HK (1) | HK1110555A1 (de) |
TW (1) | TWI372771B (de) |
WO (1) | WO2006042833A1 (de) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008019925A1 (de) * | 2006-08-14 | 2008-02-21 | Chemische Fabrik Budenheim Kg | Laserbeschriftbares polymermaterial |
WO2013087733A3 (de) * | 2011-12-13 | 2013-08-08 | Chemische Fabrik Budenheim Kg | Halogenfreies flammschutzmittel für thermoplastisches polyurethan (tpu) |
US9175160B2 (en) | 2013-08-28 | 2015-11-03 | Sabic Global Technologies B.V. | Blend of poly(phenylene ether) particles and polyoxymethylene, article thereof, and method of preparation |
US9493621B2 (en) | 2013-07-23 | 2016-11-15 | Sabic Global Technologies B.V. | Rigid foam and associated article and method |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004050479A1 (de) * | 2004-10-15 | 2006-04-27 | Chemische Fabrik Budenheim Kg | Formmasse für die Herstellung schwer entflammbarer Gegenstände, Pigment hierfür und dessen Verwendung |
DE102007050327A1 (de) | 2007-10-19 | 2009-04-23 | EBCO Schäumtechnik GmbH & Co. KG | Flammfester Werkstoff auf der Basis von mit Flammschutzmitteln versetzten Polymeren, Polymer-Formteil aus einem solchen Werkstoff und Verfahren zu dessen Herstellung |
CN101724259B (zh) * | 2008-10-24 | 2013-02-06 | 中国石油化工股份有限公司 | 一种可激光标记的聚酰胺组合物及其制备方法 |
CN101891170B (zh) * | 2010-07-12 | 2012-01-25 | 华东理工大学 | 一种晶型稳定的结晶v型聚磷酸铵制备方法 |
CN102424713B (zh) * | 2011-11-19 | 2013-06-26 | 江苏百安居管业有限公司 | 超静音彩塑复合聚氯乙烯排水管材及其制造方法 |
CN103304967A (zh) * | 2013-06-24 | 2013-09-18 | 苏州新区佳合塑胶有限公司 | 一种无卤阻燃增强型pbt |
US9447227B2 (en) | 2013-10-03 | 2016-09-20 | Sabic Global Technologies B.V. | Flexible polyurethane foam and associated method and article |
DE102013112387B3 (de) * | 2013-11-11 | 2014-12-24 | Chemische Fabrik Budenheim Kg | Dotiertes Kupfer-II-Hydroxid-Phosphat, Verfahren zu dessen Herstellung und Verwendung |
CN105386294A (zh) * | 2015-10-16 | 2016-03-09 | 辽宁石油化工大学 | 一种涤纶阻燃织物及其制作方法 |
DE102017212099A1 (de) | 2017-07-14 | 2019-01-17 | Clariant Plastics & Coatings Ltd | Additivmischungen für Kunststoffe, lasermarkierbare Polymerzusammensetzungen enthaltend diese und deren Verwendung |
KR102007745B1 (ko) * | 2018-10-23 | 2019-08-07 | 주식회사 레진텍 | 증폭된 단파장광에 의한 변색 물질 및 이를 포함하는 수지 조성물 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0542115A1 (de) * | 1991-11-11 | 1993-05-19 | BASF Aktiengesellschaft | Thermoplastische Formmassen mit lasersensitiver Pigmentierung |
EP0764683A1 (de) * | 1995-09-21 | 1997-03-26 | Bayer Ag | Laserbeschriftbare Polymer-Formmassen |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0327508A3 (de) * | 1988-02-03 | 1991-02-06 | Ciba-Geigy Ag | Verfahren zur Laserbeschriftung pigmentierter Systeme |
JPH01222994A (ja) | 1988-03-03 | 1989-09-06 | Dainippon Ink & Chem Inc | レーザーマーキング用材料とマーキング方法 |
EP0345032B1 (de) | 1988-05-31 | 1996-09-11 | Dainippon Ink And Chemicals, Inc. | Verfahren und Zusammensetzung für Lasermarkierung |
GB8823482D0 (en) * | 1988-10-06 | 1988-11-16 | Ciba Geigy Ag | Flame retardants |
DE3917294A1 (de) * | 1989-05-27 | 1990-11-29 | Huels Chemische Werke Ag | Mit laserlicht beschriftbare hochpolymere materialien |
US5063137A (en) * | 1989-11-09 | 1991-11-05 | Dainippon Ink And Chemicals, Inc. | Laser-marking method and resin composition for laser-marking |
DE4415802A1 (de) * | 1994-05-05 | 1995-11-09 | Merck Patent Gmbh | Lasermarkierbare Kunststoffe |
US5489639A (en) * | 1994-08-18 | 1996-02-06 | General Electric Company | Copper salts for laser marking of thermoplastic compositions |
CN1189129A (zh) * | 1995-06-26 | 1998-07-29 | 拜尔公司 | 用激光能量造成局部颜色改变以产生非常高对比度视觉信息的聚合物模塑料的应用 |
DE19531490A1 (de) * | 1995-08-26 | 1997-02-27 | Basf Ag | Verfahren zur Beschriftung von Formkörpern |
US6214916B1 (en) * | 1998-04-29 | 2001-04-10 | General Electric Company | Composition for laser marking |
NL1009588C2 (nl) | 1998-07-08 | 2000-01-11 | Dsm Nv | Polyfosfaatzout van een 1,3,5-triazineverbinding met hoge condensatiegraad, een werkwijze voor de bereiding ervan en de toepassing als vlamdover in polymeersamenstellingen. |
DE19905358B4 (de) | 1999-02-10 | 2006-11-09 | Chemische Fabrik Budenheim Kg | Verwendung von Alkalikupferdiphosphat |
JP2000290462A (ja) * | 1999-04-05 | 2000-10-17 | Techno Polymer Kk | 難燃性樹脂組成物 |
NL1012476C2 (nl) * | 1999-06-30 | 2001-01-03 | Dsm Nv | Laserbeschrijfbare polymeersamenstelling. |
JP4390237B2 (ja) * | 2000-02-14 | 2009-12-24 | 東洋合成工業株式会社 | 感光性化合物及び感光性樹脂 |
US6706785B1 (en) * | 2000-02-18 | 2004-03-16 | Rona/Emi Industries, Inc. | Methods and compositions related to laser sensitive pigments for laser marking of plastics |
US6482879B2 (en) * | 2000-04-17 | 2002-11-19 | General Electric Company | Composition for laser marking |
DE10025291A1 (de) * | 2000-05-22 | 2001-11-29 | Basf Ag | Neue Phosphor-Stickstoff-Verbindungen als Flammschutzmittel in thermoplastischen Formmassen und ihre Herstellung |
DE10053639B4 (de) * | 2000-10-28 | 2007-04-12 | Chemische Fabrik Budenheim Kg | Verwendung von Eisen-, Cobalt-, Nickel- oder Molybdänsalzen |
DE10145093A1 (de) | 2001-09-13 | 2003-04-10 | Chem Fab Budenheim Kg | Verfahren zur Herstellung von Polyphosphaten organischer Basen |
DE10241375A1 (de) * | 2002-09-06 | 2004-03-18 | Clariant Gmbh | Granulare Flammschutzmittelzusammensetzung |
DE10252007A1 (de) | 2002-11-06 | 2004-05-27 | Merck Patent Gmbh | Lasermarkierbare Pigmente |
BRPI0316929B8 (pt) | 2002-12-04 | 2016-05-17 | Dsm Ip Assets Bv | aditivo absorvedor de luz de laser, seu processo de preparação, composição gravável a laser, objeto, pasta ou látex |
DE102004050479A1 (de) * | 2004-10-15 | 2006-04-27 | Chemische Fabrik Budenheim Kg | Formmasse für die Herstellung schwer entflammbarer Gegenstände, Pigment hierfür und dessen Verwendung |
DE102004050555B4 (de) * | 2004-10-15 | 2006-09-21 | Ticona Gmbh | Lasermarkierbare flammgeschützte Formmassen und daraus erhältliche lasermarkierbare und lasermarkierte Produkte sowie Verfahren zur Lasermarkierung |
-
2004
- 2004-10-15 DE DE102004050478A patent/DE102004050478A1/de not_active Withdrawn
-
2005
- 2005-10-06 TW TW094134997A patent/TWI372771B/zh not_active IP Right Cessation
- 2005-10-14 ES ES05801643T patent/ES2309809T3/es active Active
- 2005-10-14 AU AU2005296851A patent/AU2005296851B2/en not_active Ceased
- 2005-10-14 KR KR1020077010780A patent/KR101282216B1/ko active IP Right Grant
- 2005-10-14 AT AT05801643T patent/ATE404380T1/de not_active IP Right Cessation
- 2005-10-14 EP EP05801643A patent/EP1817174B1/de active Active
- 2005-10-14 CN CN2005800353619A patent/CN101044027B/zh active Active
- 2005-10-14 US US11/665,364 patent/US7737201B2/en active Active
- 2005-10-14 WO PCT/EP2005/055285 patent/WO2006042833A1/de active Application Filing
- 2005-10-14 JP JP2007536192A patent/JP2008517088A/ja active Pending
- 2005-10-14 DE DE502005005053T patent/DE502005005053D1/de active Active
-
2008
- 2008-01-31 HK HK08101204.2A patent/HK1110555A1/xx not_active IP Right Cessation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0542115A1 (de) * | 1991-11-11 | 1993-05-19 | BASF Aktiengesellschaft | Thermoplastische Formmassen mit lasersensitiver Pigmentierung |
EP0764683A1 (de) * | 1995-09-21 | 1997-03-26 | Bayer Ag | Laserbeschriftbare Polymer-Formmassen |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008019925A1 (de) * | 2006-08-14 | 2008-02-21 | Chemische Fabrik Budenheim Kg | Laserbeschriftbares polymermaterial |
CN101501140B (zh) * | 2006-08-14 | 2012-06-06 | 化学制造布敦海姆两合公司 | 可激光书写的聚合物材料 |
US8293147B2 (en) | 2006-08-14 | 2012-10-23 | Chemische Fabrik Budenheim Kg | Laser-writable polymer material |
KR101381770B1 (ko) * | 2006-08-14 | 2014-04-07 | 케미쉐 파브릭 부덴하임 카게 | 레이저-기재가능 중합체 물질 |
WO2013087733A3 (de) * | 2011-12-13 | 2013-08-08 | Chemische Fabrik Budenheim Kg | Halogenfreies flammschutzmittel für thermoplastisches polyurethan (tpu) |
US9493621B2 (en) | 2013-07-23 | 2016-11-15 | Sabic Global Technologies B.V. | Rigid foam and associated article and method |
US9175160B2 (en) | 2013-08-28 | 2015-11-03 | Sabic Global Technologies B.V. | Blend of poly(phenylene ether) particles and polyoxymethylene, article thereof, and method of preparation |
Also Published As
Publication number | Publication date |
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CN101044027B (zh) | 2010-11-03 |
TWI372771B (en) | 2012-09-21 |
CN101044027A (zh) | 2007-09-26 |
ES2309809T3 (es) | 2008-12-16 |
KR101282216B1 (ko) | 2013-07-09 |
DE102004050478A1 (de) | 2006-04-27 |
EP1817174B1 (de) | 2008-08-13 |
JP2008517088A (ja) | 2008-05-22 |
AU2005296851A1 (en) | 2006-04-27 |
US7737201B2 (en) | 2010-06-15 |
US20090124735A1 (en) | 2009-05-14 |
HK1110555A1 (en) | 2008-07-18 |
ATE404380T1 (de) | 2008-08-15 |
EP1817174A1 (de) | 2007-08-15 |
DE502005005053D1 (de) | 2008-09-25 |
KR20070085324A (ko) | 2007-08-27 |
TW200624487A (en) | 2006-07-16 |
AU2005296851B2 (en) | 2011-01-20 |
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