WO2006041001A1 - 中性電解水、中性電解水の製造方法及び中性電解水の製造装置 - Google Patents
中性電解水、中性電解水の製造方法及び中性電解水の製造装置 Download PDFInfo
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- WO2006041001A1 WO2006041001A1 PCT/JP2005/018528 JP2005018528W WO2006041001A1 WO 2006041001 A1 WO2006041001 A1 WO 2006041001A1 JP 2005018528 W JP2005018528 W JP 2005018528W WO 2006041001 A1 WO2006041001 A1 WO 2006041001A1
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- water
- electrolyzed water
- treated
- neutral electrolyzed
- electrolysis
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Classifications
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- C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
- C02F1/4674—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation with halogen or compound of halogens, e.g. chlorine, bromine
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- C—CHEMISTRY; METALLURGY
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- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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- C—CHEMISTRY; METALLURGY
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- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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- C—CHEMISTRY; METALLURGY
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- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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- C02F2001/46123—Movable electrodes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
Definitions
- the present invention relates to neutral electrolyzed water generated by an electrolyzer equipped with a low-frequency vibration stirrer and a continuous production apparatus for the neutral electrolyzed water.
- Such electrolyzed water is strongly acidic water or strong alkaline water.
- strong acidic water the pH is 2.7 or lower, and in strong alkaline water, it is 11 or higher. Bacteria and microorganisms cannot survive. Therefore, neutral electrolyzed water having an effect equal to or better than that of conventional products was required.
- Patent Document 1 (Nippon Techno Co., Ltd.) discloses a technique in which the blades of a vibratory flow stirrer are treated with anatase-type titanium oxide so as to have sterilizing power.
- the photocatalytic action of the blades decomposes organic substances and sterilizes in water, decomposes a small amount of chlorine compounds (organic halogen compounds such as torino, rhomethanes, and dioxins), and nitrate ions in tap water.
- chlorine compounds organic halogen compounds such as torino, rhomethanes, and dioxins
- nitrate ions in tap water.
- technology for oxidizing sulfate ions in groundwater to nitrite ions and sulfite ions respectively.
- the antiseptic water obtained in this document is neutral (pH 7.5 to 7.6), but its nitrite ion concentration is about 0.08-0.
- the neutral electrolyzed water is sterilized after the treatment or is preservative water, and does not maintain the sterilizing power for a long time.
- Patent Document 2 (Nippon Techno Co., Ltd.) operates a vibration stirring means provided in a water tank.
- a method for cleaning and sterilizing food using a sterilizing means such as a sterilizing metal Z metal compound (photocatalyst), a magnetic force generating member, and an ultraviolet irradiation means is disclosed.
- this method is a method that uses the oxidizing power of a photocatalyst, and sterilizing water is produced using a photocatalyst in the vibration stirrer as described above.
- the vibration stirrer was stopped, the bactericidal effect was not sustained, and it was difficult to use as sterilized water alone.
- the sealed sterilized water did not change until the bottle was opened. Therefore, since it is generally used in association with the photocatalytic device, the sterilizing power cannot be maintained for a long time in the open type.
- Patent Document 3 discloses a method for producing sterilized water having a hypochlorous acid concentration of 0.2 to 2 ppm using a diaphragm-type electrolytic cell.
- this sterilized water has a pH of 3 or less and exhibits strong acidity. Therefore, in addition to the above, there is a problem that the lifetime of the apparatus is limited.
- Patent Document 4 (Miura Electronics Co., Ltd. and others) discloses a method for producing free chlorine water by supplying saline to an electrolytic cell having an anode and a cathode. This free chlorine water is a cleaning / sterilizing water used for foods and sanitary purposes, and contains a large amount of free chlorine.
- the neutral electrolyzed water as in the present invention has a strong sterilizing power without chlorine odor. It is effective, used for deodorizing human pets, improved bad breath, used as a lotion and health drink water, has the effects of washing food, growing plants, etc. There is still electrolytic water that maintains these effects over a long period of time and has characteristics of both strong alkalinity and strong acidity.
- Patent Document 1 JP 2004-122109 A (Nippon Techno Co., Ltd.)
- Patent Document 2 JP 2004-008093 A (Nippon Techno Co., Ltd.)
- Patent Document 3 Pamphlet of International Publication No. 96Z03881 (Totoki Equipment Co., Ltd.)
- Patent Document 4 JP-A-4 330986 (Miura Electronics Co., Ltd.)
- the present invention has been made in view of the above-described problems, and an object thereof is to provide neutral electrolyzed water that can be used in a wide range of fields and is stable for a long period of time. Another object of the present invention is to provide a method for producing the neutral electrolyzed water and a production apparatus therefor.
- the method for producing neutral electrolyzed water according to the present invention includes:
- the treated water is oscillated with a period of 10 Hz to 200 Hz and an amplitude vibration of 0. Olmm to 15 mm so as to flow, and a voltage of IV to 30 V and a voltage of IV to 30 V, 5AZdm 2 to 300AZdm 2 It has the process of performing an electrolysis with the following current densities.
- the salt concentration in the water to be treated is
- the step of performing the electrolysis is performed for 5 minutes to 90 minutes.
- the treated water is seawater.
- the water is selected from the group consisting of tap water, groundwater, well water, distilled water, soft water, ion exchange water, and reverse osmosis membrane hydraulic power. .
- the method for producing neutral electrolyzed water according to the present invention is characterized by further comprising a photocatalytic treatment of the water to be treated before the step of performing the electrolysis.
- the photocatalytic treatment is performed by bringing the water to be treated into contact with photoactivated titanium anatase. Let's say.
- the neutral electrolyzed water according to the present invention includes:
- the neutral electrolyzed water according to the present invention is characterized by having residual chlorine of 1 mgZL or more and 7000 mgZL or less.
- the neutral electrolyzed water according to the present invention is characterized in that the hydrogen ion exponent pH is greater than 6.5 and less than 8.5.
- alkaline electrolyzed water is obtained, and it is necessary to adjust the pH to make it neutral, but in the neutral electrolyzed water according to the present invention, the neutral electrolyzed water is directly neutral. Area electrolyzed water is obtained.
- the neutral electrolyzed water according to the present invention is characterized by having a redox potential of 650 mV to 800 mV.
- the neutral electrolyzed water according to the present invention is used for sterilization, health drinks, food washing, medical use, cosmetic use, spray spray use, plant growth, deodorization, antiseptic use, disinfection use, pet use.
- Group power consisting of animal, pond, fountain, storage, appreciation water, and cleaning. It is used for at least one selected application.
- the apparatus for producing neutral electrolyzed water according to the present invention includes:
- An electrolytic cell for storing the water to be treated
- a plurality of plates arranged alternately in close proximity to the electrolytic cell and connected to a DC power source via a rectifier;
- Electrolysis is performed by applying a direct current or a pulsed current to the plurality of electrode plates while vibrating the water to be treated with the vibration stirrer.
- the apparatus for producing neutral electrolyzed water according to the present invention includes:
- An electrolytic cell for storing the water to be treated
- a vibration stirrer comprising a plurality of stirring blades connected to a direct current power source via a rectifier and vibrating the water to be treated;
- Electrolysis is performed by applying a direct current or a pulsed current to the plurality of stirring blades while vibrating the water to be treated with the vibration stirrer.
- a photocatalytic treatment tank for photocatalytically treating water to be treated;
- An electrolytic cell for storing the water to be treated that has been photocatalyzed;
- a plurality of plates arranged alternately in close proximity to the electrolytic cell and connected to a DC power source via a rectifier;
- Electrolysis is performed by applying a direct current or a pulsed current to the plurality of electrode plates while vibrating the water to be treated with the vibration stirrer.
- the distance between the plurality of electrode plates is from 0.3 mm to 100 mm.
- the distance between the plurality of stirring blades is 0.3 mm or more and 100 mm or less.
- a photocatalyst treatment tank for photocatalyzing the water to be treated an electrolysis tank for storing the water to be treated photocatalyzed, and the electrolysis
- Electrolytic decomposition is performed by applying direct current or pulse current to the plurality of electrode plates while causing water to vibrate and flow.
- the vibration stirrer is an insulating vibration stirrer.
- the treated water comprises at least one salt selected from the group consisting of NaCl, KC1 and CaCl force and water.
- the vibration stirrer means a low frequency vibration flow stirrer.
- the vibration motor is driven by an inverter.
- 200Hz ⁇ A stirrer that has LOHz vibration on the stirrer shaft, which is arranged in multiple stages on the stirrer shaft and vibrates to a few centimeters or less to generate turbulent flow with low energy. .
- the insulated vibration stirrer means one that connects the vibration shaft of the vibration stirrer or that uses vibration splash as an electrode attached to the shaft.
- the neutral electrolyzed water of the present invention has properties superior to any of the existing electrolyzed water such as acidic electrolyzed water and alkaline electrolyzed water, and is used for sterilization, health drinks, food washing, medical use, Used for cosmetics, spray spraying, plant growth, deodorization, antiseptic, disinfection, pet animals, pond fountains, water storage, viewing water and cleaning. Moreover, its properties are stable for a long period of 6 months to more than 1 year after storage. However, this neutral electrolyzed water has no chlorine odor.
- FIG. 1 is a diagram showing an outline of a vibration stirring means of the present invention.
- FIG. 2 is a front view of the water electrolysis apparatus of Example 1.
- FIG. 3 is a plan view of the water electrolysis apparatus of Example 1.
- FIG. 4 is a side view of the water electrolysis apparatus of Example 1.
- FIG. 5 is a parts list of the water electrolysis apparatus of Example 1.
- FIG. 6 is an example of a front view of the water electrolysis apparatus of Example 2.
- FIG. 7 is another example of a front view of the water electrolyzer of Example 2.
- FIG. 8 is a front view of a tank of Example 2.
- FIG. 9 is a plan view of a tank of Example 2.
- FIG. 10 is a side view of the tank of Example 2.
- FIG. 11 is a diagram showing an example of an analysis chart of generated gas (raw gas).
- FIG. 12 is a front view of the water electrolyzer of Example 3.
- FIG. 13 is a diagram showing an example of the arrangement of stirring blades in Example 3.
- FIG. 14 is a diagram showing an example of the arrangement of stirring blades in Example 3.
- FIG. 15 is a diagram showing an example of the arrangement of stirring blades in Example 3.
- FIG. 16 is a diagram showing an example of the arrangement of stirring blades in Example 3.
- FIG. 16 is a side view of FIG.
- FIG. 17 is a top view of a cylindrical insulating member.
- FIG. 18 is a cross-sectional view of a cylindrical insulating member.
- FIG. 19 is a view showing a state where vibrating bars 7 and 7 are fitted in the fitting holes 24 and 25 in the cylindrical insulating member.
- FIG. 20 is a view showing a photograph of the buttocks before applying neutral electrolyzed water.
- FIG. 21 is a view showing a photograph of the buttocks after applying neutral electrolyzed water.
- FIG. 22 is a front view of an electrolysis auxiliary tank in Example 10.
- FIG. 23 is a plan view of an electrolysis auxiliary tank in Example 10.
- FIG. 24 is a side view of an auxiliary electrolysis tank in Example 10.
- FIG. 25 is a diagram showing the E. coli growth inhibitory effect of neutral electrolyzed water according to the present invention.
- FIG. 26 is a graph showing the E. coli growth inhibitory effect of neutral electrolyzed water obtained by electrolysis for 1 minute according to the present invention.
- FIG. 27 is a graph showing the E. coli growth inhibitory effect of neutral electrolyzed water obtained by electrolysis for 3 minutes according to the present invention.
- FIG. 28 is a graph showing the E. coli growth inhibitory effect of neutral electrolyzed water obtained by electrolysis for 5 minutes according to the present invention.
- FIG. 29 is a schematic view of an apparatus for producing neutral electrolyzed water according to the present invention having a photocatalyst treatment section.
- the apparatus for producing neutral electrolyzed water according to the present invention includes, for example, the following components.
- This electrolytic cell may be of a type that is electrolyzed with a vibration stirrer having vibrating blades as electrode plates.
- the anode material is made of gold, rhodium, platinum or the like, and these materials may be used alone, or may be an alloy obtained by surface-treating these materials with a conductive material.
- the cathode material is made of stainless steel, titanium, etc., and these may be used alone or may be an alloy obtained by surface treatment of these materials with a conductive material.
- the electrolytic cell is always provided with an overflow for discharging neutral electrolyzed water and a supply port for supplying water.
- a supply pump for supplying a constant amount of electrolyzed water for supplying a constant amount of electrolyzed water.
- the treated water is at least one salt selected from the group consisting of NaCl, KC1 and CaCl
- this water examples include tap water, ground water, well water, distilled water, soft water, ion exchange water, and reverse osmosis membrane water. It may also be pool water or bath water.
- Neutral electrolyzed water is produced by electrolysis using a non-diaphragm electrolyzer equipped with a plurality of electrodes and a vibration stirrer or an insulating vibration stirrer having a vibration blade as an electrode plate.
- the vibration stirrer (a kind of vibration stirring means) will be described in detail.
- FIG. 1 is a diagram showing an outline of the vibration stirring means.
- the base 16a is fixed on a mounting base 40 attached to the upper part of the electrolytic cell 10A via a vibration absorbing member 41.
- a rod-shaped guide member 43 extending upward in the vertical direction is fixed to the mounting base 40, and the guide member 43 is located in the coil panel 16b.
- An inverter 35 for controlling the vibration frequency of the vibration motor 16d is interposed between the vibration motor 16d and the rectifier 25 for driving the vibration motor 16d.
- the voltage of the rectifier 25 is, for example, 200V AC.
- the vibration stirring means of the present invention is not limited to the one shown in Fig. 1, for example, Japanese Patent No. 1941498, Japanese Patent No. 2707530, Japanese Patent No.
- the vibration stirring means of the present invention will be further described.
- the vibration motor 16d is vibrated at 10 to 500Hz by the above-mentioned inverter, and this vibration is transmitted to the vibration rod 16e.
- the vibration blade 16f is rotated under the conditions of amplitude 0.01 to 30.Omm, frequency 500 to 30000 times Z. Vibrate.
- a Eurus Vibrator (Murakami Seisakusho) low frequency vibration motor (50 Hz to 60 Hz) and a high frequency Eurus (Murakami Seisakusho) high frequency vibration motor (60 Hz to 200 Hz) can be used.
- the anode electrode considering the properties such as (1) no harmful metal ions flow out, (2) corrosion resistance, (3) low chlorine overvoltage, (4) high oxygen overvoltage, etc.
- the anode plate is preferably a stainless steel (SUS) plate or a titanium plate coated with platinum or vanadium.
- SUS stainless steel
- TiC titanium-coated Pt—Ir alloy or titanium alloy plate is also preferable.
- rhodium, nickel, nickel alloy Ni—Mo, Ni—Co, Ni—Fe, Ni
- the distance between the electrodes may be 60 mm or less, but is preferably 0.2 to 5 mm. Shortening the distance increases the amount of neutral electrolyzed water produced and prevents heat generation. However, if the distance is short, the vibration stop of the electrolyzed water must be avoided in order to prevent galling in the electric electrode. It can be produced efficiently by using a vibration stirrer and has strong bactericidal power without generating chlorine odor and is produced as neutral electrolyzed water.
- the above-described electrolytic cell has no diaphragm! /, V, so-called non-diaphragm electrolytic cell.
- the inner surface of the conventional electrolytic cell was coated with a corrosion-resistant resin, and measures for heat resistance and corrosion resistance were required.
- this is hardly necessary.
- electrolysis Sustainability of diaphragm and electrode plate S Cost was high.
- the conductivity is deteriorated.
- the salt dissolved in the water is a small salt selected from the group consisting of NaCl, KC1, and CaCl force.
- At least one salt is exemplified.
- the concentration of this salt is low, usually 0.05-: LO weight%.
- forces KCl and CaCl using NaCl are similarly effective. Also,
- Seawater mainly contains NaCl and KC1, and is included as water to be treated in the present invention.
- electrolysis is usually performed in 5 to 90 minutes. That is, using the water to be treated as described above, the voltage is normally maintained within a range of 1 to 30 V by direct current or pulse current, and the current density is normally maintained within a range of 5 to 300 AZdm 2. The electrolysis is performed.
- a pulse current is preferable to direct current.
- a pulse waveform particularly a rectangular pulse waveform is preferred. According to the pulse waveform, precipitation is prevented, long-term use is possible, and performance degradation is prevented.
- This pulse waveform is generated according to a known technique. Examples include transistor-regulated power supplies, dropper power supplies, switching power supplies, silicon rectifiers, SCR rectifiers, high frequency rectifiers, inverter digital rectifiers, and the like.
- the neutral electrolyzed water of the present invention is produced as described above. That is, it contains a large amount of H and O.
- active oxygen such as OH, D, HD and HDO as active ingredients
- This neutral electrolyzed water contains hypochlorous acid and chlorite ions. Contains 1 to 7000mgZL of residual chlorine.
- the hydrogen ion exponent pH of the neutral electrolyzed water according to the present invention is preferably in the range of 6.5 ⁇ pH ⁇ 8.5, and more preferably 6.5 ⁇ pH ⁇ 7.5. Therefore, the neutral electrolyzed water according to the present invention is neutral electrolyzed water that is rinsed with acidic or alkaline electrolyzed water.
- the neutral electrolyzed water of the present invention maintains its bactericidal power for a long period of time despite being neutral. Conventional acid electrolysis Sterilizing power exceeding water can be maintained.
- the residual chlorine concentration in the neutral electrolyzed water of the present invention is generally used within the following range. Since the residual chlorine concentration increases as electrolysis continues, the operating time of the equipment is adjusted according to the application.
- the method for measuring the residual chlorine concentration is based on JIS K0102 for tap water.
- the neutral electrolyzed water according to the present invention acts on various microorganisms in an antibacterial, antibacterial and bactericidal manner.
- these bacteria include Escherichia coli (pathogenic E. coli such as E. coli and O-157), Salmonella, Vibrio parahaemolyticus, Campylobacter erucia, Clostridium perfringens, Nagvibrio, enterococci, green Jte ( Psudomonas aeruginosa), Burkholderiac epacia, Staphylococcus aureus, Staphylo coccus epidermidis, Streptococcus pneumonia (3 ⁇ 4treptococcous pneunmonia), Serratia, Proteus, Enterob acter, Citronocacter, Entercocous, Klebsiella, Bacteroides, Legionella ), Mycobacterium, Pneumocystiscarinii, fungus, etc.
- the neutral electrolyzed water according to the present invention When used, it can be sterilized in several tens of minutes to several days. Examples of the use of the neutral electrolyzed water of the present invention include the following.
- Facial spray using neutral electrolyzed water (The spray also penetrates the pores and stratum corneum of the skin. This spray produces negative ions and is healthy.)
- the neutral electrolyzed water of the present invention is used for sterilization, health drinks, food washing, medical use, cosmetics, spray spraying, plant growth, deodorization, antiseptic and disinfecting. Used for pet animals, ponds / fountains, water storage, viewing water and cleaning.
- Figures 2, 3, 4, and 5 are a front view, a plan view, a side view, and a list of parts, respectively, showing an outline of the test apparatus.
- Vibration motor 75W 200 ⁇ ⁇ 3
- Vibrating blade 4 stainless steel plates SUS304
- Vibration axis 2 stainless steel round bars SUS304
- a container 30L 500 X 290 X 305 (unit: mm) coated with heat-resistant propylene resin was used
- Electrode Anode plate 3 pieces of titanium lath net (platinum coating)
- Cathode plate SUS304 4 sheets
- the anode plate and the cathode plate were arranged close to each other. Area of the electrode plate, anode plate 3 sheets 12d m 2, 4 sheets plate cathode was 16 dm 2.
- Sodium chloride (primary chemical) was dissolved in Tokyo tap water to adjust the sodium chloride (NaCl) concentration to 5 gZL.
- a DC current of 12V and 15A was obtained by a rectifier using AC 200VX 3 phases.
- the frequency of the vibration motor was adjusted to 45Hz by the inverter, and the electrolyzed water was allowed to flow for 6 minutes while vibrating.
- the current density was 2AZL.
- E. coli (Kantoi Science Co., Ltd .: No. ATCC8739)
- Staphylococcus aureus (Kanto Chemical Co., Inc .: No. ATCC25923)
- the obtained neutral electrolyzed water was bottled, stored in a cool dark place, and measured after one week.
- E. coli MXLM Col 20 liquid medium for E. coli
- this example was performed by a batch method that is not performed by a continuous production apparatus.
- hypochlorous acid was performed by the following method. In the following examples, the measurement method was the same.
- neutral electrolyzed water was produced in the same manner as described above using the apparatus of FIG. 6 and FIG. 7 (neutral electrolyzed water production apparatus type 2 (100L: a torino water production apparatus type 2), and the effects thereof. As a result of the examination, substantially the same effect was obtained, and the following is a description of the symbols used in the apparatus shown in FIGS.
- Fig. 2 shows the equipment (neutral electrolyzed water production equipment-type 2 (
- Example 2 Other conditions were the same as in Example 1, ie, (2) water to be treated, (3) vibrational flow, (4) bacterial species, and (5) measurement method.
- Example 2 Using the apparatus of Example 2, neutral electrolyzed water was produced continuously for one month. Unlike the case of Example 1, when the distance between the electrodes was set to 5 mm, the production amount increased about 4 times.
- a device for dissolving salt in advance was added, and neutral electrolyzed water was continuously produced. This enabled long-time continuous production. A large amount of uniform neutral electrolyzed water with no rise in liquid temperature could be produced.
- Example 4 Hypochlorous acid in the neutral electrolyzed water obtained in Example 1 and Example 2 was quantitatively measured. Table 4 shows the measurement results. In any neutral electrolyzed water, the amount of hypochlorous acid was found to be less than the diaphragm electrolyzed water (strongly acidic electrolyzed water).
- the neutral electrolyzed water of the present invention like the alkaline electrolyzed water, gargles and makeup It was confirmed that it can be used for water.
- Example 1 and Example 2 tap water was continuously electrolyzed to obtain neutral electrolyzed water according to the present invention. This neutral electrolyzed water was stored in a sealed bottle for about one week. Thereafter, the gas generated from the neutral electrolytic hydropower was collected and analyzed. The components of this generated gas are H, O
- FIG. 1 An example of an analysis chart of the generated gas (raw gas) is shown in FIG. 1
- the horizontal axis represents the observed molecular mass number
- the vertical axis represents the intensity.
- the GAIN shown shows the height of 100 times the actual height for the mass of (1), the height of 10 times the actual height for the mass of (2), The actual height is shown for the mass. That is, the masses of GAIN (1) and GAIN (2) are amplified because the amount of the corresponding gas component is small.
- the analyzer used here was a mass spectrometer (double convergence mass spectrometer) manufactured by Electronic Science Co., Ltd. [trade name: EMD-05SK]. Analysis conditions are
- FIG. 12 is a front view of the test apparatus. Insulating vibration stirring means is used.
- the stirring blades can be arranged in four ways as shown in FIGS. Since the electrode plate and the vibrating blade are integrated, the entire apparatus is downsized. The number of vibrating blades is shown in the drawing.
- the cylindrical insulating member 23 will be further described.
- the cylindrical insulating member 23 corresponds to a specific example of the electrically insulating region in the present invention. Details of the cylindrical insulating member 23 are shown in FIGS. 17 is a top view, FIG. 18 is a cross-sectional view, and 23 is a cylindrical (hard rubber) insulating member that forms an insulating region. Holes for fitting the connecting band with the generating means, that is, fitting holes 24 and 25 are provided.
- FIG. 19 shows a state where the vibrating bars 7 and 7 are fitted in the fitting holes 24 and 25.
- Reference numeral 27 denotes an electric wire, which allows the vibrating rod 7 and the vibrating blade 8 to function as electrodes.
- auxiliary blades for electrodes can be used in combination with vibrating blades 8.
- the vibration blade is not necessarily required to function as an electrode, and is dedicated to vibration stirring.
- a synthetic resin can be used as the material of the vibration blade.
- the auxiliary blade 8 serves only for the electrode, but it may not show any vibration stirring ability.
- Residual chlorine concentration 15ppm (Application to plant growth)
- Example 1 and Example 2 the vibrating blades were alternately composed of electrode plates. Therefore, the entire apparatus that does not require the electrode plate to be installed separately from the vibration stirrer is downsized. Vibrating stirrer 7 Of 5 5 W vibrating blades, 3 were anodes and the remaining 2 were cathodes, and the tank capacity was about 1Z2 compared to the tank capacity of Example 1. Furthermore, the support of the vibration motor was sealed with rubber.
- Vibration motor 75WX 3 phase 1 unit was equipped with 3 anode blades and 2 cathode blades and vibrated at 40Hz.
- Neutral electrolyzed water was produced by applying a voltage of 3 V for 10 minutes. This neutral electrolyzed water was packed in a colored bottle and stored in a refrigerator for 1 month. Used as water for cut flowers. Compared to using tap water as is, neutral electrolyzed water lasted three times longer.
- Active ingredient types OH, D, HD and HDO
- the neutral electrolyzed water according to the present invention can be killed for 3 days when used for hand washing and disinfection. Bactericidal power persisted, but with strong acidic electrolyzed water, bactericidal power was lost in one day. In addition, strong acid electricity In the dewatering, rough hand is likely to occur, but in the neutral electrolyzed water according to the present invention, the rough hand is hardly generated.
- This electrolyzed water was used for the purpose of preventing rhinitis, gargle, and oral hygiene. It was found to be suitable for hand, skin and hair hygiene.
- Figs. 20 to 21 are photographs showing the buttocks before and after applying neutral electrolyzed water.
- acidic electrolyzed water is not used for treatment although it has bactericidal activity.
- a general acidic electrolyzed water containing 20 ppm of free chlorine and a neutral electrolyzed water of the present invention (Example 3) were used.
- the neutral electrolyzed water produced in Example 3 was put as a stock solution in a handling “spray” type atomizer.
- the above neutral electrolyzed water was diluted three-fold with tap water into a similar atomizer and added as three-fold diluted water.
- the bacterium was transplanted to a normal agar medium and cultured at 35 ° C for 24 hours, and then one colony was transferred to a normal bouillon medium and cultured with shaking at 35 ° C for 18 hours.
- This bacterial solution was prepared by diluting with ordinary broth.
- test product Put 50 ml of the test product into a 100 ml sterile Erlenmeyer flask and add the test bacteria prepared in 2 above 0.1 ml of the solution was charged and stored at 35 ° C.
- the number of viable bacteria per ml in the Erlenmeyer flask was measured by a pour culture method using SCDLP agar medium. SCDLP broth medium was used for dilution when measuring viable count.
- the initial bactericidal power remained unchanged after 6 months of storage.
- the strong acid electrolyzed water lost its bactericidal power after 6 months.
- Two 10-liter tanks were prepared. One tank was filled with general strongly acidic electrolyzed water containing 10 ppm free chlorine, and 10 medakas were released. The other aquarium was filled with the neutral electrolyzed water of the present invention (Example 2), and in the same way, 10 animals were released. In addition, with tap water, meda power cannot grow.
- Neutral electrolyzed water production apparatus type 1 (30L): a Torino water production apparatus type 1 (manufactured by Nippon Techno Co., Ltd.) was used.
- Vibration motor 75W 200V X 3 phase 1 unit
- Vibrating blade 4 SUS304
- Container 500 x 290 x 305 (unit: mm) coated with heat-resistant propylene resin
- Anode plate 3 platinum-coated titanium plates
- Cathode plate 4 titanium plates
- Anode plates and cathode plates are alternately arranged.
- the area of the electrode plate was 4.8 dm 2 for the four cathode plates and 6 dm 2 for the three anode plates.
- Sodium chloride (reagent grade) was added to prepare 0.3% by weight (3 gZL) of electrolyzed water.
- Electrolysis was performed by applying a direct current of 3V.
- the frequency of the vibrating blades was 40 Hz, and the electrolysis time was 60 minutes. Residual chlorine concentration reached 300ppm.
- the pH was 6.8. There was no increase in the temperature of the electrolyzed water, and energization was possible.
- Hypochlorous acid concentration 20ppm
- Active ingredient types OH, D, HD and HDO
- This electrolyzed water was packed in a clear bottle (1 liter), stored in a refrigerator for 1 month, diluted 10 times, and used for testing.
- Example 9 The apparatus of Example 9 was equipped with the electrolysis auxiliary tank (capacity: 100 L) shown in Figs.
- Electrolytic auxiliary tank code
- This auxiliary tank and the electrolytic cell were connected by a pipe.
- neutral electrolyzed water was continuously produced using tap water. Production volume: Approximately 4.51Z minutes. Processing was possible for a long time. Practical testing was continued for one year, but the decline in performance was not recognized.
- Active ingredient types OH, D, HD and HDO
- the neutral electrolyzed water produced in Example 9 was used as a skin external preparation or cosmetic. Compared to a commercially available external preparation for skin using astringen, it was almost inferior in terms of use feeling and gloss retention.
- the above neutral electrolyzed water is combined with quasi-drugs such as cosmetics such as emulsion creams, lotions, knocks, shampoos, rinses and detergents, ointments, dispersants, creams and external liquids. Viscosity could be adjusted with water-soluble polymer compounds as thickeners, emulsifiers and film formers. In addition, general strong acid electrolyzed water cannot be used for such a use.
- Salt was dissolved in tap water to a concentration of 0.4% by weight (4 gZL).
- the frequency of the vibration motor was 43.8 Hz.
- Neutral electrolyzed water was produced using the same apparatus as in Example 2.
- Neutral electrolyzed water produced according to Example 1 was stored in a bottle in a refrigerator for 3 months and tested for its bactericidal effect. In general, strongly acidic electrolyzed water maintained sterilization ability at the beginning of production, but its sterilizing power almost disappeared after 3 months.
- E. coli clinically isolated drug resistant strain
- Bacteria species 30 seconds 60 seconds 90 seconds 1 20 seconds 3 minutes 5 minutes 1 0 minutes 20 minutes E. coli------
- Bacterial species 30 seconds 6 0 seconds 9 0 seconds 1 2 0 seconds 3 minutes 5 minutes 10 minutes 20 minutes E. coli----Staphylococcus aureus---- Bacteria ⁇ ⁇ ⁇
- Electrolyzer Heat-resistant propylene resin, 200L capacity
- Electrolyzed water was put into the tank and the vibration stirrer was powered at room temperature to dissolve completely in 5 minutes.
- the bactericidal effect without chlorine odor was equivalent to NaCl.
- Neutral electrolyzed water of Example 15 was stored in a plastic tank (16 L) for 3 months, and a water quality test of the stock solution was conducted. Residual chlorine concentration was below 250ppm of water quality standard.
- This solution was put into a small plastic spray and used for oral disinfection and dentist oral cleaning.
- finishing cleaning with tap water is required after oral sterilization, but the neutral electrolytic water according to the present invention does not require finishing cleaning. It could be used as gargle or drinking water.
- Example 17 Seawater was treated using the following apparatus for producing neutral electrolyzed water according to the present invention.
- Test equipment a Torino water production equipment type I
- Electrolysis was performed at 5 amperes (constant current) and 3.57 V, and samples were sampled at the following times.
- the concentration of water to be treated can be generally determined by adding salt solution 0.05 to 8% to water such as ion exchange and tap water. Electrolyze. At this time, it is preferable to perform electrolysis at a current density of 0.05 AZL-5A-L. The electrolysis time is preferably 10 to 90 minutes.
- the apparatus for producing neutral electrolyzed water according to the present invention may be used in such a marine vessel.
- “sterilized ice” having strong bactericidal and antiseptic effects may be produced by the apparatus for producing neutral electrolyzed water according to the present invention using seawater and used for maintaining the freshness of fish.
- this neutral electrolyzed water has a highly safe antiseptic effect without producing harmful substances such as sodium hypochlorite.
- Rectifier DC12V—20A
- the neutral electrolyzed water of the present invention has the effects as described above over a long period of time and can be expected to be used in a wide range of fields. Along with this, an increase in production volume is also predicted.
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Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2005292966A AU2005292966B2 (en) | 2004-10-08 | 2005-10-06 | Neutral electrolytic water, neutral electrolytic water production method, and neutral electrolytic water production device |
CA002577990A CA2577990A1 (en) | 2004-10-08 | 2005-10-06 | Neutral electrolytic water, neutral electrolytic water production methodand device thereof |
JP2006540908A JP4365413B2 (ja) | 2004-10-08 | 2005-10-06 | 中性電解水、中性電解水の製造方法及び中性電解水の製造装置 |
CN2005800291881A CN101010261B (zh) | 2004-10-08 | 2005-10-06 | 中性电解水、中性电解水的制造方法及中性电解水的制造装置 |
US11/660,118 US8062501B2 (en) | 2004-10-08 | 2005-10-06 | Neutral electrolytic water, neutral electrolytic water production method and device thereof |
EP05790593A EP1829826A4 (en) | 2004-10-08 | 2005-10-06 | NEUTRAL ELECTROLYTIC WATER, METHOD FOR PRODUCING NEUTRAL ELECTROLYTIC WATER, AND NEUTRAL ELECTROLYTIC WATER MANUFACTURING DEVICE |
HK08101197.1A HK1110572A1 (en) | 2004-10-08 | 2008-01-31 | Neutral electrolytic water, neutral electrolytic water production method, and neutral electrolytic water production device |
Applications Claiming Priority (2)
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JP2004-296332 | 2004-10-08 | ||
JP2004296332 | 2004-10-08 |
Publications (1)
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WO2006041001A1 true WO2006041001A1 (ja) | 2006-04-20 |
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---|---|---|---|
PCT/JP2005/018528 WO2006041001A1 (ja) | 2004-10-08 | 2005-10-06 | 中性電解水、中性電解水の製造方法及び中性電解水の製造装置 |
Country Status (8)
Country | Link |
---|---|
US (1) | US8062501B2 (ja) |
EP (1) | EP1829826A4 (ja) |
JP (1) | JP4365413B2 (ja) |
CN (1) | CN101010261B (ja) |
AU (1) | AU2005292966B2 (ja) |
CA (1) | CA2577990A1 (ja) |
HK (1) | HK1110572A1 (ja) |
WO (1) | WO2006041001A1 (ja) |
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JP2008260740A (ja) * | 2007-04-13 | 2008-10-30 | Asahi Pretec Corp | 殺菌作用および止血作用を有する電解水組成物 |
JP2009142436A (ja) * | 2007-12-13 | 2009-07-02 | Tsutomu Sanaka | 透析用水溶液 |
KR20100099099A (ko) * | 2007-09-28 | 2010-09-10 | 인두스트리에 데 노라 에스.피.에이. | 농업 분야에서의 살생물제 처리용 전기화학적 장치 |
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- 2005-10-06 AU AU2005292966A patent/AU2005292966B2/en not_active Ceased
- 2005-10-06 EP EP05790593A patent/EP1829826A4/en not_active Withdrawn
- 2005-10-06 CA CA002577990A patent/CA2577990A1/en not_active Abandoned
- 2005-10-06 JP JP2006540908A patent/JP4365413B2/ja active Active
- 2005-10-06 US US11/660,118 patent/US8062501B2/en not_active Expired - Fee Related
- 2005-10-06 WO PCT/JP2005/018528 patent/WO2006041001A1/ja active Application Filing
- 2005-10-06 CN CN2005800291881A patent/CN101010261B/zh active Active
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Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008260740A (ja) * | 2007-04-13 | 2008-10-30 | Asahi Pretec Corp | 殺菌作用および止血作用を有する電解水組成物 |
JP2015007285A (ja) * | 2007-09-28 | 2015-01-15 | インドゥストリエ・デ・ノラ・ソチエタ・ペル・アツィオーニ | 農業への応用における殺生物剤処理用の電気化学的装置 |
KR20100099099A (ko) * | 2007-09-28 | 2010-09-10 | 인두스트리에 데 노라 에스.피.에이. | 농업 분야에서의 살생물제 처리용 전기화학적 장치 |
JP2010539916A (ja) * | 2007-09-28 | 2010-12-24 | インドゥストリエ・デ・ノラ・ソチエタ・ペル・アツィオーニ | 農業への応用における殺生物剤処理用の電気化学的装置 |
KR101615502B1 (ko) * | 2007-09-28 | 2016-04-27 | 인두스트리에 데 노라 에스.피.에이. | 농업 분야에서의 살생물제 처리용 전기화학적 장치 |
JP2009142436A (ja) * | 2007-12-13 | 2009-07-02 | Tsutomu Sanaka | 透析用水溶液 |
JP2011073988A (ja) * | 2009-09-29 | 2011-04-14 | Japan Techno Co Ltd | 植物病害防除機能剤、及びそれを用いて植物を生育させる方法 |
JP2011073989A (ja) * | 2009-09-29 | 2011-04-14 | Japan Techno Co Ltd | 損傷した生体表層部の回復を促進させる機能剤、及びそれを用いて損傷した生体表層部の回復を促進させる方法 |
JP2011155861A (ja) * | 2010-01-29 | 2011-08-18 | Japan Techno Co Ltd | 採卵鶏用飲料水、それを用いた養鶏方法、及びそれにより生産される鶏卵 |
JP2018131469A (ja) * | 2010-07-22 | 2018-08-23 | リベン ファーマシューティカルズ インコーポレイテッド | 磁気双極子安定化溶液の使用を含む疾患を処置または改善する方法および行動を向上させる方法 |
WO2013002287A1 (ja) * | 2011-06-28 | 2013-01-03 | 株式会社セルフメディカル | 電解水生成装置、およびそれを含む歯科用診療装置、並びに歯科用診療装置の給水管路内を殺菌する方法 |
JP4902803B1 (ja) * | 2011-06-28 | 2012-03-21 | 株式会社セルフメディカル | 電解水生成装置、およびそれを含む歯科用診療装置、並びに歯科用診療装置の給水管路内を殺菌する方法 |
JP2015520022A (ja) * | 2012-05-15 | 2015-07-16 | ベイジン ナノ ハイ−テク マテリアル カンパニー,リミテッドBeijing Nano Hi−Tech Material Co., Ltd. | 塩類アルカリ土壌の改良方法と装置 |
WO2014103083A1 (ja) * | 2012-12-27 | 2014-07-03 | 株式会社レドックス | 清涼飲料水製造原水基準に適合した電解水及び電解水製造方法 |
Also Published As
Publication number | Publication date |
---|---|
AU2005292966A1 (en) | 2006-04-20 |
CN101010261A (zh) | 2007-08-01 |
CA2577990A1 (en) | 2006-04-20 |
CN101010261B (zh) | 2010-04-07 |
JP4365413B2 (ja) | 2009-11-18 |
US8062501B2 (en) | 2011-11-22 |
EP1829826A4 (en) | 2008-12-03 |
AU2005292966B2 (en) | 2011-02-10 |
US20070215489A1 (en) | 2007-09-20 |
HK1110572A1 (en) | 2008-07-18 |
EP1829826A1 (en) | 2007-09-05 |
JPWO2006041001A1 (ja) | 2008-05-15 |
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