WO2006022072A1 - Manufacturing method of electronic component - Google Patents

Manufacturing method of electronic component Download PDF

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Publication number
WO2006022072A1
WO2006022072A1 PCT/JP2005/011443 JP2005011443W WO2006022072A1 WO 2006022072 A1 WO2006022072 A1 WO 2006022072A1 JP 2005011443 W JP2005011443 W JP 2005011443W WO 2006022072 A1 WO2006022072 A1 WO 2006022072A1
Authority
WO
WIPO (PCT)
Prior art keywords
electronic component
conductive adhesive
substrate
component element
electrode
Prior art date
Application number
PCT/JP2005/011443
Other languages
French (fr)
Japanese (ja)
Inventor
Masachika Takata
Original Assignee
Murata Manufacturing Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Murata Manufacturing Co., Ltd. filed Critical Murata Manufacturing Co., Ltd.
Publication of WO2006022072A1 publication Critical patent/WO2006022072A1/en

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Classifications

    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H9/00Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
    • H03H9/15Constructional features of resonators consisting of piezoelectric or electrostrictive material
    • H03H9/17Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator
    • H03H9/177Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator of the energy-trap type
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H9/00Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
    • H03H9/02Details
    • H03H9/05Holders; Supports
    • H03H9/0504Holders; Supports for bulk acoustic wave devices
    • H03H9/0514Holders; Supports for bulk acoustic wave devices consisting of mounting pads or bumps
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H9/00Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
    • H03H9/02Details
    • H03H9/05Holders; Supports
    • H03H9/10Mounting in enclosures
    • H03H9/1007Mounting in enclosures for bulk acoustic wave [BAW] devices
    • H03H9/1014Mounting in enclosures for bulk acoustic wave [BAW] devices the enclosure being defined by a frame built on a substrate and a cap, the frame having no mechanical contact with the BAW device
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/30Assembling printed circuits with electric components, e.g. with resistor
    • H05K3/32Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits
    • H05K3/321Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by conductive adhesives
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/10Details of components or other objects attached to or integrated in a printed circuit board
    • H05K2201/10613Details of electrical connections of non-printed components, e.g. special leads
    • H05K2201/10621Components characterised by their electrical contacts
    • H05K2201/10636Leadless chip, e.g. chip capacitor or resistor
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/10Details of components or other objects attached to or integrated in a printed circuit board
    • H05K2201/10613Details of electrical connections of non-printed components, e.g. special leads
    • H05K2201/10954Other details of electrical connections
    • H05K2201/10992Using different connection materials, e.g. different solders, for the same connection
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/14Related to the order of processing steps
    • H05K2203/1476Same or similar kind of process performed in phases, e.g. coarse patterning followed by fine patterning
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the present invention relates to a method for manufacturing an electronic component, and more particularly relates to a method for manufacturing an electronic component including a step of mounting an electronic component element such as a piezoelectric resonant element on a substrate using a conductive adhesive. .
  • Patent Document 1 discloses an electronic component shown in FIG.
  • electrode lands 103 and 104 are formed on an insulating substrate 102 having an insulating ceramic force.
  • the electronic component element 105 is bonded onto the substrate 102 using the conductive adhesives 106 and 107.
  • the electronic component element 105 has a structure in which excitation electrodes 105b and 105c are formed on both main surfaces of an electronic component element 105a that also has a piezoelectric ceramic force.
  • the excitation electrode 105 c is bonded to the electrode land 103 by the conductive adhesive 106.
  • the excitation electrode 105b formed on the upper surface is connected to an electrode extension portion 105d that reaches the lower surface through the end surface of the electronic component body 105a.
  • the electrode extension 105d is joined to the electrode land 104 through the conductive adhesive 107.
  • a cap 108 having an opening opened downward is fixed to the base plate 102 so as to surround the electronic component element 105.
  • Patent Document 1 Japanese Patent Laid-Open No. 11-265955
  • the thermal expansion coefficient of the insulating ceramic constituting the substrate 102 and the thermal expansion coefficient of the piezoelectric ceramic constituting the electronic component body 105 a are different.
  • the electronic component body 105a was forced to generate stress due to the difference in thermal expansion coefficient.
  • the difference in thermal expansion coefficient is large, the electronic component body 105a may be destroyed by the thermal stress generated in the electronic component body 105a.
  • the conductive adhesives 106 and 107 having excellent elasticity may be used.
  • the conventional joint structure using the conductive adhesives 106 and 107 has not been able to sufficiently reduce the stress caused by the difference in thermal expansion coefficient. For this reason, cracks occurred at the bonding interface between the conductive adhesives 106 and 107 and the electronic component element 105, and the bonding reliability was not sufficient.
  • characteristics such as the elastic modulus of the conductive adhesives 106 and 107 changed with the ambient temperature, and the electrical characteristics of the electronic component 105 tended to fluctuate accordingly.
  • An object of the present invention is to solve the above-described drawbacks of the prior art, and in an electronic component having a structure in which an electronic component element is bonded on a substrate using a conductive adhesive, when the ambient temperature changes Even so, it is an object of the present invention to provide a method for manufacturing an electronic component that has excellent bonding reliability, in particular, cracks at the bonding interface between the conductive adhesive and the electronic component element, and has little variation in characteristics.
  • the present invention is a method for manufacturing an electronic component in which an electronic component element is fixed using a conductive adhesive on a substrate on which at least one main surface is provided with a plurality of electrode lands.
  • the step of preparing the substrate formed on one main surface and the electronic component element, and the portion of the electronic component element bonded to the electrode land of the substrate larger than the area bonded to the electrode land Applying and curing the first conductive adhesive to an area, and after the first conductive adhesive is cured, the first conductive adhesive is bonded to the electrode land.
  • the electronic component element has first and second end portions facing each other, and is mounted on the substrate of the electronic component element. On the surface, the electronic component element is bonded to the electrode land of the substrate in the vicinity of the first end portion and the vicinity of the second end portion.
  • the first conductive adhesive is used for removing unnecessary portions after curing the first conductive adhesive. Along with the unnecessary part, a part of the electronic component element connected to the unnecessary part of the conductive adhesive is also removed by the cutting jig.
  • the electronic component element is connected to the first and second main surfaces facing each other and the first and second main surfaces.
  • An electronic component main body having first and second end faces, and a plurality of electrodes to be connected to a plurality of electrode lands on the substrate are provided on the first main surface.
  • the electronic component main body is a piezoelectric body, and faces the first and second main surfaces via the piezoelectric body.
  • the first and second excitation electrodes are formed, whereby a piezoelectric resonator is obtained.
  • a cap is fixed to the substrate so as to cover the electronic component element.
  • a process is further provided.
  • the first conductive property is formed so that the area bonded to the electrode land on the substrate of the electronic component element has a larger area than the area bonded to the electrode land.
  • Apply adhesive Then, after the first conductive adhesive is cured, an unnecessary portion of the first conductive adhesive is formed so that the first conductive adhesive has the above-described area to be bonded to the electrode land. Is removed by cutting. Thereafter, the first conductive adhesive and the electrode land of the substrate are fixed by joining via the second conductive adhesive. Therefore, after the first conductive adhesive is cured, the internal stress in the cured first conductive adhesive can be sufficiently reduced by cutting and removing unnecessary portions of the first conductive adhesive.
  • the first conductive adhesive with reduced internal stress and the electrode land of the substrate are joined via the second conductive adhesive. Accordingly, the electronic component element is bonded to the electrode land of the substrate by two-stage curing of the first conductive adhesive and the second conductive adhesive. Moreover, in the cured product of the first conductive adhesive, the internal stress is reduced by cutting and removing the unnecessary portion. Therefore, since it is possible to effectively reduce the internal stress at the joint portion due to the conductive adhesive, cracks are hardly generated at the joint interface between the conductive adhesive and the electronic component element. Therefore, it is possible to provide an electronic component excellent in the reliability of electrical connection and mechanical joining regardless of changes in ambient temperature.
  • the electronic component element has first and second end portions facing each other, and the first component portion vicinity portion and the second end portion vicinity portion on the surface of the electronic component element mounted on the substrate.
  • the electronic component is supported in the vicinity of both ends, and is reliable in electrical connection and mechanical bonding with a conductive adhesive.
  • An electronic component having excellent properties can be provided.
  • an electronic component main body having first and second main surfaces facing each other and first and second end surfaces connecting the first and second main surfaces, and a first main
  • the first main surface side force electronic component element that can be surface mounted on the substrate is provided. Electronic parts can be provided.
  • the electronic component main body is a piezoelectric body and the first and second excitation electrodes are formed on the first and second main surfaces so as to face each other with the piezoelectric body interposed therebetween, According to the present invention, an electronic component having a piezoelectric resonator mounted on a substrate and excellent in electrical connection and mechanical bonding reliability can be provided.
  • the electronic component element is further bonded to the substrate after the electronic component element is bonded to the substrate, the electronic component element is internally formed by the substrate and the cap according to the present invention. It is possible to provide an electronic component sealed in the container.
  • FIGS. 1 (a) and 1 (b) show a method of manufacturing an electronic component according to an embodiment of the present invention, wherein unnecessary portions are cut after the first conductive adhesive is cured. It is the cross-sectional view and top view for demonstrating the process to remove.
  • FIG. 2 is a perspective view showing a mother piezoelectric plate prepared in the first embodiment.
  • FIG. 3 is a cross-sectional view for explaining the mother piezoelectric plate after curing and removing unnecessary portions after curing the first insulating adhesive.
  • FIG. 4 is a cross-sectional view of a mother piezoelectric plate showing a state where an electrode is formed by applying and curing a conductive paste following cutting and removal.
  • FIG. 5 is a perspective view for explaining a process of cutting individual piezoelectric plates to obtain individual electronic component elements.
  • FIG. 6 is a perspective view showing an electronic component element as a piezoelectric resonator obtained in the first embodiment.
  • FIG. 7 is an exploded perspective view for explaining a process of mounting the electronic component element of the first embodiment on a substrate.
  • FIG. 8 is a front sectional view showing a structure in which an electronic component element is fixed on a substrate using a second conductive adhesive in the first embodiment.
  • FIG. 9 is a front sectional view showing an example of a conventional electronic component.
  • a mother electronic component element 1 shown in FIG. 2 is prepared.
  • the mother electronic component element 1 includes a rectangular plate-like mother piezoelectric plate 2.
  • the mother piezoelectric plate 2 is made of piezoelectric ceramics polarized in the direction indicated by the arrow P! Examples of such piezoelectric ceramics include lead titanate ceramics. At the same time, other piezoelectric ceramics may be used, or a piezoelectric single crystal such as quartz may be used.
  • a first mother excitation electrode 3 is formed on the upper surface of the mother piezoelectric plate 2.
  • the excitation electrode 3 has one side surface 2 a side force extended toward the other side surface 2 b side.
  • the excitation electrode 3 is opposed to the connection electrode 4 with a gap.
  • the connection electrode 4 is extended on the upper surface of the piezoelectric plate 2 from the edge formed by the upper surface and the side surface 2b toward the side surface 2a.
  • the second excitation electrode 5 is formed on the lower surface of the piezoelectric plate 2.
  • the second excitation electrode 5 is extended from the edge formed by the side surface 2b and the lower surface toward the side surface 2a.
  • the excitation electrode 5 of the second mother is opposed to the center of the width direction connecting the excitation electrode 3 of the first mother and the side surfaces 2a and 2b of the piezoelectric plate 2 with the piezoelectric plate 2 therebetween.
  • a connection electrode 6 is formed on the lower surface of the piezoelectric plate 2 with a gap from the second excitation electrode 5.
  • the connection electrode 6 is extended from the edge formed by the side surface 2a and the lower surface toward the side surface 2b.
  • the excitation electrodes 3 and 5 and the connection electrodes 4 and 6 can be formed of a conductive material such as Ag or an Ag alloy.
  • the conductive material is not limited to Ag or Ag alloy, but may be other metals or alloys such as Cu or A1.
  • the electrode forming method is not particularly limited, and a suitable method such as thin film forming method such as vapor deposition, sputtering or plating, or applying and curing of conductive paste can be used.
  • the first conductive adhesives 7 and 8 are applied to the upper surface of the above-mentioned piezoelectric plate 2 of the mother as shown in the cross-sectional view and the plan view in FIGS. 1 (a) and 1 (b). And cure.
  • the first conductive adhesives 7 and 8 are formed on the upper surface of the mother piezoelectric plate 2, respectively, on the edge and side surfaces formed by the side surface 2a and the upper surface. It extends along the edge formed by 2b and the upper surface.
  • the first conductive adhesives 7 and 8 have a trapezoidal cross section.
  • the length of the bottom base of the trapezoid in the cross section of the other first conductive adhesive 8 is made equal to the dimension in the width direction of the connection electrode 4.
  • the dimension in the width direction refers to the dimension along the width direction of the above-described mother piezoelectric plate 2, that is, the direction connecting the side surfaces 2a and 2b.
  • the shape of the cross section of the first conductive adhesive 7 is also the same as the shape of the cross section of the other first conductive adhesive 8.
  • the application area of the first conductive adhesives 7, 8 is made larger than the area of the joint portion between the piezoelectric resonator and the conductive adhesive finally obtained by the present embodiment. .
  • alternate long and short dash lines A and B in FIG. 1 (a) indicate cutting lines, and cutting is performed along cutting lines A and B in a later step. Then, by cutting the first conductive adhesives 7 and 8 along the cutting lines A and B, the unnecessary portions 7a and 8a outside the cutting lines A and B are removed. The area of the bonded portion between the remaining cured portions 7b and 8b from which the unnecessary portions 7a and 8a are removed and the finally obtained piezoelectric resonator is naturally larger than the bonding interface before the unnecessary portions 7a and 8a are removed. It will be smaller.
  • the first conductive adhesives 7, 8 generate stress during curing, and the cured product has a large internal stress. While cutting along the cutting lines A and B, the unnecessary portions 7a and 8a are removed, so that the remaining portions of the first conductive adhesive portions 7b and 8b have an internal stress. Will be reduced.
  • a thermosetting adhesive containing conductive particles such as Ag can be used. Such conductive particles are not limited to Ag powder, and appropriate metal or alloy powders such as Cu powder and A1 powder can be used. The conductive particles may be spherical or flat! /. You can use a mixed powder of spherical conductive particles and flat conductive particles!
  • thermosetting resin examples include epoxy resin and Z or phenol resin, but are not particularly limited thereto.
  • the conductive adhesive may contain a photocurable resin that is not a thermosetting resin, in which case the first conductive adhesive 7, 8 can be cured by light irradiation. Good.
  • the first conductive adhesives 7, 8 have a trapezoidal cross-sectional shape in which the upper base is smaller than the lower base. It may be a rectangle or an inverted trapezoidal shape.
  • the first conductive adhesive 7 may be first applied so as to have a larger area than after cutting. That is, regardless of the cross-sectional shape, the internal stress acting on the bonding interface can be similarly reduced by cutting along the cutting line A and reducing the bonding area with the excitation electrode 3.
  • the mother electronic component element 1A shown in FIG. 3 is obtained.
  • a cutting jig such as a cutting blade as described above.
  • the cutting may be performed so that only the unnecessary portions 7a and 8a of the first conductive adhesives 7 and 8 are cut. That is, cut the first conductive adhesive 7 and 8 so that a part of the piezoelectric plate 2 is not cut!
  • the outer end surface of the electrode 3 and the connection electrode 6 and the first conductive adhesive portion 7b Apply and paste a conductive paste to cover the side exposed in the same direction as side 2a of the Form 9.
  • the electrode 10 is formed on the other side surface 2b by applying and curing the conductive paste. The electrode 10 extends from the side surface 2b to the end surface of the connection electrode 4 and the excitation electrode 5 on the side surface 2b side and the surface exposed by cutting along the cutting line B of the first conductive adhesive portion 8b.
  • an appropriate conductive paste such as an Ag paste can be used.
  • the electrodes 9 and 10 may be formed not only by applying and curing the conductive paste but also by a thin film forming method such as vapor deposition, sputtering or plating.
  • the electronic component element 1C has a piezoelectric plate 2A obtained by the above cutting.
  • the piezoelectric plate 2A is polarized in the direction of arrow P as described above.
  • An excitation electrode 3A is formed on the upper surface of the piezoelectric plate 2A, and an excitation electrode 5A is formed on the lower surface.
  • the excitation electrodes 3A and 5A are formed by cutting the excitation electrodes 3 and 5 of the mother.
  • the excitation electrodes 3A and 5A are opposed to each other via the piezoelectric plate 2A at the longitudinal center of the piezoelectric plate 2A. Therefore, the electronic component element 1C is an energy-confined piezoelectric resonator using the thickness shear mode.
  • connection electrode 4A is formed with a gap from the excitation electrode 3A
  • a connection electrode 6A is formed with a gap from the excitation electrode 5A on the lower surface of the piezoelectric plate 2A.
  • the connection electrodes 4A and 6A are formed by cutting the connection electrodes 4 and 6 described above.
  • the first conductive adhesive portions 7bA and 8bA are respectively formed on the excitation electrode 3A and the connection electrode 4A on the surface end side of the piezoelectric plate 2A.
  • an electrode 9A is formed on one end side of the piezoelectric plate 2A, and an electrode 10A is formed on the other end side.
  • the electrodes 9A and 10A are formed by cutting the electrodes 9 and 10.
  • a substrate 12 having a plurality of electrode lands 11a and l ib on its upper surface is prepared.
  • the substrate 12 also has an insulating ceramic force such as a dielectric or alumina.
  • the electronic component element 1C is turned over and fixed on the substrate 12 via the second conductive adhesives 13 and 14. To do.
  • the insulating adhesive 16 is applied in a rectangular frame shape and the cap 17 is joined.
  • the cap 17 has an opening that opens downward, and is provided to surround the electronic component element 1C. In this manner, a cap-type electronic component in which the electronic component element 1C is sealed in the package constituted by the substrate 12 and the cap 17 can be obtained.
  • the second conductive adhesives 13 and 14 have fluidity before curing. Therefore, if the electronic component element 1C is pressed against the second conductive adhesive 13, 14 from the first conductive adhesive portion 7bA, 8bA side, an excessive amount of the second conductive adhesive 13, 14 Is pushed to the side. In other words, as shown in FIG. 8, the lower surfaces and side surfaces of the first conductive adhesive portions 7bA and 8bA are joined to the electrode lands 11a and lib via the second conductive adhesives 13 and 14. Will be. As the second conductive adhesives 13 and 14 are cured, the electronic component element 1C is joined and fixed to the electrode lands 11a and ib.
  • the first conductive adhesive portions 7bA and 8bA are cured in advance, and the internal stress is remarkably reduced by removing the unnecessary portions 7a and 8a. Since there is a two-stage curing process using the first and second conductive adhesives, the stress due to curing can be reduced. Therefore, even if the ambient temperature changes, cracks at the bonding interface between the first conductive adhesive portions 7bA and 8bA, the excitation electrode 3A, and the connection electrode 4A are unlikely to occur. Therefore, the reliability of electrical connection and the reliability of mechanical joining can be effectively increased.
  • a piezoelectric plate having a lead titanate-based ceramic force was prepared, an Ag film was formed, patterned, and then cut to obtain the mother piezoelectric plate 2 shown in FIG.
  • a piezoelectric plate 2 having a width of 3 mm, a thickness of 0.3 mm, and a length of 20 mm was prepared.
  • the first conductive adhesive 7, 8 was applied and cured on the upper surface of the piezoelectric plate 2 of the mother.
  • the first conductive adhesive 7, 8 consists of a spherical Ag powder with a particle size of 1 to 3 111 and length Glass transition with 83% by weight of Ag powder containing 20 to 80 weight ratio of flat Ag powder of 4 to 8 ⁇ m, width of 2 to 4 ⁇ m and thickness of 0.1 to 0.2 ⁇ m It was prepared by mixing 14% by weight of a mixture of epoxy resin and phenol resin having a Tg of 130 ° C and 3% by weight of an additive such as a dispersant and kneading them using a three-roll.
  • the conductive adhesive was applied by a dispense method, maintained at a temperature of 150 ° C for 0.5 hours, and cured by heating.
  • the width direction dimension of the first conductive adhesive 7 and 8 was 800 m, and the height dimension after curing was 200 m. During heating, the temperature was maintained at 200 ° C. for 60 minutes.
  • the first conductive adhesive 7, 8 is cut along the cutting lines A, B, and the first conductive adhesive 7, 8 is the remaining portion of the first conductive adhesive 7, 8.
  • the width direction dimension of the interface bonded to the electrodes of the conductive adhesive portions 7b and 8b was set to 500 m. That is, the dimension in the width direction of the piezoelectric plate 2 after cutting was set to 2.2 mm.
  • the mother piezoelectric plate 2 obtained as described above was cut at 0.5 mm intervals in the length direction to produce the electronic component element 1C shown in FIG.
  • the same conductive adhesive as described above was applied so as to have a width of 500 m and a height dimension after curing of 200 m, and was heated and cured in the same manner.
  • the mother piezoelectric plate thus obtained was cut in the same manner as in the example to obtain an electronic component element of a comparative example.
  • the electronic component elements of Examples and Comparative Examples obtained as described above were mounted on a substrate 12 having an alumina force using a second conductive adhesive.
  • the second conductive adhesive the same one as the first conductive adhesive was used.
  • the thermal shock cycle test was done about the electronic component of the Example and the comparative example. In the thermal shock cycle test, the process of maintaining electronic components at -55 ° C for 15 minutes and then maintaining at + 125 ° C for 15 minutes was defined as one cycle, and this was repeated 500 cycles.
  • a thermal shock cycle test was performed using 20 electronic parts of Examples and Comparative Examples, and the impedance was measured after the test. If the impedance is 100 ⁇ or more as a result of impedance measurement after the thermal shock cycle test, poor connection may occur at the joint with the conductive adhesive. Judged to be bad. The results are shown in Table 1 below.
  • the method of manufacturing an electronic component using a thickness-slip type piezoelectric resonator has been described.
  • the present invention relates to an electronic component using various electronic component elements other than the piezoelectric resonator. It can be applied to the manufacturing method.

Abstract

A manufacturing method of an electronic component having an electronic component element bonded and secured onto a substrate using conductive adhesive, which provides an electronic component exhibiting excellent reliability in electrical connection and mechanical bonding at the joint regardless of ambient temperature variation. In the manufacturing method of an electronic component where an electronic component element (1C) is bonded and secured onto a substrate (12) having a plurality of electrode lands (11a, 11b) using conductive adhesive, first conductive adhesive (7, 8) is applied to a region larger than the area of bonding interface at the joint of the electronic component element (1C) by the first conductive adhesive and then it is hardened. Subsequently, unnecessary part of the first conductive adhesive (7, 8) is removed and the electronic component element (1C) is bonded to the electrode lands (11a, 11b) using second conductive adhesive (14, 15).

Description

明 細 書  Specification
電子部品の製造方法  Manufacturing method of electronic parts
技術分野  Technical field
[0001] 本発明は、電子部品の製造方法に関し、より詳細には、圧電共振素子などの電子 部品素子を基板上に導電性接着剤を用いて搭載する工程を備えた電子部品の製造 方法に関する。  TECHNICAL FIELD [0001] The present invention relates to a method for manufacturing an electronic component, and more particularly relates to a method for manufacturing an electronic component including a step of mounting an electronic component element such as a piezoelectric resonant element on a substrate using a conductive adhesive. .
背景技術  Background art
[0002] 従来より、セラミックスなど力 なる電子部品素子を基板上に導電性接着剤を用い て搭載した構造を有する電子部品が広く用いられている。例えば、下記の特許文献 1には、図 9に示す電子部品が開示されている。  Conventionally, an electronic component having a structure in which a powerful electronic component element such as ceramics is mounted on a substrate using a conductive adhesive has been widely used. For example, Patent Document 1 below discloses an electronic component shown in FIG.
[0003] 図 9に示す電子部品 101では、絶縁性セラミックス力もなる絶縁性基板 102上に、 電極ランド 103, 104が形成されている。そして、電子部品素子 105が基板 102上に 導電性接着剤 106, 107を用いて接合されている。ここでは、電子部品素子 105は、 圧電セラミックス力もなる電子部品素体 105aの両主面に励振電極 105b, 105cを形 成した構造を有する。励振電極 105cが導電性接着剤 106により電極ランド 103に接 合されている。また、上面に形成された励振電極 105bは、電子部品素体 105aの端 面を経て下面に至る電極延長部 105dに連ねられている。電極延長部 105dが導電 性接着剤 107を介して電極ランド 104に接合されている。  In the electronic component 101 shown in FIG. 9, electrode lands 103 and 104 are formed on an insulating substrate 102 having an insulating ceramic force. The electronic component element 105 is bonded onto the substrate 102 using the conductive adhesives 106 and 107. Here, the electronic component element 105 has a structure in which excitation electrodes 105b and 105c are formed on both main surfaces of an electronic component element 105a that also has a piezoelectric ceramic force. The excitation electrode 105 c is bonded to the electrode land 103 by the conductive adhesive 106. The excitation electrode 105b formed on the upper surface is connected to an electrode extension portion 105d that reaches the lower surface through the end surface of the electronic component body 105a. The electrode extension 105d is joined to the electrode land 104 through the conductive adhesive 107.
[0004] 電子部品素子 105を囲繞するように、下方に開いた開口を有するキャップ 108が基 板 102に固定されている。  A cap 108 having an opening opened downward is fixed to the base plate 102 so as to surround the electronic component element 105.
特許文献 1:特開平 11― 265955号公報  Patent Document 1: Japanese Patent Laid-Open No. 11-265955
発明の開示  Disclosure of the invention
[0005] し力しながら、上記電子部品 101では、基板 102を構成している絶縁性セラミックス の熱膨張係数と、電子部品素体 105aを構成している圧電セラミックスの熱膨張係数 とが異なるため、雰囲気温度が変化すると、熱膨張係数差により電子部品素体 105a に応力が生じざるを得な力つた。そのため、上記熱膨張係数差が大きい場合には、 電子部品素体 105aに生じた熱応力により、電子部品素体 105aが破壊することもあ つた o However, in the electronic component 101, the thermal expansion coefficient of the insulating ceramic constituting the substrate 102 and the thermal expansion coefficient of the piezoelectric ceramic constituting the electronic component body 105 a are different. When the ambient temperature changed, the electronic component body 105a was forced to generate stress due to the difference in thermal expansion coefficient. For this reason, when the difference in thermal expansion coefficient is large, the electronic component body 105a may be destroyed by the thermal stress generated in the electronic component body 105a. I
[0006] 他方、図 9と異なり、電子部品素子を、片持ち方式で導電性接着剤等により基板に 接合し、支持した場合には、電子部品素子が自由に振動することができる。従って、 温度変化による熱応力に起因する周波数温度特性の変化は生じ難い。しかしながら 、電子部品素子の導電性接着剤による接合部に応力が集中するため、耐振性及び 耐衝撃性が十分でな力つた。  On the other hand, unlike FIG. 9, when the electronic component element is bonded to and supported by a conductive adhesive or the like in a cantilever manner, the electronic component element can freely vibrate. Therefore, the change of the frequency temperature characteristic due to the thermal stress due to the temperature change hardly occurs. However, since stress concentrates on the joint portion of the electronic component element using the conductive adhesive, vibration resistance and impact resistance are sufficient.
[0007] また、電子部品 101において、前述した熱膨張係数差に起因する応力を低減する には、弾力性に優れた導電性接着剤 106, 107を用いればよいと考えられる。しかし ながら、従来の導電性接着剤 106, 107による接合構造では、熱膨張係数差に起因 する応力を十分に低減することはできな力つた。そのため、導電性接着剤 106, 107 と電子部品素子 105との接合界面においてクラックが発生し、接合の信頼性が十分 でなカゝつた。また、導電性接着剤 106, 107の弾性率などの特性が周囲温度により 変化し、それによつて電子部品 105の電気的な特性が変動しがちであった。  [0007] Further, in the electronic component 101, in order to reduce the stress caused by the above-described difference in thermal expansion coefficient, it is considered that the conductive adhesives 106 and 107 having excellent elasticity may be used. However, the conventional joint structure using the conductive adhesives 106 and 107 has not been able to sufficiently reduce the stress caused by the difference in thermal expansion coefficient. For this reason, cracks occurred at the bonding interface between the conductive adhesives 106 and 107 and the electronic component element 105, and the bonding reliability was not sufficient. In addition, characteristics such as the elastic modulus of the conductive adhesives 106 and 107 changed with the ambient temperature, and the electrical characteristics of the electronic component 105 tended to fluctuate accordingly.
[0008] 本発明の目的は、上述した従来技術の欠点を解消し、基板上に導電性接着剤を 用いて電子部品素子を接合した構造を有する電子部品において、周囲の温度が変 化した場合であっても、接合の信頼性に優れ、特に導電性接着剤と電子部品素子と の接合界面におけるクラックが生じ 1 、特性のばらつきの少ない電子部品の製造方 法を提供することにある。  [0008] An object of the present invention is to solve the above-described drawbacks of the prior art, and in an electronic component having a structure in which an electronic component element is bonded on a substrate using a conductive adhesive, when the ambient temperature changes Even so, it is an object of the present invention to provide a method for manufacturing an electronic component that has excellent bonding reliability, in particular, cracks at the bonding interface between the conductive adhesive and the electronic component element, and has little variation in characteristics.
[0009] 本発明は、少なくとも一方主面に複数の電極ランドが設けられた基板上に導電性 接着剤を用いて電子部品素子を固定する電子部品の製造方法であって、前記複数 の電極ランドが一方主面に形成された基板と、電子部品素子とを用意する工程と、前 記電子部品素子の前記基板の電極ランドに接合される部分に、該電極ランドに接合 される面積よりも大きな面積となるように第 1の導電性接着剤を塗布し、硬化させるェ 程と、前記第 1の導電性接着剤が硬化した後に、該第 1の導電性接着剤が電極ラン ドに接合される面積を有するように硬化された第 1の導電性接着剤の不要部分を切 断により除去する工程と、前記第 1の導電性接着剤の不要部分を除去した後に、第 1 の導電性接着剤と前記基板の電極ランドとを第2の導電性接着剤を介して接合する 工程とを備えることを特徴とする。 [0010] 本発明に係る電子部品の製造方法のある特定の局面では、前記電子部品素子が 、対向し合う第 1,第 2の端部を有し、前記電子部品素子の前記基板に実装される面 において、第 1の端部近傍部分と、第 2の端部近傍部分において、前記電子部品素 子が前記基板の電極ランドに接合される。 [0009] The present invention is a method for manufacturing an electronic component in which an electronic component element is fixed using a conductive adhesive on a substrate on which at least one main surface is provided with a plurality of electrode lands. The step of preparing the substrate formed on one main surface and the electronic component element, and the portion of the electronic component element bonded to the electrode land of the substrate larger than the area bonded to the electrode land Applying and curing the first conductive adhesive to an area, and after the first conductive adhesive is cured, the first conductive adhesive is bonded to the electrode land. A step of removing unnecessary portions of the first conductive adhesive cured to have a certain area by cutting, and after removing unnecessary portions of the first conductive adhesive, the first conductive adhesive And the electrode land of the substrate through a second conductive adhesive And a joining step. [0010] In a specific aspect of the method for manufacturing an electronic component according to the present invention, the electronic component element has first and second end portions facing each other, and is mounted on the substrate of the electronic component element. On the surface, the electronic component element is bonded to the electrode land of the substrate in the vicinity of the first end portion and the vicinity of the second end portion.
[0011] 本発明に係る電子部品の製造方法の他の特定の局面では、前記第 1の導電性接 着剤を硬化した後に、不要部分を除去するに際し、該第 1の導電性接着剤の不要部 分と共に、切断治具により該導電性接着剤の不要部分に連なる電子部品素子の一 部をも除去される。  [0011] In another specific aspect of the method for manufacturing an electronic component according to the present invention, the first conductive adhesive is used for removing unnecessary portions after curing the first conductive adhesive. Along with the unnecessary part, a part of the electronic component element connected to the unnecessary part of the conductive adhesive is also removed by the cutting jig.
[0012] 本発明に係る電子部品の製造方法のさらに他の特定の局面では、前記電子部品 素子として、対向し合う第 1,第 2の主面と、第 1,第 2の主面を結ぶ第 1,第 2の端面と を有する電子部品本体と、前記第 1の主面に、前記基板上の複数の電極ランドに接 合される複数の電極が設けられて 、る。  [0012] In still another specific aspect of the method of manufacturing an electronic component according to the present invention, the electronic component element is connected to the first and second main surfaces facing each other and the first and second main surfaces. An electronic component main body having first and second end faces, and a plurality of electrodes to be connected to a plurality of electrode lands on the substrate are provided on the first main surface.
[0013] 本発明に係る電子部品の製造方法のさらに別の特定の局面では、前記電子部品 本体が圧電体であり、前記第 1,第 2の主面に、該圧電体を介して対向するように第 1 ,第 2の励振電極が形成されており、それによつて圧電共振子が得られる。  In still another specific aspect of the method for manufacturing an electronic component according to the present invention, the electronic component main body is a piezoelectric body, and faces the first and second main surfaces via the piezoelectric body. Thus, the first and second excitation electrodes are formed, whereby a piezoelectric resonator is obtained.
[0014] 本発明に係る電子部品の製造方法のさらに他の特定の局面では、前記基板上に 前記電子部品素子を固定した後に、該電子部品素子を覆うように前記基板にキヤッ プを固定する工程がさらに備えられる。  [0014] In still another specific aspect of the method of manufacturing an electronic component according to the present invention, after fixing the electronic component element on the substrate, a cap is fixed to the substrate so as to cover the electronic component element. A process is further provided.
[0015] 本発明に係る電子部品の製造方法では、電子部品素子の基板上の電極ランドに 接合される部分に、電極ランドに接合される面積よりも大きな面積となるように第 1の 導電性接着剤を塗布する。そして、該第 1の導電性接着剤を硬化させた後、第 1の導 電性接着剤が電極ランドに接合される上記面積を有するように、該第 1の導電性接 着剤の不要部分を切断により除去する。しかる後、第 1の導電性接着剤と基板の電 極ランドとを第 2の導電性接着剤を介して接合することにより固定する。従って、第 1 の導電性接着剤を硬化した後に、該第 1の導電性接着剤の不要部分の切断'除去 により、硬化した第 1の導電性接着剤における内部応力を十分に低くすることができ 、そして、内部応力が低減された第 1の導電性接着剤と基板の電極ランドとが、第 2 の導電性接着剤を介して接合される。 [0016] 従って、第 1の導電性接着剤及び第 2の導電性接着剤の 2段階硬化により電子部 品素子が基板の電極ランドに接合される。しかも、第 1の導電性接着剤の硬化物に おいては、上記不要部分の切断 ·除去により内部応力が低減されている。従って、導 電性接着剤による接合部分における内部応力を効果的に低減することが可能とされ ているため、導電性接着剤と電子部品素子との接合界面におけるクラックが生じ難い 。よって、周囲温度の変化に関わらず、電気的接続及び機械的接合の信頼性に優 れた電子部品を提供することが可能となる。 [0015] In the method for manufacturing an electronic component according to the present invention, the first conductive property is formed so that the area bonded to the electrode land on the substrate of the electronic component element has a larger area than the area bonded to the electrode land. Apply adhesive. Then, after the first conductive adhesive is cured, an unnecessary portion of the first conductive adhesive is formed so that the first conductive adhesive has the above-described area to be bonded to the electrode land. Is removed by cutting. Thereafter, the first conductive adhesive and the electrode land of the substrate are fixed by joining via the second conductive adhesive. Therefore, after the first conductive adhesive is cured, the internal stress in the cured first conductive adhesive can be sufficiently reduced by cutting and removing unnecessary portions of the first conductive adhesive. Then, the first conductive adhesive with reduced internal stress and the electrode land of the substrate are joined via the second conductive adhesive. Accordingly, the electronic component element is bonded to the electrode land of the substrate by two-stage curing of the first conductive adhesive and the second conductive adhesive. Moreover, in the cured product of the first conductive adhesive, the internal stress is reduced by cutting and removing the unnecessary portion. Therefore, since it is possible to effectively reduce the internal stress at the joint portion due to the conductive adhesive, cracks are hardly generated at the joint interface between the conductive adhesive and the electronic component element. Therefore, it is possible to provide an electronic component excellent in the reliability of electrical connection and mechanical joining regardless of changes in ambient temperature.
[0017] 電子部品素子が対向し合う第 1,第 2の端部を有し、電子部品素子の基板に実装さ れる面において、第 1の端部近傍部分と、第 2の端部近傍部分において電子部品素 子が基板上の電極ランドに接合される場合には、本発明に従って、両端近傍で支持 された電子部品であって、しかも導電性接着剤による電気的接続及び機械的接合の 信頼性に優れた電子部品を提供することができる。  [0017] The electronic component element has first and second end portions facing each other, and the first component portion vicinity portion and the second end portion vicinity portion on the surface of the electronic component element mounted on the substrate. In the case where the electronic component element is bonded to the electrode land on the substrate in accordance with the present invention, the electronic component is supported in the vicinity of both ends, and is reliable in electrical connection and mechanical bonding with a conductive adhesive. An electronic component having excellent properties can be provided.
[0018] 第 1の導電性接着剤を硬化した後に、不要部分を除去するに際し、該第 1の導電 性接着剤の不要部分とともに、切断治具により導電性接着剤の不要部分に連なる電 子部品素子の一部をも除去する場合には、切断治具により一方向に切断するだけで 、導電性接着剤の不要部分を容易に除去することができる。  [0018] When the unnecessary portion is removed after the first conductive adhesive is cured, an electron connected to the unnecessary portion of the conductive adhesive together with the unnecessary portion of the first conductive adhesive by a cutting jig When part of the component element is also removed, the unnecessary part of the conductive adhesive can be easily removed simply by cutting in one direction with a cutting jig.
[0019] 電子部品素子として、対向し合う第 1,第 2の主面と、第 1,第 2の主面を結ぶ第 1, 第 2の端面とを有する電子部品本体と、第 1の主面に、基板上の複数の電極ランドに 接合される複数の電極が設けられている場合には、本発明に従って、第 1の主面側 力 基板上に面実装され得る電子部品素子を備えた電子部品を提供することができ る。  [0019] As an electronic component element, an electronic component main body having first and second main surfaces facing each other and first and second end surfaces connecting the first and second main surfaces, and a first main In the case where a plurality of electrodes bonded to a plurality of electrode lands on the substrate are provided on the surface, according to the present invention, the first main surface side force electronic component element that can be surface mounted on the substrate is provided. Electronic parts can be provided.
[0020] 電子部品本体が圧電体であり、第 1,第 2の主面に、該圧電体を介して対向するよう に第 1,第 2の励振電極が形成されている場合には、本発明に従って基板上に圧電 共振子が搭載された、電気的接続及び機械的接合の信頼性に優れた電子部品を提 供することができる。  [0020] When the electronic component main body is a piezoelectric body and the first and second excitation electrodes are formed on the first and second main surfaces so as to face each other with the piezoelectric body interposed therebetween, According to the present invention, an electronic component having a piezoelectric resonator mounted on a substrate and excellent in electrical connection and mechanical bonding reliability can be provided.
[0021] 基板上に電子部品素子を接合した後に、該電子部品素子を覆うように基板にキヤッ プを固定する工程をさらに備える場合には、本発明に従って、基板とキャップにより 電子部品素子が内部に封止された電子部品を提供することができる。 図面の簡単な説明 [0021] When the electronic component element is further bonded to the substrate after the electronic component element is bonded to the substrate, the electronic component element is internally formed by the substrate and the cap according to the present invention. It is possible to provide an electronic component sealed in the container. Brief Description of Drawings
[0022] [図 1]図 1 (a)及び (b)は、本発明の一実施形態に係る電子部品の製造方法におい て、第 1の導電性接着剤を硬化させた後に不要部分を切断除去する工程を説明する ための横断面図及び平面図である。  [0022] [FIG. 1] FIGS. 1 (a) and 1 (b) show a method of manufacturing an electronic component according to an embodiment of the present invention, wherein unnecessary portions are cut after the first conductive adhesive is cured. It is the cross-sectional view and top view for demonstrating the process to remove.
[図 2]図 2は第 1の実施形態で用意されるマザ一の圧電板を示す斜視図である。  FIG. 2 is a perspective view showing a mother piezoelectric plate prepared in the first embodiment.
[図 3]図 3は第 1の絶縁性接着剤を硬化した後不要部分を切断除去した後のマザ一 の圧電板を説明するための横断面図である。  [FIG. 3] FIG. 3 is a cross-sectional view for explaining the mother piezoelectric plate after curing and removing unnecessary portions after curing the first insulating adhesive.
[図 4]図 4は切断除去に続いて導電ペーストを塗布し、硬化させて電極を形成した状 態を示すマザ一の圧電板の横断面図である。  [FIG. 4] FIG. 4 is a cross-sectional view of a mother piezoelectric plate showing a state where an electrode is formed by applying and curing a conductive paste following cutting and removal.
[図 5]図 5はマザ一の圧電板を切断し、個々の電子部品素子を得る工程を説明する ための斜視図である。  FIG. 5 is a perspective view for explaining a process of cutting individual piezoelectric plates to obtain individual electronic component elements.
[図 6]図 6は第 1の実施形態で得られた圧電共振子としての電子部品素子を示す斜 視図である。  FIG. 6 is a perspective view showing an electronic component element as a piezoelectric resonator obtained in the first embodiment.
[図 7]図 7は第 1の実施形態の電子部品素子を基板上に搭載する工程を説明するた めの分解斜視図である。  FIG. 7 is an exploded perspective view for explaining a process of mounting the electronic component element of the first embodiment on a substrate.
[図 8]図 8は第 1の実施形態において電子部品素子を基板上に第 2の導電性接着剤 を用いて固定した構造を示す正面断面図である。  FIG. 8 is a front sectional view showing a structure in which an electronic component element is fixed on a substrate using a second conductive adhesive in the first embodiment.
[図 9]図 9は従来の電子部品の一例を示す正面断面図である。  FIG. 9 is a front sectional view showing an example of a conventional electronic component.
符号の説明  Explanation of symbols
[0023] 1…マザ一の電子部品素子 [0023] 1 ... Mother's best electronic component element
1C…電子部品素子  1C ... Electronic component element
2…圧電板  2 ... Piezoelectric plate
2a, 2b…側面  2a, 2b… side
2Α· ··圧電板  2Α ··· Piezoelectric plate
3, 5…励振電極  3, 5… Excitation electrode
3A, 5A…励振電極  3A, 5A ... Excitation electrode
4, 6· ··接続電極  4, 6 ... Connecting electrode
4A, 6Α· ··接続電極 7, 8…第 1の導電性接着剤 4A, 6Α ··· Connecting electrode 7, 8… First conductive adhesive
7bA, 8bA…第 1の導電性接着剤部分  7bA, 8bA ... 1st conductive adhesive part
9A, 10A…電極  9A, 10A ... electrode
11a, l ib…電極ランド  11a, l ib… Electrode land
12…基板  12 ... Board
13, 14· · ·第 2の導電性接着剤  13, 14 ··· Second conductive adhesive
16…絶縁性接着剤 16… Insulating adhesive
7…キャップ  7… Cap
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
[0024] 以下、図面を参照しつつ本発明の具体的な実施形態を説明することにより、本発明 を明らかにする。 Hereinafter, the present invention will be clarified by describing specific embodiments of the present invention with reference to the drawings.
[0025] 本実施形態では、まず、図 2に示すマザ一の電子部品素子 1を用意する。マザ一の 電子部品素子 1は、矩形板状のマザ一の圧電板 2を有する。マザ一の圧電板 2は、 矢印 Pで示す方向に分極処理された圧電セラミックスにより構成されて!ヽる。このよう な圧電セラミックスとしては、例えばチタン酸鉛系セラミックスを挙げることができる。も つとも、他の圧電セラミックスが用いられてもよぐあるいは水晶などの圧電単結晶が 用いられてもよい。  In the present embodiment, first, a mother electronic component element 1 shown in FIG. 2 is prepared. The mother electronic component element 1 includes a rectangular plate-like mother piezoelectric plate 2. The mother piezoelectric plate 2 is made of piezoelectric ceramics polarized in the direction indicated by the arrow P! Examples of such piezoelectric ceramics include lead titanate ceramics. At the same time, other piezoelectric ceramics may be used, or a piezoelectric single crystal such as quartz may be used.
[0026] マザ一の圧電板 2の上面には、第 1のマザ一の励振電極 3が形成されている。励振 電極 3は、圧電板 2の上面において、一方の側面 2a側力も他方の側面 2b側に向か つて延ばされている。そして、励振電極 3は、ギャップを隔てて、接続電極 4と対向さ れている。接続電極 4は、圧電板 2の上面において、上面と側面 2bとのなす端縁から 側面 2a側に向力つて延ばされて 、る。  A first mother excitation electrode 3 is formed on the upper surface of the mother piezoelectric plate 2. In the upper surface of the piezoelectric plate 2, the excitation electrode 3 has one side surface 2 a side force extended toward the other side surface 2 b side. The excitation electrode 3 is opposed to the connection electrode 4 with a gap. The connection electrode 4 is extended on the upper surface of the piezoelectric plate 2 from the edge formed by the upper surface and the side surface 2b toward the side surface 2a.
[0027] 他方、圧電板 2の下面にぉ 、ては、第 2の励振電極 5が形成されて 、る。第 2の励 振電極 5は、側面 2bと下面とのなす端縁から側面 2a側に向力つて延ばされている。 第 2のマザ一の励振電極 5は、第 1のマザ一の励振電極 3と圧電板 2の側面 2a, 2bを 結ぶ幅方向中央にぉ 、て圧電板 2を介して対向されている。圧電板 2の下面におい ては、第 2の励振電極 5とギャップを隔てて接続電極 6が形成されている。接続電極 6 は、側面 2aと下面とのなす端縁から側面 2b側に向力つて延ばされている。 [0028] 上記励振電極 3, 5及び接続電極 4, 6は、 Agもしくは Ag合金のような導電性材料 により形成され得る。導電性材料は Agまたは Ag合金に限られず、 Cuや A1などの他 の金属もしくは合金であってもよ 、。 On the other hand, the second excitation electrode 5 is formed on the lower surface of the piezoelectric plate 2. The second excitation electrode 5 is extended from the edge formed by the side surface 2b and the lower surface toward the side surface 2a. The excitation electrode 5 of the second mother is opposed to the center of the width direction connecting the excitation electrode 3 of the first mother and the side surfaces 2a and 2b of the piezoelectric plate 2 with the piezoelectric plate 2 therebetween. A connection electrode 6 is formed on the lower surface of the piezoelectric plate 2 with a gap from the second excitation electrode 5. The connection electrode 6 is extended from the edge formed by the side surface 2a and the lower surface toward the side surface 2b. [0028] The excitation electrodes 3 and 5 and the connection electrodes 4 and 6 can be formed of a conductive material such as Ag or an Ag alloy. The conductive material is not limited to Ag or Ag alloy, but may be other metals or alloys such as Cu or A1.
[0029] また、上記電極形成方法は特に限定されず、蒸着、スパッタリングもしくはメツキなど の薄膜形成法、あるいは導電ペーストの塗布'硬化等の適宜の方法を用いることがで きる。 [0029] The electrode forming method is not particularly limited, and a suitable method such as thin film forming method such as vapor deposition, sputtering or plating, or applying and curing of conductive paste can be used.
[0030] 次に、上記マザ一の圧電板 2の上面に、図 1 (a)及び (b)に横断面図及び平面図で 示すように、第 1の導電性接着剤 7, 8を塗布し、硬化させる。図 1 (a) , (b)から明らか なように、第 1の導電性接着剤 7, 8は、マザ一の圧電板 2の上面において、それぞれ 、側面 2aと上面とのなす端縁及び側面 2bと上面とのなす端縁に沿うように延ばされ ている。そして、第 1の導電性接着剤 7, 8は、横断面が台形の形状を有する。また、 他方の第 1の導電性接着剤 8の横断面の台形の下底の長さは、接続電極 4の幅方向 寸法と等しくされている。なお、幅方向寸法とは、前述したマザ一の圧電板 2の幅方 向、すなわち側面 2a, 2bを結ぶ方向に沿う寸法をいうものとする。  Next, the first conductive adhesives 7 and 8 are applied to the upper surface of the above-mentioned piezoelectric plate 2 of the mother as shown in the cross-sectional view and the plan view in FIGS. 1 (a) and 1 (b). And cure. As apparent from FIGS. 1 (a) and 1 (b), the first conductive adhesives 7 and 8 are formed on the upper surface of the mother piezoelectric plate 2, respectively, on the edge and side surfaces formed by the side surface 2a and the upper surface. It extends along the edge formed by 2b and the upper surface. The first conductive adhesives 7 and 8 have a trapezoidal cross section. The length of the bottom base of the trapezoid in the cross section of the other first conductive adhesive 8 is made equal to the dimension in the width direction of the connection electrode 4. The dimension in the width direction refers to the dimension along the width direction of the above-described mother piezoelectric plate 2, that is, the direction connecting the side surfaces 2a and 2b.
[0031] 第 1の導電性接着剤 7の横断面の形状も、他方の第 1の導電性接着剤 8の横断面 の形状と同一とされている。  The shape of the cross section of the first conductive adhesive 7 is also the same as the shape of the cross section of the other first conductive adhesive 8.
[0032] そして、この第 1の導電性接着剤 7, 8の塗布面積は、最終的に本実施形態により 得られる圧電共振子と導電性接着剤との接合部分の面積よりも大きくされている。  [0032] The application area of the first conductive adhesives 7, 8 is made larger than the area of the joint portion between the piezoelectric resonator and the conductive adhesive finally obtained by the present embodiment. .
[0033] なお、図 1 (a)の一点鎖線 A, Bは、切断線を示し、後工程において切断線 A, Bに 沿って切断が行われる。そして、第 1の導電性接着剤 7, 8が切断線 A, Bに切断され ることにより、切断線 A, Bの外側の不要部分 7a, 8aが除去される。不要部分 7a, 8a が除去された残りの硬化部分 7b, 8bと、最終的に得られる圧電共振子との接合部分 の面積は、上記不要部分 7a, 8aを除去する前の接合界面よりも当然のことながら小 さくなる。  [0033] It should be noted that alternate long and short dash lines A and B in FIG. 1 (a) indicate cutting lines, and cutting is performed along cutting lines A and B in a later step. Then, by cutting the first conductive adhesives 7 and 8 along the cutting lines A and B, the unnecessary portions 7a and 8a outside the cutting lines A and B are removed. The area of the bonded portion between the remaining cured portions 7b and 8b from which the unnecessary portions 7a and 8a are removed and the finally obtained piezoelectric resonator is naturally larger than the bonding interface before the unnecessary portions 7a and 8a are removed. It will be smaller.
[0034] そして、上記第 1の導電性接着剤 7, 8は硬化の際に、応力を生じ、硬化物は大きな 内部応力を有する。し力しながら、上記切断線 A, Bに沿って切断し、不要部分 7a, 8 aを除去することにより、残りの部分である第 1の導電性接着剤部分 7b, 8bでは、内 部応力が低減されることになる。 [0035] 上記第 1の導電性接着剤 7, 8としては、 Agなどの導電性粒子を含む熱硬化性接 着剤を用いることができる。このような導電性粒子としては、 Ag粉末に限らず、 Cu粉 末や A1粉末などの適宜の金属もしくは合金の粉末を用いることができる。また、導電 性粒子は球状であっても偏平状であってもよ!/、。ある!/、は球状の導電性粒子と偏平 状の導電性粒子の混合粉末を用いてもよ!、。 [0034] The first conductive adhesives 7, 8 generate stress during curing, and the cured product has a large internal stress. While cutting along the cutting lines A and B, the unnecessary portions 7a and 8a are removed, so that the remaining portions of the first conductive adhesive portions 7b and 8b have an internal stress. Will be reduced. [0035] As the first conductive adhesives 7, 8, a thermosetting adhesive containing conductive particles such as Ag can be used. Such conductive particles are not limited to Ag powder, and appropriate metal or alloy powders such as Cu powder and A1 powder can be used. The conductive particles may be spherical or flat! /. You can use a mixed powder of spherical conductive particles and flat conductive particles!
[0036] さらに、上記熱硬化性榭脂としては、エポキシ榭脂及び Zまたはフエノール榭脂な どを挙げることができるが、特にこれに限定されるものではない。さらに、上記導電性 接着剤は、熱硬化性榭脂ではなぐ光硬化性榭脂を含んでいてもよぐその場合に は光の照射によって第 1の導電性接着剤 7, 8を硬化すればよい。  [0036] Further, examples of the thermosetting resin include epoxy resin and Z or phenol resin, but are not particularly limited thereto. Furthermore, the conductive adhesive may contain a photocurable resin that is not a thermosetting resin, in which case the first conductive adhesive 7, 8 can be cured by light irradiation. Good.
[0037] なお、本実施形態では、第 1の導電性接着剤 7, 8は、上底が下底よりも小さい、台 形となる横断面形状を有していたが、台形に限らず、矩形であってもよぐさらに逆台 形の形状であってもよい。例えば第 1の導電性接着剤 7を例にとると、電子部品素子 である圧電板 2に設けられた励振電極 3と導電性接着剤 7とが接合している部分の面 積が、切断除去前に、切断後よりも大きな面積となるように第 1の導電性接着剤 7がま ず塗布されればよい。すなわち、横断面形状の如何に関わらず、切断線 Aに沿って 切断し、励振電極 3との接合面積を少なくすれば、同様に、接合界面に働く内部応 力を低減することができる。  [0037] In the present embodiment, the first conductive adhesives 7, 8 have a trapezoidal cross-sectional shape in which the upper base is smaller than the lower base. It may be a rectangle or an inverted trapezoidal shape. For example, taking the first conductive adhesive 7 as an example, the area of the portion where the excitation electrode 3 provided on the piezoelectric plate 2 which is an electronic component element and the conductive adhesive 7 are joined is cut and removed. First, the first conductive adhesive 7 may be first applied so as to have a larger area than after cutting. That is, regardless of the cross-sectional shape, the internal stress acting on the bonding interface can be similarly reduced by cutting along the cutting line A and reducing the bonding area with the excitation electrode 3.
[0038] 上記のようにして、切断線 A, Bに沿って、例えば切断刃などの切断治具を用いて 切断することにより、図 3に示すマザ一の電子部品素子 1Aが得られる。なお、切断に 際しては、切断線 A, Bに沿って、第 1の導電性接着剤 7, 8の硬化物だけでなぐそ れに連なる圧電板 2の一部も切断除去されていた。従って、切断線 A, Bに沿って、 切断刃により一方向に切断するだけで、容易に不要部分 7a, 8aを除去することがで きる。もっとも、切断治具を用いた切断に際しては、第 1の導電性接着剤 7, 8の不要 部分 7a, 8aのみを切断するように切断を行ってもよい。すなわち、圧電板 2の一部を 切断しな!、ように第 1の導電性接着剤 7, 8の切断を行ってもょ 、。  [0038] By cutting along the cutting lines A and B using a cutting jig such as a cutting blade as described above, the mother electronic component element 1A shown in FIG. 3 is obtained. At the time of cutting, along the cutting lines A and B, only a part of the piezoelectric plate 2 connected to the first conductive adhesive 7 and 8 was cut and removed. . Therefore, the unnecessary portions 7a and 8a can be easily removed simply by cutting in one direction along the cutting lines A and B with the cutting blade. However, when cutting using the cutting jig, the cutting may be performed so that only the unnecessary portions 7a and 8a of the first conductive adhesives 7 and 8 are cut. That is, cut the first conductive adhesive 7 and 8 so that a part of the piezoelectric plate 2 is not cut!
[0039] 次に、図 4に示すように、マザ一の圧電板 2の一方の側面 2aを覆うように、さらに電 極 3,接続電極 6の外側端面及び第 1の導電性接着剤部分 7bの側面 2aと同じ方向 に露出している側面を覆うように、導電ペーストを塗布し、硬化させることにより、電極 9を形成する。同様に、他方の側面 2b側においても、導電ペーストの塗布'硬化によ り電極 10を形成する。電極 10は、側面 2bから、接続電極 4及び励振電極 5の側面 2 b側の端面と、第 1の導電性接着剤部分 8bの切断線 Bで切断されて露出した面に至 つている。 Next, as shown in FIG. 4, so as to cover one side surface 2a of the piezoelectric plate 2 of the mother, the outer end surface of the electrode 3 and the connection electrode 6 and the first conductive adhesive portion 7b Apply and paste a conductive paste to cover the side exposed in the same direction as side 2a of the Form 9. Similarly, the electrode 10 is formed on the other side surface 2b by applying and curing the conductive paste. The electrode 10 extends from the side surface 2b to the end surface of the connection electrode 4 and the excitation electrode 5 on the side surface 2b side and the surface exposed by cutting along the cutting line B of the first conductive adhesive portion 8b.
[0040] 上記導電ペーストとしては、 Agペーストなどの適宜の導電ペーストを用いることがで きる。  [0040] As the conductive paste, an appropriate conductive paste such as an Ag paste can be used.
[0041] なお、導電ペーストの塗布'硬化に限らず、蒸着、スパッタリングもしくはメツキなどの 薄膜形成方法により電極 9, 10を形成してもよい。  [0041] It should be noted that the electrodes 9 and 10 may be formed not only by applying and curing the conductive paste but also by a thin film forming method such as vapor deposition, sputtering or plating.
[0042] 次に、図 5に示す一点鎖線 Cに沿って、マザ一の電子部品素子 1Aを切断する。こ のようにして、図 6に示す電子部品素子 1Cが得られる。電子部品素子 1Cは、上記切 断により得られた圧電板 2Aを有する。圧電板 2Aは、上記のように、矢印 P方向に分 極処理されている。 Next, along the one-dot chain line C shown in FIG. 5, the mother electronic component element 1 A is cut. In this way, the electronic component element 1C shown in FIG. 6 is obtained. The electronic component element 1C has a piezoelectric plate 2A obtained by the above cutting. The piezoelectric plate 2A is polarized in the direction of arrow P as described above.
[0043] 圧電板 2Aの上面には、励振電極 3Aが、下面には励振電極 5Aが形成されている 。励振電極 3A, 5Aは、それぞれ、マザ一の励振電極 3, 5の切断により形成されて いる。励振電極 3A, 5Aは、圧電板 2Aの長さ方向中央において圧電板 2Aを介して 対向されている。従って、電子部品素子 1Cは、厚み滑りモードを利用したエネルギ 一閉じ込め型の圧電共振子である。  An excitation electrode 3A is formed on the upper surface of the piezoelectric plate 2A, and an excitation electrode 5A is formed on the lower surface. The excitation electrodes 3A and 5A are formed by cutting the excitation electrodes 3 and 5 of the mother. The excitation electrodes 3A and 5A are opposed to each other via the piezoelectric plate 2A at the longitudinal center of the piezoelectric plate 2A. Therefore, the electronic component element 1C is an energy-confined piezoelectric resonator using the thickness shear mode.
[0044] 励振電極 3Aとギャップを隔てて、接続電極 4Aが形成されており、圧電板 2Aの下 面においては、励振電極 5Aとギャップを隔てて接続電極 6Aが形成されている。接 続電極 4A, 6Aは、前述した接続電極 4, 6が切断されることにより形成されている。 第 1の導電性接着剤部分 7bA, 8bAは、それぞれ、圧電板 2Aの面端部側の励振電 極 3A,接続電極 4A上に形成されている。  A connection electrode 4A is formed with a gap from the excitation electrode 3A, and a connection electrode 6A is formed with a gap from the excitation electrode 5A on the lower surface of the piezoelectric plate 2A. The connection electrodes 4A and 6A are formed by cutting the connection electrodes 4 and 6 described above. The first conductive adhesive portions 7bA and 8bA are respectively formed on the excitation electrode 3A and the connection electrode 4A on the surface end side of the piezoelectric plate 2A.
[0045] また、圧電板 2Aの一方端部側にぉ ヽては、電極 9Aが、他方端部側では電極 10A が形成されている。電極 9A, 10Aは、上記電極 9, 10が切断することにより形成され ている。  In addition, an electrode 9A is formed on one end side of the piezoelectric plate 2A, and an electrode 10A is formed on the other end side. The electrodes 9A and 10A are formed by cutting the electrodes 9 and 10.
[0046] 次に、図 7に示すように、上面に複数の電極ランド 11a, l ibを有する基板 12を用 意する。基板 12は誘電体やアルミナなどの絶縁性セラミックス力もなる。この基板 12 上に、第 2の導電性接着剤 13, 14を介して、上記電子部品素子 1Cを裏返して固定 する。しカゝる後、絶縁性接着剤 16を矩形枠状に塗布し、キャップ 17を接合する。キヤ ップ 17は、下方に開いた開口を有し、電子部品素子 1Cを囲繞するために設けられ ている。このようにして、基板 12とキャップ 17とで構成されるパッケージ内に、電子部 品素子 1Cが封止された、キャップ型の電子部品を得ることができる。 Next, as shown in FIG. 7, a substrate 12 having a plurality of electrode lands 11a and l ib on its upper surface is prepared. The substrate 12 also has an insulating ceramic force such as a dielectric or alumina. The electronic component element 1C is turned over and fixed on the substrate 12 via the second conductive adhesives 13 and 14. To do. Then, the insulating adhesive 16 is applied in a rectangular frame shape and the cap 17 is joined. The cap 17 has an opening that opens downward, and is provided to surround the electronic component element 1C. In this manner, a cap-type electronic component in which the electronic component element 1C is sealed in the package constituted by the substrate 12 and the cap 17 can be obtained.
[0047] ところで、図 8に示すように、第 2の導電性接着剤 13, 14を用いて、電子部品素子 1 Cを基板 12上に固定した構造では、基板 12と圧電板 2Aの熱膨張係数差が大きぐ カゝっ周囲の温度が変化したとしても、電気的接続及び機械的接合の信頼性が効果 的に高められる。これを図 8を参照して説明する。  By the way, as shown in FIG. 8, in the structure in which the electronic component element 1 C is fixed on the substrate 12 using the second conductive adhesives 13 and 14, the thermal expansion of the substrate 12 and the piezoelectric plate 2A is performed. Large coefficient difference Even if the ambient temperature changes, the reliability of electrical connection and mechanical connection can be effectively improved. This will be described with reference to FIG.
[0048] 第 2の導電性接着剤 13, 14は、硬化前には流動性を有している。従って、電子部 品素子 1Cを、第 1の導電性接着剤部分 7bA, 8bA側から第 2の導電性接着剤 13, 1 4に押し付けると、余分量の第 2の導電性接着剤 13, 14は側方に押し退けられる。す なわち、図 8に示すように、第 1の導電性接着剤部分 7bA, 8bAの下面と側面とが、 第 2の導電性接着剤 13, 14を介して電極ランド 11a, l ibに接合されることになる。 そして、第 2の導電性接着剤 13, 14が硬化することにより、電子部品素子 1Cは、電 極ランド 11a, l ibに接合'固定されることになる。  [0048] The second conductive adhesives 13 and 14 have fluidity before curing. Therefore, if the electronic component element 1C is pressed against the second conductive adhesive 13, 14 from the first conductive adhesive portion 7bA, 8bA side, an excessive amount of the second conductive adhesive 13, 14 Is pushed to the side. In other words, as shown in FIG. 8, the lower surfaces and side surfaces of the first conductive adhesive portions 7bA and 8bA are joined to the electrode lands 11a and lib via the second conductive adhesives 13 and 14. Will be. As the second conductive adhesives 13 and 14 are cured, the electronic component element 1C is joined and fixed to the electrode lands 11a and ib.
[0049] ところが、第 1の導電性接着剤部分 7bA, 8bAは、予め硬化されており、しかも上記 不要部分 7a, 8aの除去により、内部応力は著しく少なくされている。カロえて、第 1,第 2の導電性接着剤を用いて 2段階に渡る硬化工程を有するので、それによつても、硬 化による応力を低めることができる。従って、周囲の温度変化が生じたとしても、第 1 の導電性接着剤部分 7bA, 8bAと励振電極 3A及び接続電極 4Aの接合界面にお けるクラックが生じ難い。よって、電気的接続の信頼性及び機械的接合の信頼性を 効果的に高めることができる。  [0049] However, the first conductive adhesive portions 7bA and 8bA are cured in advance, and the internal stress is remarkably reduced by removing the unnecessary portions 7a and 8a. Since there is a two-stage curing process using the first and second conductive adhesives, the stress due to curing can be reduced. Therefore, even if the ambient temperature changes, cracks at the bonding interface between the first conductive adhesive portions 7bA and 8bA, the excitation electrode 3A, and the connection electrode 4A are unlikely to occur. Therefore, the reliability of electrical connection and the reliability of mechanical joining can be effectively increased.
[0050] 次に、上記実施形態の具体的な実験例につき説明する。  Next, specific experimental examples of the above embodiment will be described.
[0051] チタン酸鉛系セラミックス力もなる圧電板を用意し、 Ag膜を成膜し、パター-ングし た後、切断し、図 2に示したマザ一の圧電板 2を得た。このようにして、幅 3mm、厚み 0. 3mm及び長さ 20mmの圧電板 2を用意した。  [0051] A piezoelectric plate having a lead titanate-based ceramic force was prepared, an Ag film was formed, patterned, and then cut to obtain the mother piezoelectric plate 2 shown in FIG. Thus, a piezoelectric plate 2 having a width of 3 mm, a thickness of 0.3 mm, and a length of 20 mm was prepared.
[0052] 次に、上記マザ一の圧電板 2の上面において、第 1の導電性接着剤 7, 8を塗布し、 硬化させた。第 1の導電性接着剤 7, 8は、 1〜3 111の粒径の球状の Ag粉末と、長さ 4〜8 μ m及び幅 2〜4 μ m及び厚み 0. 1〜0. 2 μ mの偏平状の Ag粉末とを重量比 で 20 : 80の割合で含む Ag粉末 83重量%と、ガラス転移点 Tgが 130°Cのエポキシ 榭脂及びフエノール榭脂の混合物 14重量%と、分散剤などの添加剤を 3重量%とを 混合し、 3本ロールを用いて混練することにより作製した。 [0052] Next, the first conductive adhesive 7, 8 was applied and cured on the upper surface of the piezoelectric plate 2 of the mother. The first conductive adhesive 7, 8 consists of a spherical Ag powder with a particle size of 1 to 3 111 and length Glass transition with 83% by weight of Ag powder containing 20 to 80 weight ratio of flat Ag powder of 4 to 8 μm, width of 2 to 4 μm and thickness of 0.1 to 0.2 μm It was prepared by mixing 14% by weight of a mixture of epoxy resin and phenol resin having a Tg of 130 ° C and 3% by weight of an additive such as a dispersant and kneading them using a three-roll.
[0053] 上記導電性接着剤の塗布はデイスペンス法により行い、 150°Cの温度で 0. 5時間 維持し、加熱により硬化させた。この第 1の導電性接着剤 7, 8の塗布部分の幅方向 寸法は 800 mとし、硬化後の高さ方向寸法を 200 mとした。加熱に際しては、 20 0°Cの温度に 60分間維持した。  [0053] The conductive adhesive was applied by a dispense method, maintained at a temperature of 150 ° C for 0.5 hours, and cured by heating. The width direction dimension of the first conductive adhesive 7 and 8 was 800 m, and the height dimension after curing was 200 m. During heating, the temperature was maintained at 200 ° C. for 60 minutes.
[0054] しカゝる後、切断線 A, Bに沿って第 1の導電性接着剤 7, 8を切断し、第 1の導電性 接着剤 7, 8の残りの部分である第 1の導電性接着剤部分 7b, 8bの電極と接合して いる界面の幅方向寸法を 500 mとした。すなわち、切断後の圧電板 2の幅方向寸 法は 2. 2mmとした。  [0054] After that, the first conductive adhesive 7, 8 is cut along the cutting lines A, B, and the first conductive adhesive 7, 8 is the remaining portion of the first conductive adhesive 7, 8. The width direction dimension of the interface bonded to the electrodes of the conductive adhesive portions 7b and 8b was set to 500 m. That is, the dimension in the width direction of the piezoelectric plate 2 after cutting was set to 2.2 mm.
[0055] しかる後、上記のようにして得られたマザ一の圧電板 2を長さ方向において 0. 5m m間隔で切断し、図 6に示した電子部品素子 1Cを作製した。  Thereafter, the mother piezoelectric plate 2 obtained as described above was cut at 0.5 mm intervals in the length direction to produce the electronic component element 1C shown in FIG.
[0056] 比較のために、幅 2. 2mm、長さ 20mm及び厚み 0. 3mmの寸法の圧電板を用意 したことを除 ヽては上記と同様の電極が形成されたマザ一の圧電板を作製し、上記と 同じ導電性接着剤を幅 500 m及び硬化後の高さ方向寸法が 200 mとなるように 塗布し、同様にして加熱 '硬化させた。そして、このようにして得られたマザ一の圧電 板を実施例と同様にして切断し、比較例の電子部品素子を得た。  [0056] For comparison, a mother piezoelectric plate on which electrodes similar to those described above were formed, except that a piezoelectric plate having dimensions of 2.2 mm in width, 20 mm in length, and 0.3 mm in thickness was prepared. The same conductive adhesive as described above was applied so as to have a width of 500 m and a height dimension after curing of 200 m, and was heated and cured in the same manner. The mother piezoelectric plate thus obtained was cut in the same manner as in the example to obtain an electronic component element of a comparative example.
[0057] 上記のようにして得た実施例及び比較例の電子部品素子を、図 8に示したように、 アルミナ力もなる基板 12上に第 2の導電性接着剤を用いて実装した。第 2の導電性 接着剤としては、上記第 1の導電性接着剤と同じものを用いた。そして、加熱により硬 化させた後、実施例及び比較例の電子部品について、耐熱衝撃サイクル試験を行つ た。耐熱衝撃サイクル試験では、電子部品を— 55°Cに 15分間維持した後、 + 125 °Cに 15分間維持する工程を 1サイクルとし、これを 500サイクル繰り返した。実施例及 び比較例の電子部品を各 20個用い、耐熱衝撃サイクル試験を行い、試験後にイン ピーダンスを測定した。耐熱衝撃サイクル試験後のインピーダンス測定により、インピ 一ダンスが 100 Ω以上となった場合、導電性接着剤による接合部分に接続不良が生 じ、不良と判断した。結果を下記の表 1に示す。 As shown in FIG. 8, the electronic component elements of Examples and Comparative Examples obtained as described above were mounted on a substrate 12 having an alumina force using a second conductive adhesive. As the second conductive adhesive, the same one as the first conductive adhesive was used. And after hardening by heating, the thermal shock cycle test was done about the electronic component of the Example and the comparative example. In the thermal shock cycle test, the process of maintaining electronic components at -55 ° C for 15 minutes and then maintaining at + 125 ° C for 15 minutes was defined as one cycle, and this was repeated 500 cycles. A thermal shock cycle test was performed using 20 electronic parts of Examples and Comparative Examples, and the impedance was measured after the test. If the impedance is 100 Ω or more as a result of impedance measurement after the thermal shock cycle test, poor connection may occur at the joint with the conductive adhesive. Judged to be bad. The results are shown in Table 1 below.
[0058] [表 1] [0058] [Table 1]
Figure imgf000014_0001
表 1から明らかなように、実施例では、 20個中不良個数は 0であったのに対し、比較 例では、 20個中 5個の不良が見られた。従って、実施例のように、第 1の導電性接着 剤 7, 8を硬化した後、不要部分を除去することにより、第 1の導電性接着剤と電極と の接合部分の接続の信頼性を効果的に高め得ることがわかる。
Figure imgf000014_0001
As is clear from Table 1, in the example, the number of defects out of 20 was 0, while in the comparative example, 5 out of 20 defects were found. Therefore, as in the embodiment, after the first conductive adhesives 7 and 8 are cured, unnecessary portions are removed, thereby improving the connection reliability of the joint portion between the first conductive adhesive and the electrode. It turns out that it can raise effectively.
[0059] なお、上記実施形態では、厚み滑り型の圧電共振子を用いた電子部品の製造方 法につき説明したが、本発明は、圧電共振子以外の様々な電子部品素子を用いた 電子部品の製造方法に適用することができる。 In the above embodiment, the method of manufacturing an electronic component using a thickness-slip type piezoelectric resonator has been described. However, the present invention relates to an electronic component using various electronic component elements other than the piezoelectric resonator. It can be applied to the manufacturing method.

Claims

請求の範囲 The scope of the claims
[1] 少なくとも一方主面に複数の電極ランドが設けられた基板上に導電性接着剤を用 いて電子部品素子を固定する電子部品の製造方法であって、  [1] An electronic component manufacturing method for fixing an electronic component element using a conductive adhesive on a substrate having a plurality of electrode lands provided on at least one main surface,
前記複数の電極ランドが一方主面に形成された基板と、電子部品素子とを用意す る工程と、  Preparing a substrate having the plurality of electrode lands formed on one main surface and an electronic component element;
前記電子部品素子の前記基板の電極ランドに接合される部分に、該電極ランドに 接合される面積よりも大きな面積となるように第 1の導電性接着剤を塗布し、硬化させ る工程と、  Applying a first conductive adhesive to a portion of the electronic component element to be bonded to the electrode land of the substrate so as to have an area larger than the area bonded to the electrode land, and curing the first conductive adhesive;
前記第 1の導電性接着剤が硬化した後に、該第 1の導電性接着剤が電極ランド〖こ 接合される面積を有するように硬化された第 1の導電性接着剤の不要部分を切断に より除去する工程と、  After the first conductive adhesive is cured, unnecessary portions of the first conductive adhesive cured so as to have an area where the first conductive adhesive is bonded to the electrode land are cut. More removing step,
前記第 1の導電性接着剤の不要部分を除去した後に、第 1の導電性接着剤と前記 基板の電極ランドとを第 2の導電性接着剤を介して接合する工程とを備える、電子部 品の製造方法。  An electronic part comprising: removing an unnecessary portion of the first conductive adhesive; and bonding the first conductive adhesive and the electrode land of the substrate via the second conductive adhesive. Product manufacturing method.
[2] 前記電子部品素子が、対向し合う第 1,第 2の端部を有し、前記電子部品素子の前 記基板に実装される面において、第 1の端部近傍部分と、第 2の端部近傍部分にお いて、前記電子部品素子が前記基板の電極ランドに接合される、請求項 1に記載の 電子部品の製造方法。  [2] The electronic component element has first and second end portions facing each other, and on the surface of the electronic component element mounted on the substrate, a portion near the first end portion, and a second end portion 2. The method of manufacturing an electronic component according to claim 1, wherein the electronic component element is bonded to an electrode land of the substrate in a portion near the end of the substrate.
[3] 前記第 1の導電性接着剤を硬化した後に、不要部分を除去するに際し、該第 1の 導電性接着剤の不要部分と共に、切断治具により該導電性接着剤の不要部分に連 なる電子部品素子の一部をも除去する、請求項 1または 2に記載の電子部品の製造 方法。  [3] When the unnecessary portion is removed after the first conductive adhesive is cured, the unnecessary portion of the first conductive adhesive is connected to the unnecessary portion of the conductive adhesive by a cutting jig together with the unnecessary portion of the first conductive adhesive. The method of manufacturing an electronic component according to claim 1, wherein a part of the electronic component element is also removed.
[4] 前記電子部品素子として、対向し合う第 1,第 2の主面と、第 1,第 2の主面を結ぶ 第 1,第 2の端面とを有する電子部品本体と、前記第 1の主面に、前記基板上の複数 の電極ランドに接合される複数の電極が設けられている、請求項 1〜3のいずれか 1 項に記載の電子部品の製造方法。  [4] As the electronic component element, an electronic component main body having first and second main surfaces facing each other and first and second end surfaces connecting the first and second main surfaces, and the first 4. The method of manufacturing an electronic component according to claim 1, wherein a plurality of electrodes to be bonded to a plurality of electrode lands on the substrate are provided on the main surface.
[5] 前記電子部品本体が圧電体であり、前記第 1,第 2の主面に、該圧電体を介して対 向するように第 1,第 2の励振電極が形成されており、それによつて圧電共振子が得 られる、請求項 4に記載の電子部品の製造方法。 [5] The electronic component body is a piezoelectric body, and first and second excitation electrodes are formed on the first and second main surfaces so as to face each other via the piezoelectric body, Therefore, a piezoelectric resonator is obtained. The method of manufacturing an electronic component according to claim 4, wherein
前記基板上に前記電子部品素子を固定した後に、該電子部品素子を覆うように前 記基板にキャップを固定する工程をさらに備える、請求項 1〜5のいずれ力 1項に記 載の電子部品の製造方法。  The electronic component according to any one of claims 1 to 5, further comprising a step of fixing a cap to the substrate so as to cover the electronic component element after the electronic component element is fixed on the substrate. Manufacturing method.
PCT/JP2005/011443 2004-08-27 2005-06-22 Manufacturing method of electronic component WO2006022072A1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06191887A (en) * 1992-10-29 1994-07-12 Nec Kansai Ltd Glass-ceramic composite and flat package-type piezoelectric parts using the composite
JPH0730357A (en) * 1993-07-07 1995-01-31 Murata Mfg Co Ltd Chip type piezoelectric resonator
JP2001127578A (en) * 1999-10-25 2001-05-11 Tdk Corp Piezoelectric vibration component and its manufacturing method
JP2002057544A (en) * 2000-08-09 2002-02-22 Murata Mfg Co Ltd Piezoelectric oscillator

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06191887A (en) * 1992-10-29 1994-07-12 Nec Kansai Ltd Glass-ceramic composite and flat package-type piezoelectric parts using the composite
JPH0730357A (en) * 1993-07-07 1995-01-31 Murata Mfg Co Ltd Chip type piezoelectric resonator
JP2001127578A (en) * 1999-10-25 2001-05-11 Tdk Corp Piezoelectric vibration component and its manufacturing method
JP2002057544A (en) * 2000-08-09 2002-02-22 Murata Mfg Co Ltd Piezoelectric oscillator

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