WO2006014266A1 - Lubrifiant de film sec - Google Patents

Lubrifiant de film sec Download PDF

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Publication number
WO2006014266A1
WO2006014266A1 PCT/US2005/022933 US2005022933W WO2006014266A1 WO 2006014266 A1 WO2006014266 A1 WO 2006014266A1 US 2005022933 W US2005022933 W US 2005022933W WO 2006014266 A1 WO2006014266 A1 WO 2006014266A1
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Prior art keywords
composition
copolymer
acrylic copolymer
weight
percent
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PCT/US2005/022933
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English (en)
Inventor
Jasdeep Sohi
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
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Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Priority to CA002571721A priority Critical patent/CA2571721A1/fr
Priority to EP05767788A priority patent/EP1765944A1/fr
Publication of WO2006014266A1 publication Critical patent/WO2006014266A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/008—Temporary coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/32—Esters
    • C10M105/38—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/401—Fatty vegetable or animal oils used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/011—Cloud point
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/12—Gas-turbines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/252—Diesel engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/255—Gasoline engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/255—Gasoline engines
    • C10N2040/26—Two-strokes or two-cycle engines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof

Definitions

  • the invention relates generally to dry film lubricants, coatings, coated substrates, and methods related thereto.
  • Metal plates or other like materials are often used to form parts, for various uses, including automotive, appliance, and general industrial uses, via stamping.
  • the plates, or more broadly, substrates are typically stored.
  • the substrates may be exposed to conditions that can cause corrosion and/or blocking of the parts. Blocking is a surface phenomenon where two substrates adhere to each other, usually due to heat or pressure.
  • mill oils, pre-lubes, drawing compounds, and dry film lubricants are valuable for preventing corrosion or reducing blocking between substrates, such as stainless steel, galvanized steel, including hot dipped galvanized steel and electro galvanized steel, galvanneal alloy, GALVALUME ® alloy (55% aluminum, 43.5% zinc, 1.5% silicon alloy steel), cold rolled steel, hot rolled steel, or aluminum.
  • U.S. Patent No. 6,187,849 discloses a temporary lubricant coating which has a wax, an acid-neutralized polymer that is derived from polymerization of a ethylenically unsaturated monomer having an acid functionality and at least one different polymerizable, ethylenically unsaturated monomer, and certain amines.
  • the instant invention provides a product that provides good anti-blocking and good anti-corrosion properties while being able to be removed with an alkaline cleaner.
  • the present invention is directed to compositions and methods employing an acrylic copolymer or styrene/acrylic copolymer having a weight average molecular weight (Mw) of about 8,000 to about 14,000, a thermoplastic acrylic copolymer having a Mw of about 90,000 to about 130,000, water, a wax emulsion or wax dispersion, and a particulate additive.
  • a rheological additive can be used.
  • the composition further comprises at least one of ammonium hydroxide or a defoaming compound. DETAILED DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS
  • the present invention provides a composition, comprising a first copolymer that is an acrylic copolymer or styrene/acrylic copolymer having a weight average molecular weight (Mw) of about 8,000 to about 14,000 , a second copolymer that is an acrylic copolymer having a Mw of about 90,000 to about 130,000, water, a wax emulsion or dispersion, and a particulate additive.
  • Mw weight average molecular weight
  • the first copolymer has an acid number (AN) of at least 110.
  • the acid number is between about 160 and about 220.
  • AN is about 200.
  • the second copolymer has an acid number of about 90 to about 130. In one preferred embodiment, the acid number is about 116.
  • the first copolymer has a glass transition temperature (Tg) of about 60 to about 80 0 C. In one embodiment, the Tg of the first copolymer is about 70
  • the Tg of the second copolymer is about 35 to about 70 °C. In one preferred embodiment the Tg of the second copolymer is about 47 0 C.
  • the first copolymer is a styrene/acrylic copolymer.
  • the first copolymer has a low Volatile Organic Content (VOC).
  • VOC Volatile Organic Content
  • the styrene/acrylic copolymer is a solid with a molecular weight of about 11,000 and an AN of about 200.
  • Styrene/acrylic polymer compositions are commercially available.
  • CARBOSET ® GA-2299 copolymer which is a styrenic/acrylic copolymer having the following characteristics ascertained from publicly available sources: Total Solids: 99%; Tg: 7O 0 C; AN: 200; Molecular Weight (MW): 11000; and VOC: ⁇ 0.1%.
  • the styrene/acrylic copolymer is a colloidal dispersion.
  • the styrene/acrylic copolymer colloidal dispersion has total solids of about 22% to about 35%. Preferably, the total solids are about 27.5% to about 30%.
  • Some styrene/acrylic copolymer colloidal dispersions have a Brooki ⁇ eld viscosity of about 1000 cps to about 4000 cps.
  • Certain styrene/acrylic copolymer colloidal dispersions are in ammonia water (ammonium hydroxide).
  • the styrene/acrylic copolymer colloidal dispersion has a pH of about 8.4 to about 9.2.
  • the styrene/acrylic copolymer colloidal dispersion is present in a range from about 2 to about 30 percent by weight of the composition. In other embodiments, the styrene/acrylic copolymer colloidal dispersion is preferably present in an amount of about 10 to about 23 percent by weight of the composition. In one preferred embodiment, the styrene/acrylic copolymer colloidal dispersion is about 16.7 percent by weight of the composition.
  • the styrene/acrylic copolymer colloidal dispersion is a product commercially available from Noveon, Inc., Cleveland, Ohio, USA, under the trade name "CARBOSET ® GA 2300.”
  • CARBOSET® GA-2300 is a high solids solution of a low molecular weight styrene/acrylic copolymer (CARBOSET® GA-2299) and ammonia water.
  • CARBOSET® GA-2300 styrene/acrylic copolymer colloidal dispersion has the following characteristics ascertained from publicly available sources: Weight per Gallon: 8.9 lbs.; AN: about 190; VOC: ⁇ 0.1%, along with excellent freeze/thaw stability, heat stability, and mechanical stability.
  • the second copolymer comprises an acrylic monomer and at least one additional monomer.
  • Suitable acrylic monomers include methacrylic acid, acrylic acid, and their ester analogs.
  • Suitable esters include CpC 12 alkyl esters. In some embodiments, the methyl, ethyl, butyl, or 2-ethylhexyl esters are preferred.
  • Suitable monomers for the "at least one additional monomer" useful in making acrylic compositions are well known to those skilled in the art.
  • the additional monomer may be another of methacrylic acid, acrylic acid, or their ester analogs.
  • suitable monomers include ethylenically unsaturated materials, such as styrene, vinyl toluene, and nitriles such as acrylonitrile and methyacrylonitrile, and vinyl halides.
  • Yet other suitable monomers include crotonic acid, itaconic acid, and maleic acid.
  • the second copolymer that is an acrylic copolymer has a low VOC.
  • the acrylic copolymer has an AN greater than about 80.
  • the AN is about 110 to about 122.
  • the second copolymer has an AN of about 116.
  • the acrylic copolymer has a Tg of about 47 0 C.
  • the second copolymer is partially neutralized with a base.
  • that base is preferably a volatile base such as ammonia, NH 4 OH, or a primary or secondary amine.
  • the second copolymer is an emulsion in water.
  • the acrylic copolymer is a colloidal dispersion.
  • Some copolymer colloidal dispersions have a molecular weight (Mw) of about 8,600 and an AN of about 116.
  • the acrylic copolymer colloidal dispersion has total solids of about 26% to about 28%. In some embodiments, the total solids is preferably about 27%.
  • the second copolymer is an acrylic copolymer colloidal dispersion that has a Brookfield viscosity of about 10 cps to about 200 cps.
  • the thermoplastic acrylic copolymer colloidal dispersion has a pH of about 7.0 to about 8.0. In some embodiments, the pH is about 7.6.
  • Some embodiments of the invention have the second copolymer as an acrylic copolymer colloidal dispersion present in a range from about 30 to about 70 percent by weight of the composition. In certain preferred embodiments, the acrylic copolymer colloidal dispersion is about 51.8 percent by weight of the composition.
  • the second copolymer is an acrylic copolymer colloidal dispersion that is a product commercially available from Noveon, Inc., Cleveland, Ohio, USA, under the trade name "CARBOSET ® .”
  • the product is preferably CARBOSET ® 560 acrylic colloidal dispersion.
  • CARBOSET ® 560 acrylic colloidal dispersion is a thermoplastic acrylic copolymer having the following characteristics ascertained from publicly available sources: Total Solids (%): 26.0 to 28.0, Tg : 47° C, AN: 116, Total Solids by Volume: 24.5%, pH 7.0 to 8.0, Brookfield Viscosity, cps 10 to 200, Vapor Pressure (20 C): 2.34 kPa, % Volatile by weight: 73, VOC: Pounds per Gallon: 0.16/Grams per Liter: 20, Boiling Point (C): 100 0 C, Weight per Gallon: 8.6, Density: 1.0 to 1.2 kg/m 3 , MFFT: 17 0 C, and is miscible in water. While not wanting to be bound by theory, it is believed that the surface amines provide dispersion stability as water is added, and the polymer becomes more insoluble as the water content increases.
  • the polymer contains carboxylic acid functional groups.
  • Water may be added even when the components are in aqueous solution. Such added water (exclusive of water in the other components), if added, may be present in an amount up to about 30 percent by weight of the composition. In some embodiments, the added water is present in a range from about 5 to about 30 percent by weight of the composition. In one preferred embodiment, the water is about 18.3 percent by weight of the composition. In contrast, the total water present, from all sources in the composition may range from about 50 to about 80 percent by weight of the composition, preferably from about 70 to about 75 percent by weight of the composition.
  • the water is deionized water.
  • the rheological additive can be selected from a number of conventional compositions well known to those skilled in the art. Such additives are also known in the trade as anti-settling agents.
  • the rheological additive is a liquid rheological additive for aqueous coatings.
  • the rheological additive provides an anti-settling benefit. Any amount of this additive which prevents settling (i.e., maintains stability) but without rendering the composition too viscous to apply is acceptable.
  • the rheological additive is present in a range from about 0.1 to about 1 percent by weight of the composition. In certain preferred embodiments, the rheological additive is about 0.5 percent by weight of the composition.
  • the rheological additive is modified urea in N-methyl pyrrolidone, and is commercially available from BYK-Chemie USA Inc., Wallingford, Conn., USA, under the trade name "BYK ® 420.”
  • BYK®-420 is a liquid rheological additive, wherein after incorporation, a three-dimensional network is believed to develop. The resulting thixotropic flow behavior prevents settling and improves sag resistance.
  • BYK®-420 rheological additive has the following characteristics ascertained from publicly available sources: Weight per Gallon: 9.33 lbs; Density at 2O 0 C: 1.12 g/mL.
  • Crayvallac LA- 100 available from Cray VaIIy and BYK-425 from BYK-Chemie.
  • the wax is in the form of a wax emulsion.
  • the wax emulsion generally comprises a stable mixture of wax, emulsifier, and water.
  • Wax comprises natural waxes, including animal waxes, for example, beeswax and lanolin, vegetable waxes, for example, carnauba and candellila, and mineral and petroleum waxes, for example, montan, paraffin, slack, scale, and microcrystalline, and synthetic wax-like substances, such as polyethylene, polypropylene, Fischer-Tropsch compounds, and resins such as ethylene-acrylic acid.
  • a wax emulsion comprises particles that are less than one micron (1 ⁇ ) in size.
  • the wax emulsion is present in a range from about 3 to about 18 percent by weight of the composition. In one preferred embodiment, the wax emulsion is about 10.3 percent by weight of the composition. In some embodiments, the wax has a melting point in the range of 50 to 160 0 C. In certain embodiments, the melting point is from 55 to 110 0 C. In one embodiment, the wax emulsion has an melting point (Mp) of about 60 0 C.
  • the wax emulsion contains paraffin and polyethylene.
  • a wax emulsion is commercially available from Michelman, Inc., Cincinnati, Ohio, USA, under the trade name "MICHEM ® EMULSION,” and in one embodiment is preferably MICHEM ® EMULSION 62330.
  • Other wax emulsions include those sold under the tradenames MICHEM® Lube and MICHEM ® Shield from Michelman, Inc. and Aquatec 4111 from Lawter International.
  • a wax dispersion may be used.
  • a wax dispersion comprises micronized waxes dispersed in water. Any suitable wax emulsion or dispersion can be used, as long as it provides sufficient water repellency and formability to the composition. In some embodiments, the particles of the wax dispersion are greater than one micron in size.
  • the particulate additive is present in a range from about 0.01 to about 4 percent by weight of the composition. In certain preferred embodiments, the particulate additive is preferably present in an amount of about 2.0 percent by weight of the composition. The particulate additive is believed to be desirable for block and corrosion resistance, and greater amounts can be used, provided there is no negative effect on stability of the composition. [0039] In one embodiment, the particulate additive is clay or silicate. In some compositions, the silicate includes at least one of Mg or Al. In one embodiment, the particulate additive is a magnesium silicate.
  • the particulate additive is talc.
  • the talc may be, for example, hydrous magnesium silicate, and is commercially available from Reade Advanced Materials, Buffalo, Rhode Island, USA.
  • Talc is also known as talc powder, cosmetic talc, French talc, Montana talc, Texas talc, Vermont talc, industrial talc, tremolitic talc, steatite talc, fibrous non-tremolite talc, no asbestos talc, magnesium silicate talc, talcum, French chalk, talc (Mg 3 H 2 (SiOs) 4 ).
  • Nytal® 300 a talc marketed by Lansco Colors, and reported to have a median diameter of 6.9 microns. Other Nytal® talcs are reported to have mean diameters of 4.5, 7.0, 8.7, and 12.6 microns. The Nytal® talcs are believed to be a mixture of platy and needle shaped particles.
  • Another commercial product is Artie Mist®, a platy talc available from Luzenac America that has a mean diameter of 2.2 microns.
  • Nicron® 402 available from Luzenac America, is a platy talc having a mean diameter of 10 microns.
  • Vertal® 92 available from Luzenac America, is a larger diameter talc with a platy structure. The mean diameter of these particles is 17.5 microns.
  • the particulate is a plate shape. In other embodiments, the particulate is needle shaped. In certain preferred embodiments, the particulate is a mixture of the two shapes.
  • Some preferred particles have a mean particle size of about 0.5 to about 3 microns. Such preferred particles may have a mean particle size of about 2 microns. Other particles have a mean particle size of about 5 to about 25 microns. One example of such particles has a mean diameter of about 6.9 microns, another has a mean diameter of about 17 microns. In some preferred embodiments, it is desirable to have a mixture of the smaller and larger particles detailed above. Such a mixture has been observed to provide better resistance to the fingernail scratch test and anti-blocking characteristics than either type of particle does by itself.
  • the composition further comprises a viscosity builder.
  • the viscosity builder is a base.
  • the amount of the base required is that sufficient to neutralize the acid functional groups on the copolymers, which is readily calculable by one of skill in the art.
  • One suitable viscosity builder is ammonium hydroxide.
  • One commercial source of ammonium hydroxide is known by the product name "Ammonium hydroxide 26 Be” from Univar USA, Kirkland, WA, USA 98003. Ammonium hydroxide 26 Be is also known as "aqua ammonia water,” and typically contains between 28% to 30% ammonia before dilution. Another source of ammonium hydroxide is Sigma-Aldrich.
  • the ammonium hydroxide is present in a range from about 0.01 to about 0.8 percent by weight of the composition. In one preferred embodiment, the ammonium hydroxide is about 0.4 percent by weight of the composition.
  • ammonium hydroxide can be replaced with alkali bases or amines, for example 2-aminomethyl-propanol (AMP), morpholine, dimethyl ethanol amine (DMEA).
  • alkali bases or amines for example 2-aminomethyl-propanol (AMP), morpholine, dimethyl ethanol amine (DMEA).
  • the compositions further comprises a defoaming compound.
  • a defoaming compound Many defoamers are know to those skilled in the art and can be used so long as their use does not negatively impact other product properties.
  • Suitable defoaming compounds include compositions that comprise straight chain petroleum distillates, silica, surfactants, and/or wax.
  • the defoaming compound comprises about 80% to about 90% straight chain petroleum distillates, about 1% to about 10% silica, about 1% to about 10% surfactants, and about 1% to about 10% wax.
  • One preferred defoaming compound is a product commercially available under the trade name "HYDRO SPEC DO-IOl” available from Henkel Surface Technologies, Madison Heights, MI, USA, having a pH 6.5 to 7.5 (of concentrate), viscosity at 25 0 C: 800 cps to 2000 cps, and specific gravity: 0.85 to 0.90.
  • Other oil-based defoamers include those sold under the tradename Hi-Mar by the Thornley Company, and FOAMASTER SA-3 available from Fritz Chem Corporation.
  • One or more coalescing agents may be added to the instant composition.
  • Suitable agents include low molecular weight ethoxylated alcohol and propylene glycol esters of fatty acids.
  • One preferred agent is an aromatic alkoxylated ester such as, for example, an ethoxylated benzyl alcohol.
  • Suitable commercial products include Archer RC®, CAS # 515152- 38-2, from ADM. This product is derived from sunflower or corn oil fatty acids with propylene glycol.
  • Another agent is Genapol BA 040, a benzyl alcohol ethoxylate, CAS # 26403-74-7, available from Clariant.
  • a mixture of ethoxylated alcohol and propylene glycol esters of fatty acids is used.
  • the present invention provides a coating comprising any of the compositions described above where the compositions having been dried in place to remove water and any other volatiles present.
  • the composition is applied by any conventional means known in the art and is then dried.
  • the coating does not react with the substrate, nor does it oxidize, but maintains its original applied characteristics.
  • the composition of the present invention can be diluted with water to provide any desired coating weight required for protection under most storage conditions.
  • the temporary protective coating of the invention may be applied to metallic substrates by any conventional application means known in the art such as spraying, brushing, dipping, roll coating, curtain coating or the like.
  • the coating is typically applied at film weights of 100 to 600, preferably 150 to 500, and more preferably 200 to 350 milligrams per square foot. Coating weights are typically in the range from about 150 mg/ft 2 to 300 mg/ft 2 .
  • Applied temporary protective coatings can be air dried or force dried. Typically, the applied coatings are forced dried at temperatures ranging from 5O 0 C to 25O 0 C, preferably from 7O 0 C to 200 0 C, and more preferably from 9O 0 C to 15O 0 C. In yet another embodiment, once applied the coating of the present invention can be dried by achieving surface temperatures less than 200° F, and in a presently preferred embodiment as low as 170° F.
  • this coating can be removed by alkaline cleaning, but is advantageously not water-soluble. Once removed, the surface is available for further processing. Removal of the applied coating is effected by contacting the coated substrate with an aqueous alkaline solution, such as by spraying, flooding, immersion or the like.
  • the present invention provides a substrate contacted by any of the compositions described above.
  • the substrate may be stainless steel, galvanized steel, hot dipped galvanized steel, electro galvanized steel, galvanneal alloy, GALVALUME ® alloy (55% aluminum, 43.5% zinc, 1.5% silicon alloy steel), cold rolled steel, hot rolled steel, or aluminum.
  • the present invention provides a method for preventing corrosion on a substrate, comprising contacting the substrate with any of the compositions described above.
  • the present invention provides a method for reducing blocking between substrates, comprising contacting the substrates with any of the compositions described above.
  • the present invention provides, in one embodiment, a composition, comprising a copolymer comprising at least one of styrene/acrylic or acrylic, a thermoplastic acrylic copolymer, water, a rheological additive, a wax emulsion, a particulate additive, and a viscosity builder.
  • the present invention provides a composition, comprising a styrene/acrylic copolymer colloidal dispersion, a thermoplastic acrylic copolymer colloidal dispersion, water, a urea-containing rheological additive, a wax emulsion, a silicate including at least one of Mg or Al, and ammonium hydroxide.
  • the present invention also provides a composition comprising CARBOSET
  • GA-2300 copolymer water, a rheological additive, a particulate additive, a viscosity builder, a wax emulsion, and CARBOSET 560 copolymer.
  • a dry film lubricant was prepared having the components listed in TABLE 1.
  • composition functions without the talc and the ammonium hydroxide, and so these components are optional.
  • the pH of the composition should be 7 or greater.
  • Reverse Impact Tests were performed as in ASTM D2794. All the panels were subjected to impact of a ball at 80 inch/pounds. After impact, the panels were taped at the bend or dent, the tape was removed and bend radii were then wiped with copper sulfate to see if the coating was removed by the tape. Very light copper sulfate stain after taping was observed.
  • composition was cleanable with PCL 75 LC as per TPB 232070 (2% solution of PCL 75 LC in water @ 110° F for 60 sec). To determine whether there was any residue of the dry lubricant on the panels, the substrate panels were cleaned, then rinsed with deionized water and dried. A drop of about 3 Wt % copper sulfate pentahydrate solution was dropped on the panels. A 100% reaction, evidenced by the area of the panel that contacted the drop turning black within a second of contact, was observed on all the panels, indicating the panels were fully cleaned and were water break free.
  • the composition performed satisfactorily when formed, as evidenced by formability testing, such as determining limiting dome height (LDH) using a MTS Metalform 866 LDH Machine. This test was performed by contacting the panel with a die to see how far the surface could deform without disrupting the coating. [0069] The testing showed that the composition had acceptable properties for a dry film lubricant, and performed at least as well in the above tests as a commercially available dry film lubricant sold under the trade name "CHEMFORM ® " available from PPG Industries, Inc. Pittsburg, PA, USA. In particular, the competitive product showed very light copper sulfate stain in the IT bend test and reverse impact test. The competitive product showed no staining in the water spotting test.
  • formability testing such as determining limiting dome height (LDH) using a MTS Metalform 866 LDH Machine. This test was performed by contacting the panel with a die to see how far the surface could deform without disrupting the coating.
  • the testing showed that the composition had acceptable properties
  • composition from TABLE 1 and the comparative dry film lubricant were each tested in a 24 hour stack test.
  • Cold rolled steel substrate panels were coated using either the composition from TABLE 1 or the comparative dry film lubricant. Like-coated panels were clipped face to face with paper clips and placed in a beaker over water, but not sitting in the water. The beaker was covered with plastic and taped shut, and then placed in an oven at 100 0 F for 24 hours.
  • Panels coated with the composition from TABLE 1 showed no haziness, corrosion, or stickiness.
  • Panels coated with the comparative dry film lubricant were very hard to take apart and showed 80-90% haziness. It is not desired for the panels to show any corrosion or blocking as it will be hard to uncoil the coils after sitting in the hot and humid atmosphere.
  • composition from TABLE 1 and the comparative dry film lubricant were each tested in a Blocking Test using Carver hydraulic equipment at 5000-6000 psi at 14O 0 F.
  • the object of the test was to determine and compare blocking (panels sticking together to form a block as representing coiled) of panels coated with different coatings.
  • 2" X 4" strips are cut from the panels where both sides were coated with organic passivate.
  • the Carver hydraulic press used for T- bends was equipped with constant temperature heating blocks attached to variants. The variants were adjusted as necessary to maintain a constant temperature as measured by a VWR dual input J-type thermocouple.
  • Panels were tested face to face in pairs with three pairs on the press at any one time.
  • the press was to set to approximately 5000 lbs for 30 minutes. Pressure was observed to stay between 5000-6000 lbs during the course of the blocking test.
  • Panels were tested at different constant temperatures between 110-140 0 F. After 30 minutes the panels are removed from the press, allowed to cool and observed for blocking behavior. The panels passed the blocking test at that temperature if the panels fell apart easily and there is no sound when separating panels.
  • Example 1 The composition of Example 1 was prepared where the talc (17.5 micron mean diameter) was replaced with 1% each of the Artie Mist® and Nytal 300. In addition, 1% each of the BA040 and Archer RC were added to the composition.
  • Example 5 The composition of Example 5 was tested for performance by a variety of tests described below. The coating was applied to the cold rolled steel panels using a drawbar. The results are presented in Table 2. The column labeled "Performance Criteria" represents properties desired for use of dry film lubricants in commercial applications, such as automotive, appliance, and general industrial uses .
  • compositions of the present invention are surprisingly better anti-corrosive and anti-blocking compositions than known compounds.

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Abstract

La présente invention concerne des compositions et des procédés employant un premier copolymère qui est un copolymère acrylique ou un copolymère de styrène/acrylique dont le poids moléculaire moyen en poids (Mw) est d'environ 8000 à environ 14000, un deuxième copolymère qui est un copolymère acrylique ayant un Mw d'environ 90000 à environ 130000, une émulsion ou une dispersion de cire et un additif en particules. En option, la composition comprend également au moins l'un des éléments parmi un additif rhéologique, un hydroxyde d'ammonium ou un composé antimousse.
PCT/US2005/022933 2004-07-02 2005-06-28 Lubrifiant de film sec WO2006014266A1 (fr)

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TWI457432B (zh) 2008-01-30 2014-10-21 Chemetall Gmbh 將金屬表面施以一含蠟的潤滑劑組成物的方法
TWI457433B (zh) * 2008-01-30 2014-10-21 Chemetall Gmbh 將金屬表面施以一磷酸鹽層然後施以一潤滑劑層的方法
TWI457431B (zh) * 2008-01-30 2014-10-21 Chemetall Gmbh 將金屬表面施以一種潤滑劑組成物的方法
EP3114181A4 (fr) * 2014-03-07 2017-01-25 Tsytex E-Coatings Inc. Revêtement protecteur temporaire et système d'élimination
WO2016049257A1 (fr) 2014-09-26 2016-03-31 Henry Company, Llc Poudres obtenues à partir de dispersions colloïdales à base de cire et leur procédé de fabrication
WO2016070012A1 (fr) 2014-10-30 2016-05-06 Henry Company, Llc Matériaux à changement de phase à partir de dispersions colloïdales à base de cire et leur procédé de fabrication
WO2016094719A1 (fr) 2014-12-11 2016-06-16 Henry Company, Llc Matériaux à changement de phase obtenus à partir de dispersions colloïdales à base de cire et leur procédé de fabrication
EP3643759B1 (fr) * 2018-10-26 2022-03-23 Henkel AG & Co. KGaA Acier à feuillard revêtu de polycarboxylate et son utilisation pour l'emboutissage

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CN1977011A (zh) 2007-06-06
CA2571721A1 (fr) 2006-02-09
US20060003901A1 (en) 2006-01-05

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