WO2006010491A1 - Procede pour produire des blocs a phases multiples pour le nettoyage des w.-c. - Google Patents

Procede pour produire des blocs a phases multiples pour le nettoyage des w.-c. Download PDF

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Publication number
WO2006010491A1
WO2006010491A1 PCT/EP2005/007700 EP2005007700W WO2006010491A1 WO 2006010491 A1 WO2006010491 A1 WO 2006010491A1 EP 2005007700 W EP2005007700 W EP 2005007700W WO 2006010491 A1 WO2006010491 A1 WO 2006010491A1
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WIPO (PCT)
Prior art keywords
phases
phase
sodium
soluble
individual
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PCT/EP2005/007700
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German (de)
English (en)
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WO2006010491A8 (fr
Inventor
Ronald Menke
Gerd Praus
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Henkel Kommanditgesellschaft Auf Aktien
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Priority to EP05766604A priority Critical patent/EP1769061A1/fr
Publication of WO2006010491A1 publication Critical patent/WO2006010491A1/fr
Publication of WO2006010491A8 publication Critical patent/WO2006010491A8/fr

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0056—Lavatory cleansing blocks
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0078—Multilayered tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/044—Solid compositions

Definitions

  • the subject matter of the present application is a process for producing solid multi-phase WC cleaning blocks which consist of at least two phases.
  • Detergents and disinfectants have long been used in the toilet bowl under the edge of the pool (so-called rim blocks) as well as in the water tank (in- tank-biocks or cistern blocks).
  • the formulations generally contain surfactants, disinfectants and bleaches, salts, acids, complexing agents, fillers, dyes and perfumes, Ab Pattersonregulatoren and / or other components.
  • the ingredients are usually mixed, compressed and then extruded to Strän ⁇ gene. The strands are finally cut to the desired length and optionally placed in toilet bowls.
  • the toilet bowl can be cleaned and / or disinfected, for example. Furthermore, e.g. It is also possible to inhibit unpleasant odors or fragrance with a perfume.
  • the ingredients needed for these various effects are not always compatible with each other. For example, sensitive substances, such as dyes, can be attacked, for example, by antimicrobial bleaching agents; Also, the compatibility of acids or complexing agents, which are used to prevent lime, rust or urinary stone deposits, for example, with perfumes is often not given.
  • Such multi-use toilet sticks are therefore advantageously designed as multi-phase sticks.
  • the different phases can be equipped with different colors in order to signal the multiple benefit to the consumer as well. In this case, the different phases can be arranged either horizontally above one another or vertically next to or behind one another.
  • Polyphonic WC sticks have so far been produced in a single manufacturing process by co-extrusion of the different phases.
  • the various strands are brought together immediately after extrusion, pressed together and cut.
  • EP 1 165 740 B1 describes a toilet cleaning block comprising at least two phases, one phase of which contains a water-insoluble salt which makes up at least 50% by weight of the salt in this phase, and the second phase of which is a perfume and a water-soluble one Contains salt, wherein the salts in both phases should have the same anion. Other ingredients may also be included.
  • the manufacturing process also claimed is the coextrusion of the two or more phases to form the block.
  • EP 0 791 047 B1 also describes multi-phase cleaning agent pieces for flushing toilets, which, however, are configured in such a way that one phase is enclosed by a second and, if appropriate, further phases.
  • all phases can be extruded or extruded at least one phase and at least one further phase are poured, the latter in particular for liquid cores. If all phases are extruded, two or more extruders are needed, the strands of which are brought together and then cut, with a two-component or multi-component nozzle for the common extrusion of the phases enclosing each other can be used.
  • the object of the present invention was thus the development of a process for simplified production of multiphase WC sticks, which do not have the disadvantages mentioned with the same visual impression.
  • the invention therefore relates to a process for producing solid multi-phase WC cleaning block, consisting of at least two phases, characterized by the steps of mixing the components in each case for the individual phases, extrusion of the individual strands for the different phases, trimming the strands on the for the length of individual blocks, combining the blocks for the various phases and finally fixing in a water-soluble, transparent film.
  • a second subject of this invention is a multi-phase WC cleaning block which requires only one extruder to produce.
  • This toilet cleaning block is inserted into a water-soluble polyvinyl alcohol (PVAL) film.
  • PVAL polyvinyl alcohol
  • a suitable container for example a basket, is required. So that the consumer can be made aware of the multiphase, it is expedient here a transparent container use. Through the container, the phases are fixed to each other even after the dissolution of the film surrounding the block.
  • Another subject of the invention is therefore a product of a multi-phase toilet cleaning block and a transparent container.
  • toilet block or “block” or “toilet cleaning block”, “toilet stick” or “stick” and “cleaning agent piece” and “means” are used synonymously below.
  • the extrusion of the individual phases for all phases can take place successively on an extruder.
  • Both the blocks for the individual phases and the finished multiphase WC sticks are preferably cuboidal.
  • the phases can be arranged horizontally one above the other in the finished WC-stick, preferably in such a way that the larger longitudinal surfaces of the individual cuboids are in contact with each other, or vertically behind or next to each other, preferably in such a way that the smaller parallelepiped surfaces coincide with one another are in contact.
  • the can length of the longer edges of the cuboids for the individual phases is not more than twice as large as that of the shorter edges. If three or more phases are combined to form a block, they can all be arranged one above the other, all next to each other or both above and next to each other.
  • two phases may be arranged next to or behind one another and rest on a third block, the dimensions of which are preferably chosen such that complete coincidence occurs on the common area with the other two phases.
  • a third block the dimensions of which are preferably chosen such that complete coincidence occurs on the common area with the other two phases.
  • composition of the individual phases, which together form the toilet cleaning blocks according to the invention can be substantially the same except for the different contents of active substance.
  • compositions for the individual phases it is possible to use all substances which have hitherto been used for the production of detergent pieces for toilets.
  • these substances include in particular surfactants, disinfectants and bleaches, salts, acids, complexing agents, fillers, dyes, fragrances, Ab Hughes ⁇ regulators and plasticizers.
  • phase-specific active substances in the sense of this invention above all disinfectants, bleaching agents, acids, complexing agents, dyes and fragrances are considered. Accordingly, in a preferred embodiment of this invention, these are subsequently stirred into portions of the base mixture of surfactants, salts, rinse-off regulators, plasticizers and further common constituents before the portion is extruded.
  • the International Cosmetic Ingredient Dictionary and Handbook assigns to the ingredients one or more chemical classes (Chemical Classes), for example Polymeric Ethers, and one or more functions, for example Surfactants - Cleansing Agents, which in turn explains it in more detail and the nach ⁇ following, if appropriate, also referred to.
  • chemical Classes for example Polymeric Ethers
  • functions for example Surfactants - Cleansing Agents
  • the indication CAS means that the following sequence of numbers is a name of the Chemical Abstracts Service.
  • Surfactants from all known classes namely anionic, nonionic, cationic and amphoteric surfactants can be selected for use in the compositions according to the invention, but anionic and / or nonionic surfactants are preferably used.
  • fatty acids or fatty alcohols or their derivatives are-unless stated otherwise-representative of branched or unbranched carboxylic acids or alcohols or their derivatives having preferably 6 to 22 carbon atoms, in particular 8 to 20 carbon atoms 10 to 18 carbon atoms, most preferably 12 to 16 carbon atoms, for example 12 to 14 carbon atoms.
  • the former are particularly preferred for their vegetable base as based on renewable raw materials for environmental reasons, but without limiting the teaching of the invention to them.
  • the oxo alcohols obtainable, for example, by Roelen's oxo synthesis or derivatives thereof having preferably 7 to 19 carbon atoms, in particular 9 to 19 carbon atoms, more preferably 9 to 17 carbon atoms, most preferably 11 to 15 carbon atoms, for example 9 to 11, 12 to 15 or 13 to 15 carbon atoms, can be used accordingly.
  • Anionic surfactants according to the invention may be aliphatic sulfates such as fatty alcohol sulfates, fatty alcohol ether sulfates, dialkyl ether sulfates, monoglyceride sulfates and aliphatic sulfonates such as alkanesulfonates, olefinsulfonates, ether sulfonates, n-alkyl ether sulfonates, ester sulfonates and lignosulfonates.
  • aliphatic sulfates such as fatty alcohol sulfates, fatty alcohol ether sulfates, dialkyl ether sulfates, monoglyceride sulfates and aliphatic sulfonates such as alkanesulfonates, olefinsulfonates, ether sulfonates, n-alkyl ether sulfonates, ester sulfonates and
  • alkylbenzenesulfonates in particular having about 12 carbon atoms in the alkyl moiety, fatty acid cyanamides, sulfosuccinates (sulfosuccinic esters), in particular sulfosuccinic mono- and di-C 8 -C 18 -alkyl esters, sulfosuccinamates, sulfosuccin amides, fatty acid isethionates, acylaminoalkanesulfonates (fatty acid taurides), fatty acid sarcosinates, ether carboxylic acids and alkyl (ether) phosphates, and ⁇ -sulfofatty acid salts, acyl glutamates, monoglyceride disulfates and alkyl ethers of glyceryl disulfate.
  • fatty alcohol sulfates are products of sulfation reactions on corresponding alcohols
  • fatty alcohol sulfates are products of sulfation reactions on alkoxylated alcohols.
  • alkoxylated alcohols the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, for the purposes of the present invention preferably with longer-chain alcohols.
  • a complex mixture of addition products of different degrees of ethoxylation is formed from n moles of ethylene oxide and one mole of alcohol, depending on the reaction conditions.
  • a further embodiment of the alkoxylation consists in the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide.
  • Preferred fatty alcohol ethers are the sulfates of lower ethoxylated fatty alcohols with 1 to 4 ethylene oxide units (EO), in particular 1 to 2 EO, for example 1.3 EO.
  • the anionic surfactants are preferably used as sodium salts, but may also be present as other alkali metal or alkaline earth metal salts, for example magnesium salts, and in the form of ammonium or mono-, di-, tri- or tetraalkylammonium salts, in the case of the sulfonates also in the form their corresponding acid, eg Dode- cylbenzenesulfonic acid.
  • anionic surfactants are sodium cocoalkyl sulfate, sodium se ⁇ -alkanesulfonate having about 15 carbon atoms and sodium dioctylsulfosuccinate.
  • Sodium fatty alkyl sulfates and fatty alkyl + 2EO ether sulfates having 12 to 14 C atoms have proven to be particularly suitable.
  • Anionic surfactants, in particular fatty alcohol sulfates are preferably used in amounts of from 10 to 50% by weight, in particular in amounts of from 15 to 30% by weight, particularly preferably from 20 to 28% by weight.
  • Nonionic surfactants in the context of the invention can be alkoxylates such as polyglycol ethers, fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, end-capped polyglycol ethers, mixed ethers and hydroxy mixed ethers and fatty acid polyglycol esters.
  • alkoxylates such as polyglycol ethers, fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, end-capped polyglycol ethers, mixed ethers and hydroxy mixed ethers and fatty acid polyglycol esters.
  • ethylene oxide / propylene oxide block polymers fatty acid alkanolamides and fatty acid polyglycol ethers.
  • Another important class of nonionic surfactants which can be used according to the invention are the polyol surfactants, in particular the glycerides, such as alkyl polyglycosides and fatty acid glucamides.
  • Alkyl polyglycosides are surfactants which can be obtained by the reaction of sugars and alcohols by the relevant methods of preparative organic chemistry. depending on the type of production to a. Mixture of monoalkylated, oligomeric or polymeric sugar comes.
  • Preferred alkyl polyglycosides are alkyl polyglucosides wherein particularly preferred the alcohol is a long-chain fatty alcohol or a mixture of long-chain fatty alcohols having branched or unbranched C 8 - to C 8 alkyl chains and the CTigomertechnischsgrad (DP) of the sugar 1-10, preferably 1 to 6, in particular 1.1 to 3, more preferably 1.1 to 1.7, is, for example, C 8- io-alkyl-1.5-glucoside (DP of 1, 5).
  • the alcohol is a long-chain fatty alcohol or a mixture of long-chain fatty alcohols having branched or unbranched C 8 - to C 8 alkyl chains and the CTigomertechnischsgrad (DP) of the sugar 1-10, preferably 1 to 6, in particular 1.1 to 3, more preferably 1.1 to 1.7, is, for example, C 8- io-alkyl-1.5-glucoside (DP of 1, 5).
  • Preferred fatty alcohol polyglycol ethers are ethylene oxide (EO) and / or propylene oxide (PO) alkoxylated, unbranched or branched, saturated or unsaturated C 8-22 -AlkO- hole with a degree of alkoxylation up to 30, preferably ethoxylated C 12-22 fatty alcohols having a degree of ethoxylation of less than 30, preferably 12 to 28, in particular 20 to 28, particularly preferably 25, for example C 16-18 fatty alcohol ethoxylates with 25 EO.
  • EO ethylene oxide
  • PO propylene oxide
  • Nonionic surfactants in particular fatty alcohol ethoxylates and / or alkyl polyglycosides, are preferably used in amounts of from 5 to 30% by weight, in particular in amounts of from 10 to 25% by weight, particularly preferably from 14 to 20% by weight.
  • a toilet stick according to the invention contains anionic and / or nonionic surfactants in a total amount of from 20 to 60% by weight, preferably from 25 to 50% by weight, in particular from 30 to 45% by weight.
  • amphoteric surfactants which can be used according to the invention include betaines, amine oxides, alkylamidoalkylamines, alkyl-substituted amino acids, acylated amino acids or biosurfactants, of which the betaines are particularly preferred within the scope of the teaching according to the invention.
  • Suitable betaines include the alkylbetaines, the alkylamidobetaines, the imidazolinium betaines, the sulfobetaines (INCI Sultaines) and the phosphobetaines.
  • Alkyl and alkyl amido betaines having a carboxylate group are also called carbobetaines.
  • betaines and sulfobetaines are the following compounds designated as INCI: almondamidopropyl betaines, apricotamidopropyl betaines, avocadamidopropyl betaines, babassuamidopropyl betaines, behenamidopropyl betaines, behenylamine, betaines, canolamidopropyl betaines, caprylic / capramidopropyl betaines, carnitines, cetyl betaines, Cocamidoethyl betaines, cocamidopropyl betaines, cocamidopropyl hydroxysuccinols, coco betaines, cocp hydroxysultaines, coco / olearnoprylphenyl betaines, coco-sultaines, decyl betaines, dihydroxyethyl oleyl glycinates, dihydroxyethyl soy glycinates, di
  • the amine oxides suitable in accordance with the invention include alkylamine oxides, in particular alkyldimethylamine oxides, alkylamidoamine oxides and alkoxyalkylamine oxides.
  • Suitable amine oxides are the following compounds designated as INCI: Almondamidopropylamine oxides, Babassuamidopropylamine oxides, Behenamine oxides, Cocamidopropyl Amine oxides, Cocamidopropylamine oxides, Cocamine oxides, Coco-Morpholine oxides, Decylamine oxides, Decyltetradecylamine oxides, Diaminopyrimidines oxides, Dihydroxyethyl C8-10 Alkoxypropylamines oxides, dihydroxyethyl C9-11 alkoxypropylamines oxides, dihydroxyethyl C12-15 alkoxypropylamines oxides, dihydroxyethyl cocamine oxides, dihydroxyethyl lauramine oxides, dihydroxyethyl stearamines oxides, dihydroxyethyl tallowamine oxides, hydrogenated palm kernel amines oxides, hydrogenated tallowamine oxides, hydroxyethyl hydroxypropyl
  • alkylamidoalkylamines are the following gene named according to INCI Verbindun ⁇ : Cocoamphodipropionic Acid, Cocobetainamido amphopropionates, DEA-Cocoampho- dipropionate, disodium Caproamphodiacetate, Disodium Caproamphodipropionate, Disodium Capryloamphodiacetate, Disodium Capryloamphodipropionate, Disodium Cocoam- phocarboxyethylhydroxypropylsulfonate, Disodium Cocoamphodiacetate, Disodium coco amphodipropionate , Disodium Isostearoamphodiacetate, Disodium Isostearoamphodipro- pionate, Disodium Laureth-5 Carboxyamphodiacetate, Disodium Lauroamphodiacetate, Disodium Lauroamphodipropionate, Disodium Oleoamphodipropionate, Disodium PPG-2-amphodiacetate,
  • Exemplary alkyl-substituted amino acids are the following INCI compounds: Aminopropyl Laurylglutamine, Cocaminobutyric Acid, Cocaminopropionic Acid, DEA Lauraminopropionate, Disodium Cocaminopropyl Iminodiacetate, Disodium Dicarboxyethyl Cocopropylenediamine, Disodium Lauriminodipropionate, Disodium Steariminodipropionate, Disodium Tallowiminodipropionate, Lauraminopropionic Acid, Lauryl Aminopropylglycine , Lauryl Diethylenediaminoglycine, Myristaminopropionic Acid, Sodium C12-15 Alkoxypropyl Iminodipropionate, Sodium Cocaminopropionate, Sodium Lauramine Propionate, Sodium Lauriminodipropionate, Sodium Lauroyl Methylaminopropionate, TEA Lauraminopropionate and TEA Myr
  • Acylated amino acids are amino acids, in particular the 20 natural ⁇ -amino acids, which bear on the amino acyl residue RCO to a saturated or ungesquestionedtig ⁇ th fatty acid RCOOH, wherein R is a saturated or unsaturated C 6-22 alkyl, preferably C 8- 8 i Alkyl, in particular a saturated Ci O -i 6- Alkylrest, for example a saturated Ci 2- i 4- Alkylrest is.
  • the acylated amino acids can also be used as alkali metal salt, alkaline earth metal salt or alkanolammonium salt, for example mono-, di- or triethanolammonium salt.
  • acylated amino acids are the acyl derivatives summarized in accordance with INCI under amino acids, for example sodium cocoyl glutamate, lauroyl glutamic acid, capryloyl glycine or myristoyl methylalanine.
  • the substances designated as rinse-off regulators serve primarily to control the consumption of the agents during use in such a way that the intended service life is maintained.
  • Preferred regulators are solid long-chain fatty acids, such as stearic acid, but also salts of such fatty acids, fatty acid ethanolamides, such as coconut fatty acid monoethanolamide, or solid polyethylene glycols, such as those having molecular weights between 10,000 and 50,000.
  • Ab Whitneyregulatoren required in the individual phases preferably the WC sticks contain up to 15 wt .-% of Ab Whitneyregulatoren, in particular between 5 and 12 wt .-%, each based on the individual phases.
  • the nature and amount of Ab Democraticregulato ⁇ Ren may be different in the individual phases of the inventive compositions.
  • the flushing regulators are preferably part of the common base mass and accordingly contained in all phases in the same manner and in equal parts. plasticizers
  • Plasticizers serve primarily to give the detergent compositions a plasticity suitable for the formation of the pieces. These are high-boiling organic substances which are liquid at the processing temperature. Suitable plasticizers are, for example, paraffin oils, 1,2-propylene glycol, silicone oils, phthalic esters, terpenes and dihydroabietic acid esters. Preference is given to using dihydro-abietic acid methyl ester, diethyl phthalate and dibutyl phthalate. Since the function of the plasticizers can in many cases be taken over by other constituents of the compositions, above all by the perfume oils, but also by nonionic surfactants or liquid acids, their presence is only necessary in a few cases. They are then used in amounts of up to 15 wt .-%.
  • the addition of inorganic salts can also influence the consistency and the rinsing behavior of the cleaning agent pieces, but this component also improves the homogeneity of the pieces in critical cases.
  • the salts can further enhance the cleaning action of the surfactants by means of electrolytes and as buffers, and they can, for example, the polyphosphates, act as hardness-binding agents.
  • the salts used are generally the alkali metal or ammonium salts of mineral acids, if appropriate in hydrated form. Preference is given to using the sodium salts of sulfuric acid, phosphoric acids, carbonic acid and hydrochloric acid, in particular sodium carbonate and sodium sulfate. They are used in amounts of up to 50% by weight, preferably in amounts of from 10 to 40% by weight, in the individual compositions, and here too the nature and amount in the individual component compositions can be different.
  • Fillers which may also be insoluble in water, such as cellulose powder, act, inter alia, as volume.
  • fillers are contained in amounts of not more than 10% by weight, in particular not more than 5% by weight.
  • Disinfectants are verwen ⁇ det in the detergent pieces according to the invention, if in addition to the toilet cleanliness and a germ-inhibiting treatment is intended sicht ⁇ .
  • the produced in the process according to the invention ten WC block in one or more of the phases preferably up to 10 wt .-%, and in particular between 0.5 and 5 wt .-% Qeweil based on the weight of the phases) of antimicrobial agents.
  • active ingredients can come from a variety of chemical classes, but when choosing, as well as in the selection of other active ingredients and ingredients, to ensure the compatibility with the other components of the respective masses. Examples of suitable classes of active ingredients are phenols, active chlorine-releasing substances and active oxygen-containing substances.
  • Complexing agents also called sequestering agents, are ingredients which are capable of complexing and inactivating metal ions in order to prevent their detrimental effects on the stability or appearance of the agents, for example clouding. On the one hand, it is important to complex the incompatible with numerous ingredients calcium and magnesium ions of water hardness. On the other hand, the complexation of the ions of heavy metals such as iron or copper delays the oxidative decomposition of the finished agents. In addition, the complexing agents support the makes ⁇ effect.
  • Suitable examples are the following according to INCI complexing agents: aminotrimethylene, phosphonic acid, beta-alanines diacetic acid, calcium disodium EDTA, citric acid, cyclodextrin, cyclohexanediamines tetraacetic acid, diammonium citrate, diammonium EDTA, diethylenetriamine pentamethylene phosphonic acid, dipotassium EDTA , Disodium Azacycloheptane Diphosphonate, Disodium EDTA, Disodium Pyrophosphate, EDTA, Etidronic Acid, Galactic Acid, Gluconic Acid, Glucuronic Acid, HEDTA, Hydroxypropyl Cyclodextrin, Methyl Cyclodextrin, Pentapotassium Triphosphate, Penta- sodium Aminotrimethylene Phosphonate, Pentasodium Ethylenediamine Tetramethylene Phosphonates, Pentasodium Pentetates, Pentas
  • acids or their water-soluble salts are, for example, sulfamic acid, phosphoric acid, citric acid, lactic acid, acetic acid, formic acid and gluconic acid.
  • Their proportion of the individual phases of the cleaning agent pieces according to the invention can be up to 30 wt .-% and is preferably between 0 and about 20 wt .-%, in particular between 5 and 15 wt .-%, based on the single phase.
  • the funds can further dyes (INCI Colorants) are added. Both water-soluble and oil-soluble dyes can be used here. Preferably, however, oil-soluble dyes are used, in particular when a masterbatch (a base material identical for all phases) is prepared in the process according to the invention, which is further processed to form the individual phases while admixing the phase-specific ingredients. Care must be taken in the selection of dyes to be compatible with the other ingredients in the same phase of the composition but also to ensure that they do not appear substantive to the ceramic surfaces of the toilet bowls.
  • a masterbatch a base material identical for all phases
  • Care must be taken in the selection of dyes to be compatible with the other ingredients in the same phase of the composition but also to ensure that they do not appear substantive to the ceramic surfaces of the toilet bowls.
  • Dyes preferably used are those selected from the group consisting of Solvent Yellow 114 (Disperse Yellow 54, Cl 47020;., For example, Macrolex Yellow G ® from Lanxess, previously Bayer), Solvent Yellow 174 (for example, Sudan Yellow 172 ® of BASF), Solvent Yellow 16 (CI 12700, eg Fat Yellow 3 G), Solvent Yellow 179 p ⁇ perse Yellow 201; for example, Macrolex ® Yellow 6G from Lanxess, previously Bayer), Solvent Green 3 (D & C Green No. 6, Cl 61565;., for example, Macrolex ® Green 5B from Lanxess, previously Bayer), Solvent Green 7 (Cl 59040;.
  • Solvent Yellow 114 Disperse Yellow 54, Cl 47020
  • Solvent Yellow 174 for example, Sudan Yellow 172 ® of BASF
  • Solvent Yellow 16 CI 12700, eg Fat Yellow 3 G
  • Solvent Yellow 179 p ⁇ perse Yellow 201 for example, Macrol
  • Solvent Blue 104 CI 61568; example, Sandoplast Blue 2B Clariant
  • Acid Blue 9 CI: 42090; example Iragon Blue ® 9 ABL ex Ciba Specialty Chemicals
  • Solvent Blue 35 Cl: 61554; for example, fat Blue B01
  • Particularly preferred are Solvent Yellow 114 (Macrolex ® Yellow G), Solvent Green 3 (Macrolex ® Green 5 B) and Solvent Blue 104 (Sandoplast Blue 2B).
  • Dyes are preferably added to the individual phases in amounts of not more than 1% by weight, in particular less than 0.1% by weight, particularly preferably less than 0.01% by weight. added, in each case based on the single phase.
  • fragrances in the funds are a particularly good perceptible advantage.
  • the choice of suitable fragrances is essentially limited only by possible interactions with other constituents of the individual phases of the detergent pieces.
  • the total content of fragrances in the individual phases is preferably not more than 10% by weight; In particular, it is between 1 and 8% by weight, based on the individual phase.
  • the WC sticks may contain further additives customary in lump-shaped toilet cleaners which round off the property pattern of the cleaning agents. Examples include preservatives, corrosion inhibitors or enzymes.
  • the polymer used here is preferably selected from the group comprising polyvinyl alcohol (PVAL), acetalized polyvinyl alcohol, polyvinylpyrrolidone, polyethylene oxide, gelatin, cellulose, starch and derivatives of the abovementioned substances, in particular derivatives of polyvinyl alcohol (PVAL), acetalated polyvinyl alcohol, cellulose and / or mixtures of the aforementioned polymers, with PVAL and partially hydrolyzed polyvinyl acetate being particularly preferred, in particular PVAL.
  • PVAL polyvinyl alcohol
  • acetalized polyvinyl alcohol polyvinylpyrrolidone
  • polyethylene oxide gelatin
  • gelatin cellulose
  • starch starch
  • derivatives of polyvinyl alcohol (PVAL) acetalated polyvinyl alcohol
  • PVAL and partially hydrolyzed polyvinyl acetate being particularly preferred, in particular PVAL.
  • Such polyvinyl alcohols are commercially available, for example under theress ⁇ Mowiol
  • polyvinyl alcohols are, for example Mowiol ® 3-83, Mowiol ® 4-88, Mowiol ® 5-88, Mowiol ® 8-88 and L648, L734, Mowiflex LPTC 221 ex Clariant / KSE and under the trademark VINEX® vertriebe ⁇ NEN compounds of Texas polymer, for example Vinex 2034.
  • More geeig ⁇ designated polyvinyl alcohols are ELVANOL ® 51-05, 52-22, 50-42, 85-82, 75-15, T-25, T -66, 90- 50 (trademark of Du Pont), ALCOTEX ® 72.5, 78, B72, F80 / 40, F88 / 4, F88 / 26, F88 / 40, F88 / 47 (trademark of Harlow Chemical Co.) and Gohsenol ® NK-05, A-300, AH-22, C-500, GH-20, GL-03, GM-14L, KA-20, KA-500, KH-20, KP-06, N-300, NH -26, NM11Q, KZ-06 (trademark of Nippon Gohsei KK). Also the manufacturer Aquafilm Ltd. and MonoSol offer suitable water-soluble films primarily from PVAL, for example M-3030 from MonoSol LLC.
  • the multi-phase WC cleaning agent piece produced in the process according to the invention is introduced into a suitable container in order to be able to fasten it to the edge of the basin.
  • a suitable container for this purpose, known from the prior art toilet bowls are suitable.
  • the stick should be as visible as possible, so that advantageously a transparent basket is used.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

L'invention concerne un procédé pour produire un bloc de nettoyage de W.-C., solide, à phases multiples, constitué d'au moins deux phases. Ce procédé est caractérisé en ce qu'il comprend les étapes suivantes: mélange des composants pour chaque phase individuelle; extrusion des boudins individuels pour les différentes phases; découpage des boudins à la longueur requise pour les blocs individuels; regroupement des blocs pour les différentes phases et fixation dans un film transparent hydrosoluble. On obtient ainsi des blocs de nettoyage de W.-C. à plusieurs phases dont la production ne requiert qu'une seule extrudeuse. Les blocs peuvent être vendus sous forme d'un produit associé à un contenant transparent.
PCT/EP2005/007700 2004-07-22 2005-07-15 Procede pour produire des blocs a phases multiples pour le nettoyage des w.-c. WO2006010491A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP05766604A EP1769061A1 (fr) 2004-07-22 2005-07-17 Procede pour produire des blocs a phases multiples pour le nettoyage des w.-c.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004035655.6 2004-07-22
DE200410035655 DE102004035655A1 (de) 2004-07-22 2004-07-22 Verfahren zur Herstellung von Mehrphasen-Sticks für die WC-Reinigung

Publications (2)

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WO2006010491A1 true WO2006010491A1 (fr) 2006-02-02
WO2006010491A8 WO2006010491A8 (fr) 2006-05-04

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PCT/EP2005/007700 WO2006010491A1 (fr) 2004-07-22 2005-07-15 Procede pour produire des blocs a phases multiples pour le nettoyage des w.-c.

Country Status (4)

Country Link
EP (1) EP1769061A1 (fr)
DE (1) DE102004035655A1 (fr)
RU (1) RU2007106495A (fr)
WO (1) WO2006010491A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1978080A1 (fr) * 2007-03-29 2008-10-08 Bolton Manitoba SpA Composition hygiénisante adhésive pour le nettoyage et/ou la désinfection et/ou parfumer des installations sanitaires
JP2010045059A (ja) * 2008-04-21 2010-02-25 Agency For Science Technology & Research 基板上の強誘電性ポリ（ビニリデンフルオリド）膜およびその形成方法
JP2011520908A (ja) * 2008-05-14 2011-07-21 アムジエン・インコーポレーテツド 癌の治療のためのｖｅｇｆ（ｒ）阻害剤および肝細胞増殖因子（ｃ−ｍｅｔ）阻害剤との組合せ
DE102010030021A1 (de) 2010-06-14 2011-12-15 Henkel Ag & Co. Kgaa Maschinelles Reinigungsverfahren

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005061726A1 (de) * 2005-12-21 2007-07-05 Henkel Kgaa Wasch-, Spül- oder Reinigungsmittel mit vertikaler Phasengrenze
DE102007033077A1 (de) * 2007-07-13 2009-01-15 Buck- Chemie Gmbh Stückförmiges Reinigungsmittel für den Sanitärbereich mit einem Werbeträger
DE102009001841A1 (de) * 2009-03-25 2010-09-30 Henkel Ag & Co. Kgaa System aus Reinigungsmittel und Abgabevorrichtung
DE102012215615A1 (de) * 2012-04-04 2013-10-10 Henkel Ag & Co. Kgaa Streifenförmiges WC-Reinigungsprodukt
DE102015109697A1 (de) * 2015-06-17 2016-12-22 Buck-Chemie Gmbh Stückförmiges Reinigungsmittel für den WC-Bereich

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DE2030060A1 (de) * 1969-06-18 1971-02-04 Purodor S A Laboratoires de Chimie Appliquee, Paris Produkte zur Wartung, Desodorierung und Reinigung von sanitären Anlagen und Verfahren zu deren Herstellung
GB2332682A (en) * 1997-12-23 1999-06-30 Jeyes Group Ltd Lavatory cleansing blocks
WO2000023558A1 (fr) * 1998-10-19 2000-04-27 Jeyes Group Limited Bloc de nettoyage de toilettes
EP0999263A1 (fr) * 1998-11-05 2000-05-10 Buck-Chemie GmbH & Co. Compositions de nettoyage pour toilettes sous forme de pains
US20020035049A1 (en) * 1997-02-20 2002-03-21 Susheel Kumar Suri Toilet cleaning block

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CA1182371A (fr) * 1980-12-18 1985-02-12 Jeyes Group Limited Pain sanitaire pour reservoir de chasse

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Publication number Priority date Publication date Assignee Title
DE2030060A1 (de) * 1969-06-18 1971-02-04 Purodor S A Laboratoires de Chimie Appliquee, Paris Produkte zur Wartung, Desodorierung und Reinigung von sanitären Anlagen und Verfahren zu deren Herstellung
US20020035049A1 (en) * 1997-02-20 2002-03-21 Susheel Kumar Suri Toilet cleaning block
GB2332682A (en) * 1997-12-23 1999-06-30 Jeyes Group Ltd Lavatory cleansing blocks
WO2000023558A1 (fr) * 1998-10-19 2000-04-27 Jeyes Group Limited Bloc de nettoyage de toilettes
EP0999263A1 (fr) * 1998-11-05 2000-05-10 Buck-Chemie GmbH & Co. Compositions de nettoyage pour toilettes sous forme de pains

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1978080A1 (fr) * 2007-03-29 2008-10-08 Bolton Manitoba SpA Composition hygiénisante adhésive pour le nettoyage et/ou la désinfection et/ou parfumer des installations sanitaires
JP2010045059A (ja) * 2008-04-21 2010-02-25 Agency For Science Technology & Research 基板上の強誘電性ポリ（ビニリデンフルオリド）膜およびその形成方法
JP2011520908A (ja) * 2008-05-14 2011-07-21 アムジエン・インコーポレーテツド 癌の治療のためのｖｅｇｆ（ｒ）阻害剤および肝細胞増殖因子（ｃ−ｍｅｔ）阻害剤との組合せ
DE102010030021A1 (de) 2010-06-14 2011-12-15 Henkel Ag & Co. Kgaa Maschinelles Reinigungsverfahren
WO2011157630A1 (fr) 2010-06-14 2011-12-22 Henkel Ag & Co. Kgaa Procédé de lavage en machine

Also Published As

Publication number Publication date
DE102004035655A1 (de) 2006-02-16
RU2007106495A (ru) 2008-08-27
EP1769061A1 (fr) 2007-04-04
WO2006010491A8 (fr) 2006-05-04

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