WO2014076010A1 - Produit détergent et nettoyant contenant des alkylpolypentosides - Google Patents

Produit détergent et nettoyant contenant des alkylpolypentosides Download PDF

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Publication number
WO2014076010A1
WO2014076010A1 PCT/EP2013/073397 EP2013073397W WO2014076010A1 WO 2014076010 A1 WO2014076010 A1 WO 2014076010A1 EP 2013073397 W EP2013073397 W EP 2013073397W WO 2014076010 A1 WO2014076010 A1 WO 2014076010A1
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alkyl
cleaning agent
washing
agent according
acid
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PCT/EP2013/073397
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German (de)
English (en)
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Michael Dreja
Stefan Karsten
Inga Kerstin Vockenroth
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Henkel Ag & Co. Kgaa
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Publication of WO2014076010A1 publication Critical patent/WO2014076010A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives

Definitions

  • the present invention relates to a laundry detergent or cleaning composition, in particular to an aqueous hard surface cleaner containing a surfactant mixture containing at least one nonionic alkyl polyglycoside and at least one non-glycosylated surfactant.
  • the surfactants are usually both those which are obtained from renewable raw materials, as well as petrochemical surfactants.
  • one goal is to increase the use of renewable resources, i. to reduce the proportion of surfactants derived from petrochemicals in favor of surfactants based on renewable raw materials. This is both in view of the expected crude oil shortage and due to the
  • renewable raw materials are used whose raw material base remains unused as waste, such as wheat straw or grass. It is therefore an object of this invention to provide a washing or cleaning composition containing renewable resource surfactants that do not compete with food production, while having good cleaning and foaming performance.
  • washing or cleaning agent which contains a surfactant mixture which contains at least one nonionic alkylpolyglycoside which comprises at least one alkylpolypentoside and at least one non-glycosylated surfactant.
  • the present invention relates to a laundry or cleaning composition
  • a laundry or cleaning composition comprising a surfactant mixture containing at least one nonionic alkylpolyglycoside and at least one non-glycosylated surfactant, wherein the at least one nonionic alkylpolyglycoside comprises at least one nonionic alkylpolypentoside.
  • the washing or cleaning agent may be an aqueous hard surface cleaner such as e.g. one
  • Dishwashing detergent preferably a hand dishwashing detergent, or even a detergent.
  • the non-glycosylated surfactant does not contain a sugar component, i. in particular no mono-, di-, oligo-, polysaccharides or derivatives thereof and is, in various embodiments of the invention, selected from soaps, alkyl alkoxylates, betaines, alkyl ether sulfates, alkyl sulfates, linear alkyl benzene sulfonates, secondary alkane sulfonates, olefin sulfonates,
  • compositions according to the invention usually comprise the surfactant mixture in an amount of from 0.1 to 40% by weight, preferably from 1 to 35% by weight, particularly preferably from 2 to 30% by weight.
  • the invention relates to the use of the washing or cleaning agents according to the invention for cleaning surfaces or textiles, in particular for cleaning hard surfaces.
  • the invention relates to a method for cleaning surfaces or textiles, the method comprising the step of contacting the surface or textiles with the detergent composition of the invention.
  • the indication CAS means that the following sequence of numbers is a name of the Chemical Abstracts Service.
  • fatty acids or fatty alcohols or their derivatives - unless otherwise stated - representative of branched or unbranched carboxylic acids or alcohols or their derivatives having preferably 6 to 22 carbon atoms.
  • the former are particularly preferred because of their vegetable base as based on renewable raw materials for ecological reasons.
  • alkaline earth metals are referred to below as counterions for monovalent anions, this means that the alkaline earth metal is present only in half - as sufficient to charge balance - amount of substance as the anion.
  • the alkyl polyglycosides are nonionic sugar surfactants which preferably satisfy the general formula R 0 (AO) a [G] x in which R is a linear or branched, saturated or unsaturated alkyl radical having 6 to 22, preferably 6 to 18, in particular 8 to 16, particularly preferably 8 to 14 carbon atoms, [G] for a glycosidically linked sugar residue and x for a number from 1 to 10 and AO for an alkyleneoxy group, for.
  • R is a linear or branched, saturated or unsaturated alkyl radical having 6 to 22, preferably 6 to 18, in particular 8 to 16, particularly preferably 8 to 14 carbon atoms
  • [G] for a glycosidically linked sugar residue and x for a number from 1 to 10
  • AO for an alkyleneoxy group, for.
  • the group (AO) a may also contain different alkyleneoxy, z.
  • Alkyl radicals R of APG to linear radicals having the specified number of carbon atoms.
  • R When R is an unsaturated alkyl group, it may be 1 to 4 times, preferably 1 to 2 times, more preferably 1-time ethylenically unsaturated.
  • APG are nonionic surfactants and are known substances that can be obtained by the relevant methods of preparative organic chemistry.
  • they are formed by an acid-catalyzed reaction between a saccharide, including a mono-, di-, Oligo- or polysaccharide, and a fatty alcohol, which can be obtained for example from vegetable raw materials, in particular palm kernel oil, coconut oil and rapeseed oil, representable.
  • the APGs used in the teaching of the invention include alkyl polypentosides (APP), i. Alkylpolyglycosides containing one or more pentose radicals (sugar with 5
  • the alkyl polyglycosides are alkyl polypentosides of the formula R 0 (AO) a [G] x , as defined above, but at least one G is a pentose residue. In one embodiment, all G residues of the molecule are pentose residues, ie the sugar component consists exclusively of pentose residues.
  • Pentose radicals include, but are not limited to xylose, arabinose, ribose, xylulose, and ribulose. Preference is given to xylose and arabinose, in particular D-xylose and L-arabinose. Such pentoses are available from the hemicellulose resulting from the hydrolysis of biomass, grass and straw, especially rye, oat, barley and wheat fibers and straw. Hemicellulose is a mixture of plant biomass
  • hemicellulose also contains hexoses (6-carbon sugars) such as glucose, mannose and galactose, as well as sugar derivatives such as e.g.
  • Uronic acids including but not limited to hexuronic acids such as glucuronic acid,
  • Methylglucuronic acid and galacturonic acid and deoxy sugars, such as. B. rhamnose.
  • the monosaccharides mentioned in the context of the invention can be present in the D or L form, but in each case the naturally more frequently occurring isomer is preferred.
  • xylose and arabinose or their homo- and heteropolymers can be obtained by glycosylation analogous to the preparation of known APG Alkylpolypentoside.
  • the hemicellulose pentoses are more reactive than pure glucose in the known process, making the process more sustainable and energy efficient at 120 ° C.
  • the degree of polymerization obtained is better controlled, resulting in APPs with higher lipophilicity. For that reason alone is the use of
  • DP degree degree of oligomerization or polymerization
  • Alkyl glycosides used with a mean degree of oligomerization x of 1, 1 to 3.0 those alkyl glycosides whose degree of oligomerization is between 1.0 and 2.0, or less than 1.7, and in particular between 1.2 and 1.6, are preferred.
  • the glycosidic sugar xylose or arabinose is preferably used.
  • the alkylpolypentosides of the invention may also contain in one molecule several different pentose residues, for example xylose and arabinose, or also pentoses in combination with hexoses. However, it is preferred that the alkylpolypentosides of the invention contain only pentosereste.
  • the alkyl or alkenyl radical R can be derived from primary alcohols having 8 to 18, preferably 8 to 14 carbon atoms. Typical examples are caproic alcohol, caprylic alcohol,
  • Elaidyl alcohol petroselinyl alcohol, arachidyl alcohol, gadoleyl alcohol, behenyl alcohol,
  • Preferred alkylpolyglycosides are, for example, C 8 -alkyl-alkylpolyloside or -arabinoside with a DP degree of 1, 1 to 3.
  • this comprises at least one
  • Alkyl polyglycoside at least one, for example one, two, three or more alkyl polypentosides, in particular C 8 . 10 alkyl polypentosides, for example Alkylpolyxyloside or Alkylpolyarabinoside, with a DP between 1 and 2.
  • the at least one alkyl polypentosides for example Alkylpolyxyloside or Alkylpolyarabinoside, with a DP between 1 and 2.
  • Alkylpolyglycoside substantially or wholly thereof.
  • the at least one alkylpolyglycoside may further contain one, for example one, two, three or more, alkylpolyglucosides, in particular C 8 -alkyl-alkylpolyglucosides having a DP between 1 and 2.
  • the at least one alkylpolyglycoside may, for example, be a mixture of C 8 . 10 alkyl polypentosides and alkyl polyglucosides each having a DP between 1 and 2.
  • Alkyl polyglycosides which can be used in the context of the present invention are commercially available.
  • An exemplary alkyl polyglcoside mixture that can be used in the present invention is Radia® Easysurf 6781 (Wheatoleo, Oleon NV, Ertvelde, BE).
  • Radia® Easysurf 6505 or Radia® Easysurf 6726 can also be used.
  • the washing or cleaning agent according to the invention contains 0, 1 to 50 wt .-%, 0, 1 to 20% by weight, 0, 1 to 15 wt .-%, 0, 1 to 10 wt .-%, 0.1 to 5 wt .-%, 0.1 to 3 wt .-% or 0, 1 to 2 wt .-% of one or more alkyl polyglycosides.
  • the at least one alkylpolyglycoside may in various embodiments contain at least 30% by weight, preferably at least 50% by weight, more preferably at least 70% by weight, most preferably at least 80 or 90% by weight of alkylpolypentosides, based on the total amount of alkyl polyglycoside , In one embodiment, the at least one alkyl polyglycoside consists exclusively of one or more alkyl polypentosides.
  • non-glycosylated surfactants used in the present invention may be selected from the group of soaps, alkyl alkoxylates (fatty alcohol alkoxylates, FAEO), betaines, alkyl ether sulfates
  • Non-glycosylated as used herein means that the corresponding surfactant does not have a sugar residue or derivative thereof, such as sugar acid,
  • Glykosamin or similar contains.
  • Preferred non-glycosylated surfactants are anionic surfactants, in particular sulfates or sulfonates, such as those mentioned above. Particularly preferred
  • Alkyl ether sulfates (fatty alcohol ether sulfates), alkyl sulfates (fatty alcohol sulfates) and linear
  • the surfactant mixture contains at least one anionic surfactant, for example, an alkyl sulfate or alkyl ether sulfate, and another nonionic surfactant, such as an alkyl alkoxylate.
  • anionic surfactant for example, an alkyl sulfate or alkyl ether sulfate
  • another nonionic surfactant such as an alkyl alkoxylate
  • Alkyl ether sulfates (fatty alcohol ether sulfates, INCI alkyl ether sulfates) are products of
  • alkoxylated alcohols the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, in the context of the present invention preferably with longer-chain alcohols, ie with aliphatic straight-chain or mono- or multi-branched, acyclic or cyclic, saturated or mono- or polysubstituted unsaturated, preferably straight-chain, acyclic, saturated, alcohols having 6 to 22, preferably 8 to 20, particularly preferably 10 to 18 and in particular 12 to 14 carbon atoms.
  • Another embodiment of the alkoxylation is the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide.
  • low ethoxylated fatty alcohols 0.5 to 4 moles EO, preferably 1 to 2.5 moles EO
  • a concrete example is C 1 2 -i4-fatty alcohol ether sulfate with 2 EO.
  • alkyl ether sulfates are usually used as sodium salts, but may also be present as other alkali metal or alkaline earth metal salts, for example magnesium salts, and in the form of ammonium or mono-, di-, tri- or tetraalkylammonium salts.
  • Alkyl sulfates are esters of sulfuric acid with longer-chain alcohols, ie with aliphatic straight-chain or mono- or poly-branched, acyclic or cyclic, saturated or mono- or polyunsaturated, preferably straight-chain, acyclic, saturated, alcohols having 6 to 22, preferably 8 to 20, particularly preferably 10 to 18 and in particular 12 to 14 carbon atoms.
  • the alkyl sulfates of the invention may be, for example, sulfates of the formula CH 3 - (CH 2 ) n -O-SO 3 - , where n is 7 to 17.
  • Preferred fatty alcohol sulfates are C 8 -C 4 fatty alcohol sulfates, in particular C 10 -C 12 fatty alcohol sulfates.
  • the alkyl sulfates are usually used as sodium or potassium salts, but may also be present as other alkali metal or alkaline earth metal salts, for example magnesium salts, and in the form of ammonium or mono-, di-, tri- or tetraalkylammonium salts.
  • the inventive composition contains in various embodiments, 0.1 to 50 wt .-%, 0.1 to 25 wt .-%, 0, 1 to 15 wt .-%, 0.1 to 10 wt .-%, 0.1 to 5 wt .-%, 0, 1 to 3 wt .-% or 0.1 to 2 wt .-% of one or more alkyl ether or alkyl sulfates.
  • Linear alkyl benzene sulfonates are benzene derivatives substituted with a sulfonic acid group and a linear alkyl radical. Sulfonic acid and alkyl may be ortho, meta or para to each other. In general, they are compounds of the formula CH 3 - (CH 2 ) n -CH (C 6 H 4 -SO 3 (CH 2 ) m -H, where n and m are each 0, 1, 2, 3, 4, 5 , 6, 7, 8, 9, 10, 11, 12, 13, 14, 15 or 16 and n + m is 6 to 16.
  • n is 8-12, more preferably 10
  • Alkylbenzenesulfonates are usually used as sodium or potassium salts, but may also be present as other alkali or alkaline earth metal salts, for example magnesium salts, and in the form of ammonium or mono-, di-, tri- or tetraalkylammonium salts. Also possible is the use in the form of its corresponding acid, e.g.
  • Soaps are potassium or sodium salts of fatty acids, ie aliphatic straight-chain or mono- or polysubstituted, acyclic or cyclic, saturated or mono- or polyunsaturated, preferably straight-chain, acyclic, saturated, monocarboxylic acids having 6 to 22, preferably 8 to 20, especially preferably 10 to 18 and in particular 12 to 14 Carbon atoms. In one embodiment, they have the general formula CH 3 - (CH 2) n -COO ⁇ M +, wherein n is 7 to 20 and M is Na or K.
  • Secondary alkyl sulfonates are compounds of the general formula CH 3 - (CH 2 ) n -CH (SO 3 - ) - (CH 2 ) m -CH 3 , where n and m are each independently 0, 1, 2, 3, 4, 5 , 6, 7, 8, 9, 10, 11, 12, 13, 14, 15 or 16 and n + m is 5 to 15.
  • the secondary alkyl sulfonates are usually used as sodium or potassium salts, but can also be used as other alkali metal or potassium salts
  • Alkaline earth metal salts for example magnesium salts, and be present in the form of ammonium or mono-, di-, tri- or tetraalkylammonium salts. Also possible is the use in the form of its corresponding acid.
  • Olef insu Ifonate are sulfonic acid-substituted long-chain alkenes, ie aliphatic straight-chain or mono- or polysubstituted, acyclic or cyclic, mono- or polysubstituted, usually 1-4-fold, unsaturated, preferably straight-chain, acyclic, alkenes having 6 to 22, preferably 8 to 20, more preferably 10 to 18 and especially 12 to 14 carbon atoms.
  • the olefinic fluorides are preferably alpha-olefin sulfonates.
  • Methyl ester sulfonates are alpha sulfomethyl ester derivatives of fatty acids, i. aliphatic straight-chain or mono- or polysubstituted, acyclic or cyclic, saturated or mono- or polyunsaturated, preferably straight-chain, acyclic, saturated,
  • Monocarboxylic acids having 6 to 22, preferably 8 to 20, particularly preferably 10 to 18 and in particular 12 to 14 carbon atoms. These satisfy, for example, the formula CH 3 - (CH 2 ) n --CH (S0 3 - ) --COOCH 3 , where n is 9 to 15.
  • alkyl alkoxylates fatty alcohol alkoxylates
  • fatty alcohol alkoxylates fatty alcohol alkoxylates
  • alkyl alkoxylates fatty alcohol alkoxylates
  • C 8 -C 18 - alcohol polyglycol ethers ie ethoxylated and / or propoxylated long-chain alcohols, ie aliphatic straight-chain or mono- or multi-branched, acyclic or cyclic, saturated or mono- or polyunsaturated, preferably straight-chain, acyclic, saturated , Alcohols having 6 to 22, preferably 8 to 20, particularly preferably 10 to 18 and in particular 12 to 14 carbon atoms and 2 to 15 ethylene oxide (EO) and / or propylene oxide units (PO).
  • EO ethylene oxide
  • PO propylene oxide units
  • C 8 8 fatty alcohol ethoxylates used -i having 2 to 10 EO in particular C 2 _i4 fatty alcohol ethoxylates having 2 to 8 EO, for example C 1 2 -14 fatty alcohol ethoxylate with 7 EO.
  • Betaine fatty alcohol ethoxylates used -i having 2 to 10 EO, in particular C 2 _i4 fatty alcohol ethoxylates having 2 to 8 EO, for example C 1 2 -14 fatty alcohol ethoxylate with 7 EO.
  • Suitable betaines are the alkylbetaines, the alkylamidobetaines, the imidazolinium betaines, the sulfobetaines (INCI Sultaines) and the phosphobetaines and mixtures thereof. They preferably satisfy formula I,
  • n is a number from 1 to 10, preferably 2 to 5, in particular 3, x 0 or 1, preferably 1, R 2 , R 3 independently of one another Ci_ 4 -Alkylrest, optionally hydroxy-substituted such ,
  • m is a number from 1 to 4, in particular 1, 2 or 3
  • y is 0 or 1
  • Y is COO " , S0 3 ⁇ , OPO (OR 5 ) 0 " or P (0) (oR 5) 0 ", wherein R 5 is a hydrogen atom H or a d-4 alkyl.
  • Preferred betaines are the alkylbetaines of the formula (Ia), the alkylamidobetaines of the formula (Ib), the sulfobetaines of the formula (Ic) and the amidosulfobetaines of the formula (Id),
  • R is -N + (CH 3 ) 2 -CH 2 COO ⁇
  • R is -CO-NH- (CH 2 ) 3 -N + (CH 3 ) 2 -CH 2 COO -
  • R is -N + (CH 3 ) 2 -CH 2 CH (OH) CH 2 S0 3 "
  • R is -CO-NH- (CH 2 ) 3 -N + (CH 3 ) 2 -CH 2 CH (OH) CH 2 S0 3 " in which R has the same meaning as in formula I.
  • betaines are the carbo-betaines, in particular the carbo-betaines of the formula (Ia) and (Ib), most preferably the alkylamido-betaines of the formula (Ib).
  • betaines and sulfobetaines are the following compounds designated as INCI: almondamidopropyl betaines, apricotamidopropyl betaines, avocadamidopropyl betaines, babassuamidopropyl betaines, behenamidopropyl betaines, behenyl betaines, betaines, canolamidopropyl betaines, caprylic / capramidopropyl betaines, carnitines, cetyl betaines,
  • Cocamidoethyl betaines cocamidopropyl betaines, cocamidopropyl hydroxysultaines, coco-betaines, coco-hydroxysultaines, coco / oleamidopropyl betaines, coco-sultaines, decyl betaines,
  • Hydroxysultaines Hydrogenated Tallow Betaine, Isostearamidopropyl Betaine, Lauramidopropyl Betaine, Lauryl Betaine, Lauryl Hydroxysultaine, Lauryl Sultaine, Milkamidopropyl Betaine, Minkamidopropyl Betaine, Myristamidopropyl Betaine, Myristyl Betaine, Oleamidopropyl Betaine, Oleamidopropyl Hydroxysultaine, Oleyl Betaine, Olivamidopropyl Betaine, Palmamidopropyl Betaine, Palmitamidopropyl Betaine, Palmitoyl Carnitine, Palm Kernel Amidopropyl Betaine, Polytetrafluoroethylene Acetoxypropyl Betaine, Ricinol Amidopropyl Betaine, Sesamidopropyl Betaine, Soyamidopropyl Betaine, Stearamidopropyl Betaine, Stearyl Betaine, Tallowamidopropyl
  • alkylamidoalkylamines Another class of non-glycosylated surfactants are the alkylamidoalkylamines.
  • the alkylamidoalkylamines (INCI alkylamido alkylamines) are amphoteric surfactants of the formula (II)
  • - CH 2 -Z-OM (II) in R is a saturated or unsaturated C 6-22 -alkyl radical, preferably C 8 -18 alkyl group, more preferably a saturated Ci 0 -16 alkyl group, for example a saturated
  • R 2 is a hydrogen atom H or a preferably H
  • i is a number from 1 to 10, preferably 2 to 5, in particular 2 or 3,
  • R 3 is a hydrogen atom H or CH 2 COOM (to M su),
  • j is a number from 1 to 4, preferably 1 or 2, in particular 1,
  • k is a number from 0 to 4, preferably 0 or 1
  • Z is CO, S0 2, OPO (OR 4) or P (0) (OR 4) wherein R 4 is a CI_ 4 alkyl or M (see below), and
  • M is a hydrogen, an alkali metal, an alkaline earth metal or a protonated
  • Alkanolamine e.g. protonated mono-, di- or triethanolamine.
  • Preferred representatives satisfy the formulas IIa to lld,
  • R is -CO-NH- (CH 2 ) 2 -N (R 3 ) -CH 2 CH 2 O-CH 2 -COOM (IIa) R-CO-NH- (CH 2 ) 2 -N (R 3 ) -CH 2 CH 2 0-CH 2 CH 2 -COOM (IIb) R-CO-NH- (CH 2) 2 -N (R 3) -CH 2 CH 2 0-CH 2 CH (OH) CH 2 -S0 3 M (llc) R -CO-NH- (CH 2) 2 -N (R 3) -CH 2 CH 2 0-CH 2 CH (OH) CH 2 -OP0 3 HM (IId) in which R, R 3 and M have the same meaning as in formula (II).
  • alkylamidoalkylamines are the following INCI named compounds: Cocoamphodipropionic Acid, Cocobetainamido Amphopropionate, DEA-Cocoamphodipropionate, Disodium Caproamphodiacetate, Disodium Caproamphodipropionate, Disodium
  • Cocoamphocarboxyethylhydroxypropylsulfonates Disodium Cocoamphodiacetate, Disodium Cocoamphodipropionate, Disodium Isostearoamphodiacetate, Disodium
  • Cocoamphoacetate Sodium Cocoamphohydroxypropylsulfonate, Sodium Cocoamphopropionate, Sodium Cornamphopropionate, Sodium Isostearoamphoacetate, Sodium
  • Lauroamphohydroxypropylsulfonates Sodium Lauroampho PG-Acetate Phosphates, Sodium Lauroamphopropionate, Sodium Myristoamphoacetate, Sodium Oleoamphoacetate, Sodium Oleoamphohydroxypropylsulfonate, Sodium Oleoamphopropionate, Sodium
  • the alkylamidoalkylamine is preferably selected from the group comprising disodium cocoamphodiacetates, disodium lauroamphodiacetates, sodium stearoamphoacetates, sodium cocoamphoacetates, disodium cocoamphodipropionates, disodium stearoamphodiacetates, and mixtures thereof, and in particular preferably disodium
  • Cocoamphodiacetate sodium cocoamphodiacetate
  • non-glycosylated surfactants which can be used according to the invention are sulfosuccinic mono- and di-C 8 -C 8 -alkyl esters. Furthermore, sulfonated C 8 -C- 8 - fatty acids, especially dodecyl benzene sulfonate, C 8 -C 2 2-Carbonklareamidethersulfate, C 8 -C 8 - Alkylpolyglykolethercarboxylate, C 8 -C 18 -N-acyl taurides, N-acyl amino acid derivatives such as N-acyl aspartates or N-acyl glutamates, C8 18 -N-sarcosinates and C 8 -C 18 -alkyl isothionates or mixtures thereof.
  • anionic surfactants are preferably used as sodium salts, but can also be used as other alkali or alkaline earth metal salts, for example
  • Magnesium salts as well as in the form of ammonium or mono-, di-, tri- or
  • Dodecylbenzenesulfonic examples include sodium cocoalkyl sulfate, sodium sec-alkanesulfonate having about 15 carbon atoms and
  • nonionic surfactants are C 8 -C 8 -carboxylic polyglycol esters having 2 to 15 EO, for example tallow fatty acid + 6-EO esters, ethoxylated fatty acid amides having 12 to 18 C atoms in the fatty acid part and 2 to 8 EO and long-chain amine oxides having 14 to 20 To mention carbon atoms.
  • examples of such surfactants are oleyl cetyl alcohol with 5 EO, nonylphenol with 10 EO,
  • the agent according to the invention may also contain cationic surfactants.
  • Suitable cationic surfactants are i.a. the quaternary ammonium compounds of the formula
  • R VI (R VI ) (R vii ) (R viii ) (R ix ) N + X "
  • R vi to R ix for four identical or different, in particular two long and two short-chain, alkyl radicals and X " for an anion , in particular a halide ion, for example, didecyl-dimethyl-ammonium chloride, alkyl-benzyl-didecyl-ammonium chloride and mixtures thereof.
  • compositions of the invention may also contain other ingredients which depend on the formulation and the intended application.
  • additional ingredients include, but are not limited to, water, organic solvents, hydrotropes, salts, additives, for example, to improve drainage
  • Drying behavior or for adjusting the viscosity, thickening agents, UV stabilizers, perfume, pearlescing agents ICI Opacifying Agents, for example glycol distearate, eg Cutina® AGS from Cognis, or mixtures containing same, eg the Euperlane®) Cognis
  • dyes for example glycol distearate, eg Cutina® AGS from Cognis, or mixtures containing same, eg the Euperlane®) Cognis
  • dyes for example glycol distearate, eg Cutina® AGS from Cognis, or mixtures containing same, eg the Euperlane®) Cognis
  • dyes complexing agents
  • bleaching agents builders
  • corrosion inhibitors preservatives
  • preservatives for example isothiazolinone or the technical 2-bromo-2-nitropropane-1,3-diol, also referred to as bronopol, (CAS 52-51-7) which is commercially available, for
  • soybean oil, etc. plant extracts such.
  • aloe vera azulene, witch hazel extracts, algae extracts, etc.
  • allantoin A. H. A. complexes or cationic polymers, such as known as Polyquaternium polymeric quaternary ammonium compounds), and mixtures thereof.
  • detergents and cleaners of the invention may also contain:
  • Perfume boosters fillers, rinse-off regulators, microorganisms, biofilm removal agents, limescale inhibiting agents, soil adhesion reducing agents, processability improving agents, stickiness reducing agents, and mixtures thereof.
  • the agent of the invention is an aqueous hard surface cleaner.
  • it may additionally contain up to 12 Wt .-%, preferably 2 to 8 wt .-% ethanol. These are particularly preferably ethanol obtained from renewable raw materials (so-called bioethanol).
  • composition of the invention may contain one or more other water-soluble organic solvents, usually in an amount of 0 to 15 wt .-%, preferably 1 to 12 wt .-%, in particular 3 to 8 wt .-%.
  • ethanol and any further solvents which may be present are used in the context of the teaching according to the invention as needed in particular as a hydrotrope and viscosity regulator. They work solubilizing in particular for surfactants and electrolyte as well as perfume and dye and thus contribute to their incorporation, prevent the formation of liquid-crystalline phases and contribute to the formation of clear products.
  • the viscosity of the agent according to the invention decreases with increasing amount of solvent. Finally, as the amount of solvent increases, the clouding and clearing point of the composition according to the invention decreases.
  • Suitable solvents are for example, saturated or unsaturated, preferably saturated, branched or unbranched C-i_ 2 o-hydrocarbons, preferably C 2 _ 15 - hydrocarbons, with at least one hydroxy group and optionally one or more ether functions COC, ie the carbon atom chain interrupting oxygen atoms.
  • Preferred solvents are the - optionally etherified with a unilaterally 6 alkanol CI_ - C 2 -6-alkylene glycols and poly-C 2 -3-alkylene glycol ethers with an average of 1 to 9 identical or different, preferably identical, alkylene glycol per molecule as well as the CI_ 6 - Alcohols, preferably n-propanol or iso-propanol.
  • Exemplary solvents are the following according to INCI compounds: buteth-3, butoxy diglycol, butoxyethanol, butoxyisopropanol, butoxypropanol, n-butyl alcohol, t-butyl alcohol, butylene glycol, butyloctanol, diethylene glycol, dimethoxydiglycol, dimethyl ether, dipropylene glycol, ethoxydiglycol, Ethoxyethanol, ethyl hexanediol, glycol, hexanediol, 1, 2,6-hexanetriol, hexyl alcohol, hexylenes glycol, isobutoxypropanol, isopentyldiol, isopropyl alcohol (isopropanol), 3-methoxybutanol, methoxydiglycol, methoxyethanol, methoxyisopropanol, methoxymethylbutanol, methoxy PEG- 10, methylal, methyl alcohol,
  • longer-chain polyalkylene glycols in particular polypropylene glycols. Particularly preferred are about the PPG-400 or the PPG-450, but also Polypropylene glycols with larger chain lengths can be used in the context of this invention.
  • the solvent is selected from the group comprising methanol, propanol, isopropanol, ethylene glycol, butyl glycol, propylene glycol, polypropylene glycols and mixtures thereof.
  • Extremely preferred solvents are the C 3 -alcohols n-propanol and / or isopropanol and the polyalkylene glycols, especially polypropylene glycols, in particular the PPG-400.
  • alkanolamines can be used in addition to the solvents described above.
  • the agent used may further contain hydrotropes.
  • hydrotropes are Lösigesvemittler.
  • Preferred hydrotropes are short chain aromatic sulfonates, for example, sodium cumene sulfonate or sodium xylene sulfonate.
  • urea butyl glycol, glycol ether sulfates or else aliphatic short-chain anionic or amphoteric solubilizers, for example octyl sulfate or butyl glucoside.
  • the agent used in the invention may further contain one or more water-soluble salts. These may be inorganic and / or organic salts.
  • the water-soluble salt can be used in detergents with a high surfactant concentration,
  • a high alkyl ether sulfate in particular a high alkyl ether sulfate, be used to adjust a lower viscosity.
  • Inorganic salts which can be used according to the invention are preferably selected from the group consisting of colorless water-soluble halides, sulfates, sulfites, carbonates,
  • Bicarbonates nitrates, nitrites, phosphates and / or oxides of the alkali metals
  • the inorganic salt is selected from the group comprising
  • organic salts which can be used according to the invention are in particular colorless water-soluble alkali metal, alkaline earth metal, ammonium, aluminum and / or
  • Transition metal salts of carboxylic acids are selected from the group comprising formate, acetate, propionate, citrate, malate, tartrate, succinate, malonate, oxalate, lactate and mixtures thereof. additives
  • Polymers suitable as additives are, in particular, maleic acid-acrylic acid copolymer Na salt (Sokalan® CP 5), modified polyacrylic acid Na salt (Sokalan® CP 10), modified
  • Polycarboxylate Na salt Sokalan® HP 25
  • polyalkylene oxide Polycarboxylate Na salt
  • Builders suitable as additives are, in particular, polyaspartic acid sodium salt, ethylenediaminetriacetate cocoalkylacetamide (Rewopol® CHT 12), methylglycinediacetic acid tri-Na salt (Trilon® ES 9964) and acetophosphonic acid (Turpinal® SL).
  • one or more dicarboxylic acids and / or salts thereof can be added, in particular a composition of Na salts of adipic, succinic and glutaric acid, as described, for. B. under the trade name Sokalan® DSC is available.
  • the use is advantageously carried out in amounts of 0.1 to 8 wt .-%, preferably 0.5 to 7 wt .-%, in particular 1, 3 to 6 wt .-% and particularly preferably 2 to 4 wt .-%.
  • a change in the dicarboxylic acid (salt) content can - especially in amounts above 2 wt .-% - contribute to a clear solution of the ingredients. Also, within certain limits, influencing the viscosity of the mixture by this means is possible. Furthermore, this component influences the solubility of the mixture. This component is particularly preferably used at high surfactant contents, in particular at surfactant contents above 30 wt .-%.
  • INCI chelating agents also called sequestrants, are ingredients that are capable of complexing and inactivating metal ions to prevent their detrimental effects on the stability or appearance of the agents, such as clouding. On the one hand, it is important to complex the incompatible with numerous ingredients calcium and magnesium ions of water hardness. The complexation of the ions of heavy metals such as iron or On the other hand, copper retards the oxidative decomposition of the finished agents. In addition, the complexing agents support the cleaning effect.
  • Disodium EDTA Citric Acid, Cyclodextrin, Cyclohexanediamine Tetraacetic Acid, Diammonium Citrate, Diammonium EDTA, Diethylenetriamine Pentamethylene Phosphonic Acid, Dipotassium EDTA, Disodium Azacycloheptane Diphosphonate, Disodium EDTA, Disodium Pyrophosphate, EDTA, Etidronic Acid (HEDP, Hydroxyethylidene diphosphonic acid), Galactic Acid , Gluconic Acid, Glucuronic Acid, HEDTA, Hydroxypropyl Cyclodextrin, Methyl Cyclodextrin, Pentapotassium Triphosphate, Methyl Glycine Diacetic Acid (MGDA), Pentasodium Aminotrimethylene Phosphonate, Pentasodium Ethylenediamine Tetramethylene Phosphonate, Pentasodium Pentetate,
  • Pentasodium Triphosphates Pentetic Acid, Phytic Acid, Polyamines, Potassium Citrate, Potassium EDTMP, Potassium Gluconates, Potassium Polyphosphates, Potassium Trisphosphonomethylamine Oxides, Ribonic Acid, Sodium Chitosan, Methylene Phosphonates, Sodium Citrate, Sodium
  • Pentamethylene Phosphonates Sodium Dihydroxyethylglycinate, Sodium EDTMP, Sodium Gluceptate, Sodium Gluconate, Sodium Glycereth-1 Polyphosphate, Sodium Hexametaphosphate, Sodium Metaphosphate, Sodium Metasilicate, Sodium Phytate, Sodium Polydimethylglycinophenol Sulfonate, Sodium Trimetaphosphate, TEA-EDTA, TEA Polyphosphate, Tetrahydroxyethyl Ethylenediamine , Tetrahydroxypropyl Ethylenediamine, Tetrapotassium
  • Etidronates tetrapotassium pyrophosphates, tetrasodium EDTA, tetrasodium etidronates,
  • Tetrasodium Pyrophosphate Tripotassium EDTA, Trisodium Dicarboxymethyl Alaninate, Trisodium EDTA, Trisodium HEDTA, Trisodium MGDA, Trisodium NTA and Trisodium Phosphate.
  • Complexing agents are preferably used in amounts of up to 5% by weight, particularly preferably 0.1 to 2% by weight.
  • the agent may contain one or more corrosion inhibitors, preferably in an amount of from 0.01 to 10% by weight, in particular from 0.1 to 5% by weight, particularly preferably from 0.5 to 3% by weight, very preferably 1 up to 2% by weight.
  • Suitable corrosion inhibitors are, for example, the following named according to INCI: Cyclohexylamine, Diammonium Phosphate, Dilithium Oxalate, Dimethylamino Methylpropanol, Dipotassium Oxalate, Dipotassium Phosphate, Disodium
  • water-soluble and / or water-insoluble builders may be used in the detergents and cleaners according to the invention.
  • Water-soluble builders are preferred because they tend to be less likely to leave insoluble residues on hard surfaces.
  • Typical builders which may be present in the invention are the low molecular weight polycarboxylic acids and their salts, the homopolymeric and copolymeric polycarboxylic acids and their salts, the citric acid and its salts, the carbonates, phosphates and silicates.
  • Water-insoluble builders include the zeolites, which may also be used, as well as mixtures of the aforementioned builders.
  • bleaching agents can be added to the cleaning agent.
  • Suitable bleaching agents include peroxides, peracids and / or perborates, more preferably H 2 0 2 .
  • the cleaning agent therefore contains one or more antimicrobial active ingredients, preferably in an amount of 0.01 to 2% by weight, preferably 0.02 to 0.9 wt .-%, in particular 0.05 to 0.5 wt .-%, particularly preferably 0.1 to 0.4 wt .-%, most preferably 0.3 wt .-%.
  • disinfection, sanitation, antimicrobial action and antimicrobial agent have the usual meaning in the context of the teaching of the invention, for example, by KH Wallophußer in "Practice of sterilization, disinfection - Conservation: germ identification - company hygiene” (5th ed. - Stuttgart, New York : Thieme, 1995). While disinfection in the narrower sense of the medical practice means the killing of - in theory all - infectious germs, sanitation is to be understood as the greatest possible elimination of all - including the saprophytic - normally harmless to humans saprophytic - germs.
  • the extent of disinfection or sanitation depends on the antimicrobial effect of the applied agent, which decreases with decreasing content of antimicrobial agent or increasing dilution of the agent for use.
  • antimicrobial agents from the groups of alcohols, aldehydes, antimicrobial acids or their salts, carboxylic acid esters, acid amides, phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, oxygen, nitrogen acetals and formals, benzamidines, isothiazoles and their suitable Derivatives such as isothiazolines and isothiazolinones, phthalimide derivatives, pyridine derivatives, antimicrobial surface active agents
  • antimicrobial amphoteric compounds preferably selected from the group comprising ethanol, n- Propanol, i-propanol, 1, 3-butanediol, phenoxyethanol, 1, 2-propylene glycol, glycerol,
  • Preferred antimicrobial surface-active quaternary compounds contain an ammonium, sulfonium, phosphonium, iodonium or arsonium group, as described, for example, by K. H. Wallpasußer in "Praxis der Sterilisation, Desinfetechnisch - Konservmaschine:
  • antimicrobial-effective essential oils which at the same time provide scenting of the cleaning agent
  • particularly preferred antimicrobial agents are selected from the group comprising salicylic acid, quaternary surfactants, in particular benzalkonium chloride, peroxo compounds, in particular hydrogen peroxide, alkali metal hypochlorite and mixtures thereof.
  • Preservatives may also be included in compositions of the invention. As such, essentially the substances mentioned in the antimicrobial agents can be used.
  • composition according to the invention may additionally contain skin protection and skin care agents.
  • skin care agents including bisabolol, allantoin, vitamins such as panthenol, natural oils such as almond oil, plant extracts such as marigold, aloe vera, nourishing wax dispersions, nourishing polymers and other used in cosmetic care and conditioning agents and Count mixtures.
  • pH regulators including bisabolol, allantoin, vitamins such as panthenol, natural oils such as almond oil, plant extracts such as marigold, aloe vera, nourishing wax dispersions, nourishing polymers and other used in cosmetic care and conditioning agents and Count mixtures.
  • the pH of the composition according to the invention can be adjusted by means of customary pH regulators, the pH value being chosen as a function of the desired intended use.
  • the pH is in a range of 5.5 to 10.5, preferably 5.5 to 8.5, more preferably 6 to 8, especially 7.0.
  • the pH-adjusting agents are acids and / or alkalis. Suitable acids are in particular organic acids such as acetic acid, citric acid, glycolic acid, lactic acid, succinic acid, adipic acid, malic acid, tartaric acid and gluconic acid or amidosulfonic acid.
  • Preferred bases are selected from the group of alkali and alkaline earth metal hydroxides and carbonates, in particular the alkali metal hydroxides, of which potassium hydroxide and especially sodium hydroxide is particularly preferred.
  • the agent according to the invention can be volatile Contain alkali.
  • ammonia and / or alkanolamines which may contain up to 9 C atoms in the molecule, are used.
  • alkanolamines the ethanolamines are preferred and of these in turn the monoethanolamine.
  • the composition according to the invention may contain one or more buffer substances (INCI Buffering Agents), usually in amounts of 0.001 to 5 wt .-%, preferably 0.005 to 3 wt .-%, in particular 0.01 to 2 wt .-%, particularly preferably 0.05 to 1 wt .-%, most preferably 0.1 to 0.5 wt .-%, for example 0.2 wt .-%. Preference is given to buffer substances which are at the same time complexing agents or even chelating agents
  • buffer substances are the citric acid or the citrates, in particular the sodium and potassium lead, for example trisodium citrate 2H 2 0 and tripotassium citrate H 2 0.
  • the agent may also contain enzymes, preferably proteases, lipases, amylases, hydrolases and / or cellulases. They can be added to the composition according to the invention in any form established according to the prior art. In the case of liquid or gel-form detergents, these include in particular solutions of the enzymes, advantageously as concentrated as possible, sparing in water and / or added with stabilizers.
  • the enzymes can be encapsulated, for example, by spray-drying or extruding the enzyme solution together with a preferably natural polymer or in the form of capsules, for example those in which the enzymes are entrapped as in a solidified gel or in core-shell type in which an enzyme-containing core is coated with a water, air and / or chemical impermeable protective layer.
  • a preferably natural polymer or in the form of capsules for example those in which the enzymes are entrapped as in a solidified gel or in core-shell type in which an enzyme-containing core is coated with a water, air and / or chemical impermeable protective layer.
  • further active ingredients for example stabilizers, emulsifiers, pigments, bleaches or dyes, may additionally be applied.
  • Such capsules are applied by methods known per se, for example by shaking or rolling granulation or in fluid-bed processes.
  • such granules for example by applying polymeric film-forming agent, low in dust and storage stable due to
  • enzyme stabilizers may be present in enzyme-containing agents in order to protect an enzyme contained in an agent according to the invention from damage such as, for example, inactivation, denaturation or decomposition, for example by physical influences, oxidation or proteolytic cleavage.
  • Suitable enzyme stabilizers are in particular: benzamidine hydrochloride, borax, boric acids, boronic acids or their salts or esters, in particular derivatives with aromatic groups, for example substituted ones
  • Phenylboronic acids or their salts or esters Peptide aldehydes (oligopeptides with reduced C-terminus), amino alcohols such as mono-, di-, triethanol- and -propanolamine and mixtures thereof, aliphatic carboxylic acids up to d 2 , such as succinic acid, other dicarboxylic acids or salts of said acids; end-capped fatty acid amide alkoxylates; lower aliphatic alcohols and especially polyols, for example glycerol, ethylene glycol, propylene glycol or sorbitol; and reducing agents and antioxidants such as sodium sulfite and reducing sugars.
  • Other suitable stabilizers are known in the art. Preference is given to using combinations of stabilizers, for example the combination of
  • agent according to the invention is to be used as an aqueous cleaning agent for hard surfaces, a favorable viscosity at 20 ° C. and a shear rate of 30 min -1 - measured with a Brookfield LV DV II viscometer and spindle 31 - in the range from 5 to 1500 mPa s, preferably 10 to 1200 mPa s, in particular 20 to 800 mPa s.
  • the viscosity of the composition according to the invention can be reduced - in particular with a high surfactant content of the composition - by the water-soluble salts and / or solvents and / or hydrotropes present.
  • the agent may also contain viscosity regulators (thickeners).
  • the amount of viscosity regulator is usually up to 0.5 wt .-%, preferably 0.001 to 0.3 wt .-%, in particular 0.01 to 0.2 wt .-%, most preferably 0.05 to 0.15 wt .-% based on the total composition.
  • Suitable viscosity regulators are all thickeners customarily used in detergents and cleaners, to which, for example, organic natural thickeners (agar-agar, carrageenan, tragacanth, gum arabic, alginates, pectins, polyoses, guar flour,
  • composition according to the invention can contain all scents and dyes customary in detergents and cleaners.
  • the agent according to the invention can be in the form of an aqueous solution or dispersion, a gel, a powder, a granulate, a solid or any desired material Form, including a tablet, ball or cuboid present.
  • Detergents such as hand dishwashing detergents and glass cleaners become liquid formulations
  • toilet cleaners for example also in the form of toilet liquid or gel cleaners, liquid or gel formulations are also used.
  • Detergents are preferably in liquid or gel form or in the form of a powder or granules.
  • Machine dishwashing detergents are preferably in the form of a gel, a powder, a granulate or a solid.
  • WC bricks are also used in the form of a solid.
  • composition of the invention can be used as a cleaning agent for hard surfaces and is particularly suitable as a hand dishwashing detergent, but also as a glass cleaner, toilet gel rinse, toilet liquid rinse or solid toilet stone. Also included is the use as
  • the cleaning agent according to the invention for cleaning hard surfaces, in particular as hand dishwashing detergents.
  • Hard surfaces in the context of this application are windows, mirrors and other glass surfaces, surfaces made of ceramic, plastic, metal or wood and lacquered wood, which are found in household and commercial, such as bathroom ceramics, kitchen surfaces or floors.
  • the detergent is diluted before use with water or applied undiluted. In a method for cleaning hard surfaces, therefore, the cleaning agent according to the invention is applied in one process step to the surface to be cleaned.
  • composition of the invention can be used as a detergent.
  • the invention therefore also relates to the use as a laundry detergent and to a process for washing textiles using the compositions according to the invention.
  • the surface tension (OFS) of surfactants was determined using the maximum
  • Sophorolipid Sopholiance S, Soliance
  • Decyl glycoside APG 220 UPW, Cognis
  • the interfacial tension (GFS) of surfactant blends with APP was determined by spinning
  • Table 1 shows hard surface acidic cleaning agents E1 to E3 according to the invention and a comparative example V1. (In% by weight). Table 1 :
  • Decyl glycoside APG 220 UPW, Cognis
  • Ci2-i4 fatty alcohol with 7 EO Dehydol LT 7, Cognis
  • Table 2 shows glass cleaners E4 to E6 according to the invention and a comparative example V2.
  • Ci2-i4 fatty alcohol sulfate, Na salt Texapon LS 35, Cognis
  • Dipropylene glycol n-propyl ether Dowanol DPnP, Dow
  • Dipropylene glycol n-butyl ether Dowanol DPnB, Dow
  • Table 3 shows toilet gel dishwashing agents E7-I z9 according to the invention and a comparative
  • Detergent V3 shown. (In% by weight).
  • Citric acid monohydrate 3 1
  • Table 4 shows WC-liquid dishwashers E10 to E12 according to the invention and the comparative cleaning agent V4.
  • Hydroxyethylcellulose (Natrosol HHBR) 0.5 0.5 0.5 0.5 0.5 0.5 0.5
  • Table 5 shows solid WC bricks E13 to E15 according to the invention and the comparative cleaning agent V5. Table 5:
  • HEDP-4Na 1-hydroxyethane- (1, 1-di- - 3-phosphonic acid Na 4 salt
  • Raw materials e.g. natural essential oils
  • Ci 2 fatty alcohol sulfate Texapon K12, Cognis
  • Ci 6 _i8 fatty alcohol with 25 EO Genapol T 250, Clariant
  • Ci2-18 fatty acid amide Comperlan 100, Cognis
  • Ci4-i6 sodium olefinsulfonate Elfan OS 46 P, Akzo Nobel
  • inventive detergents E16 to E20 are shown.
  • Enzymes (amylase, protease, cellulase) +
  • Enzymes (amylase, protease, cellulase) +
  • Enzymes (amylase, protease, cellulase) +

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  • Engineering & Computer Science (AREA)
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  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne une composition de produit détergent ou nettoyant, en particulier un produit nettoyant aqueux pour surfaces dures, qui contient un mélange de surfactants. Le mélange de surfactants contient au moins un alkylpolyglycoside non ionique et au moins un surfactant non glycosylé, le ou les alkylpolyglycosides non ioniques comprenant au moins un alkylpolypentoside. La présente invention concerne en outre l'utilisation d'un tel produit détergent et nettoyant pour laver des textiles ou nettoyer des surfaces dures, ainsi qu'un procédé de lavage de textiles ou de nettoyage de surfaces dures qui utilise le produit détergent ou nettoyant selon l'invention.
PCT/EP2013/073397 2012-11-19 2013-11-08 Produit détergent et nettoyant contenant des alkylpolypentosides WO2014076010A1 (fr)

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DE201210221021 DE102012221021A1 (de) 2012-11-19 2012-11-19 Wasch- und Reinigungsmittel mit Alkylpolypentosiden

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CN113403627A (zh) * 2021-06-10 2021-09-17 上海佳船工程监理发展有限公司 一种船舶管道清洗工艺

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DE102020132485A1 (de) 2020-12-07 2022-06-09 Henkel Ag & Co. Kgaa Ökologisch nachhaltige Handgeschirrspülmittelzusammensetzung mit Zuckertensiden

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WO1993020179A1 (fr) * 1992-03-30 1993-10-14 Henkel Kommanditgesellschaft Auf Aktien Nettoyants pour surfaces dures
DE4311159A1 (de) * 1993-04-05 1994-10-06 Henkel Kgaa Verwendung flüssiger Konzentrate zum Reinigen harter Oberflächen
DE4326112A1 (de) * 1993-08-04 1995-02-09 Henkel Kgaa Reinigungsmittel für harte Oberflächen
FR2712889A1 (fr) * 1993-11-26 1995-06-02 Ard Arabinosides d'alkyle, procédé de préparation et applications.
FR2712890A1 (fr) * 1993-11-26 1995-06-02 Ard Arabinosides, leur procédé de préparation et leurs applications.
DE19519405A1 (de) * 1995-05-26 1996-11-28 Henkel Kgaa Wäßrige Reinigungsmittelzusammensetzung
US5688930A (en) * 1994-08-30 1997-11-18 Agro Industrie Recherches Et Developpements Process for the preparation of surface active agents using wheat by-products and their applications
US20020099187A1 (en) * 2000-11-14 2002-07-25 Bertho Jean Noel Process for preparing solubilization adjuvants from fusel oils and saccharides
US20100160201A1 (en) * 2008-08-26 2010-06-24 Scheuing David R Natural Disinfecting Cleaners

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Publication number Priority date Publication date Assignee Title
WO1993020179A1 (fr) * 1992-03-30 1993-10-14 Henkel Kommanditgesellschaft Auf Aktien Nettoyants pour surfaces dures
DE4311159A1 (de) * 1993-04-05 1994-10-06 Henkel Kgaa Verwendung flüssiger Konzentrate zum Reinigen harter Oberflächen
DE4326112A1 (de) * 1993-08-04 1995-02-09 Henkel Kgaa Reinigungsmittel für harte Oberflächen
FR2712889A1 (fr) * 1993-11-26 1995-06-02 Ard Arabinosides d'alkyle, procédé de préparation et applications.
FR2712890A1 (fr) * 1993-11-26 1995-06-02 Ard Arabinosides, leur procédé de préparation et leurs applications.
US5688930A (en) * 1994-08-30 1997-11-18 Agro Industrie Recherches Et Developpements Process for the preparation of surface active agents using wheat by-products and their applications
DE19519405A1 (de) * 1995-05-26 1996-11-28 Henkel Kgaa Wäßrige Reinigungsmittelzusammensetzung
US20020099187A1 (en) * 2000-11-14 2002-07-25 Bertho Jean Noel Process for preparing solubilization adjuvants from fusel oils and saccharides
US20100160201A1 (en) * 2008-08-26 2010-06-24 Scheuing David R Natural Disinfecting Cleaners

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CN113403627A (zh) * 2021-06-10 2021-09-17 上海佳船工程监理发展有限公司 一种船舶管道清洗工艺

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