WO2009007166A1 - Détergents ou de nettoyants contenant des tensioactifs à base de matières premières renouvelables - Google Patents

Détergents ou de nettoyants contenant des tensioactifs à base de matières premières renouvelables Download PDF

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Publication number
WO2009007166A1
WO2009007166A1 PCT/EP2008/056226 EP2008056226W WO2009007166A1 WO 2009007166 A1 WO2009007166 A1 WO 2009007166A1 EP 2008056226 W EP2008056226 W EP 2008056226W WO 2009007166 A1 WO2009007166 A1 WO 2009007166A1
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Prior art keywords
surfactants
fatty
weight
alcohol
sodium
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PCT/EP2008/056226
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German (de)
English (en)
Inventor
Detlef Buisker
Heinz-Dieter Soldanski
Christian Nitsch
Konstantin Benda
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Henkel Ag & Co. Kgaa
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Publication of WO2009007166A1 publication Critical patent/WO2009007166A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

Definitions

  • the present invention relates to surfactant-containing detergents or cleaners which comprise, at least for the most part, only those surfactants which are based on renewable raw materials. Furthermore, it relates to the use of such an agent as hand dishwashing detergents, in particular for the removal of greasy and / or oily stains of dishes. Furthermore, it relates to the use of a surfactant system which comprises, at least for the most part, only those surfactants based on renewable raw materials in a hand dishwashing detergent.
  • the object of the invention is a surfactant-containing washing or cleaning agent, which
  • petrochemical-based surfactants which in particular comprise alkanesulfonates (SAS), alkylbenzenesulfonates, betaines and / or alkoxylated surfactants, such as preferably fatty alcohol ethoxylates, fatty acid ethoxylates, fatty amine ethoxylates, fatty alcohol ether sulfates,
  • Sugar surfactants preferably alkyl polyglucosides (APG), sugar esters, in particular sucrose esters and / or sugar amides, in particular glucamides, soaps,
  • APG alkyl polyglucosides
  • sugar esters in particular sucrose esters and / or sugar amides, in particular glucamides, soaps,
  • Fatty acid sarcosinates, ester sulfonates, fatty alcohol sulfates (FAS), alkanolamides, protein-fatty acid condensates and / or Fatty amines contains, wt .-% in each case based on the total amount of surfactant contained.
  • the alkoxylated surfactants are therefore added to the petrochemical-based surfactants because the necessary alkylene oxide, preferably ethylene oxide, results from petrochemical sources, namely usually either from naphtha or from methanol, which in turn consists of raw materials such as carbon dioxide and Produced hydrogen or carbon monoxide and hydrogen, which in turn originate for the most part either the coal gasification or are obtained from natural gas and heavy residual oils.
  • petrochemical sources namely usually either from naphtha or from methanol, which in turn consists of raw materials such as carbon dioxide and Produced hydrogen or carbon monoxide and hydrogen, which in turn originate for the most part either the coal gasification or are obtained from natural gas and heavy residual oils.
  • nämlbh sugar surfactants preferably alkylpolyglucosides (APG), sugar esters, in particular sucrose esters and / or sugar amides, in particular glucamides, soaps, fatty acid sarcosinates, ester sulfonates, fatty alcohol sulfates (FAS), alkanolamides, protein-fatty acid condensates, fatty amines explained in more detail.
  • Sugar surfactants are known surface-active compounds, which include, for example, the sugar surfactant classes of the alkyl glucose esters, aldobionamides, gluconamides (sugar acid amides), glycerol amides, glycerol glycolipids, polyhydroxy fatty acid amide sugar surfactants (sugar amides) and alkyl polyglycosides.
  • sugar surfactants which can be used in the context of the teaching according to the invention are the alkyl polyglycosides, the sugar amides (especially glucamides) and the sugar esters, such as preferably sucrose esters, but especially the alkyl polyglycosides.
  • Particularly preferred sugar amides can be described by the formula (I), R'C (O) N (R ") [Z], in which R 'is a linear or branched, saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, with 5 to 21, preferably 5 to 17, in particular 7 to 15, particularly preferably 7 to 13 carbon atoms, R "is a linear or branched, saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, having 6 to 22, preferably 6 to 18 , in particular 8 to 16, particularly preferably 8 to 14 carbon atoms, a C ⁇ s-alkyl radical, in particular a methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, tert-butyl or n-pentyl radical , or hydrogen and Z represent a sugar residue, ie a monosaccharide residue.
  • sugar amides are the amides of glucose, the glucamides, for example lauroyl-methyl-glucamide.
  • Glucamides are N-alkylated, preferably N-methylated fatty acid amides, which can be obtained by reacting N-alkyl- (N-methyl-) glucosamine with fatty acid methyl esters.
  • R 1 in this aforementioned formula (II) is a linear or branched, saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, having 5 to 21, preferably 5 to 17, in particular 7 to 15, particularly preferably 7 to 13 carbon atoms, for example, for an n-Ci 2 alkyl radical
  • R 2 is a linear or branched, saturated or unsaturated alkyl radical, preferably a linear unsaturated alkyl radical, having 6 to 22, preferably 6 to 18, especially 8 to 16, particularly preferably 8 to 14 carbon atoms, a C ⁇ 5 - alkyl radical, in particular a methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, tert-butyl or n-pentyl radical, or hydrogen, but in particular a lower one Alkyl radical, generally methyl.
  • alkylpolyglycosides are very particularly preferred sugar surfactants within the scope of the teaching according to the invention and preferably satisfy the general formula (III), RO (AO) 3 [G] x in which R is a linear or branched, saturated or unsaturated alkyl radical with 6 to 22, preferably 6 to 18, in particular 8 to 16, particularly preferably 8 to 14 carbon atoms, [G] for a glycosidically linked sugar moiety and x for a number from 1 to 10 and AO for an alkyleneoxy group, for example an ethyleneoxy or propyleneoxy group, and a represents the average degree of alkoxylation from 0 to 20.
  • R is a linear or branched, saturated or unsaturated alkyl radical with 6 to 22, preferably 6 to 18, in particular 8 to 16, particularly preferably 8 to 14 carbon atoms
  • [G] for a glycosidically linked sugar moiety and x for a number from 1 to 10
  • AO for an alkyleneoxy group, for example an ethyleneoxy or
  • the group (AO) 3 may also contain different alkylene oxyharmen, eg ethyleneoxy or propyleneoxy, wherein it is then a to the average Automatalkoxyltechniksgrad, ie the sum of Ethoxyltechniks- and Propoxyltechniksgrad acts.
  • the alkyl radicals R 1 of the APG are linear unsaturated radicals having the stated number of carbon atoms.
  • APG are nonionic surfactants and are known substances that can be obtained by the relevant methods of preparative organic chemistry.
  • alkyl glycosides having a mean degree of oligomerization x of 1.1 to 3.0 are used. From an application point of view, those alkyl glycosides are preferred whose Oligomermaschinesgrad less than 1, 7 and in particular between 1, 2 and 1, 6 is.
  • the glycosidic sugar used is preferably xylose, but especially glucose.
  • the alkyl or alkenyl radical R (based on the abovementioned formula (III) RO (AO) 3 [G] x ) can be derived from primary alcohols having 8 to 18, preferably 8 to 14, carbon atoms. Typical examples are caproic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol, and technical mixtures thereof, such as those obtained in the course of the hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from Roelene's oxosynthesis.
  • the alkyl or alkenyl radical R is derived from lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol or oleyl alcohol.
  • lauryl alcohol myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol or oleyl alcohol.
  • elaidyl alcohol petroselinyl alcohol, arachidyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and technical mixtures thereof.
  • alkyl polyglycosides are, for example C 8 io- and a Ci 2 - 14 -Alkylpoly- glucoside with a DP degree of 1, 4 or 1, 5, in particular C 8-I o- alkyl-1, 5-glucoside and C 12 -i 4 -alkyl-1,4-glucoside.
  • APG may be e.g. are described by the following formula (V):
  • the average degree of oligomerization x is preferably 1, 2-1, 5.
  • the alkyl radical is preferably in the range C8-C16 (thus n in the aforementioned formula is preferably 7-15).
  • Sugar esters likewise belong to the surfactants which can be used particularly preferably according to the invention.
  • Sugar esters are esters of sugar alcohols, in particular sucrose (ie sucrose esters) with organic or inorganic acids, in particular with fatty acid (derivatives) n, for example obtainable by reactions of sucrose with fatty acid esters in solution or melt or from Alkali-catalyzed transesterification with triglycerides.
  • Monoesters of short-chain fatty acids may be preferred, for example monoesters of lauric acid.
  • sucrose esters are e.g. by the following illustrative formulas VI-VIII:
  • n in these formulas VI-VIII is preferably in the range from 1 to 20.
  • the abovementioned formulas are intended primarily to illustrate, because not least because of the 8 hydroxy functions present, the sucrose esters are generally complex mixtures.
  • Fettkladosarcosinate according to the invention are particularly preferably usable surfactants.
  • the fatty acid sarcosinates are the condensation products of fatty acids with N-methylglycine.
  • Fatty acid sarcosinates can be prepared by reacting N-methylglycine with fatty acid chloride.
  • fatty acid sarcosinates based on C 12 to C 18 fatty acids are particularly preferred.
  • Fatty acid sarcosinates are characterized by a pronounced foaming power, while they also show a low sensitivity to water hardness and high skin tolerance.
  • Preferred fatty acid sarcosinates can be described by the following general formula (IX):
  • R is a linear or branched, saturated or unsaturated alkyl radical having preferably 8 to 22 carbon atoms.
  • soaps can preferably be used according to the invention.
  • Soaps are the water-soluble alkali metal salts (preferably sodium salts or potassium salts) of the saturated and unsaturated higher fatty acids (preferably C10 to C22), which are preferably present as solid or semisolid mixtures.
  • Typical examples are the sodium, potassium, magnesium, ammonium and triethanolammonium salts of caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, Linolenic acid, elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures.
  • coconut or palm kernel fatty acids are used in the form of their sodium or potassium salts.
  • fatty alcohol sulfates can preferably be used according to the invention.
  • Preferred fatty alcohol sulfates can be described by the formula (X), R 2 O-SO 3 X. They are available, for example, by reaction of preferably saturated fatty alcohols with concentrated sulfuric acid, gaseous sulfur trioxide, chlorosulfonic acid or sulfamic acid.
  • R 2 O-SO 3 X
  • R 2 is a linear or branched, aliphatic alkyl and / or alkenyl radical having 6 to 22, preferably 12 to 18 carbon atoms and X is an alkali and / or Alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium.
  • alkyl sulfates which can be used for the purposes of the invention are the sulfation products of caproic alcohol, caprylic alcohol, capric alcohol, 2-ethylhexyl alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, Gadoleyl alcohol, behenyl and erucyl alcohol and their technical mixtures obtained by high-pressure hydrogenation of technical methyl ester fractions or aldehydes from the Roelen oxo synthesis.
  • the sulfation products can preferably be used in the form of their alkali metal salts and in particular their sodium salts.
  • Particularly preferred are alkyl sulfates based on Ci 6 / i 8 tallow fatty alcohols or vegetable fatty alcohols of comparable C chain distribution in the form of their sodium salts.
  • branched primary alcohols they are oxo alcohols, as are obtainable, for example, by reacting carbon monoxide and hydrogen with alpha-olefins according to the Shop process.
  • Such alcohol mixtures are commercially available under the trade names Dobanol® or Neodol®. Suitable alcohol mixtures are Dobanol 91®, 23®, 25®, 45®.
  • oxo alcohols as obtained by the classical oxo process of Enichema or the Condea by addition of carbon monoxide and hydrogen to olefins.
  • These alcohol mixtures are a mixture of highly branched alcohols.
  • Such alcohol mixtures are commercially available under the trade name Lial®.
  • Suitable alcohol mixtures are Lial 91®, 111®, 123®, 125®, 145®.
  • fatty acid alkanolamides can preferably be used according to the invention.
  • Fatty acid alkanolamides may be e.g. by reaction of alkanolamines with fatty acids, fatty acid methyl esters or fatty acid glycerides.
  • Preferred fatty acid alkanolamides can be described by the following formula (XI):
  • R 1 -CO is generally a fatty acid radical, in particular a stearic, coconut oil or olein radical.
  • alkanolamine di-, monoethanolamine or aminopropanols can be used, whereby the meaning of R 2 and n are defined in just mentioned formula.
  • fatty amines according to the invention can preferably be used.
  • Fatty amines are for example obtainable by a process starting from fatty alcohols, which are reacted at 210-260 0 C in the presence of dehydrogenation catalysts with ammonia or short chain alkyl or dialkylamines.
  • the salts of fatty amines are cationic emulsifiers. These are included in the term fatty amine.
  • alkylation quaternary ammonium compounds can be obtained.
  • fatty amine By oxidation of the fatty amines, for example with hydrogen peroxide, amine oxides can be obtained. These are included in the term fatty amine.
  • the amine oxides which are particularly suitable according to the invention include alkylamine oxides, in particular alkyldimethylamine oxides, alkylamidoamine oxides and alkoxyalkylamine oxides.
  • Preferred amine oxides can be described by the following formula (XII), R 6 R 7 R 8 N + -O " , in the R 6 is a saturated or unsaturated C 6 .
  • alkyl preferably C 8 _i 8 alkyl, in particular a saturated C 10 -i 6 alkyl, for example, a saturated C 12 _ 14 alkyl radical in the Alkylamidoaminoxiden via a Carbonylamidoalkylen embark -CO-NH- (CH 2 ) Z - and in the Alkoxyalkylaminoxiden via an oxaalkylene group -O- (CH 2 ) Z - is bonded to the nitrogen atom N, wherein z is in each case a number from 1 to 10, preferably 2 to 5, in particular 3,
  • R 7 , R 8 independently of one another represent a C 1-4 -alkyl radical, optionally hydroxy-substituted, for example a hydroxyethyl radical, in particular a methyl radical.
  • Suitable amine oxides are the following compounds designated as INCI: almond amidopropylamine oxides, babassuamidopropylamine oxides, behenamine oxides, cocamidopropyl amine oxides, cocamidopropylamine oxides, cocamine oxides, coco-morpholine oxides, decylamine oxides, decyltetradecylamine oxides, diaminopyrimidines oxides, dihydroxyethyl C8-10 Alkoxypropylamines oxides, dihydroxyethyl C9-11 alkoxypropylamines oxides, dihydroxyethyl C12-15 alkoxypropylamines oxides, dihydroxyethyl cocamines oxides, dihydroxyethyl lauramines oxides, dihydroxyethyl stearamines oxides, dihydroxyethyl tallowamine oxides, hydrogenated palm kernel amines oxides, hydrogenated tallowamine oxides, hydroxyethyl Hydroxy
  • ester sulfonates can preferably be used according to the invention.
  • Preferably usable ester sulfonates contain in the molecule a terminal ester and a sulfonate function, usually adjacent in the ⁇ -position.
  • This example ⁇ -ester can be obtained by reacting alkyl esters with usual sulfating agents, preferably luftver Plantntem, dry sulfur trioxide (SO3), at 80 0 C and subsequent neutralization.
  • SO3 dry sulfur trioxide
  • Preference is given in particular to methyl esters based on coconut oil (C12 / 14 chain), palm kernel oil (palm kernel sulfofatty acid ester), particularly preferably of taigmethyl ester (C16 / 18 chain).
  • Particularly preferred ester sulfonates can be described by the formula:
  • protein-fatty acid condensates can preferably be used according to the invention.
  • Protein-fatty acid condensates can be prepared, for example, by acylating protein hydrolysates, e.g. with fatty acids, fatty acid methyl esters, but preferably fatty acid chlorides or substituted maleic anhydrides.
  • N is preferably 1-13.
  • Very well known are, for example, the Lamepon® types, Gluadin® types, Hostapon® KCG or the Amisoft® types.
  • the washing or cleaning agent according to the invention preferably hand dishwashing detergent, contains more than 95% by weight, preferably more than 99% by weight, in particular 100% by weight, of surfactants based on renewable raw materials,% by weight on the total amount of surfactant contained.
  • Betaines can also be present in the agents according to the invention.
  • Suitable betaines are the alkylbetaines, the alkylamidobetaines, the imidazolinium betaines, the sulfobetaines (INCI Sultaines) and the phosphobetaines and preferably satisfy the following formula,
  • R 1 - [CO-X- (CH 2 ) n ] ⁇ -N + (R 2 ) (R 3 ) - (CH 2 ) m - [CH (OH) -CH 2 ] y - ⁇ - (XIII) in R 1 is a saturated or unsaturated C 6-22 -alkyl radical, preferably C 8 -i 8 -alkyl radical, in particular a saturated Ci -i O 6 alkyl radical, for example a saturated C 12 .i 4 alkyl
  • X is NH, NR 4 with the C M -alkyl radical R 4 , O or S
  • n is a number from 1 to 10, preferably 2 to 5, in particular 3
  • x is 0 or 1 preferably 1
  • R 2 independently represent a CI_ 4 alkyl optionally hydroxysubstituted droxyethylrest such as a hybrid, but in particular a methyl radical
  • m is a number from 1 to 4, in particular 1, 2
  • Y is COO, SO 3 , OPO (OR 5 ) O or P (O) (OR 5 ) O, wherein R 5 is a hydrogen atom H or a
  • Preferred betaines are the alkylbetaines of the formula (XIIIa), the alkylamidobetaines of the formula (Ib), the sulfobetaines of the formula (XIIIc) and the amidosulfobetaines of the formula XII (Id),
  • betaines are the carbo-betaines, in particular the carbo-betaines of the formula (Ia) and (Ib), most preferably the alkylamido-betaines of the formula (Ib).
  • betaines and sulfobetaines are the following INCI compounds: almondamidopropyl betaines, apricotamidopropyl betaines, avocadamidopropyl betaines, bassoramidopropyl betaines, behenamidopropyl betaines, behenyl betaines, betaines, canolamidopropyl betaines, caprylic / capramidopropyl betaines, camitines, cetyl betaines, cocamidoethyl betaines , Cocamidopropyl Betaine, Cocamidopropyl Hydroxysultaine, Coco Betaines, Coco Hydroxysultaine, Coco / Oleamidopropyl Betaine, Coco Sultaine, Decyl Betaine, Dihydroxyethyl Oleyl Glycinate, Dihydroxyethyl Soy Glycinate, Dihydroxyethyl Stearyl Glycinate, Dihydroxyethyl Tallow G
  • the washing or cleaning agent according to the invention contains no betaine, if necessary in amounts of ⁇ 10% by weight, ⁇ 5% by weight or ⁇ 1% by weight, based on the total amount of surfactant contained in the washing or cleaning agent but especially no betaine is included.
  • washing or cleaning agent according to the invention should contain alkylbenzenesulfonates, but this is not preferred according to the invention, then at most in amounts of ⁇ 10% by weight, ⁇ 5% by weight or ⁇ 1% by weight, based on the total, in the wash or detergent contained amount of surfactant. In particular, however, no alkylbenzenesulfonate is included.
  • Alkylbenzenesulfonates have the following general formula:
  • R is an alkyl radical (usually C8-C12) and M 1 is a monovalent cation, preferably sodium.
  • alkanesulfonates are the collective name for compounds of the general formula R-SO 2 -OM, where R is a - usually secondary - alkyl radical and M is a monovalent cation, preferably sodium.
  • washing or cleaning agent according to the invention should contain alkoxylated surfactants, but this is not preferred according to the invention, then at most in amounts of ⁇ 10% by weight, ⁇ 5% by weight or ⁇ 1% by weight, based on the total, in Detergent containing detergent amount. In particular, however, no alkoxylated surfactant is included.
  • Alkoxylated surfactants are alkylene oxide adducts, in particular fatty alcohol ethoxylates, fatty acid ethoxylates, fatty amine ethoxylates, fatty alcohol ether sulfates.
  • the total amount of surfactants present in the washing or cleaning agent according to the invention is in principle variable.
  • detergents or cleaners often contain combinations of several surfactants, for example to meet different requirements for the agent, e.g. in terms of cleaning performance and foaming, to better meet. Even with the washing or cleaning agent according to the invention, the use of a combination of a plurality of surfactants is very advantageous.
  • the washing or cleaning agent according to the invention contains a mixture of at least 2 surfactants based on renewable raw materials, preferably selected from sugar surfactants, preferably alkylpolyglucosides (APG), sugar esters, in particular sucrose esters and / or sugar amides, in particular gluc - amides, soaps, fatty acid sarcosinates, ester sulfonates, fatty alcohol sulfates (FAS), alkanolamides, protein-fatty acid condensates and / or fatty amines.
  • sugar surfactants preferably alkylpolyglucosides (APG)
  • sugar esters in particular sucrose esters and / or sugar amides, in particular gluc - amides, soaps, fatty acid sarcosinates, ester sulfonates, fatty alcohol sulfates (FAS), alkanolamides, protein-fatty acid condensates and / or fatty amines.
  • washing or cleaning agent according to the invention preferably hand dishwashing detergent, but in particular contains a mixture of APG and FAS, preferably in a ratio of 3: 1 to 1: 3, advantageously 2: 1 to 1: 2 and especially 1, 5: 1 to 1 : 1, 5, so there is a very particularly preferred embodiment of the invention.
  • APG and FAS a mixture of APG and FAS, preferably in a ratio of 3: 1 to 1: 3, advantageously 2: 1 to 1: 2 and especially 1, 5: 1 to 1 : 1, 5, so there is a very particularly preferred embodiment of the invention.
  • oily and greasy soil e.g. comprising oils, such as sunflower oil or rapeseed oil
  • fats such as butter or lard
  • APG and FAS accounts for> 80% by weight, advantageously> 90% by weight, more advantageously> 95% by weight, in particular even 100% by weight, of the total amount of the surfactants present. It has also been found that such combinations lead to particularly storage-stable agents.
  • the fatty alcohol sulfate contained, in particular when it is used in a mixture with APG, a C 8 -C 20 - alcohol sulfate, preferably a Cio-Ci 8 -Alkoholsulfat, in particular a Ci 2 -C 14 alcohol sulphate.
  • a washing or cleaning agent according to the invention preferably hand dishwashing detergent, contains 3-30% by weight, preferably 5-20% by weight, in particular 8-15% by weight, of fatty alcohol sulphate, based on the total agent, this likewise constitutes a preferred embodiment of the invention.
  • washing or cleaning agent according to the invention preferably hand dishwashing detergent, 3-30 wt .-%, preferably 5-20 wt .-%, in particular 8-15 wt .-% APG contains based on the total agent.
  • hand dishwashing detergent 3-30 wt .-%, preferably 5-20 wt .-%, in particular 8-15 wt .-% APG contains based on the total agent.
  • a washing or cleaning agent according to the invention preferably hand dishwashing detergent, additionally contains components selected from the following, preferably all the following components:
  • pH adjusting agent preferably citric acid and / or alkali citrate
  • hydrotrope preferably aromatic sulfonate, in particular cumene sulfonate, advantageously in amounts of 0-5% by weight, more preferably 0.5-2.5% by weight
  • antibacterial agents preferably sodium benzoate or sodium salicylate
  • preservative preferably sodium benzoate or sodium salicylate
  • auxiliaries for adjusting the viscosity preferably water-soluble salt, in particular sodium chloride, advantageously in amounts of 0-10% by weight, more preferably 0.1-7% by weight, particularly preferably 0.5% to 5% by weight
  • alcohol preferably bioalcohol, advantageously in amounts of from 0 to 15% by weight, preferably from 1 to 12% by weight, in particular from 3 to 8% by weight, in each case based on the total agent.
  • the agent may therefore also contain hydrotropes.
  • hydrotropes are solubilizers.
  • Preferred hydrotropes are short-chain aromatic sulfonates, for example sodium cumene sulfonate or sodium xylene sulfonate.
  • urea butyl glycol, glycol ether sulfates or else aliphatic short-chain anionic or amphoteric solubilizers, for example octyl sulfate or butyl glucoside.
  • sodium cumene sulfonate and / or sodium xylene sulfonate are the preferred hydrotropes, which are preferably present in amounts of from 0 to 5% by weight, more preferably 0.5 to 2.5% by weight, on average.
  • the agent according to the invention may preferably additionally comprise one or more water-soluble salts. It may be inorganic and / or organic salts, in a preferred embodiment, the agent contains at least one inorganic salt.
  • the water-soluble salt can be used in detergents with a high surfactant concentration to set a lower viscosity.
  • Inorganic salts which can be used according to the invention are preferably selected from the group consisting of colorless water-soluble halides, sulfates, sulfites, carbonates, hydrogen carbonates, nitrates, nitrites, phosphates and / or oxides of the alkali metals, alkaline earth metals, aluminum and / or transition metals; Furthermore, ammonium salts can be used. Particularly preferred are halides and sulfates of the alkali metals; Preferably, therefore, the inorganic salt is selected from the group comprising sodium chloride, potassium chloride, sodium sulfate, potassium sulfate and mixtures thereof.
  • the organic salts which can be used according to the invention are, in particular, colorless water-soluble alkali metal, alkaline earth metal, ammonium, aluminum and / or transition metal salts of the carboxylic acids.
  • the salts are selected from the group comprising formate, acetate, propionate, citrate, malate, tartrate, succinate, malonate, oxalate, lactate and mixtures thereof.
  • the washing or cleaning agent according to the invention contains in a preferred embodiment 0 to 10 wt .-%, preferably 0.1 to 7 wt .-%, particularly preferably 0.5 to 5 wt .-% of at least one water-soluble inorganic and / or at least one water-soluble organic salt.
  • washing or cleaning agent according to the invention preferably hand dishwashing detergent
  • the washing or cleaning agent according to the invention is in liquid form and contains> 50% by weight, preferably> 60% by weight, advantageously> 70% by weight and in particular> 80% by weight of water to the entire agent, so there is again a preferred embodiment of the invention.
  • the washing or cleaning agent according to the invention may also contain organic solvents.
  • One or more, preferably water-soluble, organic solvents may advantageously be present in an amount of from 0 to 15% by weight, preferably from 1 to 12% by weight, in particular from 3 to 8% by weight, based on the total agent.
  • the solvent can be used in the context of the teaching of the invention as needed in particular as a hydrotrope and viscosity regulator. It acts as a solubilizer, in particular for surfactants and electrolyte, as well as perfume and dye, and thus contributes to their incorporation, prevents the formation of liquid-crystalline phases and contributes to the formation of clear products.
  • the viscosity of the agent according to the invention preferably decreases with increasing amount of solvent. Finally, as the amount of solvent increases, the cloudiness and clear point of the agent according to the invention preferably also decreases.
  • Bioalcohol refers to ethanol produced from biomass.
  • the sugar, starch or cellulose components contained in plant components for example in sugar beet, sugarcane, cereals, corn, wood
  • the washing or cleaning agent according to the invention contains exclusively organic alcohol as the organic solvent.
  • suitable solvents are, for example, saturated or unsaturated, preferably saturated, branched or unbranched Ci. 20- hydrocarbons, preferably C 2 _i 5 -Kohlen- hydrogens, with at least one hydroxy group and optionally one or more ether functions COC, ie the carbon atom chain interrupting oxygen atoms.
  • Preferred solvents are the - optionally unilaterally etherified with a Ci_ 6 alkanol - C 2 - 6 alkylene glycols and poly C 2 - 3 -alkylene glycol having an average of 1 to 9 identical or different, preferably the same, alkylene glycol groups per molecule as well as the C ⁇ 6 -AlkOhOIe, preferably ethanol, n-propanol or iso-propanol, especially ethanol.
  • Exemplary solvents are the following INCI compounds: alcohol (ethanol), buteth-3, butoxy diglycol, butoxyethanol, butoxyisopropanol, butoxypropanol, n-butyl alcohol, t-butyl alcohol, butylene glycol, butyloctanol, diethylene glycol, dimethoxy diglycol, dimethyl ether, Dipropylene glycol, ethoxydiglycol, ethoxyethanol, ethyl hexanediol, glycol, hexanediol, 1, 2,6-hexanetriol, hexyl alcohol, hexylene glycol, isobutoxypropanol, isopentyldiol, isopropyl alcohol (isopropanol), 3-methoxybutanol, methoxy diglycol, methoxyethanol, methoxyisopropanol, Methoxy methyl butanol, methoxy PEG-10, methylal,
  • longer-chain polyalkylene glycols in particular polypropylene glycols.
  • polypropylene glycols Particularly preferred are, for example, the PPG-400 or the PPG-450, but also polypropylene glycols with larger chain lengths can be used in the context of this invention.
  • the solvent is selected from the group comprising methanol, ethanol, propanol, isopropanol, ethylene glycol, butyl glycol, propylene glycol, polypropylene glycols and mixtures thereof.
  • Extremely preferred solvents are the C 2 - 3 alcohols ethanol, n-propanol and / or iso-propanol, especially ethanol, and the polyalkylene glycols, especially polypropylene glycols, in particular the PPG-400.
  • alkanolamines can be used in addition to the solvents described above.
  • the flash point of the agent may be 40 ° C or below; preferred embodiments have flash points of 30 0 C to 35 ° C. Due to the high water content at the same time, however, they represent no danger if the product is used properly.
  • the agents according to the invention may optionally also contain further than the previously mentioned surfactants.
  • anionic sulfosuccinic acid surfactants for example, anionic sulfosuccinic acid surfactants, sulfosuccinates, sulfosuccinamates and sulfosuccinamides, in particular sulfosuccinates and sulfosuccinamates, most preferably sulfosuccinates.
  • the sulfosuccinates are the salts of the mono- and diesters of sulfosuccinic acid HOOCCH (SO 3 H) CH 2 COOH, while the sulfosuccinamates are the salts of the monoamides of sulfosuccinic acid and the sulfosuccinamides are the salts of the diamides of sulfosuccinic acid ,
  • the salts are preferably alkali metal salts, ammonium salts and mono-, di- or trialkanolammonium salts, for example mono-, di- or triethanolammonium salts, in particular lithium, sodium, potassium or ammonium salts, particularly preferably sodium or ammonium salts , most preferably sodium salts.
  • one or both carboxyl groups of the sulfosuccinic acid is preferably with one or two identical or different unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alcohols having 4 to 22, preferably 6 to 20, in particular 8 to 18 , more preferably 10 to 16, most preferably 12 to 14 carbon atoms esterified.
  • esters of unbranched and / or saturated and / or acyclic and / or alkoxylated alcohols in particular unbranched, saturated fatty alcohols and / or unbranched, saturated, with ethylene and / or propylene oxide, preferably ethylene oxide, alkoxylated fatty alcohols having a degree of alkoxylation of 1 to 20, preferably 1 to 15, in particular 1 to 10, more preferably 1 to 6, most preferably 1 to 4.
  • the monoesters are preferred in the context of the present invention over the diesters.
  • a particularly preferred sulfosuccinate is Sulfobemsteinklarylpolyglykolester-di-sodium salt (EO lauryl sulfosuccinate, di-sodium salt; INCI Disodium Laureth Sulfosuccinate), for example, as Tego ® sulfosuccinate F 30 (Goldschmidt) with a sulfosuccinate of 30 parts by weight % is commercially available.
  • one or both carboxyl groups of the sulfosuccinic acid forms preferably with a primary or secondary amine having one or two identical or different, unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alkyl radicals having 4 to 22 , preferably 6 to 20, in particular 8 to 18, more preferably 10 to 16, most preferably 12 to 14 carbon atoms carries, a carboxylic acid amide.
  • Particular preference is given to unbranched and / or saturated and / or acyclic alkyl radicals, in particular unbranched, saturated fatty alkyl radicals.
  • sulfosuccinates and sulfosuccinamates designated according to INCI: ammonium dinonyl sulfosuccinates, ammonium lauryl sulfosuccinates, diammonium dimethicone copolyol sulfosuccinates, diammonium lauramido-MEA sulfosuccinates, diammonium lauryl sulfosuccinates, diammonium oleamido PEG-2 Sulfosuccinate, Diamyl Sodium Sulfosuccinate, Dicapryl Sodium Sulfosuccinate, Dicyclohexyl Sodium Sulfosuccinate, Diheptyl Sodium Sulfosuccinate, Dihexyl Sodium Sulfosuccinate, Diisobutyl Sodium Sulfosuccinate, Dioctyl Sodium Sulfosuccinate, Dioctyl
  • Preferred anionic sulfosuccinic are imidosuccinate, mono-Na-sulfosuccinic acid diisobutyl ester (Monawet MB ® 45), mono-Na-sulfosuccinic acid di-octyl ester (Monawet MO-84 ® R2W, Rewopol SB ® DO 75), mono-Na sulfosuccinic acid di-tridecyl (Monawet ® MT 70), fat alkoholpolyglykolsulfosuccinat-Na-NH 4 salt (sulfosuccinate S-2), di-Na-sulfosuccinic acid mono- Ci 2 / i 4 3EO ester (Texapon ® SB -3), Natruimsulfobernsteinkladiisooctylester (Texin DOS ® 75) and di- sodium sulfosuccinic acid mono-Ci 2
  • the inventive composition contains as optional anionic sulfosuccinic acid surfactants one or more sulfosuccinates, sulfosuccinamates and / or sulfosuccinamides, preferably sulfosuccinates and / or sulfosuccinamates, in particular sulfosuccinates, in an amount of usually 0.001 to 5% by weight, preferably 0 , 01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, most preferably 0.5 to 1, 5 wt .-%, for example 1 wt. -%, relative to the total budget.
  • no anionic sulfosuccinic acid surfactant is included.
  • amphoteric surfactants which may be preferably used include alkylamidoalkylamines, alkyl substituted amino acids, acylated amino acids or biosurfactants.
  • the alkylamidoalkylamines are amphoteric surfactants of the formula (XVI), R 9 -CO-NR 10 - (CH 2 ) 1 -N (R 11 ) - (CH 2 CH 2 O) J - (CH 2 ) k - [CH (OH)] l -CH 2 ⁇ Z-OM (XVI) in the R 9 is a saturated or unsaturated C 6 . 22 alkyl, preferably C 8 _i 8 alkyl, in particular a saturated Ci O -i 6 alkyl, for example, a saturated C 12 . 14 -alkyl radical, R 10 is a hydrogen atom H or a C 1-4 -alkyl radical, preferably H, i is a number from 1 to 10, preferably 2 to 5, in particular 2 or 3,
  • R 11 is a hydrogen atom H or CH 2 COOM (to M su), j is a number from 1 to 4, preferably 1 or 2, in particular 1, k is a number from 0 to 4, preferably 0 or 1,
  • Z is CO, SO 2 , OPO (OR 12 ) or P (O) (OR 12 ), wherein R 12 is a C 1-4 alkyl radical or M (su), and M is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine , eg protonated mono-, di- or triethanolamine.
  • alkylamido alkylamines are the following compounds named according to INCI: coco amphodipropionic Acid, Cocobetainamido amphopropionates, DEA-Cocoamphodipropionate, Disodium Caproamphodiacetate, Disodium Caproamphodipropionate, Disodium Capryloamphodiacetate, Disodium Capryloamphodipropionate, Disodium Cocoamphocarboxyethylhydroxypropylsulfonate, Disodium Cocoamphodiacetate, Disodium Cocoamphodipropionate, Disodium Isostearoamphodi- acetate, Disodium Isostearoamphodipropionate , Disodium Laureth-5 Carboxyamphodiacetate, Disodium Lauroamphodiacetate, Disodium Lauroamphodipropionate, Disodium propionate Oleoamphodi-, Disodium PPG-2-lsodeceth-7
  • Preferred alkyl-substituted amino acids are monoalkyl-substituted amino acids according to formula (XVII),
  • R 13 -NH-CH (R 14 ) - (CH 2 ) U -COOM '(XVII) in the R 13 is a saturated or unsaturated C 6 . 22 alkyl, preferably C 8 _i 8 alkyl, in particular a saturated C 10 _i 6 alkyl, for example, a saturated C 12 .i 4 -alkyl radical
  • R 14 is a hydrogen atom H or a C ⁇ alkyl, preferably H, u Number from 0 to 4, preferably 0 or 1, in particular 1, and
  • M ' is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, e.g. protonated mono-, di- or triethanolamine, is alkyl-substituted imino acids according to formula (XVIII),
  • M is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, for example protonated mono-, di- or triethanolamine, where M" in the two carboxy groups may have the same or two different meanings, for example hydrogen and sodium or twice sodium is, and mono- or dialkyl-substituted natural amino acids according to formula (XIX), R 16 -N (R 17 ) -CH (R 18 ) -COOM "'(XIX) in the R 16 is a saturated or unsaturated C 6 . 22 alkyl, preferably C 8 _i 8 alkyl, in particular a saturated Ci O -i 6 alkyl, for example, a saturated C 12. 14 alkyl, R 17 is a hydrogen atom or a C ⁇ alkyl, optionally hydroxy or amine substituted , for example a methyl, ethyl, hydroxyethyl or aminopropyl radical,
  • R 18 is the radical of one of the 20 natural ⁇ -amino acids H 2 NCH (R 18 ) COOH, and M '"is a hydrogen, an alkali metal, an alkaline earth metal or a protonated alkanolamine, for example protonated mono-, di- or triethanolamine.
  • Particularly preferred alkyl-substituted amino acids are the aminopropionates according to formula (XVII a),
  • alkyl substituted amino acids are the following INCI compounds: Aminopropyl Laurylglutamine, Cocaminobutyric Acid, Cocaminopropionic Acid, DEA Lauroaminopropionate, Disodium Cocaminopropyl Iminodiacetate, Disodium Dicarboxyethyl Cocopropylenediamine, Disodium Lauriminodipropionate, Disodium Steariminodipropionate, Disodium Tallowiminodipropionate, Lauraminopropionic Acid, Lauryl Aminopropylglycine , Lauryl Diethylenediaminoglycine, Myristaminopropionic Acid, Sodium C12-15 Alkoxypropyl Iminodipropionate, Sodium Cocaminopropionate, Sodium Lauraminopropionate, Sodium Lauriminodipropionate, Sodium Lauroyl Methylaminopro- pionate, TEA Lauraminopropionate and TEA My
  • Acylated amino acids are amino acids, in particular the 20 natural ⁇ -amino acids which carry on the amino nitrogen atom the acyl radical R 19 CO of a saturated or unsaturated fatty acid R 19 COOH, where R 19 is a saturated or unsaturated C 6 . 22 alkyl, preferably C 8 . 18 alkyl, in particular a saturated Ci O -i 6 alkyl, for example a saturated C 12 . 14 alkyl.
  • the acylated amino acids can also be used as the alkali metal salt, alkaline earth metal salt or alkanolammonium salt, for example mono-, di- or triethanolammonium salt.
  • acylated amino acids are the acyl derivatives summarized in accordance with INCI under Amino Acids, for example sodium cocoyl glutamate, lauroyl glutamic acid, capryloyl glycine or myristoyl methylalanine.
  • composition according to the invention may optionally additionally contain one or more cationic surfactants (cation surfactants, INCI quaternary ammonium compounds), usually in an amount of 0.001 to 5% by weight, preferably 0.01 to 4% by weight, in particular 0, 1 to 3 wt .-%, particularly preferably 0.2 to 2 wt .-%, most preferably 0.5 to 1, 5 wt .-%, for example 1 wt .-%, based on the total agent.
  • cationic surfactants e.g., INCI quaternary ammonium compounds
  • Preferred cationic surfactants are the known quaternary surface-active compounds, in particular having an ammonium, sulfonium, phosphonium, iodonium or arsonium group. Through the use of quaternary surface-active compounds with antimicrobial action, the agent can be designed with an antimicrobial effect or its possibly existing antimicrobial effect due to other ingredients can be improved.
  • Particularly preferred cationic surfactants are the quaternary ammonium compounds (QAV, INCI quaternary ammonium compounds) according to the general formula (R ') (R ") (R'") (R IV ) N + X " , in which R 1 to R ⁇ v same represent or different C. 1 22 alkyl, C 7.
  • aralkyl radicals, or heterocyclic radicals or in the case of an aromatic compound such as pyridine-even three groups together with the nitrogen atom forming the heterocycle, for example a pyridinium or imidazolinium compound, and X "are halide ions, sulfate ions, hydroxide ions or like anions.
  • preferably at least one of the radicals has a chain length of 8 to 18, in particular 12 to 16, carbon atoms.
  • QACs are prepared by reacting tertiary amines with alkylating agents, e.g. Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced.
  • alkylating agents e.g. Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced.
  • alkylating agents e.g. Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced.
  • alkylating agents e.g. Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced.
  • the alkylation of tertiary amines with a long alkyl radical and two methyl groups succeeds particularly easily, and the quatern
  • Suitable QACs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethylbenzylammonium chloride, CAS No. 8001-54-5), benzalkone B (mp-dichlorobenzyl-dimethyl-C 1-4 -alkylammonium chloride, CAS No. 58390-78 -6), benzoxonium chloride (benzyldodecyl-bis- (2-hydroxyethyl) -ammonium chloride), cetrimonium bromide (N-hexadecyl-N, N-trimethyl-ammonium bromide, CAS No.
  • benzetonium chloride N , N-dimethyl-N- [2- [2- [p- (1,1,3,3-tetramethylbutyl) phenoxy] ethoxy] ethyl] benzylammonium chloride, CAS No. 121-54-0
  • dialkyldimethylammonium chlorides as described in U.S. Pat Di-n-decyldimethylammonium chloride (CAS No. 7173-51-5-5), didecyldimethylammonium bromide (CAS No.
  • QACs are the benzalkonium chlorides having C 8 -C 18 -alkyl radicals, in particular C 1 -C -alkyl-alkylbenzyldimethylammonium chloride.
  • a particularly preferred QAC Kokospentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ®).
  • optionally present cationic surfactants with anionic surfactants optionally present anionic surfactant and / or as little as cationic surfactant are preferably used or omitted in a particular embodiment of the invention entirely on cationic surfactants.
  • the agent according to the invention may optionally contain one or more additives from the group of surfactants, polymers and builders.
  • Substances usually in an amount of 0.001 to 5 wt .-%, preferably 0.01 to 4 wt .-%, in particular 0.1 to 3 wt .-%, particularly preferably 0.2 to 2 wt. -%, most preferably 0.5 to 1, 5 wt .-%, for example 1 wt .-%, based on the total agent.
  • Surfactants suitable as optional additives are certain of the amphoteric surfactants already described above, further anionic surfactants, nonionic surfactants and cationic surfactants, which are repeated at this point.
  • the content of surface-active additives is preferably to be selected such that the total surfactant content is in the quantitative ranges set out above.
  • suitable amphoteric surfactants are, in particular Natriumcarboxyethylkokosphospho- ethylimidazoline (Phosphoteric ® TC-6), C 8 / i 0 -Amidopropylbetain (INCI caprylic / Capramidopropyl Betaine, Betaine Tego ® 810), N-2-hydroxyethyl-N-carboxymethyl-fettklamido- ethylamine Na (Rewoteric ® AMV) and N-caprylic / capric amidoethyl-N-ethyl-propionate-Na (Rewoteric AMVSF ®) and the betaine 3- (3-cocoamido-propyl) dimethylammonium-2-hydroxypropane (INCI sultaines ; Rewoteric AM CAS ®) and the Alkylamidoalkylamin N- [N '(N "-2-hydroxyethyl
  • anionic surfactants which are suitable as additives are, in particular, anionic gemini surfactants having a diphenyloxide basic structure, 2 sulfonate groups and one alkyl radical on one or both benzene rings of the formula O 3 S (C 6 H 3 R) O (C 6 H 3 R ') SO 3 ' , in which R is an alkyl radical having, for example, 6, 10, 12 or 16 carbon atoms and R 'is R or H (Dowfax ® Dry hydrotropes Powder with C 16 alkyl radical (s); INCI Sodium Hexyldiphenyl ether sulfonates, Disodium decyl phenyl ether Di - sulfonate, Disodium lauryl phenyl ether disulfonates, Disodium Cetyl phenyl ether disulfonates) and the fluorinated anionic surfactants ammonium Cg / ⁇ -Perfluoroalkylsulfon
  • suitable nonionic surfactants are in particular C 10 dimethyl amine oxide (Ammonyx ® DO), C 10 / i 4 fatty alcohol + 1, + 2PO 6,4EO (Dehydol ® 980), C 12 / i 4 fatty alcohol + 6 EO (Dehydol ® LS6), C 8 - fatty alcohol + 1, 2PO + 9EO (Dehydol ® O10), C 16/2 o -guerbet alcohol + 8EO, n-butyl-capped (Dehypon ® G2084), mixture of several n-butyl-closed nonionic surfactants and C 8 / io APG-(Dehypon ® Ke 2555) C 8/10 fatty alcohol + 1 PO + 22EO- (2-hydroxydecyl) ether (Dehypon Ke ® 3447), C 12/14 alcohol + 5EO + 4PO -Fett- (Dehypon LS ® 54 G), C 12 / i 4 fatty alcohol
  • cationic surfactants are particularly compatible with anionic surfactants, cationic surfactants such as quaternary ammonium compounds, for example Kokospentaethoxymethyl- methosulfate (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ®).
  • quaternary ammonium compounds for example Kokospentaethoxymethyl- methosulfate (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ®).
  • Polymers suitable as additives maleic acid-acrylic acid copolymer Na salt are, in particular (Sokalan ® CP 5), modified polyacrylic acid Na salt (Sokalan ® CP 10), modified polycarboxylate Na salt (Sokalan ® HP 25) or polyalkylene suitable ,
  • suitable builders are, in particular polyaspartic acid-Na-salt, ethylene diamintriacetatkokosalkylacetamid (Rewopol ® CHT 12), methylglycine-Tri-Na-salt (Trilon ES ® 9964) and acetophosphonic (Turpinal SL ®).
  • the viscosity which is favorable for the composition according to the invention, if it is liquid, is 20 ° C. and a shear rate of 30 min -1 - measured with a Brookfield LV DV II viscometer and spindle 31, preferably in the range from 5 to 1500 mPa.sup.-1. s, preferably 10 to 1200 mPa ⁇ s, in particular 20 to 800 mPa ⁇ s Viscosities> 1500 mPa ⁇ s are also possible, but generally less preferred.
  • the viscosity of the agent according to the invention can be adjusted, in particular at a high surfactant content of the agent, e.g. be reduced by the water-soluble salts and / or solvents and / or hydro tropics contained.
  • one or more dicarboxylic acids and / or salts thereof may optionally be added, in particular a composition of Na salts of adipic, succinic and glutaric acid, for example, under the trade name Sokalan ® DSC is available.
  • the use is advantageously carried out in amounts of 0.1 to 8 wt .-%, preferably 0.5 to 7 wt .-%, in particular 1, 3 to 6 wt .-% and particularly preferably 2 to 4 wt .-%, based on the total mean.
  • a change in the dicarboxylic acid (salt) content can - especially in amounts above 2 wt .-% - contribute to a clear solution of the ingredients.
  • this component influences the solubility of the mixture.
  • This component is particularly preferably used at high surfactant contents, in particular at surfactant contents above 30 wt .-%.
  • the agent according to the invention is preferably free from dicarboxylic acid (salts).
  • the composition can optionally contain one or more further - especially in hand dishwashing detergents and cleaning agents for hard surfaces - conventional auxiliaries, active ingredients and additives, in particular UV stabilizers, perfumes, pearlescent agents (INCI opacifying agents, for example glycol distearate, for example Cutina ® AGS Fa. Cognis, or mixtures comprising, for example, the Euperlane ® from.
  • active ingredients and additives in particular UV stabilizers, perfumes, pearlescent agents (INCI opacifying agents, for example glycol distearate, for example Cutina ® AGS Fa. Cognis, or mixtures comprising, for example, the Euperlane ® from.
  • the pH of the composition according to the invention can be adjusted by means of customary pH regulators, for example acids such as mineral acids or citric acid and / or alkalis such as sodium or potassium hydroxide, wherein - in particular with the desired hand compatibility - a range from 4 to 9, preferably 5 to 8, in particular 5.5 to 7.5, is preferred.
  • acids such as mineral acids or citric acid
  • alkalis such as sodium or potassium hydroxide
  • the agent according to the invention may contain one or more buffer substances (INCI Buffering Agents), usually in amounts of 0.001 to 5 wt .-%, preferably 0.005 to 3 wt .-%, in particular 0 , 01 to 2 wt .-%, particularly preferably 0.05 to 1 wt .-%, most preferably 0.1 to 0.5 wt .-%, for example, 0.2 wt .-%, based on the total agent.
  • buffer substances which are at the same time complexing agents or even chelating agents (INCI chelating agents).
  • Particularly preferred buffer substances are citric acid or citrates, in particular the sodium and Kaliumeitrate, for example, tri- sodium citrate 2H 2 O and tripotassium-H 2 0th
  • Another object of the present invention is the use of a washing or cleaning agent according to the invention, as described above, as hand dishwashing detergents.
  • washing or cleaning agent for removing oily and / or greasy soil from dishes therefore also corresponds to a preferred embodiment of the invention.
  • Another object of the invention is the use of a surfactant system, which
  • petrochemical-based surfactants which in particular comprise alkanesulfonates (SAS), alkylbenzenesulfonates, betaines and / or alkoxylated surfactants, such as preferably fatty alcohol ethoxylates, fatty acid ethoxylates, fatty amine ethoxylates, fatty alcohol ethers,
  • surfactants based on renewable raw materials, which in particular a.
  • Sugar surfactants preferably alkyl polyglucosides (APG), sugar esters, in particular sucrose esters and / or Zuckeram ide, in particular glucamides, b. Soaps, c. Fatty acid sarcosinates, d. Estersulfonates, e. Fatty alcohol sulfates (FAS), f. Alkanolamides, g. Protein-fatty acid condensates and / or h. Fatty amines, in a hand dishwashing detergent, wherein the indication wt .-% in each case on the entire contained
  • Amount of surfactant is related. In this case, it corresponds to a preferred embodiment of the invention if in the aforementioned use a surfactant combination of APG and FAS, preferably in a ratio of 3: 1 to 1: 3, advantageously 2: 1 to 1: 2 and especially 1, 5: 1 to 1: 1, 5 is used.
  • Three hand dishwashing detergents E1 to E3 were prepared by stirring together the ingredients listed in the table below.
  • the formulation E1 corresponds to a conventional hand dishwashing detergent, while the formulations E2 and E3 contain only surfactants based on renewable raw materials. The total amount of surfactant was the same in each case.
  • the formulations E2 and E3 contained as ethanol those produced from biomass

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Abstract

L'invention concerne des détergents ou des nettoyants qui contiennent des tensioactifs à base de matières premières renouvelables. Ces agents sont tout à fait appropriés à servir de détergents pour le lavage à la main de la vaisselle. Les tensioactifs utilisés, notamment un mélange d'APG et de FAS, permettent d'obtenir des résultats exceptionnels dans le lavage à la main de la vaisselle, avant tout l'élimination des salissures de type huileux et/ou contenant des matières grasses, notamment des huiles, telles que l'huile de tournesol ou l'huile de colza, des matières grasses, telles que le beurre ou le saindoux.
PCT/EP2008/056226 2007-07-09 2008-05-21 Détergents ou de nettoyants contenant des tensioactifs à base de matières premières renouvelables WO2009007166A1 (fr)

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