WO2005113850A1 - Procede pour fabriquer une bande d'acier plaquee de zinc a chaud et comportant un revetement fer / zinc - Google Patents

Procede pour fabriquer une bande d'acier plaquee de zinc a chaud et comportant un revetement fer / zinc Download PDF

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Publication number
WO2005113850A1
WO2005113850A1 PCT/KG2004/000001 KG2004000001W WO2005113850A1 WO 2005113850 A1 WO2005113850 A1 WO 2005113850A1 KG 2004000001 W KG2004000001 W KG 2004000001W WO 2005113850 A1 WO2005113850 A1 WO 2005113850A1
Authority
WO
WIPO (PCT)
Prior art keywords
iron
zinc
sτalnοy
ποlοsy
coated steel
Prior art date
Application number
PCT/KG2004/000001
Other languages
English (en)
Russian (ru)
Other versions
WO2005113850A8 (fr
Inventor
Usenbek Kasmakun
Original Assignee
Usenbek Kasmakun
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Usenbek Kasmakun filed Critical Usenbek Kasmakun
Priority to PCT/KG2004/000001 priority Critical patent/WO2005113850A1/fr
Publication of WO2005113850A1 publication Critical patent/WO2005113850A1/fr
Publication of WO2005113850A8 publication Critical patent/WO2005113850A8/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36Elongated material
    • C23C2/40Plates; Strips
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/022Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
    • C23C2/0224Two or more thermal pretreatments
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/024Pretreatment of the material to be coated, e.g. for coating on selected surface areas by cleaning or etching

Definitions

  • Iz ⁇ b ⁇ e ⁇ enie ⁇ n ⁇ si ⁇ sya ⁇ che ⁇ n ⁇ y me ⁇ allu ⁇ gii in chas ⁇ n ⁇ s ⁇ i ⁇ ⁇ a ⁇ n ⁇ mu ⁇ izv ⁇ ds ⁇ vu and m ⁇ zhe ⁇ by ⁇ is ⁇ lz ⁇ van ⁇ ⁇ i ⁇ izv ⁇ ds ⁇ ve ⁇ n ⁇ g ⁇ s ⁇ aln ⁇ g ⁇ lis ⁇ a with ⁇ y ⁇ iem ⁇ e- ⁇ for av ⁇ m ⁇ biles ⁇ eniya, by ⁇ v ⁇ y ⁇ e ⁇ ni ⁇ i and s ⁇ i ⁇ eln ⁇ y, ele ⁇ e ⁇ niches ⁇ y ⁇ myshlenn ⁇ s ⁇ i.
  • the content of aluminum in the zinc alloy is reduced from 0.24- 0.22) to 0.16%.
  • the transition to a lower content of aluminum in zinc alloy is 20-30 hours. It should be borne in mind that in the case of transition to a lower aluminum content in 3 Zinc melting may worsen the size of the clutch of zinc alloys, which is completely steel. In the process of stamping a steel sheet with the loss of steel, it results in the destruction and deterioration (wear) of the iron and steel.
  • the method of irradiating the hot galvanized steel strip with the iron coating is carried out as follows.
  • the original material (cold-rolled product) for hot-dip galvanizing was used to select the usual low-carbon alloy steel with high-oxidized aluminum grade 08U.
  • the hot galvanized steel strip was heated by thermal combustion at 600–720 ° C in the atmosphere.
  • the steel strip with the Be- ⁇ coating does not have a noticeable cost of flow, is not affected by the deterioration.
  • a temperature of less than 600 ° C the process of non-carbonization will be slow and will take a long time.
  • temperatures above 720 ° C an excessively large diameter is found in the base, which leads to a decrease in plasticity.
  • EXAMPLE 1 A freshly wound 0.8 mm thick steel from the grade 08 was doubled to galvanizing on a non-tarnishing galvanizing system. After galvanizing, the thickness of the zinc coating was 8 microns. Carbon content in the steel base after galvanizing 0.02% ⁇ .
  • P ⁇ aza ⁇ eli ⁇ aches ⁇ va zhelez ⁇ tsin ⁇ v ⁇ g ⁇ ⁇ y ⁇ iya were: ⁇ sh ⁇ b ⁇ az ⁇ vanie ⁇ i sh ⁇ am ⁇ v ⁇ e ⁇ su ⁇ s ⁇ v ⁇ val ⁇ , is ⁇ i ⁇ anie (izn ⁇ s) ⁇ y ⁇ iya ⁇ e- ⁇ ⁇ i sh ⁇ am ⁇ v ⁇ e 450 mg / m ⁇ liches ⁇ v ⁇ sva ⁇ ny ⁇ ⁇ che ⁇ without u ⁇ udsheniya ⁇ aches ⁇ va sva ⁇ ny ⁇ s ⁇ edineny - 1200, adhesion ⁇ la ⁇ as ⁇ chnym ⁇ y ⁇ iyam was ⁇ shaya (is ⁇ y ⁇ anie ⁇ G ⁇ S ⁇ 15140-78 , G ⁇ S ⁇ 4765-73) ⁇ zi ⁇ nnaya s ⁇ y ⁇ s ⁇ zhelez ⁇ tsin ⁇ v ⁇ g ⁇ ⁇ y ⁇ iy
  • EXAMPLE 2 A freshly wound 0.8 mm thick steel from grade 08 was doubled to galvanizing on a continuous hot aggregate. 8 galvanizing. After galvanizing, the thickness of the zinc coating is 7.0 ⁇ m. The content of carbon in the steel base after hot galvanizing is 0.03%. After burning hot steel at a temperature of 720 ° C in the atmosphere, the concentration of carbon in the steel was reduced to '0.002. The thickness of the diffuse layer into the interior of the steel base is 35 ⁇ m, and the iron content in the industry is 60%, and the coefficient of normal anisotropy is 1.8 ( ⁇ ).
  • P ⁇ aza ⁇ eli ⁇ aches ⁇ va zhelez ⁇ tsin ⁇ v ⁇ g ⁇ ⁇ y ⁇ iya were: ⁇ sh ⁇ b ⁇ az ⁇ vanie ⁇ i sh ⁇ am ⁇ v ⁇ e ⁇ su ⁇ s ⁇ vue ⁇ , is ⁇ i ⁇ anie (izn ⁇ s) zhelez ⁇ tsin ⁇ v ⁇ g ⁇ ⁇ y ⁇ iya - 400 mg / m, without ⁇ liches ⁇ v ⁇ sva ⁇ ny ⁇ ⁇ che ⁇ u ⁇ udsheniya ⁇ aches ⁇ va sva ⁇ ny ⁇ s ⁇ edineny - 1400, ⁇ la ⁇ as ⁇ chnym ⁇ y ⁇ iyam adhesion was ⁇ lichnaya (is ⁇ y ⁇ anie ⁇ G ⁇ S ⁇ 15140-78, G ⁇ S ⁇ 4765-73), ⁇ zi ⁇ nnaya s ⁇ y ⁇ s ⁇ zhelez ⁇ tsin ⁇ v ⁇ g ⁇ ⁇ y

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Variable-Direction Aerials And Aerial Arrays (AREA)
  • Coating With Molten Metal (AREA)

Abstract

L'invention appartient au domaine de la métallurgie ferreuse et notamment du laminage et peut s'utiliser dans la fabrication d'une feuille mince Fe-Zn destinée à l'industrie automobile, à la fabrication d'articles ménagers et à l'industrie du bâtiment. L'invention comprend le laminage à froid, le nettoyage chimique, le réchauffement préliminaire, le recuit de recristallisation dans un four de circulation, le refroidissement, le plaquage de zinc à chaud, le refroidissement et le redressement, ce dernier stade étant précédé d'un recuit de recristallisation à thermodiffusion de la bande à 600-720 °C dans une atmosphère d'hydrogène pendant une durée permettant la réduction de la teneur en hydrogène à une valeur inférieure à 0,002 %, ainsi que la formation d'un revêtement de fer / de zinc avec une teneur en fer de 40 à 60 % et la diffusion du zinc vers l'intérieur de la base en acier à 8 - 35 micromètres, avec formation d'un ferrite de zinc dans la couche subsurfacique. L'utilisation du procédé de l'invention permet de réduire les coûts (les frais) de fabrication d'une bande d'acier avec un revêtement de Fe-Zn de 20 à 30 % en comparaison à un acier IF avec un revêtement de Fe-Zn et d'augmenter l'adhérence du revêtement de fer / zinc à la base ainsi que sa résistance à l'usure, sa capacité de être soudé, sa capacité d'accepter la peinture, sa résistance à la corrosion; elle permet en outre d'éliminer des défauts de revêtement tels que la formation de poudres ou la formation de cratères.
PCT/KG2004/000001 2004-05-20 2004-05-20 Procede pour fabriquer une bande d'acier plaquee de zinc a chaud et comportant un revetement fer / zinc WO2005113850A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/KG2004/000001 WO2005113850A1 (fr) 2004-05-20 2004-05-20 Procede pour fabriquer une bande d'acier plaquee de zinc a chaud et comportant un revetement fer / zinc

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/KG2004/000001 WO2005113850A1 (fr) 2004-05-20 2004-05-20 Procede pour fabriquer une bande d'acier plaquee de zinc a chaud et comportant un revetement fer / zinc

Publications (2)

Publication Number Publication Date
WO2005113850A1 true WO2005113850A1 (fr) 2005-12-01
WO2005113850A8 WO2005113850A8 (fr) 2006-08-03

Family

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Application Number Title Priority Date Filing Date
PCT/KG2004/000001 WO2005113850A1 (fr) 2004-05-20 2004-05-20 Procede pour fabriquer une bande d'acier plaquee de zinc a chaud et comportant un revetement fer / zinc

Country Status (1)

Country Link
WO (1) WO2005113850A1 (fr)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1227711A1 (ru) * 1983-03-31 1986-04-30 Институт Металлургии Им.А.А.Байкова Способ получени покрытий
EP0360958A2 (fr) * 1988-09-28 1990-04-04 Nippon Steel Corporation Tôle d'acier galvanisée avec une résistance au vieillissement obtenue par recouvrement continu de zinc par immersion et son procédé de fabrication
SU1750434A3 (ru) * 1986-12-29 1992-07-23 Расмет Кю (Фирма) Способ получени оцинкованной стальной полосы

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1227711A1 (ru) * 1983-03-31 1986-04-30 Институт Металлургии Им.А.А.Байкова Способ получени покрытий
SU1750434A3 (ru) * 1986-12-29 1992-07-23 Расмет Кю (Фирма) Способ получени оцинкованной стальной полосы
EP0360958A2 (fr) * 1988-09-28 1990-04-04 Nippon Steel Corporation Tôle d'acier galvanisée avec une résistance au vieillissement obtenue par recouvrement continu de zinc par immersion et son procédé de fabrication

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SHMITTS KH ET AL: "Tonly list s pokrytiem "galvanil" dlya avtomobilestroeniya.", CHEMYE METALLY., no. 3, 1989, pages 4 - 9 *

Also Published As

Publication number Publication date
WO2005113850A8 (fr) 2006-08-03

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