WO2005095767A1 - 内燃機関の排気ガス浄化装置 - Google Patents
内燃機関の排気ガス浄化装置 Download PDFInfo
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- WO2005095767A1 WO2005095767A1 PCT/JP2005/006470 JP2005006470W WO2005095767A1 WO 2005095767 A1 WO2005095767 A1 WO 2005095767A1 JP 2005006470 W JP2005006470 W JP 2005006470W WO 2005095767 A1 WO2005095767 A1 WO 2005095767A1
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- internal combustion
- combustion engine
- exhaust gas
- load
- purifying apparatus
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D23/00—Controlling engines characterised by their being supercharged
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9431—Processes characterised by a specific device
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/04—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust using liquids
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2066—Selective catalytic reduction [SCR]
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B37/00—Engines characterised by provision of pumps driven at least for part of the time by exhaust
- F02B37/12—Control of the pumps
- F02B37/24—Control of the pumps by using pumps or turbines with adjustable guide vanes
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M25/00—Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
- F02M25/14—Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture adding anti-knock agents, not provided for in subgroups F02M25/022 - F02M25/10
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/02—EGR systems specially adapted for supercharged engines
- F02M26/04—EGR systems specially adapted for supercharged engines with a single turbocharger
- F02M26/05—High pressure loops, i.e. wherein recirculated exhaust gas is taken out from the exhaust system upstream of the turbine and reintroduced into the intake system downstream of the compressor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2067—Urea
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B29/00—Engines characterised by provision for charging or scavenging not provided for in groups F02B25/00, F02B27/00 or F02B33/00 - F02B39/00; Details thereof
- F02B29/04—Cooling of air intake supply
- F02B29/0406—Layout of the intake air cooling or coolant circuit
- F02B29/0425—Air cooled heat exchangers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/0002—Controlling intake air
- F02D41/0007—Controlling intake air for control of turbo-charged or super-charged engines
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M26/00—Engine-pertinent apparatus for adding exhaust gases to combustion-air, main fuel or fuel-air mixture, e.g. by exhaust gas recirculation [EGR] systems
- F02M26/13—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories
- F02M26/22—Arrangement or layout of EGR passages, e.g. in relation to specific engine parts or for incorporation of accessories with coolers in the recirculation passage
- F02M26/23—Layout, e.g. schematics
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- the present invention relates to an exhaust gas purifying apparatus for an internal combustion engine, and more particularly, to an exhaust gas purification apparatus provided in an exhaust gas passage of an internal combustion engine with a variable exhaust turbo and purifying the exhaust gas by supplying a reducing agent.
- the present invention relates to a gas purification device.
- a device equipped with a Diesel Particulate Filter (DPF) has been developed, and NOx (nitrogen oxidizing device) has been developed.
- a device equipped with a DeNOx catalyst such as a NOx reduction catalyst or a NOx storage reduction catalyst has been developed.
- a reducing agent is supplied upstream of the exhaust gas passage in order to cause a reaction with the exhaust gas.
- This reducing agent may be supplied in atomized form (atomized) in a mist state by high-pressure injection, but is often finely divided by mixing with air. Further, with respect to fine granulation by mixing with air, in the case of an engine with an exhaust turbo, a part of the supercharged air on the supercharger side is sent to the reducing agent spraying means, and fine granulation is performed by this air. It has been proposed (for example, Patent Document 2).
- Patent Document 1 Japanese Patent Application Laid-Open No. 2000-199423 (FIG. 1, etc.)
- Patent Document 2 Japanese Patent Application Laid-Open No. 7-102949 (FIG. 1, etc.)
- the supercharged air is sent to the reducing agent injection means, albeit a little, so that the combustion air in the engine becomes insufficient, and the particulates and unburned fuel may increase.
- An object of the present invention is to provide an exhaust gas purifying apparatus for an internal combustion engine, which can improve the fineness of the reducing agent and ensure the combustion air.
- the exhaust gas purifying apparatus for an internal combustion engine includes a variable exhaust turbo for supercharging the internal combustion engine, a NOx reduction catalyst provided in an exhaust gas passage of the internal combustion engine, and the variable exhaust turbo.
- Reducing agent spraying means for spraying a reducing agent onto the NOx reduction catalyst using the supercharging pressure of the supercharger side, load detecting means for detecting a load on the internal combustion engine, and detection results of the load detecting means
- Opening control means for controlling the opening degree of the nozzle of the variable exhaust turbo on the basis of the above, wherein the opening control means controls the supercharging pressure to finely reduce the reducing agent.
- the opening degree of the variable exhaust turbo nozzle is also controlled by the opening degree control means for spraying the reducing agent. Even if the supercharging pressure does not normally rise in the range, controlling the nozzle opening of the variable exhaust turbo makes it possible to obtain a supercharging pressure higher than a predetermined value suitable for spraying the reducing agent. In this case, the reducing agent is reliably finely divided by a part of the supercharged air. Also, increasing the supercharging pressure increases the amount of combustion air supplied to the internal combustion engine, so that good combustion is performed, and the generation of particulates and the emission of unburned fuel are suppressed.
- the present invention actively controls the nozzle opening of the variable exhaust turbo for spraying the reducing agent, and adopts a configuration in which the reducing agent is sprayed with a part of the supercharging air on the conventional turbocharger side.
- the present invention is not just a combination with the configuration of a variable exhaust turbo that has a conventional power.
- the opening degree control means includes a reference load storage means storing a reference load at which the catalyst starts functioning, and the load detection means.
- a load determining unit that determines whether the detected load is equal to or greater than the reference load, and a control opening command unit that generates and issues a control opening based on a determination result of the load determining unit. It is desirable that the control opening command means maintains the supercharging pressure at or above a predetermined value by controlling the nozzle opening according to the control opening command.
- a stable operation can be performed even with respect to a change in the characteristics of the internal combustion engine and the catalyst due to a change in the outside air temperature or a change over time. It is possible to spray the reducing agent with high accuracy.
- An exhaust gas purifying apparatus for an internal combustion engine includes: a rotation speed detection unit that detects a rotation speed of the internal combustion engine; a reference rotation speed storage unit that stores a predetermined rotation speed; A rotation speed determination unit for determining whether the rotation speed detected by the speed detection unit is a rotation speed exceeding the predetermined rotation speed, and a load rotation unit for determining that the rotation speed is equal to or lower than the predetermined rotation speed. It is desirable to have an operation regulating means for regulating the operation of the control opening command means.
- the nozzle opening degree can be reduced in a low rotation speed region where the exhaust gas temperature is originally low and the catalyst does not work well, for example, in a low idle state. Since the supercharging pressure can be kept low while the pressure is kept high and the spraying of the reducing agent can be stopped, the reducing agent can be used more effectively than when only the load is used.
- the opening control means includes an opening control pattern in which a load of the internal combustion engine and a control opening command at the load correspond to each other. And a control opening command means for generating and instructing a control opening based on the opening control pattern and the detection result of the load detecting means.
- the degree control pattern preferably has a minimum value in a region near a reference load at which the catalyst starts functioning, and is a pattern for maintaining the supercharging pressure at a predetermined value or more.
- the opening degree control pattern storage means has a plurality of opening degree control patterns according to a rotation speed of the internal combustion engine, and the internal combustion engine It is preferable to include a rotation speed detecting means for detecting the rotation speed of the motor, and a pattern selection means for selecting an opening control pattern according to the detected rotation speed.
- the rotation speed as a parameter for spraying the reducing agent
- the nozzle opening degree can be reduced in a low rotation speed region where the exhaust gas temperature is originally low and the catalyst does not work well, for example, in a low idle state. Since the supercharging pressure can be kept low while the pressure is kept high and the spraying of the reducing agent can be stopped, the reducing agent can be used more effectively than when only the load is used.
- the predetermined rotational speed may be 40% or more of a rated output rotational speed. Desirable.
- the present invention when the internal combustion engine is operating in a low load range, that is, in a state where the catalyst whose exhaust gas temperature is low is not sufficiently heated but is at a low temperature and the catalyst does not work easily.
- the load detecting means detects a fuel injection amount of the internal combustion engine, and the reference load is such that the internal combustion engine has 20% of rated output torque. It is desirable that the fuel injection amount is when the above torque is output.
- the catalyst when the internal combustion engine is operating in a low load range, that is, When the temperature of the exhaust gas is low and the catalyst is not sufficiently heated and is at a low temperature, making it difficult for the catalyst to work, the catalyst can be activated by specifying the lower limit of the predetermined load and the predetermined rotation speed. Spraying of the reducing agent at the time when it does not occur is suppressed, and wasteful consumption of the reducing agent is eliminated.
- the NOx reduction catalyst is preferably a urea denitration catalyst, and the reducing agent is preferably urea water.
- the urea denitration catalyst is used as the NOx reduction catalyst and the urea water is used as the reducing agent, the NOx contained in the exhaust gas contains ammonia, which is obtained by decomposition of the sprayed urea water. Together with the catalyst and efficiently converted to harmless nitrogen gas
- the outlet side of the supercharger of the variable exhaust turbo and the reducing agent spraying unit are communicated with each other by an air extraction passage for feeding supercharged air. It is desirable that a check valve and a Z or on-off valve be provided in the extraction passage. According to the present invention, since the check valve and the Z or on-off valve are provided in the air extraction passage, even if the supercharging pressure of the variable exhaust turbo on the supercharger side is lower than the pressure of the exhaust gas. By closing these valves, it is possible to prevent exhaust gas from flowing back.
- the reducing agent spraying method of the supercharged air is intentionally performed by operating the on-off valve. It is possible to stop the supply to the side. For example, when the outside temperature is low in winter, etc., it takes a long time to heat the NOx reduction catalyst, or the NOx reduction catalyst is not sufficiently heated, and air is supplied (supply of reducing agent). If the temperature of the NOx reduction catalyst is significantly lowered due to this, the supply of air is stopped until the NOx reduction catalytic power exhaust gas is surely heated to prevent waste of the reducing agent. it can.
- an air tank is provided in an air extraction passage between an outlet side of the supercharger and the on-off valve, and an outlet side of the supercharger and the air tank are provided. It is desirable that a pressure control valve be provided in an air extraction passage between the air tank.
- the air tank since the air tank is provided, by storing the supercharged air in the air tank, the air tank acts as an accumulator, and a stable pressure for spraying the reducing agent is secured. Become like Also, the pressure fluctuation (pulsation) of the supplied air It is suppressed, and spraying at a stable pressure is also possible in this regard.
- the supercharging pressure be equal to or higher than a predetermined value, equal to or higher than 0.05 MPa (0.5 bar).
- “supercharging pressure equal to or higher than a predetermined value” refers to the pressure of the supercharging air capable of finely reducing the reducing agent.
- the spray state is improved.
- the opening degree control means controls the nozzle opening degree by the control opening degree command to reduce the supercharging pressure from the area near the reference load. It is desirable to keep approximately constant.
- the supercharging pressure is kept constant to reduce the amount of supercharged air. Section is suppressed from being supplied excessively for spraying the reducing agent. This prevents the temperature of the NOx reduction catalyst from being further lowered by the supplied air, so that wasteful consumption of the reducing agent is reliably suppressed, and the NOx reduction catalyst works well.
- the opening control means controls the nozzle opening toward the closed side before reaching the reference load vicinity region. It is desirable that the boost pressure be maintained at a predetermined value or more in a specific load region that is equal to or higher than the reference load by controlling the opening pressure to the opening side later.
- the nozzle opening is controlled to the closed side, After this, the boost pressure is controlled to the open side to obtain a supercharging pressure equal to or higher than the predetermined value.In the middle and high speed rotation speed range and middle to high load range, the supercharging pressure is gradually controlled by closing again. Can be raised.
- FIG. 1 is a schematic view showing the periphery of an internal combustion engine equipped with an exhaust gas purification device according to a first embodiment of the present invention.
- FIG. 2 is a block diagram showing a structure of a controller according to the first embodiment.
- FIG. 3 is a flowchart for explaining nozzle opening control in the first embodiment.
- FIG. 4 is a diagram illustrating an effect range in the first embodiment.
- FIG. 5 is a block diagram showing a structure of a controller according to a second embodiment of the present invention.
- FIG. 6 is an edge view for explaining nozzle opening control in a second embodiment of the present invention.
- FIG. 7 is a schematic view showing a third embodiment of the present invention.
- FIG. 8 is a schematic view showing a fourth embodiment of the present invention.
- reference load storage means 152 ... reference rotation speed storage means, 153 ... opening Control pattern storage means, 154: load determination means, 15 5: control opening command means, 156: pattern selection means, 157: rotation speed determination Means, 158... Operation regulation means, P... Charge pressure.
- FIG. 1 is a schematic diagram showing a diesel engine (internal combustion engine) 1 around which an exhaust gas purification device 10 according to a first embodiment of the present invention is mounted.
- a diesel engine (hereinafter simply referred to as an engine) 1 has a variable exhaust turbo 2.
- the supercharged air from the turbocharger 2A side of the variable exhaust turbo 2 is supplied to the engine body 4 via the aftercooler 3, and the exhaust gas from the engine body 4 is supplied to the variable exhaust turbo 2 After rotating the compressor 2B, it is discharged through the exhaust gas passage 5.
- the engine 1 of the present embodiment is provided with an EGR (Exhaust Gas Recirculation) device 6, which is configured to return a part of the exhaust gas from the exhaust manifold to the intake manifold.
- the oxygen concentration in the combustion chamber is suppressed, the combustion is moderated, and the combustion temperature is reduced, thereby reducing NOx generated during high-temperature combustion.
- the EGR device 6 is a so-called cooled EGR, and has a configuration in which the EGR gas is cooled by a dedicated radiator 6A to further reduce the combustion temperature.
- Reference numeral “7” in the figure is a radiator for cooling the engine body 4.
- the exhaust gas purifying apparatus 10 includes the above-described variable exhaust turbo 2, a urea denitration catalyst (NOx reduction catalyst) 11, a reducing agent spraying unit 12, a reducing agent supply unit 13, air supply means 14, a controller (opening degree control means) 15A for controlling them collectively, and a DPF.
- the urea denitration catalyst (NOx reduction catalyst) 11 is provided in the exhaust gas passage 5.
- the reducing agent spraying means 12 sprays urea water (reducing agent) on the urea denitration catalyst 11.
- the reducing agent supply means 13 supplies urea water to the reducing agent spraying means 12.
- the air supply means 14 extracts a part of the supercharged air from the intake passage 8 and supplies it to the reducing agent spraying means 12.
- the controller (opening control means) 15A controls these components as a whole.
- the DPF is arranged upstream of the reducing agent spraying means 12.
- variable exhaust turbo 2 is provided with a power electrician or an actuator 2C driven by fluid energy such as hydraulic pressure, pneumatic pressure, or the like, which is not illustrated or described in detail.
- the nozzle vane is driven by the actuator 2C.
- the nozzle opening is adjusted by driving, and the opening control is controlled by the controller 15A.
- the urea denitration catalyst 11 is a base metal such as zeolite and vanadium, reacts ammonia obtained from urea water as a reducing agent with NOx in exhaust gas, and decomposes NOx into nitrogen and oxygen. I'm going to purify.
- a two-fluid type injection nozzle can be adopted.
- it is a double-pipe structure nozzle, in which urea water is sucked from the outside using negative pressure due to the injection of supercharged air from the center side, and urea water is sprayed in fine mist. It is.
- urea Any structure can be used as long as water can be sprayed with fine particles.
- the reducing agent supply means 13 has a structure in which a storage tank 13C also supplies urea water to the reducing agent spraying means 12 using a pump 13B provided in a reducing agent supply passage 13A.
- A is provided with an electromagnetic solenoid type on-off valve 13D. The opening and closing of the on-off valve 13D and the driving of the pump 13B are controlled by the controller 15A.
- the air supply means 14 is a part of the supercharged air to which the force on the outlet side of the supercharger 2A of the variable exhaust turbo 2 is also supplied through an air extraction path 14A that connects the intake path 8 and the reducing agent spraying means 12.
- a check valve 14B is provided upstream of the air extraction passage 14A to prevent exhaust gas from flowing back, and an electromagnetic solenoid which is opened and closed as necessary is provided downstream of the air discharge passage 14A.
- An open / close valve 14C is provided. The opening and closing of the on-off valve 14C is also controlled by the controller 15A.
- a fuel injection device 4A is provided in the engine body 4, and a fuel injection amount signal is output from the fuel injection device 4A.
- a supercharging pressure sensor 16 is provided in an intake passage to the engine body 4, and a supercharging pressure sensor 16 outputs a supercharging pressure signal.
- An exhaust gas temperature sensor 17 is installed in the exhaust gas passage 5, and an exhaust gas temperature signal is output from the exhaust gas temperature sensor 17.
- the fuel injection device 4A, the supercharging pressure sensor 16, and the exhaust gas temperature sensor 17 have functions as load detecting means of the present invention, and the fuel injection amount signal, the supercharging pressure signal, and the exhaust gas temperature detected respectively.
- a signal is output to the controller 15A as a load.
- An engine speed sensor 18 is installed in the engine body 4, and outputs an engine speed signal from the engine speed sensor 18.
- a turbo rotation speed sensor 19 is provided in the variable exhaust turbo 2, and a turbo rotation speed signal is output from the turbo rotation speed sensor 19.
- the engine rotation speed sensor 18 and the turbo rotation speed sensor 19 have a function as a rotation speed detection means of the present invention, and the detected engine rotation speed signal and turbo rotation speed signal are respectively used as the rotation speed by the controller. Output to 15A.
- controller 15A controls the nozzle opening of the variable exhaust turbo 2 The structure will be described.
- the controller 15A is configured to include a CPU (microprocessor) or an arbitrary control circuit.
- the load detection means the fuel injection device 4A, the supercharging pressure sensor 16, the exhaust temperature sensor 17
- the actuator 2C for adjusting the nozzle opening, the pump 13B, and the on-off valves 13D and 14C are controlled based on output signals from the speed detecting means (the engine speed sensor 18 and the turbo speed sensor 19).
- the controller 15A which is an opening control unit, includes a reference load storage unit 151, a load determination unit 154, a reference rotation speed storage unit 152, a rotation speed determination unit 157, a control opening command unit 155, and an operation restriction unit 158. Is done.
- the parameters for controlling these include the temperature of the urea denitration catalyst 11 and the temperature of the engine cooling water detected by a temperature sensor (not shown), the residual amount of urea water in the storage tank 13C detected by a liquid level sensor, and the like. and so on.
- controller 15A is usually a large force that controls the fuel injection amount and the like in the engine 1, but only the description necessary for spraying urea water will be given here.
- the reference load storage means 151 stores the fuel injection amount, the exhaust temperature, and the supercharging pressure suitable for the reduction of the reducing agent in the reducing agent spraying means 12 corresponding to the reference load at which the catalyst 11 starts functioning. It is remembered.
- the fuel injection amount corresponding to the reference load in the present embodiment is a fuel injection amount when the diesel engine 1 outputs a torque of 20% or more of the rated output torque.
- the load determining means 154 determines whether the load detected by the load detecting means (the fuel injection device 4A, the supercharging pressure sensor 16, the exhaust gas temperature sensor 17) is equal to or higher than the reference load. Thus, it is determined whether or not the spray pressure that allows the reducing agent to be finely divided by the reducing agent spraying means 12 in a state where the catalyst 11 can start functioning is obtained.
- the predetermined supercharging pressure P serving as a criterion for determining the supercharging pressure is equal to or higher than the minimum pressure value suitable for finely dividing the urea water, and is equal to or higher than 0.05 MPa (0.5 bar). is there.
- the reference engine speed storage means 152 stores a predetermined engine speed N1.
- the predetermined engine speed N1 in this embodiment is 40% or more of the rated output engine speed Nr of the engine.
- the rotation speed determination means 157 determines whether the engine rotation speed detected by the rotation speed detection means (engine rotation speed sensor 18) is equal to or higher than a predetermined rotation speed N1. Thus, it is determined whether the catalyst 11 is ready to start functioning.
- the control opening command means 155 determines the increase or decrease of the opening based on the determination result of the load determination means 154, generates a final control opening, and uses a nozzle opening adjustment function. Outputs the opening control command to data 2C. Control commands are output to the pump 13B and the on-off valves 13D and 14C as needed.
- the operation restricting unit 158 restricts the operation of the load determining unit 154 and the control opening command unit 155, and does not perform the subsequent processing. To do.
- the controller 15A controls the nozzle opening degree according to the load fluctuation and the engine rotation speed so that the predetermined supercharging that enables the fine particles of the reducing agent to be performed. Get pressure.
- the controller 15A After reading the variable exhaust turbo opening degree map stored in the attached ROM (Read Only Memory) (process S1), the controller 15A reads the rotation speed detection means (engine rotation speed sensor 18). The engine rotation speed output from the ECU and the fuel injection amount output from the load detecting means (fuel injection device 4A) are acquired (process S2).
- the controller 15A selects an opening value corresponding to the engine speed and the fuel injection amount from a variable exhaust turbo opening map (not shown in FIG. 2), and performs initial setting as a nozzle opening (processing S3).
- the load determining means 154 described later determines that the supercharging pressure is larger than the predetermined value P, and When the controller 15A determines that the nozzle opening is smaller than the initial setting value, the initial setting value becomes the final nozzle opening.
- controller 15A acquires the supercharging pressure and the exhaust temperature output from the load detecting means (the supercharging pressure sensor 16 and the exhaust temperature sensor 17) (process S4).
- the rotational speed determining means 157 determines whether the engine rotational speed output from the rotational speed detecting means (engine rotational speed sensor 18) is greater than a predetermined rotational speed N1 (Process S5).
- the operation restricting means 158 which is determined to be equal to or lower than the predetermined rotational speed N1, restricts the operations of the load determining means 154 and the control opening command means 155 by not performing the subsequent processing (processing S5 ).
- the load determination unit 154 determines whether the fuel injection amount output from the load detection unit (the fuel injection device 4A) is larger than the reference load T1 stored in the reference load storage unit 151. (Processing S6).
- the load determining means 154 determines whether or not the exhaust temperature output from the load detecting means (the exhaust temperature sensor 17) is equal to or higher than a predetermined value (process S7).
- the controller 15A determines whether the area of the nozzle opening of the variable exhaust turbo 2 is the minimum (process S8). Further, the controller 15A determines whether or not the turbo rotation speed output from the rotation speed detecting means (the turbo rotation speed sensor 19) is equal to or less than an allowable value (processing S9).
- the load determination means 154 determines whether the boost pressure output from the load detection means (the boost pressure sensor 16) is greater than the predetermined value P (process S10).
- the controller 15A determines whether the nozzle opening is less than the initial set value set in the process S3 (process Sll).
- the load determining means 154 determines whether the value is greater than a value obtained by adding an arbitrary value a to the supercharging pressure predetermined value P output from the load detecting means (supercharging pressure sensor 16) (process S12).
- the control opening command means 155 reduces the nozzle opening (based on the above processing result). Process 13), increase the nozzle opening Il (process S14), or determine the setting according to the variable exhaust turbo opening map, and generate the final control opening. Then, the control opening command means 155 outputs an opening control command to the actuator 2C for adjusting the nozzle opening. Control commands are output to the pump 13B and the on-off valves 13D and 14C as needed.
- the controller 15A opens the variable exhaust turbo 2
- the nozzle opening is determined according to the degree map (processing S3). Further, the on-off valves 13D and 14C are closed until the load force T1 or the engine rotation speed reaches N1, and the supply of the supercharged air and urea water to the reducing agent spraying means 12 is stopped. The urea solution is prevented from dripping.
- the control opening command means 155 Issues a command to control the nozzle opening of the variable exhaust turbo 2 to the closing side (process S13), and increases the supercharging pressure to the value of P. Then, by operating the nozzle opening to the closing side, the supercharged air increases in calorie, the air-fuel ratio increases, and the combustion air increases.
- the control opening degree instruction means 155 determines the nozzle opening degree.
- a command is issued to control to open (step S14).
- the supercharging pressure is maintained at approximately P. It should be noted that a supercharging pressure exceeding the supercharging pressure P may be obtained to further promote the urea water fine-graining. However, this reduces the air flow rate sent to the reducing agent spraying means 12 side. If the temperature is increased more than necessary, the temperature of the urea denitration catalyst 11 may be lowered, and in this embodiment, the temperature is kept substantially constant. Then, as the air-fuel ratio gradually decreases as the nozzle opening increases, the nozzle opening tends to close compared to normal control, so that sufficient combustion air is also obtained. Has become.
- the controller 15A If it is determined that the nozzle opening is smaller than the initial set value (Process Sl 1), the control opening command means 155 controls the nozzle opening to the variable exhaust turbo 2 control for the original purpose, that is, the low load range power is high. Output is continuously and smoothly generated up to the load range, and control is returned to eliminate the time lag. That is, the area from T1 to this point corresponds to a specific load area in the present invention.
- the controller 15A of the exhaust gas purifying apparatus 10 also controls the nozzle opening of the variable exhaust turbo 2 for spraying urea water, when the engine 1 is in the low load region of T1 to T2, Even if the supercharging pressure does not normally rise, the supercharging pressure ⁇ suitable for spraying urea water can be obtained by controlling the nozzle opening of the variable exhaust turbo 2 so that it is more closed than before. At this time, the urea water can be finely divided by a part of the supercharged air.
- the amount of combustion air supplied to the engine 1 increases, so that good combustion can be realized, and generation of particulates and emission of unburned fuel can be suppressed.
- the temperature of the exhaust gas is low, and the urea denitration catalyst 11 is not sufficiently heated and does not work well, that is, the area where the load is less than 20% of the rated torque Tr but less than T1, or the engine speed.
- the turbocharged air is shut off by closing the on-off valves 13D and 14C, etc., and the urea water is not sprayed. Can be prevented from being wasted.
- FIG. 4 is a torque diagram showing a relationship between an engine load and a rotation speed.
- the hatched portion indicates that the urea water is satisfactorily used when the controller 15A is not used for spraying the urea water, that is, when the nozzle opening of the variable exhaust turbo 2 is controlled as before.
- the area to be sprayed is shown.
- the supercharging pressure is increased by controlling the nozzle opening even in a small low-load region where the supercharging pressure is low and spraying is not performed well in the past. Can be surely sprayed.
- the urea denitration catalyst 11 is used as the NOx reduction catalyst and urea water is used as the reducing agent, the NOx contained in the exhaust gas is converted into ammonia obtained by decomposition of the sprayed urea water. At the same time, it comes into contact with the catalyst and can be efficiently converted to harmless nitrogen gas.
- the on-off valve 14C is provided, even when the engine 1 is driven at a predetermined load T1 or more, the on-off valve 14C is operated to intentionally spray the reducing agent with supercharged air. Means Supply to the 12 side can be stopped. Therefore, when the outside temperature is low in winter, etc., it takes a long time to heat the urea denitration catalyst 11 or the urea denitration catalyst 11 is not sufficiently heated, and the air supply (supply of urea water ), The supply of air can be stopped until the urea denitration catalyst 11 is reliably heated by the exhaust gas, and the reducing agent is wasted. Can be prevented.
- the supercharging pressure at the time of spraying the urea water is set to 0.05 MPa (0.5 bar) or more, so that a good spray state can be realized.
- the supercharging pressure In controlling the supercharging pressure, in a specific region where the temperature of the urea denitration catalyst 11 does not easily rise, such as a low load region between T1 and T2, the supercharging pressure is set to a substantially constant value. In order to maintain it, it is possible to prevent a part of the supercharged air from being supplied excessively for spraying urea water. This can prevent the temperature of the urea denitration catalyst 11 from further lowering due to the supplied air, so that wasteful consumption of urea water can be suppressed more reliably and the urea denitration catalyst 11 can work reliably.
- the feedback control is performed, and based on the detection results of the load such as the fuel injection amount, the supercharging pressure, the exhaust temperature, and the rotation speed of the engine and the variable exhaust turbo, the nozzle is controlled. Adjust the opening and take the control method.
- the second embodiment based on the fuel injection amount and the engine rotation speed, the second embodiment uniquely uses the opening control pattern stored in the opening control pattern storage unit 153 based on the fuel injection amount and the engine rotation speed.
- This embodiment is different from the first embodiment in that so-called feed forward control for controlling the opening degree is performed.
- the opening control means 15B includes an opening control pattern storage means 153, a pattern selection means 156, and a control opening command means 155.
- the opening control pattern storage means 153 stores an opening control pattern that takes a local minimum value in a region near the reference load at which the catalyst starts functioning and maintains the supercharging pressure at a predetermined value P or more. Memorize a plurality according to.
- the no-turn selecting means 156 selects one of the plurality of opening control patterns stored in the opening control pattern storage means 153 according to the fuel injection amount output by the fuel injection device and the detected engine rotation speed. Select a pattern.
- the control opening command means 155 generates and issues a control opening based on the opening control pattern selected by the pattern selection means 156.
- the nozzle of the variable exhaust turbo 2 is compared with the conventional control (control not considering the urea water spray) indicated by the two-dot chain line.
- the nozzle opening for controlling the opening to the closing side is stored.
- the boost pressure is increased to the value P at an early stage.
- the supercharged air increases in calorie, the air-fuel ratio increases, and the combustion air increases.
- the on-off valves 13D and 14C are closed until the load force T1 is reached, thereby preventing the urea water from dripping unnecessarily.
- the nozzle opening is controlled to be on the open side, that is, to take a minimum value in the region near the reference load T1.
- the chirping degree is stored.
- the supercharging pressure during this period is kept constant at substantially P.
- the point that the region from T1 to T2 corresponds to a specific load region in the present invention is the same in the present embodiment.
- # 1 and # 2 the force with which the air-fuel ratio gradually decreases The nozzle opening tends to close as compared with the normal control, so that sufficient combustion air can be obtained.
- the above-described effects (1) to (8) are obtained, and since the control response is high due to the feedforward, the speed can be reduced even when the load or the rotation speed suddenly changes. And powerful response is possible.
- a stable effect as in the first embodiment may not be obtained with respect to a change in the characteristics of the internal combustion engine and the catalyst due to a change in the outside air temperature or a change over time.
- FIG. 7 shows an exhaust gas purification device 10 according to a third embodiment of the present invention.
- an air tank 14D is provided between the supercharger 2 ⁇ outlet side and the on-off valve 14C in the air extraction passage 14A, and a check valve is provided between the air tank 14D and the supercharger 2 ⁇ outlet side.
- This embodiment differs from the first embodiment in that a pressure control valve 14E is provided instead.
- Other configurations and control methods are the same as in the first embodiment.
- the air tank 14D in the present embodiment functions as an accumulator for storing air pressure for supplying to the reducing agent spraying means 12.
- the pressure control valve 14E opens the air extraction passage 14A upstream of the air tank 14D to release the air sent from the turbocharger 2 ⁇ side and release the air from the air tank 14D.
- Protect 14D etc. In this embodiment, the effects (1) to (8) described above can be obtained in the same manner by the same configuration as in the first embodiment. It has the following effects.
- An air tank 14D that functions as an accumulator is provided on the air extraction passage 14A.By storing air pressure in this air tank 14D, a stable pressure for spraying urea water is secured. it can. Further, pressure fluctuations (pulsations) of the air in the air supply means 14 can be effectively attenuated by the air tank 14D, and spraying at a stable pressure can be realized also in this respect.
- the pressure control valve 14E is provided on the upstream side of the air tank 14D, it is possible to prevent the pressure in the air extraction passage 14A including the air tank 14D from excessively rising, and Protection within the system can be achieved.
- the fourth embodiment of the present invention shown in FIG. 8 differs from the first embodiment in that only a check valve 14B is provided on an air extraction passage 14A. Therefore, in the present embodiment, the structure of the air supply means 14 can be simplified, and the control of the on-off valve 14C (FIG. 1) by the controller 15A can be dispensed with. Other configurations and control methods are the same as in the first embodiment.
- the present invention is not limited to the above-described embodiment, but includes other configurations and the like that can achieve the object of the present invention.
- the present invention includes the following modifications and the like.
- the supercharging pressure ⁇ when the load is between T1 and T2, the supercharging pressure ⁇ is controlled so as to be substantially constant at 0.05 MPa (0.5 bar).
- the boost pressure may exceed 05MPa (0.5bar).
- the temperature of the exhaust gas is low, and the operation of the urea denitration catalyst 11 is also weak.
- the supercharging pressure ⁇ is greatly increased here, the amount of air supplied will increase.
- the temperature of the urea denitration catalyst 11 may be further lowered, and the sprayed urea water will be used without permission. For this reason, even when increasing the supercharging pressure ⁇ , it is necessary to refrain from increasing it excessively, and it is preferable to suppress it to about 0.1 MPa (lbar).
- the supercharging pressure P is constant, and in addition, 0.05 to 0.lMPa (0 The supercharging pressure P can be varied almost linearly in the range of 5 to lbar)! ,.
- the urea denitration catalyst 11 using urea water as a reducing agent was used.
- a DeNOx catalyst using hydrocarbon (HC) such as fuel as a reducing agent, or a NOx storage reduction A catalyst or the like may be used.
- the load refers to all loads required for the engine or those having a correlation with the loads, and is not necessarily related to the force.
- a value measured by a torque meter may be used as the load.
- the reference load storage unit 151 and the reference rotation speed storage unit 152 exist as storage units, and the load determination unit 154 and the rotation speed determination unit 157 exist as determination units.
- a load storage unit having a plurality of reference loads according to the rotation speed, and a reference load selection unit to select a reference load according to the detected rotation speed may be provided.
- the initial opening setting from the variable exhaust turbo opening map and subsequent judgment may be performed using only the load without using the rotation speed.
- a force in which only the feed-forward control for uniquely controlling the opening by the opening control pattern is performed is combined with a feedback control using a load or the like detected by another. May be used.
- the exhaust gas purifying apparatus of the present invention can be applied to any equipment having an internal combustion engine with a variable exhaust turbo, such as automobiles such as trucks and buses, and various industrial machines including construction machines.
- a variable exhaust turbo such as automobiles such as trucks and buses
- various industrial machines including construction machines.
- the benefits that contribute to environmental improvement are great!
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
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- General Chemical & Material Sciences (AREA)
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- Exhaust Gas After Treatment (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
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JP2006511840A JP4653736B2 (ja) | 2004-04-02 | 2005-04-01 | 内燃機関の排気ガス浄化装置 |
DE112005000759T DE112005000759B4 (de) | 2004-04-02 | 2005-04-01 | Abgasemissions-Steuervorrichtung eines Verbrennungsmotors |
US11/547,057 US7765793B2 (en) | 2004-04-02 | 2005-04-01 | Exhaust emission control device of internal combustion engine |
SE0602037A SE529691C2 (sv) | 2004-04-02 | 2006-10-02 | Avgasemissionsregleranordning för en förbränningsmotor |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004-110009 | 2004-04-02 | ||
JP2004110009 | 2004-04-02 |
Publications (1)
Publication Number | Publication Date |
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WO2005095767A1 true WO2005095767A1 (ja) | 2005-10-13 |
Family
ID=35063834
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2005/006470 WO2005095767A1 (ja) | 2004-04-02 | 2005-04-01 | 内燃機関の排気ガス浄化装置 |
Country Status (6)
Country | Link |
---|---|
US (1) | US7765793B2 (ja) |
JP (1) | JP4653736B2 (ja) |
KR (1) | KR100787484B1 (ja) |
CN (1) | CN100562652C (ja) |
DE (1) | DE112005000759B4 (ja) |
WO (1) | WO2005095767A1 (ja) |
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JP2007285242A (ja) * | 2006-04-19 | 2007-11-01 | Denso Corp | 内燃機関用排気浄化装置 |
WO2008066482A1 (en) * | 2006-11-29 | 2008-06-05 | Scania Cv Ab (Publ) | Arrangement and method for a supercharged combustion engine |
WO2009032141A1 (en) * | 2007-08-30 | 2009-03-12 | Caterpillar Inc. | Machine, engine system and operating method |
US20110041815A1 (en) * | 2007-02-05 | 2011-02-24 | Volvo Lastvagnar Ab | Exhaust purification system with a diesel particulate filter and a method of cleaning said filter |
JP2012247360A (ja) * | 2011-05-30 | 2012-12-13 | Isuzu Motors Ltd | 尿素水補給スタンド案内装置 |
WO2013088850A1 (ja) * | 2011-12-13 | 2013-06-20 | 日立造船株式会社 | 尿素水噴霧構造 |
DE102007000333B4 (de) * | 2006-06-16 | 2014-02-20 | Denso Corporation | Abgasemissionsreinigungsvorrichtung, Zusatzmittelzufuhrvorrichtung und Abgasreinigungssystem |
US8661786B2 (en) * | 2008-07-01 | 2014-03-04 | Woodward, Inc. | Passive secondary air delivery system for two bed catalyst system |
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JP2009221881A (ja) * | 2008-03-13 | 2009-10-01 | Yanmar Co Ltd | エンジン |
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KR101394037B1 (ko) * | 2012-08-28 | 2014-05-09 | 기아자동차 주식회사 | 배기가스 배기시스템 |
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DE102014010250B3 (de) * | 2014-07-11 | 2015-07-23 | Thomas Magnete Gmbh | Verfahren zur Einspritzung von Flüssigkeit in den Abgasstrang eines Verbrennungsmotors |
DE102015005051A1 (de) * | 2015-04-21 | 2016-10-27 | Man Diesel & Turbo Se | System zur Eindüsung von Harnstoff in einen Abgasstrang |
JP6213523B2 (ja) * | 2015-06-09 | 2017-10-18 | トヨタ自動車株式会社 | 内燃機関の制御装置 |
US10273848B2 (en) | 2016-09-14 | 2019-04-30 | Caterpillar Inc. | Reductant delivery system |
US20190195106A1 (en) * | 2017-12-22 | 2019-06-27 | Cummins Emission Solutions Inc. | Systems and methods for air assisted injection of a reductant into an aftertreatment system |
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- 2005-04-01 CN CNB2005800103187A patent/CN100562652C/zh not_active Expired - Fee Related
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Cited By (11)
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JP2007285242A (ja) * | 2006-04-19 | 2007-11-01 | Denso Corp | 内燃機関用排気浄化装置 |
JP4687548B2 (ja) * | 2006-04-19 | 2011-05-25 | 株式会社デンソー | 内燃機関用排気浄化装置 |
DE102007000333B4 (de) * | 2006-06-16 | 2014-02-20 | Denso Corporation | Abgasemissionsreinigungsvorrichtung, Zusatzmittelzufuhrvorrichtung und Abgasreinigungssystem |
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US20110041815A1 (en) * | 2007-02-05 | 2011-02-24 | Volvo Lastvagnar Ab | Exhaust purification system with a diesel particulate filter and a method of cleaning said filter |
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WO2009032141A1 (en) * | 2007-08-30 | 2009-03-12 | Caterpillar Inc. | Machine, engine system and operating method |
US8069651B2 (en) | 2007-08-30 | 2011-12-06 | Caterpillar Inc. | Machine, engine system and operating method |
US8661786B2 (en) * | 2008-07-01 | 2014-03-04 | Woodward, Inc. | Passive secondary air delivery system for two bed catalyst system |
JP2012247360A (ja) * | 2011-05-30 | 2012-12-13 | Isuzu Motors Ltd | 尿素水補給スタンド案内装置 |
WO2013088850A1 (ja) * | 2011-12-13 | 2013-06-20 | 日立造船株式会社 | 尿素水噴霧構造 |
Also Published As
Publication number | Publication date |
---|---|
KR100787484B1 (ko) | 2007-12-21 |
US7765793B2 (en) | 2010-08-03 |
US20070271918A1 (en) | 2007-11-29 |
DE112005000759T5 (de) | 2007-02-22 |
CN1938499A (zh) | 2007-03-28 |
JPWO2005095767A1 (ja) | 2008-02-21 |
JP4653736B2 (ja) | 2011-03-16 |
KR20060128038A (ko) | 2006-12-13 |
DE112005000759B4 (de) | 2008-05-08 |
CN100562652C (zh) | 2009-11-25 |
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