WO2005087179A1 - Kit dentaire pour enrober les plans dentaires - Google Patents

Kit dentaire pour enrober les plans dentaires Download PDF

Info

Publication number
WO2005087179A1
WO2005087179A1 PCT/JP2005/004332 JP2005004332W WO2005087179A1 WO 2005087179 A1 WO2005087179 A1 WO 2005087179A1 JP 2005004332 W JP2005004332 W JP 2005004332W WO 2005087179 A1 WO2005087179 A1 WO 2005087179A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
meth
coating
dental
filler
Prior art date
Application number
PCT/JP2005/004332
Other languages
English (en)
Japanese (ja)
Inventor
Tetsuya Toida
Machiko Takashi
Original Assignee
Sun Medical Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sun Medical Co., Ltd. filed Critical Sun Medical Co., Ltd.
Priority to JP2006511005A priority Critical patent/JPWO2005087179A1/ja
Publication of WO2005087179A1 publication Critical patent/WO2005087179A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds

Definitions

  • the present invention relates to a dental coating material. More specifically, it is used for improving the aesthetics of teeth, such as giving gloss to teeth and adjusting the color tone by applying to teeth, for protecting !, dental coating materials, dental etching agents, dental
  • the present invention relates to a dental coating kit, which may include a primer for dental use, a dental adhesive, and the like.
  • Methods for improving the color tone of the natural tooth surface include (1) a method using a chemical solution such as hydrogen peroxide solution, and (2) a method of attaching a prosthesis called a laminate veneer.
  • (2) the laminating base method is a method of adhering a porcelain resin having a small thickness to the dentin, and is excellent in aesthetics (for example, see Non-Patent Documents 1 and 2).
  • the artificial material is loaded on the tooth material by a method such as coating the surface of the tooth material with a laminating base method or a dental composite resin.
  • the tooth material In the case of the laminating method, the tooth material must be cut by the thickness of the porcelain resin, and (2) the porcelain resin, that is, the prosthesis is produced. In order to do so, high technical skills are required, (3) complicated processing steps are required, and (4) treatment costs are high.
  • Non-Patent Document 1 Asami Tanaka, Natsu Serbage, "Porcelain Laminate Bar”, Dental Diamond Special Issue Aesthetic Dental 21—In Search of Creation of Individuality and Healthy Beauty, Dental Diamond Ltd., 2001, p. 76-81
  • Non-Patent Document 2 Akira Senda and 2 others, "Veneer Restoration for Discolored Teeth", Aichi Gakuin University Dental Journal, 1986, Vol. 24, P. 553-566
  • the present invention provides a dental coating kit that can be adjusted to a desired color tone, can work safely and quickly in a short time, and can enhance the glossiness of the tooth surface without scraping the tooth surface.
  • the purpose is to provide.
  • the present inventors have conducted intensive studies to solve the above-mentioned problems relating to the aesthetics of teeth. As a result, a coating material comprising a specific composition was found to have high safety, workability, and aesthetics (bleaching properties). The present inventors have found that the present invention has the above-mentioned ability, and have completed the present invention.
  • a coating containing (a) an ethylenically unsaturated compound, (b) a polymerization initiator, and (c) a filler.
  • the value of% by weight is defined as f, and the (c) filter in the coating composition ( ⁇ ) filled in the container ( ⁇ ) is
  • the coating composition (I) has a filler content weight% (f) of 5-80% by weight.
  • said coating yarn ⁇ product ([pi) FILLER one containing by weight 0/0 (f) is a 0 20 wt%
  • One type is preferably a (meth) acrylate ester monomer.
  • the coating composition (I) may further contain a coloring agent.
  • the dental coating kit according to the present invention further comprises a container (III) filled with a dental etching agent (III), a container (IV) filled with a dental primer (IV), and a dental adhesive. It may include at least one type of container having a group strength selected from the container (V) filled with the agent (V).
  • the coating kit according to the present invention can be adjusted to a desired color tone, can work safely and in a short time, and can enhance the gloss of the tooth surface.
  • the coating material is applied to the tooth surface using the dental coating kit according to the present invention, the occurrence of coating unevenness and thickness unevenness is suppressed, and the coating film is thin, so that the tooth structure is reduced. It is also excellent in wearing feeling without having to cut the surface.
  • the dental coating material used in the present invention includes the coating composition (I) filled in the container (I) and the coating composition ( ⁇ ) filled in the container (II), and the composition (I) and the composition ( ⁇ ) to be used as a dental coating material for forming an opaque coating material layer.
  • the coating composition (I) used in the present invention comprises at least (a) an ethylenically unsaturated compound.
  • the ethylenically unsaturated compound (a) used in the coating composition (I) is known Monofunctional monomers or polyfunctional monomers can be used, and preferably, a radical polymerizable monomer can be used.
  • (meth) acrylate esters are preferably used because of their relatively low stimulus to the human body.
  • a monomer having an acidic group in the molecule is preferably used as a component that gives a particularly high adhesive force to tooth material. Therefore, a combination of (meth) acrylate and a monomer having an acidic group such as a carboxyl group or an anhydride group, a phosphoric acid group or a sulfonic acid group is also preferably used.
  • the coating composition (I) is used as a part of the composition for the outermost layer material, the abrasion resistance is improved by blending a high amount of the polyfunctional monomer.
  • Examples of the monofunctional (meth) acrylate which can be used in the present invention include methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, and butyric (meth) acrylate. Hexyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, dodecyl (meth) acrylate, and lauryl (meth) acrylate;
  • Alicyclic (meth) acrylates such as cyclohexyl (meth) acrylate and isobutyl (meth) acrylate;
  • Aromatic (meth) acrylates such as benzyl (meth) acrylate
  • Polyethylene glycol mono (meth) acrylate such as diethylene glycol mono (meth) acrylate, triethylene glycol mono (meth) acrylate, polyethylene glycol mono (meth) acrylate, polypropylene glycol mono (meth) acrylate;
  • Ethylene glycol monomethyl ether (meth) acrylate ethylene glycol monoethyl ether (meth) acrylate, diethylene glycol monomethyl ether (meth) acrylate, triethylene glycol monomethyl ether (meth) acrylate, polyethylene glycol monomethyl ether (meth) (Poly) glycol monoalkyl ether (meth) acrylates, such as acrylates, polypropylene glycol monoalkyl ether (meth) acrylates;
  • Fluoroalkyl esters of (meth) acrylic acid such as perfluorooctyl (meth) acrylate and hexafluorobutyl (meth) acrylate;
  • ⁇ - (meth) ataryloxypropyltrimethoxysilane ⁇ - (meth) ataryloxypropyltrimethoxy And (meth) acrylate having a heterocyclic ring such as tetrafurfuryl (meth) acrylate.
  • alkyl (meth) acrylates such as methyl (meth) acrylate and ethyl (meth) acrylate;
  • (Meth) acrylate having an ethylene glycol chain in the molecule such as triethylene glycol monomethyl ether (meth) acrylate and triethylene glycol mono (meth) acrylate are particularly preferably used.
  • alkyl (meth) acrylates polyethylene glycol mono (meth) atalylate, (poly) glycol monoalkyl ether (meth) atalylate, fluoroalkyl esters of (meth) acrylic acid, (meth) Monofunctional monomers having neither a hydroxyl group nor an acidic group, such as silane compounds having an attaryloxyalkyl group and (meth) acrylates having a complex ring, are ethylenically unsaturated compounds (al). It can preferably be used in an amount in the range up to 20% by weight, more preferably up to 10% by weight, based on the whole.
  • hydroxyl group-containing (meth) acrylates 2-hydroxyethyl (meth) acrylate, 1,3-dihydroxypropyl mono (meth) acrylate, erythritol mono (meth) acrylate, and the like are preferably used.
  • 2-hydroxyethyl (meth) acrylate 1,3-dihydroxypropyl mono (meth) acrylate, erythritol mono (meth) acrylate, and the like are preferably used.
  • the hydroxyl group-containing monofunctional monomer represented by the hydroxyl group-containing (meth) acrylate is preferably 30% by weight or less, more preferably 20% by weight or less, based on the whole ethylenically unsaturated compound (al). It can be used in amounts in the range, more preferably up to 2% by weight.
  • These monofunctional monomers can be used alone or in combination of two or more, and can also be used in combination with a polyfunctional monomer described later.
  • Examples of the polyfunctional (meth) acrylate which can be used in the present invention include, for example, ethylenedalichol di (meth) acrylate, propylene glycol di (meth) acrylate, butylene glycol di (meth) acrylate, and neopentyl glycol diol.
  • Poly (meth) acrylates of alkane polyols such as (meth) acrylate, hexylene glycol, di (meth) acrylate, trimethylolpropane tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, diethylene glycol di (meta) ) Atharylate, triethylene glycol di (meth) atalylate, polyethylene glycol di (meth) atalylate, dipropylene glycol di (meth) atalylate, polypropylene glycol di (meth) atalylate, dibutylene Polyoxyalkane polyols such as glycol di (meth) acrylate and dipentaerythritol hexa (meth) acrylate
  • R is a hydrogen atom or a methyl group
  • m and n are an integer of 0 to 10, which may be the same or different.
  • R 1 is
  • H 2 C CC-0 ⁇ H e -CH-CH 2 -0-R 1 -O-CH 2 -CH-CH £ - (0-R 1 -0-CH2-CH-CH;!) N -0 -CC-CH 2
  • R is a hydrogen atom or a methyl group
  • n is an integer of 0-10
  • R 1 is
  • a polyfunctional (meth) ataryl having a urethane bond in a molecule represented by the following formula (3) is exemplified.
  • R is a hydrogen atom or a methyl group
  • R 1 is [0030]
  • polyfunctional (meth) acrylates for example, triethylene glycol di (meth) acrylate, polyethylene glycol di (meth) acrylate, di (meth) acrylate having an ethylene glycol chain in the molecule,
  • Etc. are particularly preferably used.
  • the pentaerythritol triatalylate and the pentaerythritol tetralate may be used as the polyfunctional atalylate.
  • Polyfunctional acrylates of pentaerythritol and dipentaerythritol such as atalylate, dipentaerythritol tetraatalylate, dipentaerythritol pentaatalylate, dipentaerythritol hexaarylate, ethylene glycol diatalylate, triethylene glycol diatari Rate, or other diglycerolates of ethylene glycolone ligomers,
  • Triazines such as 2-probenoic acid (2,4,6-trioxo-1,3,5-triazine-1,3,5- (2H, 4H, 6H) tolyl) tri-1,2-ethanedyl ester
  • a polyfunctional acrylate having a ring is particularly preferred in view of the surface hardness of the finally obtained cured product.
  • These polyfunctional monomers are preferably used with respect to the entire ethylenically unsaturated compound (a).
  • polyfunctional monomers can be used alone or in combination of two or more kinds, and can also be used in combination with a monofunctional monomer.
  • the monomer having an acidic group in the molecule includes, for example, (meth) acrylic acid and its anhydride, 1,4-di (meth) atalyloxicetyl pyromellitic acid, 6- (meth) Atariloxicetyl naphthalene 1,2,6-tricarboxylic acid, N- (meth) atalyloyl p-aminobenzoic acid, N (meth) atalyloyl o-aminobenzoic acid, N (meth) atariloyl m-aminobenzoic acid, N ( Meta) Attalyloyl 5-aminosalicylic acid, N- (meth) atalyloyl 4-aminosalicylic acid, 4- (meth) atalyloxicetyl trimellitic acid and its anhydride, 4- (meth) atalyloxybutyl trimellitic acid And its anhydride, 4 (meth) atari-mouth xy
  • (Meth) acrylic acid containing a phosphoric acid group such as 2- (meth) ataryloxyshethylphosphoric acid, 2- (meth) ataryloxyshethylphenolphosphoric acid, 10- (meth) ataryloxydecylphosphoric acid Acid ester monomers;
  • the monomers having an acidic group can be used alone or in combination.
  • the monomer having an acidic group is contained in 100 parts by weight of the whole ethylenically unsaturated compound (a).
  • these monomers having an acidic group can be used as a total of 100 ethylenically unsaturated compounds (a).
  • the monomer having an acid group may be either a monofunctional monomer or a polyfunctional monomer. After being classified into any of the classifications, it can be used in the range of each suitable use amount.
  • a hydroxyl group-containing polyfunctional monomer can be used instead of or in combination with the above-mentioned hydroxyl group-containing monofunctional monomer.
  • the total amount of the hydroxyl group-containing monofunctional monomer and the total amount of the hydroxyl group-containing polyfunctional monomer is preferably based on 100 parts by weight of the whole ethylenically unsaturated compound (al). It can be used in an amount of 30 parts by weight or less, more preferably 20 parts by weight or less, and even more preferably 2 parts by weight or less.
  • the monomer having a hydroxyl group can be classified as a polyfunctional monomer, the monomer is also classified as a polyfunctional monomer, Can be used in a suitable amount range.
  • ethylenically unsaturated compounds (a) include, for example, vinyl
  • Examples thereof include acetate, butylpyrrolidone, maleic anhydride, maleic acid, and benzoyl benzoate. These can be used alone or in combination of two or more.
  • Examples of the photopolymerization initiator (b a) include (b a) a-ketocarbonyl compound and (b a) a
  • Examples of the a-ketocarbon compound (b a) include ⁇ -diketone and ⁇ -ketoaldehyde.
  • ⁇ -ketocarboxylic acid ⁇ -ketocarboxylic acid ester and the like.
  • diacetinol, 2,3 pentadione, 2,3-hexadione, benzyl, 4,4'dimethoxybenzyl, 4,4'diethoxybenzyl, 4,4'oxybenzyl, 4,4 ' ⁇ -diketones such as dichlorobenzyl, 4-nitrobenzyl, hynaphthyl, j8-naphthyl, camphorquinone, camphorquinone sulfonic acid, camphorquinone carboxylic acid, 1,2-cyclohexanedione; methyldalioxal, ⁇ -keto aldehydes such as furglyoxal; ⁇ -keto carboxylic acids such as pyruvate, benzoylformate, phenylpyruvate, methyl pyruvate, ethyl be
  • a-ketocarbonyl compounds it is preferable to use an a-diketone from the viewpoint of stability and the like.
  • ⁇ -diketones diacetyl, benzyl and camphorquinone are particularly preferable.
  • phosphyl phosphoxide compound (b ⁇ ) for example, benzoyl dimethoxy phosph
  • the 12 components can be used alone or in combination.
  • peroxide (b ⁇ ) for example, dicarboxylic acid peroxides such as diacetyl peroxide, dipropyl peroxide, dibutyl peroxide, dicapryl peroxide, dilauryl peroxide, etc. , Benzoyl peroxide ( ⁇ ), ⁇ , ⁇ '-dichlorobenzoyl peroxide, ⁇ , ⁇ '-dimethoxybenzoyl peroxide, ⁇ , ⁇ '-dimethylbenzoyl peroxide, ⁇ , ⁇ '-di Organic peroxides such as benzoylperoxide-substituted derivatives such as -trodibenzoylperoxide;
  • Inorganic peroxides such as ammonium persulfate, potassium persulfate, potassium chlorate, potassium bromate and potassium perphosphate. Of these, ⁇ is preferred.
  • reducing conjugates include, for example, ⁇ , ⁇ dimethyla-line, ⁇ , ⁇ dimethyl- ⁇ -toluidine, ⁇ , ⁇ getyl- ⁇ -toluidine, ⁇ , ⁇ -diethanol ⁇ -toluidine, ⁇ , ⁇ -dimethyl- ⁇ — Tert-butylaniline, ⁇ , ⁇ -dimethylanisidine, ⁇ , ⁇ dimethyl- ⁇ -chloraniline, ⁇ , ⁇ dimethylaminoethyl (meth) acrylate, ⁇ , ⁇ -ethylethylethyl (meth) acrylate, ⁇ ⁇ , ⁇ -Dimethylaminobenzoic acid and its alkyl ester, ⁇ , ⁇ -Getylaminobenzoic
  • Filament (c) is blended in the coating composition (I) used in the present invention.
  • Filler (c) is blended in the coating composition (I) used in the present invention.
  • C) is used by appropriately selecting from inorganic fillers, organic fillers, and organic-inorganic composite fillers.
  • the inorganic filler used in the present invention has an irregular shape even if it has a spherical shape. There may be.
  • Known inorganic fillers can be appropriately selected and used, and examples thereof include, for example, groups I, II, III, and IV of the periodic law, transition metals and their oxides, hydroxides, chlorides, and sulfates. , Sulfites, carbonates, phosphates, silicates, and mixtures and composite salts thereof can also be selected.
  • glass powders such as silicon dioxide, strontium glass, lanthanum glass, norium glass, quartz powder, barium sulfate, aluminum oxide, titanium oxide, barium salt, glass beads, glass fiber, barium fluoride, Lead salts, glass fillers containing talc, colloidal silica, silica gel, zirconium oxide, tin oxide, and other ceramic powders can be used.
  • the particle diameter of the inorganic filler is appropriately selected and used.
  • the force average particle diameter is usually 0.001 to 5 O / zm, preferably 0.001 to 10 / zm.
  • These inorganic fillers can be used alone or in combination of two or more, and may be used in combination with an organic filler or Z and an organic-inorganic composite filler.
  • organic fillers examples include polymethyl (meth) acrylate, polyethyl (meth) acrylate, methyl (meth) acrylate, ethyl (meth) acrylate copolymer, methyl (meth) acrylate / butyl (meth) ataly
  • Non-crosslinkable polymers such as methyl copolymers, methyl (meth) acrylates and styrene copolymers, methyl (meth) acrylate, ethylene glycol di (meth) atalylate copolymer, methyl (meth) acrylate, tri (Meth) acrylate polymers such as ethylene glycol di (meth) acrylate copolymer and a copolymer of methyl (meth) acrylate and butadiene monomer can be used.
  • the average particle size of the filler used by appropriately selecting the particle size of the filler is usually 0.001 to 50 / zm and
  • TMPT filler trimethylolpropane methacrylate and silica filler are mixed, polymerized, and then pulverized
  • shape of the organic-inorganic composite filler There is no particular limitation on the shape of the organic-inorganic composite filler.
  • the average particle size of the filler used by appropriately selecting the particle size of the filler is usually 0.001 to 50 / zm and 0.001 to m. Is preferred.
  • the weight content of filler (c) to the total 100 parts by weight of the filler (c) 0/0 (f ) [(c ) / [(a) + (b) + (c)] X 100] is preferably 5 to 80 parts by weight, more preferably 10 to 70 parts by weight.
  • the dental coating agent is within the above range. If the content percentage by weight of the filler is within the above range, the dental coating agent
  • the container filled with (I) is stored for a long time, it can be used stably for a long period of time without separating the filler component.
  • the coating composition (I) used in the present invention may further contain a coloring agent (d).
  • coloring agent (d) used here known dental pigments and dyes can be used.
  • the blending amount of the coloring agent (d) depends on the amount of the ethylenically unsaturated compound contained in the coating composition (I).
  • the coating composition (I) used in the present invention may further contain other additives as long as the object of the present invention is not impaired.
  • other additives include bactericides, stabilizers, polymerization inhibitors and the like.
  • the coating composition ( ⁇ ) used in the present invention comprises at least (a) an ethylenically unsaturated compound.
  • Examples of the ethylenically unsaturated compound (a) include ethylenic compounds used in the coating composition (I).
  • the same kind as the monomer type of the unsaturated unsaturated compound (a) can be preferably used.
  • the mixing ratio of the monomer used as the ethylenically unsaturated compound (a) is also known.
  • composition ratio of the body is the same or different!
  • Monofunctional monomers are preferred with respect to 100 parts by weight of the entire ethylenically unsaturated compound (a).
  • the polyfunctional monomer is 100 parts by weight of the whole ethylenically unsaturated compound (a).
  • it can be used in an amount within the range of 5-90 parts by weight, more preferably 5-80 parts by weight.
  • composition ( ⁇ ) used in the present invention may contain (b) a polymerization initiator.
  • the initiator (b) is the same as the polymerization initiator (b) suitably used in the coating composition (I).
  • the ratio it is preferable to use the same polymerization ratio as the polymerization initiator (b).
  • the compound types of the polymerization initiators (b) and (b) may be the same or different. Also, the compound types of the polymerization initiators (b) and (b) may be the same or different. Also, the compound types of the polymerization initiators (b) and (b) may be the same or different. Also, the compound types of the polymerization initiators (b) and (b) may be the same or different. Also, the compound types of the polymerization initiators (b) and (b) may be the same or different. Also,
  • the compounding ratio of the polymerization initiators (b) and (b) may be the same or different.
  • composition ( ⁇ ) used in the present invention may contain (c) a filler.
  • the types of the fillers (C) and (C) may be the same or different.
  • the ethylenically unsaturated compound (a) contained in the composition ( ⁇ ) is optionally contained.
  • the content by weight of filler 0/0 (f) may be 0.
  • the following effects can be exerted by combining the fibrous composition (I) and the fibrous composition (I) with a high filler content (%) and a low fibrous content (F).
  • the coating material has less coating unevenness.
  • the coating layer has less thickness unevenness.
  • the work can be performed by adjusting the viscosity to a desired one of the worker, the work can be performed safely and in a short time, and the workability is excellent.
  • the difference (f f) between the filler content weight% (f) and the filler content weight% (f) is preferably
  • the ratio (f / ⁇ ) of the filler content weight% (f) to the filler content weight% (f) is preferably
  • the content by weight (f) of the filler (c) in the yarn composition ( ⁇ ) is 0 to 20 parts by weight.
  • the force of mixing the composition ( ⁇ ) with the composition (I) for use it is preferable to adjust the amount of the filler so as to have a viscosity suitable for application, and also to use the force.
  • the total amount of the filler (c) and the filler (c) is determined by the total weight of the mixture of the composition (I) and the composition ( ⁇ ).
  • the coating can be performed with less unevenness in coating and less unevenness in thickness of the coating film.
  • composition ( ⁇ ) also contains (d) a coloring agent as in the composition (I)! Colorant (d
  • the amount of the coloring agent (d) is determined by the amount of ethylene contained in the composition ( ⁇ ).
  • the species and the mixing ratio to Z or the composition may be the same or different.
  • composition ( ⁇ ) other additives that can be used for the composition (I) can be used in a range that does not impair the effects of the present invention.
  • these coated yarns (I) and (II) it is preferable that water is substantially not contained, and components excluding fillers are excluded from these compositions (monomer, polymerization initiator, coloring agent). ) Based on the whole, it is preferably at most 3% by weight.
  • the tooth is pretreated.
  • the pretreatment include ( ⁇ ) etching treatment of the bonding surface with a dental etching agent, (IV) modification treatment of the bonding surface with a dental primer or etching and modification treatment of the bonding surface with a primer having an etching ability, And (V) a treatment for forming an adhesive layer with an adhesive.
  • the dental etching agent ( ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ) is preferably an acidic aqueous solution. Specific examples include a phosphoric acid aqueous solution and a citric acid aqueous solution. More preferably, the concentration of the acidic substance is 10 to 60%, preferably 5 to 70%.
  • Other additives may be further added to the dental etching agent (III) as long as the object of the present invention is not impaired. Examples of additives include thickeners, bactericides, stabilizers, and colorants such as pigments and dyes.
  • Examples of the dental primer (IV) used in the present invention include, for example, an aqueous solution containing 50% by weight of 2-phenyl.
  • a primer having an etching ability used for etching the adhesive surface and the modification treatment for example, a component that modifies demineralized tooth material and promotes diffusion of the adhesive to the tooth material, and an organic acid ( Aqueous solution containing a monomer having an acidic group).
  • Components that promote the diffusion of the adhesive into the tooth material include, for example, alkylene glycol, polyalkylene glycol, 2-hydroxyethyl (meth) acrylate, and 1,3-dihydroxypropyl mono (meth) acrylate.
  • a hydroxyl group-containing monomer such as polyethylene glycol ( (Meth) atalilate and the like.
  • the above-mentioned organic acid contains a monomer having an acidic group.
  • a monomer contains a carboxyl group or a monomer containing an anhydride group thereof, a phosphoric acid group or a sulfonic acid group.
  • Monomers can be mentioned.
  • the monomer having an acidic group is preferably contained in an amount of 5 to 50 parts by weight based on 100 parts by weight of the dental primer (IV).
  • the dental primer (IV) may also optionally contain the monomers exemplified for the compositions (I) and (II) of the present invention.
  • this monomer is preferably 30% by weight or less based on the entire dental primer (IV). , More preferably in an amount in the range of up to 15% by weight.
  • this monomer is preferably 50% by weight or less based on the entire dental primer (IV). , More preferably at most 40% by weight, even more preferably at most 10% by weight, particularly preferably at most 7% by weight.
  • the content of the monomer is preferably 5 to 50% by weight, more preferably 10 to 50% by weight, based on the whole dental primer (IV). Can be used in quantity.
  • the dental primer (IV) is substantially harmless, as typified by water, ethanol, acetone and the like! ⁇ Water-soluble organic solvents are included as appropriate!
  • water When water is used, it can be used in an amount of preferably 40% by weight or less, more preferably 5 to 30% by weight, based on the entire dental primer (IV).
  • a substantially harmful water-soluble organic solvent such as ethanol or acetone
  • it is preferably 70% by weight or less, more preferably 10 to 60% by weight, based on the entire dental primer (IV). Available in a range of quantities.
  • a primer may be added to the primer (IV).
  • the dental primer (IV) is resistant to a tooth layer and a coating layer composed of the adhesive composition of the present invention and enamel by further mixing a fluorine ion releasing substance.
  • Acidity can be imparted.
  • the fluorine ion releasing substance include fluorine glass such as fluoroaluminosilicate glass, metal fluorides such as sodium fluoride and potassium fluoride, and fluorine ion releasing polymers such as a copolymer of methyl methacrylate and methacrylic fluoride. And cetylamine hydrofluoride.
  • the dental primer (IV) may contain other additives as long as the object of the present invention is not impaired.
  • other additives include thickeners, bactericides, stabilizers, and coloring agents such as pigments and dyes.
  • the adhesive (V) used in the present invention contains at least one monomer having an acidic group in the molecule.
  • a monomer having an acidic group in the molecule in the adhesive (V) By containing a monomer having an acidic group in the molecule in the adhesive (V), the adhesiveness to tooth material and the like is improved.
  • Examples of the acidic group include a carboxyl group or an anhydride group thereof, a phosphoric acid group, a sulfonic acid group, and the like.
  • Examples of the monomer having an acidic group in the molecule include those used in the composition (I).
  • the monomers exemplified for the ethylenically unsaturated compound (a) can be suitably used. Minute
  • the monomer having an acidic group in the monomer is preferably contained in an amount of 5 to 20 parts by weight, more preferably 10 to 15 parts by weight, based on 100 parts by weight of the adhesive. ,.
  • the adhesive (V) may appropriately contain the monomers exemplified in the compositions (I) and (II) of the present invention.
  • the monofunctional monomer having no hydroxyl group and no acidic group preferably accounts for 30% by weight or less, more preferably 15% by weight or less, based on the whole adhesive (V).
  • the monomer having a hydroxyl group can be used in an amount of preferably 30% by weight or less, more preferably 20% by weight or less, based on the whole adhesive (V).
  • the polyfunctional monomer can be used in an amount of preferably 5 to 80% by weight, more preferably 10 to 70% by weight, based on the whole adhesive (V).
  • Water can be used in an amount of preferably 40% by weight or less, more preferably 5 to 30% by weight, based on the whole adhesive (V).
  • a filler may be added to the adhesive (V).
  • a fluorine ion-releasing substance into the adhesive (V)
  • acid resistance is imparted to the tooth layer and the coating layer composed of the adhesive composition of the present invention and enamel.
  • a fluorine ion releasing substance include fluorine glass such as fluoroaluminosilicate glass, metal fluorides such as sodium fluoride and potassium fluoride, and a copolymer of methyl methacrylate and methacrylate fluoride. And cetylamine hydrofluoride.
  • additives can be added to the adhesive (V) as long as the object of the present invention is not impaired.
  • additives include thickeners, bactericides, stabilizers, and colorants such as pigments and dyes.
  • the surface hardness (Pickers hardness) of the coating film formed on the tooth surface obtained using the dental coating kit according to the present invention is preferably 10-60, more preferably 20-60. If the surface hardness is within the above range, the surface will not be shiny even when cleaned with a toothbrush which has high abrasion properties, and “excellent aesthetics”.
  • the outermost layer may be formed using a hard coat material after forming the opaque coating material layer using the coating kit according to the present invention.
  • the hard coat material may be the same as the coating material obtained by mixing the composition (I) and the composition ( ⁇ ) used in the present invention, or a different coating material may be used.
  • the hard coat material used for the outermost layer preferably has abrasion resistance and coloring resistance.
  • the thickness of the opaque coating material layer obtained by the dental coating kit of the present invention is preferably from 20 to 300 m from the viewpoint of the hiding power of the colorant and the operability.
  • the outermost layer which is a hard coat material
  • the outermost layer preferably has a thickness of 110 m.
  • the thickness of the adhesive layer is desirably 3-100 / zm.
  • the thickness of the primer layer is usually 3 m or less.
  • the overall thickness of the tooth-surface coating laminated structure obtained using the dental tooth-surface coating kit according to the present invention is such that there is no uncomfortable feeling, meshing with the opposing tooth, and peeling off by a scaler. From the point of view, 20-400 m is preferable, and 30-300 m is more preferable.
  • the adhesive strength of the dental tooth surface coating layer obtained by the present invention is preferably 5 MPa or more, more preferably 8 MPa or more.
  • the adhesive strength of the coating layer is preferably in the range of 2 to 20 MPa, more preferably in the range of 41 IMPa.
  • the composition of the dental tooth surface coating kit of the present invention essentially requires a container filled with the coating composition (I) and a container filled with the coating composition ( ⁇ ), and if necessary, an etching agent ( It is characterized in that at least one selected from the group consisting of a container filled with III), a container filled with primer (IV) and a container filled with adhesive (V) is used in combination.
  • the hard coat material composition for the outermost layer may be filled in another container and included in the coating kit according to the present invention. This hard coat material composition may be the same as the coating composition (I) or ( ⁇ ).
  • an opaque coating layer is formed by directly applying a coating material obtained by mixing the coating composition (I) and the coating composition (II) to enamel on the tooth surface.
  • a coating material obtained by mixing the coating composition (I) and the coating composition (II) to enamel on the tooth surface.
  • the above-mentioned dental etching agent obtained by mixing the coating composition (I) and the coating composition (II) to enamel on the tooth surface.
  • the above coating material After treating the tooth surface with (III) and Z or the dental primer (IV), the above coating material can be applied to form an opaque coating layer. Further, in order to adjust the color tone of the tooth surface, the above-mentioned coating material may be used for recoating several times.
  • an adhesive (V) is used to improve durability in the oral cavity, an adhesive layer is formed using the adhesive (V), and then a coating material layer is formed thereon. If an etchant (III) is used to further enhance durability, apply it before using dental primer (IV) or Z and adhesive (V). When a hard coat material is combined to improve abrasion, a hard coat material layer is formed on the opaque coating material layer.
  • UDMA 1,6-bis (methacryloxyshetyloxycarbonylamino) —2,2,4-trimethylhexane
  • TEGDMA triethylene glycol dimethacrylate
  • DMTPO diphenyl (2,4,6-trimethylbenzoyl) phosphinoxide
  • Coating composition (I 1) consisting of 5 parts by weight, 20 parts by weight of UDMA, 5 parts by weight of TEGDMA, 8 parts by weight of RDMA, 1 part by weight of CQO, and 0.1 part by weight of butoxystil dimethylaminobenzoate, and MM A59
  • a coating composition (II 1) consisting of 3 parts by weight, 37 parts by weight of A-9300, and 04 parts by weight of DMTP was prepared.
  • an etching agent (III 1) consisting of 23 parts by weight of phosphoric acid, 66 parts by weight of purified water, and 11 parts by weight of polybutylpyrrolidone, 41 parts by weight of acetone, 29 parts by weight of purified water, 13 parts by weight of 4MET A, MMA4 Parts by weight, UDMA10 parts by weight, HEMA3 parts by weight, and DMTP OO.
  • a primer (IV-1) consisting of 1 part by weight was prepared.
  • An adhesive sample was prepared by the method described below, and the adhesive strength was measured.
  • a mixture of the coating composition (I1) and the coating composition (II-1) at a weight ratio of 5: 1 [(1-1): (II-1)] is applied on the primer layer. Then, light irradiation was performed with a dental halogen irradiator for 20 seconds to form an opaque coating layer. These operations cure the primer layer and the opaque coating layer.
  • An adhesive rod was adhered to the opaque coating layer using a super bond (manufactured by Sun Medical Co., Ltd.), and planted.
  • the above-mentioned adhesive sample was placed in a thermostat at 37 ° C and 100% humidity and allowed to stand for 24 hours, and then the tensile adhesive strength was measured.
  • the tensile adhesion test was performed using a testing machine AGS-1000D (manufactured by Shimadzu Corporation) at a crosshead speed of 2 mmZmin.
  • the film thickness of the adhesive sample was measured.
  • the coating thickness was the thickness of the entire primer layer and opaque coating layer.
  • Test samples were prepared by the following method, and color unevenness was evaluated.
  • VITA shade guide model that imitates the tooth substance
  • the coating composition (d) and the coating composition (II-1) were mixed at a weight ratio of 5: 1 [(1-1): (II 1)].
  • the obtained mixture was applied to the above-mentioned shade guide using a brush, and irradiated with light using a dental halogen irradiator for 20 seconds.
  • the application of the above mixture and light irradiation were repeated until the color tone of the surface became the same as the shade guide of color tone A1.
  • test sample thus prepared was evaluated by five persons,
  • Table 1 shows the test results.
  • Example 1 The same as in Example 1 except that the coating composition ( ⁇ -1) was changed to the coating composition ( ⁇ -2)-(II-17) shown in Table 1, respectively, the adhesion test, the measurement of the film thickness, And evaluation of color mura. Table 1 shows the test results.
  • the lower forehead was polished with 180 # water-resistant abrasive paper to cut out a flat adhesive enamel surface.
  • the primer solution (IV-1) was contained in a sponge, applied to the enamel surface, and dried by blowing air.
  • a mixture obtained by mixing the coating composition (I 1) and the coating composition ( ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ -1) at a weight ratio of 5: 1 [(11): ( ⁇ -1)] is applied onto the primer layer. Then, light irradiation was performed with a dental halogen irradiator for 20 seconds to form an opaque coating layer. Then, in the same manner as in Example 1, the adhesion test and the measurement of the film thickness were performed. The evaluation of color unevenness was performed in the same manner as in Example 1. Table 1 shows the test results.
  • the lower forehead was polished with 180 # water-resistant abrasive paper to cut out a flat adhesive enamel surface.
  • the primer solution (IV-1) was contained in a sponge, applied to the enamel surface, and dried by blowing air.
  • a mixture obtained by mixing the coating composition (I 1) and the coating composition (4-4) at a weight ratio of 5: 1 [(11): ( ⁇ -4)] is applied onto the primer layer. Then, light irradiation was performed with a dental halogen irradiator for 20 seconds to form an opaque coating layer. Then, in the same manner as in Example 1, the adhesion test and the measurement of the film thickness were performed. The evaluation of color unevenness was performed in the same manner as in Example 1. Table 1 shows the test results.
  • a coating composition comprising 60 parts by weight of MMA, 35 parts by weight of A-9300, and 5 parts by weight of a glass glass filler (average particle size: 1 ⁇ m) (I-118) ) was prepared.
  • Example 1 In the same manner as in Example 1 except that the coating composition (I1) was used as an operation coating material alone without using the coating composition (II-1), the adhesion test, the measurement of the film thickness, and the Evaluation of color unevenness was performed. Table 1 shows the test results.
  • the adhesion test and the coating thickness were performed in the same manner as in Example 1 except that the coating composition ( ⁇ -1) was changed to Metafil Flo (A2 color) (composite resin manufactured by Sun Medical Co., Ltd .: 60% by weight of a filler). The measurement and the evaluation of color unevenness were performed. Table 1 shows the test results.
  • composition (I) Composition (I I) Test results
  • Composition name Composition name Color unevenness Adhesive strength Film thickness
  • Example 4 1-1 II -4 ⁇ (30) A -9300 (66)-DMTP0 (4) None ⁇ Layer a 250 / m
  • Example 8 1 — 1 1 1-8 ⁇ (40) A-9300 (40) TEMA (20) ⁇ None ⁇ 17 Pa 180jLim
  • Example 9 I-1 1 I-9 Hidden (59) A-9300 (37) ⁇ 0MTP0 (2) CQ (2) None 19MPa 200
  • Example 10 1 ⁇ 1 1 1-1 0 MA (96) ⁇ ⁇ DHTP0 (4) None ⁇ 12 Pa llO ⁇ n
  • Example 11 1 -1 1 1-1 1 ⁇ (10) 2.6E (86) ⁇ Hidden 0 (4) None 0 11MPa 300
  • Example 12 1 -1 1 1-12 TEGDMA (50) UDMA: 46) ⁇ DMTP0 (2) CO (2) None 0 16MPa 300 jum
  • Example 13 1 -1 1 1-13 TEGDMA (50) TMPT (46) ⁇ DMTP0 (2) CO (2) None ⁇ 15KIPa 160 «in
  • Example 14 1-1 1 1-14 TMPT (50) 2.6 E (46) ⁇ DMTPO (2) CQ (2)

Landscapes

  • Health & Medical Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Plastic & Reconstructive Surgery (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Dental Preparations (AREA)
  • Dental Tools And Instruments Or Auxiliary Dental Instruments (AREA)
  • Paints Or Removers (AREA)

Abstract

L'invention a pour but de fournir un kit d'enrobage dentaire qui permet l'ajustement avec une couleur préférée et une application sécurisée dans un court laps de temps, qui peut améliorer le brillant des plans dentaires, sans pour autant augmenter la surface d'une dent. L'objectif est atteint en produisant un kit d'enrobage dentaire constitué d'un boîtier (I) rempli d'une composition d'enrobage (I) constituée (a1) d'un composé éthyléniquement insaturé, (b1) d'un initiateur de polymérisation et (c1) d'un remplisseur et d'un boîtier (II) rempli d'une composition d'enrobage (II) constituée (a2) d'un composé éthyléniquement insaturé et, si nécessaire, (b2) d'un initiateur de polymérisation et (c2) d'un remplisseur, caractérisé par le fait que le contenu (wt%) du remplisseur (c2) de la composition (II), [(c2)/[(a2) + (b2) + (c2)] × 100, est inférieur au contenu (wt%) du remplisseur (c1) de la composition (I), [(c1)/[(a1) + (b1) + (c1)] x 100.
PCT/JP2005/004332 2004-03-11 2005-03-11 Kit dentaire pour enrober les plans dentaires WO2005087179A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2006511005A JPWO2005087179A1 (ja) 2004-03-11 2005-03-11 歯科用歯面コーティングキット

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2004-069345 2004-03-11
JP2004069345 2004-03-11

Publications (1)

Publication Number Publication Date
WO2005087179A1 true WO2005087179A1 (fr) 2005-09-22

Family

ID=34975296

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2005/004332 WO2005087179A1 (fr) 2004-03-11 2005-03-11 Kit dentaire pour enrober les plans dentaires

Country Status (2)

Country Link
JP (1) JPWO2005087179A1 (fr)
WO (1) WO2005087179A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009536154A (ja) * 2006-04-12 2009-10-08 セントリックス、インコーポレーテッド 流動抵抗性を有する歯科用液状除痛製剤
JP2010275267A (ja) * 2009-06-01 2010-12-09 Tokuyama Dental Corp 歯のコーティング用キット
WO2015064090A1 (fr) * 2013-10-31 2015-05-07 クラレノリタケデンタル株式会社 Kit de matériau de réglage de ton de couleur dentaire
JP2017506242A (ja) * 2014-02-18 2017-03-02 スリーエム イノベイティブ プロパティズ カンパニー 接着剤結合組成物及びその使用
JP2017507138A (ja) * 2014-02-18 2017-03-16 スリーエム イノベイティブ プロパティズ カンパニー 歯科用組成物及びその使用

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000143428A (ja) * 1994-08-01 2000-05-23 San Medical Kk 歯科用治具および歯科用キット
JP2000178111A (ja) * 1998-12-17 2000-06-27 San Medical Kk 歯科用接着剤のキット
JP2000186010A (ja) * 1998-09-10 2000-07-04 San Medical Kk 歯科用接着材セット
JP2002255722A (ja) * 2001-02-27 2002-09-11 Tokuyama Corp 歯科用硬化性組成物
JP2003081731A (ja) * 2001-09-12 2003-03-19 Kuraray Co Ltd 歯科用組成物
WO2004032884A1 (fr) * 2002-10-08 2004-04-22 Kuraray Medical Inc. Necessaire de revetement dentaire

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000143428A (ja) * 1994-08-01 2000-05-23 San Medical Kk 歯科用治具および歯科用キット
JP2000186010A (ja) * 1998-09-10 2000-07-04 San Medical Kk 歯科用接着材セット
JP2000178111A (ja) * 1998-12-17 2000-06-27 San Medical Kk 歯科用接着剤のキット
JP2002255722A (ja) * 2001-02-27 2002-09-11 Tokuyama Corp 歯科用硬化性組成物
JP2003081731A (ja) * 2001-09-12 2003-03-19 Kuraray Co Ltd 歯科用組成物
WO2004032884A1 (fr) * 2002-10-08 2004-04-22 Kuraray Medical Inc. Necessaire de revetement dentaire

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009536154A (ja) * 2006-04-12 2009-10-08 セントリックス、インコーポレーテッド 流動抵抗性を有する歯科用液状除痛製剤
JP2010275267A (ja) * 2009-06-01 2010-12-09 Tokuyama Dental Corp 歯のコーティング用キット
WO2015064090A1 (fr) * 2013-10-31 2015-05-07 クラレノリタケデンタル株式会社 Kit de matériau de réglage de ton de couleur dentaire
JPWO2015064090A1 (ja) * 2013-10-31 2017-03-09 クラレノリタケデンタル株式会社 歯科用色調調整材キット
US9675527B2 (en) 2013-10-31 2017-06-13 Kuraray Noritake Dental Inc. Dental color tone adjustment material kit
JP2017506242A (ja) * 2014-02-18 2017-03-02 スリーエム イノベイティブ プロパティズ カンパニー 接着剤結合組成物及びその使用
JP2017507138A (ja) * 2014-02-18 2017-03-16 スリーエム イノベイティブ プロパティズ カンパニー 歯科用組成物及びその使用

Also Published As

Publication number Publication date
JPWO2005087179A1 (ja) 2008-01-24

Similar Documents

Publication Publication Date Title
US9937105B2 (en) High strength dental material
CA2617821C (fr) Systeme catalyseur pour compositions dentaires
JP2868448B2 (ja) 重合性歯科材料
JPH0818947B2 (ja) 重合可能な歯科材料、該材料からなる充填剤及びインレー並びに固定セメント
JP2010513297A (ja) 酸性成分及び光退色性染料を有する歯科用組成物の使用方法
CA2150098C (fr) Appret dentaire
JP5191401B2 (ja) 歯科用組成物
JP2023510962A (ja) 高い硬化深度を有する審美的歯科充填材料
AU2003271104B2 (en) Dental coating kit
WO2005087179A1 (fr) Kit dentaire pour enrober les plans dentaires
US20100216907A1 (en) One-package type tooth surface coating material
JPWO2005074862A1 (ja) エナメル質接着性組成物
JP5331697B2 (ja) 歯科用重合性組成物およびそのキット
JP2022173073A (ja) 歯科用成形体の生成のための透明な破壊靭性重合樹脂
US20110077320A1 (en) Dental restorative material composition
JP5279233B2 (ja) レジン硬化物製歯科補綴物表面処理用プライマー組成物
JP2021080196A (ja) 歯科用組成物
JP2008001665A (ja) ２液型の歯科用接着剤
JP2021059515A (ja) 歯科用接着性組成物
JP2016153382A (ja) 歯科用硬化性組成物
JP6145009B2 (ja) 歯科用硬化性組成物
JP5448495B2 (ja) レジン硬化物製歯科補綴物表面処理用プライマー組成物
JP2004315460A (ja) 歯科用マニキュアキット
US11998621B2 (en) Transparent, fracture-tough polymerization resins for the production of dental shaped bodies
JP2004196735A (ja) 歯科用コーティング組成物

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SM SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): BW GH GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DPEN Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed from 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2006511005

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

WWW Wipo information: withdrawn in national office

Country of ref document: DE

122 Ep: pct application non-entry in european phase