WO2005061855A1 - Gasturbinenbauteil - Google Patents
Gasturbinenbauteil Download PDFInfo
- Publication number
- WO2005061855A1 WO2005061855A1 PCT/DE2004/002706 DE2004002706W WO2005061855A1 WO 2005061855 A1 WO2005061855 A1 WO 2005061855A1 DE 2004002706 W DE2004002706 W DE 2004002706W WO 2005061855 A1 WO2005061855 A1 WO 2005061855A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gas turbine
- turbine component
- metal foam
- component according
- carrier
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D11/00—Preventing or minimising internal leakage of working-fluid, e.g. between stages
- F01D11/08—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between rotor blade tips and stator
- F01D11/12—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between rotor blade tips and stator using a rubstrip, e.g. erodible. deformable or resiliently-biased part
- F01D11/127—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between rotor blade tips and stator using a rubstrip, e.g. erodible. deformable or resiliently-biased part with a deformable or crushable structure, e.g. honeycomb
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D11/00—Preventing or minimising internal leakage of working-fluid, e.g. between stages
- F01D11/08—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between rotor blade tips and stator
- F01D11/12—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between rotor blade tips and stator using a rubstrip, e.g. erodible. deformable or resiliently-biased part
- F01D11/122—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between rotor blade tips and stator using a rubstrip, e.g. erodible. deformable or resiliently-biased part with erodable or abradable material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D25/00—Component parts, details, or accessories, not provided for in, or of interest apart from, other groups
- F01D25/08—Cooling; Heating; Heat-insulation
- F01D25/14—Casings modified therefor
- F01D25/145—Thermally insulated casings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D25/00—Component parts, details, or accessories, not provided for in, or of interest apart from, other groups
- F01D25/24—Casings; Casing parts, e.g. diaphragms, casing fastenings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/60—Properties or characteristics given to material by treatment or manufacturing
- F05D2300/612—Foam
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T50/00—Aeronautics or air transport
- Y02T50/60—Efficient propulsion technologies, e.g. for aircraft
Definitions
- the invention relates to a gas turbine component, namely a static gas turbine component.
- titanium alloys titanium alloys
- nickel alloys also called super alloys
- high-strength steels are used, for example, for compressor housings and turbine housings.
- Titanium alloys are typical materials for compressor parts.
- Nickel alloys are suitable for the hot parts of the aircraft engine.
- As a production method for gas turbine components made of titanium alloys, nickel alloys or other alloys, investment casting and forging are primarily known from the prior art. All highly stressed gas turbine components, such as components for a compressor, are forgings. Components for a turbine, however, are usually designed as investment castings.
- MMC materials metal matrix composite materials
- high-strength fibers are embedded in the metal material.
- the production of gas turbine components from such MMC materials is complex and therefore expensive.
- the mass of the static Gas turbine components affect the total weight of a gas turbine, in particular an aircraft engine.
- the present invention is based on the problem of proposing a new type of static gas turbine component.
- the static gas turbine component is at least partially formed from a metal foam.
- metal foams enables a cost-effective alternative to MMC materials and significant weight savings.
- 1 shows a block diagram to illustrate a method for producing gas turbine components according to the invention
- 2 shows a gas turbine component according to the invention, designed as a housing structure, according to a first exemplary embodiment of the invention, in a highly schematic manner
- FIG. 3 shows a gas turbine component according to the invention, designed as a housing structure, according to a second exemplary embodiment of the invention, in a highly schematic form
- FIG. 4 shows a gas turbine component according to the invention, designed as a housing structure, according to a third exemplary embodiment of the invention, in a highly schematic manner
- FIG. 5 shows a gas turbine component according to the invention, designed as an inlet lining, according to a further exemplary embodiment of the invention, in a highly schematic representation;
- FIG. 6 shows a gas turbine component according to the invention, embodied as an inlet lining, according to a further exemplary embodiment of the invention, in a highly schematic representation
- FIG. 7 shows a gas turbine component according to the invention, designed as an inlet lining, according to a further exemplary embodiment of the invention, in a highly schematic representation
- FIG. 8 shows a gas turbine component according to the invention, embodied as an inlet lining, according to a further exemplary embodiment of the invention, in a highly schematic representation
- FIG. 9 shows a gas turbine component according to the invention, designed as a pipeline system, according to a further exemplary embodiment of the invention, in a highly schematic representation
- FIG. 10 shows a gas turbine component according to the invention, designed as a pipeline system, according to a further exemplary embodiment of the invention, in a highly schematic representation
- FIG. 12 e shows a gas turbine component according to the invention, designed as a pipeline system, according to a further exemplary embodiment of the invention, in a highly schematic representation
- FIG. 13 shows a gas turbine component according to the invention, designed as a pipeline system, according to a further exemplary embodiment of the invention, in a highly schematic illustration.
- FIGS. 1 to 13 each showing gas turbine components according to the invention in a highly schematic manner.
- steps should be taken beforehand with reference to FIG a preferred manufacturing method for static gas turbine components made of metal foam are described.
- An inventive static gas turbine component for an aircraft engine is such that a metal ⁇ be provided a blowing agent powder and in a second step 1 1 in a first step 10.
- the metal powder provided is a metal powder based on an aluminum alloy or titanium alloy or nickel alloy. It is also possible to use metal powder based on a cobalt alloy or an iron alloy. Metal powders made of intermetallic titanium-aluminum alloys can also be used. Titanium hydride is provided in particular as a blowing agent.
- the metal powder provided and the blowing agent provided are mixed in a step 12.
- the resulting mixture of metal powder and blowing agent is then compressed into a semi-finished product.
- the compression can take place either in the sense of step 13 by extrusion or in the sense of step 14 by axial hot pressing.
- step 15 At the end of the compression according to step 13 or step 14, there is accordingly a semi-finished product, which is visualized by step 15 in the flow diagram of FIG. 1.
- the semifinished product is practically indistinguishable from a conventional metal, but it contains the blowing agent and is therefore foamable.
- the semifinished product present in step 15 is heated in the sense of step 16, to just above its melting point, so that the metal is melted and the propellant is released.
- the foaming of the semi-finished product is triggered by the gas release of the blowing agent.
- the foaming is carried out until a defined degree of foaming is reached. As soon as this defined degree of foaming has been reached, the foaming is stopped by cooling below the melting point of the metal powder used. This stabilizes the foam structure.
- the foaming triggered by the heating of the semi-finished product above the melting point of the metal powder and the corresponding termination of the foaming by cooling below the melting point of the metal powder are visualized together by step 16.
- surface processing or other processing or finishing of the manufactured component in the sense of step 17 can also take place.
- the component can be connected to a carrier.
- FIG. 1 shows that in the sense of a step 18, in addition to the metal powder provided in the sense of step 10 and the blowing agent provided in the sense of step 11, further constituents can be mixed with the metal powder and the blowing agent in step 12.
- the other constituents can be, for example, an additional metal powder with a different melting point or different powder grain size, a different blowing agent or ceramic particles, ceramic fibers or other inorganic or organic elements.
- FIG. 2 shows a first exemplary embodiment of a gas turbine component according to the invention, which forms a housing structure 19, the housing structure 19 being formed at least in regions from metal foam.
- the housing structure 19 of FIG. 2 has a first section or region 20 which is formed from metal foam and a second region 21 which serves as a carrier for the metal foam.
- the carrier 21 is arranged on one side of the metal foam 20, the metal foam 20 being firmly connected to the carrier 21.
- Carrier 21 and metal foam 20 form a simple sandwich structure in the exemplary embodiment in FIG. 2.
- the carrier 21 also has an angled section 22, the section 22 having a bore 23 for connection to other components.
- FIG. 3 likewise shows a gas turbine component according to the invention, which is designed as a housing structure 24, the exemplary embodiment in FIG. 3 differing from the exemplary embodiment in FIG. 2 in that a section or region 21 and 25 designed as a carrier is arranged on both sides of the metal foam 20 and is firmly connected to the metal foam 20.
- the arrangement of FIG. 3 can also be referred to as a double sandwich construction.
- the carriers 21 and 25 on both sides of the metal foam 20 can consist of the same or different materials, namely metal alloys.
- 4 shows a further gas turbine component according to the invention, which is designed as a housing structure 26 and is likewise formed in some areas from metal foam 20, the metal foam 20 in the embodiment of FIG. 4 being surrounded on all sides by sections or areas designed as supports.
- 5 to 8 show exemplary embodiments of static gas turbine components according to the invention, in which the components according to the invention form an inlet lining.
- 5 shows a first inlet covering 27 according to the invention, which is formed from a metal foam 28, the metal foam 28 being firmly connected to a carrier 29.
- the inlet lining 28 is used for the wear-free or low-wear rubbing against a rotating rotor blade 30 of the gas turbine.
- the inlet lining 27 is fixed with respect to the rotating rotor blade 30 and accordingly forms a static gas turbine component.
- FIG. 6 shows a further inlet covering 31, which in turn is formed from a metal foam 28 and a support 29 which is firmly connected to the metal foam 28.
- the inlet lining 31 of FIG. 6 also serves to rub against the radially outer ends of rotating blades of the gas turbine, the carrier 29 performing a thermal insulation function in the inlet lining 31 of FIG. 6.
- FIG. 7 shows a further inlet covering 32 according to the invention, which in turn consists of a metal foam 28 and a carrier 29 assigned to the metal foam 28 and firmly connected to the metal foam 28.
- the static or fixed inlet lining 32 of FIG. 7 interacts with labyrinth seals 33, which are also referred to as sealing fins.
- labyrinth seals 33 which are also referred to as sealing fins.
- Such sealing fins as shown schematically in FIG. 7, have different outer radii, so that the inlet lining 32 provided by the metal foam 28 has a stepped contour.
- the inside diameter of the inlet covering 32 provided by the metal foam 28 is adapted to the outside diameter of the labyrinth seals 33. It should be noted that the design of the inlet covering 32 according to FIG.
- the honeycomb construction of the prior art known from the prior art Inlet pads can be replaced.
- the metal foam 28 is firmly connected to the carrier 29, in particular glued or soldered.
- FIG. 8 shows a further inlet covering 34 according to the invention, which in turn is formed from a metal foam 28 and a carrier 29 for the metal foam.
- openings or bores 35 are made in the carrier 29.
- a gas flow can be passed through the bores 35 in the direction of the arrows 36 for cooling, in which case the metal foam 28 is open-pored.
- Such an open-pore metal foam 28 can have gas flowing through it. This is illustrated by the arrows 37.
- FIGS. 9 to 13 show further preferred gas turbine components which are formed in some areas from metal foam, all gas turbine components shown in FIGS. 9 to 13 forming a pipeline system.
- a pipeline system 38 is shown, the pipeline system 38 being formed by a closed-walled tube 39 which is surrounded on the outside concentrically by metal foam 40.
- metal foam 40 With such a pipeline system, which in some areas consists of metal foam, improved vibration properties and thermal insulation properties of pipeline systems can be realized within gas turbines. This prevents the piping systems from igniting or coking.
- FIG. 10 shows an embodiment of a pipeline system 41, the pipeline system 41 of FIG. 10 again being formed by a closed-walled pipe 39 which is surrounded on the outside by metal foam 40. 10 illustrates that the metal foam 40 can have any shape on the outside of the closed-wall tube 39.
- the pipe system 42 shown in FIG. 12 differs from the pipe system 41 of FIG. 10 in that a fastening means 43 is integrated in the metal foam 40.
- a fastening means can be foamed onto the tube in a simple manner. This significantly simplifies the connection with other components.
- Fig. 1 1 shows a piping system 44 according to the invention, which in turn is partially formed from metal foam.
- a closed-walled tube 39 is again provided, the tube 39 in the exemplary embodiment in FIG. 11 having a closed inner wall 45 and a closed outer wall 46.
- the tube 39 is accordingly double-walled in the embodiment of FIG. 11.
- the metal foam 40 is positioned between the two walls 45 and 46.
- FIG. 13 shows a further exemplary embodiment of a pipeline system 47 according to the invention, the pipeline system 47 of FIG. 13 having four closed-walled tubes 39, which are positioned together in a metal foam 40.
- a plurality of pipes 39 are therefore combined to form an integral unit via the metal foam 40.
- All of the exemplary embodiments of a gas turbine component according to the invention shown in FIGS. 2 to 13 are static components for aircraft engines.
- the components according to the invention have a minimized weight, good thermal insulation properties and are furthermore inexpensive to produce. Vibrations that occur can be dampened safely and well via the metal foam.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/582,930 US7775766B2 (en) | 2003-12-20 | 2004-12-09 | Gas turbine component |
EP04802912A EP1702138B1 (de) | 2003-12-20 | 2004-12-09 | Gasturbinenbauteil |
CA002547619A CA2547619A1 (en) | 2003-12-20 | 2004-12-09 | Gas turbine component |
DE502004003916T DE502004003916D1 (de) | 2003-12-20 | 2004-12-09 | Gasturbinenbauteil |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10360164A DE10360164A1 (de) | 2003-12-20 | 2003-12-20 | Gasturbinenbauteil |
DE10360164.3 | 2003-12-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005061855A1 true WO2005061855A1 (de) | 2005-07-07 |
Family
ID=34683687
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE2004/002706 WO2005061855A1 (de) | 2003-12-20 | 2004-12-09 | Gasturbinenbauteil |
Country Status (5)
Country | Link |
---|---|
US (1) | US7775766B2 (de) |
EP (1) | EP1702138B1 (de) |
CA (1) | CA2547619A1 (de) |
DE (2) | DE10360164A1 (de) |
WO (1) | WO2005061855A1 (de) |
Cited By (7)
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WO2007031279A1 (de) * | 2005-09-16 | 2007-03-22 | Orbiter Group Beteiligungsgesellschaft Mbh | Verwendung eines metallschaumes in strömungsmaschinen, insbesondere in turbinen, lüftern und pumpen |
EP1878876A2 (de) | 2006-07-11 | 2008-01-16 | Rolls-Royce plc | Abreibbare Dichtungsschicht einer Gasturbine sowie Verfahren zu deren Herstellung |
WO2008011864A1 (de) * | 2006-07-26 | 2008-01-31 | Mtu Aero Engines Gmbh | Gasturbine mit einem mantelringsegment umfassend einen rezirkulationskanal |
EP2184449A1 (de) * | 2008-11-05 | 2010-05-12 | Siemens Aktiengesellschaft | Leitschaufelträger, und Gasturbine und Gas- bzw. Dampfturbinenanlage mit solchem Leitschaufelträger |
EP2372103A1 (de) * | 2007-12-04 | 2011-10-05 | Hitachi Ltd. | Dichtungsanordnung für eine Dampfturbine |
EP2881666A1 (de) * | 2013-12-09 | 2015-06-10 | Siemens Aktiengesellschaft | Düsenträger aus metallischem Schaum |
FR3071427A1 (fr) * | 2017-09-22 | 2019-03-29 | Safran | Carter de turbomachine |
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DE102006022164B4 (de) * | 2006-05-12 | 2012-07-19 | Mtu Aero Engines Gmbh | Verfahren zum Aussteifen eines Rotorelements |
GB2449249B (en) * | 2007-05-14 | 2009-10-21 | Rolls Royce Plc | Seal assembley |
DE102007038507A1 (de) * | 2007-08-14 | 2009-02-19 | Endress + Hauser Flowtec Ag | Rohrleitung bzw. Messrohr mit mindestens einer, mindestens bereichsweise isolierenden Schicht und Verfahren zu dessen Herstellung |
US8313288B2 (en) * | 2007-09-06 | 2012-11-20 | United Technologies Corporation | Mechanical attachment of ceramic or metallic foam materials |
DE102007047739B4 (de) * | 2007-10-05 | 2014-12-11 | Rolls-Royce Deutschland Ltd & Co Kg | Gasturbinenverdichter mit Anlaufschicht |
DE102008005479A1 (de) * | 2008-01-23 | 2009-07-30 | Rolls-Royce Deutschland Ltd & Co Kg | Gasturbine mit einem Verdichter mit flüssigkeitsbeaufschlagter Einlaufschicht |
DE102008005480A1 (de) * | 2008-01-23 | 2009-07-30 | Rolls-Royce Deutschland Ltd & Co Kg | Gasturbine mit einem Verdichter mit Einlaufschicht mit luftaushärtendem Material |
US8257016B2 (en) | 2008-01-23 | 2012-09-04 | Rolls-Royce Deutschland Ltd & Co Kg | Gas turbine with a compressor with self-healing abradable coating |
DE102008019331A1 (de) | 2008-04-16 | 2009-10-22 | Rolls-Royce Deutschland Ltd & Co Kg | Einlaufdichtung für den Kompressor eines Gasturbinentriebwerks |
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JP5411569B2 (ja) * | 2009-05-01 | 2014-02-12 | 株式会社日立製作所 | シール構造とその制御方法 |
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US20130017070A1 (en) * | 2011-07-13 | 2013-01-17 | General Electric Company | Turbine seal, turbine, and process of fabricating a turbine seal |
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JP5597174B2 (ja) * | 2011-09-20 | 2014-10-01 | 株式会社日立製作所 | アブレイダブルコーティングを有する部材およびガスタービン |
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US10156359B2 (en) | 2012-12-28 | 2018-12-18 | United Technologies Corporation | Gas turbine engine component having vascular engineered lattice structure |
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US9517606B2 (en) * | 2014-08-06 | 2016-12-13 | The Boeing Company | Composite structure and method of forming thereof |
US9789536B2 (en) | 2015-01-20 | 2017-10-17 | United Technologies Corporation | Dual investment technique for solid mold casting of reticulated metal foams |
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US11674405B2 (en) | 2021-08-30 | 2023-06-13 | General Electric Company | Abradable insert with lattice structure |
US11834956B2 (en) * | 2021-12-20 | 2023-12-05 | Rolls-Royce Plc | Gas turbine engine components with metallic and ceramic foam for improved cooling |
US11746660B2 (en) | 2021-12-20 | 2023-09-05 | Rolls-Royce Plc | Gas turbine engine components with foam filler for impact resistance |
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EP1186748A1 (de) * | 2000-09-05 | 2002-03-13 | Siemens Aktiengesellschaft | Laufschaufel für eine Strömungsmaschine sowie Strömungsmaschine |
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- 2004-12-09 US US10/582,930 patent/US7775766B2/en not_active Expired - Fee Related
- 2004-12-09 CA CA002547619A patent/CA2547619A1/en not_active Abandoned
- 2004-12-09 WO PCT/DE2004/002706 patent/WO2005061855A1/de active IP Right Grant
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Cited By (11)
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WO2007031279A1 (de) * | 2005-09-16 | 2007-03-22 | Orbiter Group Beteiligungsgesellschaft Mbh | Verwendung eines metallschaumes in strömungsmaschinen, insbesondere in turbinen, lüftern und pumpen |
EP1878876A2 (de) | 2006-07-11 | 2008-01-16 | Rolls-Royce plc | Abreibbare Dichtungsschicht einer Gasturbine sowie Verfahren zu deren Herstellung |
EP1878876A3 (de) * | 2006-07-11 | 2013-01-16 | Rolls-Royce plc | Abreibbare Dichtungsschicht einer Gasturbine sowie Verfahren zu deren Herstellung |
WO2008011864A1 (de) * | 2006-07-26 | 2008-01-31 | Mtu Aero Engines Gmbh | Gasturbine mit einem mantelringsegment umfassend einen rezirkulationskanal |
US8092148B2 (en) | 2006-07-26 | 2012-01-10 | Mtu Aero Engines Gmbh | Gas turbine having a peripheral ring segment including a recirculation channel |
EP2372103A1 (de) * | 2007-12-04 | 2011-10-05 | Hitachi Ltd. | Dichtungsanordnung für eine Dampfturbine |
US8128351B2 (en) | 2007-12-04 | 2012-03-06 | Hitachi, Ltd. | Seals in steam turbine |
US8500397B2 (en) | 2007-12-04 | 2013-08-06 | Hitachi, Ltd. | Seals in steam turbine |
EP2184449A1 (de) * | 2008-11-05 | 2010-05-12 | Siemens Aktiengesellschaft | Leitschaufelträger, und Gasturbine und Gas- bzw. Dampfturbinenanlage mit solchem Leitschaufelträger |
EP2881666A1 (de) * | 2013-12-09 | 2015-06-10 | Siemens Aktiengesellschaft | Düsenträger aus metallischem Schaum |
FR3071427A1 (fr) * | 2017-09-22 | 2019-03-29 | Safran | Carter de turbomachine |
Also Published As
Publication number | Publication date |
---|---|
EP1702138A1 (de) | 2006-09-20 |
US7775766B2 (en) | 2010-08-17 |
EP1702138B1 (de) | 2007-05-23 |
US20070122269A1 (en) | 2007-05-31 |
CA2547619A1 (en) | 2005-07-07 |
DE10360164A1 (de) | 2005-07-21 |
DE502004003916D1 (de) | 2007-07-05 |
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