WO2005016873A3 - 4-biphenylsubstituierte pyrazolidin-3,5-dion- derivative als schädlingsbekämpfungsmittel und/oder herbizide und/oder mikrobiozide - Google Patents

4-biphenylsubstituierte pyrazolidin-3,5-dion- derivative als schädlingsbekämpfungsmittel und/oder herbizide und/oder mikrobiozide Download PDF

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Publication number
WO2005016873A3
WO2005016873A3 PCT/EP2004/008638 EP2004008638W WO2005016873A3 WO 2005016873 A3 WO2005016873 A3 WO 2005016873A3 EP 2004008638 W EP2004008638 W EP 2004008638W WO 2005016873 A3 WO2005016873 A3 WO 2005016873A3
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WO
WIPO (PCT)
Prior art keywords
dione derivatives
pyrazolidin
biphenylsubstituted
biphenyl
formula
Prior art date
Application number
PCT/EP2004/008638
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English (en)
French (fr)
Other versions
WO2005016873A2 (de
Inventor
Reiner Fischer
Thomas Bretschneider
Ernst Rudolf F Gesing
Dieter Feucht
Karl-Heinz Kuck
Peter Loesel
Olga Malsam
Christian Arnold
Thomas Auler
Martin Jeffrey Hills
Heinz Kehne
Original Assignee
Bayer Cropscience Ag
Reiner Fischer
Thomas Bretschneider
Ernst Rudolf F Gesing
Dieter Feucht
Karl-Heinz Kuck
Peter Loesel
Olga Malsam
Christian Arnold
Thomas Auler
Martin Jeffrey Hills
Heinz Kehne
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CN2004800293416A priority Critical patent/CN1863806B/zh
Application filed by Bayer Cropscience Ag, Reiner Fischer, Thomas Bretschneider, Ernst Rudolf F Gesing, Dieter Feucht, Karl-Heinz Kuck, Peter Loesel, Olga Malsam, Christian Arnold, Thomas Auler, Martin Jeffrey Hills, Heinz Kehne filed Critical Bayer Cropscience Ag
Priority to CA002535512A priority patent/CA2535512A1/en
Priority to BRPI0413531-8A priority patent/BRPI0413531A/pt
Priority to KR1020067002980A priority patent/KR101110112B1/ko
Priority to JP2006522945A priority patent/JP5432432B2/ja
Priority to EP04763708A priority patent/EP1656382A2/de
Priority to US10/567,788 priority patent/US8119566B2/en
Priority to AU2004265089A priority patent/AU2004265089B2/en
Publication of WO2005016873A2 publication Critical patent/WO2005016873A2/de
Publication of WO2005016873A3 publication Critical patent/WO2005016873A3/de
Priority to US13/017,194 priority patent/US8168566B2/en
Priority to US13/347,931 priority patent/US8586783B2/en
Priority to US13/952,858 priority patent/US8987500B2/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/612—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety
    • C07C69/616—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety polycyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/28—Two oxygen or sulfur atoms
    • C07D231/30—Two oxygen or sulfur atoms attached in positions 3 and 5
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00—Antiparasitic agents
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00—Antiparasitic agents
    • A61P33/14—Ectoparasiticides, e.g. scabicides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/49—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups
    • C07C205/56—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by carboxyl groups having nitro groups bound to carbon atoms of six-membered aromatic rings and carboxyl groups bound to acyclic carbon atoms of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/62—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/28—Two oxygen or sulfur atoms
    • C07D231/30—Two oxygen or sulfur atoms attached in positions 3 and 5
    • C07D231/32—Oxygen atoms
    • C07D231/36—Oxygen atoms with hydrocarbon radicals, substituted by hetero atoms, attached in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/08—Bridged systems

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Die vorliegende Erfindung betrifft neue 4-Biphenylsubstituierte Pyrazolidin-3,5-dion-Derivate, der Formel (I) in welcher A, D, G, W, X, Y und Z die oben angegebenen Bedeutungen haben, mehrere Verfahren zu ihrer Herstellung und ihre Verwendung als Schädlingsbekämpfungsmittel und/oder Herbizide und/oder Mikrobizide. Außerdem betrifft die Erfindung selektiv herbizide Mittel, die 4-Biphenylsubstituierte Pyrazolidin-3,5-dion-Derivate der Formel (I) einerseits und eine die Kulturpflanzenverträglichkeit verbessernde Verbindung andererseits enthalten.
PCT/EP2004/008638 2003-08-14 2004-08-02 4-biphenylsubstituierte pyrazolidin-3,5-dion- derivative als schädlingsbekämpfungsmittel und/oder herbizide und/oder mikrobiozide WO2005016873A2 (de)

Priority Applications (11)

Application Number Priority Date Filing Date Title
EP04763708A EP1656382A2 (de) 2003-08-14 2004-08-02 4-biphenylsubstituierte pyrazolidin-3,5-dion-derivate als schädlingsbekämpfungsmittel und/oder herbizide und/oder mikrobiozide
CA002535512A CA2535512A1 (en) 2003-08-14 2004-08-02 4-biphenylsubstituted pyrazolidin-3,5-dione derivatives
BRPI0413531-8A BRPI0413531A (pt) 2003-08-14 2004-08-02 derivados de órazpçodoma-3.5-diona substituìda com 4-bifenila
KR1020067002980A KR101110112B1 (ko) 2003-08-14 2004-08-02 4-비페닐 치환된 피라졸리딘-3,5-디온 유도체
JP2006522945A JP5432432B2 (ja) 2003-08-14 2004-08-02 ４−ビフェニル置換ピラゾリジン−３，５−ジオン誘導体
CN2004800293416A CN1863806B (zh) 2003-08-14 2004-08-02 4-联苯基取代的吡唑烷-3,5-二酮衍生物
US10/567,788 US8119566B2 (en) 2003-08-14 2004-08-02 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives
AU2004265089A AU2004265089B2 (en) 2003-08-14 2004-08-02 4-biphenylsubstituted pyrazolidin-3,5-dione derivatives
US13/017,194 US8168566B2 (en) 2003-08-14 2011-01-31 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives
US13/347,931 US8586783B2 (en) 2003-08-14 2012-01-11 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives
US13/952,858 US8987500B2 (en) 2003-08-14 2013-07-29 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10337497A DE10337497A1 (de) 2003-08-14 2003-08-14 4-Biphenylsubstituierte-Pyrazolidin-3,5-dion-Derivate
DE10337497.3 2003-08-14

Related Child Applications (4)

Application Number Title Priority Date Filing Date
US10/567,788 A-371-Of-International US8119566B2 (en) 2003-08-14 2004-08-02 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives
US13/017,194 Division US8168566B2 (en) 2003-08-14 2011-01-31 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives
US13/347,931 Division US8586783B2 (en) 2003-08-14 2012-01-11 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives
US13/952,858 Division US8987500B2 (en) 2003-08-14 2013-07-29 4-biphenyl-substituted pyrazolidin-3,5-dione derivatives

Publications (2)

Publication Number Publication Date
WO2005016873A2 WO2005016873A2 (de) 2005-02-24
WO2005016873A3 true WO2005016873A3 (de) 2005-04-07

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PCT/EP2004/008638 WO2005016873A2 (de) 2003-08-14 2004-08-02 4-biphenylsubstituierte pyrazolidin-3,5-dion- derivative als schädlingsbekämpfungsmittel und/oder herbizide und/oder mikrobiozide

Country Status (11)

Country Link
US (4) US8119566B2 (de)
EP (1) EP1656382A2 (de)
JP (2) JP5432432B2 (de)
KR (1) KR101110112B1 (de)
CN (3) CN102050722B (de)
AR (1) AR045246A1 (de)
AU (1) AU2004265089B2 (de)
BR (1) BRPI0413531A (de)
CA (1) CA2535512A1 (de)
DE (1) DE10337497A1 (de)
WO (1) WO2005016873A2 (de)

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US8013172B2 (en) 2006-02-21 2011-09-06 Bayer Cropscience Ag Cycloalkylphenyl substituted cyclic ketoenols
US8993782B2 (en) 2006-12-04 2015-03-31 Bayer Cropscience Ag Cis-alkoxyspirocyclic biphenyl-substituted tetramic acid derivatives

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DE102004011006A1 (de) * 2004-03-06 2005-09-22 Bayer Cropscience Ag Suspensionskonzentrate auf Ölbasis
DE102004044827A1 (de) 2004-09-16 2006-03-23 Bayer Cropscience Ag Jod-phenylsubstituierte cyclische Ketoenole
DE102004049041A1 (de) * 2004-10-08 2006-04-13 Bayer Cropscience Ag Fungizide Wirkstoffkombinationen
DE102004053191A1 (de) * 2004-11-04 2006-05-11 Bayer Cropscience Ag 2,6-Diethyl-4-methyl-phenyl substituierte Tetramsäure-Derivate
DE102004053192A1 (de) * 2004-11-04 2006-05-11 Bayer Cropscience Ag 2-Alkoxy-6-alkyl-phenyl substituierte spirocyclische Tetramsäure-Derivate
DE102005057250A1 (de) * 2005-11-29 2007-06-06 Bayer Cropscience Gmbh Wirkstoffe zur Steigerung der Stressabwehr in Pflanzen gegenüber abiotischem Stress und Methoden zu ihrer Auffindung
DE102005059469A1 (de) 2005-12-13 2007-06-14 Bayer Cropscience Ag Insektizide Zusammensetzungen mit verbesserter Wirkung
JO3598B1 (ar) * 2006-10-10 2020-07-05 Infinity Discovery Inc الاحماض والاسترات البورونية كمثبطات اميد هيدروليز الحامض الدهني
DE102006057036A1 (de) 2006-12-04 2008-06-05 Bayer Cropscience Ag Biphenylsubstituierte spirocyclische Ketoenole
US8252841B2 (en) 2007-10-19 2012-08-28 The Board Of Regents Of The University Of Texas System Methods of inhibiting bacterial virulence and compounds relating thereto
TW201000107A (en) * 2008-04-09 2010-01-01 Infinity Pharmaceuticals Inc Inhibitors of fatty acid amide hydrolase
US8524748B2 (en) 2008-10-08 2013-09-03 Panmira Pharmaceuticals, Llc Heteroalkyl biphenyl antagonists of prostaglandin D2 receptors
ES2395704T3 (es) * 2008-12-19 2013-02-14 Novartis Ag Derivados de isoxazolina y su uso como pesticida
WO2010102758A2 (de) 2009-03-11 2010-09-16 Bayer Cropscience Ag Halogenalkylmethylenoxy-phenyl-substituierte ketoenole
JP2012523424A (ja) 2009-04-07 2012-10-04 インフイニトイ プハルマセウトイカルス インコーポレイテッド 脂肪酸アミドヒドロラーゼの阻害薬
EP2417115A4 (de) 2009-04-07 2012-10-31 Infinity Pharmaceuticals Inc Fettsäureamidhydrolase-hemmer
DK2451767T3 (da) 2009-07-07 2019-11-11 Bayer Cropscience Ag Fremgangsmåde til fremstilling af (2,4 dimethylbiphenyl 3 yl)eddikesyrer, deres estere samt mellemforbindelser
CA2788587C (en) 2010-02-03 2020-03-10 Infinity Pharmaceuticals, Inc. Fatty acid amide hydrolase inhibitors
ES2700996T3 (es) * 2010-02-10 2019-02-20 Bayer Cropscience Ag Cetoenoles cíclicos sustituidos con bifenilo
DE102010008644A1 (de) 2010-02-15 2011-08-18 Bayer Schering Pharma Aktiengesellschaft, 13353 Zyklische Ketoenole zur Therapie
JP5842594B2 (ja) 2010-12-27 2016-01-13 住友化学株式会社 ピリダジノン化合物、それを含有する除草剤及び有害節足動物防除剤
AR087008A1 (es) * 2011-06-22 2014-02-05 Syngenta Participations Ag Derivados de n-oxi-pirazolo-triazepina-diona
DK2806741T3 (da) 2012-01-26 2020-05-18 Bayer Ip Gmbh Phenylsubstituerede ketoenoler til bekæmpelse af fiskeparasitter
EP3913068B1 (de) 2015-10-12 2023-08-02 Advanced Cell Diagnostics, Inc. In-situ-detektion von nukleotidvarianten bei proben mit hohem rauschen sowie zugehörige zusammensetzungen und verfahren
CN109180667B (zh) * 2018-09-10 2021-08-06 湖南大学 8-(苯并呋喃-5-基)苯并噁嗪酮衍生物及其应用
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US8586783B2 (en) 2013-11-19
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US20130018202A1 (en) 2013-01-17
US20080188371A1 (en) 2008-08-07
US8168566B2 (en) 2012-05-01
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US8119566B2 (en) 2012-02-21
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JP2007502255A (ja) 2007-02-08
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EP1656382A2 (de) 2006-05-17
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