WO2004101272A1 - Feuille de support d'image - Google Patents

Feuille de support d'image Download PDF

Info

Publication number
WO2004101272A1
WO2004101272A1 PCT/AU2004/000626 AU2004000626W WO2004101272A1 WO 2004101272 A1 WO2004101272 A1 WO 2004101272A1 AU 2004000626 W AU2004000626 W AU 2004000626W WO 2004101272 A1 WO2004101272 A1 WO 2004101272A1
Authority
WO
WIPO (PCT)
Prior art keywords
substrate
image
image carrying
carrying sheet
sheet
Prior art date
Application number
PCT/AU2004/000626
Other languages
English (en)
Inventor
Anthony John Luk Anderson
Gerard Michael Mc Cluskey
Original Assignee
Digiglass Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AU2003902296A external-priority patent/AU2003902296A0/en
Priority claimed from AU2003903224A external-priority patent/AU2003903224A0/en
Application filed by Digiglass Pty Ltd filed Critical Digiglass Pty Ltd
Publication of WO2004101272A1 publication Critical patent/WO2004101272A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10743—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing acrylate (co)polymers or salts thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/1077—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyurethane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10788—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic

Definitions

  • This invention relates to the production of a sheet with an image that is visible from one or both sides of the sheet, such as laminated glass.
  • the image may take the form of a pattern, artistic work, written indicia or any other visually discernible form.
  • the invention also relates to a sheet with an image.
  • Laminated glass has many applications as a construction material. It can for example be used to form windows, walls, doors and screens. It can also be used for the construction of articles such as coffee tables, and other small articles of furniture. Laminated glass is specified or desired in a number of applications as a result its inherent safety characteristics compared to normal glass sheets.
  • Laminated glass is typically formed by joining two sheets of glass using a polyvinyl butyral interlayer. The production process normally involves placing the interlayer between the two sheets of glass, applying heat to soften the interlayer and then passing the sheets through nip rollers that squeeze the glass sheets into contact with the softened interlayer. A further step involves the treatment of the laminate so formed in an autoclave to complete the bonding process.
  • the image can be for the purposes of decoration or can serve a functional purpose by partially or completely obscuring the view through the laminated glass sheet.
  • Hitherto attempts to produce laminated glass with images have presented serious practical problems.
  • One way that an image has been formed on laminated glass is by screen printing onto the finished laminated sheet. This is a cumbersome process and limits the images that can be produced both in colour and detail. For example a multi-colour image requires a printing step for each colour.
  • the images can only be formed on discrete panels and for practical purposes this means that the images cannot be formed in a regular manner so that the panels can be subsequently arbitrarily cut.
  • an image carrying sheet including:
  • the substrate having an image formed by sublimation.
  • a substrate for use in the above image carrying sheet including an image formed on the substrate by sublimation.
  • a method of producing a substrate including:
  • an image carrying sheet including:
  • the present invention is an image carrying sheet including a substrate with an image, the image formed by sublimating at least one dye from a transfer medium to the substrate wherein the formed image does not significantly decrease the bonding ability of the image carrying sheet.
  • the image carrying sheet further includes a first sheet bonded to the substrate. More preferably, the image on the substrate can be viewed through the first sheet.
  • the first sheet is glass, acrylic, perspex or polycarbonate.
  • the substrate is an interlayer.
  • the substrate is polyvinyl butyral, polyurethane, ethylene vinyl acetate or ionoplast.
  • the substrate is polyester, polypropylene, polyethylenetelephthalate (PET), polybutylene tetephthalate (PBT), acrylics, polymethylacrylate, polymethacrylimide (PMI), polycarbonate, stryeneacrylicnitryl,
  • the substrate includes a coating of polyester, polypropylene, polyethylenetelephthalate (PET), polybutylene tetephthalate (PBT), acrylics, polymethylacrylate, polymethacrylimide (PMI), polycarbonate, stryeneacrylicnitryl, K-resin (stryenic block copolymer) polyethersulphone, polysulphone, clarified polypropylene, vinyl, polystyrene, polyvinyl butyrate, polyacrylate, cellulose acetate or cellulose acetate/butyrate.
  • PET polyethylenetelephthalate
  • PBT polybutylene tetephthalate
  • acrylics polymethylacrylate
  • PMI polymethacrylimide
  • PMI polycarbonate
  • stryeneacrylicnitryl polycarbonate
  • K-resin (stryenic block copolymer) polyethersulphone polysulphone, clarified polypropylene, vinyl, polystyrene, polyvinyl butyrate, polyacrylate
  • the substrate is a holographic foil.
  • Figure 1 A schematic diagram of a substrate, arranged for application of a sublimation process according to one embodiment of the invention.
  • Figure 2 A schematic diagram of layers of an image carrying sheet, arranged for application of the sublimation process according to another embodiment of the invention.
  • Figure 3 A schematic diagram of the layers of an image carrying sheet, arranged for application of the sublimation process according to another embodiment of the invention.
  • an image is formed on a substrate 2 by sublimating dyes on an image transfer medium 3 such as paper.
  • an image transfer medium 3 such as paper.
  • this sheet is supported on each side by two supporting sheets 1 , 5.
  • a sheet of heat resistant film 4 is also provided so that the supporting sheet 5 can be easily removed after the sublimation process.
  • the sublimation process uses heat and pressure to transfer an image from the transfer medium 3 to the substrate 2.
  • the transfer medium 3 is removed from the substrate 2 after the sublimation process.
  • the sublimation process uses a controlled atmosphere with a controllable pressure and temperature. In one embodiment, the sublimation process is undertaken in an autoclave.
  • the substrate 2, transfer medium 3, heat resistant film 4 and supporting sheets 1 , 5 form a layered sandwich and are in a vacuum. This could be formed by packing the layered sandwich in a vacuum bag and creating a vacuum within the bag.
  • the support layer 1 is a layer of the finished product, for example a rigid layer of glass or perspex and is bonded to the substrate 2 during the sublimation process.
  • the support sheet 1 supports the image carrying sheet 2 and allows it to be handled and/or treated with minimal relative movement between the image carrying sheet 2 and the support sheet 1 during the process of forming the image.
  • Some of the processes suitable for forming the image require the sheet to be moved through a processing line which includes, for example, a nip roller, at a consistent rate to prevent "banding and misses" in the printing.
  • many of the processes suitable for forming the image on the substrate 2 involve the use of heat.
  • the substrate can be an interlayer that is very heat sensitive and typically loses much of its mechanical strength at temperatures of 60°C and above. The use of a support sheet 1 allows the interlayer to be handled and/or treated in systems involving the use of heat without unacceptable stretching or damage.
  • the heat resistant film 4 is provided to assist the removal of the support sheet 5.
  • the support sheet 5 does not soften, during the sublimation process, so as to provide additional support to the substrate 2, for example PMMA, polycarbonate or glass.
  • an image is formed on a substrate 11 by sublimating dyes from an image transfer medium 12 such as paper.
  • an image transfer medium 12 such as paper.
  • a sheet of heat resistant film 13, 14 is also provided so that the supporting sheets 15, 16 can be easily removed after the sublimation process.
  • the substrate 11 is not bonded to another sheet during the sublimation process.
  • the substrate 11 may therefore represent the final image carrying sheet product, for example a sheet of acrylic, or an intermediate layer of a final product, which will then be bonded to other sheets in further processes.
  • Both supporting sheets 15, 16 are removed after the sublimation process.
  • an image is formed on a substrate 22 . by sublimating dyes on an image transfer medium 23 such as paper.
  • An interlayer sheet 21 of the final image carrying sheet product is also attached.
  • As the image carrying sheet 22 and sheet 21 soften during the sublimation process, these sheets are supported on each side by two supporting sheets 26, 27.
  • a sheet of heat resistant film 24, 25 is also provided so that the supporting sheets 26, 27 can be easily removed after the sublimation process.
  • the substrate 22 such as a polyurethane interlayer and the sheet 21 such as acrylic are bonded together during the sublimation process. Both supporting sheets 26, 27 are removed after the sublimation process. The sheet 21 and substrate 22 becomes part of the final product.
  • Additional sheets may also be applied after the sublimation process to form a laminate of acrylic, polyurethane interlayer, polyurethane interlayer and acrylic. These can be applied by a laminating these layers or using an autoclave to bond the sheets together. Additionally, it is preferable that the image is allowed to cure on the substrate before the image carrying sheet is used in further processing, such as glass lamination. Depending upon ambient temperatures a curing period of up to 24 hours or more has been found to be beneficial in some cases.
  • the substrate can be formed as an interlayer of any appropriate type, for example polyvinyl butyral, polyurethane, ethylene vinyl acetate or ionoplast.
  • the image can be printed on interiayers that are substantially transparent once laminated between two sheets that are at least semi transparent.
  • interiayers that are designed to be opaque or partially opaque through for example colouring can be used.
  • Interiayers of any thickness otherwise appropriate for the laminating of glass can be used. Commonly available interiayers are in multiples of 0.38mm in thickness.
  • the substrate could be any appropriate material, for example a polymer which may include polyester, polypropylene, polyethylenetelephthalate (PET), polybutylene tetephthalate (PBT), acrylics, polymethylacrylate, polymethacrylimide (PMI), polycarbonate, stryeneacrylicnitryl, K-resin (stryenic block copolymer) polyethersulphone, polysulphone, clarified polypropylene, vinyl, polystyrene, polyvinyl butyrate, polyacrylate, cellulose acetate, cellulose acetate/butyrate.
  • the substrate could also be any suitable material such as a holographic foil with a coating of one or more of the above.
  • the sheet 1 , 11 , 21 could be any appropriate material, for example glass, acrylic, perspex or polycarbonate. These may be fully transparent or only partially transparent and could include tinting. These sheets may also include a textured finish in the end product. This can include having a textured finish on a non heat softening support sheet so that when heated, for example during the sublimation process, the heat softening material may substantially conform to the textured finish of the non heat softening support sheet. Additionally these sheets may also include coatings for their protection, coatings to assist in the joining process or coatings to assist the reception of an image.
  • Adhesion promoting coatings are generally polyester based such as Resydrol Van 6113W/42WALG, manufactured by Solutia.
  • Other coatings are aliphatic polyurethane dispersions such as DaotanTM VTW 1233, manufactured by Solutia or Permathane RU41-347, manufactured by Stahl.
  • the sublimation dye may not be as fade resistant, particularly in outdoor applications, as other dyes. It may be that an UV absorbing additive be incorporated into the adhesion promoting coating.
  • suitable UV absorbing compounds include hexadecyl 3,5-di-tert-butyl-4-hydroxy-benzoate, available as Cyasorb UV-2908; 2-hydroxy-4-(octyloxy)benzophenone, available as Cyasorb UV531 ; 2-(2'-hydroxy-5 , -methylphenyl)benzotriazole, available as Tinuvin 900 from Ciba Geigy Corporation; 2-(3', 5'-di-tert-butyl-2'-hydroxyphenyl)-5- chlorobenzotriazole, available as Tinuvin 327 from Ciba Geigy Corporation; 2-(4- benzoyl-3-hydroxyphenoxy)ethylacrylate (available as Cyasorb UV-416) and poly(2-(4-benzoyl-3-hydroxyphenoxy)e
  • the quality of the image formed in this way is superior to that obtained by other printing methods (e.g. screenprinting, flexographic printing);
  • the image can be effectively encapsulated between transparent plies and is thus protected from abrasion, marring and scratching. Additionally the image is protected from damage from cleaning chemicals.
  • the image is printed using a sublimation dye, such as Digistar PES available from Lechler S.p.A., to a transfer medium, such as Jetcol HTR® 4000 paper manufactured by Coldenhove Textil.
  • a sublimation dye such as Digistar PES available from Lechler S.p.A.
  • the printed image on the transfer medium is then placed onto the interlayer and a layer of glass.
  • a heat resistant film for example Dartek® nylon film made by DuPont, is then placed on the other side to the transfer medium and a second layer of glass is used and forming a sandwich with the two layers of glass on the outside.
  • This sandwich is schematically shown in Figure 1 and is then vacuum packed and transferred to an autoclave which typically operates at a temperature of 135°C at a pressure of 11.5 bar.
  • the heat and pressure of the autoclave transfers the image from the transfer medium to the interlayer by sublimation of the dye.
  • the second layer of glass, heat resistant film and transfer medium is removed.
  • the glass and interlayer may be returned to a controlled environment to recondition the interlayer.
  • a second interlayer is applied to the interlayer with the image and another glass layer sandwiches the two interiayers. This sandwich is moved through an oven operating at a temperature of approximately 200°C before passing between nip rollers exerting a pressure of around 10 bar. This results in both the interiayers softening and bonding the two sheets of glass together.
  • the nip rollers ensure that there is no entrapped air in the laminated sheet.
  • the laminated sheets so formed are then transferred to an autoclave which typically operates at a temperature of 135°C at a pressure of 11.5 bar. They are typically autoclaved for around 3.5 hours.
  • Samples of laminated sheet were prepared in accordance with the above described example using a 0.38mm thick PVB R11 polyvinyl butyral interlayer produced by Solutia Australia Pty Ltd.
  • the glass sheets were 3mm thick.
  • Example 2 The image is printed to the transfer medium as in Example 1.
  • the transfer medium is placed onto a heat softening sheet, in this example an acrylic sheet.
  • a heat resistant film for example Dartek® nylon film made by DuPont, is then placed on either side.
  • a non heat softening sheet is then placed on either side of the heat resistant film creating a sandwich.
  • This sandwich is schematically shown in Figure 2 and is then vacuum packed transferred to an autoclave which typically operates at a temperature of 135°C at a pressure of 11.5 bar. The heat and pressure of the autoclave transfers the image from the transfer medium to the interlayer by sublimation of the dye.
  • a laminated sheet with polyurethane interlayer and acrylic sheets was prepared in a similar manner to Example 1. The only difference being the acrylic sheets were supported during both stages by a non heat softening support sheet such as glass with a heat resistant film between the acrylic sheet and the support sheet. This sandwich is schematically shown in Figure 3.
  • the image is printed to the transfer medium as in Example 1.
  • the transfer medium is placed onto a holographic foil having a polyester film on the surface which it contacts.
  • a heat resistant film for example Dartek® nylon film made by DuPont, is then placed on either side.
  • a non heat softening sheet is then placed on either side of the heat resistant film creating a sandwich.
  • This sandwich is then vacuum packed transferred to an autoclave which typically operates at a temperature of 135°C at a pressure of 11.5 bar. The heat and pressure of the autoclave transfers the image from the transfer medium to the interlayer by sublimation of the dye.
  • holographic foil After the sublimation process all additional layers are separated leaving the holographic foil with an image.
  • This imaged foil is then adhered to acrylic, glass or similar material using double sided adhesive tape or similar material.
  • This laminate is then nip rolled and a self adhesive vinyl backing is applied so as to protect the holographic foil.

Landscapes

  • Laminated Bodies (AREA)

Abstract

L'invention concerne une feuille de support d'image comprenant : un substrat stratifié prévu entre des couches rigides, substrat sur lequel une image est formée par sublimation. Les couches sont de préférence formées de verre ou de Perspex.
PCT/AU2004/000626 2003-05-13 2004-05-13 Feuille de support d'image WO2004101272A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
AU2003902296 2003-05-13
AU2003902296A AU2003902296A0 (en) 2003-05-13 2003-05-13 Image carrying sheet
AU2003903224 2003-06-24
AU2003903224A AU2003903224A0 (en) 2003-06-24 2003-06-24 Image carrying sheet

Publications (1)

Publication Number Publication Date
WO2004101272A1 true WO2004101272A1 (fr) 2004-11-25

Family

ID=33453164

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/AU2004/000626 WO2004101272A1 (fr) 2003-05-13 2004-05-13 Feuille de support d'image

Country Status (1)

Country Link
WO (1) WO2004101272A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014198422A1 (fr) 2013-06-14 2014-12-18 Tesa Labtec Gmbh Système thérapeutique transdermique (tts) doté de rotigotine

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4173672A (en) * 1977-09-06 1979-11-06 Mannheim Jose R Decorated safety glass
FR2639631A3 (fr) * 1988-11-28 1990-06-01 Siv Soc Italiana Vetro Agencement de composants d'un vitrage de securite
US5364479A (en) * 1990-10-11 1994-11-15 Societe Italiana Vetro-Siv-S.P.A. Process for the manufacture of decorated sheets of laminated safety glass
EP1129844A1 (fr) * 2000-02-29 2001-09-05 Brevet 2000 Holding S.A. Plaque décorative faite d'un matériau composite stratifié en verre et/ou plastiques transparents
JP2002307639A (ja) * 2001-04-13 2002-10-23 Shin Etsu Polymer Co Ltd 成形用印刷シート及び押釦スイッチ用キートップ部材

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4173672A (en) * 1977-09-06 1979-11-06 Mannheim Jose R Decorated safety glass
FR2639631A3 (fr) * 1988-11-28 1990-06-01 Siv Soc Italiana Vetro Agencement de composants d'un vitrage de securite
US5364479A (en) * 1990-10-11 1994-11-15 Societe Italiana Vetro-Siv-S.P.A. Process for the manufacture of decorated sheets of laminated safety glass
EP1129844A1 (fr) * 2000-02-29 2001-09-05 Brevet 2000 Holding S.A. Plaque décorative faite d'un matériau composite stratifié en verre et/ou plastiques transparents
JP2002307639A (ja) * 2001-04-13 2002-10-23 Shin Etsu Polymer Co Ltd 成形用印刷シート及び押釦スイッチ用キートップ部材

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Derwent World Patents Index; Class A97, AN 2003451471 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014198422A1 (fr) 2013-06-14 2014-12-18 Tesa Labtec Gmbh Système thérapeutique transdermique (tts) doté de rotigotine

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