WO2003021005A1 - Procede de revetement metallique de produit non conducteur - Google Patents

Procede de revetement metallique de produit non conducteur Download PDF

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Publication number
WO2003021005A1
WO2003021005A1 PCT/JP2002/008655 JP0208655W WO03021005A1 WO 2003021005 A1 WO2003021005 A1 WO 2003021005A1 JP 0208655 W JP0208655 W JP 0208655W WO 03021005 A1 WO03021005 A1 WO 03021005A1
Authority
WO
WIPO (PCT)
Prior art keywords
plating
product
nonconductor
nonconductor product
conducted
Prior art date
Application number
PCT/JP2002/008655
Other languages
English (en)
French (fr)
Inventor
Hideo Honma
Atsushi Kawahara
Taiji Nishiwaki
Takeshi Bessho
Masatsugu Nakanishi
Shigeru Suzuki
Akira Teranishi
Original Assignee
Kanto Kasei Co., Ltd.
Kanto Gakuin University Surface Engineering Research Institute
Toyota Jidosha Kabushiki Kaisha
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanto Kasei Co., Ltd., Kanto Gakuin University Surface Engineering Research Institute, Toyota Jidosha Kabushiki Kaisha filed Critical Kanto Kasei Co., Ltd.
Priority to EP20020762884 priority Critical patent/EP1445347B1/en
Priority to KR1020047002267A priority patent/KR100883726B1/ko
Priority to DE60238213T priority patent/DE60238213D1/de
Priority to JP2003525702A priority patent/JP4147317B2/ja
Priority to US10/486,169 priority patent/US6992000B2/en
Publication of WO2003021005A1 publication Critical patent/WO2003021005A1/ja

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/1851—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material
    • C23C18/1862—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material by radiant energy
    • C23C18/1868—Radiation, e.g. UV, laser
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/2006—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30
    • C23C18/2026—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30 by radiant energy
    • C23C18/2033—Heat
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/2006—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30
    • C23C18/2026—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30 by radiant energy
    • C23C18/204—Radiation, e.g. UV, laser
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/2006—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30
    • C23C18/2046—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30 by chemical pretreatment
    • C23C18/2053—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30 by chemical pretreatment only one step pretreatment
    • C23C18/206—Use of metal other than noble metals and tin, e.g. activation, sensitisation with metals
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/2006—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30
    • C23C18/2046—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30 by chemical pretreatment
    • C23C18/2073—Multistep pretreatment
    • C23C18/208—Multistep pretreatment with use of metal first
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00—Apparatus or processes for manufacturing printed circuits
    • H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
    • H05K3/18—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using precipitation techniques to apply the conductive material
    • H05K3/181—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using precipitation techniques to apply the conductive material by electroless plating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S438/00—Semiconductor device manufacturing: process
    • Y10S438/903—Catalyst aided deposition
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Optics & Photonics (AREA)
  • Toxicology (AREA)
  • Chemically Coating (AREA)
PCT/JP2002/008655 2001-08-31 2002-08-28 Procede de revetement metallique de produit non conducteur WO2003021005A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP20020762884 EP1445347B1 (en) 2001-08-31 2002-08-28 Method of plating nonconductor product
KR1020047002267A KR100883726B1 (ko) 2001-08-31 2002-08-28 부도체 제품의 도금방법
DE60238213T DE60238213D1 (de) 2001-08-31 2002-08-28 Verfahren zum beschichten eines nichtleiterprodukts
JP2003525702A JP4147317B2 (ja) 2001-08-31 2002-08-28 不導体製品のめっき方法
US10/486,169 US6992000B2 (en) 2001-08-31 2002-08-28 Method of plating nonconductor product

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2001262790 2001-08-31
JP2001-262790 2001-08-31
JP2002107356 2002-04-10
JP2002-107356 2002-04-10

Publications (1)

Publication Number Publication Date
WO2003021005A1 true WO2003021005A1 (fr) 2003-03-13

Family

ID=26621365

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2002/008655 WO2003021005A1 (fr) 2001-08-31 2002-08-28 Procede de revetement metallique de produit non conducteur

Country Status (8)

Country Link
US (1) US6992000B2 (ja)
EP (1) EP1445347B1 (ja)
JP (1) JP4147317B2 (ja)
KR (1) KR100883726B1 (ja)
CN (1) CN100390319C (ja)
DE (1) DE60238213D1 (ja)
TW (1) TW562873B (ja)
WO (1) WO2003021005A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007084873A (ja) * 2005-09-21 2007-04-05 Bokuno Horiguchi 導電性無電解めっき粉体の製造方法
JP2008255460A (ja) * 2007-04-09 2008-10-23 Rohm & Haas Electronic Materials Llc ポリイミド樹脂の無電解めっき処理方法
JP2010522829A (ja) * 2007-03-30 2010-07-08 ダンマルクス テクニスケ ウニベルシテット 選択金属化向けポリマー製品の調製
US7820279B2 (en) 2003-07-23 2010-10-26 Toyota Jidosha Kabushiki Kaisha Resin substrate having a resin-metal composite layer and method for manufacturing thereof
JP2013204107A (ja) * 2012-03-29 2013-10-07 Kanto Gakuin 無電解めっき方法および配線板
JP5830596B1 (ja) * 2014-12-25 2015-12-09 キヤノン・コンポーネンツ株式会社 めっき皮膜付樹脂製品並びに樹脂製品及びめっき皮膜付樹脂製品の製造方法
JP2016121387A (ja) * 2014-12-25 2016-07-07 キヤノン・コンポーネンツ株式会社 めっき皮膜付樹脂製品の製造方法

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4135459B2 (ja) * 2002-10-10 2008-08-20 トヨタ自動車株式会社 無電解めっき素材の前処理方法及びめっき被覆部材の製造方法
JP4064801B2 (ja) * 2002-12-12 2008-03-19 新光電気工業株式会社 金属膜形成処理方法、半導体装置及び配線基板
US7677198B2 (en) * 2005-11-28 2010-03-16 Industrial Technology Research Institute Method and apparatus for growing a composite metal sulphide photocatalyst thin film
KR100843156B1 (ko) 2007-06-25 2008-07-02 대덕전자 주식회사 풀 애디티브 인쇄 회로 기판 제조 방법
JPWO2010024175A1 (ja) * 2008-08-25 2012-01-26 株式会社関東学院大学表面工学研究所 積層体及びその製造方法
US9783890B2 (en) * 2012-10-26 2017-10-10 Rohm And Haas Electronic Materials Llc Process for electroless plating and a solution used for the same
KR101418004B1 (ko) * 2013-01-25 2014-07-09 한국전기연구원 산화제가 첨가된 에천트를 이용한 고농도 실리콘카바이드 에칭방법
KR20180120257A (ko) * 2016-04-15 2018-11-05 알프스 덴키 가부시키가이샤 부재, 전기·전자 부품, 전기·전자 기기, 및 부재의 제조 방법
US20190032220A1 (en) * 2017-07-25 2019-01-31 Rohm And Haas Electronic Materials Llc Chrome-free etch solutions for chemically resistant polymer materials

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5075004A (ja) * 1973-11-02 1975-06-20
US4659587A (en) * 1984-10-11 1987-04-21 Hitachi, Ltd. Electroless plating process and process for producing multilayer wiring board
JPH02285076A (ja) * 1989-04-26 1990-11-22 Hitachi Chem Co Ltd 無電解めっき用半導体光触媒のパターン形成法
US5126921A (en) * 1990-07-06 1992-06-30 Akira Fujishima Electronic component and a method for manufacturing the same
JPH08253869A (ja) * 1995-03-14 1996-10-01 Sharp Corp 樹脂の無電解メッキ方法
JPH1088361A (ja) * 1996-09-18 1998-04-07 Furukawa Electric Co Ltd:The 高分子成形体への無電解メッキ方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7316313A (nl) * 1973-11-29 1975-06-02 Philips Nv Werkwijze voor de vervaardiging van lichtgevoelig materiaal.
JPH075773B2 (ja) * 1992-12-22 1995-01-25 工業技術院長 紫外レーザーを用いたフッ素系高分子成形品の表面改質方法
JP3168761B2 (ja) * 1993-02-26 2001-05-21 ぺんてる株式会社 金属被覆粉体の製造方法
US6709806B2 (en) * 2000-03-31 2004-03-23 Kabushiki Kaisha Toshiba Method of forming composite member
JP2002080245A (ja) * 2000-06-28 2002-03-19 Canon Inc 反射型光学素子及びその製造方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5075004A (ja) * 1973-11-02 1975-06-20
US4659587A (en) * 1984-10-11 1987-04-21 Hitachi, Ltd. Electroless plating process and process for producing multilayer wiring board
JPH02285076A (ja) * 1989-04-26 1990-11-22 Hitachi Chem Co Ltd 無電解めっき用半導体光触媒のパターン形成法
US5126921A (en) * 1990-07-06 1992-06-30 Akira Fujishima Electronic component and a method for manufacturing the same
JPH08253869A (ja) * 1995-03-14 1996-10-01 Sharp Corp 樹脂の無電解メッキ方法
JPH1088361A (ja) * 1996-09-18 1998-04-07 Furukawa Electric Co Ltd:The 高分子成形体への無電解メッキ方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1445347A4 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7820279B2 (en) 2003-07-23 2010-10-26 Toyota Jidosha Kabushiki Kaisha Resin substrate having a resin-metal composite layer and method for manufacturing thereof
JP2007084873A (ja) * 2005-09-21 2007-04-05 Bokuno Horiguchi 導電性無電解めっき粉体の製造方法
JP2010522829A (ja) * 2007-03-30 2010-07-08 ダンマルクス テクニスケ ウニベルシテット 選択金属化向けポリマー製品の調製
JP2008255460A (ja) * 2007-04-09 2008-10-23 Rohm & Haas Electronic Materials Llc ポリイミド樹脂の無電解めっき処理方法
JP2013204107A (ja) * 2012-03-29 2013-10-07 Kanto Gakuin 無電解めっき方法および配線板
JP5830596B1 (ja) * 2014-12-25 2015-12-09 キヤノン・コンポーネンツ株式会社 めっき皮膜付樹脂製品並びに樹脂製品及びめっき皮膜付樹脂製品の製造方法
JP2016121387A (ja) * 2014-12-25 2016-07-07 キヤノン・コンポーネンツ株式会社 めっき皮膜付樹脂製品の製造方法

Also Published As

Publication number Publication date
JP4147317B2 (ja) 2008-09-10
US6992000B2 (en) 2006-01-31
CN1650046A (zh) 2005-08-03
JPWO2003021005A1 (ja) 2004-12-16
CN100390319C (zh) 2008-05-28
EP1445347A4 (en) 2008-04-16
TW562873B (en) 2003-11-21
US20040219374A1 (en) 2004-11-04
EP1445347B1 (en) 2010-11-03
EP1445347A1 (en) 2004-08-11
KR20040036713A (ko) 2004-04-30
KR100883726B1 (ko) 2009-02-12
DE60238213D1 (de) 2010-12-16

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