WO2003008045A2 - Verfahren zur immobilisierung von verbrennungsrückständen - Google Patents
Verfahren zur immobilisierung von verbrennungsrückständen Download PDFInfo
- Publication number
- WO2003008045A2 WO2003008045A2 PCT/AT2002/000211 AT0200211W WO03008045A2 WO 2003008045 A2 WO2003008045 A2 WO 2003008045A2 AT 0200211 W AT0200211 W AT 0200211W WO 03008045 A2 WO03008045 A2 WO 03008045A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- residues
- treatment
- waste
- chemical treatment
- filtrate
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 33
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 13
- 239000000126 substance Substances 0.000 claims abstract description 27
- 239000002699 waste material Substances 0.000 claims abstract description 26
- 239000000463 material Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000706 filtrate Substances 0.000 claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 9
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 238000003860 storage Methods 0.000 claims abstract description 7
- 238000011049 filling Methods 0.000 claims abstract description 4
- 238000007669 thermal treatment Methods 0.000 claims abstract description 3
- 238000004064 recycling Methods 0.000 claims abstract 2
- 229910001385 heavy metal Inorganic materials 0.000 claims description 7
- 235000011837 pasties Nutrition 0.000 claims description 7
- 239000002351 wastewater Substances 0.000 claims description 7
- 239000010802 sludge Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 238000000746 purification Methods 0.000 claims description 5
- 230000003100 immobilizing effect Effects 0.000 claims description 4
- 238000009434 installation Methods 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000009388 chemical precipitation Methods 0.000 claims description 2
- 230000001502 supplementing effect Effects 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims 1
- 238000002848 electrochemical method Methods 0.000 claims 1
- 230000008021 deposition Effects 0.000 abstract description 4
- 238000005065 mining Methods 0.000 abstract description 2
- 238000002955 isolation Methods 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
- 230000009469 supplementation Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 12
- 241000196324 Embryophyta Species 0.000 description 10
- 238000004140 cleaning Methods 0.000 description 5
- 239000002893 slag Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 239000010881 fly ash Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000004065 wastewater treatment Methods 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000549527 Fraxinus gooddingii Species 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000002920 hazardous waste Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- -1 iron ions Chemical class 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 238000010169 landfilling Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/33—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by chemical fixing the harmful substance, e.g. by chelation or complexation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B1/00—Dumping solid waste
- B09B1/008—Subterranean disposal, e.g. in boreholes or subsurface fractures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/08—Toxic combustion residues, e.g. toxic substances contained in fly ash from waste incineration
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2203/00—Aspects of processes for making harmful chemical substances harmless, or less harmful, by effecting chemical change in the substances
- A62D2203/02—Combined processes involving two or more distinct steps covered by groups A62D3/10 - A62D3/40
Definitions
- the invention relates to a method for immobilizing solid, liquid and / or pasty residues from the combustion and from the exhaust gas cleaning following the combustion, in particular from plants for the thermal treatment of waste.
- JP 8-309310 A discloses the treatment of fly ash from incinerators which contains heavy metals.
- the fly ash is mixed with an aqueous mineral acid solution and a pH value of less than or equal to 4 is set, the heavy metals being eluted.
- a pH value of less than or equal to 4 is set, the heavy metals being eluted.
- iron ions an oxidation reaction and a subsequent precipitation reaction, the heavy metals are converted into a precipitation product with iron hydroxide and finally bound as ferrite by adding an alkaline substance.
- the object of the invention is to avoid the disadvantages mentioned in the landfilling of insufficiently treated residues and to develop a method for immobilizing solid, liquid and / or pasty residues from the combustion and from the exhaust gas purification following the combustion, which the goals and principles of future-oriented waste economy met with economically reasonable costs.
- the wet chemical treatment at basic pH values partially elutes harmful substances from the residues and deliberately changes the hydraulic and mineralogical properties; Furthermore, gas formation from metallic residues (e.g. aluminum) is promoted, so that the reaction product from the wet chemical treatment can be subjected to the further immobilization steps after it has been dewatered.
- This is achieved in particular by adjusting the pH in the range from 8 to 13, preferably in the range from 11.5 to 12.5, in order to ensure that the gas formation potential from the reaction of metallic compounds is reduced.
- the wet chemical treatment can be carried out with the addition of lye, preferably in the form of alkaline residues or waste, it being possible to use electrochemical processes in addition to improve the chemical reaction in point b).
- the method according to the invention also fulfills the guidelines for waste management, published by the Federal Ministry for the Environment, Teen and Family in 1988, according to which a future-oriented waste economy includes comprehensive treatment of waste, so that ultimately only "earth crust-like" residues are deposited.
- the following properties are to be understood: insoluble or permanently poorly soluble
- An environmentally compatible disposal of solid, liquid and / or pasty residues from the combustion as well as from the exhaust gas cleaning following the combustion thus includes:
- gases generated during the wet chemical treatment according to point b) can be flared, stored or recycled, preferably for energy use in the incineration plant or in an external plant.
- the amount of the filtrate recirculated in point d) can advantageously be 3: 1 to 20: 1, depending on the solids content in the wet chemical treatment and the water content in the mechanically dewatered reaction product, based on the amount of waste supplied to the wet chemical treatment. It works on the basis of a closed water balance and additional process water required is advantageously fed from the incineration plant (e.g. thin sludge from wastewater treatment)
- the filtrate to be returned is subjected to intermediate treatment, for example for the chemical precipitation of dissolved heavy metals.
- intermediate treatment of the filtrate to be recycled can be carried out using organosulfidic compounds, for example TMT 15.
- the mechanically dewatered reaction product with the addition of mineral or inorganic auxiliaries and other suitable residues and wastes can be processed to landfill that can be deposited.
- dry materials are preferably used for the dewatered reaction product and, if required, wastewater is also used to adjust the optimum moisture for the controlled installation and compaction on the landfill (e.g. reaching the optimal density of the process).
- wastewater is also used to adjust the optimum moisture for the controlled installation and compaction on the landfill (e.g. reaching the optimal density of the process).
- gravel washing sludge can be added.
- the required amount of water can be covered by using any contaminated rainwater that occurs in the area where the landfill is installed, as well as any seepage water that may still be squeezed out during the compression process.
- the wet chemical treatment 2 is carried out of residues that cannot be deposited directly or are not suitable for producing landfill material (e.g. ash) while setting a basic pH value, if necessary in combination or in addition to electrochemical treatment.
- the gases obtained in the wet chemical treatment 2 in particular hydrogen, and possibly other gases such as ammonia, hydrogen sulfide, methane and phosphine are preferably fed to the incinerator in area 1 for energy use or a gas storage 3, or used in an external system for energy purposes (e.g. gas engine) or disposed of (e.g. gas torch).
- gases obtained in the wet chemical treatment 2 in particular hydrogen, and possibly other gases such as ammonia, hydrogen sulfide, methane and phosphine are preferably fed to the incinerator in area 1 for energy use or a gas storage 3, or used in an external system for energy purposes (e.g. gas engine) or disposed of (e.g. gas torch).
- Waste water concentrates or thin sludge from waste water purification for example from wet waste gas purification, can be fed to wet chemical treatment 2. This is necessary in view of the total water balance and the replacement for the moisture discharged onto the landfill body 5 via the production of the landfill material 4 and is advantageous compared to the use of fresh water.
- the mechanical dewatering 6 of the suspension from the wet chemical treatment 2 is preferably carried out using filter presses or other devices, advantageously together or alternately with other residues from the same system.
- the filtrate obtained in the mechanical dewatering 6 is returned to the wet chemical treatment 2, if appropriate after a chemical intermediate treatment 7 by means of precipitants, for example organosulfides for the precipitation and separation of dissolved heavy metals.
- precipitants for example organosulfides for the precipitation and separation of dissolved heavy metals.
- the amount of filtrate returned is based on a closed water balance, with additional water advantageously being supplied from area 1 of the incineration plant (for example thin sludge from wastewater treatment).
- the dewatered residues from the mechanical dewatering 6 are combined with residues from the incineration plant 1 that can be deposited directly, with mineral auxiliaries and / or other solid, pasty or liquid residues from external plants, e.g. processed according to the principle of "diagenetic inerting" (AT 389 474 B) into a depositable mass or landfill material (see production of landfill material 4).
- the landfill goods produced according to the appropriate recipe are stored indefinitely in accordance with the legal requirements, preferably on surface landfills 5 or for the filling of underground cavities by mining technology.
- the slightly occurring leachate (from the area of the installation site 8 and any squeezed water from the landfill material) can be used in the production of the landfill material 4 if required.
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Business, Economics & Management (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Management (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02744921A EP1406702A2 (de) | 2001-07-16 | 2002-07-16 | Verfahren zur immobilisierung von verbrennungsrückständen |
AU2002317023A AU2002317023A1 (en) | 2001-07-16 | 2002-07-16 | Methods for the immobilisation of combustion residues |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ATGM565/01 | 2001-07-16 | ||
AT0056501U AT5356U1 (de) | 2001-07-16 | 2001-07-16 | Verfahren zur immobilisierung von verbrennungsrückständen |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2003008045A2 true WO2003008045A2 (de) | 2003-01-30 |
WO2003008045A3 WO2003008045A3 (de) | 2003-04-17 |
Family
ID=3493968
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/AT2002/000211 WO2003008045A2 (de) | 2001-07-16 | 2002-07-16 | Verfahren zur immobilisierung von verbrennungsrückständen |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1406702A2 (de) |
AT (1) | AT5356U1 (de) |
AU (1) | AU2002317023A1 (de) |
WO (1) | WO2003008045A2 (de) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CZ298404B6 (cs) * | 1996-12-20 | 2007-09-19 | Meadwestvaco Packaging Systems, Llc | Prepravka predmetu a její prírez |
EP2308986A1 (de) | 2006-05-17 | 2011-04-13 | Pioneer Hi-Bred International Inc. | Künstliche Pflanzenminichromosome |
WO2011082318A2 (en) | 2009-12-30 | 2011-07-07 | Pioneer Hi-Bred International, Inc. | Methods and compositions for the introduction and regulated expression of genes in plants |
WO2011082310A2 (en) | 2009-12-30 | 2011-07-07 | Pioneer Hi-Bred International, Inc. | Methods and compositions for targeted polynucleotide modification |
WO2012129373A2 (en) | 2011-03-23 | 2012-09-27 | Pioneer Hi-Bred International, Inc. | Methods for producing a complex transgenic trait locus |
WO2012149470A1 (en) | 2011-04-27 | 2012-11-01 | Amyris, Inc. | Methods for genomic modification |
EP2568048A1 (de) | 2007-06-29 | 2013-03-13 | Pioneer Hi-Bred International, Inc. | Verfahren zur Veränderung des Genoms einer Zelle von Einkeimblättrigen |
WO2013066423A2 (en) | 2011-06-21 | 2013-05-10 | Pioneer Hi-Bred International, Inc. | Methods and compositions for producing male sterile plants |
WO2014093485A1 (en) | 2012-12-13 | 2014-06-19 | Pioneer Hi-Bred International, Inc. | Methods and compositions for producing and selecting transgenic plants |
WO2015095804A1 (en) | 2013-12-19 | 2015-06-25 | Amyris, Inc. | Methods for genomic integration |
US10612041B2 (en) | 2014-03-21 | 2020-04-07 | The Board Of Trustees Of The Leland Stanford Junior University | Genome editing without nucleases |
EP3839050A2 (de) | 2012-04-18 | 2021-06-23 | The Board of Trustees of the Leland Stanford Junior University | Disruptionsfreies gen-targeting |
EP4219731A2 (de) | 2016-05-18 | 2023-08-02 | Amyris, Inc. | Zusammensetzungen und verfahren zur genomischen integration von nukleinsäuren in exogene landepads |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4135368A1 (de) * | 1991-10-26 | 1993-07-29 | Preussag Ag | Verfahren zur aufbereitung von filterstaeuben, insbesondere aus abfallverbrennungsanlagen |
EP0635282A1 (de) * | 1993-07-23 | 1995-01-25 | Abb Research Ltd. | Verfahren zur Reststoffbehandlung in Müllverbrennungsanlagen |
WO1996003181A1 (es) * | 1994-07-22 | 1996-02-08 | Tresold Tratamiento De Residuos Solidos, S.L. | Procedimiento de tratamiento e inertizacion de cenizas procedentes de residuos solidos sometidos a procesos termicos |
FR2764531A1 (fr) * | 1997-06-11 | 1998-12-18 | B & C Services Sarl | Procede pour traiter les residus d'epuration des fumees d'incineration d'ordures menageres et/ou de dechets industriels |
FR2770159A1 (fr) * | 1997-10-24 | 1999-04-30 | Recupyl Sa | Procede de recyclage des refiom et refidi par voie hydrometallurgique |
FR2792856A1 (fr) * | 1999-04-30 | 2000-11-03 | B & C Services Sarl | Procede pour decontaminer un produit contenant des metaux |
-
2001
- 2001-07-16 AT AT0056501U patent/AT5356U1/de not_active IP Right Cessation
-
2002
- 2002-07-16 WO PCT/AT2002/000211 patent/WO2003008045A2/de not_active Application Discontinuation
- 2002-07-16 EP EP02744921A patent/EP1406702A2/de not_active Withdrawn
- 2002-07-16 AU AU2002317023A patent/AU2002317023A1/en not_active Abandoned
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4135368A1 (de) * | 1991-10-26 | 1993-07-29 | Preussag Ag | Verfahren zur aufbereitung von filterstaeuben, insbesondere aus abfallverbrennungsanlagen |
EP0635282A1 (de) * | 1993-07-23 | 1995-01-25 | Abb Research Ltd. | Verfahren zur Reststoffbehandlung in Müllverbrennungsanlagen |
WO1996003181A1 (es) * | 1994-07-22 | 1996-02-08 | Tresold Tratamiento De Residuos Solidos, S.L. | Procedimiento de tratamiento e inertizacion de cenizas procedentes de residuos solidos sometidos a procesos termicos |
FR2764531A1 (fr) * | 1997-06-11 | 1998-12-18 | B & C Services Sarl | Procede pour traiter les residus d'epuration des fumees d'incineration d'ordures menageres et/ou de dechets industriels |
FR2770159A1 (fr) * | 1997-10-24 | 1999-04-30 | Recupyl Sa | Procede de recyclage des refiom et refidi par voie hydrometallurgique |
FR2792856A1 (fr) * | 1999-04-30 | 2000-11-03 | B & C Services Sarl | Procede pour decontaminer un produit contenant des metaux |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CZ298404B6 (cs) * | 1996-12-20 | 2007-09-19 | Meadwestvaco Packaging Systems, Llc | Prepravka predmetu a její prírez |
EP2308986A1 (de) | 2006-05-17 | 2011-04-13 | Pioneer Hi-Bred International Inc. | Künstliche Pflanzenminichromosome |
EP2568048A1 (de) | 2007-06-29 | 2013-03-13 | Pioneer Hi-Bred International, Inc. | Verfahren zur Veränderung des Genoms einer Zelle von Einkeimblättrigen |
WO2011082318A2 (en) | 2009-12-30 | 2011-07-07 | Pioneer Hi-Bred International, Inc. | Methods and compositions for the introduction and regulated expression of genes in plants |
WO2011082310A2 (en) | 2009-12-30 | 2011-07-07 | Pioneer Hi-Bred International, Inc. | Methods and compositions for targeted polynucleotide modification |
EP3078748A2 (de) | 2009-12-30 | 2016-10-12 | Pioneer Hi-Bred International, Inc. | Verfahren und zusammensetzungen zur einbringung und regulierten expression von genen in pflanzen |
WO2012129373A2 (en) | 2011-03-23 | 2012-09-27 | Pioneer Hi-Bred International, Inc. | Methods for producing a complex transgenic trait locus |
US8685737B2 (en) | 2011-04-27 | 2014-04-01 | Amyris, Inc. | Methods for genomic modification |
WO2012149470A1 (en) | 2011-04-27 | 2012-11-01 | Amyris, Inc. | Methods for genomic modification |
US9701971B2 (en) | 2011-04-27 | 2017-07-11 | Amyris, Inc. | Methods for genomic modification |
WO2013066423A2 (en) | 2011-06-21 | 2013-05-10 | Pioneer Hi-Bred International, Inc. | Methods and compositions for producing male sterile plants |
EP3839050A2 (de) | 2012-04-18 | 2021-06-23 | The Board of Trustees of the Leland Stanford Junior University | Disruptionsfreies gen-targeting |
WO2014093485A1 (en) | 2012-12-13 | 2014-06-19 | Pioneer Hi-Bred International, Inc. | Methods and compositions for producing and selecting transgenic plants |
WO2014143304A1 (en) | 2012-12-13 | 2014-09-18 | Pioneer Hi-Bred International, Inc. | Methods and compositions for producing and selecting transgenic plants |
WO2015095804A1 (en) | 2013-12-19 | 2015-06-25 | Amyris, Inc. | Methods for genomic integration |
US10612041B2 (en) | 2014-03-21 | 2020-04-07 | The Board Of Trustees Of The Leland Stanford Junior University | Genome editing without nucleases |
EP4219731A2 (de) | 2016-05-18 | 2023-08-02 | Amyris, Inc. | Zusammensetzungen und verfahren zur genomischen integration von nukleinsäuren in exogene landepads |
Also Published As
Publication number | Publication date |
---|---|
AU2002317023A1 (en) | 2003-03-03 |
AT5356U1 (de) | 2002-06-25 |
EP1406702A2 (de) | 2004-04-14 |
WO2003008045A3 (de) | 2003-04-17 |
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