WO2002068540A2 - Verfahren und vorrichtung zur kontinuierlichen rodox-regelung bei azokupplungen - Google Patents
Verfahren und vorrichtung zur kontinuierlichen rodox-regelung bei azokupplungen Download PDFInfo
- Publication number
- WO2002068540A2 WO2002068540A2 PCT/EP2002/001718 EP0201718W WO02068540A2 WO 2002068540 A2 WO2002068540 A2 WO 2002068540A2 EP 0201718 W EP0201718 W EP 0201718W WO 02068540 A2 WO02068540 A2 WO 02068540A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- electrode
- measuring cell
- flow
- flow measuring
- redox
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B41/00—Special methods of performing the coupling reaction
- C09B41/006—Special methods of performing the coupling reaction characterised by process features
- C09B41/008—Special methods of performing the coupling reaction characterised by process features using mechanical or physical means, e.g. using ultra-sound, milling during coupling or microreactors
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B41/00—Special methods of performing the coupling reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/20—Measuring; Control or regulation
- B01F35/21—Measuring
- B01F35/2133—Electrical conductivity or dielectric constant of the mixture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/80—Forming a predetermined ratio of the substances to be mixed
- B01F35/82—Forming a predetermined ratio of the substances to be mixed by adding a material to be mixed to a mixture in response to a detected feature, e.g. density, radioactivity, consumed power or colour
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0086—Processes carried out with a view to control or to change the pH-value; Applications of buffer salts; Neutralisation reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/02—Feed or outlet devices; Feed or outlet control devices for feeding measured, i.e. prescribed quantities of reagents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B41/00—Special methods of performing the coupling reaction
- C09B41/006—Special methods of performing the coupling reaction characterised by process features
- C09B41/007—Special methods of performing the coupling reaction characterised by process features including condition or time responsive control, e.g. automatically controlled processes; Stepwise coupling
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0025—Crystal modifications; Special X-ray patterns
- C09B67/0027—Crystal modifications; Special X-ray patterns of quinacridones
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/416—Systems
- G01N27/4166—Systems measuring a particular property of an electrolyte
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00851—Additional features
- B01J2219/00853—Employing electrode arrangements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00889—Mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00891—Feeding or evacuation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/0095—Control aspects
- B01J2219/00952—Sensing operations
- B01J2219/00954—Measured properties
- B01J2219/00966—Measured properties pH
Definitions
- azo dyes 4- [5-hydroxy-3-methyl-pyrazol-1-yl] -benzenesulfonic acid, 2-amino-naphthalene-1,5-disulfonic acid, 5-methoxy-2-methyl-4 [3-oxo-butyrylamino] benzenesulfonic acid, 2-methoxy-5-methyl-4- [3-oxo-butyr lamino] benzenesulfonic acid, 4-acetylamino-2-amino-benzenesulfonic acid, 4- [4-chloro-6- (3-sulfo-phenylamino) - [1,3,5] -triazin-2-yI-amino] -5-hydroxy-naphthalene-2,7-disulfonic acid, 4-acetylamino-5-hydroxy-naphthalene-2,7 -disulfonic acid, 4-amino-5-hydroxy-naphthalen
- buffer solutions can be added to the educt streams, preferably of organic acids and their salts, e.g.
- Azo pigments can be monoazo or disazo pigments. It can too
- Mixtures of azo pigments can be produced.
- dispersion- and also water-soluble anionic and cationic dyes come into consideration.
- they are mono-, dis- or polyazo dyes and formazan or anthraquinone dyes.
- the water-soluble dyes are in particular the alkali metal salts or ammonium salts of the reactive dyes and the acidic wool dyes or nouns cotton dyes of the azo series.
- the azo dyes are preferably metal-free and metallizable monoazo, disazo and trisazo dyes which have one or more sulfonic acid or carboxylic acid groups contain, heavy metal-containing, in particular copper, chromium or cobalt-containing monoazo, disazo and trisazo.
- the preparation of the precursors for the metal-containing dyes can be carried out by conventional methods in a conventional batch process.
- Cl. Come as reactive azo dyes.
- Cl. Acid Yellow 17, 23; Direct Yellow 17, 86, 98, 132, 157; and Direct Black 62, 168 and 171 can be produced using this method.
- a flow measuring cell (Fig. 1a, 1b, 1c) has proven itself for carrying out the method, which is arranged by a rotating redox electrode (1) which is arranged approximately in the middle of the flow tube (2) of the flow measuring cell transversely to the flow direction of the reaction mixture and in a sliding contact (3) for
- Signal acquisition is rotatably mounted; a rod-shaped body (4) touching the rotating redox electrode with a cleaning effect; a reference electrode (5); and a pH electrode (6) is marked.
- the rotating redox electrode (1) consists of a conductive material, preferably of W, Au, Pt, Ag, Sb, Mo, Cr or an alloy thereof, graphite or at least 80% of one of the materials mentioned. Redox electrodes made of tungsten are particularly preferred.
- the redox electrode is rotatably mounted, for example in a Cu socket, and is set in rotation about its longitudinal axis by an external drive device, for example by an electric motor. The signal is picked up via a sliding contact in the bearing.
- the reference electrode (5) which is preferably a commercially available Ag / AgCl electrode, calomel electrode or Pt / H 2 normal hydrogen electrode, serves as the counter electrode.
- the redox electrode (1) is touched during its rotation by a rod-shaped body (4) consisting of or coated with an inert material, for example polyvinylidene difluoride (PVDF), polytetrafluoroethylene (PTFE), particularly preferably consisting of or coated with an abrasive material, such as eg Corundum, Arkana stone or silicon carbide, so that the electrode surface is continuously mechanically cleaned.
- PVDF polyvinylidene difluoride
- PTFE polytetrafluoroethylene
- abrasive material such as eg Corundum, Arkana stone or silicon carbide
- the body (4) is expediently pressed onto the rotating redox electrode by a tracking device (7), in particular a spiral spring or a weight.
- the point of contact between the body (4) and the redox electrode is preferably in the middle of the flow tube (2) and reduces the flow cross-section at this point (measuring point). This keeps the dead volume low.
- the measuring cell also contains a pH electrode (6), e.g. a commercially available glass electrode.
- the measuring cell is expediently constructed in such a way that the pH electrode (6), the reference electrode (5) and the rod-shaped body (4) including the tracking device are parallel to one another and are each offset by 90 ° to the rotating redox electrode and vertically to the direction of flow.
- the housing (8) of the measuring cell is expediently made of an inert material, such as e.g. PVDF, PTFE or polypropylene.
- the invention also relates to a device (FIG. 2) for carrying out a continuous online controlled azo coupling reaction, characterized by a flow measuring cell (M) connected to a continuously operated reactor (R) and storage vessels (A, B and optionally C), as described above ,
- the redox electrode (1) and reference electrode (5) are connected to the storage vessels A (coupling component) and B (diazo component), the pH electrode to the storage vessel C (buffer, lye, acid).
- the volume flows A, B, C are controlled via conventional controllable conveying devices, such as Pumps or valves.
- a sample is taken after leaving the reactor.
- An analytical method such as DC or HPLC is used to check for a possible excess of a component and / or a spot test with H acid solution (CAS No. 90-20-0) to detect excess diazonium salt or with real blue salt solution (CAS No. .20282-70-6) Excess coupling material carried out.
- the educt streams diazonium salt solution and / or naphthol solution are corrected.
- the redox potential is determined at a constant pH, for example 187 mV when using a tungsten electrode against Ag / AgCI.
- any deviation from this defined redox potential is corrected by a corresponding change in the educt streams A and / or B.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02722096A EP1363975B1 (de) | 2001-02-23 | 2002-02-19 | Verfahren und vorrichtung zur kontinuierlichen rodox-regelung bei azokupplungen |
US10/468,472 US20040131507A1 (en) | 2001-02-23 | 2002-02-19 | Method and device for continous redox adjustment in azoic couplings |
KR10-2003-7011023A KR20030090646A (ko) | 2001-02-23 | 2002-02-19 | 아조 커플링에서 연속 산화환원의 조절 방법 및 장치 |
JP2002568643A JP4060713B2 (ja) | 2001-02-23 | 2002-02-19 | アゾカップリングにおける連続的な酸化還元調整のための方法および装置 |
DE50202624T DE50202624D1 (de) | 2001-02-23 | 2002-02-19 | Verfahren und vorrichtung zur kontinuierlichen rodox-regelung bei azokupplungen |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10108716A DE10108716A1 (de) | 2001-02-23 | 2001-02-23 | Verfahren und Vorrichtung zur kontinuierlichen Redox-Regelung bei Azokupplungen |
DE10108716.0 | 2001-02-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2002068540A2 true WO2002068540A2 (de) | 2002-09-06 |
WO2002068540A3 WO2002068540A3 (de) | 2002-12-05 |
Family
ID=7675223
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2002/001718 WO2002068540A2 (de) | 2001-02-23 | 2002-02-19 | Verfahren und vorrichtung zur kontinuierlichen rodox-regelung bei azokupplungen |
Country Status (9)
Country | Link |
---|---|
US (1) | US20040131507A1 (de) |
EP (1) | EP1363975B1 (de) |
JP (1) | JP4060713B2 (de) |
KR (1) | KR20030090646A (de) |
CN (1) | CN1210350C (de) |
CZ (1) | CZ20032272A3 (de) |
DE (2) | DE10108716A1 (de) |
ES (1) | ES2240730T3 (de) |
WO (1) | WO2002068540A2 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2228410A1 (de) * | 2009-03-11 | 2010-09-15 | Clariant International Ltd. | C.I. Pigment Red 112 mit verbesserter Dispergierbarkeit |
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DE10143189A1 (de) * | 2001-09-04 | 2003-03-20 | Clariant Gmbh | Verfahren und Vorrichtung zur prozeßbegleitenden Reinigung von Mikro-und Minireaktoren |
US6969505B2 (en) | 2002-08-15 | 2005-11-29 | Velocys, Inc. | Process for conducting an equilibrium limited chemical reaction in a single stage process channel |
US6622519B1 (en) | 2002-08-15 | 2003-09-23 | Velocys, Inc. | Process for cooling a product in a heat exchanger employing microchannels for the flow of refrigerant and product |
US7014835B2 (en) * | 2002-08-15 | 2006-03-21 | Velocys, Inc. | Multi-stream microchannel device |
US7294734B2 (en) * | 2003-05-02 | 2007-11-13 | Velocys, Inc. | Process for converting a hydrocarbon to an oxygenate or a nitrile |
WO2004103539A2 (en) * | 2003-05-16 | 2004-12-02 | Velocys Inc. | Process for forming an emulsion using microchannel process technology |
US7485671B2 (en) * | 2003-05-16 | 2009-02-03 | Velocys, Inc. | Process for forming an emulsion using microchannel process technology |
US7220390B2 (en) * | 2003-05-16 | 2007-05-22 | Velocys, Inc. | Microchannel with internal fin support for catalyst or sorption medium |
US8580211B2 (en) * | 2003-05-16 | 2013-11-12 | Velocys, Inc. | Microchannel with internal fin support for catalyst or sorption medium |
WO2005032693A2 (en) * | 2003-08-29 | 2005-04-14 | Velocys Inc. | Process for separating nitrogen from methane using microchannel process technology |
US7029647B2 (en) * | 2004-01-27 | 2006-04-18 | Velocys, Inc. | Process for producing hydrogen peroxide using microchannel technology |
US7084180B2 (en) * | 2004-01-28 | 2006-08-01 | Velocys, Inc. | Fischer-tropsch synthesis using microchannel technology and novel catalyst and microchannel reactor |
US9023900B2 (en) | 2004-01-28 | 2015-05-05 | Velocys, Inc. | Fischer-Tropsch synthesis using microchannel technology and novel catalyst and microchannel reactor |
US8747805B2 (en) | 2004-02-11 | 2014-06-10 | Velocys, Inc. | Process for conducting an equilibrium limited chemical reaction using microchannel technology |
US7305850B2 (en) * | 2004-07-23 | 2007-12-11 | Velocys, Inc. | Distillation process using microchannel technology |
EP1781389A2 (de) * | 2004-07-23 | 2007-05-09 | Velocys, Inc. | Destillationsverfahren mit hilfe von mikrokanal-technologie |
JP2010210118A (ja) * | 2009-03-09 | 2010-09-24 | Jamco Corp | 漏水防止用安全弁を備えた旅客機搭載用スチームオーブン |
CN102618063B (zh) * | 2012-03-09 | 2013-11-20 | 大连理工大学 | 水溶性偶氮染料的螺旋管混沌混合的连续化制备方法 |
GB201214122D0 (en) | 2012-08-07 | 2012-09-19 | Oxford Catalysts Ltd | Treating of catalyst support |
CN103130679B (zh) * | 2013-03-12 | 2014-03-26 | 浙江迪邦化工有限公司 | 重氮化合物的自动控制连续生产方法及装置 |
WO2016201218A2 (en) | 2015-06-12 | 2016-12-15 | Velocys, Inc. | Synthesis gas conversion process |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1085278B (de) * | 1958-03-08 | 1960-07-14 | Hoechst Ag | Verfahren zur kontinuierlichen Herstellung von Azopigmenten |
DE2352735A1 (de) * | 1973-10-20 | 1975-10-23 | Hoechst Ag | Verfahren und vorrichtung zum regeln der zugabe einer komponente bei der diskontinuierlichen azofarbstoffherstellung |
WO2001059013A1 (de) * | 2000-02-09 | 2001-08-16 | Clariant International Ltd | Verfahren zur herstellung von azofarbmitteln in mikroreaktoren |
Family Cites Families (5)
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US3826741A (en) * | 1972-11-03 | 1974-07-30 | Nihon Filter Co Ltd | Method of treating waste solution containing chromate ion or cyanide ion |
US4479852A (en) * | 1983-01-21 | 1984-10-30 | International Business Machines Corporation | Method for determination of concentration of organic additive in plating bath |
US4725339A (en) * | 1984-02-13 | 1988-02-16 | International Business Machines Corporation | Method for monitoring metal ion concentrations in plating baths |
US5106478A (en) * | 1990-12-06 | 1992-04-21 | Wolf Musow | Electrode wiper cleaning system |
DE10049200A1 (de) * | 2000-10-05 | 2002-04-11 | Clariant Gmbh | Verfahren zur Herstellung von Azofarbmitteln |
-
2001
- 2001-02-23 DE DE10108716A patent/DE10108716A1/de not_active Withdrawn
-
2002
- 2002-02-19 CN CNB028053702A patent/CN1210350C/zh not_active Expired - Fee Related
- 2002-02-19 CZ CZ20032272A patent/CZ20032272A3/cs unknown
- 2002-02-19 ES ES02722096T patent/ES2240730T3/es not_active Expired - Lifetime
- 2002-02-19 JP JP2002568643A patent/JP4060713B2/ja not_active Expired - Fee Related
- 2002-02-19 EP EP02722096A patent/EP1363975B1/de not_active Expired - Lifetime
- 2002-02-19 KR KR10-2003-7011023A patent/KR20030090646A/ko active IP Right Grant
- 2002-02-19 WO PCT/EP2002/001718 patent/WO2002068540A2/de active IP Right Grant
- 2002-02-19 US US10/468,472 patent/US20040131507A1/en not_active Abandoned
- 2002-02-19 DE DE50202624T patent/DE50202624D1/de not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1085278B (de) * | 1958-03-08 | 1960-07-14 | Hoechst Ag | Verfahren zur kontinuierlichen Herstellung von Azopigmenten |
DE2352735A1 (de) * | 1973-10-20 | 1975-10-23 | Hoechst Ag | Verfahren und vorrichtung zum regeln der zugabe einer komponente bei der diskontinuierlichen azofarbstoffherstellung |
WO2001059013A1 (de) * | 2000-02-09 | 2001-08-16 | Clariant International Ltd | Verfahren zur herstellung von azofarbmitteln in mikroreaktoren |
Non-Patent Citations (1)
Title |
---|
CHEMICAL ABSTRACTS, vol. 100, no. 22, 1984 Columbus, Ohio, US; abstract no. 176459d, VANA, JAROSLAV ET AL: "Amperometrictracing of coupling during production of azo dyes" Seite 84; XP002208437 & CS 208 965 A 1. Februar 1984 (1984-02-01) * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2228410A1 (de) * | 2009-03-11 | 2010-09-15 | Clariant International Ltd. | C.I. Pigment Red 112 mit verbesserter Dispergierbarkeit |
US8062416B2 (en) | 2009-03-11 | 2011-11-22 | Clariant Finance (Bvi) Limited | Pigment red 112 with enhanced dispersibility |
Also Published As
Publication number | Publication date |
---|---|
JP4060713B2 (ja) | 2008-03-12 |
EP1363975A2 (de) | 2003-11-26 |
ES2240730T3 (es) | 2005-10-16 |
CN1492910A (zh) | 2004-04-28 |
CN1210350C (zh) | 2005-07-13 |
CZ20032272A3 (cs) | 2003-11-12 |
EP1363975B1 (de) | 2005-03-30 |
DE50202624D1 (de) | 2005-05-04 |
KR20030090646A (ko) | 2003-11-28 |
US20040131507A1 (en) | 2004-07-08 |
JP2004532293A (ja) | 2004-10-21 |
DE10108716A1 (de) | 2002-09-19 |
WO2002068540A3 (de) | 2002-12-05 |
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