WO2002050232A2 - Procede pour l'elimination de surfaces plastiques de residus adherant electrostatiquement - Google Patents
Procede pour l'elimination de surfaces plastiques de residus adherant electrostatiquement Download PDFInfo
- Publication number
- WO2002050232A2 WO2002050232A2 PCT/EP2001/014558 EP0114558W WO0250232A2 WO 2002050232 A2 WO2002050232 A2 WO 2002050232A2 EP 0114558 W EP0114558 W EP 0114558W WO 0250232 A2 WO0250232 A2 WO 0250232A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- plastic
- component
- plastic surfaces
- weight
- water
- Prior art date
Links
- 239000004033 plastic Substances 0.000 title claims abstract description 42
- 229920003023 plastic Polymers 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 34
- 238000004140 cleaning Methods 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 9
- 239000012141 concentrate Substances 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 10
- 239000003599 detergent Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 239000012188 paraffin wax Substances 0.000 claims description 6
- 150000003335 secondary amines Chemical class 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 150000003141 primary amines Chemical class 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- -1 fatty acid salt Chemical class 0.000 claims description 3
- 150000003505 terpenes Chemical class 0.000 claims description 3
- 235000007586 terpenes Nutrition 0.000 claims description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- 239000008139 complexing agent Substances 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 239000002216 antistatic agent Substances 0.000 description 19
- 239000000243 solution Substances 0.000 description 19
- 239000012459 cleaning agent Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 235000013405 beer Nutrition 0.000 description 7
- 238000012360 testing method Methods 0.000 description 5
- 239000000428 dust Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005187 foaming Methods 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical class NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 235000013361 beverage Nutrition 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical class [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 238000007600 charging Methods 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000007786 electrostatic charging Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 235000013618 yogurt Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/42—Amino alcohols or amino ethers
- C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
Definitions
- the removal of electrostatically bound residues from plastic surfaces is particularly important in the industrial sector, for example when cleaning secondary food packaging such as yoghurt trays, beverage crates or transport boxes for bread, meat, etc., from painted surfaces such as from motor vehicles and generally when cleaning plastic surfaces such as window frames , Linings of ventilation shafts or wall cladding as well as foils, textiles etc. are associated with difficulties, since the respective objects with plastic surfaces attract the dirt shortly after manufacture or cleaning due to their charging.
- the inorganic constituents of the dust (soot, carbonates, silicates), which make up more than 60% by weight of the dust weight, adhere firmly to the surfaces and cannot be completely removed with conventional cleaners even after intensive treatment.
- External antistatic agents for the surface treatment of statically chargeable objects are also described comprehensively in the prior art and have a number of advantages over “internal antistatic agents”: they are inexpensive to manufacture, are used in highly dilute solutions and, owing to the periodically repeated use, do not have to be extremely expensive have great long-term stability and can also be used on almost all statically chargeable surfaces. "External antistatic agents” increase the surface conductivity and thus enable an improved flow of charges. Outer antistatic agents are generally substances with at least one hydrophilic part of the molecule and give a more or less hygroscopic film on the surfaces.
- surface-active antistatic agents can be broken down into nitrogen-containing (amines , A ide, quaternary ammonium compounds), phosphorus-containing (phosphoric acid esters) and sulfur-containing (alkylsulfonates, alkylsulfates) antistatic substances, and non-surface-active compounds can also be used as antistatic agents - the best known is the use of carbon black, silicon dioxide, aluminosilicates and metal oxides both as internal and also as an external antistatic.
- External antistatic agents are usually applied to the surfaces to be treated using solutions in water, alcohols, petrol, chlorinated hydrocarbons, etc. by brushing, dipping or spraying. Economic, ecological, occupational health and occupational safety considerations play a role in the selection of solvents and antistatic agents.
- Common external antistatic agents which are used for surface treatment often have the disadvantage of forming precipitates with anionic cleaning agents on account of their content of cationic compounds, so that they have to be used in a subsequent step. For use in dishwashers and spraying machines, these agents must be low-foaming, wet the surfaces well and dry quickly.
- Common external antistatic agents have only minor effects with regard to polarizability and electrical conductivity of the treated surfaces. In addition, the long-term effects of commercially available antistatic agents are usually poor.
- statically chargeable surface refers to horizontal and non-horizontal surfaces which, owing to insulating Material properties tend to charge.
- this includes plastics, in particular thermoplastics and thermosets, in which this problem is particularly pronounced.
- DE 197 07 650 recommends antistatic cleaning agent concentrates which, when added to water, provide an antistatic cleaning solution, characterized in that they contain: a) 1 to 12% by weight of one or more alkoxylated primary or secondary amines, b) 1 up to 10% by weight of a fatty acid salt, c) 2 to 12% by weight of one or more low-foaming nonionic surfactants and the remainder water or an aqueous solution of further auxiliaries and active ingredients.
- DE 197 07 650 recommends a method for cleaning statically chargeable surfaces, in which an antistatic aqueous cleaning agent is applied to the statically chargeable surfaces to be cleaned and is then allowed to run off.
- the antistatic aqueous cleaning agent to be used in this process is obtained by diluting an antistatic cleaning agent concentrate with water.
- DE 197 07 650 acts as an antistatic, alkoxylated primary or secondary amines. These are distinguished by their usability both as internal antistatic agents and as external antistatic agents in cleaning agents of the present invention.
- DE 197 07 650 With the cleaning agents described in DE 197 07 650, common contaminants can be removed. However, if there are impurities that adhere to it due to interactions with the electrostatically charged surface, then the cleaning effect of the agents described in DE 197 07 650 is not sufficient. Accordingly, the disadvantage of DE 197 07 650 is that the method mentioned is not aimed at the removal of electrostatically adhering residues. On the other hand, it is disadvantageous that special, again antistatic components have to be used to implement DE 197 07 650.
- the process should be designed so that the use of antistatic components should not be essential for the success of the process.
- the present invention relates to a method for cleaning plastic surfaces contaminated with electrostatically bound residues by treatment with water and / or aqueous cleaning solutions, in which, prior to the treatment mentioned, the plastic surfaces of the plastic containers with a liquid agent containing at least one non-polar component with paraffinic properties , are pretreated.
- the apolar component mentioned with paraffinic properties is selected from compounds which have a dielectric constant between 1 and 10, preferably between 1 and 6.
- the dielectric constant mentioned can be determined by customary measurement methods, in particular by measurement with a decameter under the conditions 50 Hz and 20 ° C. according to DIN 53483.
- the plastic surfaces come from plastic containers, the pretreatment mentioned being carried out as soon as possible, preferably immediately after the production or printing of the plastic containers, which is to be understood as a point in time at which there is still no visible contamination.
- the pretreatment preferably takes place within 24 hours after production or printing. Since beverage crates are usually printed, a preferred interval for the pretreatment in this case would be the period within 24 hours after the printing ink has dried
- the method according to the invention can also be preferred in the method according to the invention to carry out the aforementioned pretreatment shortly before the treatment of the plastic surfaces, in particular to carry out plastic containers with water and / or aqueous cleaning solutions, with “shortly before” preferably being a time interval of a few seconds up to a time interval sufficiently short before the treatment of the plastic surfaces with water and / or cleaning solutions, so that a non-drip even film is spread on the surface.
- the pretreatment mentioned can of course also take place at any time between the production or printing and the treatment of the plastic containers mentioned with water and / or aqueous cleaning solution.
- apolar component with paraffinic properties is selected from paraffin, terpene, oil or oil-like compounds and polymers or mixtures of these components, compounds such as orange terpenes or pure paraffin being particularly suitable.
- the apolar component mentioned preferably makes up a proportion of 1 to 100% by weight, particularly preferably 50 to 100% by weight, based on the total liquid agent to be used for the pretreatments, additional components preferably being selected from fatty alcohols and their derivatives, fatty acids and their derivatives are contained.
- liquid pretreatment agent mentioned is sprayed onto the plastic surfaces, preferably in undiluted form.
- a further preferred embodiment of the method according to the invention includes that the treatment of the pretreated plastic surfaces to be carried out according to the invention with water and / or aqueous cleaning solutions takes place at a temperature of 35 to 90 ° C.
- this aqueous treatment step the residues, including the apolar components, are preferably detached from the plastic surface.
- This treatment step is preferably carried out in a conventional crate washer or corresponding continuous cleaning machines carried out.
- the duration of the treatment step is preferably between 30 seconds and 15 minutes.
- a cleaning agent concentrate is dissolved in water in a weight ratio of 1: 1000 to 1:50, preferably in a weight ratio of 1: 200 to 1: 100, to produce the same. Then this solution is preferably applied to the surfaces to be cleaned or the objects to be cleaned are immersed in this solution, the solution then being allowed to run off.
- the detergent concentrate to be diluted a) 1 to 12% by weight of one or more alkoxylated primary or secondary amines, particularly preferably ethoxylated secondary amines, b) 1 to 10% by weight of a fatty acid salt, particularly preferably one Triethanolamine salt of a C 8 -0 0 fatty acid, which was very particularly preferably synthesized before or during the manufacture of the detergent concentrate from triethanolamine and the fatty acid, and c) contains 2 to 12% by weight of one or more nonionic surfactants.
- the cleaning agent concentrate to be diluted contains, as additional components, complexing agents, preferably EDTA or NTA, and also further auxiliary or active substances, further alkalis, builder substances, further anionic and nonionic surfactants, enzymes, preservatives, oxidizing agents, Dyes and / or perfumes are present.
- complexing agents preferably EDTA or NTA
- auxiliary or active substances further alkalis, builder substances, further anionic and nonionic surfactants, enzymes, preservatives, oxidizing agents, Dyes and / or perfumes are present.
- Another object of the present invention is a method for treating plastic surfaces, in particular plastic containers for the subsequent improved removal of electrostatically bound contaminants, in which the surfaces of the plastic containers are pretreated with a liquid agent containing at least one non-polar component with paraffinic properties.
- a liquid agent containing at least one non-polar component with paraffinic properties containing at least one non-polar component with paraffinic properties.
- the sample tests were carried out on beer crates, which were produced in-house by a large German brewery and made available for the tests.
- the beer crates were yellow crates with a capacity of eleven 0.5 L beer bottles each.
- the cleaning solutions used for the aqueous alkaline cleaning are contained in Table 1. To check the cleaning effect, these solutions were prepared in the laboratory and pumped around with a pump. The temperature of the solutions was around 50 ° C. during the test. In the tests, the solutions to be examined were rinsed through a hose from a distance of about 0.2 m over a period of about 3 minutes to a visibly heavily soiled area of the beer crates contaminated with electrostatically bound residues. In the tests, the mechanical action corresponded approximately to the mechanical action which would normally be present when the corresponding surface was rinsed off with tap water.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Abstract
L'invention concerne un procédé pour le nettoyage de surfaces plastiques salies par des résidus adhérant électrostatiquement par traitement avec de l'eau ou avec des solutions nettoyantes aqueuses. Le procédé selon l'invention est caractérisé en ce qu'on traite préalablement les surfaces plastiques avec un agent liquide contenant au moins un constituant apolaire ayant des propriétés paraffiniques.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10065933.0 | 2000-12-21 | ||
| DE10065933A DE10065933C1 (de) | 2000-12-21 | 2000-12-21 | Verfahren zur Entfernung elektrostatisch gebundener Rückstände von Kunststoffoberflächen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2002050232A2 true WO2002050232A2 (fr) | 2002-06-27 |
| WO2002050232A3 WO2002050232A3 (fr) | 2002-09-26 |
Family
ID=7669549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2001/014558 WO2002050232A2 (fr) | 2000-12-21 | 2001-12-12 | Procede pour l'elimination de surfaces plastiques de residus adherant electrostatiquement |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE10065933C1 (fr) |
| WO (1) | WO2002050232A2 (fr) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2125076A (en) * | 1982-07-22 | 1984-02-29 | Rheem Australia Pty Ltd | Fire-retardant, anti-static compositions |
| US5174316A (en) * | 1991-03-06 | 1992-12-29 | Food Technology International Inc. | Method and apparatus for cleaning material recovered from soiled plastic containers, packaging and the like |
| DE4209042C1 (en) * | 1992-03-20 | 1993-09-16 | Chemische Werke Kluthe Gmbh & Co, 6900 Heidelberg, De | Reusable coated plastic container for protection against abrasion and soiling - has easily stripped coating prepd. from dispersion of aq. polyvinyl acetate, emulsifier, stabiliser, plasticiser, release agent, wetting agent and water or aq. alcohol |
| DE19707650A1 (de) * | 1997-02-26 | 1998-08-27 | Henkel Ecolab Gmbh & Co Ohg | Reinigung statisch aufladbarer Oberflächen mit antistatischen wäßrigen Reinigungsmitteln |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1019991B (de) * | 1955-03-31 | 1957-11-28 | Boehme Fettchemie Gmbh | Avivier- und Praepariermittel fuer Textilmaterialien |
| FR1156513A (fr) * | 1956-07-24 | 1958-05-19 | Préparation permettant d'éliminer l'électricité statique des fibres textiles de synthèse | |
| US2972536A (en) * | 1957-09-03 | 1961-02-21 | Eastman Kodak Co | Anti-static quaternary salts of c-vinylpyridine polymers with haloacetone cyanohydrins |
| BE572404A (fr) * | 1957-10-31 | |||
| GB873214A (en) * | 1958-08-20 | 1961-07-19 | British Nylon Spinners Ltd | Non-ionic detergent compositions |
-
2000
- 2000-12-21 DE DE10065933A patent/DE10065933C1/de not_active Expired - Fee Related
-
2001
- 2001-12-12 WO PCT/EP2001/014558 patent/WO2002050232A2/fr active Application Filing
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2125076A (en) * | 1982-07-22 | 1984-02-29 | Rheem Australia Pty Ltd | Fire-retardant, anti-static compositions |
| US5174316A (en) * | 1991-03-06 | 1992-12-29 | Food Technology International Inc. | Method and apparatus for cleaning material recovered from soiled plastic containers, packaging and the like |
| DE4209042C1 (en) * | 1992-03-20 | 1993-09-16 | Chemische Werke Kluthe Gmbh & Co, 6900 Heidelberg, De | Reusable coated plastic container for protection against abrasion and soiling - has easily stripped coating prepd. from dispersion of aq. polyvinyl acetate, emulsifier, stabiliser, plasticiser, release agent, wetting agent and water or aq. alcohol |
| DE19707650A1 (de) * | 1997-02-26 | 1998-08-27 | Henkel Ecolab Gmbh & Co Ohg | Reinigung statisch aufladbarer Oberflächen mit antistatischen wäßrigen Reinigungsmitteln |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2002050232A3 (fr) | 2002-09-26 |
| DE10065933C1 (de) | 2002-07-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE19807195B4 (de) | Zusammensetzung und Verfahren zum Reinigen und zum Trocknen von Fahrzeugen | |
| EP0876460B1 (fr) | Agent de nettoyage pour surfaces dures | |
| DE69530692T2 (de) | Teppichreinigung- und- regeneriermittel | |
| EP0213554B1 (fr) | Produit de nettoyage désémulsifiant à effet de rétention d'humidité superficielle | |
| EP0986631B1 (fr) | Detergent faiblement moussant | |
| DE69907421T2 (de) | Mittel für die reinigung harter oberflächen | |
| EP0231886B1 (fr) | Utilisation d'amines grasses éthoxylées comme solubiliseurs | |
| DE3144457A1 (de) | Verfahren zur beschichtung von glaswaren, beschichtungsmittel dafuer und damit beschichtete glaswaren | |
| EP0511253B1 (fr) | Produits de nettoyage desemulsifiants et application | |
| DE2840464B2 (de) | Reinigungsmittel für Fenster, Spiegel und reflektierende Oberflächen | |
| DE2448755A1 (de) | Waessriges spuel- und ueberzugsmittel fuer harte oberflaechen | |
| WO2001021752A1 (fr) | Produit nettoyant aqueux a plusieurs phases | |
| DE2856143A1 (de) | Scheibenreinigungsmittel | |
| WO1992020835A1 (fr) | Utilisation de 2-ethylhexylesters d'acides gras comme agents de nettoyage a froid | |
| DE2758629C3 (de) | Verfahren zum Reinigen der verzinnten Oberfläche eines eisenhaltigen Metalls | |
| WO2000039270A1 (fr) | Produit de nettoyage aqueux multiphase | |
| DE10065933C1 (de) | Verfahren zur Entfernung elektrostatisch gebundener Rückstände von Kunststoffoberflächen | |
| WO2000031218A1 (fr) | Procede d'usinage et de nettoyage de metal | |
| DE4215689A1 (de) | Stickstofffreie Wirkstoffkomponente in Wäscheweichspülerformulierungen | |
| DE3218054C2 (fr) | ||
| EP0264634B1 (fr) | Agent brillant séchant pour la voiture | |
| EP0944702B1 (fr) | Produits de nettoyage du verre | |
| WO1994014945A1 (fr) | Nettoyant liquide neutre (i) | |
| DE19707650A1 (de) | Reinigung statisch aufladbarer Oberflächen mit antistatischen wäßrigen Reinigungsmitteln | |
| DE3147111A1 (de) | Verfahren zum reinigen von druckwalzen und hierzu geeigneter reiniger |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AK | Designated states |
Kind code of ref document: A2 Designated state(s): PL US |
|
| AL | Designated countries for regional patents |
Kind code of ref document: A2 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR |
|
| AK | Designated states |
Kind code of ref document: A3 Designated state(s): PL US |
|
| AL | Designated countries for regional patents |
Kind code of ref document: A3 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR |
|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
| DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
| 122 | Ep: pct application non-entry in european phase |