WO2002035621A1 - Catalyseur d"oxydation de composé gazeux - Google Patents
Catalyseur d"oxydation de composé gazeux Download PDFInfo
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- WO2002035621A1 WO2002035621A1 PCT/JP2001/009454 JP0109454W WO0235621A1 WO 2002035621 A1 WO2002035621 A1 WO 2002035621A1 JP 0109454 W JP0109454 W JP 0109454W WO 0235621 A1 WO0235621 A1 WO 0235621A1
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- metal oxide
- oxide particles
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- oxidation
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- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
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- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
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- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
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- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
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- C01B2203/10—Catalysts for performing the hydrogen forming reactions
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- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
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- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
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- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
- H01M2004/8684—Negative electrodes
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- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
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- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
- H01M8/1226—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material characterised by the supporting layer
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- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Definitions
- the present invention relates to a gaseous compound oxidation catalyst, and more particularly, to a catalyst for promoting a gaseous compound oxidation reaction by oxygen ions supplied via a solid electrolyte in an environment free of oxygen molecules. More specifically, the present invention relates to a gaseous compound oxidation catalyst that can be suitably used for a solid oxide fuel cell.
- the present applicant has proposed a solid electrolyte fuel cell shown in FIG. 1 in Japanese Patent Application Laid-Open No. 2000-348736.
- a solid electrolyte element 16 A is composed of an oxygen ion conduction type solid electrolyte substrate 10, and electrodes 12, 14 a formed on both sides of the solid electrolyte substrate 10. Consists of
- Solid electrolyte substrate 1 0, Jirukonia stabilized with 8 mol% of I Tsu Application Benefits ⁇ (Y 2 0 3) (YS ⁇ ) consists fired body.
- the other electrode 14a is substantially composed of a porous platinum layer, and is supplied with methane gas as fuel and acts as an anode.
- Oxygen (O 2 ) supplied to force sword 12 is It is ionized at the boundary with the degraded substrate 10 to become oxygen ions (o 2 ⁇ ), and is conducted to the anode 14 a via the solid electrolyte substrate 10.
- the oxygen ions (O 2- ) react with the methane (CH 4 ) gas supplied to the anode 14a to produce water (H 2 O), carbon dioxide (CO 2 ), hydrogen (H 2 ) Generates carbon monoxide (CO).
- CH 4 methane
- CO 2 hydrogen
- electrons are emitted from the oxygen ions at the anode 14a, so that a potential difference is generated between the force source 12 and the anode 14a.
- Anodic 1 4 a is an oxidation catalyst formed by supporting a multi-porous platinum layer 2 2 a formed on one surface of the solid electrolyte substrate 1 0, the metal oxide particles child consisting PdCo0 2 on its outer surface Layer 2 2b.
- the oxidation catalyst layer 22b promotes the oxidation reaction between oxygen (O 2- ) and methane in the anode 14a.
- the solid oxide fuel cell shown in Fig. 1 uses cermet particles composed of nickel (Ni) and nickel oxide (NiO) as the oxidation catalyst by using the above oxidation catalyst. Power generation characteristics can be improved as compared with a conventional solid electrolyte fuel cell.
- PdCo0 2 metal oxide particles with an oxidation catalyst was used as obtained cowpea the double decomposition method or a hot press pressure synthesis method.
- PdCoO 2 PdCl 2 and CoO undergo a metathesis reaction under high temperature and high pressure in the metathesis method, and PdO and CoO are sealed in a platinum tube and heated in the high temperature and pressure synthesis method.
- the obtained metal oxide particles had a large particle size and varied, so that the particles were made finer by pulverization and then uniformized by classification. This is because the oxidation catalyst This is because the higher the oxidizing ability is obtained, the finer the constituent metal oxide particles are.
- An object of the present invention is to provide an oxidation catalyst for gaseous compounds having excellent oxidizing ability and comprising fine metal oxide particles without requiring a pulverizing step.
- the oxidation catalyst for a gaseous compound of the present invention promotes an oxidation reaction of a gaseous compound by oxygen ions supplied via a solid electrolyte in an environment free of oxygen molecules.
- the composition of the metal oxide particles is represented by the following formula:
- A is a member selected from the group consisting of Pd, Pt, Cu and Ag;
- B is a member selected from the group consisting of Co, Cr, Rh, Al, Ga, Fe, In, Sc and Tl;
- the particle size of the finally obtained metal oxide particles is affected by the mixing state and particle size of the starting materials, and as a result, the catalytic ability of the oxidation catalyst is also affected You.
- the oxidation catalyst of the present invention is a metal oxide obtained by calcining a precipitate obtained by mixing two metal hydrates obtained by a coprecipitation method from a mixed solution in which two metal salts having different metal ions are dissolved. Object particles.
- the precipitate formed by mixing two types of metal hydrates obtained by the coprecipitation method has fine particles and uniform particle size. Therefore, the metal oxide obtained by calcining this precipitate The particles are fine and uniform in particle size. By using the metal oxide particles as an oxidation catalyst, high oxidizing ability can be obtained.
- FIG. 1 is a cross-sectional view showing one embodiment of a solid oxide fuel cell suitable for applying the oxidation catalyst of the present invention.
- FIG. 2 is a cross-sectional view showing another embodiment of a solid oxide fuel cell suitable for applying the oxidation catalyst of the present invention.
- FIG. 3 is a chart showing an X-ray diffraction pattern of metal oxide particles (PdCoO 2) obtained by using the coprecipitation method according to the present invention.
- FIG. 4 is a cross-sectional view showing a measuring device for measuring the power generation characteristics of the solid electrolytic device.
- FIG. 5 shows the discharge characteristics of a solid electrolyte fuel cell obtained by using the metal oxide particles (PdCoO 2 ) as an oxidation catalyst in the anode of the solid electrolyte element according to the co-precipitation method of the method of the present invention.
- the graph is shown in comparison with.
- FIG. 6 shows metal oxide particles (PdCo ⁇ 2 ) obtained by the coprecipitation method of the method of the present invention.
- 7 is a graph showing the power density of a solid electrolyte fuel cell in which a solid electrolyte element is used as an oxidation catalyst in an anode of a solid electrolyte element in comparison with a conventional example and a comparative example.
- FIG. 7 is a graph for explaining the method of measuring the maximum current density.
- FIG. 8 is a graph showing the method of the present invention in which the metal oxide particles (PdCo O 2 ) were co-precipitated in an anode of a solid electrolyte device.
- 9 is a graph showing the maximum current density of a solid electrolyte fuel cell using an oxidation catalyst as compared with a conventional example and a comparative example.
- FIG. 9 is a chart showing an X-ray diffraction pattern of metal oxide particles (PtCoO 2 ) obtained by using the coprecipitation method according to the present invention.
- the metal oxide particles as the oxidation catalyst of the present invention are obtained by calcining a precipitate composed of two types of metal hydrates obtained by a coprecipitation method from a mixed solution in which two types of metal salts having different metal ions are dissolved. Obtained.
- the metal salt a metal salt that can be dissolved in water or hot water is preferable.
- the precipitate separated by filtration is a mixture of two metal hydrates.
- the precipitate particles generated by coprecipitation from the solution are fine and uniform in particle size, and are not affected by the particle size of the metal salt as the starting material.
- the precipitate separated by filtration is dried and then fired. Since secondary agglomeration of the particles occurs during drying, it is preferable to bake the particles after drying so that the particles are simply pulverized so as to break the secondary agglomeration.
- the firing is performed by filling the precipitate in a sealed container such as a quartz glass tube and heating it. By this calcination, only hydrogen is eliminated from the two metal hydrates, and metal oxide particles in which the two metals are bonded via oxygen are generated.
- the metal oxide particles have a composition shown by the following formula.
- A is Pd, Pt, Cu or Ag
- B is Co, Cr, Rh, Al, Ga, Fe, In, Sc or Tl.
- the metal oxide particles of the present invention are fine and uniform in particle size, and have a high catalytic ability for the oxidation reaction of gaseous compounds such as methane and carbon monoxide.
- the oxidation catalyst of the present invention comprising the metal oxide particles is a catalyst for promoting the oxidation reaction of a gaseous compound by oxygen ions supplied via a solid electrolyte in an environment free of oxygen molecules, Typically, it can be used as an oxidation catalyst for a solid oxide fuel cell, and is particularly suitable as an oxidation catalyst for a solid oxide fuel cell using methane as fuel.
- the methane oxidation catalyst is typically a hexagonal metal oxide such as PtCoO 2 , PdCrO 2 , PdRhO 2 , PdCoO 2 , CuCoO 2 , CuAlO 2 , CuGaO 2 , CuFeO 2 , CuRhO 2 , AgCoO 2 , AgCoO 2 , AgFe0 2, AgCrO 2,
- AgRh0 2, AgGa0 2, Agln0 2 , AgSc0 2, AgTl O 2 force are suitable S, PdCoO 2 and PtCoO 2 are preferred especially.
- Solid metallic oxide particles of anodic 1 4 with the oxidation catalyst in a electrolyte element 1 6 A are formulated, anodic 1 4 a methane (CH 4) Gas is supplied.
- the anode 14a is composed of a porous platinum layer 22a formed on one surface of the solid electrolyte substrate 10 and metal oxide particles for a methane oxidation catalyst on the outer surface of the porous platinum layer 22a. And an oxidation catalyst layer 22b formed by carrying a catalyst.
- the porous platinum 22a is formed by applying platinum paste to one surface of a solid electrolyte substrate 10 made of a fired YSZ body, and then firing in the air.
- the oxidation catalyst layer 22b is prepared by mixing a predetermined amount of metal oxide particles as a methane oxidation catalyst with an organic binder to form an oxide paste, which is applied on the porous platinum layer 22a. After that, it is formed by firing in air.
- FIG. 2 Another embodiment in which the oxidation catalyst of the present invention is used in a solid electrolyte fuel cell using methane as a fuel will be described.
- the structure of the solid oxide fuel cell shown in FIG. 2 is basically the same as the structure shown in FIG. 1, except that the anode 14b has a single-layer structure.
- the anode 14b has a structure in which metal oxide particles 20 as a methane oxidation catalyst are dispersed in a porous platinum layer and exist as a large number of dispersed phases.
- the anode 14b is prepared by mixing a predetermined amount of the metal oxide particles 20 with a platinum paste to form a composite paste, and applying the composite paste to one surface of a solid electrolyte substrate 10 made of a YSZ fired body. It is formed by firing in air.
- a high oxidizing ability is exhibited by the oxidation catalyst comprising fine and uniform oxide particles according to the present invention.
- PdCl 2 ⁇ (5-6 mmol) was added to 200 ml of distilled water and dissolved by stirring at 60-80 ° C. for 1 hour and 15 minutes. Then, after the solution temperature dropped to 40 to 50 ° C, 35% hydrochloric acid (0.03 ml) was added, and the mixture was stirred for 5 to 10 minutes. In this state, it was confirmed visually that PdCl 2 was completely dissolved.
- a 0.125 M aqueous NaOH solution 100 ml was added dropwise little by little over 45 to 60 minutes to obtain a colloidal precipitate.
- the precipitate was suction-filtered using filter paper (manufactured by Toyo Roshi Kaisha, standard 4A), and washed with 100 ml of distilled water at the same time. The filtered sediment and filter paper were then dried together in an oven at 70 ° C. for about 1 hour 30 minutes.
- the X-ray diffraction pattern of the precipitate confirmed that the precipitate was a mixture of Pd (OH) 2 and Co (OH) 2 .
- the dried precipitate was ground in a mortar, sealed in a quartz glass tube, and baked at 600 ° C. and 800 ° C. for 8 hours each.
- PdCoO 2 was produced by RD Shannon, DB Rogers, and according to the method described in T. Preitt; Inorganic Chemistry, Vol. 10, N04, (1971), pp. 713-718.
- the product removed from the transparent quartz tube was lightly pulverized with an agate mortar • pestle.
- Example 2 Using the PdCoO 2 of Example 1 obtained by the coprecipitation method as an oxidation catalyst, a solid electrolyte fuel cell shown in FIG. 2 was produced.
- the solid electrolyte substrate 10 is made of a YSZ fired body made of zirconia (YSZ) stabilized with 8 mol% of Y 2 O 3 .
- the anode 14b has the PdCoO 2 particles obtained in Example 1 dispersed as metal oxide particles 20 in the porous platinum layer, and exists as a large number of dispersed phases.
- Anode 14b was prepared by mixing a predetermined amount of PdCoO 2 obtained in Example 1 with platinum paste to form a composite paste, which was then sintered with YSZ. After being applied to one surface of a solid electrolyte substrate 10 made of a body, it was formed by firing in air at 130 ° C. for about 1 hour.
- Example 2 the solid electrolyte fuel cell shown in FIG. 2 was produced.
- the metal oxide particles 2 0 as an oxidation catalyst was used PdCo0 2 obtained in the double decomposition method of a conventional example 1.
- Example 2 the solid electrolyte fuel cell shown in FIG. 2 was produced.
- the metal oxide particles 2 0 as an oxidation catalyst, a weight ratio of 4: Sami Tsu preparative particles consisting of 1 nickel oxide is (NiO) and stabilized with 8 mol% Y 2 O 3 with di Rukoyua (YSZ) (Hereinafter referred to as Nicermet).
- the measuring device shown in FIG. 4 is composed of a first ceramic device having one end and the other end closed in a hollow portion 32 of a heating furnace 30 by plugs 48 a and 48 b made of silicone rubber.
- the cylindrical body 34 is inserted, and the second cylindrical body 36 made of ceramic is inserted into the first cylindrical body 34 through the plug 48 a at one end of the first cylindrical body 34.
- One end of the second cylindrical body 36 is closed by a stopper 50 made of silicone rubber, and the other end is sealed by an anode 14 b of a solid electrolyte element 16 B disposed therein.
- a methane gas supply pipe 38 extends through the plug 48a at one end of the second cylindrical body 36 to the vicinity of the anode 14b, and substantially contains moisture. Supply dry methane gas at a predetermined flow rate to the anode 14b.
- a discharge pipe 42 is also inserted into the second cylindrical body through a plug 48a at one end of the second cylindrical body 36, and discharges combustion gas including methane combustion gas.
- An oxygen supply pipe 40 extends through the plug 48 b at the other end of the first cylinder 34 to the vicinity of the power source 12 of the solid electrolyte element 16 B, and supplies oxygen at a predetermined flow rate. Feed force sword 1 2
- the discharge pipe 44 also penetrates the plug 48 b at the other end of the first cylinder 34 and enters the first cylinder 34, and the unused remaining amount of the supplied oxygen described above. Discharge the minute.
- thermocouple 46 extends through the plug 48 b at the other end of the first cylindrical body 34 to the vicinity of the solid electrolyte element 16 B, and reduces the ambient temperature near the solid electrolyte element 16. Measure.
- the discharge characteristics were measured while controlling the furnace 30 so that the temperature measured by the thermocouple 46 was 850 ° C. That is, the extraction voltage was measured while changing the extraction current from the power source 12 and the anode 14b of the solid electrolyte element 16B.
- FIG. 5 shows the measurement results of Example 2, Conventional Example 2, and Comparative Example as “coprecipitation method”, “metathesis method”, and “Nicermet”, respectively.
- the horizontal axis shows the current density (the amount of extraction current per unit area of the electrode), and the vertical axis shows the extraction voltage.
- FIG. 6 shows the generated power density curves obtained from the respective discharge characteristic curves in FIG. 5 as “coprecipitation method”, “double decomposition method”, and “Nicermet”.
- the vertical axis represents power density (voltage X current density), and the horizontal axis represents current density. Indicates the degree.
- the curve of the generated power density is ⁇ above, and the larger the maximum value of the generated power density and the larger the area surrounded by the curve, the larger the power generation amount.
- the maximum current density was measured using the measuring device shown in FIG. 4 while changing the ambient temperature of the solid electrolyte element 16 B in various ways.
- the maximum current density refers to the current density when the extraction voltage in the discharge measurement curve shown in FIG. 5 becomes zero, and indicates the power generation capacity of the solid electrolyte element 16B.
- the extraction voltage was measured by changing the extraction current amount from the solid electrolyte element 16 B, and the current density at the point X obtained by extrapolating until the extraction voltage became zero port was obtained. Is the maximum current density.
- FIG. 8 shows the relationship between the measured temperature and the maximum current density for Example 2, Conventional Example 2 and Comparative Example as “coprecipitation method”, “metalysis method”, and “N: i_cermet” as described above. .
- the PtCl 2 reagent (1.12 mmol) was added to 400 ml of distilled water, and the mixture was stirred and dissolved at 60 to 80 ° C. for 1 hour and 15 minutes. Then the solution After the temperature was lowered to 40 to 50 ° C., stirring was carried out for 5 to 10 minutes while 35% hydrochloric acid was added dropwise at a rate of 0.06 ml with a mic mouth pipe. In this state, it was confirmed visually that PtCl 2 was completely dissolved.
- the resulting PtCl 2 solution CoCl 2 ⁇ 6 H 2 O ( 1. 1 2 mmol) was added and stirred for 15 minutes. As a result, a mixed solution in which equimolar PtCl 2 and CoCl 2 were dissolved was obtained.
- a 0.125 M aqueous NaOH solution 200 ml was added dropwise little by little over 45 to 60 minutes to obtain a colloidal precipitate.
- the precipitate was suction-filtered using filter paper (manufactured by Toyo Roshi Kaisha, standard 4A), and washed simultaneously with 100 ml of distilled water. The filtered sediment and filter paper were then dried together in a dryer at 90-110 ° C for about 1 hour 30 minutes.
- the X-ray diffraction pattern of the precipitate confirmed that the precipitate was a mixture of PtCl 2 and Co (OH) 2 .
- the dried precipitate was ground in a mortar, filled in a platinum tube, sealed in a quartz glass tube, and baked at 75 ° C. for 8 hours. Filling the platinum tube is to prevent the reaction between the quartz and the powder sample during heating.
- the oxidation catalyst according to the present invention is composed of metal oxide particles obtained by a coprecipitation method, it is finer and more finely divided than metal oxide particles obtained by a conventional metathesis method or a high-temperature pressure synthesis method. Particle size is uniform. As a result, the catalyst can exhibit higher catalytic performance than before, and at the same time, it does not require a pulverizing step for miniaturization and uniform particle size as in the conventional case, so that the cost of catalyst production can be reduced.
- the solid electrolyte fuel cell using the oxidation catalyst according to the present invention can obtain remarkably excellent battery characteristics as compared with the conventional one.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Combustion & Propulsion (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Fuel Cell (AREA)
- Inert Electrodes (AREA)
- Catalysts (AREA)
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002538496A JPWO2002035621A1 (ja) | 2000-10-27 | 2001-10-26 | 気体状化合物の酸化触媒 |
EP01976854A EP1345279A4 (en) | 2000-10-27 | 2001-10-26 | GAS COMPOSITION OXIDATION CATALYST |
US10/149,399 US6720100B2 (en) | 2000-10-27 | 2001-10-26 | Catalyst for oxidation of gaseous compound |
CA002395884A CA2395884A1 (en) | 2000-10-27 | 2001-10-26 | Catalyst for oxidation of gaseous compound |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000328466 | 2000-10-27 | ||
JP2000-328466 | 2000-10-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002035621A1 true WO2002035621A1 (fr) | 2002-05-02 |
Family
ID=18805314
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2001/009454 WO2002035621A1 (fr) | 2000-10-27 | 2001-10-26 | Catalyseur d"oxydation de composé gazeux |
Country Status (5)
Country | Link |
---|---|
US (1) | US6720100B2 (ja) |
EP (1) | EP1345279A4 (ja) |
JP (1) | JPWO2002035621A1 (ja) |
CA (1) | CA2395884A1 (ja) |
WO (1) | WO2002035621A1 (ja) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080038592A1 (en) * | 2004-10-08 | 2008-02-14 | Harlan Anderson | Method of operating a solid oxide fuel cell having a porous electrolyte |
US8067332B2 (en) * | 2006-05-03 | 2011-11-29 | Samsung Sdi Co., Ltd. | Methanation catalyst, and carbon monoxide removing system, fuel processor, and fuel cell including the same |
WO2012029743A1 (ja) * | 2010-08-31 | 2012-03-08 | 本田技研工業株式会社 | 金属酸素電池 |
EP2937448A1 (en) * | 2014-04-25 | 2015-10-28 | Panasonic Intellectual Property Management Co., Ltd. | Method for generating oxygen, and water electrolysis device |
JP6715351B2 (ja) * | 2016-12-27 | 2020-07-01 | 国立大学法人秋田大学 | 排気ガス浄化触媒用デラフォサイト型酸化物及びこれを用いた排気ガス浄化触媒 |
US10722870B2 (en) * | 2016-12-27 | 2020-07-28 | Mitsui Mining & Smelting Co., Ltd. | Exhaust gas purification catalyst |
US20210388516A1 (en) * | 2018-09-26 | 2021-12-16 | Max Planck Gesellschaft Zur Förderung Der Wissenschaften eV | Electrocatalysts for hydrogen evolution reactions (her) with delafossite oxides abo2 |
CN112758996B (zh) * | 2020-12-14 | 2022-04-19 | 清华大学 | 一种双功能氧电催化剂及其制备和应用 |
WO2023139040A1 (en) | 2022-01-21 | 2023-07-27 | Basf Se | Mixed platinum ruthenium oxide and electrodes for the oxygen evolution reaction |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS49104873A (ja) * | 1973-01-25 | 1974-10-03 | ||
EP0270203A1 (en) * | 1986-12-03 | 1988-06-08 | Catalysts and Chemicals Inc, Far East | Heat resistant catalyst and method of producing the same |
EP0602864A2 (en) * | 1992-12-18 | 1994-06-22 | Johnson Matthey Public Limited Company | Palladium containing metal oxide catalyst |
JP2000348736A (ja) * | 1999-06-03 | 2000-12-15 | Shinko Electric Ind Co Ltd | 固体電解質燃料電池 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3498931A (en) * | 1968-04-02 | 1970-03-03 | Du Pont | Electrically conductive oxides containing palladium and their preparation |
US3804740A (en) * | 1972-02-01 | 1974-04-16 | Nora Int Co | Electrodes having a delafossite surface |
US3862023A (en) * | 1972-09-15 | 1975-01-21 | Ppg Industries Inc | Electrode having silicide surface |
US4173518A (en) * | 1974-10-23 | 1979-11-06 | Sumitomo Aluminum Smelting Company, Limited | Electrodes for aluminum reduction cells |
LU76107A1 (ja) * | 1976-10-29 | 1978-05-16 | ||
US4492811A (en) * | 1983-08-01 | 1985-01-08 | Union Oil Company Of California | Heterojunction photovoltaic device |
-
2001
- 2001-10-26 WO PCT/JP2001/009454 patent/WO2002035621A1/ja not_active Application Discontinuation
- 2001-10-26 US US10/149,399 patent/US6720100B2/en not_active Expired - Fee Related
- 2001-10-26 JP JP2002538496A patent/JPWO2002035621A1/ja active Pending
- 2001-10-26 CA CA002395884A patent/CA2395884A1/en not_active Abandoned
- 2001-10-26 EP EP01976854A patent/EP1345279A4/en not_active Ceased
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS49104873A (ja) * | 1973-01-25 | 1974-10-03 | ||
EP0270203A1 (en) * | 1986-12-03 | 1988-06-08 | Catalysts and Chemicals Inc, Far East | Heat resistant catalyst and method of producing the same |
EP0602864A2 (en) * | 1992-12-18 | 1994-06-22 | Johnson Matthey Public Limited Company | Palladium containing metal oxide catalyst |
JP2000348736A (ja) * | 1999-06-03 | 2000-12-15 | Shinko Electric Ind Co Ltd | 固体電解質燃料電池 |
Non-Patent Citations (1)
Title |
---|
See also references of EP1345279A4 * |
Also Published As
Publication number | Publication date |
---|---|
US6720100B2 (en) | 2004-04-13 |
JPWO2002035621A1 (ja) | 2004-03-04 |
EP1345279A4 (en) | 2004-11-10 |
EP1345279A1 (en) | 2003-09-17 |
US20020183200A1 (en) | 2002-12-05 |
CA2395884A1 (en) | 2002-05-02 |
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