WO2002030844A1 - Novel material for building interior utilizing coconut shell waste and manufacturing thereof - Google Patents
Novel material for building interior utilizing coconut shell waste and manufacturing thereof Download PDFInfo
- Publication number
- WO2002030844A1 WO2002030844A1 PCT/KR2000/001164 KR0001164W WO0230844A1 WO 2002030844 A1 WO2002030844 A1 WO 2002030844A1 KR 0001164 W KR0001164 W KR 0001164W WO 0230844 A1 WO0230844 A1 WO 0230844A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- building interior
- manufacturing
- present
- coconut shell
- coconut shells
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims abstract description 40
- 235000013162 Cocos nucifera Nutrition 0.000 title claims abstract description 32
- 244000060011 Cocos nucifera Species 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000002699 waste material Substances 0.000 title abstract description 6
- 239000000853 adhesive Substances 0.000 claims abstract description 22
- 230000001070 adhesive effect Effects 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 235000013311 vegetables Nutrition 0.000 claims abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 39
- 238000000034 method Methods 0.000 claims description 20
- 238000007731 hot pressing Methods 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 229920000945 Amylopectin Polymers 0.000 claims description 5
- 229920000856 Amylose Polymers 0.000 claims description 5
- 238000010000 carbonizing Methods 0.000 claims description 4
- 239000000428 dust Substances 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- 239000003245 coal Substances 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 10
- 238000004064 recycling Methods 0.000 abstract 1
- 238000002474 experimental method Methods 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 13
- 239000007789 gas Substances 0.000 description 11
- 230000001473 noxious effect Effects 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 8
- 238000001035 drying Methods 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- 229920002472 Starch Polymers 0.000 description 4
- 238000003763 carbonization Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 239000010902 straw Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 241000208822 Lactuca Species 0.000 description 3
- 235000003228 Lactuca sativa Nutrition 0.000 description 3
- 240000007594 Oryza sativa Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000007791 dehumidification Methods 0.000 description 3
- 238000004332 deodorization Methods 0.000 description 3
- 238000004079 fireproofing Methods 0.000 description 3
- 231100001261 hazardous Toxicity 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000005662 Paraffin oil Substances 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 235000008429 bread Nutrition 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000011505 plaster Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 206010003645 Atopy Diseases 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 229920002488 Hemicellulose Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 230000003028 elevating effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 206010025482 malaise Diseases 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/10—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products
- E04C2/16—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products of fibres, chips, vegetable stems, or the like
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B2001/742—Use of special materials; Materials having special structures or shape
- E04B2001/745—Vegetal products, e.g. plant stems, barks
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/24—Structural elements or technologies for improving thermal insulation
- Y02A30/244—Structural elements or technologies for improving thermal insulation using natural or recycled building materials, e.g. straw, wool, clay or used tires
Definitions
- the present invention relates to a novel material for building interior and the manufacturing method thereof. More particularly, the present invention relates to the material for building interior produced by the process comprising: producing the activated carbon from wasted coconut shells by heating in the Rotary kiln over 1,800 °C; mixing the produced activated carbon with natural vegetable aqueous adhesive; cold pressing the mixture; and drying.
- Korean Patent Publication No. 86-1688 disclosed the manufacturing method of boards from rice straw and Korean Utility Model Publication No. 71-1753 relates to the synthetic resin boards.
- the present invention utilize coconut shells which were not used in other objects but only wasting, and which were known as domestic wastes not easily decomposed by microorganisms.
- Ligenous components are mainly cellulose, hemicellulose and lignin, which comprise carbon, oxygen and hydrogen.
- dried coconut shells are rapidly oxidized and decomposed by heating about 280°C and emit gases such as CO 2 , CO, H 2 and CH . Elevating heating temperature up to 650°C ⁇ 700°C, the content of O 2 and H 2 in the emitted gases decreases and the degree of crystallization as activated carbons increases. Besides, heating dried coconut shells over 1,800°C, the black carbide of coconut shells is produced in the shape of crystalline diamond. The higher gets the heating temperature, the larger the content of carbon. According to experiments executed by the present inventors, when heating over 1,800°C, the carbon content of the activated carbon gets to 95% in maximum.
- Carbonized coconut shells have the vesicular structure, in which numerous micropores are formed and thereby have the functions of deodorization, dehumidification and filtration.
- Negatively charged carbide of coconut shells emits a lot of anions and adsorbs cations, by that means it makes the indoor environment comfortable and beneficial to human health.
- the carbide of coconut shells adsorbs noxious electromagnetic waves radiated from various kinds of electronic products and can intercept the man' s disclosure to the noxious electromagnetic waves indoor place.
- Conventionally disclosed and used materials for building interior contain many hazardous chemicals such as carcinogenic xylene, DBP, TOP, decane and so forth.
- coconut shells which are grown at the subtropical zone and the tropical zone, are used.
- the degree of carbonization of the coconut shells is required preferably dry-distilled coal or open-hearth coal carbonized at 400°C ⁇ 500°C, more preferably black coal carbonized at 600°C ⁇ 700°C, and most preferably white coal carbonized over 1,000°C.
- charcoal emits the energy of 6,700cal/g at 400°C, 8,000cal/g at 600°C, and 7,000cal/g over 1,000°C.
- the carbon content of coconut shells at the state of raw material is about 50%, and after carbonization at 400 °C the carbon content gets to 70%, and at 700 °C to 90%, and over 1,000°C to 95%.
- These coconut shell based activated carbon, produced over mesothermen, have the vesicular structure having numerous micropores.
- These activated carbons have the functions of deodorization, dehumidification and filtration, and are very effective in soundproofing, heat insulation, heat conservation and fire-proofing, and have the availability of processing such as nailing and sawing, and are good for interrupting hazardous waves such as electromagnetic wave and waterway wave.
- the present invention has an object to provide a novel material for building interior which is effective in soundproofing, heat insulation, heat conservation and fire-proofing, and which has the availability of processing such as nailing and sawing, and which is good for interrupting hazardous waves such as electromagnetic wave and waterway wave as aforementioned.
- Another object of the present invention is to provide the manufacturing method of said novel material for building interior.
- the present invention provides a material for building interior in the shape of board through the processes comprising: carbonizing coconut shells over mesothermen; grinding the activated carbon produced by carbonizing process; mixing grinded activated carbon with natural vegetable aqueous adhesive; cold pressing the mixture; and drying. And, to accomplish the above objects, the board-type building interior produced through said processes was estimated by various experiments.
- Fig. 1 is a process diagram of the exemplary illustration according to the present invention.
- Fig. 2 is a photograph showing the material for building interior by the process of the present invention.
- the manufacturing process of the novel material for building interior comprises: carbonizing the collected coconut shells over mesothermen; grinding the activated carbon coagula of coconut shells with the hammer-type grinder; mixing natural vegetable aqueous adhesive with grinded activated carbon; cold pressing the mixture; and drying the board-type material for building interior which is molded by cold pressing.
- the carbonized coconut shells have the characteristic of high stiffness and uniform distribution of micropores. After coconut shells are inserted into the Rotary Kiln, heating with paraffin oil burner over 1,800°C, the organic substances in the coconut shells are decomposed.
- the cooled coagula of the coconut shell based activated carbon is very stiff, they are grinded into granules by hammer-type grinder not manually. If required, thereafter the vacuum adso ⁇ tion process may be added, for the purpose of removing the activated carbon dust.
- the natural vegetable aqueous adhesive prepared specially, is mixed with granular activated carbons obtained through said 2 process.
- the specially prepared adhesive is preferably a kind of the natural vegetable aqueous adhesives, which is harmless to man as the building interior.
- the mixing rate of the activated carbon and the aqueous adhesive is preferably 7-8 : 3 ⁇ 2 by weight.
- the aqueous adhesive is prepared by the composition of said activated carbon 4kg, amylopectin 600g, amylose 200g and water(H 2 O) 3kg. Namely, the composition of aqueous adhesive is preferable at the rate of water(H 2 O) 75% ⁇ 85%, amylopectin 10% ⁇ 20%, amylose 1% ⁇ 10% by weight.
- the board-type material for building interior produced by said hot pressing process is dried and solidified with hot blast over 90 °C for 4 hours.
- the product of the present invention is provided for the various experiments.
- coconut shells 10kg were inserted into the Rotary Kiln and heated at 1,800°C for one hour with a paraffin oil burner.
- the carbide coagula of coconut shells 4.5kg, left after heating decomposition, were put into the hammer-type grinder and grinded into granules.
- the Homogenizer uniformly mixed the granular activated carbon 4.5kg with the natural vegetable aqueous adhesive 2kg.
- Example 2 After grinding process of said Example 1, the activated carbon dust was removed from the granular activated carbons with the vacuum adsorber. Because the natural aqueous adhesive is used in the material for building interior of the present invention, noxious gases are not emitted, apart from conventional materials for building interior, and moreover the function of adsorbing noxious gases makes a comfortable indoor environment. As well, the vegetable aqueous adhesive, used in the present invention, is prepared by utilizing the tackiness of amylopectin and the coagulation of amylose and heating at 80 °C in water, so that the adhesive is the - starch pastes in the semitransparent liquid state and convenient for use.
- the water molecules in the mixture of the adhesive and the granular activated carbons are evaporated at the state of hot- pressing over 90 ° C about 5 minutes, and through the retrogradation of starch, due to the cohesion of amylose with amylopectin, the granular activated carbons are solidified, and the regradation of starch is completed by re-drying over 90 ° C .
- the material for building interior of the present invention was heated at 100°C, but noxious gases such as ammonia, sulfur dioxide, hydrogen and so forth were not emitted at all.
- Experiment 6 Effects of deodorization and adsorbing noxious gases. Inserting each 30 cigarette-butts and one loaf of bread into said boxes in experiment 5 and keeping in for 2 days, the bread in the box made of the material of the present invention did not smell at all.
- Experiment 7 Effect of vapor-proofing. After wet cotton spread in two schales and put a nail on each schale, one of the schales was inserted into the box made of the material of the present invention in the experiment 5 and the other into the plaster board box for one week. As the result of estimating the conosion degree of the nails, no rust was observed in the nail kept in the box made of the material of the present invention.
- the present invention provides a novel material for building interior and the manufacturing method thereof.
- the material for building interior of the present invention which is made from coconut shells and natural aqueous adhesive, does not emit noxious gases at all but adsorb noxious gases emitted from other combustibles when a fire breaks out, thus the safety of the material of the present invention is very high.
- the material of the present invention has the high performance for construction such as nailing and sawing and is very effective in heat insulation, soundproofing, dehumidification, heat conservation, and fireproofing.
- the activated carbons contained in the material of the present invention emit numerous anions and adsorb cations and kinds of hazardous waves, thus the material of the present invention is very effective in maintaining the indoor environment comfortable.
- the material for building interior of the present invention is thus highly applicable in building interior industrial field.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Ceramic Engineering (AREA)
- Architecture (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Building Environments (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2000279677A AU2000279677A1 (en) | 2000-10-11 | 2000-10-17 | Novel material for building interior utilizing coconut shell waste and manufacturing thereof |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2000-0059856A KR100421069B1 (ko) | 2000-10-11 | 2000-10-11 | 폐기된 코코넛 껍질을 이용한 건축용 내장재 및 그 제조방법 |
KR2000-59856 | 2000-10-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002030844A1 true WO2002030844A1 (en) | 2002-04-18 |
Family
ID=19693019
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2000/001164 WO2002030844A1 (en) | 2000-10-11 | 2000-10-17 | Novel material for building interior utilizing coconut shell waste and manufacturing thereof |
Country Status (3)
Country | Link |
---|---|
KR (1) | KR100421069B1 (ko) |
AU (1) | AU2000279677A1 (ko) |
WO (1) | WO2002030844A1 (ko) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100587132B1 (ko) * | 2005-09-20 | 2006-06-08 | 이화형 | 생활목질폐기물로부터의 작업성이 뛰어난 기능성 숯보드의제조 |
KR100911177B1 (ko) * | 2007-08-02 | 2009-08-06 | 최현의 | 인조 구조관 제조방법 |
KR101013265B1 (ko) | 2010-06-29 | 2011-02-09 | 송우숙 | 용출수 흡수용 코코피트 블럭 및 그 제조방법 |
KR101892244B1 (ko) | 2015-12-11 | 2018-08-27 | 주식회사 케이디우드테크 | 코코넛 모자이크 타일 제작 방법 및 이에 의해 제작된 코코넛 모자이크 타일 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5164355A (en) * | 1991-01-23 | 1992-11-17 | Air Products And Chemicals, Inc. | High capacity coconut shell char for carbon molecular sieves |
KR930000380A (ko) * | 1991-06-01 | 1993-01-15 | 최정식 | 활성탄 제조 방법 |
JPH0821069A (ja) * | 1994-07-08 | 1996-01-23 | Toyotsukusu:Kk | 熱伝導率を高めたクッション材 |
KR970025873A (ko) * | 1995-11-14 | 1997-06-24 | 정임수 | 코코낫 열매를 이용한 방열재 |
JPH1113262A (ja) * | 1997-06-23 | 1999-01-19 | Tou X:Kk | 床下地材 |
KR20000015266A (ko) * | 1998-08-28 | 2000-03-15 | 최수현 | 휘발성 유기물질을 이용한 탄소 분자체 제조 방법 |
KR20000039750A (ko) * | 1998-12-15 | 2000-07-05 | 김상근 | 천연 코코넛 섬유를 이용한 내장재 및 그 제조방법 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0418910A (ja) * | 1990-05-11 | 1992-01-23 | Masamune Shiraishi | カーボンフィルターの製造方法およびカーボンフィルター |
KR0169646B1 (ko) * | 1994-10-12 | 1999-05-15 | 추호석 | 대차의 관성반경 측정장치 및 그 방법 |
KR19980066254U (ko) * | 1997-05-13 | 1998-12-05 | 김기현 | 야자섬유로 된 방음, 단열성 벽판 |
-
2000
- 2000-10-11 KR KR10-2000-0059856A patent/KR100421069B1/ko not_active IP Right Cessation
- 2000-10-17 AU AU2000279677A patent/AU2000279677A1/en not_active Abandoned
- 2000-10-17 WO PCT/KR2000/001164 patent/WO2002030844A1/en active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5164355A (en) * | 1991-01-23 | 1992-11-17 | Air Products And Chemicals, Inc. | High capacity coconut shell char for carbon molecular sieves |
KR930000380A (ko) * | 1991-06-01 | 1993-01-15 | 최정식 | 활성탄 제조 방법 |
JPH0821069A (ja) * | 1994-07-08 | 1996-01-23 | Toyotsukusu:Kk | 熱伝導率を高めたクッション材 |
KR970025873A (ko) * | 1995-11-14 | 1997-06-24 | 정임수 | 코코낫 열매를 이용한 방열재 |
JPH1113262A (ja) * | 1997-06-23 | 1999-01-19 | Tou X:Kk | 床下地材 |
KR20000015266A (ko) * | 1998-08-28 | 2000-03-15 | 최수현 | 휘발성 유기물질을 이용한 탄소 분자체 제조 방법 |
KR20000039750A (ko) * | 1998-12-15 | 2000-07-05 | 김상근 | 천연 코코넛 섬유를 이용한 내장재 및 그 제조방법 |
Also Published As
Publication number | Publication date |
---|---|
KR100421069B1 (ko) | 2004-03-04 |
AU2000279677A1 (en) | 2002-04-22 |
KR20010007865A (ko) | 2001-02-05 |
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