WO2002000773A3 - Kovalent vernetzte polymere und polymermembranen via sulfinatalkylierung - Google Patents

Kovalent vernetzte polymere und polymermembranen via sulfinatalkylierung Download PDF

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Publication number
WO2002000773A3
WO2002000773A3 PCT/EP2001/005826 EP0105826W WO0200773A3 WO 2002000773 A3 WO2002000773 A3 WO 2002000773A3 EP 0105826 W EP0105826 W EP 0105826W WO 0200773 A3 WO0200773 A3 WO 0200773A3
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WIPO (PCT)
Prior art keywords
polymer
groups
sulphinate
following
cross
Prior art date
Application number
PCT/EP2001/005826
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English (en)
French (fr)
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WO2002000773A9 (de
WO2002000773A2 (de
Inventor
Jochen Kerres
Wei Zhang
Chy-Ming Tang
Thomas Haering
Original Assignee
Univ Stuttgart
Jochen Kerres
Wei Zhang
Chy-Ming Tang
Thomas Haering
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10024575A external-priority patent/DE10024575A1/de
Application filed by Univ Stuttgart, Jochen Kerres, Wei Zhang, Chy-Ming Tang, Thomas Haering filed Critical Univ Stuttgart
Priority to JP2002505894A priority Critical patent/JP2004502008A/ja
Priority to CA2379962A priority patent/CA2379962C/en
Priority to IL14772601A priority patent/IL147726A0/xx
Priority to AU93695/01A priority patent/AU784360B2/en
Priority to BR0106652-8A priority patent/BR0106652A/pt
Priority to EP01974075A priority patent/EP1290069A2/de
Publication of WO2002000773A2 publication Critical patent/WO2002000773A2/de
Priority to US10/173,830 priority patent/US6982303B2/en
Publication of WO2002000773A3 publication Critical patent/WO2002000773A3/de
Priority to PCT/DE2002/004173 priority patent/WO2003050169A2/de
Priority to DE10295737.1T priority patent/DE10295737B4/de
Priority to AU2002364268A priority patent/AU2002364268A1/en
Publication of WO2002000773A9 publication Critical patent/WO2002000773A9/de
Priority to AU2006202592A priority patent/AU2006202592A1/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0093—Chemical modification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/52—Polyethers
    • B01D71/522—Aromatic polyethers
    • B01D71/5222—Polyetherketone, polyetheretherketone, or polyaryletherketone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
    • B01D71/68—Polysulfones; Polyethersulfones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/82—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/411—Organic material
    • H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1044—Mixtures of polymers, of which at least one is ionically conductive
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. insitu polymerisation or insitu crosslinking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1086—After-treatment of the membrane other than by polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/30—Cross-linking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
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  • General Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Polymers & Plastics (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Secondary Cells (AREA)
  • Fuel Cell (AREA)

Abstract

Kovalent vernetztes Polymer oder kovalent vernetzte Polymermembran, bestehend aus einem oder mehreren Polymeren, die die folgenden funktionellen Gruppen tragen können (M=Hal(F, Cl, Br, I), OR, NR2; R=Alkyl, Hydroxyalkyl, Aryl; (Me=H, Li, Na, K, Cs, oder andere Metallkationen oder Ammoniumionen); a) Vorstufen von Kationenaustauschergruppen: SO2M und/oder POM2 und/oder COM; b) Sulfinatgruppen SO2Me und die mittels folgenden organischen Verbindungen kovalent vernetzt sein können: a) di- tri- oder oligofunktionellen Halogenalkanen oder Halogenaromaten, die mit Sulfinatgruppen SO2Me zur Reaktion gebracht worden waren, wodurch im Polymer/im Polymerblend/in der Polymermembran folgende Vernetzungsbrücken vorhanden sind (Y=Vernetzungsbrücke, X=Hal (F, Cl, Br, I), OR, Y=-(CH2)x-; -Arylen-; -(CH2)x-Arylen-; CH2Arylen-CH2-, x=3-12): Polymer-SO2-Y-SO2-Polymer und/oder b) Verbindungen, die folgende Gruppen enthalten: Hal-(CH2)x-NHR, die auf der einen Seite (Hal-) mit Sulfinatgruppen SO2Me zur Reaktion gebracht worden waren, und auf der anderen Seite (-NHR) mit SO2M-Gruppen, wodurch im Polymer/im Polymerblend/in der Polymermembran folgende Vernetzungsbrücken vorhanden sind: Polymer-SO2-(CH2)x-NR-SO2-Polymer und/oder c) Verbindungen, die folgende Gruppen enthalten: NHR-(CH2)x-NHR, die mit SO2Me-Gruppen zur Reaktion gebracht worden waren, wodurch im Polymer/im Polymerblend/in der Polymermembran folgende Vernetzungsbrücken vorhanden sind: Polymer-SO2-NR-(CH2)x-NR-SO2-Polymer.
PCT/EP2001/005826 2000-05-19 2001-05-21 Kovalent vernetzte polymere und polymermembranen via sulfinatalkylierung WO2002000773A2 (de)

Priority Applications (11)

Application Number Priority Date Filing Date Title
JP2002505894A JP2004502008A (ja) 2000-05-19 2001-05-21 スルフィナートアルキル化を介した共有結合架橋ポリマーおよびポリマー膜
CA2379962A CA2379962C (en) 2000-05-19 2001-05-21 Covalently cross-linked polymers and polymer membranes via sulfinate alkylation
IL14772601A IL147726A0 (en) 2000-05-19 2001-05-21 Polymers and polymer membranes covalently cross-linked by sulphinate alkylation
AU93695/01A AU784360B2 (en) 2000-05-19 2001-05-21 Polymers and polymer membranes covalently cross-linked by sulphinate alkylation
BR0106652-8A BR0106652A (pt) 2000-05-19 2001-05-21 A invenção refere-se a um polìmero covalentemente reticulado ou membrana polimérica consistinto de um ou mais polìmeros
EP01974075A EP1290069A2 (de) 2000-05-19 2001-05-21 Kovalent vernetzte polymere und polymermembranen via sulfinatalkylierung
US10/173,830 US6982303B2 (en) 2000-05-19 2002-06-19 Covalently cross-linked polymers and polymer membranes via sulfinate alkylation
AU2002364268A AU2002364268A1 (en) 2001-05-21 2002-11-04 Covalently cross-linked composite membranes
PCT/DE2002/004173 WO2003050169A2 (de) 2001-05-21 2002-11-04 Kovalent vernetzte kompositmembranen
DE10295737.1T DE10295737B4 (de) 2001-05-21 2002-11-04 Kovalent vernetzter Komposit, kovalente vernetzte Kompositmembran, Verfahren zu deren Herstellung und Verwendung der Membranen
AU2006202592A AU2006202592A1 (en) 2000-05-19 2006-06-17 Polymers and polymer membranes covalently cross-linked by sulphinate alkylation

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE10024575.7 2000-05-19
DE10024575A DE10024575A1 (de) 2000-11-02 2000-05-19 Kovalent vernetzte Polymere und Polymermembranen via Sulfinatalkylierung
DE10054233A DE10054233A1 (de) 2000-05-19 2000-11-02 Kovalent vernetzte Kompositmembranen
DE10054233.6 2000-11-02

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US5119602A Continuation 2000-05-19 2002-01-22

Publications (3)

Publication Number Publication Date
WO2002000773A2 WO2002000773A2 (de) 2002-01-03
WO2002000773A3 true WO2002000773A3 (de) 2002-07-18
WO2002000773A9 WO2002000773A9 (de) 2003-02-13

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Application Number Title Priority Date Filing Date
PCT/EP2001/005826 WO2002000773A2 (de) 2000-05-19 2001-05-21 Kovalent vernetzte polymere und polymermembranen via sulfinatalkylierung

Country Status (9)

Country Link
EP (1) EP1290069A2 (de)
JP (1) JP2004502008A (de)
CN (1) CN100354344C (de)
AU (2) AU784360B2 (de)
BR (1) BR0106652A (de)
CA (1) CA2379962C (de)
DE (1) DE10054233A1 (de)
IL (1) IL147726A0 (de)
WO (1) WO2002000773A2 (de)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10024575A1 (de) * 2000-11-02 2001-11-22 Univ Stuttgart Kovalent vernetzte Polymere und Polymermembranen via Sulfinatalkylierung
WO2003050169A2 (de) * 2001-05-21 2003-06-19 Haering Thomas Kovalent vernetzte kompositmembranen
KR100403754B1 (ko) * 2001-06-19 2003-10-30 송민규 연료전지용 복합 고분자 전해질 막, 이의 제조방법 및이를 포함하는 연료전지
DE10209784A1 (de) * 2001-09-01 2003-12-04 Univ Stuttgart Inst Fuer Chemi Sulfinatgruppen enthaltende Oligomere und Polymere und Verfahren zu ihrer Herstellung
AU2003229264A1 (en) 2002-02-28 2003-09-09 Universitat Stuttgart Oligomers and polymers containing sulfinate groups, and methods for producing the same
DE10391005D2 (de) * 2002-02-28 2005-04-14 Thomas Haering Schichtstrukturen und Verfahren zu deren Herstellung
JP4827044B2 (ja) * 2002-02-28 2011-11-30 ウニヴェルズィテート シュトゥットガルト スルフィナート基を含むオリゴマー及びポリマー、並びにその製造方法
KR100486728B1 (ko) 2002-12-12 2005-05-03 삼성에스디아이 주식회사 나노복합전해질막 및 이를 채용한 연료전지
WO2005090480A1 (ja) * 2004-03-23 2005-09-29 Mitsubishi Gas Chemical Co., Inc. 固体高分子電解質、固体高分子ゲル膜、固体高分子電解質膜、および燃料電池
JP6016019B2 (ja) * 2012-10-30 2016-10-26 独立行政法人国立高等専門学校機構 燃料電池用の電解質膜、燃料電池用の電解質膜の製造方法および燃料電池
CN108258170B (zh) * 2017-12-05 2021-07-16 宜宾天原集团股份有限公司 一种聚醚醚酮基锂电池隔膜的制备方法
CN109659601B (zh) * 2018-12-12 2021-09-28 南京师范大学 一种多酸/高分子聚合物杂化纳米线材料作为固态电解质的应用
HUE055324T2 (hu) 2019-07-31 2021-11-29 Innolith Tech Ag SO2 alapú elektrolit újratölthetõ akkumulátorcellához és azt tartalmazó újratölthetõ akkumulátorcella
CN115646223B (zh) * 2022-10-19 2023-06-27 安徽省海徽化工有限公司 一种耐污染聚醚砜超滤膜

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AU2006202592A1 (en) 2006-07-13
CA2379962A1 (en) 2002-01-03
CA2379962C (en) 2016-10-18
WO2002000773A9 (de) 2003-02-13
CN100354344C (zh) 2007-12-12
BR0106652A (pt) 2002-04-09
AU9369501A (en) 2002-01-08
WO2002000773A2 (de) 2002-01-03
AU784360B2 (en) 2006-03-16
EP1290069A2 (de) 2003-03-12
CN1440438A (zh) 2003-09-03
JP2004502008A (ja) 2004-01-22
IL147726A0 (en) 2002-08-14

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