Classifications

• • G—PHYSICS
  • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
  • G21C—NUCLEAR REACTORS
  • G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
  • G21C3/42—Selection of substances for use as reactor fuel
  • G21C3/58—Solid reactor fuel Pellets made of fissile material
  • G21C3/62—Ceramic fuel
  • G21C3/64—Ceramic dispersion fuel, e.g. cermet
• • G—PHYSICS
  • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
  • G21C—NUCLEAR REACTORS
  • G21C1/00—Reactor types
  • G21C1/04—Thermal reactors ; Epithermal reactors
  • G21C1/06—Heterogeneous reactors, i.e. in which fuel and moderator are separated
  • G21C1/08—Heterogeneous reactors, i.e. in which fuel and moderator are separated moderator being highly pressurised, e.g. boiling water reactor, integral super-heat reactor, pressurised water reactor
  • G21C1/084—Boiling water reactors
• • G—PHYSICS
  • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
  • G21C—NUCLEAR REACTORS
  • G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
  • G21C3/30—Assemblies of a number of fuel elements in the form of a rigid unit
  • G21C3/36—Assemblies of plate-shaped fuel elements or coaxial tubes
• • G—PHYSICS
  • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
  • G21C—NUCLEAR REACTORS
  • G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
  • G21C3/42—Selection of substances for use as reactor fuel
  • G21C3/58—Solid reactor fuel Pellets made of fissile material
  • G21C3/62—Ceramic fuel
  • G21C3/626—Coated fuel particles
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E30/00—Energy generation of nuclear origin
  • Y02E30/30—Nuclear fission reactors
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10S376/00—Induced nuclear reactions: processes, systems, and elements
  • Y10S376/90—Particular material or material shapes for fission reactors
  • Y10S376/901—Fuel
  • Y10S376/903—Shapes

Definitions

• the invention mainly relates to a monobloc or massive combustible element, designed to be used in the core of a nuclear reactor, in contact with any heat transfer fluid such as water or a gas, to define at will a fast spectrum. or thermal, by a simple adaptation of its dimension ent.
• the invention also relates to a fast spectrum boiling water nuclear reactor using fuel elements of this type. Such a reactor can in particular be used to consume the plutonium produced in existing water nuclear reactors, used for the production of electricity.
• Nuclear reactors intended for the production of electrical energy commonly use nuclear fuel assemblies of square or hexagonal cross section, arranged vertically side by side to form the heart of the reactor.
• each of the assemblies comprises a bundle of fuel rods, supported by a frame.
• Each of the pencils consists of nuclear fuel pellets stacked on top of each other at inside a very long tube.
• the nuclear fuel pellets are made of uranium dioxide, comprising fertile uranium 238 atoms and fissile uranium 235 atoms.
• the pellets nuclear fuel is made up of a mixture of uranium dioxide and plutonium dioxide. They then include uranium 238 atoms, plutonium atoms 238, 239, 241 and 242, as well as a small proportion of uranium 235.
• the coated fissile particles comprise a fissile nucleus, of substantially spherical shape, coated with several successive layers comprising in particular an internal porous layer capable of housing the fission gases and supporting the swelling of the nucleus, and a layer of Sic silicon carbide forming a tight barrier for fission products.
• These particles are said to be of the "TRISO" type. Depending on the manufacturing process used, their diameter varies between around a few hundred microns and a few millimeters.
• the coated particles are agglomerated in a different form by a carbon matrix.
• a first type of fuel element developed in the United States of America and in France, the coated particles are agglomerated in the form of cylindrical rods, which are then inserted into vertical tubular channels provided for this purpose in blocks of graphite, of hexagonal section, forming the heart of a high temperature reactor, gas cooled.
• the cylindrical rods are obtained by agglomerating the coated particles and a matrix based on graphite powder.
• the coated particles are agglomerated in the form of balls, which are piled up in bulk with graphite balls of the same dimension, to constitute the heart of a high temperature reactor, gas cooled.
• the balls are obtained by agglomerating the coated particles and a carbon matrix to form the central part of the ball, and by coating this central part with a peripheral layer devoid of coated particles.
• the uranium 238 atoms contained in these assemblies are fertile, that is to say that they capture the neutrons to generate plutonium atoms of which only the isotopes 239 and 241 are fissile in the thermal domain .
• nuclear reactors are currently under study to • to use this plutonium as fuel, that is to say to produce electrical energy, while consuming this plutonium in order to reduce the volume of waste from existing nuclear reactors.
• the main object of the invention is a fuel element of a new type, suitable for industrial implementation and not having the drawbacks of conventional nuclear fuel assemblies with rod bundles.
• the invention also relates to a fuel element of new design, capable of producing at will a fast neutron spectrum or a thermal or epithermal neutron spectrum, by a simple modification of its dimensioning.
• the subject of the invention is also a combustible element whose original design allows it in particular to use as combustible material the plutonium produced by existing nuclear reactors, placing themselves in a fast spectrum, which is particularly favorable with regard to the consumption of plutonium.
• a monobloc fuel element for a nuclear reactor formed of coated fissile particles, embedded in a matrix, characterized in that it comprises a plurality of parallel plates separated by spaces and connected together by junction parts, said matrix being inert with respect to the balance of heavy nuclei (fissile and fertile) and neutral with respect to a heat transfer fluid capable of circulating in said spaces.
• the fission gases released under irradiation are retained in the coated particles, without it being necessary to provide expansion chambers comparable to those which currently equip the rods containing the nuclear fuel pellets.
• the total height of the core can be significantly reduced compared to a traditional reactor.
• the modification of the ratio of the thicknesses of the plates and of the spaces which separate them makes it possible to obtain a fast spectrum or a thermal or epithermal spectrum at will.
• the fuel element has a substantially parallelepiped external shape.
• the plates are substantially planar.
• said plates are preferably substantially vertical and at least one of the spaces which separate them is capable of receiving a control member, capable of controlling the piloting or stopping of the reactor.
• the parallel plates and the junction parts are advantageously perforated, at predetermined levels, to form windows for transverse flow of the heat-transfer fluid, which makes it possible to increase the exchange surface between the fuel element and said element. fluid and homogenize the heat transfer fluid over the entire section of the reactor core.
• the space capable of receiving a control member has a cross-section in horizontal section and divides the fuel element into four sub-assemblies each comprising several plates connected together by some of the junction parts, others of said junction parts interconnecting each of the sub-assemblies, at the periphery of the fuel element.
• a second control system independent of the first and always in the shape of a cross can be placed between four ad combustible fuel elements.
• a first space capable of receiving a first plate-shaped control member is formed in a central part of the fuel element.
• a second series of spaces, opening at the periphery of said element and capable of receiving a second rake-shaped control member, is then formed at least on one side of the central part.
• the plates and the spaces preferably have uniform thicknesses.
• the thicknesses of the plates and of the spaces are in a ratio of 1 capable of defining a fast spectrum.
• the coated particles comprise nuclei of fissile bodies chosen from the group comprising uranium and plutonium.
• the inert matrix is made of a material offering an effective absorption section with low neutrons and a high thermal conductivity.
• the subject of the invention is also a boiling water nuclear reactor, comprising a core comprising a plurality of fuel elements produced as defined above, the ratio between the thicknesses of the plates and spaces being a compromise between the constraints related to the moderation of neutrons and the extraction of thermal power. To obtain a fast spectrum, this ratio is substantially equal to 1.
• FIG. 1 is a top view which schematically shows a fuel element according to a first embodiment of one invention
• FIG. 2 is a top view comparable to Figure 1, illustrating a second embodiment of the invention
• FIG. 3 is a side view of one fuel element of Figure 2;
• - Figure 4 is a top view comparable to Figures 1 and 2, illustrating a third embodiment of one invention.
• FIG. 5 shows the neutron spectrum obtained by calculation, in an infinite medium, assuming that fuel elements according to the invention form the heart of a boiling water nuclear reactor, at a level of the heart where the rate presence of steam is 40%.
• FIG. 1 there is shown schematically a top view of a fuel element 10 according to a first embodiment of the invention.
• the fuel element 10 is in the form of a one-piece or monolithic brick, produced in one piece.
• the fuel element has a substantially parallelepiped external shape.
• the fuel element can have, in horizontal section, the shape of a square of approximately 30 cm on a side, for a height less than one meter.
• This shape makes it possible to juxtapose and superimpose identical fuel elements 10 inside the vessel of a nuclear reactor, to form the heart of this reactor. Juxtaposed columns are thus produced in a square pitch network, taking care to provide spaces between the fuel elements of the adjacent columns. These spaces facilitate the circulation of a heat transfer fluid and, as will be seen in more detail below, the possible installation of control members.
• the fuel elements can be maintained by a frame also facilitating the gripping by handling members.
• the fuel element 10 can take a different shape, such as a hexagonal shape in section along a horizontal plane.
• the fuel element 10 comprises one or more groups of parallel plates 12, separated by spaces 14 and connected together by junction parts l ⁇ a and 16b.
• the plates 12 are flat, arranged substantially vertically, and have uniform thicknesses, identical from one plate to another.
• the spaces 14 separating the adjacent plates 12 have uniform thicknesses.
• the thicknesses of the plates 12 and of the spaces 14 are identical and substantially equal to 2 cm.
• the plates 12 and the junction parts 16a, 16b are perforated at predetermined levels, to form windows 26 regularly distributed over the entire height of the fuel element.
• This arrangement makes it possible to homogenize the heat transfer fluid from one combustible element to another, in order to limit the power distribution instabilities linked to the thermal part (low in normal operation) of the neutron flux. This is particularly advantageous when the fuel element is used in a boiling water nuclear reactor, since the heat transfer fluid is then in the form of a two-phase mixture. Indeed, the windows 22 then make it possible to homogenize the vapor vacuum rate of this mixture over the entire section of the reactor core.
• windows 26 also makes it possible to increase the exchange surface between the element fuel 10 and the heat transfer fluid and, consequently, the power density of the core while retaining its neutron properties.
• the plates 12 as well as the joining parts 16 forming the one-piece fuel element 10 are made up of coated fissile particles, dispersed in a matrix inert with respect to the balance of the fissile and fertile nuclei and neutral with respect to the fluid coolant capable of circulating inside and around the fuel element 10, in particular in the spaces 14.
• the coated fissile particles are particles comparable to the "TRISO" type particles described above. Each of them comprises a nucleus of a fissile body constituted by plutonium and / or uranium. This core is coated with several layers', integrating a layer of silicon carbide Sic. The particles thus obtained are substantially spherical particles whose diameter can vary between a few hundred microns and a few millimeters.
• Uranium is, for example, in the form of depleted uranium dioxide U0 2 (for example 0.25% uranium 235 to 99.75% uranium 238).
• Plutonium is for example in the form of plutonium dioxide Pu0 2 obtained from plutonium from an existing pressurized water nuclear reactor.
• the fuel element 10 contains both uranium and plutonium, it is obtained by agglomerating both particles comprising a uranium dioxide core and particles comprising a plutonium dioxide nucleus, or mixed oxide particles (U, Pu) 0 2 .
• the fuel may also contain an appropriate proportion of thorium as a fertile element.
• the coated fissile particles thus produced are dispersed in a matrix inert with respect to the balance of the fissile and fertile nuclei and neutral with respect to the heat transfer fluid.
• the inert matrix is preferably made up either of silicon carbide Sic, or of a metal, or of a combination of the two.
• the presence of a metal, in limited proportion, in the matrix in which the coated fissile particles are dispersed makes it possible to facilitate the manufacture and the machining of the fuel elements 10 and to improve their mechanical characteristics.
• the use of steel can be useful when the dimensioning of the fuel element determines a fast spectrum operation, the steel absorbing little neutrons.
• the fuel element 10 comprises four juxtaposed sub-assemblies 18 of the same dimensions.
• Each of the sub-assemblies 18 is formed by several parallel plates 12 (four in FIG. 1), connected to each other by joining parts 16a (which may or may not be combustible).
• the joining parts 16a also have the form of vertically oriented plates. In FIG. 1, two joining parts 16a connect the adjacent plates 12.
• the plates 12 of two contiguous sub-assemblies 18 are perpendicular to one another, so as to limit the leakage of the neutrons.
• Other junction parts 16b connect the sub-assemblies 18 to each other, to the peripheral of the fuel element 10, in the extension of the plates 12 bordering this periphery.
• FIG. 1 allows to define, inside the fuel element 10, a space 20 having a cross shape in horizontal section.
• This space 20 with cross-shaped section can receive a control member 22 also having a cross shape in horizontal section.
• This control member 22 ensures the piloting and / or the shutdown of the reactor under the effect of a displacement in a vertical direction, according to techniques analogous to those which are commonly used in existing nuclear reactors.
• the control member 22 can in particular be made of a boron carbide alloy
• a complementary control member also in the form of a cross, can also be placed in the spaces 23 which separate four adjacent fuel elements 10, in the reactor core.
• This control member 24 can in particular be used in addition to the previous one, to control the emergency shutdown of the reactor.
• the plates 12 and the spaces 14 have thicknesses el and e2 substantially equal. The ratio of these thicknesses el and e2 is therefore substantially equal to 1.
• This arrangement is particularly suitable for a fuel element intended to operate on a fast spectrum, in the presence of a heat transfer fluid consisting of water. In other words, the water layers separating the adjacent plates 12 are then sufficiently thin, in comparison with the thickness of these plates, so that the water practically does not fulfill a moderating function and only participates in cooling. of the fuel element.
• the heat transfer fluid fulfills an increasingly important moderating function.
• a simple dimensional modification of the thicknesses el and e2 thus makes it possible to transform the fuel element operating in the fast spectrum illustrated in FIG. 1 into a fuel element operating in the thermal or epithermal spectrum.
• Figures 2 and 3 show a second embodiment of a nuclear fuel element according to the invention.
• the fuel element illustrated in FIGS. 2 and 3 has general characteristics identical to those of the fuel element which has just been described with reference to FIG. 1. The only difference relates to the fact that the plates 12 of each of the four sub-assemblies 18 are all parallel to each other, instead of being perpendicular from one sub-assembly to the other as in the embodiment of FIG. 1.
• Figure 4 there is shown a top view of a third embodiment of a fuel element according to the invention. In this case, the fuel element no longer consists of four sub-assemblies, connected together by four joining parts 16b, but by two sub-assemblies 18, connected together by two joining parts 16b at the periphery of the fuel element 10.
• the two sub-assemblies 18 have mirror symmetry with respect to each other. Each of them comprises a series of plates 12, parallel to each other, as well as a single junction part 16a connecting between them the planar plates 12, at their end facing the center of the fuel element. Each sub-assembly 18 thus has in section the shape of a comb, in which the joining part 16a is perpendicular to the plates 12.
• the joining parts 16a and 16b delimit, in the central part of the fuel element 10, a space 28 of horizontal section in the form of an elongated rectangle, which extends over the entire height of the fuel element.
• a first control member 30, in the form of a plate, can be received in this space 28 in order to control and / or shut down the reactor.
• the plates 12 of each of the sub-assemblies 18 define between them spaces 14 of uniform thickness. These spaces 14 open at the outer periphery of the fuel element.
• a second control member 32 of horizontal section in the form of a rake, can also be received in each of the series of spaces 14 formed between the plates 12 of the same sub-assembly 18.
• control member 32 may have a section such that it penetrates both between the plates 12 of two adjacent fuel elements 10. Like the control member 24 in FIG. 1, the control member 32 can in particular be used for the emergency shutdown of the reactor.
• the arrangement which has just been described with reference to FIG. 4 gives the combustible element a shape comparable to that of a radiator, which favors the heat exchanges between said combustible element and the heat transfer fluid.
• a preferred application of the fuel element according to the invention relates to a boiling water nuclear reactor operating in fast spectrum, used to consume plutonium.
• a fast spectrum is easily obtained.
• the fuel element can consist substantially of half (by volume) of coated fissile particles consisting of half of fissile oxide and half of coating with SiC, the other half. being formed by the inert matrix.
• this matrix is made up of silicon carbide
• approximately 75% by volume of the fuel element is made up of silicon carbide.
• the fuel element 10 can comprise for example 34% by volume of particles containing depleted uranium dioxide U0 2 and 16% by volume of particles containing plutonium dioxide Pu0 2 .
• the particles of depleted uranium dioxide U0 2 then comprise, for example, approximately 50% by volume of depleted uranium dioxide U0 2 and approximately 50% by volume of silicon carbide Sic.
• depleted uranium dioxide designates here an oxide containing 0.25% by volume of uranium 235 for 99.75% by volume of uranium 238.
• the particles of plutonium dioxide Pu0 2 comprise approximately 50% by volume of plutonium dioxide and approximately 50% by volume of silicon carbide Sic.
• the content of fissile nuclei in fuel elements is optimized according to the strategy assigned to the core of the reactor.
• the plutonium content is determined on the basis of the duration chosen for the fuel cycle; the content of depleted uranium is chosen to obtain a satisfactory compromise between the need to obtain high kinetic coefficients (Doppler coefficient and fraction of delayed neutrons) and that of limiting the production of plutonium by the conversion reaction of uranium 238 into plutonium 239.
• thorium can be used in the composition of the assembly. By way of illustration, calculations have been made on the basis of the composition of the fuel elements given previously as an example.
• Table I gives the initial composition in heavy nuclei of a reactor core in accordance with the example considered, as well as the final composition of this core, at the expiration of three 54-month cycles (value given by way of example ) in the core of a fast-spectrum boiling water nuclear reactor.
• the mass values expressed in kilograms, have been calculated on the assumption of a heart having a diameter of 4 meters and a height of 376 cm, which corresponds to a combustible volume of approximately 23 m 3 .
• Table I shows that the use of fuel elements thus constituted, in a boiling water reactor operating in fast spectrum, makes it possible to ensure a high consumption of plutonium, close to 43% of the initial charge in the example considered.
• the only solution used, concerning a water reactor under pressure using 30% MOX fuel is limited to a consumption of about 25% plutonium.
• fissile plutonium and in particular plutonium 241 remains high after three cycles of 54 months (value given by way of example). This makes it possible to envisage an additional reprocessing of plutonium in the case of a multiple recycling strategy.
• FIG. 5 shows the neutron spectrum of a boiling water reactor formed of fuel elements according to the invention, the core of which conforms to Table I.
• FIG. 5 represents the distribution of the neutron flux (ns _1 .cif 2 ) as a function of energy (in electronvolts), in infinite medium, for a vapor presence rate of 40%.
• This spectrum was established using the APOLLO 2 calculation code from the French Atomic Energy Commission. It confirms that the flux of neutrons in the core is essentially a flux of fast neutrons (speed of the order of 40,000 km / s).
• the proportion of the fast flux ⁇ l on the total flux ⁇ is 32.3%
• the proportion of the deceleration flux ⁇ 2 on the total flux ⁇ is 44.3%
• the proportion of the epithermal flux ⁇ 3 on the total flux ⁇ is 22 '
• the proportion of the thermal flux ⁇ 4 on the total flux ⁇ is 1.1%. It is therefore possible to generate a significant number of fissions of uranium 238 and plutonium 240.
• the conversion of uranium 238 to plutonium 239 is reduced, as are the thermal fissions of plutonium 239, which is favorable to obtaining a high delayed neutron fraction in the heart.
• Neutron calculations show that the reactivity coefficient of the new core (in an infinite medium) is around 1.307.
• the power and cycle length values can be adapted by according to needs. In the case of a volume power of 45.8 M per m 3 of core (more fluid fuel), we obtain cycles which are very long and we can arrive at an unloading combustion rate higher than 160 G j / t . This results in the completion of cycles of 54 months, that is to say 4.5 years.
• the Doppler coefficient obtained by the same calculation is of the order of - 2.63 cfm / ° C, which makes it possible to envisage an intrinsically safe behavior of the heart in the event of power excursion resulting in an increase in the fuel temperature.
• the proportion of delayed neutrons is 315 cfm, which allows a good margin of control of the reactor in the event of untimely withdrawal of a control member.
• This favorable phenomenon is accentuated by the fact that the coated fissile particles are dispersed in a silicon carbide matrix having a high resistance to fracturing and a high melting temperature.
• the moderating coefficient is negative and limited over the entire temperature range between 300 ° C. (nominal reactor operating temperature) and 20 ° C.
• this moderating coefficient is equal to - 14.88 at 220 ° C and - 8.16 at 20 ° C.
• each combustible element defines a water passage section Sp and a fuel section Se both equal to 0.0032 m 2 .
• the mass flow of the chosen heat transfer fluid being 750 kg / m 2 . s, this leads to flow rates slightly higher than lm / s, which implies low hydraulic head losses of the water flow in the core.
• the temperature at the center of the fuel is around 400 ° C, taking a linear conduction coefficient of 60 W / m 2. ° C (approximate value for Sic at 400 ° C).
• This relatively small temperature difference between the 295 ° C refrigerant and the fuel favors the management of most accidental transients taken for the sizing of backup systems, for the re-watering of the core in particular.
• the low temperature level compared to the integrity domain of the coated fissile particles and their matrix in Sic suggests that the risks of core melting will be very low.
• the arrangement which has just been described makes it possible to promote an operation of the reactor in natural convection by "ventilating" the core of the reactor, by allowing a large passage section of the flow of water in the core, with speeds d weak flow in the core to obtain low pressure losses.
• the choice of a low recirculation rate (for example, equal to 4) allows high vacuum rates at the top of the core, therefore a great driving force due to the significant density difference between the liquid contained in the water return and the two-phase mixture in the heart.
• the fast spectrum and the two-phase aspect of the heat transfer fluid exclude the use of soluble boron. Of even, the effectiveness of poisons consumable in fuel is limited.
• control member 22 with cross-shaped section, made of absorbent material (B 4 C for example) about 1 cm thick, makes it possible to carry out a return under sub-critical conditions in the most penalizing hypothesis of an infinite medium and a new core, as well as in the liquid water configuration corresponding to the start of the reactor.
• control and reactivity compensation bodies made of materials having an efficiency adapted to needs and having improved resistance to irradiation, such as hafnium diboride HfB 2 or compounds of dysprosium and of boron.
• the complementary control members such as the member 24 in FIG. 1 have, for example, a thickness of approximately 0.5 cm. These organs can be used as complementary stop systems, for piloting, or even for the incineration of actinides or fission products, which play the role of consumable poisons.

Landscapes

• Engineering & Computer Science (AREA)
• Physics & Mathematics (AREA)
• Plasma & Fusion (AREA)
• General Engineering & Computer Science (AREA)
• High Energy & Nuclear Physics (AREA)
• Chemical & Material Sciences (AREA)
• Ceramic Engineering (AREA)
• Dispersion Chemistry (AREA)
• Monitoring And Testing Of Nuclear Reactors (AREA)

Priority Applications (2)

Applications Claiming Priority (2)

Publications (1)

Family

ID=8850260

Family Applications (1)

Country Status (4)

Families Citing this family (7)

Citations (5)

Family Cites Families (18)

• 2000
  • 2000-05-16 FR FR0006204A patent/FR2809225B1/fr not_active Expired - Fee Related
• 2001
  • 2001-05-15 US US10/030,427 patent/US6665366B2/en not_active Expired - Lifetime
  • 2001-05-15 JP JP2001584436A patent/JP5318312B2/ja not_active Expired - Fee Related
  • 2001-05-15 WO PCT/FR2001/001467 patent/WO2001088927A1/fr not_active Ceased

Patent Citations (5)

Also Published As

Similar Documents

Legal Events