WO2001059861A2 - Procede et appareil permettant d'etablir une pression negative a l'interieur d'une enceinte destinee a recevoir un systeme de piles a combustible - Google Patents

Procede et appareil permettant d'etablir une pression negative a l'interieur d'une enceinte destinee a recevoir un systeme de piles a combustible Download PDF

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Publication number
WO2001059861A2
WO2001059861A2 PCT/US2001/004109 US0104109W WO0159861A2 WO 2001059861 A2 WO2001059861 A2 WO 2001059861A2 US 0104109 W US0104109 W US 0104109W WO 0159861 A2 WO0159861 A2 WO 0159861A2
Authority
WO
WIPO (PCT)
Prior art keywords
fuel cell
enclosure
cell system
air
damper
Prior art date
Application number
PCT/US2001/004109
Other languages
English (en)
Other versions
WO2001059861A3 (fr
Inventor
Michael M. Walsh
Robert S. Traver
Russel H. Marvin
George M. Allen
Original Assignee
Plug Power, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23999809&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2001059861(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Plug Power, Inc. filed Critical Plug Power, Inc.
Priority to EP01908986A priority Critical patent/EP1256140B1/fr
Priority to AU2001236785A priority patent/AU2001236785A1/en
Priority to DE60136687T priority patent/DE60136687D1/de
Publication of WO2001059861A2 publication Critical patent/WO2001059861A2/fr
Publication of WO2001059861A3 publication Critical patent/WO2001059861A3/fr

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04104—Regulation of differential pressures
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the invention relates to a method and apparatus for establishing a negative pressure inside an enclosure that houses a fuel cell system.
  • a fuel cell is an electrochemical device that converts chemical energy that is produced by a reaction directly into electrical energy.
  • one type of fuel cell includes a proton exchange membrane (PEM), often called a polymer electrolyte membrane, that permits only protons to pass between an anode and a cathode of the fuel cell.
  • PEM proton exchange membrane
  • diatomic hydrogen a fuel
  • the electrons produced by this reaction travel through circuitry that is external to the fuel cell to form an electrical current.
  • oxygen is reduced and reacts with the hydrogen protons to form water.
  • the fuel cell stack may include plates (graphite composite or metal plates, as examples) that are stacked one on top of the other, and each plate may be associated with more than one fuel cell of the stack.
  • the plates may include various channels and orifices to, as examples, route the reactants and products through the fuel cell stack.
  • PEMs may be dispersed throughout the stack between the anodes and cathodes of the different fuel cells.
  • the fuel cell stack typically is housed in an enclosure that encloses the stack and other components of a fuel cell system.
  • the fuel cell system may leak small amounts of gases, such as hydrogen, for example.
  • gases such as hydrogen, for example.
  • a blower may be located inside the enclosure to establish a positive pressure inside the enclosure to both dilute any stray gases and force the diluted gases outside of the enclosure. Because the stray gases must be diluted to a very small concentration outside of the enclosure, typically the blower must generate a large air flow, an air flow that might freeze compartments of the fuel cell system.
  • a fuel cell system in an embodiment of the invention, includes a fuel cell stack, an enclosure housing the fuel cell stack and a blower that is located inside the enclosure.
  • the blower is adapted to draw air from an interior of the enclosure to produce an air flow through the fuel cell stack and establish a negative pressure inside the enclosure with respect to a region outside of the enclosure.
  • Fig. 1 is a perspective view of a fuel cell system according to an embodiment of the invention.
  • Fig. 2 is a front view of the fuel cell system of Fig. 1 according to an embodiment of the invention.
  • Fig. 3 is a rear view of the fuel cell system of Fig. 1 according to an embodiment of the invention.
  • Fig. 4 is a side view of an air flow hood of the system according to an embodiment of the invention.
  • Fig. 4 A is a top view of a damper flap according to an embodiment of the invention.
  • Fig. 5 illustrates pressure versus air flow curves to illustrate operation of a damper according to an embodiment of the invention.
  • Fig. 6 is a top view of a louver of the fuel cell system according to an embodiment of the invention.
  • Fig. 7 is a cross-sectional view of the louver taken along line 7-7 of Fig. 6.
  • Fig. 8 depicts a cross-sectional view of the louver taken along line 8-8 of Fig. 6.
  • Fig. 8 A depicts a side view of the louver according to an embodiment of the invention.
  • Fig. 9 is a more detailed schematic diagram of the components of the fuel cell system according to an embodiment of the invention.
  • an embodiment 7 of a fuel cell system in accordance with the invention includes an enclosure, or cabinet 11.
  • the cabinet 11 houses components of the fuel cell system 7, such as a blower 20.
  • the blower 20 draws air from an interior region 18 of the cabinet 11 to establish an air flow that supplies oxygen (a reactant) to a fuel cell stack of the system 7.
  • the blower 20 and other components 19 are contained within the interior region 18 of the cabinet 11.
  • a concern is that in some cases, the components 19 may leak a small amount of gas (hydrogen, as an example).
  • Fig. 2 depicts a front view of the fuel cell system 7 with a front panel 14 (see Fig. 1) of the cabinet 11 being removed.
  • the system 7 includes a filter 16 (a high efficiency particulate arresting (HEP A) filter, for example) that is disposed in an opening 17 of the cabinet 11.
  • HEP A high efficiency particulate arresting
  • the cabinet 11 is otherwise sealed from receiving air from outside of the cabinet 11, an arrangement that causes all air that enters the cabinet 11 to flow through the filter 16.
  • the filter 16 may be located in a rear panel 15 (see Fig. 3) of the cabinet 11 and may be located closer to the bottom than the top of the cabinet 11.
  • the system 7 includes an air flow hood 18 that is located inside the cabinet 11 and is sealed to the filter 16 so that all outside air that enters the cabinet 11 passes through the hood 18.
  • the hood 18 directs all incoming air into an upwardly extending conduit 28 that has an opening 29 for releasing the air into the interior region 18.
  • a sealed connection is not formed between an air intake 22 of the blower 20 and the conduit 28, an arrangement that is consistent with the creation of the negative pressure inside the cabinet 11.
  • the air blower 20 may be located near the top of the cabinet 11. During the course of its operation, the blower 20 draws air from the interior region 18 through the air intake 22 and directs the air into an outlet port 23 of the blower 20.
  • the filter 16 introduces a pressure drop, as depicted by a pressure curve 38 of the pressure in the air flow path versus the air flow in Fig. 5. As shown by the curve 38, for a small air flow, the filter 16 may not provide a sufficient pressure drop to sustain an acceptable pressure in the air flow. Thus, for purposes of increasing the pressure drop for a low air flow, the fuel cell system 7 may include a damper to restrict air communication through the opening 29 to increase the pressure of the flow.
  • the damper may include a solid disk-like flap 32 (see also Fig. 4A) that is pivotably mounted (by a hinge 30, such as an elastomer hinge, for example) to the conduit 28 to open and close the opening 29.
  • a hinge 30 such as an elastomer hinge, for example
  • gravity acts on the flap 32 to keep the flap 32 in a horizontal position to close the opening 29.
  • the air flow lifts up the flap 32 and flows through the opening 29, as depicted by the partial open position of the flap 32 in Fig. 4.
  • the weight of the air flap 32 and the moment force that is exerted by the hinge 30 may be taken into account for purposes of calculating the minimum amount of air flow that is need to raise the flap 32.
  • the damper maybe formed from a louver that is secured in place over the opening 29.
  • a louver 40 that is depicted in Fig. 6 may be used in place of the solid flap 32.
  • the louver 40 is secured in place over the opening 29 and includes flaps 42 that open according to the rate of the air flow.
  • the louver 40 may be formed out of an elastomer and thus, each flap 42 may exhibit a variable resistance to the air flow.
  • each flap 42 may be formed by creating two parallel incisions 50 (see Fig. 8) through the louver 40.
  • the incisions 50 are joined by a perpendicular incision 48 (see Fig. 7) through the louver 40, leaving an attached portion to form the flap 42 and forming openings 54 (see Fig. 8A) that increase in size with larger air flows, as depicted in a side view of the flap 42 in Fig. 8 A.
  • the other components 19 of the fuel cell system 7 may include a humidification tank 64 that receives an air flow from the conduit 31 that extends from the outlet port 23 of the air blower 20.
  • the humidification tank 64 also receives a fuel flow from a fuel processor, or reformer 62.
  • the humidification tank 64 produces steam by circulating de-ionized water through a heat source, such as a tail gas oxidizer 112, via the water and steam lines 114. In this manner, the air and fuel flows are combined with the steam inside the tank 64 to produce humidified air and fuel flows that exit the humidification tank 64 via outlet conduits 67 and 65, respectively.
  • the fuel cell system 7 may include water separators 66 and 69 that are coupled to the conduits 67 and 65, respectively, to remove any excess water from the humidified air and fuel flows.
  • the outlet ports of the water separators 66 and 67 are coupled to conduits 68 and 72, respectively, that extend through control valves 74 that regulate the air and fuel flows and provide the flows via conduits 78 and 80 to the fuel cell stack 8.
  • the fuel cell stack 8 includes output terminals 90 that furnish a DC voltage that an inverter 94 uses to produce AC voltages on output terminals 110 of the fuel cell system 7.
  • the fuel cell system 7 may furnish power to a house or an automobile.
  • a current sensor 92 may be coupled in line with one of the output terminals 90 to provide an indication of the output current of the fuel cell stack 8 to a controller 96.
  • the controller 96 may also receive indications of the cell voltages of the fuel cell stack 8 via a cell voltage measuring circuit 97. Based on these parameters, the controller 96 may interact with the reformer 62 to control the fuel flow into the fuel cell stack 8.
  • the tail gas oxidizer 112 receives the exhaust air and fuel flows via outlet conduits 82 and 84, respectively, and oxidizes any remaining gases left in these flows.
  • the system 7 may include a coolant subsystem 100 that circulates a coolant through the fuel cell stack 8, such as de-ionized water, for example.
  • the coolant subsystem 100 may circulate de-ionized water between a water tank 102 and the fuel cell stack 8.
  • the fuel cell system 7 may also include a pump 104 and that pumps deionized water, as needed, into the humidification tank 64.
  • the water separators 66 and 69 include outlet ports that are connected to water lines to carry water from the water separators 66 and 69, respectively to the water tank 102.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

L'invention concerne un système de piles à combustible (7) comprenant un empilement de piles à combustible (8), une enceinte (11) recevant l'empilement de piles à combustible (18) et une soufflerie (20). Celle-ci (20) est située à l'intérieur de l'enceinte (11) et est conçue pour aspirer l'air à partir de l'intérieur de l'enceinte (11) en vue de produire un flux d'air dans l'empilement de piles à combustible (8) et d'établir une pression négative à l'intérieur de l'enceinte (11) par rapport à une région (9) située à l'extérieur de l'enceinte (11).
PCT/US2001/004109 2000-02-11 2001-02-08 Procede et appareil permettant d'etablir une pression negative a l'interieur d'une enceinte destinee a recevoir un systeme de piles a combustible WO2001059861A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP01908986A EP1256140B1 (fr) 2000-02-11 2001-02-08 Procede et appareil permettant d'etablir une pression negative a l'interieur d'une enceinte destinee a recevoir un systeme de piles a combustible
AU2001236785A AU2001236785A1 (en) 2000-02-11 2001-02-08 Method and apparatus for establishing a negative pressure inside an enclosure that houses a fuel cell system
DE60136687T DE60136687D1 (de) 2000-02-11 2001-02-08 Verfahren und einrichtung zur herstellung eines niedrigen druckes innerhalb eines ein brennstoffzellen-system enthaltenden geschlossenen raumes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/502,885 US6610431B1 (en) 2000-02-11 2000-02-11 Method and apparatus for establishing a negative pressure inside an enclosure that houses a fuel cell system
US09/502,885 2000-02-11

Publications (2)

Publication Number Publication Date
WO2001059861A2 true WO2001059861A2 (fr) 2001-08-16
WO2001059861A3 WO2001059861A3 (fr) 2002-03-07

Family

ID=23999809

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/004109 WO2001059861A2 (fr) 2000-02-11 2001-02-08 Procede et appareil permettant d'etablir une pression negative a l'interieur d'une enceinte destinee a recevoir un systeme de piles a combustible

Country Status (6)

Country Link
US (2) US6610431B1 (fr)
EP (1) EP1256140B1 (fr)
AT (1) ATE415717T1 (fr)
AU (1) AU2001236785A1 (fr)
DE (1) DE60136687D1 (fr)
WO (1) WO2001059861A2 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6794070B2 (en) 2001-11-24 2004-09-21 Robert Bosch Gmbh Fuel cell apparatus with compressor means for reducing fuel leakage danger and improving efficiency
EP1463142A2 (fr) * 2003-02-20 2004-09-29 Nissan Motor Co., Ltd. Ventilation controlée d'un système de piles à combustible
WO2004091007A2 (fr) 2003-04-04 2004-10-21 Texaco Development Corporation Appareil convertisseur de combustible integre et enveloppe et procedes d'utilisation associes
WO2004091008A2 (fr) * 2003-04-04 2004-10-21 Texaco Development Corporation Appareil de conversion de combustible portatif et enceinte et procede d'installation correspondant
US7101175B2 (en) 2003-04-04 2006-09-05 Texaco Inc. Anode tailgas oxidizer
WO2023249494A1 (fr) 2022-06-20 2023-12-28 Corvus Energy AS Système de sécurité et de support pour un module de pile à combustible

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DE19910695C1 (de) * 1999-03-10 2000-08-10 Siemens Ag Verfahren zum Betreiben einer Brennstoffzellenanlage und Brennstoffzellenanlage
US7090943B2 (en) * 2003-01-23 2006-08-15 Plug Power Inc. Regulating the communication of power to components of a fuel cell system
US7094486B2 (en) * 2003-05-05 2006-08-22 Delphi Technologies, Inc. Purge system for a fuel cell enclosure
US20090317667A2 (en) * 2004-05-05 2009-12-24 Ansaldo Fuel Cells S.P.A. Differential pressure control method for molten carbonate fuel cell power plants
EP1624516B1 (fr) * 2004-08-02 2012-10-17 Siemens Aktiengesellschaft Méthode de fonctionnement d'une pile a combustible placée dans un logement et dispositif pour mettre en oeuvre le procédé
DE102005030908A1 (de) * 2005-06-30 2007-01-04 Viessmann Werke Gmbh & Co Kg Gerät zur Bereitstellung thermischer und elektrischer Energie
EP1826858A1 (fr) * 2006-02-23 2007-08-29 Siemens Aktiengesellschaft Unité de pile à combustible et une méthode pour le fonctionnement d'un unité de pile à combustible
US7883813B2 (en) * 2006-04-03 2011-02-08 Bloom Energy Corporation Fuel cell system ventilation scheme
US8034500B2 (en) * 2007-05-30 2011-10-11 Idatech, Llc Systems and methods for starting and operating fuel cell systems in subfreezing temperatures
US8521333B2 (en) * 2008-04-17 2013-08-27 Andritz Environmental Solutions Method and apparatus for flue gas recirculation
US9444110B2 (en) * 2009-01-15 2016-09-13 Doosan Fuel Cell America, Inc. System and method for reducing fuel cell power plant emissions

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US4517259A (en) * 1984-03-23 1985-05-14 Westinghouse Electric Corp. Air motor drive for fuel cell power plant air circulator
US5356729A (en) * 1993-06-15 1994-10-18 Aer Energy Resources, Inc. Diffusion controlled air manager for metal-air battery

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CA1312648C (fr) 1988-12-22 1993-01-12 Richard F. Buswell Bloc d'alimentation a pile a combustible
US5178969A (en) 1990-07-06 1993-01-12 Kabushiki Kaisha Toshiba Fuel cell powerplant system
DE69213917T2 (de) 1991-12-24 1997-02-27 Toshiba Kawasaki Kk Kraftwerk mit Brennstoffzellen
US5235846A (en) 1991-12-30 1993-08-17 International Fuel Cells Corporation Fuel cell leakage detection technique
US5314762A (en) * 1992-05-12 1994-05-24 Sanyo Electric Co., Ltd. Portable power source
DE4425186C1 (de) 1994-07-16 1996-03-07 Mtu Friedrichshafen Gmbh Brennstoffzellenanordnung und Verfahren zum Betreiben einer Brennstoffzellenanordnung
EP0813264A3 (fr) * 1996-06-14 2004-02-25 Matsushita Electric Industrial Co., Ltd. Dispositif de piles à combustibles, système d'alimentation en combustible pour pile à combustible et appareil électrique portable
US5851689A (en) * 1997-01-23 1998-12-22 Bechtel Corporation Method for operating a fuel cell assembly
US5980726A (en) * 1998-05-05 1999-11-09 Proton Energy Systems Hydrogen electrochemical system environment
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Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
US4517259A (en) * 1984-03-23 1985-05-14 Westinghouse Electric Corp. Air motor drive for fuel cell power plant air circulator
US5356729A (en) * 1993-06-15 1994-10-18 Aer Energy Resources, Inc. Diffusion controlled air manager for metal-air battery

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6794070B2 (en) 2001-11-24 2004-09-21 Robert Bosch Gmbh Fuel cell apparatus with compressor means for reducing fuel leakage danger and improving efficiency
EP1463142A3 (fr) * 2003-02-20 2005-03-30 Nissan Motor Co., Ltd. Ventilation controlée d'un système de piles à combustible
EP1463142A2 (fr) * 2003-02-20 2004-09-29 Nissan Motor Co., Ltd. Ventilation controlée d'un système de piles à combustible
US7285345B2 (en) 2003-02-20 2007-10-23 Nissan Motor Co., Ltd. Ventilation of fuel cell power plant
WO2004091008A3 (fr) * 2003-04-04 2005-06-09 Texaco Development Corp Appareil de conversion de combustible portatif et enceinte et procede d'installation correspondant
WO2004091007A3 (fr) * 2003-04-04 2005-06-09 Texaco Development Corp Appareil convertisseur de combustible integre et enveloppe et procedes d'utilisation associes
WO2004091008A2 (fr) * 2003-04-04 2004-10-21 Texaco Development Corporation Appareil de conversion de combustible portatif et enceinte et procede d'installation correspondant
US7101175B2 (en) 2003-04-04 2006-09-05 Texaco Inc. Anode tailgas oxidizer
WO2004091007A2 (fr) 2003-04-04 2004-10-21 Texaco Development Corporation Appareil convertisseur de combustible integre et enveloppe et procedes d'utilisation associes
AU2004227786B2 (en) * 2003-04-04 2010-07-29 Texaco Development Corporation Integrated fuel processor apparatus and enclosure and methods of using same
US7829227B2 (en) 2003-04-04 2010-11-09 Texaco Inc. Integrated fuel processor apparatus and enclosure and methods of using same
US7858245B2 (en) 2003-04-04 2010-12-28 Texaco Inc. Methods of using integrated fuel processor apparatus and enclosure
US8211387B2 (en) 2003-04-04 2012-07-03 Texaco Inc. Anode tailgas oxidizer
US8354081B2 (en) 2003-04-04 2013-01-15 Texaco, Inc. Portable fuel processor apparatus and enclosure and method of installing same
WO2023249494A1 (fr) 2022-06-20 2023-12-28 Corvus Energy AS Système de sécurité et de support pour un module de pile à combustible

Also Published As

Publication number Publication date
US6610431B1 (en) 2003-08-26
US20030198855A1 (en) 2003-10-23
EP1256140B1 (fr) 2008-11-26
WO2001059861A3 (fr) 2002-03-07
US6787263B2 (en) 2004-09-07
ATE415717T1 (de) 2008-12-15
AU2001236785A1 (en) 2001-08-20
DE60136687D1 (de) 2009-01-08
EP1256140A2 (fr) 2002-11-13

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