WO2001053360A1 - Process for producing substantially amorphous propylene-based polymers - Google Patents

Process for producing substantially amorphous propylene-based polymers Download PDF

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Publication number
WO2001053360A1
WO2001053360A1 PCT/EP2001/000339 EP0100339W WO0153360A1 WO 2001053360 A1 WO2001053360 A1 WO 2001053360A1 EP 0100339 W EP0100339 W EP 0100339W WO 0153360 A1 WO0153360 A1 WO 0153360A1
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WO
WIPO (PCT)
Prior art keywords
formula
group
methyl
butyl
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2001/000339
Other languages
English (en)
French (fr)
Inventor
Luigi Resconi
Simona Guidotti
Giovanni Baruzzi
Cristiano Grandini
Ilya E. Nifant'ev
Igor A. Kashulin
Pavel V. Ivchenko
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Basell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Technology Co BV filed Critical Basell Technology Co BV
Priority to AU37295/01A priority Critical patent/AU3729501A/en
Priority to JP2001553831A priority patent/JP2003520869A/ja
Priority to US09/936,832 priority patent/US6730754B2/en
Priority to AT01909617T priority patent/ATE292148T1/de
Priority to DE60109680T priority patent/DE60109680T2/de
Priority to BR0105177-6A priority patent/BR0105177A/pt
Priority to EP01909617A priority patent/EP1159310B1/en
Publication of WO2001053360A1 publication Critical patent/WO2001053360A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
PCT/EP2001/000339 2000-01-18 2001-01-12 Process for producing substantially amorphous propylene-based polymers Ceased WO2001053360A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
AU37295/01A AU3729501A (en) 2000-01-18 2001-01-12 Process for producing substantially amorphous propylene-based polymers
JP2001553831A JP2003520869A (ja) 2000-01-18 2001-01-12 実質的に非晶質のプロピレンベースのポリマーの製造方法
US09/936,832 US6730754B2 (en) 2000-01-18 2001-01-12 Process for producing substantially amorphous propylene-based polymers
AT01909617T ATE292148T1 (de) 2000-01-18 2001-01-12 Verfahren zur herstellung von im wesentlichen amorphen polymeren auf propylen-basis
DE60109680T DE60109680T2 (de) 2000-01-18 2001-01-12 Verfahren zur herstellung von im wesentlichen amorphen polymeren auf propylen-basis
BR0105177-6A BR0105177A (pt) 2000-01-18 2001-01-12 Processo para produzir homopolìmeros ou copolìmeros substancialmente amorfos de propileno
EP01909617A EP1159310B1 (en) 2000-01-18 2001-01-12 Process for producing substantially amorphous propylene-based polymers

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP00200193 2000-01-18
EP00200193.1 2000-01-18
EP00202791.0 2000-08-07
EP00202791 2000-08-07

Publications (1)

Publication Number Publication Date
WO2001053360A1 true WO2001053360A1 (en) 2001-07-26

Family

ID=26071752

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2001/000339 Ceased WO2001053360A1 (en) 2000-01-18 2001-01-12 Process for producing substantially amorphous propylene-based polymers

Country Status (11)

Country Link
US (1) US6730754B2 (https=)
EP (2) EP1533324B1 (https=)
JP (1) JP2003520869A (https=)
KR (1) KR100675053B1 (https=)
CN (1) CN100457787C (https=)
AT (2) ATE430753T1 (https=)
AU (1) AU3729501A (https=)
BR (1) BR0105177A (https=)
DE (2) DE60109680T2 (https=)
ES (2) ES2239665T3 (https=)
WO (1) WO2001053360A1 (https=)

Cited By (29)

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WO2003024982A1 (de) * 2001-09-14 2003-03-27 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe mit einem kondensierten heterocyclus
US6559251B1 (en) 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins
WO2003078480A3 (en) * 2002-03-14 2003-11-27 Dow Global Technologies Inc Polycyclic, fused heteroring compounds, metal complexes and polymerization process
US6683150B1 (en) 2002-12-19 2004-01-27 Equistar Chemicals, Lp High molecular weight polypropylene process
WO2004013194A2 (en) 2002-08-02 2004-02-12 Equistar Chemicals, Lp Catalysts and process for making polyolefins
US6693155B1 (en) 2003-03-05 2004-02-17 Equistar Chemicals, Lp Propylene polymerization process
US6759361B2 (en) 2001-06-04 2004-07-06 Equistar Chemicals, Lp Aluminoboronate activators for single-site olefin polymerization catalysts
US6794468B1 (en) 2003-05-12 2004-09-21 Equistar Chemicals, Lp Olefin polymerization process
US6818713B1 (en) 2003-08-11 2004-11-16 Equistar Chemicals, Lp Process for making polyethylene
US6841500B2 (en) 2002-12-03 2005-01-11 Equistar Chemicals, Lp Bimetallic indenoindolyl catalysts
WO2005026221A1 (en) 2003-09-09 2005-03-24 Equistar Chemicals, Lp Hydrosilane additives for increased polyolefin molecular weight
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
US6933353B2 (en) 2003-07-07 2005-08-23 Equistar Chemicals, Lp Olefin polymerization process
US6958377B2 (en) 2003-10-15 2005-10-25 Equistar Chemicals, Lp Olefin polymerization process
US6967231B1 (en) 2004-09-23 2005-11-22 Equistar Chemicals, Lp Olefin polymerization process
US6987196B2 (en) 2001-04-10 2006-01-17 Basell Polyolefine Gmbh Process for the production of monohalide or dihalide metallocene compounds
US6995220B2 (en) 2004-04-29 2006-02-07 Equistar Chemicals, Lp Ethylene polymerization process
US6998451B2 (en) 2003-07-01 2006-02-14 Equistar Chemicals, Lp Olefin polymerization process
US7141690B2 (en) 2002-02-08 2006-11-28 Sumitomo Chemical Company, Limited Transition metal complexes, ligands, polymerization catalysts for olefins, and process for production of olefin polymers
US7196147B2 (en) 2005-07-01 2007-03-27 Equistar Chemicals, Lp Olefin polymerization process with improved operability and polymer properties
US7230056B2 (en) 2005-07-01 2007-06-12 Equistar Chemicals, Lp Catalyst preparation method
US7365137B2 (en) 2001-07-17 2008-04-29 Basell Polyolefine Gmbh Multistep process for the (co) polymerization of olefins
US7423098B2 (en) 2006-01-17 2008-09-09 Equistar Chemicals, Lp Polyethylene process
US7638586B2 (en) 2006-09-26 2009-12-29 Equistar Chemicals, Lp Olefin polymerization process
US7638584B2 (en) 2006-06-20 2009-12-29 Equistar Chemicals, Lp Olefin polymerization process
US7816478B2 (en) 2008-09-03 2010-10-19 Equistar Chemicals, Lp Polyethylene thick film and process for preparing polyethylene
US7829641B2 (en) 2008-07-16 2010-11-09 Equistar Chemicals, Lp Process for the preparation of multimodal polyethylene resins
US7834112B2 (en) 2001-09-14 2010-11-16 Basell Polyolefine Gmbh Method of polymerization of olefins
EP3524612A4 (en) * 2017-09-25 2019-12-18 LG Chem, Ltd. LIGAND CONNECTION, TRANSITION METAL CONNECTION AND CATALYST COMPOSITION WITH THE TRANSITION METAL CONNECTION

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CA2363628A1 (en) 1999-02-22 2000-08-31 James Allen Ponasik Jr. Catalysts containing n-pyrrolyl substituted nitrogen donors
US7271209B2 (en) 2002-08-12 2007-09-18 Exxonmobil Chemical Patents Inc. Fibers and nonwovens from plasticized polyolefin compositions
CN100345896C (zh) 2002-08-12 2007-10-31 埃克森美孚化学专利公司 增塑聚烯烃组合物
US8003725B2 (en) 2002-08-12 2011-08-23 Exxonmobil Chemical Patents Inc. Plasticized hetero-phase polyolefin blends
US7662885B2 (en) 2002-08-12 2010-02-16 Exxonmobil Chemical Patents Inc. Method to make an article comprising polymer concentrate
US7998579B2 (en) 2002-08-12 2011-08-16 Exxonmobil Chemical Patents Inc. Polypropylene based fibers and nonwovens
US7531594B2 (en) 2002-08-12 2009-05-12 Exxonmobil Chemical Patents Inc. Articles from plasticized polyolefin compositions
DE10303225A1 (de) * 2003-01-28 2004-08-05 Inventis Technologies Gmbh Katalysatorkombination, isotaktische Polymere sowie ein Verfahren zur Herstellung von linearen isotaktischen Polymeren und dessen Verwendung
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US7589145B2 (en) * 2004-04-15 2009-09-15 Exxonmobil Chemical Patents Inc. Syndiotactic rich polyolefins
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US8389615B2 (en) 2004-12-17 2013-03-05 Exxonmobil Chemical Patents Inc. Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin
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US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
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US9428598B2 (en) 2014-02-07 2016-08-30 Eastman Chemical Company Amorphous propylene-ethylene copolymers
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US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
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KR101719064B1 (ko) 2014-11-13 2017-03-22 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR101910701B1 (ko) * 2015-07-02 2018-10-22 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR102584264B1 (ko) * 2017-06-28 2023-10-05 주식회사 엘지화학 신규한 리간드 화합물 및 이를 포함하는 전이금속 화합물
KR102531558B1 (ko) * 2017-06-28 2023-05-15 주식회사 엘지화학 리간드 화합물 및 전이금속 화합물의 제조방법
KR102328690B1 (ko) * 2017-07-27 2021-11-18 주식회사 엘지화학 신규한 전이금속 화합물 및 이를 제조하는 방법
US11225495B2 (en) 2017-07-27 2022-01-18 Lg Chem, Ltd. Transition metal compound and method for preparing the same
KR102259746B1 (ko) * 2017-12-26 2021-06-02 주식회사 엘지화학 올레핀계 중합체
JP7071016B2 (ja) 2018-05-04 2022-05-18 エルジー・ケム・リミテッド エチレン／アルファ－オレフィン共重合体及びその製造方法
WO2019212304A1 (ko) * 2018-05-04 2019-11-07 주식회사 엘지화학 에틸렌/알파-올레핀 공중합체 및 이의 제조방법
EP3715389B1 (en) 2018-05-04 2023-05-17 Lg Chem, Ltd. Adhesive composition including ethylene/alpha-olefin copolymer
KR102601720B1 (ko) * 2018-09-07 2023-11-14 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
JP7423332B2 (ja) * 2019-03-29 2024-01-29 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒、およびオレフィン重合体の製造方法
JP7308644B2 (ja) * 2019-03-29 2023-07-14 三井化学株式会社 オレフィン・環状オレフィン共重合体の製造方法
CN116212948B (zh) * 2023-02-14 2024-07-09 四川九天五洋新材料有限责任公司 一种丙烯气相环氧化成型催化剂及其制备方法

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DE60138657D1 (de) 2009-06-18
KR20010112350A (ko) 2001-12-20
JP2003520869A (ja) 2003-07-08
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ES2239665T3 (es) 2005-10-01
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ATE430753T1 (de) 2009-05-15
EP1533324A3 (en) 2006-06-07
CN1372571A (zh) 2002-10-02
AU3729501A (en) 2001-07-31
BR0105177A (pt) 2002-01-15
CN100457787C (zh) 2009-02-04
ATE292148T1 (de) 2005-04-15
DE60109680D1 (de) 2005-05-04
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EP1159310B1 (en) 2005-03-30
US20020147286A1 (en) 2002-10-10

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