WO2004013194A3 - Catalysts and process for making polyolefins - Google Patents
Catalysts and process for making polyolefins Download PDFInfo
- Publication number
- WO2004013194A3 WO2004013194A3 PCT/US2003/021540 US0321540W WO2004013194A3 WO 2004013194 A3 WO2004013194 A3 WO 2004013194A3 US 0321540 W US0321540 W US 0321540W WO 2004013194 A3 WO2004013194 A3 WO 2004013194A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- supported
- catalysts
- ethylene copolymers
- indolyl
- open architecture
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03766850A EP1525228A2 (en) | 2002-08-02 | 2003-07-10 | Catalysts and process for making polyolefins |
AU2003248919A AU2003248919A1 (en) | 2002-08-02 | 2003-07-10 | Catalysts and process for making polyolefins |
JP2004526037A JP4829498B2 (en) | 2002-08-02 | 2003-07-10 | Catalyst and process for the production of polyolefins |
BR0313308-7A BR0313308A (en) | 2002-08-02 | 2003-07-10 | Catalysts and processes for producing olefins |
CA2494611A CA2494611C (en) | 2002-08-02 | 2003-07-10 | Catalyst comprising bridged indeno[1,2-b]indolyl metal complex |
MXPA05001075A MXPA05001075A (en) | 2002-08-02 | 2003-07-10 | Catalysts and process for making polyolefins. |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/211,085 | 2002-08-02 | ||
US10/211,085 US6559251B1 (en) | 2002-08-02 | 2002-08-02 | Process for making low-density polyolefins |
US10/382,233 US6838410B2 (en) | 2002-08-02 | 2003-03-05 | Catalysts for making polyolefins |
US10/382,233 | 2003-03-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2004013194A2 WO2004013194A2 (en) | 2004-02-12 |
WO2004013194A3 true WO2004013194A3 (en) | 2004-07-15 |
Family
ID=31498031
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2003/021540 WO2004013194A2 (en) | 2002-08-02 | 2003-07-10 | Catalysts and process for making polyolefins |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP1525228A2 (en) |
KR (1) | KR20050034728A (en) |
CN (1) | CN100429240C (en) |
AU (1) | AU2003248919A1 (en) |
BR (1) | BR0313308A (en) |
CA (1) | CA2494611C (en) |
MX (1) | MXPA05001075A (en) |
WO (1) | WO2004013194A2 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6818713B1 (en) * | 2003-08-11 | 2004-11-16 | Equistar Chemicals, Lp | Process for making polyethylene |
US7276567B2 (en) | 2004-04-16 | 2007-10-02 | Exxonmobil Chemical Patents Inc. | Heterocyclic substituted metallocene compounds for olefin polymerization |
US6995220B2 (en) * | 2004-04-29 | 2006-02-07 | Equistar Chemicals, Lp | Ethylene polymerization process |
US7273914B2 (en) * | 2005-08-03 | 2007-09-25 | Equistar Chemicals, Lp | Olefin polymerization methods |
US7868197B2 (en) | 2005-12-14 | 2011-01-11 | Exxonmobil Chemical Patents Inc. | Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization |
US7429635B2 (en) | 2006-09-28 | 2008-09-30 | Equistar Chemicals, Lp | Preparation of ultra high molecular weight linear low density polyethylene |
US7812104B2 (en) | 2008-01-18 | 2010-10-12 | Exxonmobil Chemical Patents Inc. | Production of propylene-based polymers |
CA2760264C (en) | 2011-12-05 | 2018-08-21 | Nova Chemicals Corporation | Passivated supports for use with olefin polymerization catalysts |
CN112920227B (en) * | 2021-02-18 | 2022-09-23 | 山东京博石油化工有限公司 | Indenoindole structure-containing metallocene compound, preparation method and application thereof, and preparation method of alpha-olefin |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6239062B1 (en) * | 1999-09-02 | 2001-05-29 | Equistar Chemicals, L.P. | Olefin polymerization catalysts containing indolyl-amido ligands |
WO2001053360A1 (en) * | 2000-01-18 | 2001-07-26 | Basell Technology Company B.V. | Process for producing substantially amorphous propylene-based polymers |
US6559251B1 (en) * | 2002-08-02 | 2003-05-06 | Equistar Chemicals, Lp | Process for making low-density polyolefins |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5495035A (en) | 1994-06-01 | 1996-02-27 | University Of Iowa Research Foundation | Synthesis of ANSA-metallocene catalysts |
ES2190131T3 (en) | 1997-11-12 | 2003-07-16 | Basell Polyolefine Gmbh | METALOCENES AND CATALYSTS FOR POLYMERIZATION OF OLEFINS. |
US6232260B1 (en) | 1999-10-14 | 2001-05-15 | Equistar Chemicals, L.P. | Single-site catalysts for olefin polymerization |
-
2003
- 2003-07-10 EP EP03766850A patent/EP1525228A2/en not_active Withdrawn
- 2003-07-10 WO PCT/US2003/021540 patent/WO2004013194A2/en active Application Filing
- 2003-07-10 MX MXPA05001075A patent/MXPA05001075A/en active IP Right Grant
- 2003-07-10 BR BR0313308-7A patent/BR0313308A/en not_active IP Right Cessation
- 2003-07-10 CN CNB038185245A patent/CN100429240C/en not_active Expired - Fee Related
- 2003-07-10 KR KR1020057001862A patent/KR20050034728A/en not_active Application Discontinuation
- 2003-07-10 AU AU2003248919A patent/AU2003248919A1/en not_active Abandoned
- 2003-07-10 CA CA2494611A patent/CA2494611C/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6239062B1 (en) * | 1999-09-02 | 2001-05-29 | Equistar Chemicals, L.P. | Olefin polymerization catalysts containing indolyl-amido ligands |
WO2001053360A1 (en) * | 2000-01-18 | 2001-07-26 | Basell Technology Company B.V. | Process for producing substantially amorphous propylene-based polymers |
US6559251B1 (en) * | 2002-08-02 | 2003-05-06 | Equistar Chemicals, Lp | Process for making low-density polyolefins |
Also Published As
Publication number | Publication date |
---|---|
MXPA05001075A (en) | 2005-06-06 |
WO2004013194A2 (en) | 2004-02-12 |
BR0313308A (en) | 2005-07-12 |
EP1525228A2 (en) | 2005-04-27 |
AU2003248919A1 (en) | 2004-02-23 |
KR20050034728A (en) | 2005-04-14 |
CN100429240C (en) | 2008-10-29 |
CA2494611C (en) | 2012-01-24 |
CA2494611A1 (en) | 2004-02-12 |
CN1681848A (en) | 2005-10-12 |
AU2003248919A8 (en) | 2004-02-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AU7119800A (en) | Preparation of ultra-high-molecular-weight polyethylene | |
MXPA00006074A (en) | Nickel diimine catalysts with methylalumoxane as cocatalyst, method of polymerization of olefins therewith and polymers produced. | |
CA2480399A1 (en) | Method for polymerisation of olefins with indeno-indolyl catalysts | |
CA2316165A1 (en) | Homopolymers and copolymers of ethylene | |
DK0790259T3 (en) | Supported metallocene alumina catalysts for the production of polyethylene with a wide monomodal molecular weight distribution | |
AU3766400A (en) | Olefin polymerization with fatty amine additives | |
NO985694L (en) | Preparation of stereoregular polymers | |
EP1561762A4 (en) | Process for producing propylene/ethylene block copolymer and propylene/ethylene block copolymer | |
EP3020738A3 (en) | Catalyst and catalyst component thereof | |
TW200613347A (en) | Supported metallocene catalyst, method of preparing the catalyst and method of preparing polyolefin using the catalyst | |
DE50005332D1 (en) | CATALYST SYSTEM | |
HUT75187A (en) | Supported olefin polymerization catalyst, its preparation and process for producing polyethylene | |
NO952217L (en) | Ethylene selective metallocenes with high activity | |
EP1123938A3 (en) | Organometallic fluorenyl compounds, preparation, and use | |
WO2004013194A3 (en) | Catalysts and process for making polyolefins | |
EP1518868A3 (en) | An ethylene copolymer and a film made therefrom | |
EP1632505A4 (en) | Ethylene polymer | |
EP2463315A3 (en) | Process for preparing a multimodal polyolefin employing a Ziegler-Natta catalyst | |
CA2152552A1 (en) | Process for preparing cycloolefin copolymers | |
DE60029399D1 (en) | COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINES | |
TW428001B (en) | Catalysts for the polymerization of alpha-olefins | |
KR970065563A (en) | Aluminum compound-containing solid catalyst component, catalyst for olefin polymerization and preparation method of olefin polymer | |
EP0887355A4 (en) | Process for preparing olefin polymers | |
MY143540A (en) | Supported polymerization catalysts | |
AU7540700A (en) | Modified supported catalysts for the polymerization of olefins |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A2 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NI NO NZ OM PG PH PL PT RO RU SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG UZ VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A2 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: PA/a/2005/001075 Country of ref document: MX |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2004526037 Country of ref document: JP Ref document number: 1020057001862 Country of ref document: KR Ref document number: 20038185245 Country of ref document: CN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2494611 Country of ref document: CA Ref document number: 2003766850 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 1020057001862 Country of ref document: KR |
|
WWP | Wipo information: published in national office |
Ref document number: 2003766850 Country of ref document: EP |