KR970065563A - Aluminum compound-containing solid catalyst component, catalyst for olefin polymerization and preparation method of olefin polymer - Google Patents

Aluminum compound-containing solid catalyst component, catalyst for olefin polymerization and preparation method of olefin polymer Download PDF

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KR970065563A
KR970065563A KR1019970008898A KR19970008898A KR970065563A KR 970065563 A KR970065563 A KR 970065563A KR 1019970008898 A KR1019970008898 A KR 1019970008898A KR 19970008898 A KR19970008898 A KR 19970008898A KR 970065563 A KR970065563 A KR 970065563A
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compound
containing solid
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transition metal
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신이치 구마모토
히로아키 가타야마
아키오 이마이
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고사이 아키오
스미토모가가쿠고교 가부시키가이샤
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    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

담체를 오가노알루미늄옥시 화합물과 접촉시킨 다음 친전자성 그룹을 보유하는 화합물과 접촉시켜 수득한 알루미늄 화합물 함유 고체 촉매 성분, 알루미늄 화합물 함유 고체 촉매 성분을 전이 금속 화합물과 접촉시켜 수득한 전이 금속 함유 고체 촉매 성분, 알루미늄 화합물 함유 고체 촉매 성분과 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매 및 올레핀 중합용 촉매를 사용하여 올레핀을 중합시키거나 공중합시킴을 포함하는 올레핀 중합체의 제조방법.A transition metal-containing solid obtained by contacting a carrier with an organoaluminumoxy compound and then contacting the aluminum compound-containing solid catalyst component and the aluminum compound-containing solid catalyst component with the transition metal compound A method for producing an olefin polymer comprising polymerizing or copolymerizing an olefin using a catalyst component, an olefin polymerization catalyst comprising an aluminum compound-containing solid catalyst component and an organoaluminum compound, and an olefin polymerization catalyst.

Description

알루미늄 화합물 함유 고체 촉매 성분, 올레핀 중합용 촉매 및 올레핀 중합체의 제조 방법Aluminum compound-containing solid catalyst component, catalyst for olefin polymerization and preparation method of olefin polymer

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (19)

담체를 오가노알루미늄옥시 화합물과 접촉시킨 다음 친전자성 그룹을 보유하는화합물과 접촉시켜 수득한 알루미늄 화합물 함유 고체 촉매 성분.An aluminum compound containing solid catalyst component obtained by contacting a carrier with an organoaluminumoxy compound followed by contact with a compound having an electrophilic group. 제1항에 있어서, 친전자성 그룹을 보유하는 화합물이 또한 극성 작용성 그룹을 보유하는 알루미늄 화합물함유 고체 촉배 성분.The aluminum compound-containing solid catalyst component according to claim 1, wherein the compound having an electrophilic group also has a polar functional group. 제1항에 있어서, 친전자자성 그룹을 보유하는 화합물이 할로겐화 페놀인 알루미늄 화합물 함유 고체 촉매 성분.The aluminum catalyst-containing solid catalyst component according to claim 1, wherein the compound having an electrophilic group is a halogenated phenol. 제1항에 따르는 알루미늄 화합물 함유 고체 촉매 성분을 전이 금속 화합물과 접촉시켜 수득한 전이 금속 함유 고체 촉매 성분.A transition metal-containing solid catalyst component obtained by contacting the aluminum compound-containing solid catalyst component according to claim 1 with a transition metal compound. 제2항에 따르는 알루미늄 화합물 함유 고체 촉매 성분을 전이 금속 화합물과 접촉시켜 수득한 전이 금속 함유 고체 촉매 성분.A transition metal-containing solid catalyst component obtained by contacting the aluminum compound-containing solid catalyst component according to claim 2 with a transition metal compound. 제3항에 따르는 알루미늄 화합물 함유 고체 촉매 성분을 전이 금속 화합물과 접촉시켜 수득한 전이 금속 함유 고체 촉매 성분.A transition metal-containing solid catalyst component obtained by contacting the aluminum compound-containing solid catalyst component according to claim 3 with a transition metal compound. 제4항에 있어서, 전이 금속 화합물이 메탈로센 전이 금속 화합물인 전이 금속 함유 고체 촉매 성분.The transition metal-containing solid catalyst component according to claim 4, wherein the transition metal compound is a metallocene transition metal compound. 제1항에 따르는 알루미늄 화합물 함유 고체 촉매 성분, 전이 금속 화합물 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.A catalyst for olefin polymerization comprising the aluminum compound-containing solid catalyst component according to claim 1, a transition metal compound and an organoaluminum compound. 제2항에 따르는 알루미늄 화합물 함유 고체 촉매 성분, 전이 금속 화합물 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.A catalyst for olefin polymerization comprising the aluminum compound-containing solid catalyst component according to claim 2, a transition metal compound and an organoaluminum compound. 제3항에 따르는 알루미늄 화합물 함유 고체 촉매 성분, 전이 금속 화합물 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.A catalyst for olefin polymerization comprising the aluminum compound-containing solid catalyst component according to claim 3, a transition metal compound and an organoaluminum compound. 제4항에 따르는 전이 금속 함유 고체 촉매 성분 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.A catalyst for olefin polymerization comprising the transition metal-containing solid catalyst component according to claim 4 and an organoaluminum compound. 제5항에 따르는 전이 금속 함유 고체 촉매 성분 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.A catalyst for olefin polymerization comprising the transition metal-containing solid catalyst component according to claim 5 and an organoaluminum compound. 제6항에 따르는 전이 금속 함유 고체 촉매 성분 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.A catalyst for olefin polymerization comprising the transition metal-containing solid catalyst component according to claim 6 and an organoaluminum compound. 제7항에 따르는 올레핀 중합용 촉매를 사용하여 올레핀을 중합시킴을 포함하여, 올레핀 중합체를 제조하는 방법.A process for preparing an olefin polymer, comprising polymerizing olefins using the catalyst for olefin polymerization according to claim 7. 제8항에 따르는 올레핀 중합용 촉매를 사용하여 올레핀을 중합시킴을 포함하여, 올레핀 중합체를 제조하는 방법.A process for preparing an olefin polymer, comprising polymerizing olefins using the catalyst for olefin polymerization according to claim 8. 제9항에 따르는 올레핀 중합용 촉매를 사용하여 올레핀을 중합시킴을 포함하여, 올레핀 중합체를 제조하는 방법.A process for preparing an olefin polymer, comprising polymerizing olefins using the catalyst for olefin polymerization according to claim 9. 제14항에 있어서, 올페핀 중합체가 에틸렌/α-올레핀 공중합체인 방법.The method of claim 14, wherein the olfepin polymer is an ethylene / α-olefin copolymer. 제15항에 있어서, 올페핀 중합체가 에틸렌/α-올레핀 공중합체인 방법.The method of claim 15, wherein the olfepin polymer is an ethylene / α-olefin copolymer. 제16항에 있어서, 올페핀 중합체가 에틸렌/α-올레핀 공중합체인 방법.The method of claim 16, wherein the olfepin polymer is an ethylene / α-olefin copolymer. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019970008898A 1996-03-19 1997-03-17 Aluminum compound-containing solid catalyst component, catalyst for olefin polymerization and method for proucing olefin polymer KR100473441B1 (en)

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DK0685494T3 (en) * 1994-06-03 1999-02-15 Pcd Polymere Ag Catalyst supports, supported metallocene catalysts and their use in the production of polyolefins

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CN1097063C (en) 2002-12-25
DE19711304B4 (en) 2009-01-08
CN1168387A (en) 1997-12-24
DE19711304A1 (en) 1997-10-30
JP3959132B2 (en) 2007-08-15
JPH09249707A (en) 1997-09-22
SG83662A1 (en) 2001-10-16
US6100213A (en) 2000-08-08
KR100473441B1 (en) 2005-07-18
US6333388B1 (en) 2001-12-25

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