KR970065563A - 알루미늄 화합물 함유 고체 촉매 성분, 올레핀 중합용 촉매 및 올레핀 중합체의 제조방법 - Google Patents

알루미늄 화합물 함유 고체 촉매 성분, 올레핀 중합용 촉매 및 올레핀 중합체의 제조방법 Download PDF

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KR970065563A
KR970065563A KR1019970008898A KR19970008898A KR970065563A KR 970065563 A KR970065563 A KR 970065563A KR 1019970008898 A KR1019970008898 A KR 1019970008898A KR 19970008898 A KR19970008898 A KR 19970008898A KR 970065563 A KR970065563 A KR 970065563A
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compound
containing solid
catalyst component
solid catalyst
transition metal
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KR100473441B1 (ko
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신이치 구마모토
히로아키 가타야마
아키오 이마이
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고사이 아키오
스미토모가가쿠고교 가부시키가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

담체를 오가노알루미늄옥시 화합물과 접촉시킨 다음 친전자성 그룹을 보유하는 화합물과 접촉시켜 수득한 알루미늄 화합물 함유 고체 촉매 성분, 알루미늄 화합물 함유 고체 촉매 성분을 전이 금속 화합물과 접촉시켜 수득한 전이 금속 함유 고체 촉매 성분, 알루미늄 화합물 함유 고체 촉매 성분과 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매 및 올레핀 중합용 촉매를 사용하여 올레핀을 중합시키거나 공중합시킴을 포함하는 올레핀 중합체의 제조방법.

Description

알루미늄 화합물 함유 고체 촉매 성분, 올레핀 중합용 촉매 및 올레핀 중합체의 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 담체를 오가노알루미늄옥시 화합물과 접촉시킨 다음 친전자성 그룹을 보유하는화합물과 접촉시켜 수득한 알루미늄 화합물 함유 고체 촉매 성분.
  2. 제1항에 있어서, 친전자성 그룹을 보유하는 화합물이 또한 극성 작용성 그룹을 보유하는 알루미늄 화합물함유 고체 촉배 성분.
  3. 제1항에 있어서, 친전자자성 그룹을 보유하는 화합물이 할로겐화 페놀인 알루미늄 화합물 함유 고체 촉매 성분.
  4. 제1항에 따르는 알루미늄 화합물 함유 고체 촉매 성분을 전이 금속 화합물과 접촉시켜 수득한 전이 금속 함유 고체 촉매 성분.
  5. 제2항에 따르는 알루미늄 화합물 함유 고체 촉매 성분을 전이 금속 화합물과 접촉시켜 수득한 전이 금속 함유 고체 촉매 성분.
  6. 제3항에 따르는 알루미늄 화합물 함유 고체 촉매 성분을 전이 금속 화합물과 접촉시켜 수득한 전이 금속 함유 고체 촉매 성분.
  7. 제4항에 있어서, 전이 금속 화합물이 메탈로센 전이 금속 화합물인 전이 금속 함유 고체 촉매 성분.
  8. 제1항에 따르는 알루미늄 화합물 함유 고체 촉매 성분, 전이 금속 화합물 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.
  9. 제2항에 따르는 알루미늄 화합물 함유 고체 촉매 성분, 전이 금속 화합물 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.
  10. 제3항에 따르는 알루미늄 화합물 함유 고체 촉매 성분, 전이 금속 화합물 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.
  11. 제4항에 따르는 전이 금속 함유 고체 촉매 성분 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.
  12. 제5항에 따르는 전이 금속 함유 고체 촉매 성분 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.
  13. 제6항에 따르는 전이 금속 함유 고체 촉매 성분 및 오가노알루미늄 화합물을 포함하는 올레핀 중합용 촉매.
  14. 제7항에 따르는 올레핀 중합용 촉매를 사용하여 올레핀을 중합시킴을 포함하여, 올레핀 중합체를 제조하는 방법.
  15. 제8항에 따르는 올레핀 중합용 촉매를 사용하여 올레핀을 중합시킴을 포함하여, 올레핀 중합체를 제조하는 방법.
  16. 제9항에 따르는 올레핀 중합용 촉매를 사용하여 올레핀을 중합시킴을 포함하여, 올레핀 중합체를 제조하는 방법.
  17. 제14항에 있어서, 올페핀 중합체가 에틸렌/α-올레핀 공중합체인 방법.
  18. 제15항에 있어서, 올페핀 중합체가 에틸렌/α-올레핀 공중합체인 방법.
  19. 제16항에 있어서, 올페핀 중합체가 에틸렌/α-올레핀 공중합체인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970008898A 1996-03-19 1997-03-17 알루미늄화합물함유고체촉매성분,올레핀중합용촉매및올레핀중합체의제조방법 KR100473441B1 (ko)

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JP96-062610 1996-03-19
JP06261096A JP3959132B2 (ja) 1996-03-19 1996-03-19 アルミニウム化合物含有固体触媒成分、オレフィン重合用触媒及びオレフィン重合体の製造方法

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KR100473441B1 KR100473441B1 (ko) 2005-07-18

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US (2) US6100213A (ko)
JP (1) JP3959132B2 (ko)
KR (1) KR100473441B1 (ko)
CN (1) CN1097063C (ko)
DE (1) DE19711304B4 (ko)
SG (1) SG83662A1 (ko)

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DE59503827D1 (de) * 1994-06-03 1998-11-12 Pcd Polymere Ag Katalysatorträger, geträgerte Metallocenkatalysatoren und deren Verwendung für die Herstellung von Polyolefinen

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JP3959132B2 (ja) 2007-08-15
US6100213A (en) 2000-08-08
CN1097063C (zh) 2002-12-25
DE19711304A1 (de) 1997-10-30
JPH09249707A (ja) 1997-09-22
US6333388B1 (en) 2001-12-25
SG83662A1 (en) 2001-10-16
CN1168387A (zh) 1997-12-24
KR100473441B1 (ko) 2005-07-18
DE19711304B4 (de) 2009-01-08

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