WO2000064233A1 - Procede et appareil d'enrobage d'un objet par un gel - Google Patents
Procede et appareil d'enrobage d'un objet par un gel Download PDFInfo
- Publication number
- WO2000064233A1 WO2000064233A1 PCT/JP1999/002203 JP9902203W WO0064233A1 WO 2000064233 A1 WO2000064233 A1 WO 2000064233A1 JP 9902203 W JP9902203 W JP 9902203W WO 0064233 A1 WO0064233 A1 WO 0064233A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mold
- gelling agent
- gel
- agent
- gel coating
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
- A01C1/06—Coating or dressing seed
Definitions
- the present invention provides a method and an apparatus for coating a seed, or a cell having a germination / rooting ability, which has a growth ability, with a gelling agent. And a gel coating method.
- a coating in which an inclusion such as seeds or cell debris is coated with an elastic polymer gel containing a nutrient substance or a drug hereinafter, the inclusion is referred to as “seed”, and the coating is referred to as “coated seed”).
- seed an inclusion such as seeds or cell debris
- coated seed means not only seed but also any object having a growth ability, such as a cell piece having germination and rooting properties.
- the coated seeds are effective in protecting the seeds from animal damage and disinfecting the seeds.
- the seeds can be easily handled and sowing work can be performed more efficiently. It has many advantages, including the ability to improve the germination rate by absorbing nutrients in the gel.
- typical methods for automatically producing the coated seed include a double cylinder nozzle method and a molding method.
- the double cylindrical nozzle method will be described with reference to FIG.
- the inside of the gel containing section 3 of the gel containing block 2 to which the gelling agent is supplied from the gelling agent tank (not shown) is lightly pressurized by an air cylinder (not shown), and the passage 4 of the gel containing section 3 and the passage
- the cylindrical plunger 6 movably mounted in the nozzle block 1 is moved up and down.
- the plunger 6 is moved upward against the elastic force of the coil spring 7 disposed at the upper end, the valve 8 is slightly opened, and the gelling agent is discharged to the lower end of the valve 8 to form a thin film of the gelling agent. .
- the seed 9 is thrown into the passage 6 a of the plunger 6 to After the gel 9 is held on the thin film, the inside of the gel housing portion 3 is further pressurized to increase the internal pressure of the space 5, and the valve 8 is greatly opened to discharge a large amount of the gelling agent.
- the agent wraps the seeds 9 together with the film to form the granular gel-coated seeds 9a
- the gel-coated seeds 9a are moved by their own weight to a lower hardening tank (not shown) where the hardener is used. Fall.
- the gel portion of the gel-coated seed 9a is hardened while being transported in the hardening tank, and the hardener is washed off in the water washing section to obtain a product.
- the mold method is a method in which the seed is put into a mold having a spherical inner surface, and at the same time, a gelling agent and a hardening agent are filled, and after the gel is cured, the gel-coated seed is removed from the mold.
- a thin film of the gelling agent is not provided to support the seed on the thin film, so that it is not necessary to increase the viscosity of the gelling agent to enhance the supporting force.
- the viscosity can be freely set to a high degree of germination efficiency.
- the seeds cannot be coated in a spherical shape due to poor release of the gelling agent, and in the worst case, the gel-coated seeds that have been subjected to gel coating do not come off from the mold. Further, each time the gel coating process is performed, it is necessary to remove the hardening agent or the gelling agent attached to the mold, so that the work efficiency is low. Disclosure of the invention
- the present invention is a gel coating processing method which is an improvement of the above-mentioned molding method, and comprises a gelling agent.
- the gelling agent and the encapsulant are poured into a mold that has both impermeable or gelling agent impermeability and curing agent permeability, and the mold is immersed in the curing agent to cure the entire mold.
- the gelling agent By allowing the gelling agent to permeate and uniformly harden the gelling agent around the enclosure from the contact portion with the mold, the enclosure can be easily detached from the mold as a gel coating. Since this method does not support the inclusions with a thin film of a gelling agent, the gel coating process can be performed reliably even with heavy or weakly germinating inclusions.
- the curing of the gelling agent proceeds sequentially from the contact area with the mold, the uncured gelling agent does not adhere to the inner surface of the mold, and the mold release of the gel coating is reduced by the conventional molding method. As a result, the gelling agent can be remarkably improved, and the residual gelling agent in the mold can be suppressed.
- the mold is preliminarily immersed in a curing agent and taken out before injecting the gelling agent and the inclusion, so that the curing agent is retained in the mold, and the gelling agent and the mold are separated. Since a thin hardened layer of the gelling agent is formed in advance at the contact portion, the mold release of the gel coating can be further improved.
- the mold used in the above method has an inner surface comprising a hemispherical part projecting downward and a cylindrical part standing upright on the hemispherical part, and having a total depth from the upper end of the cylindrical part to the lower end of the hemispherical part.
- the diameter is equal to or larger than the diameter of the hemispherical portion, so that the gel coating can be reliably made spherical.
- a mold made of an elastic body is used as the mold, and the gel coating material inside the mold is extruded into a curing agent by pressing and deforming from the lower part of the mold, and then the mold is restored to its original shape.
- the mold release of the gel coating can be performed more rapidly by mechanical extrusion.
- the thickness of the hardened layer formed in advance in response to the hardener held in the mold is determined by the radius of the hemispherical portion that constitutes the lower part of the mold and protrudes downward. 20% or less. For this reason, the spheroidization of the gel coating proceeds due to surface tension while floating in the curing agent, so that the spheroidization of the gel coating is more complete. Everything can be done.
- the present invention provides a gel coating apparatus suitable for using the above-mentioned gel coating method. That is, the gel coating apparatus according to the present invention comprises: a mold having both a gelling agent impermeability or a gelling agent impermeability and a curing agent permeability; A gelling agent supply means for discharging an amount of the gelling agent used in the filling material into the mold; and a curing agent installed below the gelling agent supply means and the filling material supply means.
- a means for collecting the gel covering material to be taken out of the curing tank wherein the mold in which the gelling agent and the filling material are injected by the filling material supplying means and the gelling material supplying means is immersed in the mold.
- the mold in which the gelling agent and the filling material are injected by the filling material supplying means and the gelling material supplying means is immersed in the mold.
- the gelling agent and the filling material are injected into the mold by means of the filling material supply means and the gelling material supply means, respectively, and the mold is immersed in the curing tank by the mold immersion means and removed.
- the gelling agent in the mold is uniformly cured from the contact area with the mold by the curing agent that has penetrated the entire mold, so that the gel-coated enclosure is easily separated from the mold,
- the gel coating is collected by the gel coating collecting means. Since this device does not have a structure in which the inclusion is supported by a thin film of the gelling agent, the gel coating process can be performed reliably even with a heavy inclusion or an inclusion having a weak germination property.
- the uncured gelling agent does not adhere to the inner surface of the mold, and the releasability of the gel coating is significantly improved, Of the gelling agent can also be suppressed.
- the gel-coated material collecting means includes two pulleys arranged in front and rear, a belt wound around the pulley, and a plurality of paddles standing outside the belt.
- the paddle moves in the curing tank integrally with the belt by rotating the pulley to generate a circulating flow, and transfers the gel coating floating on the liquid surface and the gel coating transferred to the end. They are scooped and discharged outside.
- This configuration creates a circulating flow that transports the floating gel coating and discharges the cured gel coating.
- the manufacturing cost can be reduced by reducing the number of devices and the space can be saved.
- the mold immersion means includes: an upper plenum disposed near the surface of the curing agent liquid in the curing tank in the vicinity of the gelling agent supply means and the enclosure supply means; And a lower belt disposed deeply in the curing agent, and a molded belt wound around the upper pulley and the lower pulley.
- FIG. 1 is a perspective view of a main part of a gel coating apparatus according to the present invention, showing a gel coating processing method according to the present invention.
- FIG. 2 is a gel coating processing in a main part of the gel coating processing apparatus.
- Explanatory diagram showing the procedure a) is an explanatory diagram showing the situation where the mold was previously immersed in the hardener, b) is an explanatory diagram showing the situation where the seed and the gelling agent were injected into the mold, and c) is an explanatory diagram showing the situation.
- Fig. 3 is an explanatory view showing a situation in which the curing agent has penetrated into the mold.
- Fig. 3 is an explanatory view showing a situation in which the gel-coated seed has detached from the mold.
- FIG. 3 is a side sectional view of the mold
- Fig. 4 is FIG. 5 is a side cross-sectional view showing a schematic configuration of a first embodiment of a gel coating apparatus according to the present invention
- FIG. 7 is a partial cross-sectional side view showing a schematic configuration of the second embodiment.
- FIG. 7 shows a conventional structure employing a double cylindrical nozzle method.
- FIG. 3 is a partial side sectional view of a main part of the gel coating device.
- the hardened outermost surface is separated from the inner wall of the mold 27.
- the detached gel-coated seeds 9a are formed into particles by the action of surface tension and, due to the low specific gravity of the gel portion, float on the surface of the hardener 26 by buoyancy as shown in d) in FIG. .
- the gel coating method according to the present invention is an application of the molding method, and is based on the thin film of the gelling agent 30 as in the double cylindrical nozzle method using the apparatus shown in FIG.
- the application range of the weight of the seeds 9 and the viscosity of the gelling agent 30 can be greatly expanded, and the hardening agent 26 penetrates from the entire mold 27 to the inside.
- the gelling agent 30 is hardened in order from the contact portion with the mold 27, the mold release of the gel-coated seed 9a is significantly improved as compared with the conventional molding method, and the inner surface of the mold 27 is improved. It is also possible to prevent the gelling agent 30 from remaining on the surface.
- the inner surface shape of the mold 27 is not particularly limited, as shown in FIG. 3, a hemispherical portion 27 d protruding downward, and a cylindrical portion standing on the hemispherical portion 27 d
- the entire depth 33 from the upper end of the cylindrical portion 27c to the lower end of the hemispherical portion 27d be at least twice the radius 32 of the hemispherical portion, that is, at least the diameter. .
- the soft gel-coated seeds 9 a which are hardened during curing, protrude from the upper end of the mold 27, and the protruding portion is easily deformed due to resistance such as liquid flow, Furthermore, the amount of gelling agent 30 required for spheroidization could not be secured. It is.
- the permeability of the gelling agent 30 in the mold 27 needs to be impermeable or poorly permeable, but this is because the gelling agent 30 injected into the mold 27 leaks out. This is to prevent it. Even in the case of poor permeability, it takes more than 1 second for the permeation of the mold 27 in anticipation of the time from the supply of the gelling agent 30 into the mold 27 to the immersion in the curing agent 26. It is preferable. If the time is shorter than this, the gelling agent 30 supplied into the mold 27 before dipping in the curing tank 18 may leak.
- the mold 27 be easily deformed when pressed from below, so that the gel-coated seed 9a inside is extruded from the mold 27, and is an elastic body having an elasticity that can be immediately restored to the original form. Thereby, a mechanical pushing force can be applied to the buoyancy, and the mold releasability can be further improved.
- the thickness 34 of the hardened layer 31 of the gelling agent 30 formed by reacting with 6 is limited to 20% or less of the radius 32.
- the hardening agent 26 does not undergo spheroidization due to the surface tension during suspension, and the inner shape of the mold 27 does not change.
- the curing of the gel portion is completed as it is, and as a result, spherical gel-coated seeds 9a cannot be obtained.
- the raw materials and additives of the curing agent 26 are selected.
- the concentration of the curing agent 26 is set, and the immersion time in the curing agent 26 until the gel-coated seeds 9a are finally removed from the curing tank 18 is set.
- the thickness 34 is suppressed to 20% or less of the radius 32 in the hemispherical portion 27 d of the mold 27.
- Examples of such a material having gelling agent impermeability or gelling agent impermeability, elasticity, and permeability and retention of a hardening agent include cloth such as nonwoven fabric, paper, sponge, and the like. There is a pore material such as a wire mesh or a porous resin, metal, or ceramic. The material is not particularly limited, and any material having the above characteristics may be used. A material having shape memory properties other than the above properties is effective.For example, using a shape memory alloy whose shape changes with temperature change in the mold 27, instead of pressing and deforming, the bath in the hardening tank 18 is used.
- the gel coating apparatus is composed of a mold 2, an enclosure supply means 11, a gelling agent supply means 12, a mold immersion means 10, a curing tank 18, and a gel coating material recovery means 13. .
- the enclosure supply means 11 is detachably attached to a seed hopper 28 containing a large number of enclosures such as seeds 9 and an arm (not shown) rotatably supported in a horizontal plane.
- the suction tip 29 includes a suction tip 29 and the like.
- the suction tip 29 is configured to be able to reciprocate horizontally above the seed hopper 28 and the mold 27 at the injection position 38.
- the gelling agent supply means 12 includes a gelling agent tank (not shown), a tube extending from the gelling agent tank, and a supply nozzle 35 connected to the end of the tube.
- the supply nozzle 35 is configured to reciprocate horizontally above the mold 27.
- the mold immersion means 10 is composed of a swing arm 36 connected to a mold 27 and the like.
- the swing arm 36 is provided with an actuator (not shown) under the liquid level of the curing tank 18 and the curing.
- Tank not shown
- the gel-coated material collecting means 13 includes two pulleys 19 and 20 arranged in front and rear, a belt 24 wound between the pulleys 19 and 20, and an outside of the belt 24. It consists of paddles 25, 25 and 25 '.
- An intermediate plate 18a is provided horizontally at a certain height from 18b, so as to stabilize the circulating flow 37.
- the middle plate 18a is used as a member for pushing up the bottom of the mold 27 immersed in the curing agent 26 by the mold immersion means 10. May be used.
- the gel coating is performed in the following procedure.
- Capping process can be performed. First, when the mold 27 is at the injection position 38, the supply nozzle 35 moves to the upper side of the mold 27, injects the gelling agent 30 into the mold 27, and supplies from above the mold 27. When the nozzle 35 returns to the home position, the suction tip 29 that sucks and adsorbs the seed 9 in the seed hopper 28 is moved in reverse. Then, when the suction tip 29 returns to the home position, the supply nozzle 35 moves up again to the mold 27 and injects the gelling agent 30 into the mold 27.
- the mold 27 into which the gelling agent 30 and the seed 9 have been injected is lowered by the swing arm 36 and immersed in the curing agent 26 to cure the gel. Accordingly, the mold 27 can be pressed against the upper surface of the middle plate 18a to promote the release of the gel-coated seed 9a.
- the mold 27 returns to the pouring position.
- the gel-coated seed 9a generated by repeating the above procedure rides on the circulating flow 37 generated by the paddle 25, and while being guided by the paddle 25, spheroidization and hardening also proceed to reach the end.
- the gel-coated seed 9a is transferred out of the curing tank 18.
- the gel coating apparatus is composed of an enclosure supply means 15, a gelling agent supply means 16, a mold immersion means 14 containing a mold 27, a curing tank 18, and a gel coating material recovery means 17. ing.
- the enclosure supply means 15 includes a seed hopper 28 containing a large number of enclosures such as seeds 9 and an unillustrated arm rotatably supported in a horizontal plane.
- the suction tip 29 is detachably attached to the lower surface of the seed hopper.
- the suction tip 29 is capable of horizontally reciprocating above the seed hopper 28 and the standby position 40. It is configured to be able to swing up and down between and the seed injection position 41 below.
- the gelling agent supply means 16 is composed of a gelling agent tank (not shown), a tube, and a preliminary supply nozzle 42a and a main supply nozzle 42b connected to the end of the tube.
- the preliminary supply nozzle 4 2a is disposed at a preliminary injection position 4 3 in front of the seed injection position 4 1, and the main supply nozzle 4 2 b is disposed at a main injection position 4 4 behind the seed injection position 4 1. I have.
- the mold immersion means 14 uses the curing agent in the curing tank 18 near each injection position 41, 43, 44. 26, an upper pulley 21 disposed in the vicinity of the liquid surface, a hardener separated from the upper pulley 21 and a lower pulley 22 disposed deep in the liquid surface, and a lower pulley 22 A mold belt 23 wound around the upper pulley 21 and embedded with a mold 27 having an opening facing outward.
- the gel coating material collecting means 17 includes a rotating body 17 a disposed on the liquid surface at the rear of the curing tank 18, and a plurality of blades implanted on the outer periphery of the rotating body 17 a. 17 b ⁇ 17 b ⁇ ⁇ etc., so that the gel-coated seed 9 a detached from the mold 27 can be scraped out of the curing tank 18.
- the gel coating device having such a configuration can perform the gel coating process in the following procedure.
- the molded belt 23 is constantly driven and rotated by driving the upper and lower pulleys 21 and 22.
- the gelling agent 30 is injected into the mold 27 by the preliminary supply nozzle 42a, and thereafter, when the mold 27 comes to the seed injection position 41.
- the suction tip 29 sucking and adsorbing the seed 9 in the seed hopper 28 descends from the standby position 40 to the seed injection position 41, and throws the seed 9 into the mold 27.
- the gelling agent 30 is injected again into the mold 27 by the main supply nozzle 42b.
- the mold 27 into which the gelling agent 30 and the seeds 9 are injected gradually settles in the hardening agent 26 as the mold belt 23 rotates, and the gel hardens in the hardening agent 26.
- the gel-coated seed 9a released from the mold 27 floats in the hardener 36 by buoyancy.
- the gel-coated seeds 9a generated by repeating the above procedure ride on the flow generated by the rotation of the mold belt 23, and are hardened while being hardened. It is transported. Therefore, the present embodiment is suitable for mass production because gel coating can be performed continuously, and the size, shape, and shape of the sealed object are adjusted by adjusting the rotation speed of the mold belt 23.
- the curing conditions can be optimized according to the viscosity of the gelling agent.
- a plurality of mold belts 23 each including the mold 27 of the first embodiment or the mold 27 of the second embodiment are arranged in the left-right direction, and the supply means of the filling material and the supply of the gelling agent are correspondingly provided.
- the gel coating method and the apparatus thereof according to the present invention as described above can be applied to any material having a growth ability, such as seeds or cell fragments having germination and rooting properties, as an inclusion.
- This method is applied to a method and an apparatus that can surely perform gel coating processing on an enclosure having such a weight or an enclosure having any germinability.
- a spherical gel coating having excellent mold release properties can be obtained, and a gel coating method and apparatus can be provided in which the amount of the gelling agent remaining in the mold is small.
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- Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Environmental Sciences (AREA)
- Pretreatment Of Seeds And Plants (AREA)
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP1999/002203 WO2000064233A1 (fr) | 1999-04-23 | 1999-04-23 | Procede et appareil d'enrobage d'un objet par un gel |
US09/959,369 US6572809B1 (en) | 1999-04-23 | 1999-04-23 | Gel coating method and apparatus |
EP99919521A EP1181856B1 (en) | 1999-04-23 | 1999-04-23 | Gel coating method and apparatus |
JP2000613238A JP4332831B2 (ja) | 1999-04-23 | 1999-04-23 | ゲル被覆加工方法およびその装置 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP1999/002203 WO2000064233A1 (fr) | 1999-04-23 | 1999-04-23 | Procede et appareil d'enrobage d'un objet par un gel |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000064233A1 true WO2000064233A1 (fr) | 2000-11-02 |
Family
ID=14235562
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1999/002203 WO2000064233A1 (fr) | 1999-04-23 | 1999-04-23 | Procede et appareil d'enrobage d'un objet par un gel |
Country Status (4)
Country | Link |
---|---|
US (1) | US6572809B1 (ja) |
EP (1) | EP1181856B1 (ja) |
JP (1) | JP4332831B2 (ja) |
WO (1) | WO2000064233A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007178287A (ja) * | 2005-12-28 | 2007-07-12 | Seiko Instruments Inc | 薄切片作製装置 |
US20110239535A1 (en) * | 2010-04-01 | 2011-10-06 | Ball Horticultural Company | Cast pellets for planting seeds |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10524427B2 (en) | 2004-02-13 | 2020-01-07 | Klondike Agricultural Products, LLC | Agricultural systems and methods |
CN101894904B (zh) * | 2010-07-15 | 2011-12-28 | 电子科技大学 | 一种金属基薄膜热电偶及其生产方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US4808430A (en) | 1987-02-27 | 1989-02-28 | Yazaki Corporation | Method of applying gel coating to plant seeds |
JPH02128611A (ja) * | 1988-11-08 | 1990-05-17 | Yazaki Corp | 種子のゲル被覆装置 |
JPH09149710A (ja) * | 1995-11-29 | 1997-06-10 | Yazaki Corp | 種子のゲル被覆加工方法及びその装置 |
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US3533812A (en) * | 1961-11-07 | 1970-10-13 | Interpace Corp | Process for the manufacture of ceramic articles,and product derived from such process |
USRE32476E (en) * | 1970-12-21 | 1987-08-18 | Minnesota Mining And Manufacturing Company | Consolidation of aggregate material |
US4203936A (en) * | 1976-12-27 | 1980-05-20 | The Bendix Corporation | Water slurry process for manufacturing phenolic resin bonded friction materials |
US4422990A (en) * | 1982-04-01 | 1983-12-27 | Castle & Cooke Techniculture, Inc. | Method and apparatus for making soil plugs |
US4779376A (en) * | 1983-10-25 | 1988-10-25 | Plant Genetics, Inc. | Delivery system for seeds |
US4780987A (en) * | 1983-10-25 | 1988-11-01 | Plant Genetics, Inc. | Method for the preparation of hydrated, pregerminated seeds in gel capsules |
JPS61273298A (ja) * | 1985-05-28 | 1986-12-03 | Nippon Kokan Kk <Nkk> | 粉体の成形方法 |
GB2187995B (en) * | 1986-01-22 | 1989-11-01 | Honda Motor Co Ltd | Process for producing cylindrical reinforcing fibrous molding |
GB2189596B (en) * | 1986-04-16 | 1990-08-01 | Pa Consulting Services | Methods of and apparatus for preparing tissue specimens |
US4931241A (en) * | 1987-08-06 | 1990-06-05 | Ltv Aerospace And Defense Company | Method for producing structures by isostatic compression |
US4806357A (en) * | 1987-11-25 | 1989-02-21 | The Regents Of The University Of California | Apparatus and method for encapsulating seeds and the like |
JP3125847B2 (ja) * | 1995-06-15 | 2001-01-22 | 矢崎総業株式会社 | ゲル被覆種子のゲル層易崩壊処理方法 |
JP3125848B2 (ja) * | 1995-07-14 | 2001-01-22 | 矢崎総業株式会社 | ゲル被覆種子の保存方法 |
JP3095119B2 (ja) * | 1995-11-29 | 2000-10-03 | 矢崎総業株式会社 | 被覆種子の硬化装置 |
JP3125854B2 (ja) * | 1995-12-13 | 2001-01-22 | 矢崎総業株式会社 | 種子のゲル被覆加工装置における加工部 |
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1999
- 1999-04-23 EP EP99919521A patent/EP1181856B1/en not_active Expired - Lifetime
- 1999-04-23 JP JP2000613238A patent/JP4332831B2/ja not_active Expired - Fee Related
- 1999-04-23 WO PCT/JP1999/002203 patent/WO2000064233A1/ja active Application Filing
- 1999-04-23 US US09/959,369 patent/US6572809B1/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4808430A (en) | 1987-02-27 | 1989-02-28 | Yazaki Corporation | Method of applying gel coating to plant seeds |
JPH02128611A (ja) * | 1988-11-08 | 1990-05-17 | Yazaki Corp | 種子のゲル被覆装置 |
JPH09149710A (ja) * | 1995-11-29 | 1997-06-10 | Yazaki Corp | 種子のゲル被覆加工方法及びその装置 |
Non-Patent Citations (1)
Title |
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See also references of EP1181856A4 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007178287A (ja) * | 2005-12-28 | 2007-07-12 | Seiko Instruments Inc | 薄切片作製装置 |
US20110239535A1 (en) * | 2010-04-01 | 2011-10-06 | Ball Horticultural Company | Cast pellets for planting seeds |
US10798869B2 (en) * | 2010-04-01 | 2020-10-13 | Ball Horticultural Company | Cast pellets for planting seeds |
US11399455B1 (en) | 2010-04-01 | 2022-08-02 | Ball Horticultural Company | Cast pellets for planting seeds |
Also Published As
Publication number | Publication date |
---|---|
US6572809B1 (en) | 2003-06-03 |
JP4332831B2 (ja) | 2009-09-16 |
EP1181856A1 (en) | 2002-02-27 |
EP1181856B1 (en) | 2011-12-14 |
EP1181856A4 (en) | 2007-05-02 |
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