WO2000059305A1 - Composition microbiocide - Google Patents

Composition microbiocide Download PDF

Info

Publication number
WO2000059305A1
WO2000059305A1 PCT/EP2000/002823 EP0002823W WO0059305A1 WO 2000059305 A1 WO2000059305 A1 WO 2000059305A1 EP 0002823 W EP0002823 W EP 0002823W WO 0059305 A1 WO0059305 A1 WO 0059305A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
formulation
composition
microbiocidal
active ingredients
Prior art date
Application number
PCT/EP2000/002823
Other languages
German (de)
English (en)
Inventor
Wolfgang Lindner
Original Assignee
Troy Chemie Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Troy Chemie Gmbh filed Critical Troy Chemie Gmbh
Priority to DE10080787T priority Critical patent/DE10080787D2/de
Priority to AU43967/00A priority patent/AU4396700A/en
Publication of WO2000059305A1 publication Critical patent/WO2000059305A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P1/00—Disinfectants; Antimicrobial compounds or mixtures thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A01N43/52—1,3-Diazoles; Hydrogenated 1,3-diazoles condensed with carbocyclic rings, e.g. benzimidazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P13/00—Herbicides; Algicides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P3/00—Fungicides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2401/00—Form of the coating product, e.g. solution, water dispersion, powders or the like
    • B05D2401/20—Aqueous dispersion or solution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface

Definitions

  • the present invention relates to a special microbiocidal composition, its production and use for coating, inter alia, mineral substrates as well as wood and textiles.
  • the composition contains at least one active ingredient from four groups of different synergistic fungicides and algicides. It is particularly suitable for long-term avoidance of graying and discoloration of coatings, e.g. Facade painting.
  • Exterior wall and roof coatings that are exposed to the weather and light quickly change color due to dust and vegetation, e.g. Mold, yeast, algae and lichens.
  • the growth with fungi can also affect the coating in its physical properties, e.g. Change adhesive strength, elasticity etc.
  • the changes described are the result of a complex surface process in which physical and microbiological effects interact.
  • microorganisms, fungi and algae prefer to settle and grow on soiled facade coatings, or that coatings colonized by algae and fungi quickly turn gray mechanically due to dust build-up.
  • the tendency to soiling has been reduced by modifying the coating materials.
  • the binders can be chosen so that the stickiness after film formation is very low.
  • the tendency to discolouration can also be favorably influenced by the choice of fillers and pigments as well as the theological additives. Particular attention has been paid to the adjustment of the water balance within such coating compositions. A quick drying after wetting prevents dust adherence as well as fungus and algae growth. Replacing reinforcement fibers made of cellulose with those made of synthetic materials such as nylon or polyester can also make the coating more stable.
  • microbiocidal substances can delay discoloration and graying.
  • Such substances are said to be easy to handle in a coating-producing factory, typically a paint factory.
  • they are said to have little or no effect on the physical properties of the coating compositions.
  • fungicidal and algicidal active ingredients in the form of aqueous dispersions are therefore used as additives in order to avoid the introduction of solvents.
  • MERGAL S 90 PASTE from Troy Chemie consists of 2-methoxycarbonylaminobenzimidazole (BCM), 2-n-octylisothiazolin-3-one (OITZ) and 2-methylthio-4-cyclopropylamino-6-tertiarybutylamino-l, 3,5- triazine (Mctt).
  • JP-A 110 35 409 describes algicidal and fungicidal compositions comprising triazine and benzimidazole derivatives. These compositions can be used, for example, for circulating water systems, emulsion paints, solvent paints or plastic products made of PVP.
  • DE-A 197 05 085 describes exterior paints with a mixture consisting of a pyrithione derivative and an algicidally active triazine and optionally a benzimidazole or thiophene derivative, that is to say a combination of two or three classes of compounds having a microbiocidal action, for preventing fouling, in particular by fungi Alternaria genus.
  • the object of the invention was therefore to provide a microbiocidal composition, in particular for use in coating compositions such as emulsion paints, synthetic resin plasters, silicone resin paints, silicone resin plasters, mineral paints and plasters, pigmented wood coatings based on alkyd resin, which have improved resistance to graying and discoloration due to physico-chemical and exhibit biological processes and thereby get an extended service life.
  • coating compositions such as emulsion paints, synthetic resin plasters, silicone resin paints, silicone resin plasters, mineral paints and plasters, pigmented wood coatings based on alkyd resin, which have improved resistance to graying and discoloration due to physico-chemical and exhibit biological processes and thereby get an extended service life.
  • coating compositions such as emulsion paints, synthetic resin plasters, silicone resin paints, silicone resin plasters, mineral paints and plasters, pigmented wood coatings based on alkyd resin, which have improved resistance to graying and discoloration due to physico-chemical and
  • compositions, formulations and coatings according to the invention which, in addition to the customary auxiliaries, e.g. Fillers, binders from the range of acrylates or styrene-acrylates or silicone resins, titanium dioxide pigments, conventional additives to improve the physical properties, contain a combination of at least four active substances from four different classes of substances, which are described below, and protect or discolour them against discolouration and graying. are protected.
  • the combination according to the invention of the at least four active substances from different substance classes can be provided in a formulation which can be used as an additive in coating materials and does not require any organic solvents and is itself solvent-free.
  • the present invention thus relates to a microbiocidal composition
  • a microbiocidal composition comprising in each case at least one active ingredient selected from groups a), b), c) and d):
  • Rl and R2 represent alkyl groups
  • Rl, R2 alkyl groups preferably methyl
  • R5 H chlorine, bromine, fluorine or alkyl
  • R3, R4 represent H, chlorine, bromine, alkyl, trifluoromethyl or O-alyl, where aryl can be substituted, to call.
  • the above-mentioned active substances of group d) include in particular the following triazine derivatives with favorable physical properties, i.e. properties favorable for preservation, e.g. low water solubility and low vapor pressure:
  • Mctt 2-Methylthio-4-cyclopropylamino-6-tertiarybutylamino-l, 3,5-triazine (Mctt), or a mixture of two or more thereof, especially Mctt and / or Terbutryn.
  • N ', N'-dialkylurea derivatives of the formula II as active ingredients d) are the following compounds with favorable physical properties:
  • compositions according to the invention preferably contain the active ingredients a) to d) in the following proportions by weight: a) 1 - 20% by weight, more preferably 3 - 12% by weight, b) 0.5 - 5% by weight, more preferably 1 - 3% by weight, c) 1 - 15% by weight %, more preferably 3 - 10% by weight, d) 1 - 30% by weight, more preferably 4 - 15% by weight,
  • the present invention also relates to a microbicidal formulation, preferably a coating composition, with a content of the composition according to the invention of 0.001 to 2% by weight, preferably 0.01 to 1% by weight, in each case based on the total amount of the microbicidal agents Formulation.
  • the formulation according to the invention can be prepared using conventional methods known to those skilled in the art. It is no different from the production of conventional formulations.
  • the composition according to the invention is added during production as an additional additive.
  • the formulation comprises fillers, inert components, solvents and auxiliaries.
  • the facade and roof coating materials consist of
  • Water a synthetic resin dispersion and / or a silicone resin as a binder, titanium dioxide of the rutile type as a pigment, commercially available fillers such as calcium carbonate, chalk, Polyacrylate-based dispersants,
  • Cellulose-based thickeners e.g., xanthan gums, layered silicates, commercially available defoamers, pH regulators, e.g. Ammonia, aliphatic amines, sodium hydroxide solution, potassium hydroxide solution.
  • pH regulators e.g. Ammonia, aliphatic amines, sodium hydroxide solution, potassium hydroxide solution.
  • the coating compositions can be formulated in a manner known per se.
  • the ingredients are mixed, solid active ingredients being finely ground in water in the presence of the formulation auxiliaries to form a premix and then stirred into the liquid active ingredients.
  • other solvents can be included.
  • Aromatic petrol, xylene, trimethylbenzene are particularly suitable for non-polar systems; Ketones such as Acetone, cyclohexanone, isophorone, methyl isobutyl ketone; Ethers and glycol ethers such as e.g. Diisopropyl ether, dimethoxyethane, diethylene glycol dimethyl ether, triethylene glycol dimethyl ether, esters such as ethyl acetate, butyl acetate; Glycols, their mono- and diethers or their mono- or diesters.
  • additives can be included, such as defoamers, dispersants, emulsifiers, dyes, pigments, film-forming aids, thickeners, rheology modifiers, plasticizers, etc.
  • quaternary ammonium salts such as e.g. Didecyldimethylammonium chloride
  • Thiocyanate compounds such as 2-thiocyanatomethylthiobenzothiazole, Carbamates such as iodopropynyl butyl carbamate,
  • Isothiazolinone derivatives which are different from the substances according to b), e.g. 5-chloro-2-methylisothiazolinone / 2-methylisothiazolinone
  • Triazole fungicides e.g. Tebuconazole, propiconazole
  • Imidazole fungicides e.g. Prochloraz, Imazalil
  • Aldehydes e.g. Formaldehyde or its depot compounds
  • Nitriles e.g. Tetrachlorophthalonitrile inorganic oxides such as e.g. Zinc oxide.
  • the present invention also relates to the use of the formulation according to the invention for the microbicidal finishing of coating compositions, in particular paints, paints or plasters, in particular facade coating compositions, roof tile coating compositions, emulsion paints, synthetic resin plasters, silicone resin paints, silicone resin plasters, mineral paints, mineral plasters and pigmented wood paints based on alkyd resins.
  • coating compositions in particular paints, paints or plasters, in particular facade coating compositions, roof tile coating compositions, emulsion paints, synthetic resin plasters, silicone resin paints, silicone resin plasters, mineral paints, mineral plasters and pigmented wood paints based on alkyd resins.
  • composition or formulation according to the invention can also be used advantageously in sealants and other technical coatings.
  • coatings which have the composition according to the invention or are provided with specified active compound mixtures are not covered with vegetation even in regions and resist the discoloration in which finishing with the microbicides customary today is ineffective.
  • the coatings according to the invention are notable in particular for their high resistance to growth due to a broad spectrum of
  • Algae such as green algae e.g. of the following types:
  • Chlamydomonas Chlorella, Chlorococcum, Microspora, Platymonas, Pleurococcus, Scenedesmus, Stichococcus, Trentepohlia and Ulothrix;
  • Blue-green algae such as:
  • Yellow-green algae e.g. Tribonema
  • Bacteria such as Escherichia coli
  • Yeasts such as Rhodotorula spec.
  • Mushrooms such as:
  • the present invention relates to the use of the composition or formulation described above to avoid the graying and discoloration of coatings, in particular exterior paints.
  • composition or formulation according to the invention represents a significant advance over the prior art because it can be easily prepared in user-friendly, solvent-free formulations, is stable in the coating compositions, does not cause discoloration and is therefore easy to use as an additive.
  • the compositions or formulations according to the invention also allow a reduction in the economic outlay, in particular to the extent that the concentrations of the individual active compounds are lower than in the previously known “two or three combinations”.
  • the renovation cycles of the facades provided with the coating agents used according to the invention are also extended This makes a significant contribution to protecting the environment and reducing energy consumption, and coatings on full thermal insulation systems (ETICS) according to the invention are particularly advantageous.
  • the color was produced in a Netzsch dissolver in a manner known from the prior art. For this purpose, water was initially introduced and then the thickeners and other components were introduced and dispersed in the order given in Table 1.
  • Sample 1 each represents a formulation without microbicidal active ingredients.
  • Samples 2 and 3 are formulations according to the invention, all other formulations are comparative samples.
  • Ms Mucor spec.
  • Aa96820 Altemaria altemata (wild site strain - 96820)
  • the color samples thus obtained were each coated at 300 g / m 2 on round filter papers (No. 597 from Schleicher & Schüll, diameter 5.5 cm) and then dried at a temperature of 30 ° C. for 72 hours.
  • test specimens coated with paint were watered with tap water for 72 and 144 hours.
  • the leaching water was changed every 24 hours.
  • the growth resistance against algae was tested on solid Bold algae nutrient media. After double-sided sterilization under UV light, the dry test specimens were placed on the culture media in petri dishes. In each case 5 ml of a well-grown algae culture in Bold nutrient solution was inoculated onto the surface to be tested under sterile conditions, so that the color surface was pale green. After a incubation period of 14 days at a temperature of 29 ° C, the degree of fouling with algae on the paint coats was assessed visually on a scale from 0 to 4:
  • Synthetic resin plaster fouling test against algae in a laboratory test (VdL method 05)
  • the dispersion plaster was prepared analogously to the preparation according to Example 1.
  • the respective sample 1 corresponds to a formulation according to the invention and the other samples correspond to comparison samples.
  • Mctt was always used as triazine in the sample according to the invention and in comparison samples 2 and 4, while comparison samples 3 and 5 contained terbutryn as triazine.
  • Synthetic resin plasters fouling test against fungi, especially Altemaria altemata in a laboratory test (VdL method 06).
  • test specimens were exposed on calcium silicate carriers in a warm, humid climate, irrigated and exposed to extremely high algae concentrations.
  • a flora of bacteria, fungi and algae developed in the chamber.
  • Algae solutions from Chlorella fusca, Stichococcus bacillaris, Trentepholia odorata were inoculated.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

Composition microbiocide qui comporte au moins un principe actif choisi dans les groupes (a) à (d). Le groupe (a) comprend 2-méthoxycarbonylaminobenzimidazol ou thiabendazol, le groupe (b) comprend octylisothiazolin-3-one ou 3-iodpropinoxy-N-butylcarbamate, le groupe (c) comprend 2-mercaptopyridine-N-oxyde-sel de zinc, et le groupe (d) comprend un dérivé de N-aryl-N',N'-diméthylurée ou un dérivé de triazine exempt de chlore tiré de la classe des 2-méthylmercapto-dialkylamino-sym-triazines. La présente invention concerne également des revêtements qui contiennent ladite composition.
PCT/EP2000/002823 1999-04-01 2000-03-30 Composition microbiocide WO2000059305A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE10080787T DE10080787D2 (de) 1999-04-01 2000-03-30 Mikrobiozide Zusammensetzung
AU43967/00A AU4396700A (en) 1999-04-01 2000-03-30 Microbicidal composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19915055.9 1999-04-01
DE19915055 1999-04-01

Publications (1)

Publication Number Publication Date
WO2000059305A1 true WO2000059305A1 (fr) 2000-10-12

Family

ID=7903370

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2000/002823 WO2000059305A1 (fr) 1999-04-01 2000-03-30 Composition microbiocide

Country Status (3)

Country Link
AU (1) AU4396700A (fr)
DE (1) DE10080787D2 (fr)
WO (1) WO2000059305A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002015693A1 (fr) * 2000-08-21 2002-02-28 Thor Gmbh Composition biocide synergique
JP2004131478A (ja) * 2002-08-14 2004-04-30 L'air Liquide Sante Internatl 殺菌作用および殺藻作用を有する水性分散液
EP1466526A2 (fr) * 2003-04-07 2004-10-13 Rohm And Haas Company Composition microbicide
EP1468607A2 (fr) * 2003-04-07 2004-10-20 Rohm And Haas Company Composition microbicide
WO2004098289A1 (fr) * 2003-05-07 2004-11-18 Laboratorios Miret S.A. Composition antimicrobienne synergique contenant terbutryne
EP2233003A1 (fr) * 2009-03-27 2010-09-29 LANXESS Deutschland GmbH Enduit protégé contre l'algicide
CN113292553A (zh) * 2021-05-12 2021-08-24 烟台大学 中肋骨条藻杀藻用芳基噻唑-色胺类化合物及其组合剂

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4900736A (en) * 1986-12-16 1990-02-13 Schulke Mayr, Gmbh Salts of alkyl-2-benzimidazole-carbamate and fungicidal compositions thereof suitable for paints and plaster
GB2304574A (en) * 1995-08-24 1997-03-26 Advanced Engineering Services Fungicidal composition using a water-based wax emulsion as a carrier
WO1998021962A1 (fr) * 1996-11-20 1998-05-28 Troy Corporation Algocide synergique
DE19705085A1 (de) * 1997-01-30 1998-08-06 Schuelke & Mayr Gmbh Algizides und fungizides Konservierungsmittel mit Alternaria-Wirksamkeit
JPH115707A (ja) * 1997-06-13 1999-01-12 Takeda Chem Ind Ltd 防藻剤組成物
JPH1135409A (ja) * 1997-05-20 1999-02-09 Takeda Chem Ind Ltd 防藻・防かび組成物

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4900736A (en) * 1986-12-16 1990-02-13 Schulke Mayr, Gmbh Salts of alkyl-2-benzimidazole-carbamate and fungicidal compositions thereof suitable for paints and plaster
GB2304574A (en) * 1995-08-24 1997-03-26 Advanced Engineering Services Fungicidal composition using a water-based wax emulsion as a carrier
WO1998021962A1 (fr) * 1996-11-20 1998-05-28 Troy Corporation Algocide synergique
DE19705085A1 (de) * 1997-01-30 1998-08-06 Schuelke & Mayr Gmbh Algizides und fungizides Konservierungsmittel mit Alternaria-Wirksamkeit
JPH1135409A (ja) * 1997-05-20 1999-02-09 Takeda Chem Ind Ltd 防藻・防かび組成物
JPH115707A (ja) * 1997-06-13 1999-01-12 Takeda Chem Ind Ltd 防藻剤組成物

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 1999, no. 04 30 April 1999 (1999-04-30) *
PATENT ABSTRACTS OF JAPAN vol. 1999, no. 05 31 May 1999 (1999-05-31) *

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002015693A1 (fr) * 2000-08-21 2002-02-28 Thor Gmbh Composition biocide synergique
US6846777B2 (en) 2000-08-21 2005-01-25 Thor Gmbh Synergistic biocidal composition
JP2004131478A (ja) * 2002-08-14 2004-04-30 L'air Liquide Sante Internatl 殺菌作用および殺藻作用を有する水性分散液
JP4602652B2 (ja) * 2002-08-14 2010-12-22 エール・リキード・サンテ（アンテルナスィオナル） 殺菌作用および殺藻作用を有する水性分散液
EP1466526A2 (fr) * 2003-04-07 2004-10-13 Rohm And Haas Company Composition microbicide
EP1468607A2 (fr) * 2003-04-07 2004-10-20 Rohm And Haas Company Composition microbicide
JP2004307483A (ja) * 2003-04-07 2004-11-04 Rohm & Haas Co 殺微生物組成物
EP1466526A3 (fr) * 2003-04-07 2004-11-24 Rohm And Haas Company Composition microbicide
EP1468607A3 (fr) * 2003-04-07 2004-12-15 Rohm And Haas Company Composition microbicide
WO2004098289A1 (fr) * 2003-05-07 2004-11-18 Laboratorios Miret S.A. Composition antimicrobienne synergique contenant terbutryne
EP2233003A1 (fr) * 2009-03-27 2010-09-29 LANXESS Deutschland GmbH Enduit protégé contre l'algicide
CN113292553A (zh) * 2021-05-12 2021-08-24 烟台大学 中肋骨条藻杀藻用芳基噻唑-色胺类化合物及其组合剂

Also Published As

Publication number Publication date
DE10080787D2 (de) 2001-08-09
AU4396700A (en) 2000-10-23

Similar Documents

Publication Publication Date Title
DE60303553T2 (de) Wässerige Dispersionen mit fungizide und algizide Wirkung
EP1919995B1 (fr) Composition aqueuse pour peintures d&#39;exterieur, d&#39;interieur, de façade et de toit
DE2541142C3 (de) Biocid-Komposition und deren Verwendung für nicht vergilbende und sich nicht verfärbende Ausrüstungen natürlicher oder industrieller Materialien und Produkte
DE102005045129A1 (de) Zubereitung zur fungiziden und algiziden Ausrüstung alkalischer Beschichtungszusammensetzungen
SK57296A3 (en) Biocidal agent, its manufacturing process and use
EP0601674B1 (fr) Dispersion aqueuse à activité fongicide et algistatique
PL199673B1 (pl) Kompozycja przeciwgrzybiczna i/lub przeciwalgowa, jej zastosowanie oraz sposób ochrony mokrej niebieskiej skóry oraz świeżego ściętego drewna
DE19705085C2 (de) Algizides und fungizides Konservierungsmittel mit Alternaria-Wirksamkeit
EP0944317A1 (fr) Melanges microbicides
DE10144187B4 (de) Konservierungsmittel für Beschichtungszusammensetzungen
EP2213166B1 (fr) Compositions biocides contenant du 2-méthylisothiazolin-3-one et une haloalkylsulfone
EP0513409B1 (fr) Utilisation d&#39;un agent microbicide pour la fabrication des tuiles en béton
WO2000059305A1 (fr) Composition microbiocide
US6117817A (en) Algicide combination
EP0475123B1 (fr) Utilisation de 2-n-alkyle-1,2-benzisothiazolin-3-ones comme microbiocides techniques
EP3739008A1 (fr) Matière de revêtement aqueuse, en particulier matière de revêtement aqueuse pâteuse, revêtement obtenu à partir de la matière de revêtement et son utilisation
DE2845408C3 (de) N-(2-Methyl-1 -naphthyD-maleinimid, Verfahren zu dessen Herstellung und seine Verwendung
EP3498784A1 (fr) Substance de revêtement, procédé de fabrication de la substance de revêtement et son utilisation
WO2007131735A2 (fr) Concentré pour la conservation de films
DE2504548A1 (de) 2,3-dicyan-5,6-dihydro-p-dithiine, insbesondere mit fungizider wirkung
DE60029780T2 (de) Biozide zusammensetzungen
DE19741403A1 (de) Mischungen von Benzothiophenderivaten
DE2904390A1 (de) Verduennbare benzimidazolcarbaminsaeurealkylester-formulierung, verfahren zu ihrer herstellung und verwendung als biozid
AT370762B (de) Anstrichsmischung mit fungiziden eigenschaften
DE2904309A1 (de) Verfahren und mittel zur pilzbekaempfung

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
REF Corresponds to

Ref document number: 10080787

Country of ref document: DE

Date of ref document: 20010809

WWE Wipo information: entry into national phase

Ref document number: 10080787

Country of ref document: DE

122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: JP