WO2000041890A1 - Support recepteur d'impression a jet d'encre - Google Patents

Support recepteur d'impression a jet d'encre Download PDF

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Publication number
WO2000041890A1
WO2000041890A1 PCT/GB1999/004347 GB9904347W WO0041890A1 WO 2000041890 A1 WO2000041890 A1 WO 2000041890A1 GB 9904347 W GB9904347 W GB 9904347W WO 0041890 A1 WO0041890 A1 WO 0041890A1
Authority
WO
WIPO (PCT)
Prior art keywords
receiver medium
coating
medium according
oil
ink
Prior art date
Application number
PCT/GB1999/004347
Other languages
English (en)
Inventor
Richard Anthony Hann
Graham Alistair Page
Gary Wayne Morrison
Original Assignee
Imperial Chemical Industries Plc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Plc filed Critical Imperial Chemical Industries Plc
Publication of WO2000041890A1 publication Critical patent/WO2000041890A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508—Supports

Definitions

  • This invention concerns a receiver medium for use in ink jet printing, particularly for use with oil-based ink jet printing inks, and also relates to a method of making such a medium and a method of printing using such a medium.
  • oil-based ink is used to mean a substantially non-aqueous ink composition employing solvents or diluents other than water and containing one or more oils.
  • ink jet printing is a widely used printing technique.
  • ink jet printing inks are water-based compositions, and such inks are widely used in a range of different ink jet printers, for commercial, office and domestic use, including desk-top printers.
  • Oil-based ink jet printing inks comprising a low viscosity dispersion of pigment in non-volatile non- aqueous diluent comprising a major amount of aliphatic hydrocarbon (oil) and a minor amount of oleyl alcohol are also known; see WO 96/24642.
  • Such oil-based inks have the advantages of enabling printing to be performed very rapidly and also producing a water- resistant end product.
  • Such inks are not, however, widely used commercially, and currently the only commercially available ink jet printers designed to use oil-based inks are wide- format printers designed to print on large rolls of paper, typically about 1 metre in width.
  • Becausg oil-based inks are non-volatile, the diluent must be absorbed or otherwise permanently accommodated by the receiver medium to produce an acceptable print.
  • Such oil-based inks produce good results when printing on paper and similar absorbent materials, with the oil being rapidly absorbed by the porosity of the paper or other material while leaving the pigment near the surface.
  • oil-based inks are not capable of providing adequate prints on non-absorbent media eg transparent media (which cannot have macroscopic pores as these scatter light and render the material opaque), and so cannot be used, for example, in production of transparency sheets for use in overhead projectors (OHPs). They are also unsuitable for use with currently available glossy media.
  • US Re 34933 concerns receiver sheets for use in offset lithography and similar printing techniques using solvent-based inks containing oil.
  • the receiver sheets may comprise a transparent substrate, eg of transparent polyester such as polyethylene terephthalate, carrying a transparent ink-receptive polymeric layer comprising one or more polymers or copolymers, eg a copolymer of n-butyl methacrylate and isobutyl methacrylate.
  • a transparent substrate eg of transparent polyester such as polyethylene terephthalate
  • a transparent ink-receptive polymeric layer comprising one or more polymers or copolymers, eg a copolymer of n-butyl methacrylate and isobutyl methacrylate.
  • Such receiver sheets may be used to produce transparent printed images, eg by offset lithography.
  • the receiver sheets are not, however, suited to use in ink jet printing using oil-based printing inks.
  • a receiver medium For use with mechanical printing techniques, such as offset lithography, a receiver medium requires properties of mechanical stability and abrasion resistance that are not necessary when printing
  • the solvent-based inks used for this purpose are rather different from oil-based ink jet printer inks, typically being high viscosity compositions with high solids content, and having a much smaller content of oil as compared with oil-based ink jet printer inks.
  • These prior art receiver sheets are not capable of absorbing the high oil content of oil-based ink jet printer inks, nor of adequately coping with the low viscosity properties of such inks.
  • the present invention thus aims to provide a novel receiver medium suitable for use with ink jet printers using oil-based printing ink.
  • a receiver medium for use with oil-based ink jet printing ink comprising a substrate having an ink-receiving surface bearing a coating of crosslinked polymer comprising polyalkene, the alkene having at least 4 carbon atoms.
  • Suitable polyalkenes are soft polymers, having low glass transition temperatures (Tgs), typically below -30°C, with the chains of the polymers being in a very mobile state. Polyalkenes having a low degree of crystallinity are preferred.
  • the polymer chains are nonpolar and so have high compatibility with the oil of the ink. The polymers are thus able to absorb large quantities of oil (due to compatibility) rapidly (due to the mobile state of the polymer chains).
  • such polymers tend to be rubbery at best and possibly soft and sticky, which are undesirable characteristics.
  • absorption of oil from the ink, in use has a plasticising effect on the polymer and reduces Tg, making the material softer and/or stickier.
  • Crosslinking acts to stabilise the polymer, by forming a three-dimensional network and making the polymer harder, less sticky and more robust.
  • crosslinking reduces the rate of oil uptake, which can be disadvantageous.
  • Crosslinking also reduces the capacity for oil, although this is generally not of practical significance except at very high degrees of crosslinking as capacity is generally more than adequate.
  • the degree of crosslinking of the polyalkene should thus be adjusted to give an appropriate balance of coating characteristics, with preferred coatings being able rapidly to absorb large quantities of oil on application of oil-based ink, having good pigment adhesion with the dispersed pigment being permanently fixed on the surface, and being reasonably robust and resistant to damage.
  • the coating is capable of absorbing oil, there is no need for the substrate itself to be able to absorb oil.
  • oil-based inks By applying such a coating to non-absorbent substrates it is thus possible for oil-based inks to be printed successfully onto non-absorbent substrates such as glossy white film materials in a way that has not hitherto been possible.
  • the coatings are optically transparent and so can be used on transparent substrates eg for the production of transparency sheets for use in OHPs.
  • the substrate may alternatively be of other materials including metal, plastics, wood etc, and materials having metallised or other non-absorbent finishes.
  • the substrate there is, however, no need for the substrate to be non-absorbent, and the coating can be equally well applied to an absorbent substrate, including absorbent paper, card etc.
  • the substrate itself may also act to absorb some of the oil from ink applied in use, in which case the coating may be made thinner than would be required on a non-absorbent substrate.
  • the substrate can be selected from a very wide range of materials.
  • the substrate is typically in the form of a film or sheet, but the physical form is not important as the coating can be applied to substrates of a wide variety of physical forms.
  • Typical substrate materials include polymeric materials having suitable properties including dimensional stability, optical transparency, translucency or opacity, tensile strength, adhesion characteristics, thermal stability, hardness etc for the intended purpose.
  • Transparent polymeric substrate materials suitable for use in the production of transparencies include sheets or films of polyester eg poly(ethyleneterephthalate) (PET) such as Melinex (Melinex is a Trade Mark) or poly(ethylenenaphthalate) (PEN).
  • PET poly(ethyleneterephthalate)
  • PEN poly(ethylenenaphthalate)
  • Polycarbonate sheets may also be used for this purpose.
  • Such transparent sheets typically have a thickness of about 50 to about 150 ⁇ m.
  • polysulphones include polysulphones, polyvinyl chloride, polystyrene, polyimides, polyolefins, polymethyl methacrylate, cellulose esters such as cellulose acetate etc.
  • polysulphones include polysulphones, polyvinyl chloride, polystyrene, polyimides, polyolefins, polymethyl methacrylate, cellulose esters such as cellulose acetate etc.
  • polysulphones include polyvinyl chloride, polystyrene, polyimides, polyolefins, polymethyl methacrylate, cellulose esters such as cellulose acetate etc.
  • cellulose esters such as cellulose acetate etc.
  • a wide range of paper and card materials may also be used as the substrate.
  • the substrate may be pre-treated, eg in known manner, prior to application of the coating.
  • the substrate may be pre-treated with an adhesion-promoting priming layer, eg of parachlorometacresol (PCMC).
  • PCMC parachlorometacresol
  • the alkene of the coating may be branched or straight chain.
  • the alkene is preferably substantially non-crystalline.
  • the alkene is preferably a diene, more preferably a 1,3 diene with buta-l,3-diene and isoprene being the currently preferred alkenes.
  • the polyalkene must be suitably functionalised to enable crosslinking, eg by inclusion of hydroxy groups, amino groups etc in known manner, for crosslinking in known manner.
  • hydroxy groups can be crosslinked using formaldehyde resin chemistry, eg using melamine-formaldehyde resin, or by use of polynmctional isocyanates etc.
  • the degree of crosslinking should be adjusted to give a coating with desired properties, as discussed above.
  • the chain length between crosslinks is suitable in the range 10 to 500 monomer units, preferably 20 to 200, and especially 30 to 100 units.
  • Good results have been obtained using Liquiflex H from Krahn Chemie (Liquiflex H is a Trade Mark) which is a hydroxy-ended polybutadiene of molecular weight about 2700 with one hydroxy group at each end of the molecule, ie having two hydroxy groups per molecule.
  • Liquiflex H is a viscous liquid at room temperature.
  • Liquiflex H can be readily crosslinked using melamine-formaldehyde resin, eg in the form of Cymel 303 from Dyno Cyanamid (Cymel 303 is a Trade Mark).
  • Melamine-formaldehyde resin has 3 reactive functional groups and 3 less reactive functional groups, and is capable of providing appropriate crosslinking with the bifunctional hydroxy groups of Liquiflex H.
  • Crosslinking can be readily performed in known manner, eg by mixing the materials with a suitable catalyst such as p-toluenesulphonic acid (PTSA) solution and curing the mixture for a suitable time at a suitable temperature to achieve a desired degree of crosslinking to produce a product having desired properties.
  • PTSA p-toluenesulphonic acid
  • Cymel 303 Using mixtures of Liquiflex H and Cymel 303 it was found appropriate to use Cymel 303 in an amount in the range 1 to30%, preferably 3 tol5%, typically about 10%, based on the weight of Liquiflex H.
  • LIR-410 from Kuraray (LIR-410 is a Trade Mark) which comprises an isoprene backbone graft copolymerised with maleic monomethyl ester to give a material with a molecular weight of about 25,000. Functionality is provided by the residual acid groups on the maleic residues; there are 10 reactive groups per molecule.
  • This material can similarly be readily crosslinked using melamine- formaldehyde resin, eg Cymel 303 as described above.
  • a mixture of alkenes may be used in production of the polyalkene. Additionally or alternatively, a mixture of polyalkenes may be used: in this case all the polyalkenes desirably have the same functional groups, eg hydroxy groups, for crosslinking purposes.
  • Suitable curing conditions time and temperature
  • the coating materials may be applied by any suitable coating technique, including those known in the field, eg by use of a Meier bar, by roller coating, rod coating, slide coating, curtain coating, doctor coating etc.
  • the coating may be applied to the entire surface of the substrate or to only selected areas of the substrate surface. In the case of a sheet or film of substrate, the coating will typically be applied to at least one surface and possibly both surfaces (to enable double-sided printing).
  • the coating thickness will typically be 30 to lOO ⁇ m for non-absorbent substrates, eg about 80 ⁇ m, with thinner coatings, eg about 5 ⁇ m, being suitable for absorbent coatings, with coating thickness being selected depending on substrate properties and desired characteristics of the receiver medium.
  • the coating desirably includes particulate filler material, to modify mechanical properties of the coating and in particular to enhance stiffness and rigidity, making the coating less soft.
  • suitable materials for this purpose include inorganic, organic or polymeric particulates such as silica including amorphous silica, crystalline silica, fumed silica, aluminium trihydrate, calcirarf carbonate, glass, clays, aluminium silicates, polyolefin particulates, organic pigments and mixtures thereof.
  • porous inorganic particulate material eg silica: in this event the porous filler material may also functional to absorb some of the oil from ink applied to the receiver medium.
  • Particulate filler material has a tendency to increase light scattering, reducing coating transparency, so this factor must be taken into consideration in relation to transparent substrates and coatings, while being of no relevance to opaque receiver media.
  • the particulate filler material may additionally act to increase surface roughness of the coating, thus reducing the tendency of the coating to block ie stick by wetting action to adjacent surfaces: this tendency arises from the low Tg of the coating.
  • Filler material particles suitably have a primary size in the range 5nm to 50 ⁇ m.
  • Fillers with a dimension much smaller than the wavelength of light can be used at higher loadings than larger fillers (because of their lower scattering) and therefore make a greater contribution to the mechanical properties of the coating, but are less efficient at creating surface roughness than are fillers with a major dimension of comparable size to the coating thickness. It is often desirable to incorporate fillers of two different sizes in order to optimise the overall properties of the coating.
  • the receiver medium may include an optional top coat (or supercoat) over the crosslinked polyalkene coating.
  • a top coat desirably has the following characteristics:
  • the top coat should be capable of absorbing oil from applied oil-based ink reasonably rapidly.
  • the top coat should be of higher Tg than the coating so as to reduce the tendency of the receiver medium to block.
  • the top coat should exhibit good adhesion to pigment of applied ink.
  • the top coat conveniently comprises one or more polymers, and one example of a top coat formulation is a mixture of polybutadiene, styrene butadiene rubber and polystyrene.
  • the top coat is typically much thinner than the crosslinked polyalkene coating, eg having a thickness in the range 0.2 to 5 ⁇ m.
  • the top coat desirably includes particulate filler material, eg as discussed above, to improve anti-blocking properties and possibly also to absorb oil and to improve pigment adhesion and other receiver medium properties.
  • the receiver medium includes a top coat, possibly comprising particulate filler material, it may nevertheless be desirable to include particulate filler material in the crosslinked polyalkene coating to perform a stiffening function. Again the light-scattering effect of particulate filler materials must be born in mind when dealing with transparent receiver media.
  • the anti-blocking effect can be maximised without introducing too much light scattering, as smaller particles (typically up to lO ⁇ m) can be used than would be required in the thicker crosslinked polyalkene coating, and the particles are concentrated near the surface of the assembly.
  • a top coat may be applied by any suitable coating technique, for example those discussed above in connection with the crosslinked polyalkene coating.
  • lubricants and release agents such as waxes and silicones, may be included to reduce friction and/or adhesion at the coating surface.
  • the invention provides a method of making a receiver medium for use with oil-based ink jet printing ink, comprising applying to an ink-receiving surface of a substrate a coating of crosslinked polymer comprising polyalkene, the alkene having at least 4 carbon atoms.
  • the receiver medium is used by oil-based ink jet printing ink being applied thereto by an inkjet printing technique, eg in known manner, using known ink-jet printing apparatus.
  • the ink may be, eg, generally as described in WO 96/24642 discussed above.
  • the oil of the ink is rapidly absorbed by the ink-receiving surface (ie the coating of crosslinked polyalkene and possibly also by the top coat if present) and may also in part be absorbed by the substrate if absorbent, as discussed above.
  • the invention thus provides a method of printing, comprising applying oil- based ink to the ink-receiving surface of receiver medium in accordance with the invention by an inkjet printing technique.
  • the coatings described in the present application may optionally be used in conjunction with coatings described in the specifications of our co-pending UK application Nos. 9900489.7, 9900490.5 and 9900491.3.
  • a polyisoprene emulsion coating as described in the specification of application No. 9900490.5 may be applied over a crosslinked polyalkene coating as described in the present specification.
  • Samples of experimental receiver media were made and tested for their ability to absorb oil- based ink (comprising organic pigments dispersed in aliphatic hydrocarbon oil with oleyl alcohol, generally as described in WO 96/24642 by placing a few drops of ink on the edge of the coating, and drawing a Meier bar " (24 ⁇ m unless otherwise stated) over the surface. The ink was then viewed obliquely in order to determine the drying time. The ability of the prints to withstand abrasion was also determined by drawing a rubber-gloved finger lightly over the printed area. Transparency was normally judged simply by looking at the samples, and this was confirmed from time to time by placing representative samples on an OHP.
  • oil- based ink comprising organic pigments dispersed in aliphatic hydrocarbon oil with oleyl alcohol, generally as described in WO 96/24642 by placing a few drops of ink on the edge of the coating, and drawing a Meier bar " (24 ⁇ m unless otherwise stated)
  • Liquiflex H a hydroxy-ended polybutadiene of molecular weight about 2700, with two hydroxyl groups per molecule
  • Cymel 303 melamine-formaldehyde resin crosslinked using Cymel 303 melamine-formaldehyde resin, on transparent PET film.
  • the resultant receiver medium was tested with magenta ink, by the technique described above. A 12 ⁇ m layer dried in 30 to 35 seconds; a 24 ⁇ m layer dried in 70 to 100 seconds.
  • the drying time of a 24 ⁇ m layer of magenta ink was 30 to 35 seconds, and the film showed good absorption and control of ink when tested on a laboratory inkjet printer.
  • a mixture of Liquiflex stock solution A (5 g) and PTSA solution (0.2 g) was coated onto Melinex O PET film using a 150 ⁇ m Meier bar and cured in an oven at 120 °C with a cure time of 120 seconds.
  • the drying time of a 24 ⁇ m layer of magenta ink was 70 to 90 seconds. All the above coatings had a soft rubbery feel, the coatings with the best absorption being the softest. All of the prints were susceptible to abrasion damage.
  • PK3 1.0g (Di n Butylamine salt of pTSA, 28% w/w in Methanol from ICI Imagedata)
  • Scripset 550 is a styrene maleic anhydride copolymer from Monsanto. Lincur M is poly parahydroxystyrene from Maruzen Petrochemical Co. Scripset 550 and Lincur M are Trade Marks.
  • Additive was added in an amount of 5% w/w of the weight of the supercoat.
  • the supercoat formulations containing additive were again coated onto a coating as described in Example 2 using a K4 Meier bar and cured for 30 seconds at 110°C.
  • the additives used were soluble lubricants/release agents, the function of which is to reduce friction and reduce adhesion of the coating surface while not modifying the surface roughness of the coating. Results of these were as follows:
  • Crodamide ER erucaminde wax, from Croda (Crodamide ER is a Trade Mark)
  • Crodamide ER is a Trade Mark
  • Tegomer 6440 (copoly dimethylsiloxane caprolactone from Tego Chemie (Tegomer 6440 is a Trade Mark)) - Improved pigment adhesion and lowered friction and easier release.
  • a further enhancement of the surface handleability was made by the addition of 2.5% w/w Fluo HT (micronised polytetrafluoroethylene, mean diameter 2 ⁇ m, from Micropowders Inc. (Fluo HT is a Trade Mark)) on solids of the supercoat.
  • Fluo HT micronised polytetrafluoroethylene, mean diameter 2 ⁇ m, from Micropowders Inc. (Fluo HT is a Trade Mark)
  • Samples were then made up by using a 100 ⁇ m layer of a base coat formulation (made by mixing together the ingredients as specified in the table below) onto clear unprimed Melinex O and curing for 180 seconds at 130 °C.
  • a base coat formulation made by mixing together the ingredients as specified in the table below
  • a supercoat formulation (made by mixing together the ingredients as specified in the table below) was coated with a 36 ⁇ m Meier bar onto the base coat, followed by drying for 30 seconds at 130 °C.
  • the supercoat did not affect drying time, but reduced the tack.
  • LIR-410 from Kuraray
  • LIR-410 comprises an isoprene backbone (in place of the butadiene backbone of Liquiflex H) and is graft copolymerised with maleic monomethyl ester to give a material with a molecular weight of about 25,000.
  • Functionality is provided by residual carboxylic acid groups on the maleic residues; there are 10 reactive groups per molecule.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)

Abstract

L'invention concerne un support récepteur utilisé avec une encre d'impression à jet d'encre à base d'huile comprenant un substrat présentant une surface de réception de l'encre enduite d'un revêtement de polymère réticulé renfermant un polyalcène, notamment un butadiène réticulé avec une résine mélamine-formaldéhyde. Le revêtement peut absorber l'huile et l'utiliser comme revêtement qui permet l'impression des substrats non absorbants avec des encres à base d'huile, notamment des supports optiquement transparents tels que des films de polyéthylène térephtalate, en vue notamment de la production de feuilles transparentes utilisées dans les rétroprojecteurs ce qui n'était pas viable jusqu'à présent. Selon une variante, le substrat peut être absorbant et peut servir à absorber une partie de l'huile de l'encre appliquée. L'invention concerne aussi un procédé de production de ce support et un procédé d'impression utilisant ce support.
PCT/GB1999/004347 1999-01-12 1999-12-22 Support recepteur d'impression a jet d'encre WO2000041890A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9900488 1999-01-12
GB9900488.9 1999-01-12

Publications (1)

Publication Number Publication Date
WO2000041890A1 true WO2000041890A1 (fr) 2000-07-20

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PCT/GB1999/004347 WO2000041890A1 (fr) 1999-01-12 1999-12-22 Support recepteur d'impression a jet d'encre

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WO (1) WO2000041890A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6589636B2 (en) 2001-06-29 2003-07-08 3M Innovative Properties Company Solvent inkjet ink receptive films
WO2003080356A1 (fr) * 2002-03-26 2003-10-02 Ucb, S.A. Film imprimable
EP1398168A1 (fr) * 2002-09-10 2004-03-17 Konica Corporation Feuille pour l'enregistrement par jet d'encre et procédé de formation d'image
US6720042B2 (en) 2001-04-18 2004-04-13 3M Innovative Properties Company Primed substrates comprising radiation cured ink jetted images
US6846075B2 (en) 2001-06-29 2005-01-25 3M Innovative Properties Company Imaged articles comprising a substrate having a primed surface
US6881458B2 (en) 2002-06-03 2005-04-19 3M Innovative Properties Company Ink jet receptive coating
EP1407892A3 (fr) * 2002-10-07 2006-03-15 Konica Corporation Elément pour impression par jet d'encre

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US4559256A (en) * 1982-09-25 1985-12-17 Fumio Matsumoto Image receiving transparent base film
US4713280A (en) * 1986-07-29 1987-12-15 Minnesota Mining And Manufacturing Company Receptor sheet for impact printers
JPH0276775A (ja) * 1988-09-14 1990-03-16 Matsushita Electric Ind Co Ltd インクジェット用記録シート
EP0404492A2 (fr) * 1989-06-23 1990-12-27 Xerox Corporation Substrat transparent
EP0698638A1 (fr) * 1994-07-18 1996-02-28 Shell Internationale Researchmaatschappij B.V. Dispersions aqueuses réticulables de polymères de diènes à fonctions hydroxyles et de résines aminoplastes
US5688598A (en) * 1996-06-28 1997-11-18 Morton International, Inc. Non-blistering thick film coating compositions and method for providing non-blistering thick film coatings on metal surfaces

Patent Citations (6)

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Publication number Priority date Publication date Assignee Title
US4559256A (en) * 1982-09-25 1985-12-17 Fumio Matsumoto Image receiving transparent base film
US4713280A (en) * 1986-07-29 1987-12-15 Minnesota Mining And Manufacturing Company Receptor sheet for impact printers
JPH0276775A (ja) * 1988-09-14 1990-03-16 Matsushita Electric Ind Co Ltd インクジェット用記録シート
EP0404492A2 (fr) * 1989-06-23 1990-12-27 Xerox Corporation Substrat transparent
EP0698638A1 (fr) * 1994-07-18 1996-02-28 Shell Internationale Researchmaatschappij B.V. Dispersions aqueuses réticulables de polymères de diènes à fonctions hydroxyles et de résines aminoplastes
US5688598A (en) * 1996-06-28 1997-11-18 Morton International, Inc. Non-blistering thick film coating compositions and method for providing non-blistering thick film coatings on metal surfaces

Non-Patent Citations (1)

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Title
PATENT ABSTRACTS OF JAPAN vol. 014, no. 266 (M - 0982) 8 June 1990 (1990-06-08) *

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6720042B2 (en) 2001-04-18 2004-04-13 3M Innovative Properties Company Primed substrates comprising radiation cured ink jetted images
US6846075B2 (en) 2001-06-29 2005-01-25 3M Innovative Properties Company Imaged articles comprising a substrate having a primed surface
US6793859B2 (en) 2001-06-29 2004-09-21 3M Innovative Properties Company Solvent inkjet ink receptive films
US6800341B2 (en) 2001-06-29 2004-10-05 3M Innovative Properties Company Solvent inkjet ink receptive films
US6589636B2 (en) 2001-06-29 2003-07-08 3M Innovative Properties Company Solvent inkjet ink receptive films
US6896944B2 (en) 2001-06-29 2005-05-24 3M Innovative Properties Company Imaged articles comprising a substrate having a primed surface
US7025453B2 (en) 2001-06-29 2006-04-11 3M Innovative Properties Company Imaged articles comprising a substrate having a primed surface
WO2003080356A1 (fr) * 2002-03-26 2003-10-02 Ucb, S.A. Film imprimable
US6881458B2 (en) 2002-06-03 2005-04-19 3M Innovative Properties Company Ink jet receptive coating
EP1398168A1 (fr) * 2002-09-10 2004-03-17 Konica Corporation Feuille pour l'enregistrement par jet d'encre et procédé de formation d'image
US7387381B2 (en) 2002-09-10 2008-06-17 Konica Corporation Ink jet recording sheet and image forming method
CN100411881C (zh) * 2002-09-10 2008-08-20 柯尼卡株式会社 喷墨记录片材以及成像方法
EP1407892A3 (fr) * 2002-10-07 2006-03-15 Konica Corporation Elément pour impression par jet d'encre
US7090903B2 (en) 2002-10-07 2006-08-15 Konica Corporation Ink-jet recording sheet

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