WO2000041564A1 - Compositions de resine servant a lutter contre de petits animaux et elements moules dans cette resine - Google Patents
Compositions de resine servant a lutter contre de petits animaux et elements moules dans cette resine Download PDFInfo
- Publication number
- WO2000041564A1 WO2000041564A1 PCT/JP2000/000160 JP0000160W WO0041564A1 WO 2000041564 A1 WO2000041564 A1 WO 2000041564A1 JP 0000160 W JP0000160 W JP 0000160W WO 0041564 A1 WO0041564 A1 WO 0041564A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- resin
- small animals
- derivatives
- controlling small
- controlling
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
Definitions
- the present invention relates to a small animal controlling resin composition and a small animal controlling member formed by molding the resin composition.
- Compositions have been proposed. These resins are resins that can hold a large amount of chemicals such as insecticides, but have the drawback of insufficient strength, heat resistance, and chemical resistance. For this reason, members formed by molding the resin composition itself as a molding material have extremely limited use situations, and can be used for applications requiring little strength, such as cat collars. (See Japanese Patent Application Laid-Open No. Hei 6-315532, Japanese Patent Application Laid-Open No. Hei 5-284,871, Japanese Patent Laid-Open No. Hei 6-141,724, etc.).
- the present invention has been made in view of the above-mentioned problems of the prior art, and is a resin material used as a structural material or the like, which has strength, heat resistance, and chemical resistance and can exhibit small animal control performance over a long period of time.
- the task is to provide
- component B a phosphoric acid ester derivative, a phosphazene derivative, a carboxylic acid amide derivative, and a carboxylic acid ester derivative
- component C small animal control
- the present invention provides a small animal controlling resin composition containing a drug having a property (hereinafter, may be simply referred to as “component C”).
- the small animal controlling resin composition according to the present invention may further contain (D) a fibrous inorganic filler (hereinafter sometimes simply referred to as “D component”). It is preferable to add a fibrous inorganic filler since the sustained release can be further enhanced. The addition of the fibrous inorganic filler is also preferable because it contributes to improving the mechanical properties.
- D component a fibrous inorganic filler
- a small animal controlling member obtained by molding any of the small animal controlling resin compositions.
- the obtained small animal-controlling resin composition of the present invention may be directly molded into a desired shape to be used as a small-animal-controlling member.
- the pellets may be stored and distributed by pelletizing. Pellets and the like can be formed by a known method.
- the polyamide resin examples include polyamide 6, polyamide 66, polyamide 11 and polyamide 12 resin.
- aromatic polyamide resins such as polyamide MXD and polyamide 6T resin.
- polyacetal resin examples include, in addition to a homopolymer composed of only an oxymethylene unit, a copolymer containing an oxymethylene unit as a main component and other copolymerized units such as an oxethylene unit as an auxiliary component. And a graft copolymer obtained by graft copolymerization.
- component (A) one kind selected from a polyamide resin or a polyacetal resin can be used alone, or a mixture of two or more kinds selected from these can be used.
- the polyamide resin or polyacetal resin used as the component (A) may be used as an alloy with another resin as long as the effects of the present invention are not impaired.
- examples of resins that can be used as other resins include polyethylene, polypropylene, polystyrene, acrylonitrile-butadiene-styrene resin, polyarylate, polyphenylene ether, thermoplastic polyurethane, and liquid crystalline polyester. These can be used in the component (A) in a proportion of less than 70 parts by weight.
- (B) at least one compound selected from a sulfonamide derivative, a sulfonic acid ester derivative, a carboxylic acid amide derivative, and a carboxylic acid ester derivative has an action of dissolving and holding the component (C) and imparting a sustained release property. It is considered something.
- carboxylic acid ester derivatives include hydroxyl group, nitro group
- examples include alkyl esters and aromatic esters of various carboxylic acids which may be substituted with a group, an amino group, an epoxy group, octylogen, etc.
- Those having a hydroxyl group or an epoxy group have good compatibility with polyamide. Therefore, it is preferable.
- carboxylic acid ester derivatives include, for example, dimethyl phthalate, methyl phthalate, di-n-octyl phthalate, diphenyl phthalate, benzyl phthalate, dimethoxyethyl phthalate, and 45 epoxyhexahydrophthalic acid.
- Phosphate derivatives include trimethyl phosphate, triethyl phosphate, tributyl phosphate, tris (2-ethylhexyl) phosphate, 2-ethylhexyl diphenyl phosphate, and tributoxyshetyl phosphate.
- Triphenyl phosphate Triphenyl phosphate, cresyl diphenyl phosphate, isodecyl diphenyl phosphate, tricresyl phosphate, trixylenyl phosphate, tri (chloroethyl) phosphate, dimethylphenyl diphenyl phosphate, tetrakis (2,4-di-tert-butylphenyl) ) 4, 4'-Bifene diphosphonate and the like.
- m represents an integer of 3 to 25.
- RR 2 denote the same or different alkyl group of 1 to 8 carbon atoms, alkyl groups and Z or Ariru optionally substituted phenylene Le group group having 1 to 8 carbon atoms.
- n an integer of 3 to 1000.
- R 3 and R 4 are the same or different and represent an alkyl group having 1 to 8 carbon atoms, or a phenyl group which may be substituted with an alkyl group having 1 to 8 carbon atoms and / or an aryl group.
- Y represents a group P (OR 3 ) 4 , a group—P (OR 4 ) 4 , a group—P ( ⁇ ) (OR 3 ) 2 or a group—P ( ⁇ ) (OR 4 ) 2 .
- at least one phosphazene compound selected from these phosphazene compounds is an o-, m- or p-phenylene group, a biphenylene group, and a compound represented by the following general formula ( 3) General formula (3)
- r represents 0 or 1
- A represents a group S ⁇ 2 —, —S—, —O— or _C (CH 3 ) 2 —.
- cyclic phosphazene compound represented by the general formula (1) include: Propoxycyclotetraphosphazene, decapropoxycyclobe And cyclic phosphazene compounds such as'.
- linear phosphazene compound represented by the general formula (2) examples include a linear phosphazene compound in which a linear dichlorophosphazene is substituted with a propoxy group and a Z or phenoxy group.
- cross-linking structure represented by the general formula (3) examples include, for example, 4,4′-sulfonyldiphenylene (bisphenol-S residue), 4,4 ′ one-year-old xydiphenylene group, 4′-thiodiphenylene group and 4,4′-diphenylene group.
- phosphazene derivatives may have an amino group and a phenyl or amino group substituted at any position.
- One of these phosphazene derivatives may be used alone, or a mixture of two or more thereof may be used. Further, it may be a mixture of a cyclic phosphazene and a linear phosphazene.
- Examples of the carboxylic acid amide derivative include N-cyclohexylbenzoic acid amide.
- sulfonamide derivatives examples include N-methyl-benzenesulfonamide, N-ethyl-benzenesulfonamide, N-butyl-benzenesulfonamide, N-cyclohexylbenzenesulfonamide, and N-ethyl-P-toluenesulfonamide. , N-butyl-toluenesulfonamide, N-cyclohexyltoluenesulfonamide and the like.
- Examples of the sulfonic acid ester derivative include ethyl benzenesulfonate.
- component (B) one kind selected from a sulfonamide derivative, a sulfonic acid ester derivative, a carboxylic acid amide derivative, and a carboxylic acid ester derivative can be used alone, or a mixture of two or more kinds selected from these can be used. .
- Small animal control agents include various agricultural pests, sanitary pests and other A drug that has a controlling activity on small animals such as reptiles, spiders, mites, and rats.A compound that has a small animal repellent activity, a small animal with insecticidal, acaricidal, spidericidal or rodenticidal activity. Examples thereof include compounds having an activity, compounds having an activity of inhibiting the feeding of small animals, and compounds having a growth controlling activity of small animals.
- small-animal-controlling agents include chloronicotinyl-based insecticides such as imidacloprid, compounds having a silicon atom such as silafluofen, benfracarb, aranicarp, and methoxydiazone (metoxaxiazone, 5-—).
- chloronicotinyl-based insecticides such as imidacloprid
- compounds having a silicon atom such as silafluofen, benfracarb, aranicarp
- methoxydiazone metaloxaxiazone, 5-—.
- carbosurphan fenobocalp, kylarvalyl, mesomil, propoxal, phenoxycarp, etc.
- Pyrethrin, arethrin, dl, d-T80 arelesrin, d-T80-resmethrin, bio-aresulin, d-T80-phthalthrine, fusurinsulin, resmethrin, flamemetryn, propar thr in, permethrin, acrinatrine, etofen Prox, Tralomethrin, Pyrethroids such as phenothrin, d-phenothrin, fenvalerate, empentrin, praletrin, and tefluthrin, dichlorobos, funitrothion, diazinon, marathon, propaphos, fenthion, trichlorfon, nared, temefos, clofophos, clofophos, clofophos, clofophos, clofofos, Examples thereof include organophosphorus compounds such as azamethiphos, pyri
- acaricides such as Kelsen, chlorfenavir, debufenviradopyridabene, milbemectin, and fenpyroximate
- rodenticides such as silyloside, norbomide, norbomide, zinc arsenide, thallium sulphate, noble, antu, perfurin, Coumarin, bear tetralyl, bromadiol (bromad iol one), difetiarone And the like.
- the fibrous inorganic filler those having an average fiber diameter of 0.05 to 10 ⁇ m and an average fiber length of 3 to 150 / zm are preferably used. Gum fiber, potassium titanate fiber, potassium titanate fiber, titania fiber, monoclinic titania fiber, silica fiber, wollastonite, zonotolite, etc. can be exemplified, and various fillers are used alone or in combination. be able to. Among these fibrous inorganic fillers, potassium 8-thiocyanate fiber is particularly preferred.
- a fibrous inorganic filler since the sustained release can be further enhanced.
- the addition of the fibrous inorganic filler is also preferable because it contributes to the improvement of mechanical properties.
- the fibrous inorganic filler can be used as is, but in order to improve the interfacial adhesion to the resin and further improve the mechanical properties, a silane coupling agent such as aminosilane, epoxysilane, or acrylic silane or a titanate coupling agent Surface treatment with such a surface treatment agent may be used.
- an inorganic filler such as zeolite can be used in combination as long as the object of the present invention is not impaired.
- the mixing ratio of each component in the resin composition of the present invention can be appropriately set depending on the specifically selected component.
- the component (B) is added to component (A) in an amount of 100 to 105 parts by weight. It is advisable to mix 100 parts by weight, preferably 2 to 50 parts by weight, and 0.01 to 30 parts by weight, preferably 0.1 to 20 parts by weight of the component (C).
- the blending amount is preferably 2 to 60 parts by weight based on 100 parts by weight of the component (A). If the amount of the component (D) exceeds 60 parts by weight, molding becomes difficult, which is not preferable. If the amount is less than 2 parts by weight, the effect of adding the fibrous inorganic filler is not sufficiently obtained.
- the small animal control resin composition of the present invention can be produced, for example, by blending each component and melt-kneading.
- the components can be blended by dry mixing in advance using a tumbler, a blender, a mixer, or the like. It can also be done by feeding from different hoppers.
- the obtained small animal-controlling resin composition of the present invention may be directly formed into a desired shape to form a small-animal-controlling member, or may be once extruded, pelletized by a pelletizer, stored and distributed. Good. Pellets or the like can be formed by a known method.
- the small animal controlling resin composition of the present invention When molding the small animal controlling resin composition of the present invention, it can be molded by various known molding methods.
- molding methods include injection molding, extrusion molding, press molding, blow molding, and the like. Machining molding and the like can be exemplified.
- the shape of the small animal-controlling member of the present invention is not particularly limited, and may be any shape such as a plate, a rod, a cylinder, a comb, and a sphere.
- the resin composition for controlling small animals of the present invention can be molded into two or more colors together with a usual resin composition, metal, or the like to form a structural member or the like having a desired part having small animal control properties.
- component (A) use polyamide 12 as polyamide resin.
- Product name “Diamid L 19 40 ”, manufactured by Daicel Huls Co., Ltd.“ PA ” is indicated in the type column in the table) and melted.
- the plunger pump and the component (B) in the ratio shown in Table 1 or Table 2 below (using N-butyl-benzenesulfonamide as the sulfonamide derivative.
- component (A) Polyacetal resin. Product name “Duracon M90-44”, manufactured by Polyplastics Co., Ltd.) (Indicated as “POM” in the type column) and melt.
- component (B) using N-butyl-benzenesulfonamide as the sulfonamide derivative
- component (C) for insecticide.
- a cylindrical test molded product having an inner diameter of 15 ⁇ , a thickness of 1.5 mm, and a length of 4 Omm was produced by an injection molding machine using an injection molding machine.
- an injection molding machine was used to prepare a cylindrical test molded article having an inner diameter of 15 ⁇ , a wall thickness of 1.5mm, and a length of 4Omm using an injection molding machine.
- Component (B) is 2-ethylhexyl parahydroxybenzoate (carboxylate Derivatives.
- the resin compositions of Examples 10 to 12 were obtained in the same manner as in Example 1 except that the type column in the table was changed to "B").
- a cylindrical test molded product having an inner diameter of 15 mm ⁇ i), a thickness of 1.5 mm, and a length of 40 mm was prepared by an injection molding machine.
- Examples 13 to 15 and the ratios of Examples 13 to 15 were changed in the same manner as in Example 1 except that the component (B) was replaced with a phosphazene compound represented by the following general formula (4) (indicated by “C” in the column of type in the table). Thus, a resin composition of Comparative Example 8 was obtained.
- a cylindrical test molded product having an inner diameter of 15 ⁇ , a wall thickness of 1.5 mm, and a length of 40 mm was prepared with an injection molding machine.
- the component A (using the same polyamide resin as in Example 1; trade name “Diamid L 1940”) is charged and melted. From the side hopper of the twin-screw extruder, use the plunger pump and the components shown in Table 1 for the components (B) (using N-butyl-benzenesulfonamide as the sulfonamide derivative) and component (C) (using permethrin as the insecticide) )
- the mixture of (1) and (2) is used as the component (D) (potassium 8 titanate fiber having an average fiber diameter of 0.5 m and an average fiber length of 18 ⁇ is used as the fibrous inorganic filler.
- Product name “Tismo D”, Otsuka Chemical Co., Ltd.) Made in the company. "A” is displayed in the type column in the table). Subsequently, it was pelletized to obtain the resin compositions of Examples 16 to 21.
- a molded product for a cylindrical test having an inner diameter of 15 ⁇ , a wall thickness of 1.5 mm, and a length of 40 mm was prepared with an injection molding machine.
- Comparative Example 7 With respect to the resin composition of Comparative Example 6, a cylindrical test molded product having an inner diameter of 15 mm ⁇ , a thickness of 1.5 mm, and a length of 40 mm was prepared in the same manner as in each example using an injection molding machine. Comparative Example 7
- ethylene vinyl acetate resin (vinyl acetate content 32% by weight, trade name “Ultra Sen 750”, Toyo Soda Kogyo Co., Ltd.)
- EVA is indicated in the column of (A) component type) in the table) 80 parts by weight are charged and melted. 20 parts by weight of component (C) (using permethrin as an insecticide) from a twin-screw extruder side hopper (1) with a plunger pump, followed by pelletization to obtain a resin composition of Comparative Example 7 .
- test molded articles obtained in each of the examples and comparative examples were placed in an environment of 25 ° C, and on the 7th day, At the third and sixth months, gooses (manufactured by Toray Industries, Inc., trade name "Tetron C-119 Skylark") were attached to both ends of the test molded product, and the spider spider (Age 1 ena 1 imb ata) 1 Five specimens each containing the animals were prepared, and the life and death of the spider was confirmed 24 hours later.
- gooses manufactured by Toray Industries, Inc., trade name "Tetron C-119 Skylark
- the spider spider was alive and dead with tweezers, and it was judged dead when there was no response.
- ⁇ Spider spider mortality of 80% or more
- ⁇ Spider spider mortality of 40% or more and less than 80%
- X Spider spider mortality of less than 40%.
- Test pieces were prepared by injection molding using the resin compositions of Example 4 and Comparative Examples 6 and 7, and tensile strength (ASTM D 638), bending strength (ASTM D 790), and heat deflection temperature (AS TM) D 648, 4.6 kgZ cm 2 ) and gasoline resistance were tested.
- the gasoline resistance was determined by immersing a test piece (inner diameter 15 ⁇ , wall thickness 1.5mm, cylindrical shape with a length of 40mm) in gasoline (regular gasoline manufactured by Idemitsu Oil Co., Ltd.) at 25 ° C. The length of the test piece immediately after being taken out was measured and evaluated by the dimensional change before and after immersion.
- the molded articles of the examples have sufficient strength and heat resistance.
- the small animal control resin composition according to the present invention has strength, heat resistance, and chemical resistance that can be used as various structural members and the like, and can exhibit small animal control performance over a long period of time. It is possible to obtain a sex member.
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00900400A EP1145632B1 (en) | 1999-01-18 | 2000-01-14 | Resin compositions for controlling small animals and molded members for controlling small animals made thereof |
US09/889,130 US7368123B1 (en) | 1999-01-18 | 2000-01-14 | Pesticidal resin compositions and pesticidal products formed from the same |
DE60035483T DE60035483T2 (de) | 1999-01-18 | 2000-01-14 | Zusammensetzungen zur bekämpfung von kleintieren sowie daraus hergestellte formteile zur bekämpfung von kleintieren |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP00974399A JP4361152B2 (ja) | 1999-01-18 | 1999-01-18 | 小動物防除性樹脂組成物及び該樹脂組成物を成形してなる小動物防除性部材 |
JP11/9743 | 1999-01-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000041564A1 true WO2000041564A1 (fr) | 2000-07-20 |
Family
ID=11728801
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2000/000160 WO2000041564A1 (fr) | 1999-01-18 | 2000-01-14 | Compositions de resine servant a lutter contre de petits animaux et elements moules dans cette resine |
Country Status (5)
Country | Link |
---|---|
US (1) | US7368123B1 (ja) |
EP (1) | EP1145632B1 (ja) |
JP (1) | JP4361152B2 (ja) |
DE (1) | DE60035483T2 (ja) |
WO (1) | WO2000041564A1 (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8404260B2 (en) | 2008-04-02 | 2013-03-26 | Bayer Cropscience Lp | Synergistic pesticide compositions |
JP5604753B2 (ja) * | 2010-06-24 | 2014-10-15 | 株式会社ニックス | 小動物防除性樹脂組成物 |
JP2015078138A (ja) * | 2013-10-15 | 2015-04-23 | 株式会社ニックス | 小動物防除性樹脂組成物 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03153601A (ja) * | 1989-11-09 | 1991-07-01 | Mitsubishi Petrochem Co Ltd | 抗ダニ性熱可塑性樹脂組成物 |
EP0569791A2 (de) * | 1992-05-12 | 1993-11-18 | Bayer Ag | Formkörper zur Bekämpfung von Ektoparasiten bei Tieren |
JPH07157630A (ja) * | 1993-12-08 | 1995-06-20 | Polyplastics Co | ポリアセタール樹脂組成物 |
JPH09169916A (ja) * | 1995-12-19 | 1997-06-30 | Fukuvi Chem Ind Co Ltd | 防虫樹脂組成物およびその成形体 |
JPH09221592A (ja) * | 1996-02-15 | 1997-08-26 | Toray Ind Inc | ポリアミド樹脂組成物 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4184099A (en) * | 1977-04-27 | 1980-01-15 | International Flavors & Fragrances Inc. | Composition for slow release of volatile ingredients at _high temperature; and article comprising same |
US4405360A (en) * | 1979-06-22 | 1983-09-20 | Environmental Chemicals, Inc. | Controlled release of herbicide compounds utilizing a thermoplastic matrix |
US5374600A (en) * | 1990-01-29 | 1994-12-20 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Oil-absorbent polymer and use therefor |
JPH0624903A (ja) * | 1992-04-09 | 1994-02-01 | Nippon Bayeragrochem Kk | 植物処理剤 |
DE69320167T2 (de) * | 1992-12-25 | 1999-01-21 | Japan Synthetic Rubber Co Ltd | Antibakterielle Kunstharzzusammensetzung |
IT1273607B (it) * | 1995-04-26 | 1997-07-08 | Ciba Geigy Spa | Combinazione di stabilizzanti per polimeri sintetici organici |
DE69600983T2 (de) * | 1995-04-28 | 1999-04-15 | Bayer Agrochem Kk | Kapselpräparate zur Behandlung von Pflanzen |
JPH0914358A (ja) | 1995-06-29 | 1997-01-14 | Tsubakimoto Chain Co | 抗菌性及び防かび性のチェーン |
-
1999
- 1999-01-18 JP JP00974399A patent/JP4361152B2/ja not_active Expired - Fee Related
-
2000
- 2000-01-14 DE DE60035483T patent/DE60035483T2/de not_active Expired - Lifetime
- 2000-01-14 EP EP00900400A patent/EP1145632B1/en not_active Expired - Lifetime
- 2000-01-14 US US09/889,130 patent/US7368123B1/en not_active Expired - Fee Related
- 2000-01-14 WO PCT/JP2000/000160 patent/WO2000041564A1/ja active IP Right Grant
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03153601A (ja) * | 1989-11-09 | 1991-07-01 | Mitsubishi Petrochem Co Ltd | 抗ダニ性熱可塑性樹脂組成物 |
EP0569791A2 (de) * | 1992-05-12 | 1993-11-18 | Bayer Ag | Formkörper zur Bekämpfung von Ektoparasiten bei Tieren |
JPH07157630A (ja) * | 1993-12-08 | 1995-06-20 | Polyplastics Co | ポリアセタール樹脂組成物 |
JPH09169916A (ja) * | 1995-12-19 | 1997-06-30 | Fukuvi Chem Ind Co Ltd | 防虫樹脂組成物およびその成形体 |
JPH09221592A (ja) * | 1996-02-15 | 1997-08-26 | Toray Ind Inc | ポリアミド樹脂組成物 |
Non-Patent Citations (1)
Title |
---|
See also references of EP1145632A4 * |
Also Published As
Publication number | Publication date |
---|---|
US7368123B1 (en) | 2008-05-06 |
DE60035483D1 (de) | 2007-08-23 |
JP4361152B2 (ja) | 2009-11-11 |
EP1145632A4 (en) | 2006-01-11 |
EP1145632A1 (en) | 2001-10-17 |
DE60035483T2 (de) | 2007-12-06 |
JP2000212005A (ja) | 2000-08-02 |
EP1145632B1 (en) | 2007-07-11 |
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