WO2000017922A1 - PROCEDE POUR AMINCIR CHIMIQUEMENT, PAR VOIE HUMIDE, DES COUCHES DE Si DANS UNE REGION EMETTEUR ACTIF D'UN TRANSISTOR BIPOLAIRE - Google Patents
PROCEDE POUR AMINCIR CHIMIQUEMENT, PAR VOIE HUMIDE, DES COUCHES DE Si DANS UNE REGION EMETTEUR ACTIF D'UN TRANSISTOR BIPOLAIRE Download PDFInfo
- Publication number
- WO2000017922A1 WO2000017922A1 PCT/DE1999/003068 DE9903068W WO0017922A1 WO 2000017922 A1 WO2000017922 A1 WO 2000017922A1 DE 9903068 W DE9903068 W DE 9903068W WO 0017922 A1 WO0017922 A1 WO 0017922A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- silicon
- base
- bipolar transistor
- wet
- Prior art date
Links
- 239000000126 substance Substances 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims abstract description 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 12
- 239000010703 silicon Substances 0.000 claims abstract description 12
- 239000010410 layer Substances 0.000 claims description 76
- 239000002019 doping agent Substances 0.000 claims description 12
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 5
- 239000002356 single layer Substances 0.000 claims description 4
- 238000005530 etching Methods 0.000 claims description 3
- 229910021421 monocrystalline silicon Inorganic materials 0.000 claims 2
- 238000011065 in-situ storage Methods 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000003631 wet chemical etching Methods 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 230000007704 transition Effects 0.000 abstract 1
- 238000007704 wet chemistry method Methods 0.000 abstract 1
- 229920005591 polysilicon Polymers 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000000407 epitaxy Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 229910021419 crystalline silicon Inorganic materials 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66234—Bipolar junction transistors [BJT]
- H01L29/66242—Heterojunction transistors [HBT]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/30604—Chemical etching
Definitions
- the invention relates to a method for wet chemical thinning of Si layers in the active emitter region of a bipolar transistor.
- the high-speed properties of bipolar transistors can be further improved with the aid of epitaxial processes for producing the base and the base connection.
- the option of in-situ doping is used to achieve lower base widths and layer resistances.
- the deposition of heterolayers has a favorable effect on the setting of base layer resistance and current gain.
- the method of differential epitaxy was used to generate epitaxial base layers. Differential epitaxy means that epitaxial growth takes place in both semiconductor and insulator areas. In this way, the inner base and the base connection can be created on the isolator area at the same time.
- the disadvantage here is that the thickness of the epitaxial layer of the inner base cannot be set independently of that of the base connection on the insulator region.
- the object of the invention is to propose a method for wet chemical thinning of the epitaxial silicon layer in the active emitter region of a bipolar transistor, which
- a sufficiently small epitaxial layer thickness in the area of the active base-emitter junction A thicker epitaxial layer between the emitter and base and in the outer base region enables the lowest possible base connection resistances.
- the epitaxial layer thickness above the base is generally increased and subsequently made within the active emitter region by means of suitable methods, such as, for example, B. wet chemical etching, reduced.
- this object is achieved by generating a wet chemical surface relief in the area of the active emitter.
- an additional in-situ doping epitaxially in the cover layer above the deposited base.
- ALD atomic layer Doping
- the metering and the vertical positioning of the dopant layer are adjusted with atomic layer accuracy.
- This atomic layer accuracy of introducing the doping as an etch stop layer offers the advantage to adjust the thickness of the emitter layer to be etched with atomic layer accuracy
- the atomic layer doping is introduced during the deposition of the emitter layer.
- FIG. 1 Schematic representation of a bipolar transistor during the manufacture vers
- a Fig. 2 Schematic representation of a bipolar transistor during the manufacture vers
- Example 1 The invention will now be described using the example of the production of a bipolar transistor.
- 1 shows the implementation of the wet chemical thinning of the silicon cover layer 3 + 9 in the active emitter region 7 of a bipolar transistor with a base connection in the field insulation region.
- An epitaxial layer sequence consisting of buffer layer 1, in-situ doped base layer 2 and cover layer 3 + 9, in which there is an etching stop layer 5, covers the area of the future emitter as a single-crystal layer stack 1; 2; 3; 5; 9 and part of the field isolation region 6 as a polycrystalline layer stack 1/1; 2/1; 3/1; 5/1; 9/1.
- the structured epitaxial layer is covered with a dielectric 4, which was only removed in the area of the active emitter region 7.
- the doping dose of the etch stop layer 5 in the lid produced by means of ALD, is smaller than a monolayer of the respective dopant, so that the lid layer 9 lying above it has grown single-crystal.
- the cover layer is partially removed in the active emitter region.
- the etching stop layer 5 can be removed by means of likewise known wet chemical etching agents.
- An epitaxial layer sequence consisting of buffer layer 1, in-situ doped base layer 2 and cover layer 3, in which there is a dopant layer 10 which, due to the nature of its production, causes the cover layer 8 after the formation of the dopant layer 10 continues to grow polycrystalline, covers the area of the future emitter and part of the field isolation area 6 as a polycrystalline layer stack 1/1; 2/1; 3/1; 10/1; 8/1.
- the structured epitaxial layer is covered with a dielectric 4, which was only removed in the area of the active emitter region 7.
- the doping dose of the dopant layer 10 in the cover is greater than a monolayer of the respective dopant with a thickness of less than 3 nm, so that the cover layer 8 lying above it grows polycrystalline.
- the polycrystalline part of the cover layer 8, including the dopant layer 10 is removed in the active emitter region 7 with the aid of known wet chemical etching agents which remove polysilicon highly selectively with respect to the dielectric 4 and the crystalline silicon 3.
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Ceramic Engineering (AREA)
- Bipolar Transistors (AREA)
Abstract
L'invention concerne un procédé pour amincir chimiquement, par voie humide, des couches de Si dans une région émetteur d'un transistor bipolaire. L'invention a pour but de fournir un procédé permettant d'amincir chimiquement par voie humide la couche épitaxiée de silicium dans une région émetteur actif d'un transistor bipolaire, améliorant les propriétés de vitesse élevée du transistor bipolaire et permettant d'obtenir, en particulier dans la région de transition active base-émetteur, une épaisseur de couche épitaxiée suffisamment faible entre l'émetteur et la base et, dans la région de base extérieure, une couche épitaxiée plus épaisse, en vue de réaliser des résistances de connexion de base aussi faibles que possible. Ce but est atteint, conformément à l'invention, grâce à une production en relief en surface, chimiquement par voie humide, dans la région de l'émetteur actif. Pour obtenir des érosions déterminées de silicium dans la région de l'émetteur actif, il est avantageux de réaliser un dopage in situ supplémentaire, par épitaxie, dans la couche du couvercle, au-dessus de la base séparée. Ces dopages in situ servent de couches d'arrêt de gravure permettant un enlèvement déterminé de silicium, de façon bien reproductible, avec des agents d'attaque chimique par voie humide de types connus. Comme procédé de production de la couche d'arrêt d'attaque, on utilise l''Atomic Layer Doping' (dopage par couche atomique) (ALD).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1998145790 DE19845790B4 (de) | 1998-09-21 | 1998-09-21 | Verfahren zur naßchemischen Abdünnung von Si-Schichten im aktiven Emittergebiet eines Bipolartransistors |
DE19845790.1 | 1998-09-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000017922A1 true WO2000017922A1 (fr) | 2000-03-30 |
Family
ID=7883442
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE1999/003068 WO2000017922A1 (fr) | 1998-09-21 | 1999-09-20 | PROCEDE POUR AMINCIR CHIMIQUEMENT, PAR VOIE HUMIDE, DES COUCHES DE Si DANS UNE REGION EMETTEUR ACTIF D'UN TRANSISTOR BIPOLAIRE |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE19845790B4 (fr) |
WO (1) | WO2000017922A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004053393B4 (de) | 2004-11-05 | 2007-01-11 | Atmel Germany Gmbh | Verfahren zur Herstellung einer vertikal integrierten Kaskodenstruktur und vertikal integrierte Kaskodenstruktur |
DE102004053394B4 (de) | 2004-11-05 | 2010-08-19 | Atmel Automotive Gmbh | Halbleiteranordnung und Verfahren zur Herstellung einer Halbleiteranordnung |
DE102004055213B4 (de) * | 2004-11-16 | 2009-04-09 | Atmel Germany Gmbh | Verfahren zur Herstellung einer integrierten Schaltung auf einem Halbleiterplättchen |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0483487A1 (fr) * | 1990-10-31 | 1992-05-06 | International Business Machines Corporation | Transistor à base epitaxiale auto-aligné et sa méthode de fabrication |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5198372A (en) * | 1986-01-30 | 1993-03-30 | Texas Instruments Incorporated | Method for making a shallow junction bipolar transistor and transistor formed thereby |
US5096842A (en) * | 1988-05-16 | 1992-03-17 | Kabushiki Kaisha Toshiba | Method of fabricating bipolar transistor using self-aligned polysilicon technology |
JPH06101473B2 (ja) * | 1988-12-05 | 1994-12-12 | 日本電気株式会社 | 半導体装置 |
US5024957A (en) * | 1989-02-13 | 1991-06-18 | International Business Machines Corporation | Method of fabricating a bipolar transistor with ultra-thin epitaxial base |
US5648294A (en) * | 1989-11-29 | 1997-07-15 | Texas Instruments Incorp. | Integrated circuit and method |
US5160994A (en) * | 1990-02-19 | 1992-11-03 | Nec Corporation | Heterojunction bipolar transistor with improved base layer |
JPH0669227A (ja) * | 1992-05-29 | 1994-03-11 | Texas Instr Inc <Ti> | 化合物半導体のヘテロ接合バイポーラトランジスタ及びその製造方法 |
JPH06132298A (ja) * | 1992-10-14 | 1994-05-13 | Mitsubishi Electric Corp | 半導体装置の製造方法 |
US5593905A (en) * | 1995-02-23 | 1997-01-14 | Texas Instruments Incorporated | Method of forming stacked barrier-diffusion source and etch stop for double polysilicon BJT with patterned base link |
DE19533677A1 (de) * | 1995-09-12 | 1997-03-13 | Daimler Benz Ag | Verfahren zur Herstellung eines Heterobipolartransistors |
US5640025A (en) * | 1995-12-01 | 1997-06-17 | Motorola | High frequency semiconductor transistor |
WO1997024757A1 (fr) * | 1995-12-28 | 1997-07-10 | Philips Electronics N.V. | Procede de production d'un transistor bipolaire vertical a alignement automatique sur un dispositif du type silicium sur isolant |
DE19609933A1 (de) * | 1996-03-14 | 1997-09-18 | Daimler Benz Ag | Verfahren zur Herstellung eines Heterobipolartransistors |
US5773350A (en) * | 1997-01-28 | 1998-06-30 | National Semiconductor Corporation | Method for forming a self-aligned bipolar junction transistor with silicide extrinsic base contacts and selective epitaxial grown intrinsic base |
-
1998
- 1998-09-21 DE DE1998145790 patent/DE19845790B4/de not_active Expired - Fee Related
-
1999
- 1999-09-20 WO PCT/DE1999/003068 patent/WO2000017922A1/fr active Application Filing
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0483487A1 (fr) * | 1990-10-31 | 1992-05-06 | International Business Machines Corporation | Transistor à base epitaxiale auto-aligné et sa méthode de fabrication |
Non-Patent Citations (1)
Title |
---|
LAN W H ET AL: "RECESSED-GATE ALGAAS/INGAAS/GAAS PSEUDORPMORPHIC HEMT WITH SI- PLANAR-DOPED ETCH STOP LAYER", ELECTRONICS LETTERS,GB,IEE STEVENAGE, vol. 31, no. 7, 30 March 1995 (1995-03-30), pages 592 - 594, XP000504333, ISSN: 0013-5194 * |
Also Published As
Publication number | Publication date |
---|---|
DE19845790A1 (de) | 2000-03-23 |
DE19845790B4 (de) | 2008-12-04 |
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