WO1999060183A1 - Anti-haft-beschichtung und verfahren zu ihrer herstellung - Google Patents
Anti-haft-beschichtung und verfahren zu ihrer herstellung Download PDFInfo
- Publication number
- WO1999060183A1 WO1999060183A1 PCT/EP1999/003381 EP9903381W WO9960183A1 WO 1999060183 A1 WO1999060183 A1 WO 1999060183A1 EP 9903381 W EP9903381 W EP 9903381W WO 9960183 A1 WO9960183 A1 WO 9960183A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- coating
- welding
- coating according
- carbon
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/0605—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K31/00—Processes relevant to this subclass, specially adapted for particular articles or purposes, but not covered by only one of the preceding main groups
- B23K31/02—Processes relevant to this subclass, specially adapted for particular articles or purposes, but not covered by only one of the preceding main groups relating to soldering or welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/224—Anti-weld compositions; Braze stop-off compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K37/00—Auxiliary devices or processes, not specially adapted to a procedure covered by only one of the preceding main groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K37/00—Auxiliary devices or processes, not specially adapted to a procedure covered by only one of the preceding main groups
- B23K37/06—Auxiliary devices or processes, not specially adapted to a procedure covered by only one of the preceding main groups for positioning the molten material, e.g. confining it to a desired area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/235—Preliminary treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/30—Assembling printed circuits with electric components, e.g. with resistor
- H05K3/32—Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits
- H05K3/34—Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by soldering
- H05K3/3452—Solder masks
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/30—Self-sustaining carbon mass or layer with impregnant or other layer
Definitions
- Patent application non-stick coating and process for its production
- the invention relates to an Aftti adhesive coating for welding and soldering devices and electrical contacts according to the preamble of claim 1 and a method for its production according to claim 7.
- a preferred area of application is the protection of mounting, guiding and fixing devices for welding and / or soldering devices, and in particular of automated welding lines in the automotive industry.
- No. 4,156,807 proposes to apply a boron nitride layer to protect a workpiece against metallic contaminants in the form of hot welding spatter or welding beads.
- Boron nitride is very temperature-resistant and therefore prevents thermally induced damage to the workpiece from hot metallic contaminants.
- boron nitride is relatively soft, so that depending on the conditions of use of the workpiece to be machined, the layer may be mechanically damaged and the protective effect may be lost.
- boron nitride is a good electrical insulator, the insulation property of which is undesirable, for example in the case of electrical contacts to be protected. Another Another significant disadvantage is the only moderate non-stick effect of boron nitride against metallic contaminants.
- DE 41 10 539 A1 teaches the protection of a component with a high copper content against microscopic or macroscopic contamination such as flue gases or splashes of liquid metal by means of a protective layer made of titanium nitride or titanium carbonitride. Since the components in DE 41 10 539 A1 are to be changed as little as possible in terms of their electrical properties, these titanium-based hard materials are well suited there because of their high temperature stability and good electrical conductivity. As with boron nitride, their disadvantage is their moderate non-stick effect against metallic impurities. Furthermore, they have the disadvantage that these protective layers can be deposited in PVD or CVD processes with typically relatively high temperatures of more than 450 ° C. For this reason, such protective layers based on titanium cannot be used or can only be used to a limited extent in the case of temperature-sensitive substrates. Furthermore, the good electrical conductivity of the non-stick coating can be undesirable depending on the application.
- the invention has for its object to largely avoid the problems of the prior art and to provide an alternative for the above-mentioned protective layers against metallic contaminants from welding and soldering processes.
- This alternative protective layer is said to be thermally stable and, in particular, to have good non-stick properties in relation to the mostly ductile metallic impurities.
- the anti-stick effect is to be given in particular with respect to the commonly used materials of the welding and soldering devices, i.e. primarily compared to steels and die casting.
- Another task is to provide a hard protective layer with good wear and friction properties so that it can be used universally as mechanically as possible.
- Another task is to provide a non-stick layer which can be tuned in its electrical conductivity so that it can be used as universally as possible with regard to its electrical behavior.
- Another object is to provide a non-stick layer against metallic contaminants, which if possible does not damage the workpiece or component to be protected when it is applied.
- the coatings of diamond-like carbon according to the invention for preventing metallic contaminants from welding and / or soldering processes from adhering to a surface are very hard, temperature-stable and adhesion-inhibiting, show very good wear behavior and favorable friction behavior. These coatings can be deposited easily and inexpensively, in particular by gas phase deposition, and in particular by means of the PVD or the CVD method. This means that deposition is also possible on curved surfaces with a complicated surface geometry.
- a partial coating of the welding or soldering device is also possible.
- a partial coating can consist in coating at least the surface areas exposed to the metallic contaminants. These are, in particular, the guides as well as fixing and holding devices for the components to be joined, but also welding jaws and welding nozzles.
- Amorphous hydrocarbon layers (aC.H), hydrogen-free amorphous hydrocarbon layers (a: C) and silicon-containing hydrocarbon layers (Si: CH) are particularly advantageous for the purposes of the present invention.
- the latter have particularly good non-stick properties that match those of Teflon ®.
- Metal-containing carbon coating (Me-C: H coating) can still ensure good electrical contact. Due to the composition and the increase in the metal content, which is preferably between 10% and 49.9%, the electrical conductivity of the coating can be increased and optimized for the particular application.
- the metals that are used are preferably metals from subgroups of the periodic table of the elements such as W, Zr, Cr, Au, Ag, Pt, Cu, Ta, Hf and V, but also Ti.
- the layer thickness is between 0.2 ⁇ m to 15 ⁇ m.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Optics & Photonics (AREA)
- Plasma & Fusion (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Vapour Deposition (AREA)
- Arc Welding In General (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Laminated Bodies (AREA)
- Connections Effected By Soldering, Adhesion, Or Permanent Deformation (AREA)
- Manufacture Of Switches (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP99952100A EP1080244B1 (de) | 1998-05-18 | 1999-05-17 | Anti-haft-beschichtung und verfahren zu ihrer herstellung |
AT99952100T ATE210206T1 (de) | 1998-05-18 | 1999-05-17 | Anti-haft-beschichtung und verfahren zu ihrer herstellung |
US09/700,738 US6478843B1 (en) | 1998-05-18 | 1999-05-17 | Anti-adherent coating and method for the production thereof |
DE59900506T DE59900506D1 (de) | 1998-05-18 | 1999-05-17 | Anti-haft-beschichtung und verfahren zu ihrer herstellung |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19822273.4 | 1998-05-18 | ||
DE19822273 | 1998-05-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999060183A1 true WO1999060183A1 (de) | 1999-11-25 |
Family
ID=7868177
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1999/003381 WO1999060183A1 (de) | 1998-05-18 | 1999-05-17 | Anti-haft-beschichtung und verfahren zu ihrer herstellung |
Country Status (6)
Country | Link |
---|---|
US (1) | US6478843B1 (de) |
EP (1) | EP1080244B1 (de) |
AT (1) | ATE210206T1 (de) |
DE (2) | DE19922161A1 (de) |
ES (1) | ES2169954T3 (de) |
WO (1) | WO1999060183A1 (de) |
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DE10119348A1 (de) * | 2001-04-20 | 2002-10-24 | Ego Elektro Geraetebau Gmbh | Verfahren zum Herstellen eines Heizkörpers und Heizkörper |
JP2008506036A (ja) * | 2004-07-09 | 2008-02-28 | オー・ツェー・エリコン・バルザース・アクチェンゲゼルシャフト | Me−DLC硬質材料コーティングを備えた銅含有導電性材料 |
US7956175B2 (en) | 2003-09-11 | 2011-06-07 | Ibis Biosciences, Inc. | Compositions for use in identification of bacteria |
US7964343B2 (en) | 2003-05-13 | 2011-06-21 | Ibis Biosciences, Inc. | Method for rapid purification of nucleic acids for subsequent analysis by mass spectrometry by solution capture |
US8017358B2 (en) | 2001-03-02 | 2011-09-13 | Ibis Biosciences, Inc. | Method for rapid detection and identification of bioagents |
US8026084B2 (en) | 2005-07-21 | 2011-09-27 | Ibis Biosciences, Inc. | Methods for rapid identification and quantitation of nucleic acid variants |
US8057993B2 (en) | 2003-04-26 | 2011-11-15 | Ibis Biosciences, Inc. | Methods for identification of coronaviruses |
US8073627B2 (en) | 2001-06-26 | 2011-12-06 | Ibis Biosciences, Inc. | System for indentification of pathogens |
US8084207B2 (en) | 2005-03-03 | 2011-12-27 | Ibis Bioscience, Inc. | Compositions for use in identification of papillomavirus |
US8097416B2 (en) | 2003-09-11 | 2012-01-17 | Ibis Biosciences, Inc. | Methods for identification of sepsis-causing bacteria |
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US8158936B2 (en) | 2009-02-12 | 2012-04-17 | Ibis Biosciences, Inc. | Ionization probe assemblies |
US8158354B2 (en) | 2003-05-13 | 2012-04-17 | Ibis Biosciences, Inc. | Methods for rapid purification of nucleic acids for subsequent analysis by mass spectrometry by solution capture |
US8163895B2 (en) | 2003-12-05 | 2012-04-24 | Ibis Biosciences, Inc. | Compositions for use in identification of orthopoxviruses |
US8173957B2 (en) | 2004-05-24 | 2012-05-08 | Ibis Biosciences, Inc. | Mass spectrometry with selective ion filtration by digital thresholding |
US8182992B2 (en) | 2005-03-03 | 2012-05-22 | Ibis Biosciences, Inc. | Compositions for use in identification of adventitious viruses |
US8187814B2 (en) | 2004-02-18 | 2012-05-29 | Ibis Biosciences, Inc. | Methods for concurrent identification and quantification of an unknown bioagent |
US8214154B2 (en) | 2001-03-02 | 2012-07-03 | Ibis Biosciences, Inc. | Systems for rapid identification of pathogens in humans and animals |
US8268565B2 (en) | 2001-03-02 | 2012-09-18 | Ibis Biosciences, Inc. | Methods for identifying bioagents |
US8298760B2 (en) | 2001-06-26 | 2012-10-30 | Ibis Bioscience, Inc. | Secondary structure defining database and methods for determining identity and geographic origin of an unknown bioagent thereby |
US8407010B2 (en) | 2004-05-25 | 2013-03-26 | Ibis Biosciences, Inc. | Methods for rapid forensic analysis of mitochondrial DNA |
DE102013203464A1 (de) | 2013-02-28 | 2013-06-20 | E.G.O. Elektro-Gerätebau GmbH | Verfahren zur Herstellung einer Heizeinrichtung und Heizeinrichtung |
US8534447B2 (en) | 2008-09-16 | 2013-09-17 | Ibis Biosciences, Inc. | Microplate handling systems and related computer program products and methods |
US8546082B2 (en) | 2003-09-11 | 2013-10-01 | Ibis Biosciences, Inc. | Methods for identification of sepsis-causing bacteria |
US8550694B2 (en) | 2008-09-16 | 2013-10-08 | Ibis Biosciences, Inc. | Mixing cartridges, mixing stations, and related kits, systems, and methods |
US8563250B2 (en) | 2001-03-02 | 2013-10-22 | Ibis Biosciences, Inc. | Methods for identifying bioagents |
US8822156B2 (en) | 2002-12-06 | 2014-09-02 | Ibis Biosciences, Inc. | Methods for rapid identification of pathogens in humans and animals |
US8871471B2 (en) | 2007-02-23 | 2014-10-28 | Ibis Biosciences, Inc. | Methods for rapid forensic DNA analysis |
US8950604B2 (en) | 2009-07-17 | 2015-02-10 | Ibis Biosciences, Inc. | Lift and mount apparatus |
US9149473B2 (en) | 2006-09-14 | 2015-10-06 | Ibis Biosciences, Inc. | Targeted whole genome amplification method for identification of pathogens |
US9194877B2 (en) | 2009-07-17 | 2015-11-24 | Ibis Biosciences, Inc. | Systems for bioagent indentification |
US9598724B2 (en) | 2007-06-01 | 2017-03-21 | Ibis Biosciences, Inc. | Methods and compositions for multiple displacement amplification of nucleic acids |
US9873906B2 (en) | 2004-07-14 | 2018-01-23 | Ibis Biosciences, Inc. | Methods for repairing degraded DNA |
US9890408B2 (en) | 2009-10-15 | 2018-02-13 | Ibis Biosciences, Inc. | Multiple displacement amplification |
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DE102004003119A1 (de) * | 2004-01-21 | 2005-08-11 | BSH Bosch und Siemens Hausgeräte GmbH | Vorrichtung zum Erwärmen von Speisen mittels induktiver Kopplung und Vorrichtung zur Übertragung von Energie |
JP5049358B2 (ja) * | 2010-01-25 | 2012-10-17 | 株式会社神戸製鋼所 | 半導体検査装置用コンタクトプローブピンの基材上にタングステン含有ダイヤモンドライクカーボン皮膜を製造する方法 |
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GB2269105A (en) * | 1992-07-28 | 1994-02-02 | Dr Joseph Franks | Dental filling instrument with coated working surfaces |
WO1994012680A1 (en) * | 1992-11-25 | 1994-06-09 | Gehan Anil Joseph Amaratunga | Doping of highly tetrahedral diamond-like amorphous carbon |
Family Cites Families (4)
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US5728465A (en) * | 1991-05-03 | 1998-03-17 | Advanced Refractory Technologies, Inc. | Diamond-like nanocomposite corrosion resistant coatings |
JPH05228623A (ja) | 1992-02-17 | 1993-09-07 | Sumitomo Electric Ind Ltd | ダイヤモンド多結晶体半田付け工具 |
DE4417235A1 (de) | 1993-05-21 | 1994-11-24 | Fraunhofer Ges Forschung | Plasmapolymer-Schichtenfolge als Hartstoffschicht mit definiert einstellbarem Adhäsionsverhalten |
US5771873A (en) * | 1997-04-21 | 1998-06-30 | Ford Global Technologies, Inc. | Carbonaceous deposit-resistant coating for engine components |
-
1999
- 1999-05-12 DE DE19922161A patent/DE19922161A1/de not_active Ceased
- 1999-05-17 US US09/700,738 patent/US6478843B1/en not_active Expired - Fee Related
- 1999-05-17 AT AT99952100T patent/ATE210206T1/de active
- 1999-05-17 EP EP99952100A patent/EP1080244B1/de not_active Expired - Lifetime
- 1999-05-17 DE DE59900506T patent/DE59900506D1/de not_active Expired - Lifetime
- 1999-05-17 ES ES99952100T patent/ES2169954T3/es not_active Expired - Lifetime
- 1999-05-17 WO PCT/EP1999/003381 patent/WO1999060183A1/de active IP Right Grant
Patent Citations (3)
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US5100701A (en) * | 1987-04-29 | 1992-03-31 | Siemens Aktiengesellschaft | Solder-repelling coating for tools |
GB2269105A (en) * | 1992-07-28 | 1994-02-02 | Dr Joseph Franks | Dental filling instrument with coated working surfaces |
WO1994012680A1 (en) * | 1992-11-25 | 1994-06-09 | Gehan Anil Joseph Amaratunga | Doping of highly tetrahedral diamond-like amorphous carbon |
Non-Patent Citations (1)
Title |
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DE MARTINO C ET AL: "Improvement of mechanical properties of a-C:H by silicon addition", DIAMOND AND RELATED MATERIALS, vol. 6, no. 5-7, 1 April 1997 (1997-04-01), pages 559-563, XP004081096, ISSN: 0925-9635 * |
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US8563250B2 (en) | 2001-03-02 | 2013-10-22 | Ibis Biosciences, Inc. | Methods for identifying bioagents |
US8802372B2 (en) | 2001-03-02 | 2014-08-12 | Ibis Biosciences, Inc. | Methods for rapid forensic analysis of mitochondrial DNA and characterization of mitochondrial DNA heteroplasmy |
US8268565B2 (en) | 2001-03-02 | 2012-09-18 | Ibis Biosciences, Inc. | Methods for identifying bioagents |
US8017358B2 (en) | 2001-03-02 | 2011-09-13 | Ibis Biosciences, Inc. | Method for rapid detection and identification of bioagents |
US8265878B2 (en) | 2001-03-02 | 2012-09-11 | Ibis Bioscience, Inc. | Method for rapid detection and identification of bioagents |
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US8214154B2 (en) | 2001-03-02 | 2012-07-03 | Ibis Biosciences, Inc. | Systems for rapid identification of pathogens in humans and animals |
DE10119348A1 (de) * | 2001-04-20 | 2002-10-24 | Ego Elektro Geraetebau Gmbh | Verfahren zum Herstellen eines Heizkörpers und Heizkörper |
US8298760B2 (en) | 2001-06-26 | 2012-10-30 | Ibis Bioscience, Inc. | Secondary structure defining database and methods for determining identity and geographic origin of an unknown bioagent thereby |
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US8921047B2 (en) | 2001-06-26 | 2014-12-30 | Ibis Biosciences, Inc. | Secondary structure defining database and methods for determining identity and geographic origin of an unknown bioagent thereby |
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Also Published As
Publication number | Publication date |
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ES2169954T3 (es) | 2002-07-16 |
US6478843B1 (en) | 2002-11-12 |
DE19922161A1 (de) | 1999-12-09 |
EP1080244B1 (de) | 2001-12-05 |
ATE210206T1 (de) | 2001-12-15 |
EP1080244A1 (de) | 2001-03-07 |
DE59900506D1 (de) | 2002-01-17 |
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