WO1999010274A1 - Procede de production de diamants artificiels - Google Patents

Procede de production de diamants artificiels Download PDF

Info

Publication number
WO1999010274A1
WO1999010274A1 PCT/RU1998/000273 RU9800273W WO9910274A1 WO 1999010274 A1 WO1999010274 A1 WO 1999010274A1 RU 9800273 W RU9800273 W RU 9800273W WO 9910274 A1 WO9910274 A1 WO 9910274A1
Authority
WO
WIPO (PCT)
Prior art keywords
pressure
diamond
diamonds
fullerene
group
Prior art date
Application number
PCT/RU1998/000273
Other languages
English (en)
Russian (ru)
Inventor
Alexandr Yakovlevich Vul
Sergei Viktorovich Kidalov
Sergei Vasilievich Kozyrev
Valery Mikhailovich Davidenko
Veniamin Alexandrovich Yashin
Sukyas Semenovich Ordanyan
Vladislav Sergeevich Lysanov
Original Assignee
Zakrytoe Aktsionernoe Obschestvo 'nauchno-Tekhnicheskoe Agentstvo 'intellekt'
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zakrytoe Aktsionernoe Obschestvo 'nauchno-Tekhnicheskoe Agentstvo 'intellekt' filed Critical Zakrytoe Aktsionernoe Obschestvo 'nauchno-Tekhnicheskoe Agentstvo 'intellekt'
Publication of WO1999010274A1 publication Critical patent/WO1999010274A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
    • B01J3/06—Processes using ultra-high pressure, e.g. for the formation of diamonds; Apparatus therefor, e.g. moulds or dies
    • B01J3/062—Processes using ultra-high pressure, e.g. for the formation of diamonds; Apparatus therefor, e.g. moulds or dies characterised by the composition of the materials to be processed
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/25—Diamond
    • C01B32/26—Preparation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2203/00—Processes utilising sub- or super atmospheric pressure
    • B01J2203/06—High pressure synthesis
    • B01J2203/0605—Composition of the material to be processed
    • B01J2203/061—Graphite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2203/00—Processes utilising sub- or super atmospheric pressure
    • B01J2203/06—High pressure synthesis
    • B01J2203/0605—Composition of the material to be processed
    • B01J2203/0615—Fullerene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2203/00—Processes utilising sub- or super atmospheric pressure
    • B01J2203/06—High pressure synthesis
    • B01J2203/065—Composition of the material produced
    • B01J2203/0655—Diamond

Definitions

  • the invention is available for the use of high-output materials.
  • the method of producing an artificial diamond including the pulsed effect on the sample of the metal and the pressure and 2 nag ⁇ ev ⁇ m ⁇ u ⁇ em ⁇ us ⁇ aniya im ⁇ ulsa ele ⁇ iches ⁇ g ⁇ ⁇ a ⁇ ⁇ b ⁇ aztsu, s ⁇ de ⁇ zhaschemu me ⁇ all g ⁇ u ⁇ y of: copper, aluminum, ni ⁇ el, zhelez ⁇ with v ⁇ lyucheniem mel ⁇ dis ⁇ e ⁇ sny ⁇ chas ⁇ its g ⁇ a ⁇ i ⁇ a, s ⁇ edny ⁇ azme ⁇ ⁇ - 5 ⁇ y ⁇ m ⁇ m 5-150, ⁇ i following s ⁇ n ⁇ shenii ⁇ m ⁇ nen ⁇ v. Rev.%: group - 5-55, metal of the indicated group - 45-95 (see patent ⁇ ⁇ 1820890, ⁇ P ⁇ ⁇ 01 ⁇ 31/06. published 07.06.93).
  • the method of producing diamonds is known, including exposure to carbon-bearing material with high pressure and heating in the region of stability of diamond.
  • the carbon-friendly material used is al-ka-carbine in ammo. Larsa-karbin may
  • a well-known method makes it possible to speed up the process and to increase the output of diamonds, but the same output rate still turns out to be short
  • a well-known method of operation uses a measurement of high temperature and pressure and does not prevent the production of diamonds in the form of 3 install
  • the method of producing diamond is known, including the compression of carbon-containing material for a good value and its heating with a pressure of 5 after that.
  • the material used is different for different weight (see otherwise).
  • a pressure gradient above 1 GPa / mm may be generated.
  • the value of the main pressure reaches 15-25 GPa.
  • the method of acquiring diamonds from the original raw materials containing the carbon components, including the main components, is known.
  • the most commercially available materials are sulleren C ⁇ i> or carbon
  • the closest to the claimed method of production of artificial x diamonds are the methods of production of diamonds. Taken for just because it coincides with the claimed method for the largest number 4 facts
  • the method includes operating on a fully-integrated vehicle located between two layers of a total mass of about 10% of the total mass. a pressure of 6.7 GPa and heating to a temperature of 5 parts 200-1850 ° C with catalysts: nickel.
  • a well-known method of production allows to increase the output of diamonds up to 10% of the order of 90%;
  • the objective of the present invention was to develop a cost-effective way of producing artificial diamonds, which would increase the pressure to a higher pressure.
  • the task posed is solved in that way in the process of making artificial diamonds.
  • Fullerene may be introduced in the form of emitting soot or as an extract of ⁇ l-25 lerenes.
  • a nec- essary condition for the production of increased diamond output is the separation of fullerene in the bulk of the group.
  • the inventive method for the production of artificial diamonds is as follows. PREPARES A SHILE FROM A GROUP WITH ADDITION
  • thermo-electric isolating tank closing with burnt-down powder pouches from a mixture of slab and lime.
  • the charged container places high pressure in the appliance of the type "very hot”, compresses to 4.5 GPa, and heats up at a constant speed.
  • Example 6 They also handle the same operation and pressure, at the same time and at the same time. and that in Example 1, with the addition of fullerenes C 60 + C 0 in the amount of 0.6 wt.% of the mass of the mixture, introducing them from 20 of the extract. For the transfer of the group to diamond, it averaged 22.7% of the total sintering. Example 6.
  • Example 8 They perform the same operations and pressure and the same pressure, at the same time as 30 hours and the temperature. and that in Example 6, with the addition of fullerenes Sat + C 70 in the amount of 0.6 wt.% of the mass of the mixture, entering them from the fullerene extract. For the transition of the group into diamond, it was in the environment 8 it 55.0% from one week. Example 8.
  • Example 10 It takes the same operating conditions and pressure at the same time, 5 times and temperature, and that is also in the case of 6. With the addition of fullerenes of + + 70 , the mass is equal to 0.01%. . For the transition of the group to diamond, it averaged 57% of the single sintering. Example 9. 10 The same operations and pressures are the same as the pressure, the time of the discharge and the temperature. and that in Example 1. with the addition of C 6 auxiliary + C 70 fullerenes in the amount of 0.62 wt.% of the mass of the mixture, entering it from the fullerene extract. For the transition to diamond, it averaged 22.5% of the total sintering. 15 Example 10
  • Example 12 We also performed the same operations and pressures at the same time, at the same time 30 times and at the temperature, which, as in Example 1, were processed without adding fullerene. For the transfer of the group to diamond, it averaged 22.6% of the total sintering. 9 Example 12.
  • the claimed method of producing artificial diamonds was amended under conditions of industrial use.
  • 1740 extracts from a shiite containing 0.15% fullerenes were obtained.
  • the share of diamond output was 52.5% on average.
  • Out of shechity. containing 0.225% of fullerenes, 1710 seconds were obtained.
  • the share of diamond output in the average was 15 58.3%. It was also obtained in 1780 sec. Of shiita, containing 0.3% of the percentage.
  • the average share of the transfer to diamond amounted to 54.2%.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

Cette invention concerne un procédé de production de diamants artificiels, lequel se rapporte aux techniques de production de matériaux d'une grande dureté et, plus précisément, à la synthèse de diamants que l'on utilise principalement dans la fabrication d'instruments diamantés. Ce procédé de production de diamants artificiels consiste à exercer une action sur du graphite contenant du fullerène et sur un catalyseur, ceci en appliquant une pression et une température dans la plage de stabilité du diamant, puis en maintenant le mélange à la température et à la pression de synthèse. Ce procédé se caractérise en ce que l'on introduit du fullerène selon une quantité représentant de 10-2 à 6 x 10-1 % en poids de la masse de graphite, et en ce que ledit fullerène est réparti dans la masse de graphite. Le fullerène peut être introduit sous forme de suies contenant du fullerène ou sous forme de concentré de fullerènes. Ce procédé permet d'accroître la production de diamants artificiels à des pressions ne dépassant pas 5,5 GPa.
PCT/RU1998/000273 1997-08-22 1998-08-20 Procede de production de diamants artificiels WO1999010274A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU97114492 1997-08-22
RU97114492A RU2131763C1 (ru) 1997-08-22 1997-08-22 Способ получения искусственных алмазов

Publications (1)

Publication Number Publication Date
WO1999010274A1 true WO1999010274A1 (fr) 1999-03-04

Family

ID=20196678

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU1998/000273 WO1999010274A1 (fr) 1997-08-22 1998-08-20 Procede de production de diamants artificiels

Country Status (2)

Country Link
RU (1) RU2131763C1 (fr)
WO (1) WO1999010274A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7842111B1 (en) 2008-04-29 2010-11-30 Us Synthetic Corporation Polycrystalline diamond compacts, methods of fabricating same, and applications using same
US7841428B2 (en) 2006-02-10 2010-11-30 Us Synthetic Corporation Polycrystalline diamond apparatuses and methods of manufacture
US7972397B2 (en) 2006-07-31 2011-07-05 Us Synthetic Corporation Methods of manufacturing a polycrystalline diamond element using SP2-carbon-containing particles
US8986408B1 (en) 2008-04-29 2015-03-24 Us Synthetic Corporation Methods of fabricating polycrystalline diamond products using a selected amount of graphite particles

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106622031A (zh) * 2016-12-20 2017-05-10 吕华伟 一种新型二维复合超硬材料及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2684090A1 (fr) * 1991-11-27 1993-05-28 Centre Nat Rech Scient Utilisation de fullerenes comme produits de depart dans la fabrication de diamant.
WO1993011068A1 (fr) * 1991-11-25 1993-06-10 Gruen Dieter M Conversion de fullerene en diamant
WO1994021557A1 (fr) * 1993-03-23 1994-09-29 Gruen Dieter M Conversion de fullerenes en diamant
RU2108288C1 (ru) * 1995-10-02 1998-04-10 Научно-технический Центр "Сверхтвердые Материалы" Полиморфное соединение углерода

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1644996A1 (ru) * 1989-04-21 1991-04-30 Ю. А Истомин и В Ю Истомин Способ получени алмазов

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1993011068A1 (fr) * 1991-11-25 1993-06-10 Gruen Dieter M Conversion de fullerene en diamant
US5328676A (en) * 1991-11-25 1994-07-12 Gruen Dieter M Conversion of fullerenes to diamond
FR2684090A1 (fr) * 1991-11-27 1993-05-28 Centre Nat Rech Scient Utilisation de fullerenes comme produits de depart dans la fabrication de diamant.
WO1994021557A1 (fr) * 1993-03-23 1994-09-29 Gruen Dieter M Conversion de fullerenes en diamant
RU2108288C1 (ru) * 1995-10-02 1998-04-10 Научно-технический Центр "Сверхтвердые Материалы" Полиморфное соединение углерода

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7841428B2 (en) 2006-02-10 2010-11-30 Us Synthetic Corporation Polycrystalline diamond apparatuses and methods of manufacture
US8501144B1 (en) 2006-02-10 2013-08-06 Us Synthetic Corporation Polycrystalline diamond apparatuses and methods of manufacture
US7972397B2 (en) 2006-07-31 2011-07-05 Us Synthetic Corporation Methods of manufacturing a polycrystalline diamond element using SP2-carbon-containing particles
US8246701B2 (en) 2006-07-31 2012-08-21 Us Synthetic Corporation Methods of fabricating polycrystalline diamond elements and compacts using SP2-carbon-containing particles
US8936117B2 (en) 2006-07-31 2015-01-20 Us Synthetic Corporation Methods of fabricating polycrystalline diamond elements and compacts using SP2-carbon-containing particles
US9434050B2 (en) 2006-07-31 2016-09-06 Us Synthetic Corporation Methods of fabricating abrasive elements using SP2-carbon-containing particles
US7842111B1 (en) 2008-04-29 2010-11-30 Us Synthetic Corporation Polycrystalline diamond compacts, methods of fabricating same, and applications using same
US8734550B1 (en) 2008-04-29 2014-05-27 Us Synthetic Corporation Polycrystalline diamond compact
US8986408B1 (en) 2008-04-29 2015-03-24 Us Synthetic Corporation Methods of fabricating polycrystalline diamond products using a selected amount of graphite particles
US9777537B1 (en) 2008-04-29 2017-10-03 Us Synthetic Corporation Polycrystalline diamond compacts

Also Published As

Publication number Publication date
RU2131763C1 (ru) 1999-06-20

Similar Documents

Publication Publication Date Title
JP2682486B2 (ja) カーボンナノチューブの精製方法
SU644728A1 (ru) Способ получени карбида титана
US3306720A (en) Method for the production of diamond compact abrasives
WO1999010274A1 (fr) Procede de production de diamants artificiels
CA2702021A1 (fr) Utilisation de la technique de frittage flash pour la synthese et la densification d'iodoapatites
JP4174689B2 (ja) 予備合金化された、銅含有粉末およびダイヤモンド工具の製造におけるその使用
US2246165A (en) Method for producing sintered hard metal from pulverulent materials
US2134950A (en) Graphitized carbon black
US4017426A (en) Highly porous conductive ceramics and a method for the preparation of same
US3003966A (en) Polycrystalline garnet materials
CA1157626A (fr) Methode d'epistaxie de diamants
RU2443507C2 (ru) Способ переработки отходов твердого сплава вк8 электроэрозионным диспергированием
US6030596A (en) Synthesis of diamonds
WO2003086971A1 (fr) Procede de synthese de materiaux superdurs
RU2128624C1 (ru) Способ получения углеродной смеси высокой реакционной способности и устройство для его осуществления
RU2229434C2 (ru) Способ получения кубического нитрида бора повышенной прочности
JP2560252B2 (ja) 窒化ケイ素微粉末及びその製造方法
JP2793691B2 (ja) 窒化ジルコニウム粉末の製造方法
DE102011014204B4 (de) Verfahren zur Synthese von Diamanten
FR2620865A1 (fr) Procede de preparation de supraconducteurs et produits ainsi obtenus
US2042684A (en) Method of securing a homogeneous mixture of hard materials and matrix metals
RU2142407C1 (ru) Способ очистки кубического нитрида бора
JPS6253218B2 (fr)
CA1120628A (fr) Poudre d'aluminium ne produisant pas de poussiere et dispersible dans l'eau
FR2555154A1 (fr) Procede de preparation d'oxyde metallique modifie

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): BY CN JP UA US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
122 Ep: pct application non-entry in european phase