WO1998006884A1 - Verfahren und vorrichtung zum elektrochemischen behandeln langgestreckter gegenstände - Google Patents
Verfahren und vorrichtung zum elektrochemischen behandeln langgestreckter gegenstände Download PDFInfo
- Publication number
- WO1998006884A1 WO1998006884A1 PCT/EP1997/004341 EP9704341W WO9806884A1 WO 1998006884 A1 WO1998006884 A1 WO 1998006884A1 EP 9704341 W EP9704341 W EP 9704341W WO 9806884 A1 WO9806884 A1 WO 9806884A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- electrode
- treated
- sealing means
- treatment
- electrochemically
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F7/00—Constructional parts, or assemblies thereof, of cells for electrolytic removal of material from objects; Servicing or operating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/06—Suspending or supporting devices for articles to be coated
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/02—Electroplating of selected surface areas
- C25D5/022—Electroplating of selected surface areas using masking means
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/04—Tubes; Rings; Hollow bodies
Definitions
- the invention relates to a method and a device for the electrochemical treatment of elongated objects, in particular for the electrochemical etching or metallization of preferably rod-shaped items to be treated.
- Masked ends i.e. shielded in such a way that certain areas of the rods no metal is deposited.
- the boundaries between the areas to be coated and the areas not to be coated are specified, with small tolerances being observed:
- the transition between the areas to be coated and the areas not to be coated must be within +/- 3, for example
- the hard chrome layer must be uniformly thick up to these limits. A layer thickness increase or decrease at the borders must be avoided. Furthermore, the layer must be very uniformly thick over the entire circumference of the rod in order to avoid subsequent processing by grinding.
- the rods are attached to racks, which in turn are attached to transportable product carriers.
- the frames are provided with individual masks so that both rod ends are not coated in the area provided. Since different shock absorber cylinders with variable rod lengths, diameters and coating areas in the middle of the rod are to be treated, a sufficient number of masks and frames must be kept in stock.
- the frames are loaded with the rods by hand, since the large range of products that can be found in practice is one
- the frame technology is also disadvantageous because of the two-part masks to be used, including the power leads. It is not possible to use tubular electrodes to enclose the rod in the electrochemical cell with the known frames, since a rod usually fastened to the frame on both sides cannot be inserted into such an electrode. For this reason, the electrodes are divided and only face the rods on two sides. As a result, no uniformly thick layer is deposited on the rods: on the
- Feeding the bath current to the rods must be electrically conductive and therefore preferably consist of metal.
- the metal must therefore be protected by a plastic coating. However, this is prone to errors.
- a plating rack for holding a plurality of rod-shaped, preferably cylindrical objects, such as, for example, piston rods has been proposed in DE 25 24 31 5 A1.
- the cylindrical rods accommodated in sleeve-shaped receiving parts should be coated on the circumference with a layer thickness that is as uniform as possible.
- the rods be used during the electrochemical process Treatment to rotate around its longitudinal axis.
- the metal layer is delimited at the ends in the longitudinal direction of the rod by protective sleeves which are adjustable in length and individually tailored to the material to be treated.
- the electroplating frame is designed in such a way that it can be adapted to the rod length by means of vertically adjustable side parts.
- Electroplating of elongated, cylindrical bodies disclosed. These bodies are arranged concentrically in tubular anodes and fastened at one end in a stepped metal core. The cathodic current is supplied via this metal core. The metal core is separated from the electrolytic cell by an insulating body.
- the metal core and the insulating body limit the electroplating layer at the upper end of the material to be treated.
- the lower end is protected from unwanted galvanization by a protective sheet.
- each body to be galvanized must be individually attached and, moreover, the protective lacquer for masking the one end region of the treatment body must be applied accurately and detached again after completion of the metallization, the method described is technically complex and therefore likewise disadvantageous.
- the present invention is therefore based on the problem of to avoid parts of the known methods and devices and in particular a uniform electrochemical treatment of the elongated objects, a simple shielding of the objects on the areas not to be treated, whereby an exact limitation of the areas to be treated with narrow tolerances is achieved, a low carryover of the treatment liquids and To enable rinsing water from one bath to the following and an inexpensive electrochemical treatment of objects with different dimensions. In addition, many objects should be editable at the same time.
- the elongated objects are preferred
- Rods in particular round rods, which may be tapered at the ends or threaded, are electrochemically treated with a process with the following essential process steps:
- the method and the device can preferably be used to coat cylinders for vehicle shock absorbers and other rod-shaped parts, such as, for example, poppet valve shafts.
- the invention is not limited to the treatment of round bars; objects with other cross-sections can also be treated.
- an individual electrolytic cell with defined adjustable masks with sealants in the form of sealing sleeves is provided on both rod ends to delimit the surfaces to be treated.
- the single cell essentially comprises an electrode with a cavity, which is preferably tubular is well-trained. This is arranged essentially vertically in the immersion bath. As a result, the rods can be lowered into and preferably lifted out of the immersion bath in a preferably vertical position, so that the amount of carry-over from one bath to the next is minimized.
- Each rod is inserted into such a single cell.
- the tubular electrodes are as long as required for the longest rod to be treated.
- the area to be treated electrochemically on the object is adjusted by a relative axial movement of the object and the shielding mask to one another. Another possibility is to adjust the area to be treated electrochemically on the object by the depth of immersion of the object in the immersion bath.
- the shielding mask is designed as a sheath partially enclosing the object in the axial direction.
- a sealant is also provided on the shielding mask, which is in contact with the wall of the cavity.
- the shell is preferably tubular. The mask closes in the axial direction with the sealant, preferably in the form of a sleeve.
- the rod to be treated is inserted concentrically into the electrode until the product carrier is put down.
- the sealant has an opening for inserting the object.
- the sleeve is circular and the opening in the middle of the sleeve is provided.
- the shielding mask is held in the immersion bath by a suitable means (holder). Furthermore, a device for axial height adjustment of the shielding mask is provided.
- a lower shielding mask can also be arranged in the electrodes.
- the two coating boundaries on the rod are uniform for each product carrier on which all objects to be treated are attached are set, or for each row of goods carriers on which several objects to be treated are attached. A new adjustment of these settings is only necessary when changing the dimensions of the items to be treated for a subsequent goods carrier or a subsequent series of goods carriers.
- the bath flow is fed to the objects via the product carrier and the electrically conductive grippers.
- the individual electrodes are connected individually or together to the opposite pole of the bath current source.
- the gripper for the object essentially comprises a fixed leg and a movable leg, and clamping jaws fastened to the legs.
- the object is gripped by a means exerting a closing force on the clamping jaws.
- the rods can be lifted out of the bath and transferred to the subsequent treatment bath without wasting time, since the treatment solution or the rinsing water drips quickly, because the lower ends of the rod are free of masks and holders. At the upper end there is only one gripper with a small surface, so that in total are carried away together with only small amounts of liquid.
- the method enables the rod to be positioned in the center of a tubular electrode.
- the distance of all surface areas of the rod from the opposite electrode wall is the same over the entire circumference. This is a prerequisite for uniform electrochemical treatment, for example coating. Therefore, the rods no longer have to be reworked mechanically.
- the gripper according to the invention By using the gripper according to the invention with a fixed and a movable leg and when treating rods with very different diameters, the position of the rod axis relative to the gripper axis changes. This can be compensated for by different positioning of the gripper when the rod is lowered into the individual cell. In the case of the rod diameters that usually occur, two different sinking positions are sufficient to provide all the rod diameters that occur with a sufficiently uniform coating.
- sealing means In order to be able to treat objects with different dimensions electrochemically, further preferred embodiments of the sealing means are proposed: For the treatment of elongated objects, for example rods with varying diameters, two sealing means in the form of sleeves lying on top of one another can be used, each of which has an opening for insertion of the object through which it is passed, and radial incisions running towards the openings, wherein the incisions of the two sealants are arranged offset from one another. Furthermore, a plurality of sealing means lying one above the other in the form of sleeves can also be provided, which have openings for inserting the object with different diameters. To increase the mechanical flexibility of the sealing means at the point of penetration for the rods, sealing means with a thickness that decreases towards the opening are preferably used.
- At least one additional metal body which is electrically connected to the object and is arranged in the axial direction beyond the sealing means in the area not to be treated electrochemically can be provided. Its use reduces the electrical field line distribution focused on the object, so that the threshold value for the electrochemical treatment is no longer exceeded in this area.
- the envelope surrounding the object can also be extended into the area to be treated electrochemically.
- Another preferred embodiment is to use perforated electrodes. This makes it possible to convey the treatment liquid contained in the immersion bath against the object through the perforations in the electrode in order to achieve a targeted flow and thus influence the electrochemical treatment process.
- Figure 1 Goods carrier for transporting the material to be treated through the immersion bath system
- Figure 2a Schematic side view of a treatment station, partly in section
- Figure 2b Schematic plan view of a treatment station, partly in section;
- FIG. 3 Single cell in cross section
- Figure 4 Cuff in top view and in cross section for rods to be treated with different diameters
- Figure 5 Single cell in cross section, variant with an additional metallic body in the lower shielding area.
- the goods carrier shown in Figure 1 consists of a multi-part frame 1, which is placed on the frame supports 2 on the container for the treatment liquid.
- Pliers-shaped grippers 3 are attached to the frame.
- the grippers consist of a fixed leg 4 and a movable leg 5. The latter is rotatably mounted with an axis 6 in the leg 4.
- the clamping jaw 8 on the fixed leg is curved inwards with a cross section that is preferably trapezoidal.
- the clamping jaw 9 on the movable leg has the outwardly curved, spherical profile shown.
- Rods 10 with different shaft diameters can thus be gripped. When gripping, they are aligned exactly in the longitudinal direction of the gripper in the prism-shaped jaw. In the illustration in FIG. 1, the rods are arranged vertically.
- the jaws 8 and 9 can also be attached to the legs in a reversed configuration.
- the rods are exerted on the moveable bar! 5 gripped or released.
- a force for example exerted by a pressure cylinder in the direction of arrow 11, opens the gripper 3. All the grippers on the goods carrier are opened or closed using known methods and means of mechanical engineering. These are therefore not shown.
- a product carrier can hold 32 bars in the loading station. This process as well as the emptying process can be easily automated even with changing dimensions of the rods.
- the dimensions of the bars to be machined are at least the same size in each row in the product carrier.
- the carrying arms 12 are used to transport the goods carrier by means of a trolley from bath to bath.
- the frame 1 and the frame supports 2 and all the gripper parts are designed to be electrically conductive.
- the bath flow is fed to the goods carrier and thus to the items to be treated, that is to say the bars 10, via the frame supports.
- the support points are clamped for safe power conduction.
- the frames are expediently made of copper with a titanium sheath for protection against corrosion.
- the lower area of the metallic gripper immersed in the bath can optionally be minimally metallized. For this reason, at least this area of the grippers is provided with an insulating layer except for the clamping jaws. If necessary, the clamping jaws are demetallized chemically or electrolytically in an appropriate bath.
- the goods carrier is placed on the goods carrier receivers 15.
- the frame in the treatment bath 16 is positioned exactly by the frame supports 2 and the frame holder 15. The following are built into the treatment bath with the bath container 14:
- the aperture support is one with openings 18 for electrolyte interchangeable plastic plate with side supports 19.
- the supports are supported on both sides on height adjustment devices 20, which are moved in a defined manner by drives 21 shown symbolically.
- Cuff 24 which has a concentric hole, closed.
- the panel support comprises a plastic plate 13 which carries all of the upper tubular masks 26. At the same time, this plate covers the usually hot bath. This greatly reduces the escape of aggressive vapors.
- the masks are closed at the bottom with an elastic cuff 27 each.
- the rod to be treated protrudes into the individual cell 22 through a concentric hole in the cuff.
- the upper panel support is supported on both sides by height adjustment devices 28, which are moved in a defined manner by symbolically illustrated drives 29.
- Electrodes 30 for forming the individual cells 22 are Electrodes 30 for forming the individual cells 22:
- a tubular electrode 30 is installed stationary for each individual cell 22.
- the electrodes are fastened in an electrically conductive manner in an electrode insert 31.
- the insert is oriented so that the rods to be treated are positioned centrally in the tubular electrode 30 when the product carrier is put down.
- the rods 10 to be treated are brought into the individual cells 22 by means of the plant transport device and the goods carrier and are positioned there exactly in the x, y and z axes.
- the area to be treated electrochemically the rod is delimited at the top and bottom by the masks 23, 26 and by the sleeves 24, 27 in each individual cell.
- the position of the boundary is set specifically for each item to be treated, for a row on the goods carrier or for the entire goods carrier.
- the limitation for each product carrier is individually set automatically. If rods of different lengths are to be treated per row on the goods carrier, the limits for each row are adjusted individually.
- the target values for the adjustments are transmitted to the control system of the immersion bath system when the product carrier is loaded.
- the height of the upper and lower panel supports is set on the basis of these setpoints via the fine adjustment devices 20, 28.
- the actual height values are reported back to the control system from the system.
- This device enables a precise, partial treatment of rods with very different dimensions in a bath container without having to change this or the goods carrier.
- the polarity of the bath current supply lines is shown in FIGS. 2a and 2b for an electrochemical metallization. The polarity given in brackets applies to the electrochemical etching process.
- the treatment station is shown in a top view without a goods carrier.
- the bars 10, the clamping jaws 8, 9 and the legs 4, 5 of the gripper are shown as the only parts of the goods carrier.
- the upper diaphragm support 25 is not shown in order to reveal the view of the electrodes 30, the electrode insert 31 as well as the lower mask 23 and the lower sleeve 24.
- the single drives M1 and M2 for the height adjustments which are shown in simplified form for the sake of the drawing, can also be implemented by one drive for all support points of a panel support. Drive elements such as shafts and gears ensure parallel height adjustment.
- the current position of the panel supports is reported back to the control system by displacement sensors, not shown. This is thus able to move to any predetermined position of the diaphragm carrier in a targeted manner.
- the correct position of the panel supports 17, 25 can be approached before or after the product rack has been placed in the bath container 14
- the rod 10 to be treated can generally have a plurality of screwed-on shoulders 30, some with threads.
- the clamping jaws 8 and 9 grip the rod at the attachment 33.
- the rod is touched at one point via the clamping jaws 9, a half-cylinder, and is printed into the p ⁇ smen-shaped clamping jaw 8 for exact alignment.
- Both jaws are made of a wear-resistant, corrosion-resistant and electrically conductive material. It is advisable to attach the jaws to the legs of the grippers in an interchangeable manner.
- the tubular masks 23, 26, which are arranged in the electrode 30, can be adjusted in height. They are arranged concentrically to the electrode.
- the coverings for the rods are provided with an extension 35 on the side facing the treatment room 34 and an extension 36 below.
- These extensions mask the end of the surfaces to be treated in such a way that there is no increase or decrease in current density to the delimitation point 37 hm which are formed by the sleeves 24, 27. Without these extensions, a current density and thus layer thickness increase occurs during electrolytic metallization (so-called bone effect).
- These extensions are not limited to a cylindrical tube extension. Rather, these extensions can also have other shapes for adaptation to the individual cell. For example, funnel-shaped mask closings in both directions are also suitable, i.e. funnels drawn in or opening. Furthermore, the extensions can also be provided with openings.
- FIG. 5 shows such a curvature of the cuff, which is achieved by a downward movement of the rod.
- the cuffs 24, 27 tightly enclose the rod 10. They preferably consist of an elastic material that is wear and corrosion resistant. Films made of plastic, such as FPM (fluorine / rubber plastic), are suitable.
- the sleeves have a round opening that is not larger than the smallest rod diameter at the limiting point 37. They are fastened in the tube so that the opening lies in the center of the mask.
- a cuff can also be attached in a floating manner in the tubular masks. The cuff then lies close to the rod even when the axes of rod 10 and mask 23, 26 are not aligned.
- the cuff has a multilayer pinnate structure. This allows the treatment of rods with large differences in diameter at the delimitation point 37. With a long service life of the sleeves, rods with very different rod diameters can also be produced in one system. Such is shown in FIG Cuff shown.
- the individual layers are offset from one another in such a way that the cuts 42 in one sleeve film are covered by the other film. The same applies to other locations. It is also advantageous if the layers have stepped diameters of the central opening 40. In this case, the limitation point
- the layers are gripped by a cuff holder 41.
- the holder is fixed or floating in the mask.
- the sleeves 24, 27 can also be designed such that their thickness decreases in the radial direction from the outside to the center.
- the thickness can decrease continuously, as shown in FIG. 5, or in steps. This has the advantage that the sleeve is very flexible in the penetration area of the rod, although the sleeve is very dimensionally stable in the area of the outer diameter.
- the sleeve consists of electrically non-conductive brushes.
- the brushes are fastened in the cuff holder and point radially to the cuff center. In the case of dense bristles, reliable masking and a long service life are also achieved with this.
- the measures for field-free spaces 38, 39 are essentially met by the measures described above, for example when using feathered sleeves or if the tolerances between the axis of the rod and the axis of the masks 23, 26 are too great, electrical field lines from the treatment space 34 in the largely field-free Penetrate spaces. If the field line density in these rooms is so small that this results in a current density at the end regions of the rod that are not to be coated, which is below the threshold value for an electrolytic treatment, for example a metal deposition, no electrochemical treatment takes place. However, if the field line density in these rooms is so large that the threshold value is exceeded, the areas not to be treated are treated electrochemically. For example, metal is deposited. The resulting layer is considerably thinner than the layer deposited in the area of the treatment room. However, an additional one is undesirable for their removal
- the threshold value in the lower space 39 can be exceeded more easily .
- an enlargement of the metal surfaces located in this space 39, which are at the same electrical potential as the rod, is provided.
- a metallic body 44 is arranged in the center of the space 39. This is freely movable in the axial direction. For this purpose, it is attached to a holding element 45 made of non-conductive material, which is guided in the mask 23.
- the holding element 45 can either as
- Float be formed so that it is pressed upward in the liquid, or it is displaced upwards by a spring 46 arranged between the holding element and the lower diaphragm support 17. In both measures, the metallic body 44 rests on the lower sleeve 24 when there is no rod in the single cell 22.
- the electrode 30 is preferably designed as an insoluble electrode.
- the electrode can be designed, for example, as a perforated tube so that a good electrolyte exchange can take place in the treatment room 34.
- An expanded metal grid from which the electrode is formed is suitable, for example.
- a further electrolyte exchange takes place through the gap 43 (FIG. 3). If the diameter of the masks 23, 26 and the inner diameter of the electrode are the same size and the masks are firmly connected to the electrode, then the gap 43 is omitted. In this case, the electrodes can be adjusted telescopically together with the mask adjustment. In this case, the electrolyte in the treatment room 34 is exchanged solely via the electrode perforations.
- the surface of the electrode must be chemically and electrochemically resistant. Surface coatings
- Platinum or mixed oxides are so stable that the electrodes have a long service life.
- the electrodes are connected to the electrode insert in an electrically conductive manner.
- the bath power source is connected to all electrodes via this insert.
- An individual bath current source can be assigned to each electrode for particularly precise or individual treatment.
- the electrodes are attached to the electrode insert in an electrically insulated manner and connected to the respective current source with an insulated cable. In special cases, the electrode can also be soluble.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP50938898A JP4139439B2 (ja) | 1996-08-09 | 1997-08-07 | 棒状の対象物を電気化学的に処理するための方法と装置 |
EP97940064A EP0874921B1 (de) | 1996-08-09 | 1997-08-07 | Verfahren und vorrichtung zum elektrochemischen behandeln langgestreckter gegenstände |
DE59700999T DE59700999D1 (de) | 1996-08-09 | 1997-08-07 | Verfahren und vorrichtung zum elektrochemischen behandeln langgestreckter gegenstände |
US09/170,356 US6168691B1 (en) | 1996-08-09 | 1998-10-13 | Device for electrochemical treatment of elongate articles |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19632132A DE19632132C1 (de) | 1996-08-09 | 1996-08-09 | Verfahren zur elektrochemischen Behandlung von stabförmigem Behandlungsgut und Vorrichtung zur Durchführung des Verfahrens |
DE19632132.8 | 1996-08-09 | ||
DE19722983A DE19722983C2 (de) | 1996-08-09 | 1997-06-02 | Verfahren zur elektrochemischen Behandlung von stabförmigem Behandlungsgut und Vorrichtung zur Durchführung des Verfahrens |
DE19722983.2 | 1997-06-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998006884A1 true WO1998006884A1 (de) | 1998-02-19 |
Family
ID=26028257
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1997/004341 WO1998006884A1 (de) | 1996-08-09 | 1997-08-07 | Verfahren und vorrichtung zum elektrochemischen behandeln langgestreckter gegenstände |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0874921B1 (de) |
JP (1) | JP4139439B2 (de) |
ES (1) | ES2142690T3 (de) |
WO (1) | WO1998006884A1 (de) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19822196A1 (de) * | 1998-05-16 | 1999-11-18 | Lemfoerder Metallwaren Ag | Verfahren zur selektiven, bereichsweisen Beschichtung metallischer Bauteile und Vorrichtung zur Durchführung des Verfahrens |
WO2015055537A1 (de) * | 2013-10-17 | 2015-04-23 | Damm Oberflächentechnik Gmbh & Co. Kg | Verfahren und vorrichtung zum beschichten von kopfstützbügeln oder kopfstützstangen |
WO2016098087A3 (de) * | 2014-12-19 | 2016-08-18 | Weber-Hydraulik Gmbh | Verfahren zum optischen beschriften und/oder markieren von rundmaterial |
CN108637604A (zh) * | 2018-05-14 | 2018-10-12 | 山推工程机械股份有限公司 | 一种油缸轴的制备方法 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4910347B2 (ja) * | 2005-09-27 | 2012-04-04 | トヨタ自動車株式会社 | スペーサを兼ねた集電電極を備えた燃料電池セルモジュール |
US8394253B2 (en) | 2010-11-16 | 2013-03-12 | Strategic Resource Optimization, Inc. | Electrolytic system and method for generating biocides having an electron deficient carrier fluid and chlorine dioxide |
JP6282773B1 (ja) | 2017-06-30 | 2018-02-21 | 株式会社ショーワ | マスキング治具、電気メッキ装置 |
WO2024095404A1 (ja) * | 2022-11-02 | 2024-05-10 | 日立Astemo株式会社 | マスキング治具、電気メッキ装置 |
Citations (3)
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EP0024964A1 (de) * | 1979-08-03 | 1981-03-11 | Centre Technique Des Industries Mecaniques | Vorrichtung zur elektrolytischen Plattierung und diese Vorrichtung verwendendes Verchromungsverfahren |
US4419194A (en) * | 1981-05-20 | 1983-12-06 | Brevetti Elettrogalvanici Superfiniture S.R.L. | Method and apparatus for continuously chromium-plating |
EP0196251A1 (de) * | 1985-03-12 | 1986-10-01 | Commissariat A L'energie Atomique | Vorrichtung zur Erzeugung einer elektrolytischen Metallschicht konstanter Dicke |
-
1997
- 1997-08-07 WO PCT/EP1997/004341 patent/WO1998006884A1/de active IP Right Grant
- 1997-08-07 EP EP97940064A patent/EP0874921B1/de not_active Expired - Lifetime
- 1997-08-07 JP JP50938898A patent/JP4139439B2/ja not_active Expired - Lifetime
- 1997-08-07 ES ES97940064T patent/ES2142690T3/es not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0024964A1 (de) * | 1979-08-03 | 1981-03-11 | Centre Technique Des Industries Mecaniques | Vorrichtung zur elektrolytischen Plattierung und diese Vorrichtung verwendendes Verchromungsverfahren |
US4419194A (en) * | 1981-05-20 | 1983-12-06 | Brevetti Elettrogalvanici Superfiniture S.R.L. | Method and apparatus for continuously chromium-plating |
EP0196251A1 (de) * | 1985-03-12 | 1986-10-01 | Commissariat A L'energie Atomique | Vorrichtung zur Erzeugung einer elektrolytischen Metallschicht konstanter Dicke |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19822196A1 (de) * | 1998-05-16 | 1999-11-18 | Lemfoerder Metallwaren Ag | Verfahren zur selektiven, bereichsweisen Beschichtung metallischer Bauteile und Vorrichtung zur Durchführung des Verfahrens |
DE19822196C2 (de) * | 1998-05-16 | 2000-05-11 | Lemfoerder Metallwaren Ag | Verfahren zur selektiven bereichsweisen Beschichtung metallischer Bauteile und Vorrichtung zur Durchführung des Verfahrens |
WO2015055537A1 (de) * | 2013-10-17 | 2015-04-23 | Damm Oberflächentechnik Gmbh & Co. Kg | Verfahren und vorrichtung zum beschichten von kopfstützbügeln oder kopfstützstangen |
WO2016098087A3 (de) * | 2014-12-19 | 2016-08-18 | Weber-Hydraulik Gmbh | Verfahren zum optischen beschriften und/oder markieren von rundmaterial |
CN107002268A (zh) * | 2014-12-19 | 2017-08-01 | 德万波液压有限公司 | 用于圆形材料的光学铭刻和/或标记的方法 |
US20170362730A1 (en) * | 2014-12-19 | 2017-12-21 | Weber-Hydraulik Gmbh | Method for optically inscribing and/or marking round stock |
US10557209B2 (en) | 2014-12-19 | 2020-02-11 | Weber-Hydraulik Gmbh | Method for optically inscribing and/or marking round stock |
CN108637604A (zh) * | 2018-05-14 | 2018-10-12 | 山推工程机械股份有限公司 | 一种油缸轴的制备方法 |
Also Published As
Publication number | Publication date |
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EP0874921B1 (de) | 2000-01-12 |
JP4139439B2 (ja) | 2008-08-27 |
EP0874921A1 (de) | 1998-11-04 |
ES2142690T3 (es) | 2000-04-16 |
JP2000516303A (ja) | 2000-12-05 |
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